KR100878283B1 - Method for preparing seasoned seaweed seasoned with garlic salt and seasoned seaweed prepared from - Google Patents
Method for preparing seasoned seaweed seasoned with garlic salt and seasoned seaweed prepared from Download PDFInfo
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/60—Edible seaweed
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/10—Natural spices, flavouring agents or condiments; Extracts thereof
- A23L27/105—Natural spices, flavouring agents or condiments; Extracts thereof obtained from liliaceae, e.g. onions, garlic
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/40—Table salts; Dietetic salt substitutes
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- Life Sciences & Earth Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Edible Seaweed (AREA)
Abstract
본 발명은 마늘소금으로 조미된 조미김의 제조방법 및 그로부터 제조된 조미김에 관한 것이다.The present invention relates to a method of preparing seasoned seaweed seasoned with garlic salt and seasoned seaweed prepared therefrom.
본 발명의 조미김의 제조방법은 원료 김 표면에 기름을 발라 250 내지 280℃에서 1차 배소(焙燒)하고; 상기 1차 구이김에 소금 100 중량부에 대하여, 마늘 분말 30 내지 200 중량부로 혼합하여 제조된, 마늘소금을 뿌려 조미하고; 마늘의 함유성분과 원료 김의 지방산과의 항산화 작용으로 조미김의 과산화지질 생성을 억제함으로써, 가공 후 저장성이 연장되고 산화가 억제되어 마늘함유 기능성이 부여되고 바삭한 식감이 유지된 조미김을 제공할 수 있다. 이에, 본 발명의 마늘소금으로 조미된 조미김의 제조방법은 가공과 저장과정 중 품질을 향상시키고, 건강기능성을 강화할 수 있는 고부가가치 제품생산을 구현할 수 있다. The method for preparing seasoned laver of the present invention is to firstly roast at 250 to 280 ° C by lubricating the raw laver surface; 100 parts by weight of the first roasted salt, garlic powder prepared by mixing 30 to 200 parts by weight of salt, sprinkled with garlic salt; By inhibiting the formation of peroxidized lipids of seasoned seaweed by the antioxidant activity between the ingredients of garlic and fatty acids of raw seaweed, the shelf life after processing is prolonged and oxidation is suppressed, which gives garlic-containing functionality and maintains crispy texture. Can be. Thus, the method of manufacturing seasoned seaweed seasoned with garlic salt of the present invention can implement high value-added products that can improve quality during processing and storage, and enhance health functionality.
Description
본 발명은 마늘소금으로 조미된 조미김의 제조방법 및 그로부터 제조된 조미김에 관한 것으로서, 더욱 상세하게는 조미김의 제조단계에 마늘 소금으로 조미하여 제조함으로써, 마늘의 함유성분과 원료 김의 지방산과의 항산화 작용으로 조미김의 과산화지질 생성을 억제하여 가공 후, 저장성이 연장되고 산화가 억제되어 마늘함유 기능성이 부여되고, 바삭한 식감이 유지된 조미김의 제조방법 및 그로부터 제조된 마늘소금으로 조미된 조미김에 관한 것이다.The present invention relates to a method of preparing seasoned seaweed seasoned with garlic salt and seasoned seaweed prepared therefrom, and more specifically, by preparing seasoning with garlic salt in the seasoning step of seasoning seaweed, The antioxidative action of seasoning laver prevents the formation of lipid peroxide, and after processing, shelf life is prolonged and oxidation is inhibited, and garlic-containing function is given, and the crispy texture is preserved and seasoned with garlic salt prepared therefrom. It is about seasoned seaweed.
김은 높은 영양가와 독특한 풍미를 함유하고 있는 대표적인 해조가공품의 하나로서, 국민소득 향상과 식생활의 개선에 따라 편의 위주의 소포장, 간편, 즉석식품과 건강지향의 기능성 식품 중심으로 발달함에 따라, 최근 조미김의 생산 및 그 소비가 날로 증가하고 있다.Seaweed is one of the representative seaweed products with high nutritional value and unique flavor. As it is developed as a convenience-oriented small package, convenience, instant food, and health-oriented functional food in accordance with the improvement of national income and diet, recent seasoning The production and consumption of seaweed is increasing day by day.
이러한 조미김의 시장은 단순히 소금을 뿌려 구워진 포장된 배소김의 형태에서부터 조미김 제조단계에 기능성 소재를 가미하여, 그 기능성 소재로부터 기능성이 동시 에 부여된 조미김 형태로 확대되고 있다.The market of seasoned seaweed is expanding from the form of simply roasted roasted seaweed to the seasoned seaweed making step by adding functional material, and from the functional material to seasoned seaweed.
그러나, 조미김은 고온의 가열처리 과정을 거치므로 저장 유통 중 지방질의 산화, 색소의 파괴, 이미, 이취 등이 발생하여 품질이 급격히 저하된다. 이러한 가공 중 열에 대한 안정성과 저장중의 안정화의 문제는 원료 김의 성분차이 및 건조 김의 가공 특성에 의한 내적인 요인과 저장, 유통 중 산화되는 외적인 요인에 의해 야기된다. However, seasoned laver is subjected to a high temperature heat treatment, so oxidation of fat, destruction of pigments, odor, odor, etc. occur during storage and circulation, and the quality is drastically deteriorated. The problem of stability to heat during processing and stabilization during storage is caused by internal factors due to the difference in composition of raw seaweed and processing characteristics of dried seaweed and external factors which are oxidized during storage and distribution.
지방질 산화의 내적인 요인으로 원료 김에는 이피에이(EPA) 등의 고도불포화지방산 함량이 50% 이상 함유되어 있고, 산화촉진제로 작용할 수 있는 클로로필이 400∼700㎎으로 함유되어 있다. 특히, 조미김은 200∼230℃의 고온에서 10∼15초간 배소하고 10∼15%의 유지류로 도포되기 때문에 조미김의 지방질 산화는 더욱 촉진된다.As an internal factor of lipid oxidation, raw seaweed contains 50% or more of polyunsaturated fatty acid such as EPA and 400-700mg of chlorophyll which can act as an oxidation promoter. In particular, since seasoning laver is roasted for 10 to 15 seconds at a high temperature of 200 to 230 ° C. and applied with 10 to 15% of oil or fat, lipid oxidation of seasoning laver is further promoted.
또한, 지방질 산화의 외적인 요인으로는 저장, 유통 중 저장온도, 외기습도, 포장방법, 광원 등을 들 수 있다.In addition, external factors of lipid oxidation include storage temperature during storage, circulation, outside air humidity, packaging method, light source, and the like.
이에, 조미김 분야에서는 지방질 산화를 억제하여 품질 향상을 꾀하고자 부단히 노력하고 있다. 그 일례로는 원료 김을 40∼60℃에서 단순 건조하여 수분함유량을 10∼15%로 조절함으로써, 배소온도, 저장온도, 수분활성도, 광원, 포장 조건 등 최적의 가공 및 저장조건을 찾고자 연구가 집중되고 있다. 그 결과, 평균수분이 건조김의 안정성에 가장 큰 영향을 미치며 성분 중 색소와 유리아미노산의 변화가 품질변화에 크게 작용하므로, 이와 같은 기술개발의 방향은 그 요인이 다양하고 상호작용을 하기 때문에 최적화시키기 어려울 뿐만 아니라 최적조건을 찾아내더라도 경 쟁력이 약하고 영세한 건조김 제조의 생산라인에 모두 적용하기 어려운 문제점이 있다.Therefore, in the field of seasoned seaweed, efforts are continuously made to improve quality by inhibiting lipid oxidation. For example, by simply drying the raw laver at 40 ~ 60 ℃ and adjusting the water content to 10 ~ 15%, researches to find the optimum processing and storage conditions such as roasting temperature, storage temperature, water activity, light source, packaging condition, etc. It is concentrated. As a result, the average moisture has the greatest influence on the stability of the dried seaweed and the change of pigment and free amino acid among the components greatly affects the quality change. Therefore, the direction of such technology development is optimized because the factors vary and interact. Not only are they difficult to make, but even when the optimum conditions are found, there is a problem that it is difficult to apply them all to the production line of the production of small and dry laver.
최근에는 항산화제인 NaAr가 색소와 지방질 산화 억제에 효과적이라는 연구결과로부터, 건조 김의 지방질 산화를 억제하기 위하여, 항산화제를 처리하는 보다 적극적인 방법이 시도되고 있으나, 아직까지 기술개발수준이 미흡한 실정이다.Recently, the research results that antioxidant antioxidant NaAr is effective in inhibiting pigment and fat oxidation, a more active way to treat antioxidants to suppress the fat oxidation of dried seaweed, but the technology development level is still insufficient. .
또한, 김은 생산시기, 장소 및 제조방법에 따라 품질이 매우 다양하며, 특히 저장유통조건 등이 적당하지 않으면 품질이 쉽게 저하되어 색택이나 향미 등이 저하된다. 따라서 김의 저장에 있어서 무엇보다 색택의 기본이 되는 색소성분의 변화를 억제하는 것이 중요하다. In addition, the quality of the seaweed varies greatly depending on the production time, place and manufacturing method, especially if the storage and distribution conditions are not suitable, the quality is easily degraded, color gloss or flavor is reduced. Therefore, in the storage of seaweed, it is important to suppress the change of the pigment component which is the basis of color tack above all.
상기 문제를 해결하기 위한 기존 연구개발 결과, 김의 건조 시 열처리 온도가 낮을수록 색소함량의 감소가 적었고 저장 중에 색소류의 안정도는 제품의 최종수분함량에 따라 매우 다르다는 연구결과로부터, 김의 가공 시 색소의 변화를 방지하기 위해 항산화제를 처리하기도 한다.As a result of the existing research and development to solve the above problem, the lower the heat treatment temperature during drying of the seaweed, the smaller the decrease in pigment content, and the stability of the dyes during storage was very different depending on the final moisture content of the seaweed. Some antioxidants are treated to prevent pigment changes.
그러나 항산화제는 대부분 고가이고, 합성 화합물계 항산화제의 사용에 따른 부작용에 대한 우려가 예상되고 최근 소비자들의 웰빙 트렌드에 상충되므로, 시장경쟁력이 저하된다.However, most of the antioxidants are expensive, and concerns about side effects from the use of synthetic compound antioxidants are anticipated and conflict with the well-being trends of consumers.
현재 김을 소비하고 생산하는 국가는 대한민국, 일본, 중국 등으로 극히 국소적이었으나, 최근 서구인의 동양 식사나 식품에 대한 요구가 증가하고 있기 때문에, 앞으로 한중일을 중심으로 김의 세계적인 시장규모는 점차 증가할 것으로 예상된다. 따라서, 김의 품질을 향상시키는 기술력의 보유는 국제적인 제품 경쟁력을 강화시 키는 산업분야로 성장할 것이다. Currently, the countries that consume and produce seaweed have been extremely local to Korea, Japan, and China. However, as the demand for western foods and foods from Westerners is increasing recently, the global market size of seaweed is gradually increasing. It is expected to. Therefore, holding the technology to improve the quality of seaweed will grow into an industrial field to strengthen the international product competitiveness.
이에, 본 발명자들은 종래의 조미김이 가공 후, 지방질의 산화로 인해 야기되는 품질저하를 최소화하기 위하여 노력한 결과, 제조 과정에 마늘소금으로 조미하여 마늘의 함유성분과 원료 김의 지방산과의 항산화 작용으로 조미김의 과산화지질 생성을 억제한다는 사실을 발견하고, 최종 제품인 조미김의 저장기간을 연장시키고 산화를 억제하여 마늘함유 기능성을 부여하고 바삭거리는 식감을 장시간 유지할 수 있으므로, 가공과 저장과정 중 품질을 향상시키고, 건강기능성을 강화할 수 있는 고부가가치 제품생산을 구현함으로써, 본 발명을 완성하였다.Therefore, the present inventors tried to minimize the quality degradation caused by the oxidation of fat after processing the conventional seasoning seaweed, seasoned with garlic salt in the manufacturing process, the antioxidant action of the components of garlic and fatty acids of raw seaweed Discovered that it inhibits lipid peroxide formation of seasoned seaweed, and extends the shelf life of seasoned seaweed as a final product and inhibits oxidation to give garlic-containing functionality and maintain crispy texture for a long time. The present invention has been completed by implementing a high value-added product that can improve and enhance the health functionalities.
본 발명의 목적은 원료 김에 마늘소금으로 조미하여 제조되는 조미김의 제조방법을 제공하는 것이다.It is an object of the present invention to provide a method for preparing seasoned seaweed, which is prepared by seasoning with garlic salt in raw seaweed.
본 발명의 다른 목적은 상기 제조방법으로 제조되어, 저장성이 연장되고 산화가 억제되어 마늘함유 기능성이 부여되고, 바삭한 식감이 유지된 마늘소금으로 조미된 조미김을 제공하는 것이다.Another object of the present invention is to provide a seasoning seasoned with garlic salt prepared by the above production method, storage shelf life is prolonged, oxidation is suppressed, garlic-containing functionality, crispy texture maintained.
상기 목적을 달성하기 위하여, 본 발명은 원료 김 표면에 기름을 발라 250 내지 280℃에서 1차 배소하고; 상기 1차 구이김에 소금 100 중량부에 대하여, 마늘 분말 30 내지 200 중량부로 혼합하여 제조된, 마늘소금을 뿌려 조미하고, 마늘소금으로 조미된 조미김의 제조방법을 제공한다.In order to achieve the above object, the present invention is the primary roasting at 250 to 280 ℃ lubricating the raw seaweed surface; With respect to 100 parts by weight of salt to the first roasted seaweed, prepared by mixing 30 to 200 parts by weight of garlic powder, sprinkled with garlic salt, seasoning with garlic salt provides a method for producing seasoned seaweed.
상기 마늘소금이 0.3 내지 1.5g/㎠의 양으로 뿌려 조미되는 것이며, 상기 마늘 분말은 동결 건조한 후, 분쇄하여 제조되되, 상기 마늘 분말의 수분함량이 2 내지 3%를 충족한다. 또한, 상기 원료 김의 수분 함량은 10 내지 11%를 충족한다. The garlic salt is seasoned by sprinkling with an amount of 0.3 to 1.5g / ㎠, the garlic powder is prepared by crushing after drying, the moisture content of the garlic powder satisfies 2 to 3%. In addition, the moisture content of the raw seaweed meets 10 to 11%.
또한, 본 발명은 상기 제조방법으로 제조되되, 마늘의 함유성분과 원료 김의 지방산과의 항산화 반응으로, 과산화지질의 생성이 억제되므로 저장성이 연장되고 건강 기능성이 향상되며 바삭한 식감이 유지된, 마늘소금으로 조미된 조미김을 제공한다.In addition, the present invention is prepared by the manufacturing method, the antioxidant reaction between the ingredients of garlic and fatty acids of raw seaweed, the production of lipid peroxide is suppressed, so that the shelf life is extended, the health function is improved and the crispy texture is maintained, garlic Provide seasoned seaweed seasoned with salt.
본 발명은 가공 후, 지방산의 산화로 인해 제품 품질 저하의 문제를 해소한 조미김의 제조방법을 제공하였다.The present invention provides a method for producing seasoned seaweed, after processing, which solves the problem of product quality deterioration due to oxidation of fatty acids.
본 발명은 조미김의 제조단계에, 마늘 분말이 함유된 마늘소금으로 조미함으로써, 마늘의 함유성분과 원료 김의 지방산과의 항산화 반응으로, 과산화지질의 생성량을 억제함으로써, 저장성이 연장되고 산화가 억제되어 마늘함유 기능성이 부여되고, 바삭한 식감이 유지된, 마늘소금으로 조미된 조미김을 제공할 수 있다.The present invention is seasoned with garlic salt containing garlic powder in the production step of seasoned seaweed, and by the antioxidant reaction between the ingredients of garlic and fatty acids of raw seaweed, by suppressing the amount of lipid peroxide produced, the shelf life is extended and oxidation It is possible to provide seasoned seaweed seasoned with garlic salt, which is suppressed and endowed with garlic-containing functionality and maintains a crispy texture.
이하, 본 발명을 상세히 설명하고자 한다.Hereinafter, the present invention will be described in detail.
본 발명은 조미김의 가공 후, 지방질의 산화로 인한 저장안정성이 저하되는 종래의 문제점을 해소하기 위하여, 제조단계에서 항산화력이 우수한 마늘 분말을 함유한 마늘소금으로 조미하는 것으로 이루어진 조미김의 제조방법을 제공한다.The present invention, after the processing of seasoning laver, in order to solve the conventional problem that the storage stability due to oxidation of fat is reduced, the production of seasoning laver consisting of seasoning with garlic salt containing garlic powder with excellent antioxidant power in the manufacturing step Provide a method.
더욱 상세하게는 원료 김 표면에 기름을 발라 250 내지 280℃에서 1차 배소하고; 상기 1차 구이김에 소금 100 중량부에 대하여, 마늘 분말 30 내지 200 중량부로 혼합하여 제조된, 마늘소금으로 조미된 조미김의 제조방법을 제공하는 것이다.More specifically, the surface of the raw laver is oiled and roasted first at 250 to 280 ° C .; With respect to 100 parts by weight of the salt to the first roasting, prepared by mixing 30 to 200 parts by weight of garlic powder, to provide a seasoning seasoned with garlic salt seasoning.
본 발명에서 사용되는 마늘(Allium Sativum L.)은 백합과 파속에 속하는 호냉성 월동 채소작물로서, 오래 전부터 항균, 항암, 항혈전 작용, 암세포 성장 억제작용, 콜레스테롤 저하 및 노화방지 작용을 한다는 보고로부터, 건강 유지에 유익한 식품으로 알려져 왔다.Garlic ( Allium Sativum L. ) used in the present invention is a cold-frozen winter vegetables belonging to the genus Liliaceae. It is known as a food beneficial for maintaining health.
특히, 국내의 경우, 김치류의 부재료 또는 양념류로 사용되어 온 마늘은 알리신, 다이아릴 다이설피드 등의 1, 2차 생성물을 함유하여 생체기능을 조절하는 것으로, 상기 생성물의 싸이오설피네이트(thiosulfinate)가 생리적으로 중요한 -SH와 강하게 반응하여 각종 효능을 강하게 나타낼 뿐만 아니라 티아민(thiamine)과 반응하여 알리티아민(allithiamine)을 생성, 티아민의 체내작용을 높여주는 독특한 생리활성이 보고된 바 있다. Particularly, in Korea, garlic, which has been used as an ingredient or seasoning for kimchi, contains primary and secondary products such as allicin and diaryl disulfide to control biological functions, and thiosulfinate of the product. ) Reacts strongly with -SH which is physiologically important, and shows various effects, and has also been reported to generate alliamine by reacting with thiamin (thiamine), thereby enhancing the physiological activity of thiamin.
따라서, 본 발명에서 마늘을 사용하여 조미김을 제조함으로써, 가공 후 저장과정에서 발생하는 품질 저하를 최소화하는 동시에 건강 기능성을 강화할 수 있다.Therefore, by preparing the seasoning laver using garlic in the present invention, it is possible to minimize the deterioration of the quality generated during the storage after processing and at the same time enhance the health functionality.
본 발명의 마늘소금으로 조미된 조미김의 제조방법에서, 마늘소금은 마늘 분말을 동결 건조한 후, 통상의 방법으로 분쇄하여 제조되되, 상기 마늘 분말의 수분함량이 2 내지 3%를 충족하고, 원료 김의 수분함량을 10 내지 11% 이내로 조절하여 최종 제품 내 수분으로 인한 품질저하문제를 최소화할 수 있다. In the method of preparing seasoned seaweed seasoned with garlic salt of the present invention, garlic salt is prepared by freeze-drying garlic powder and then pulverizing by a conventional method, and the moisture content of the garlic powder satisfies 2 to 3%, and 10 ~ 11% water content of seaweed It can be adjusted within to minimize the quality degradation problem caused by moisture in the final product.
본 발명의 마늘소금으로 조미된 조미김의 제조방법에서, 원료 김을 250 내지 280℃에서 1차 배소하고, 마늘소금으로 조미된 후, 380 내지 400℃에서 2차 배소함으로 써, 원료 김을 두 번 구워 자체 내 함유하고 있는 고도불포화지방산과 클로로필의 함량을 낮출 수 있다.In the method of preparing seasoned seaweed seasoned with garlic salt of the present invention, the raw seaweed is first roasted at 250 to 280 ° C, seasoned with garlic salt, and then the second roasted at 380 to 400 ° C. It can reduce the content of polyunsaturated fatty acids and chlorophyll in itself.
본 발명에서 사용되는 마늘소금은 상기 분쇄된 마늘 분말을 소금 100 중량부에 대하여, 30 내지 200 중량부로 혼합하여 제조된다. 이때, 마늘 분말의 함량이 30 중량부 미만이면, 마늘 분말로부터 얻고자 하는 항산화성이 미약하여 바람직하지 않고, 200 중량부를 초과하면, 저장성은 만족할만 하나, 과량의 마늘 분말로 인하여, 마늘 특유의 아린 식감이 부여되어 상품 기호도에 불리하다. Garlic salt used in the present invention is prepared by mixing the ground garlic powder with respect to 100 parts by weight of salt, 30 to 200 parts by weight. At this time, if the content of garlic powder is less than 30 parts by weight, it is not preferable because the antioxidant properties to be obtained from the garlic powder is weak, and if it exceeds 200 parts by weight, the shelf life is satisfactory, but due to the excess garlic powder, Arin's texture is imparted, which is disadvantageous in terms of product preference.
상기 제조된 마늘소금은 1차 구이김에 0.3 내지 1.5g/㎠의 양으로 되도록 조미되는 것이 바람직하며, 이때, 마늘소금의 양이 0.3g/㎠ 미만이면, 조미가 약하여 선호도를 낮출 수 있을 뿐 아니라, 마늘소금으로 얻고자 하는 항산화 작용이 미흡하고, 반면에, 1.5g/㎠을 초과하면, 최종제품인 조미김에 과다한 마늘맛과 짠맛 감소로 인해 식미감을 저하시킨다. The prepared garlic salt is 0.3 to the primary roasting The seasoning is preferably 1.5g / cm 2, and if the amount of garlic salt is less than 0.3g / cm 2, the seasoning is weak and not only lower the preference, but also the antioxidant activity to be obtained with garlic salt is insufficient. On the other hand, when the content exceeds 1.5g / cm 2, the flavor is reduced due to excessive garlic and salty taste in the final seasoned seaweed.
또한, 본 발명은 상기 제조방법으로 제조되되, 마늘소금의 성분과 원료 김의 지방산과의 항산화 반응으로, 과산화지질의 생성량이 억제되어 저장성이 연장되고 건강 기능성이 향상되며 바삭한 식감이 유지된, 마늘소금으로 조미된 조미김을 제공한다.In addition, the present invention is prepared by the above method, by the antioxidant reaction of the components of garlic salt and fatty acids of raw seaweed, the amount of production of lipid peroxide is suppressed, the shelf life is extended, the health function is improved, the crispy texture is maintained, garlic Provide seasoned seaweed seasoned with salt.
특히, 도 1은 본 발명의 마늘소금으로 조미된 조미김에 대하여 과산화지질의 생성량 측정결과를 도시한 것으로서, 본 발명의 조미김에 가미된 마늘 소금은 원료 김의 성분 중, 지방산과 항산화 반응하여 과산화지질의 생성을 억제한 결과를 보이며, 상기 과산화지질의 생성 억제능은 마늘소금을 사용하지 않고 종래의 소금으로 제조된 조미김의 경우보다, 50 내지 80% 정도 감소된 결과를 보인다[표 5]. 따라서, 본 발명의 마늘소금으로 조미된 조미김은 가공 후, 저장 기간동안 지방질의 산화로 인한 품질저하의 문제를 해소할 수 있다. In particular, Figure 1 shows the results of measurement of the production amount of lipid peroxide for seasoned seaweed seasoned with garlic salt of the present invention, the garlic salt seasoned with seasoning seaweed of the present invention is an antioxidant reaction with fatty acids in the ingredients of raw seaweed, lipid peroxide It shows the result of suppressing the production of the lipid peroxide production inhibition ability shows a 50 to 80% reduced results than in the case of seasoned seaweed made with conventional salt without using garlic salt [ Table 5 ]. Therefore, seasoned seaweed seasoned with garlic salt of the present invention can solve the problem of deterioration due to oxidation of fat during storage and after processing.
또한, 상기 과산화지질의 생성억제로부터, 본 발명의 조미김은 지방질 산화로 인한 기름의 찌든 냄새와 맛(이취, 이미)이 없고, 초기 가공시의 바삭한 식감을 적어도 6개월 이상 유지할 수 있다[표 6].Further, from the generated inhibition of lipid peroxide, seasoned laver of the present invention has no odor stricken due to lipid oxidation of oil and flavor (odor, already), and a crispy texture of the initial processing can be maintained for at least 6 months Table 6 ].
따라서, 본 발명의 마늘소금을 이용한 조미김은 합성 화합물인 항산화제를 사용하지 않으면서도 가공 후, 저장과정 중 품질을 향상시키고 건강기능성을 강화할 수 있는 고부가가치 제품이다.Therefore, seasoned seaweed using garlic salt of the present invention is a high value-added product that can improve the quality and enhance the health functionality during the storage process after processing without using the antioxidant compound which is a synthetic compound.
이하, 실시예를 통하여 본 발명을 보다 상세히 설명하고자 한다. Hereinafter, the present invention will be described in more detail with reference to Examples.
본 실시예는 본 발명을 보다 구체적으로 설명하기 위한 것이며, 본 발명의 범위가 이들 실시예에 한정되는 것은 아니다. This embodiment is intended to illustrate the present invention in more detail, and the scope of the present invention is not limited to these examples.
<실시예 1><Example 1>
2006년산 태안 6쪽 마늘을 동결 건조한 후 분쇄기로 분쇄하여 마늘 분말을 제조하였다. 맛소금(백설) 100 중량부에 대하여, 상기 제조된 마늘 분말을 33 중량부를 혼합하여 체로 고르게 쳐서 마늘소금을 제조하였다. 15ㅧ20cm의 김 한 장에 0.5g의 옥수수유를 고르게 바르고 250℃에서 1차로 굽고, 0.3g의 마늘소금을 뿌려 380 내지 400℃에서 15초간 2차로 구워, 마늘소금으로 조미한 조미김을 제조하였다. Garlic powder was prepared by freeze-drying the garlic of Taean 6 pages from 2006 and pulverizing with a grinder. Garlic salt was prepared by mixing 33 parts by weight of the prepared garlic powder with respect to 100 parts by weight of taste salt (snow white) and sieving evenly with a sieve. 0.5g corn oil is evenly applied to a piece of 15 ㅧ 20cm laver and baked first at 250 ° C. Sprinkle 0.3g garlic salt for 2 seconds at 380 to 400 ° C for 15 seconds to prepare seasoned seasoning with garlic salt. It was.
<실시예 2><Example 2>
마늘소금 제조시, 맛소금 100 중량부에 대하여 상기 제조된 마늘 분말을 50 중량부로 혼합하는 것을 제외하고는, 상기 실시예 1과 동일하게 실시하여 조미김을 제조하였다.When preparing garlic salt, seasoning laver was prepared in the same manner as in Example 1 except for mixing 50 parts by weight of the prepared garlic powder with respect to 100 parts by weight of taste salt.
<실시예 3><Example 3>
마늘소금 제조시, 맛소금 100 중량부에 대하여 상기 제조된 마늘 분말을 150 중량부로 혼합하는 것을 제외하고는, 상기 실시예 1과 동일하게 실시하여 조미김을 제조하였다.When preparing garlic salt, seasoning laver was prepared in the same manner as in Example 1 except for mixing the prepared garlic powder in an amount of 150 parts by weight based on 100 parts by weight of salt.
<실시예 4><Example 4>
마늘소금 제조시, 맛소금 100 중량부에 대하여 상기 제조된 마늘 분말을 200 중량부로 혼합하는 것을 제외하고는, 상기 실시예 1과 동일하게 실시하여 조미김을 제조하였다.When preparing garlic salt, seasoning laver was prepared in the same manner as in Example 1 except for mixing 200 parts by weight of the prepared garlic powder with respect to 100 parts by weight of taste salt.
<비교예 1> Comparative Example 1
마늘소금을 사용하지 않고 통상의 맛소금만을 이용한 것을 제외하고는, 상기 실시예 1과 동일하게 실시하여 조미김을 제조하였다.Seasoning laver was prepared in the same manner as in Example 1, except that garlic salt was not used and only ordinary salt was used.
<실험예 1> 중량변화 측정Experimental Example 1 Weight Change Measurement
상기 제조된 조미김을 잘 밀봉하여 실온에서 1주, 6주 및 12주 보관한 후, 무작위로 10장씩 선발하여 그 중량을 측정하였다.The seasoned laver was sealed well and stored at room temperature for 1 week, 6 weeks, and 12 weeks, and then randomly selected 10 sheets were weighed.
상기 표 1의 결과로부터, 통상의 소금만으로 조미한 비교예 1의 조미김과 실시예 1 내지 5에서 마늘소금으로 조미한 조미김의 경우, 중량변화에 큰 차이가 없었다.From the results of Table 1, in the case of seasoning laver of Comparative Example 1 seasoned with ordinary salt only and seasoned laver seasoned with garlic salt in Examples 1 to 5, there was no significant difference in weight change.
<실험예 2> 색도측정Experimental Example 2 Chromaticity Measurement
상기 제조된 조미김을 색차계(Color reader, CR-300 Chroma Meter, Minolta Camera Co., Osaka, Japan)를 사용하여 색도를 측정하였으며, a, b, L 값을 3회 반복하여 그 평균값을 표 2에 기재하였다.Wherein the prepared seasoning Kim using the color difference meter (Color reader, CR-300 Chroma Meter, Minolta Camera Co., Osaka, Japan) was measured for chromaticity, a, b, and the L value is repeated three times the average value table 2 is described.
<< 실험예Experimental Example 3> 일반성분 분석 3> General Ingredient Analysis
상기 제조된 조미김에 대하여, 수분 함량은 105℃ 건조법, 조단백질 함량은 키달(Kjeldhal)법으로 측정하고, 조지방은 속실렛(Soxhlet)법 및 조회분은 550℃ 직접 회화법으로 측정하였다. 그 결과를 표 3에 기재하였다.For the prepared seasoned seaweed, moisture content was measured by 105 ° C. drying method, crude protein content by Kjeldhal method, crude fat was measured by Soxhlet method and crude ash by 550 ° C. direct incineration method. The results are shown in Table 3 .
상기 표 3에서 보는 바와 같이, 실시예 1 내지 5에서 마늘소금으로 조미하여 제조된 조미김의 경우, 최종수분함량이 비교적 낮았으므로 저장 중에 김의 색소류의 안정성이 확보됨을 예측할 수 있다.As shown in Table 3, in the case of seasoned seaweed prepared by seasoning with garlic salt in Examples 1 to 5, the final moisture content is relatively low, it can be predicted that the stability of the pigments of seaweed during storage.
<실험예 4> 지방산 분석Experimental Example 4 Fatty Acid Analysis
상기 제조된 조미김 10g을 n-헥산에 가하여 추출한 후 40℃에서 감압 농축한 시료 0.1g에 n-헥산 5㎖를 첨가하여 섞은 후, 2N-KOH MeOH 100㎕를 첨가 하여 3000 rpm에서 10분 원심 분리하였다. 그 결과, 상층액을 사용하여 가스크로마토그래피(GC)로 분석하였으며, 이때, 가스 크로마토그래피 측정은 오븐온도가 180℃(5min)이고 10℃/5min씩 230℃까지 승온온도, 주입온도 230℃ 및 검출온도 250℃로 설정하고, Innowax (30×0.25×0.1) 컬럼을 사용하여 분석시간 15분 동안 측정하였다.10 g of the seasoned seaweed was added to n-hexane and extracted, and 5 ml of n-hexane was added to 0.1 g of the sample concentrated under reduced pressure at 40 ° C., followed by addition of 100 μl of 2N-KOH MeOH and centrifuged at 3000 rpm for 10 minutes. Separated. As a result, the supernatant was analyzed by gas chromatography (GC), wherein the gas chromatography measurement was performed at an oven temperature of 180 ° C. (5 min) and 10 ° C./5 min increments up to 230 ° C., injection temperature 230 ° C. and The detection temperature was set to 250 ° C. and measured for 15 minutes using an Innowax (30 × 0.25 × 0.1) column.
또한, 토코페놀 함량은 상기 제조된 조미김 10g을 n-헥산에 가하여 추출한 후 40℃ 에서 감압 농축한 시료 0.1g에 메탄올 5㎖를 첨가하고 강하게 섞은 후, 3000 rpm에서 10분 원심 분리하고 그 상층액을 사용하여 HPLC를 사용하여 분석하였다.In addition, the tocophenol content was extracted by adding 10 g of the seasoned seaweed prepared in n-hexane, and then, 5 g of methanol was added to 0.1 g of the sample concentrated under reduced pressure at 40 ° C. and mixed vigorously, followed by centrifugation at 3000 rpm for 10 minutes, and the upper layer. The solution was analyzed using HPLC.
<< 실험예Experimental Example 5> 5> 과산화지질 생성량 측정Measurement of lipid peroxide production
상기 제조된 조미김 10g을 n-헥산을 가하여 추출 후 40℃에서 감압 농축한 시료 100 ㎍에 1% TBA(2-thiobarbituric acid), 2.8% TCA(trichloroacetic acid)를 각각 1㎖ 씩 첨가 섞어준 후 100℃에서 15분 동안 끓이고 충분히 냉각한 다음 피리딘: n-부탄올 (1:14)로 섞은 용액을 2㎖ 첨가하고 섞어준 후 3000rpm에서 10 분 동안 원심분리 후, 상층액만 취해 532nm에서 비색정량하였다. 10 g of the prepared seasoned seaweed was extracted by adding n-hexane, followed by adding 1 ml of 1% TBA (2-thiobarbituric acid) and 2.8% TCA (trichloroacetic acid) to 100 µg of the sample, which was concentrated under reduced pressure at 40 ° C. After boiling at 100 ° C. for 15 minutes and cooling sufficiently, 2 ml of a solution mixed with pyridine: n-butanol (1:14) was added and mixed, followed by centrifugation at 3000 rpm for 10 minutes, and only the supernatant was taken to colorimetrically at 532 nm. .
상기 과산화지질 생성량의 측정결과, 마늘소금이 아닌, 통상의 소금으로 조미한 조미김의 경우[비교예 1], 시간이 경과함에 따라, 과산화지질의 생성량이 현저하게 증가하였으므로, 조미김의 저장 기간 중, 기름의 산패로 인한 품질저하를 예상할 수 있다. As a result of the measurement of the amount of lipid peroxide produced, in the case of seasoned laver seasoned with normal salt instead of garlic salt [Comparative Example 1], as the time elapsed, the amount of lipid peroxide increased significantly, so that the storage period of seasoned laver The deterioration of oil quality due to rancidity can be expected.
반면에, 도 1은 본 발명의 마늘소금으로 조미된 조미김에 대한 과산화지질 생성량 측정결과를 도시한 것으로서, 실시예 1 내지 5에서 제조된 조미김은 시간이 경과되어도 과산화지질인 말론디알데하이드(Malondialdehyde, 이하 "MDA"라 한다)의 생성량이 비교예 1에 대비하여, 50 내지 80% 정도 감소되었다. 따라서 본 발명의 마늘소금으로 조미한 조미김은 마늘의 함유성분과 원료 김의 지방산과의 항산화 반응으 로 과산화지질의 생성량이 현저히 감소함에 따라 가공 및 저장 후, 제품 품질이 유지되므로 저장성이 연장되었다.On the other hand, Figure 1 shows the results of the measurement of lipid peroxide production for seasoned seaweed seasoned with garlic salt of the present invention, the seasoning laver prepared in Examples 1 to 5 is malondialdehyde (Malondialdehyde) even if time passes , Hereinafter referred to as “MDA”), was reduced by about 50 to 80% compared to Comparative Example 1. Therefore, seasoned seaweed seasoned with garlic salt of the present invention has prolonged shelf life because the product quality is maintained after processing and storage as the amount of lipid peroxide is significantly reduced due to the antioxidant reaction between the ingredients of garlic and fatty acids of raw seaweed. .
<실험예 6>Experimental Example 6 식감에 대한 관능실험 Sensory experiment on texture
상기 제조된 조미김을 실온에서 1개월, 3개월 및 6개월 보관 처리한 후, 성별 및 나이에 제한 없이 100명의 소비자를 대상으로 즉각적으로 감지하여 식감에 대한 관능실험을 하기 기준에 준하여 수행하였다. The prepared seasoned seaweed was stored at room temperature for 1 month, 3 months and 6 months, and then immediately sensed by 100 consumers without any restriction on gender and age, and sensory experiments on texture were performed based on the following criteria.
◎: 이미, 이취가 없고, 바삭한 식감으로 평가한 소비자가 80명 이상인 경우, (Double-circle): When there are 80 or more consumers who have already evaluated by a crisp texture without odor,
○: 이미, 이취가 없고, 바삭한 식감으로 평가한 소비자가 40 내지 80명 이내인 경우, (Circle): When there are already no odor and 40 or 80 consumers evaluated with crisp texture,
△: 이미, 이취가 없고, 바삭한 식감으로 평가한 소비자가 40명 이하인 경우(Triangle | delta): When there are 40 or less consumers who have already evaluated by the crispy texture without odor.
상기 결과로부터, 본 발명의 마늘소금으로 조미한 조미김은 지방산의 산화로 인한 산패가 억제되므로, 시간이 경과함에 따라 기름에 찌든 냄새(異臭)가 없고, 초기의 바삭한 식감을 보존하였다.From the above results, seasoned seaweed seasoned with garlic salt of the present invention is suppressed rancidity due to the oxidation of fatty acids, so that there is no oily odor over time, and the initial crispy texture was preserved.
상기에서 살펴본 바와 같이, 본 발명은 고온의 가열처리 과정을 거쳐 제조되는 조미김의 저장성을 연장시킬 수 있는 제조방법으로 제공하였다. As described above, the present invention provides a manufacturing method that can extend the shelf life of seasoned seaweed produced through a high temperature heat treatment process.
본 발명의 조미김의 제조방법은 제조과정에 마늘 소금으로 조미하여, 마늘의 함유성분과 김의 지방산과 항산화 반응하여 과산화지질 생성을 억제함으로써, 가공 후, 저장과정 중 품질을 향상시키고 건강기능성을 강화할 수 있는 고부가가치 제품을 제공할 수 있다.The seasoning method of seasoning laver of the present invention is seasoned with garlic salt during the manufacturing process, by inhibiting the formation of lipid peroxide by antioxidant reaction with the components of garlic and fatty acids of seaweed, improves the quality during storage, after processing and health functional It can provide high value products that can be enhanced.
본 발명의 마늘소금으로 조미된 조미김은 마늘의 소비확대를 촉진하므로, 마늘을 재배하는 농가와 다양한 산업계의 경제적 이익을 제공할 수 있다.Seasoned seaweed seasoned with garlic salt of the present invention promotes increased consumption of garlic, and can provide economic benefits to farmers and various industries that grow garlic.
또한, 김을 소비하는 국가의 확대로 국제적인 제품 경쟁력을 강화에 기여할 수 있다.In addition, the expansion of countries that consume laver can contribute to strengthening international product competitiveness.
이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술사상 범위 내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연한 것이다.Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.
도 1은 본 발명의 마늘소금으로 조미된 조미김에 대한 과산화지질 생성량 측정결과이다. 1 is a measurement result of lipid peroxide production for seasoned seaweed seasoned with garlic salt of the present invention.
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KR101276374B1 (en) | 2011-01-12 | 2013-06-18 | 씨제이제일제당 (주) | A method of inhibiting rancidity of seasoned laver using powder of vitamin tree leaves |
KR101366969B1 (en) * | 2012-08-22 | 2014-02-24 | 주식회사솔뫼에프엔씨 | Manufacturing method for seasoned laver using black garlic |
KR101371814B1 (en) * | 2011-11-21 | 2014-03-07 | 김용주 | Manufacturing method of roasted-seasoned Laver using salts with Halocynthia roretzi and Tricholoma matsutake, and its product produced thereby |
KR20230081756A (en) | 2021-11-29 | 2023-06-08 | 농업회사법인 주식회사 자연향기 | Manufacturing method for seasoned laver |
KR102695367B1 (en) | 2023-07-25 | 2024-08-13 | 노장식 | Manufacturing method of seasoning with adhesion by heating and melting |
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KR20060101056A (en) * | 2005-03-19 | 2006-09-22 | 윤연순 | Roasted laver containing Molokia and its manufacturing method |
KR20070001293A (en) * | 2005-06-29 | 2007-01-04 | 박현정 | Garlic laver and preparation method thereof |
KR20070082995A (en) * | 2006-02-20 | 2007-08-23 | 주식회사 해맛 | Coating salt, preparation method thereof and seasoning |
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KR20060101056A (en) * | 2005-03-19 | 2006-09-22 | 윤연순 | Roasted laver containing Molokia and its manufacturing method |
KR20070001293A (en) * | 2005-06-29 | 2007-01-04 | 박현정 | Garlic laver and preparation method thereof |
KR20070082995A (en) * | 2006-02-20 | 2007-08-23 | 주식회사 해맛 | Coating salt, preparation method thereof and seasoning |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101276374B1 (en) | 2011-01-12 | 2013-06-18 | 씨제이제일제당 (주) | A method of inhibiting rancidity of seasoned laver using powder of vitamin tree leaves |
KR101371814B1 (en) * | 2011-11-21 | 2014-03-07 | 김용주 | Manufacturing method of roasted-seasoned Laver using salts with Halocynthia roretzi and Tricholoma matsutake, and its product produced thereby |
KR101366969B1 (en) * | 2012-08-22 | 2014-02-24 | 주식회사솔뫼에프엔씨 | Manufacturing method for seasoned laver using black garlic |
KR20230081756A (en) | 2021-11-29 | 2023-06-08 | 농업회사법인 주식회사 자연향기 | Manufacturing method for seasoned laver |
KR102695367B1 (en) | 2023-07-25 | 2024-08-13 | 노장식 | Manufacturing method of seasoning with adhesion by heating and melting |
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