KR100866044B1 - Think coating coated with high hardness antimicrobial inorganic paints containing silver ions - Google Patents

Think coating coated with high hardness antimicrobial inorganic paints containing silver ions Download PDF

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KR100866044B1
KR100866044B1 KR1020060039242A KR20060039242A KR100866044B1 KR 100866044 B1 KR100866044 B1 KR 100866044B1 KR 1020060039242 A KR1020060039242 A KR 1020060039242A KR 20060039242 A KR20060039242 A KR 20060039242A KR 100866044 B1 KR100866044 B1 KR 100866044B1
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coating
coated
parts
weight
silver
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KR20060058067A (en
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권우상
이영호
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권우상
이영호
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • B05D3/0272After-treatment with ovens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2262Oxides; Hydroxides of metals of manganese
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2286Oxides; Hydroxides of metals of silver

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Application Of Or Painting With Fluid Materials (AREA)
  • Sink And Installation For Waste Water (AREA)

Abstract

수용성 무기질 도료로서 은이온제, 인산, 산화 알미늄, 산화 망간, 규산, 마그네슘, 증류수를 적정량으로 혼합 조성한 도료를 제조하여 상기 제조된 도료를 씽크의 금속판재 내,외 표면 코팅층에 10미크론 두께로 피복 코팅하여 전기로에서 약 250℃ 온도로 10분간 소성 시켜서 도포하여 고 항균성과 9H 이상의 경도를 갖도록 구성함을 특징으로한 은이온제가 함유된 고경도 무기질 도료의 제조방법 및 도료를 도포 코팅한 씽크.As a water-soluble inorganic paint, a coating material prepared by mixing silver ions, phosphoric acid, aluminum oxide, manganese oxide, silicic acid, magnesium, and distilled water in an appropriate amount was prepared to coat the prepared coating with a thickness of 10 microns on the inner and outer surface coating layers of the metal plate of the sink. A method of manufacturing a high hardness inorganic paint containing a silver ionic agent and a coating coated with a coating, characterized in that it is coated and calcined at an electric furnace for about 10 minutes at a temperature of about 250 ° C. to have a high antibacterial property and a hardness of 9H or more.

내,외면 코팅층, 은(銀)이온제(산화은), 인산, 산화 망간, 규산, 산화 알미늄, 증류수Inner and outer coating layers, silver ions (silver oxide), phosphoric acid, manganese oxide, silicic acid, aluminum oxide, distilled water

Description

은(銀)이온제가 함유된 고경도 항균성 무기질도료를 도포 코팅한 씽크{omitted}Think coated with high hardness antimicrobial inorganic paints containing silver ions

도 1은 본발명의 평면 예시도1 is a plan view of the present invention

도 2는 본발명의 정면 예시도2 is a front view of the present invention

도 3은 본발명의 측면 예시도3 is a side view of the present invention

도 4는 본발명 도 3의 부분 확대단면 예시도Figure 4 is a partial enlarged cross-sectional view of the present invention Figure 3

<도면의 주요부분에 대한 부호설명><Code Description of Main Parts of Drawing>

1 : 씽크, 2 : 주연턱, 3 : 배출구, 4 : 금속판재,1: sink, 2: main jaw, 3: outlet, 4: metal plate,

5 : 내면 코팅층, 6 : 외면 코팅층5: inner coating layer, 6: outer coating layer

본발명은 주방기기, 주방기구등의 금속표면에 고경도의 도료를 피막 코팅하여 기존의 스텐레스 씽크대에서 발생하는 녹과 물때, 표면 스크레치 발생을 감소시키고 일반적인 도료와는 달리 가력한 항균성을 갖는 은이온제를 함유시켜 고항균성으로 인하여 음식물을 조리하는 씽크대를 위생적으로 관리하고 내구성이 강하여 견고하면서 장기간 사용하여도 처음과 나중이 동일한 항균성 및 녹발생, 물대 및 표면 스크레치의 발생이 없도록한 은이온제가 함유된 고경도 항균성 무기질도료를 도포 코팅한 씽크에 관한 것이다The present invention is to coat the hard surface of the metal surface of kitchen appliances, kitchen utensils, etc., to reduce the rust and splatter, surface scratches generated in the existing stainless steel sinks, and unlike other paints, silver ions with potential antibacterial properties It contains a silver ionic agent that sanitizes the sink for cooking food due to high antibacterial properties, and it is durable and strong, so that it has the same antibacterial and rust as the first and last, even if it is used for a long time. It relates to a sink coated with a high hardness antimicrobial inorganic paint

종래에는 무기질 피막도료, 무기질 피막조성물등의 발명이 다수 출원 공고되여 있는데, 몇가지 살펴보면 첫째 : 10-1994-402245호, 둘째 : 10-1995-66598호, 셋째 : 10-2003-80029호, 내째 : 10-2003-101172호 등이 알려져 있으며,Conventionally, the invention of inorganic coating paint, inorganic coating composition, etc. has been published a number of applications, looking at some of the first: 10-1994-402245, second: 10-1995-66598, third: 10-2003-80029, the second: 10-2003-101172 and the like are known,

첫째의 구성은 변성구산염,실리카등을 2.8-7.03%, 접착제10-50%, 마이카, 탈크, 규회석, 체질안료20-80%, 무기안료10-50%, 정수5-3%, 복합염20-80%, 알루미늄 더스트5-50%, 증류수20-60%로 구성되는 무기질 조성물이고, 둘째의 구성은 수분산성 알카리규산염15-30%, 수분산성 실리카15-30%, 유기관능성 실리카1-4%, 반은물25-60%를 함유하는 것을 특징으로 한 도료 조성물이며, 셋째의 구성은 광촉매30-50%, 조촉매1.5-3%, 화성암 분말35-40%, 흐름방지제1-5%, 착색안료3-5%, 고비점 용제0.3-1%, 물5%, 소포제0.1-0.2%, 증점제5-7%, 분산제0.3-1.2%, 인산염4-6%, 동결방지제0.1-0.2%로 구성되는 도료이 이고, 넷째의 구성은 골로이달 알루미나와 유기관능성 실란화합물 가수분해를 통해 얻어진 바인더에 안료, 첨가제 및 용제를 포함하는 상도 조성물을 포함하여 2코드 1베이킹 시스템으로 도장하는 무기질계 피막 조성물로 형성되는 피막조성물과 피막도료가 알려저 있고,The first is composed of modified gurate, silica, 2.8-7.03%, adhesive 10-50%, mica, talc, wollastonite, sieving pigment 20-80%, inorganic pigment 10-50%, purified water 5-3%, complex salt Inorganic composition consisting of 20-80%, aluminum dust 5-50%, distilled water 20-60%, the second composition is water dispersible alkali silicate 15-30%, water dispersible silica 15-30%, organofunctional silica 1 -4%, half-silver water 25-60%, the third composition is a photocatalyst 30-50%, cocatalyst 1.5-3%, igneous rock powder 35-40%, flow inhibitor 1- 5%, pigmented pigment 3-5%, high boiling point solvent 0.3-1%, water 5%, defoamer 0.1-0.2%, thickener 5-7%, dispersant 0.3-1.2%, phosphate 4-6%, cryoprotectant 0.1- The paint consists of 0.2%, and the fourth composition comprises two coats including a top composition comprising pigment, additives and solvents in a binder obtained through hydrolysis of the colloidal alumina and the organofunctional silane compound. The coating composition and the coating film formed of the inorganic coating composition to seal the baking system 1, and that known,

은나노를 코팅제로 이용하거나 조리기구에 코팅하는 구성은 10-2004-73067호 및 10-2005-101587호로 출원 공개되여 있는데, 전자는 코팅 대상인 금송의 상부에 순차적으로 적층되는 프라이머, 미드, 탑 코팅제에 있어서, 상기 프라이머, 미드 및 탑 코팅제는 각각 불소수지 코팅제 또는 세라믹 불소수지 코팅제100 중량부에 실리콘 산화물로 표면이 코팅된 은, 금 또는 백금 나노입자가 각각0.0001 중량부 이하, 0.0001중량부, 0.0001중량부 내지 0.03중량부로 혼합된 것을 특징으로하는 항균성 코팅제 이고, 후지는 은나노 마블코팅 조리기구 및 그제조방법에 관한 것으로서 금속표면에 다중 코팅층이 형성된 조리기구에 있어서, 상기 코팅층 위에 은나노가 함유된 마블코팅액을 도포하여 점박이 형상의 은나노 마블층을 시킨 것을 특징으로하고, 그제조방법은 은나노가 함유된 코팅층을 형성시켜 기계적 성질이 향상되고 항균, 살균등 인체에 유익한 특성을 제공함으로서 조리기구의 품질을 높일수 있도록 금속표면에 프라이머 코팅층을 형성한후 300-350℃에서 15-20분간 건조하고 은나노 마블층이 형성된 코팅층상에 투명 코팅액을 도포하여 400-420℃에서 18분간 열처리 하는 것을 특징으로 하는 제조방법에 관한 것이며,The composition of using silver nano coating or coating on cooking utensils is disclosed as 10-2004-73067 and 10-2005-101587. The former is applied to primers, mids, and top coatings that are sequentially stacked on top of the gold pine to be coated. In the primer, the mid and the top coating agent, the silver, gold or platinum nanoparticles coated with silicon oxide on the surface of 100 parts by weight of the fluororesin coating agent or the ceramic fluororesin coating agent, respectively, 0.0001 parts by weight, 0.0001 parts by weight, 0.0001 parts by weight It is an antimicrobial coating agent characterized in that it is mixed to 0.03 parts by weight, and Fuji relates to a silver nano marble coating cookware and a method for manufacturing the same, in a cooking utensil having a multi-coating layer formed on the metal surface, a marble coating liquid containing silver nano on the coating layer By applying a spotted silver nano marble layer, and the manufacturing method of the silver nano By forming the coating layer, the mechanical properties are improved, and antibacterial, sterilization and other beneficial properties to the human body by providing a primer coating layer on the metal surface to improve the quality of the cookware, and then dried at 300-350 ℃ for 15-20 minutes and silver nano It relates to a manufacturing method characterized by applying a transparent coating solution on the coating layer formed with a marble layer and heat-treated at 400-420 ℃ for 18 minutes,

세면대나 욕조등에 은나노를 2-999ppm정도를 함유기켜서된 구성은 10-2004-80607호로 알려져 있으나 상기 구성은 높은 열에는 산화되고 색상의 변질등으로 제품의 질이 저하되고 항균력이 저하되는 문제점이 있었다It is known that 10-2004-80607 is composed of silver nano in the wash basin or bath, etc., but it is oxidized under high heat and the quality of the product is deteriorated due to the color change etc. there was

또 20-0301554호의 표면 코팅막을 구성한 씽크가 등록되여 있으며 이것은 스텐레스 판재로된 씽크의 내,외표면에 고 진공상태에서 공기가스의주입과 코팅공정의 가스를 주입하여 골드색 티타늄 코팅층을 피복 성형케함을 특징으로 한 씽크로서 상기한 종래의 발명등은 은이온제가 함유된 고경도 항균성 무기질 도료의 제조방법 및 사기도료를 씽크에 도포 코팅하는 구성과는 전혀 상이한 기술이 였던 것이다In addition, a sink consisting of the surface coating film of No. 20-0301554 is registered, which injects air gas and coating gas into the inner and outer surfaces of the stainless plate sink to coat the gold titanium coating layer. The above-described conventional invention as a sink is a technology that is completely different from the method of manufacturing a high hardness antimicrobial inorganic paint containing silver ions and a constitution paint coating on the sink.

본발명은 이와같은 종래의 여러 가지 무기질 피막도료, 무기질 피막 조성물등과 은나노를 코팅제로 이용하거나 은나노를 조리기구에 코팅하는 기술구성과는 달리 수용성 무기질 도료로서 통상의 방법으로 다양한 물을 이용하여 은봉에 전원을 인가하여 제조된 은이온제, 인산, 산화망간, 규산, 산화알마늄, 마그네슘, 증류수가 함유된 높은 경도와 항균성을 갖는 무기질 도료를 제조하고 상기도료를 씽크의 표면에 도포 코팅하여 소성후 고경도의 세균에 항균하는 씽크를 구성토록함에 목적이 있는바 첨부된 도면에 의하여 상세히 설명하면 다음과 같다The present invention is a water-soluble inorganic paint, using a variety of conventional inorganic coating paints, inorganic coating compositions, such as silver nano coating as coating agent or silver nano coating on cooking utensils using a variety of water in a conventional method It is manufactured by applying inorganic power to silver ions, phosphoric acid, manganese oxide, silicic acid, aluminum oxide, magnesium oxide, magnesium distilled water, and inorganic paints with high hardness and antibacterial properties. After the purpose of configuring the antimicrobial sink to the high hardness bacteria described in detail by the accompanying drawings as follows.

수용성 무기질 도료로서 은을 산화 한 은이온제(산화 은) 2중량부, 인산 17-20중량부, 산화알미늄 3-5중량부, 산화망간 3-5중량부, 규산 5-8중량부, 증류수 60-70중량부로 혼합 조성하여 피막 코팅용 도료를 제조하여 상기 제조된 도료를 주연턱(2)과 배출구(3) 및 금속판재(4)로 구성된 씽크(1)의 내면코팅층(5)과 외면코팅층(6)이되도록 10미크론의 두께로 피복하여 전기로에서 상기 도료를 피복한 씽크(1)를 약 250℃의 온도로 10분간 소성시켜서 피막을 형성함을 특징으로 한 것이다2 parts by weight of silver ionic agent (silver oxide) oxidized silver, 17-20 parts by weight of phosphoric acid, 3-5 parts by weight of aluminum oxide, 3-5 parts by weight of manganese oxide, 5-8 parts by weight of silicic acid, distilled water 60-70 parts by weight of the mixed composition to prepare a coating for coating coating the coating material prepared in the outer coating layer (5) and the outer surface of the sink (1) consisting of the periphery (2), the outlet (3) and the metal plate (4) It is characterized in that the coating layer 6 is coated with a thickness of 10 microns to form a film by firing the sink 1 coated with the paint in an electric furnace at a temperature of about 250 ° C. for 10 minutes.

이와 같이된 본발명의 작용을 설명하면 다음과 같다The operation of the present invention thus described is as follows.

씽크(1)의 금속판재(4)의 내면코팅층(5)과 외면코팅층(6)을 10미크론의 두께로 코팅함으로서 주방의 씽크대에설치하여 사용하면 식기, 금속제, 유리제등이 부딪쳐도 경도가 9H이상으로 강하여 긁히거나 손상되거나 벗겨진는 폐다이 없이 내스크레치성으로 내외의 표면을 보호하며 각종 병원균이나 세균의 번식을 은이온제가 억제하는 항균력에 의하여 위생적이며 녹발생과 물때의 발생을 억제하게 되며 씽크(1)의 금속판제(4)의 내면코팅층(5)만을 피막 도포하여도 같은 효과를 얻게 된다 주방, 특히 조리와 세척등을 하는 씽크는 환경오염이나 병원균, 세균등의 번식으로부터 취약하기 때문에 각별히 신경을 기울이지 않으면 여러 가지 새로운 세균이 발생하고 있으며 이에대한 면역력은 점점더 취약해지고 있기 때문에 이들 병원균, 세균등을 사전에 억제, 살균하는 것은 매우 중요하며 원천적으로 음식물을 조리하는 주방의 씽크에서부터 항균과 멸균성을 갖는 표면처리등이 중요한 과제로되어 왔고 잘알려진 것과 같이 항균과 멸균력을 갖는 은(銀)은 항균력이 우수하고 인체에 영향력이 전혀 없는 물질로서 600여종의 병원균을 살균하고 곰팡이균을 제거하며 음이온을 발생 시킨다는 사실은 주지된바 있으나, 찬물과 더운물(100℃)을 번갈아 사용하여 접촉하는 씽크(1)에 표면 처리하여 100℃전후의 고온에서도 산화되거나 변질, 변색되어 항균력이 떨어지지 않도록하여 상품성이 저하하지 않도록함은 물론 상기 방법으로 제조되는 도료는 씽크(1)외에도 욕조, 세면대 및 기타 주방기기, 주방기구등에 코팅 피막하여 사용할 경우에는 우수한 항균효과와 견고성을 갖게된다When the inner coating layer 5 and the outer coating layer 6 of the metal plate 4 of the sink 1 are coated with a thickness of 10 microns and installed on the sink of the kitchen, the hardness is 9H or higher even when the tableware, metal, glass, etc. collide. Strong, scratched, damaged, or peeled off, scratch-resistant without scratching, protects the inside and outside surfaces, sanitary by the antimicrobial power of silver ions to suppress the growth of various pathogens and bacteria, and prevents the occurrence of rust and scale. The same effect can be achieved by coating only the inner coating layer 5 of the metal plate 4 of the metal plate. The kitchen, especially the sinks for cooking and washing, are susceptible to environmental pollution, propagation of pathogens, bacteria, etc. If you don't pay attention, many new bacteria are developing and immunity against them is becoming more vulnerable. Sterilization is very important, and from the sink of the kitchen to cook food from the source, the surface treatment with antibacterial and sterilization has been an important task. As is well known, silver with antibacterial and sterilization has excellent antibacterial activity. It is well known that it has no influence on the human body and sterilizes 600 kinds of pathogens, removes fungi, and generates negative ions. However, the surface of the sink (1) contacted by alternating between cold and hot water (100 ℃) It is treated by oxidation, alteration and discoloration at high temperature around 100 ℃ to prevent the antibacterial activity from dropping, so as not to deteriorate the commerciality, and the paint produced by the above method is not only used for the sink (1) but also in bathtubs, sinks and other kitchen appliances and kitchen appliances. When used as a coating film, it has excellent antibacterial effect and robustness

상기한 방법으로 성형한 씽크(1)의 금속판재(4)를 한국건자재 시험연구원에서 항균 시험과 경도시험을 한 결과는 다음표와 같다The results of the antibacterial test and the hardness test of the metal plate 4 of the sink 1 formed by the method described above at the Korea Institute of Building Materials are as follows.

시험표1Exam Table 1

Figure 112007506205661-pat00007
Figure 112007506205661-pat00007

사용균주 : Escherichia coli ATCC 25922Use strain: Escherichia coli ATCC 25922

세균(대장균)배양시험에서 24시간후 99.8%의 항균 작용 효과가 입증되고The bacterium (E. coli) culture test showed a 99.8% antimicrobial effect after 24 hours

시험표2 Exam Table 2

Figure 112007506205661-pat00008
Figure 112007506205661-pat00008

은이온(은나노)의 항균효과는 널리 주지된바 있고The antibacterial effect of silver ions (silver nano) has been widely known

산화알미늄(酸化Aluminium)은 천연적으로는 장옥석으로 산출되며 수산화 알미늄을 태워 만드는 백색의 분말로 알미늄의 제조 원료로 쓰이고 연마제 여과재료, 내화 재료등으로 쓰이며 산화망간(酸化Mangan)은 산화제일 망간, 삼이산화 망간, 사삼산화 망간, 이산화 망간, 삼산화 망간, 칠이산화 망간,을 통틀어서 산화 망간이라 하며, 규산(Silicic acid)은 규소와 산소와 수소가 혼합한 가장약한 산인데 규산소오다의 녹은물에 산을 더하여 갈라낸 교상(膠狀)의 침전물이며 천연적으로는 수정, 석영, 부싯돌, 마노등으로 되여 있고, 유리나 자기를 만드는데 사용 되는 것이다Aluminum oxide is naturally produced as feldspar and is a white powder made by burning aluminum hydroxide. It is used as a raw material for producing aluminum. It is used as an abrasive filter material, a refractory material, and manganese oxide is manganese oxide. Manganese trioxide, manganese trioxide, manganese dioxide, manganese trioxide, manganese dioxide, and manganese dioxide are collectively called manganese oxide.Silicic acid is the weakest acid mixed with silicon, oxygen, and hydrogen. It is a clump of sediment, which is divided by acid, and is naturally made of crystal, quartz, flint, and agate. It is used to make glass or porcelain.

증류수는 잘알려진 것과 같이 보통의 물을 증류하여 얻는 거의 순수한 화학실험용, 정밀공업용으로 쓰인다Distilled water, as is well known, is used for almost pure chemical experiments and precision industries obtained by distilling ordinary water.

인산은 인을 태워 그 생성물을 물에 용해하여 얻는 산의 총칭으로 정린산, 메타인산, 피로인산 등의 종류가 있고 정린산은 삼염기산으로 무색 투명한 주상 결정으로 조해성(潮解性)이 있고 일부는 강장제로도 쓰인다Phosphoric acid is a generic name of the acid obtained by burning phosphorus and dissolving the product in water. There are kinds of phosphoric acid, metaphosphoric acid and pyrophosphoric acid. Junglin acid is tribasic acid, which is colorless and transparent columnar crystal. Also used as a tonic

이와같이된 본발명은 씽크 및 주방기기 주방기구등의 금속판 표면에 피복 코팅하여 250℃의 온도로 소성하여 피막을 형성함으로서 씽크로 사용시 더운물과 찬물을 번갈아 가면서 계속 접촉하고 식기, 유리그릇 사기그롯등과 조리물의 세척시에 잦은 부딪침과 손상시킴에도 변색, 변질, 녹발생, 물때, 스크레치 발생등을 현저히 감소 시키고 강한 항균력을 갖이므로서 주변 환경에서의 각종 세균에 의한 오염을 방지할수 있고, 씽크의 상품 기치를 높여서 수출시장의 경쟁에서 우위를 확보할수 있는 효과적인 것이다The present invention has a coating coating on the surface of metal plates such as sinks and kitchen utensils and calcined at a temperature of 250 ° C. to form a film, whereby the hot water and cold water are kept in contact with the sink alternately. Regardless of frequent bumps and damages when washing foods, it significantly reduces discoloration, deterioration, rust, scale, scratches, etc., and has strong antibacterial ability to prevent contamination by various germs in the surrounding environment. It is effective to raise the banner and gain an edge over the competition in the export market.

Claims (3)

수용성 무기질 도료로서 은이온제(산화은) 2중량부, 인산 17-20중량부, 산화 알미늄 3-5중량부, 산화 망간 3-5중량부, 규산 5-8중량부, 증류수 60-70중량부로 조성하여 됨을 특징으로 한 은이온제가 함유된 고경도 항균성 무기질 도료As a water-soluble inorganic paint, 2 parts by weight of silver ions (silver oxide), 17-20 parts by weight of phosphoric acid, 3-5 parts by weight of aluminum oxide, 3-5 parts by weight of manganese oxide, 5-8 parts by weight of silicic acid, 60-70 parts by weight of distilled water High hardness antimicrobial inorganic paint containing silver ion agent 상기 청구항1의 도료를 씽크의 금속판재 내, 외면 코팅 층이 되도록 10미크론 두께로 도포하여 전기로에서 250℃ 온도로 10분간 소성하여 피막을 형성케하여 항균력을 갖도록 함을 특징으로 한 은이온제가 함유된 고경도 항균성 무기질 도료를 도포 코팅한 씽크The coating material of claim 1 is coated with a thickness of 10 microns so as to be an outer coating layer in the metal plate of the sink, and baked at 250 ° C. in an electric furnace for 10 minutes to form a film to have an antimicrobial effect. Coated and coated with hardened antimicrobial mineral paint 제1항의 무기질 도료를 씽크의 내,외 코팅층에 도포 피막하여 경도 9H이상이 되게하여 내스크로치 성으로 표면을 보호케 함을 특징으로 한 은이온제가 함유된 고경도 항균성 무기질 도료를 도포 코팅한 씽크.The inorganic coating of claim 1 is coated on the inner and outer coating layers of the sink to have a hardness of 9H or more to protect the surface with scratch resistance, which is coated with a high hardness antimicrobial inorganic coating containing silver ionic agent. Think.
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JPH0860040A (en) * 1994-08-12 1996-03-05 Koji Yamada Antibacterial inorganic coating composition
JPH09267070A (en) * 1996-04-01 1997-10-14 Yodogawa Steel Works Ltd Antifungal coated metallic sheet
KR20050111607A (en) * 2003-04-02 2005-11-25 엘지전자 주식회사 Antibiotic method for parts of refrigerator using antibiotic substance
KR20060006877A (en) * 2005-12-05 2006-01-20 임구수 Manufacturing method of permeable ceramic building finish

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0860040A (en) * 1994-08-12 1996-03-05 Koji Yamada Antibacterial inorganic coating composition
JPH09267070A (en) * 1996-04-01 1997-10-14 Yodogawa Steel Works Ltd Antifungal coated metallic sheet
KR20050111607A (en) * 2003-04-02 2005-11-25 엘지전자 주식회사 Antibiotic method for parts of refrigerator using antibiotic substance
KR20060006877A (en) * 2005-12-05 2006-01-20 임구수 Manufacturing method of permeable ceramic building finish

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