KR100818039B1 - The composition of function adiabatic panel - Google Patents
The composition of function adiabatic panel Download PDFInfo
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- KR100818039B1 KR100818039B1 KR20070061899A KR20070061899A KR100818039B1 KR 100818039 B1 KR100818039 B1 KR 100818039B1 KR 20070061899 A KR20070061899 A KR 20070061899A KR 20070061899 A KR20070061899 A KR 20070061899A KR 100818039 B1 KR100818039 B1 KR 100818039B1
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- C04B14/02—Granular materials, e.g. microballoons
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- C04B14/064—Silica aerogel
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- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
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- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
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- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
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- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
- C04B24/20—Sulfonated aromatic compounds
- C04B24/22—Condensation or polymerisation products thereof
- C04B24/226—Sulfonated naphtalene-formaldehyde condensation products
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- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
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- C04B24/2641—Polyacrylates; Polymethacrylates
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
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- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
Description
본 발명은 기능성 단열 패널의 조성물에 관한 것으로 구체적으로는 원적외선 음이온 항균 탈취 기능을 갖는 인체에 무해한 광물성 분말과 수경화성을 갖고 분말 결합력을 높이는 무기질계 분말. 합성수지 혼화제등으로 이루어지는 기능성 단열 패널 조성물로서 공기를 정화하며 유해한 중금속을 흡착 제거하고 원적외선 음이온 항균 탈취 기능을 가지는 인체에 무해한 일라이트와 황토 분말. 수화 작용을 촉진시키고 강도를 높이며 수화 조직의 치밀화를 시키는 마이크로 시멘트, 순수 무기질계 재료로 입자가 미세하고 강도 향상과 수화 치밀성을 높인 마이크로 실리카, 우수한 단열성 방음성 등으로 신소재로 주목받는 실리카 에어로젤. 많은 양의 수분을 흡수하여 비중이 낮고 소수성인 실리카 에어로젤과 마이크로 실리카 및 시멘트등의 재료와 잘 혼화되게 하여 부착력과 치밀성을 유지하게 하는 흡수성 폴리머, 수분과 접촉시 빠르게 경화하여 조직의 치밀성과 강도를 높이는 반수석고. 기타 수경성을 갖는 광물성분과 반응 하여 수경화성을 가지며 수밀성과 장기 강도를 향상시키고 분자간의 결합력을 높이는 작용을 하는 산화마그네슘 각 재료와의 유동성을 증가시키고 동결 방지 및 작업성을 좋게하는 나프탈렌 설폰산염 포르말린 축합물. 물보다 비중이 높아 수면 위로 뜨지 않고 소량 첨가로 균열 방지 및 강도를 향상시키는 셀룰로스 섬유로 구성되는 기능성 단열 패널 조성물에 관한 것이다.The present invention relates to a composition of a functional thermal insulation panel, specifically a mineral powder having a far-infrared anion antibacterial deodorizing function and inorganic powder that is harmless to the human body and has a hardening property and increases powder binding force. It is a functional insulating panel composition composed of synthetic resin admixtures, which purifies the air, adsorbs and removes harmful heavy metals, and has a far infrared anion antibacterial and deodorizing function. It is a micro cement that promotes hydration, increases strength, and densifies hydration tissues. It is a fine inorganic material, micro silica with fine particles, high strength, and high hydration density. Absorbent polymer that absorbs a large amount of moisture and mixes well with low specific gravity and hydrophobic silica airgel, micro silica and cement, and maintains adhesion and compactness. The height is half gypsum. Naphthalene sulfonate formalin condensation that reacts with other hydrophobic minerals to increase fluidity with each material and improve fluidity, long-term strength, and intermolecular adhesion, and to prevent freezing and workability. water. The present invention relates to a functional insulating panel composition composed of cellulose fibers that have a specific gravity higher than water and do not float on the water surface, thereby improving crack prevention and strength by adding a small amount.
현재 여러 종류의 단열재가 생산 판매되고 있는 실정이며 에너지 절감을 위하여 높은 단열성의 단열재를 필요로 하고 있으나 개발이 느린 상태이고 신소재인 에어로젤을 합성하여 단열재에 적용 시키는 기술이 아주 미미한 상태로 실리카 에어로젤을 단열재의 양면으로 된 판상내에 충진을 하는 등 합성된 복합체로 만드는데 많은 어려움이 있고 국내 및 외국의 사례를 봐도 많은 연구를 하고 있으나 실적이 저조한 상태임.Currently, various kinds of insulation materials are produced and sold. In order to save energy, high insulation materials are needed for energy saving. However, the development is slow and the technology to synthesize new airgels and apply them to insulation materials is very insignificant. There are many difficulties in making composite composites, such as filling in two-sided plates, and many studies have been conducted in domestic and foreign cases, but the results are poor.
본 발명자도 이에 편성하여 실리카 에어로젤을 합성하는 기술개발을 하게 되었음.The present inventors have also been organized to develop a technology for synthesizing silica airgel.
본 발명은 기능성을 갖는 광물성 성분과 무기질계 경화제 합성수지 등으로 판상을 형성하고 강도와 지지력을 높이며 자체적으로는 강도와 신축성이 약해 사용하기가 어려운 실리카 에어로젤을 합성하여 일체화 시켜 단열성능을 향상시킨 초 단열성의 판상형 단열재임. 실리카 에어로젤이 수경성인 기타 재료와 접촉하여 반응하고 경화되어 특별한 물성을 그대로 유지하므로 단열 성능을 높였으며 기존의 단열재와는 차별화 될수 있는 것으로서 다기능성과 단열성을 향상 시킨 기능성 단열 패널 조성물을 제공함에 있다.The present invention forms a plate with a mineral component and an inorganic curing agent synthetic resin having a functional property, and increases strength and supporting power, and by itself synthesizes and integrates a silica airgel, which is difficult to use due to its weak strength and elasticity, thereby improving thermal insulation performance. Plate-shaped insulation. Silica airgel reacts with other materials that are hydraulic and cured to maintain special physical properties as it is, thus improving insulation performance and being able to be differentiated from existing insulation materials, thereby providing a functional insulation panel composition having improved versatility and insulation properties.
본 발명에 의한 기능성 단열 패널 조성물은 중량비로 일라이트와 황토중 하나 이상 선택한 기능성 광물 성분 30∼35%, 마이크로 시멘트 25∼30%, 소수성 표면으로 개질된 실리카 에어로젤 분말 12∼18%, 마이크로 실리카 2∼4%, 폴리 아크릴산계 흡수성 폴리머 2∼5%, 반수석고15∼20%, 산화 마그네슘 7∼10%, 나프탈렌 설폰산염 포르말린 축합물 0.1∼0.3%, 셀룰로스 섬유 0.5∼1.3%로 구성되는 기능성 단열 패널 조성물 이라 하겠다.The functional insulating panel composition according to the present invention comprises 30 to 35% of functional mineral components selected from one or more of illite and ocher by weight ratio, 25 to 30% of micro cement, 12 to 18% of silica airgel powder modified to hydrophobic surface, and micro silica 2 Functional insulation comprising 4% to 4%, polyacrylic acid absorbent polymer 2 to 5%, hemihydrate gypsum 15 to 20%, magnesium oxide 7 to 10%, naphthalene sulfonate formalin condensate 0.1 to 0.3%, cellulose fiber 0.5 to 1.3% It will be referred to as a panel composition.
상기 조성물의 주성분이 되는 일라이트는 운모형 점토의 일종으로 견운모 보다 더 미립하며 패널의 채움제 작용과 마이크로 시멘트의 수화 반응 촉진 작용을 하며 그 자체가 높은 원적외선 방사와 항균 탈취 공기 정화등을 하며 도료 및 수처리와 토양 개선제등으로 다 방면으로 사용되고 있고 황토 또한 유사한 기능들을 가지고 있으며 타 재료와의 혼화성이 좋고 고유의 기능을 유지하여 항상 실내를 쾌적한 상태로 유지 할수 있다. 마이크로 시멘트는 순수 무기질계의 미립 시멘트로 일반적인 미립자 시멘트의 특성인 입경이 고르고 최대 입경 크기가 작아 높은 침투율을 발현하고 미 분말이므로 활성화가 빠르게 진행 되어 기타 재료와 혼화시 치밀한 조직을 이루어 조기 강도가 우수하게 나타나므로 주 바인드로 작용을 함.Illite, which is the main component of the composition, is a kind of mica-type clay, which is more fine than mica and promotes the filling function of the panel and the hydration reaction of micro cement. It is used in various fields such as water treatment and soil improver, and ocher also has similar functions. It is compatible with other materials and maintains its unique function so that the room can be kept in a comfortable state at all times. Micro Cement is a pure inorganic fine cement, which has the characteristic of uniform particle size and small maximum particle size, shows high penetration rate, and fine powder, so it activates quickly and forms a dense structure when mixed with other materials. Acts as the primary bind.
에어로젤(Aerogel)은 1930년대에 처음 발견된 이후 열 전기 소리 충격등에 강하고 무게도 같은 부피의 공기보다 3배 밖에 무겁지 않아 미래의 단열재 충격 완충재 방음재등으로 주목을 받아온 신소재이고 재료는 규소 산화물이다. 그러나 강도 및 신축성이 부족해 자체적으로는 사용이 쉽지가 않아서 실용화에 어려움을 겪고 있는 실정이다. 이를 본 발명에서는 패널내로 복합적으로 합성시켜 일체화시킨 것이 특징이라 하겠다. 마이크로 실리카는 실리카를 초미립 상태로 만든 것으로 화학적으로 안정되며 순백색의 무취한 물질로 99%의 고순도의 다공성 실리카이고 유동성과 분산성이 우수하며 비중이 낮아 물위에 뜨는 성질을 이용해 실리가 에어로젤과의 혼화성을 높이고 마이크로 시멘트와의 분자간 접촉을 하여 수경화하여 강도를 높이는데 중요한 기능을 한다 하겠다. 폴리 아크릴산계 흡수성 폴리머는 아크릴 아마이드를 자가 중합하여 NaOH로 가수 분해 시켜 제조된 초 고·흡수성 고분자 중합 폴리머로 다가의 금속 이온이 수용액중에 있으면 수분을 다시 배출하는 성질이 있어 마이크로 시멘트 및 기타 재료와 폴리머가 반응을 하면서 열적 성질이 향상되며 일단 수분을 흡수하면 PH나 열등의 조건 변화에서 빠르게 수분을 방출 하지는 않지만 다가의 금속 양이온이 들어있는 수용액에서는 수분을 방출하여 소수성으로 처리된 실리카 에어로젤과 친수성인 기타 재료와 치밀성을 유지하여 수분 안전성을 유지할수 있다. 반수석고는 황산 칼슘으로 하소 석고라고도 하며 물을 가하면 2분자의 결정수를 함유하는 원래의 석고로 되어 부피 팽창과 함께 경화가 되는데 이를 이용해 기타 성분과의 반응으로 경화체를 형성한다. 산화 마그네슘은 물에 약간 녹아 알카리성을 가지는데 공기중의 물과 이산화탄소를 흡수하면서 서서히 히드록시 탄산마그네슘이 된다. 높은 표면적과 빠른 화학적 반응으로 기타 재료와의 흡착성 및 강도를 높인다. 나프탈렌 설폰산염 포르말린 축합물은 물에 잘녹고 음이온으로 감수제의 기능을 가지며 마이크로 시멘트 입자를 분산시키며 유동성이 우수하여 패널의 내구성을 향상 시킨다. 셀룰로스 섬유는 목재의 재질에서 특수 가공 처리되는 것으로 판넬의 수축 균열을 억제하며 충격이나 파손에 대한 저항력을 증대 시킨다. 이에 모든 재료에 물을 40∼55% 혼합 하여 5분내로 교반후 원하는 두께 및 형태로 만들수 있는 기능성 단열 패널의 조성물이다.Aerogel is a new material that has been attracting attention as a thermal insulation shock absorber and soundproofing material since it was first discovered in the 1930s and is only 3 times heavier than air of the same volume of air and the same volume of air. However, due to its lack of strength and elasticity, it is not easy to use on its own, which makes it difficult for practical use. In the present invention it will be characterized by a composite synthesized and integrated into the panel. Micro-silica is made of ultra-fine silica and is chemically stable. It is a pure white, odorless substance. It is 99% high purity porous silica, has excellent fluidity and dispersibility, and low specific gravity. It will play an important role in increasing the strength by increasing the miscibility and hydrocuring by intermolecular contact with micro cement. Polyacrylic acid-based absorbent polymer is an ultra-high-absorbent polymer polymer produced by self-polymerizing acrylamide and hydrolyzing with NaOH. When polyvalent metal ions are in aqueous solution, water is discharged again. The reaction improves the thermal properties. Once water is absorbed, it does not release water rapidly under changes in pH or inferior conditions, but in aqueous solutions containing polyvalent metal cations, it releases water and hydrophobicly treated silica aerogels. Moisture safety can be maintained by maintaining material and compactness. Hemihydrate gypsum is also called calcined gypsum with calcium sulfate, and when water is added, it becomes the original gypsum containing two molecules of crystalline water, which is cured with volume expansion. Magnesium oxide is slightly soluble in water and alkaline. It absorbs water and carbon dioxide in the air and gradually becomes hydroxy magnesium carbonate. High surface area and fast chemical reaction increase the adsorption and strength with other materials. Naphthalene sulfonate formalin condensate is well soluble in water, has the function of water-reducing agent as anion, disperses micro cement particles and improves the durability of the panel by excellent fluidity. Cellulose fibers are specially processed from wood, which suppresses shrinkage cracking of panels and increases resistance to impact and breakage. This is a composition of a functional insulating panel that can be mixed to 40 to 55% of water in all materials and made into a desired thickness and form after stirring within 5 minutes.
본 발명에 의한 기능성 단열 패널의 조성물은 주 성분이 수경화를 하는 천연 무기질계 성분과 합성수지 및 초 단열성을 갖는 실리카 에어로젤을 복합체로 합성한 것으로 여러가지의 기능성과 단열 성능을 향상 시킨 복합 단열재로 기존의 판상형의 단열재를 대체 할수 있으며 단열을 필요로 하는 벽체 바닥 지붕및 실내외의 모든곳에 적용할 수가 있다. 다 기능성 및 환경 친화적이고 에너지 절감 효과가 우수하다The composition of the functional thermal insulation panel according to the present invention is a composite composite of a natural inorganic component, which the main component is hydrocured, a synthetic resin and a silica airgel having ultra-insulating properties. It can replace the plate-shaped insulation and can be applied to the wall floor roof which needs insulation and to indoor and outdoor. Versatile, environmentally friendly and energy saving
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KR100940618B1 (en) | 2008-03-12 | 2010-02-05 | 이재환 | The composition of adiabatic blanket |
KR100944068B1 (en) | 2008-02-12 | 2010-02-24 | 이재환 | The powder paint composition of adiabatic function |
KR101083133B1 (en) | 2009-05-18 | 2011-11-11 | 이재환 | Complex aerogel coating composition |
KR101083743B1 (en) * | 2011-02-23 | 2011-11-15 | 가나기업(주) | The making of plastering material which is both eco-friendly and functional, using natural loess, and the plastering procedures thereof |
KR101142466B1 (en) | 2010-03-18 | 2012-05-08 | 이차연 | concrete surface ongbyeokyong loess coatings and how to deal with it and the surface structure |
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KR20010019741A (en) * | 1999-08-30 | 2001-03-15 | 윤종용 | Apparatus and method for scroll function of pointing device in computer system |
KR20040004773A (en) * | 2002-07-05 | 2004-01-16 | (주)디텍 | Antibacterial Gypsum Board |
KR100550827B1 (en) | 2005-06-20 | 2006-02-10 | 석성기업주식회사 | A well-being panel using foam concrete |
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KR20010019741A (en) * | 1999-08-30 | 2001-03-15 | 윤종용 | Apparatus and method for scroll function of pointing device in computer system |
KR20040004773A (en) * | 2002-07-05 | 2004-01-16 | (주)디텍 | Antibacterial Gypsum Board |
KR100550827B1 (en) | 2005-06-20 | 2006-02-10 | 석성기업주식회사 | A well-being panel using foam concrete |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100944068B1 (en) | 2008-02-12 | 2010-02-24 | 이재환 | The powder paint composition of adiabatic function |
KR100940618B1 (en) | 2008-03-12 | 2010-02-05 | 이재환 | The composition of adiabatic blanket |
KR101083133B1 (en) | 2009-05-18 | 2011-11-11 | 이재환 | Complex aerogel coating composition |
KR101142466B1 (en) | 2010-03-18 | 2012-05-08 | 이차연 | concrete surface ongbyeokyong loess coatings and how to deal with it and the surface structure |
KR101083743B1 (en) * | 2011-02-23 | 2011-11-15 | 가나기업(주) | The making of plastering material which is both eco-friendly and functional, using natural loess, and the plastering procedures thereof |
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