KR100810598B1 - The organic sludge reduction facilities by means of electrolysis - Google Patents
The organic sludge reduction facilities by means of electrolysis Download PDFInfo
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Abstract
Description
본 발명은 전기분해조가 포함된 유기슬러지 감량장치에 관한 것으로서, 더욱 상세하게는 생물학적 처리 과정 중에서 반송슬러지를 전기분해장치에 통과시켜 전기분해시 발생되는 고활성의 차아염소산으로 유기슬러지를 구성하는 미생물의 세포를 파괴시켜 미생물 내의 세포질이 외부로 흘러나오도록 하고, 이 세포질이 생물처리에서 재포식되어 무기물로의 전환율을 높이는 방법으로, 전기분해처리장치로의 유입율, 운전조건 및 전기분해장치를 유기적으로 조합하여 종래 전기분해에 의한 유기슬러지 감량화에서 가장 큰 문제점이었던 미생물의 과산화에 의한 탈질 탈인 공정이 포함된 생물학적고도처리의 효율을 저하시키지 않고 목표한 슬러지 감량율을 최소의 에너지로 달성할 수 있게 하는 전기분해조가 포함된 유기슬러지 감량장치에 관한 것이다.The present invention relates to an organic sludge reduction apparatus including an electrolysis tank, and more particularly, a microorganism constituting the organic sludge with highly active hypochlorous acid generated during electrolysis by passing the return sludge through the electrolysis unit during a biological treatment process. By breaking down the cells of the microorganism so that the cytoplasm in the microorganism flows to the outside, and the cytoplasm is re-formed in the biological treatment to increase the conversion rate to the inorganic material. In combination with the present invention, it is possible to achieve the target sludge reduction rate with the minimum energy without degrading the efficiency of the biological advanced treatment including the denitrification and dephosphorization process by the peroxidation of microorganism, which was the biggest problem in the reduction of organic sludge by conventional electrolysis. Of organic sludge reduction apparatus comprising electrolysis tank to be.
현재까지 대부분의 오 · 폐수처리는 가장 보편적으로 생물학적 처리가 주류를 이루었으며, 초기에는 유기물의 제거가 주목적이었으나, 부영양화 등의 문제로 현재는 유기물 이외에도 질소, 인 등의 제거를 포함한 고도처리공정으로 발전하고 있다. Until now, most of the wastewater treatment has been the most common biological treatment. Initially, the removal of organic matter was the main purpose. However, due to problems such as eutrophication, it is now a highly advanced process including removal of nitrogen and phosphorus. It is developing.
그러나 상기와 같은 생물학적 처리에서는 필연적으로 슬러지가 발생하게 되며, 발생슬러지는 부피의 감소 및 물성안정화를 위하여 반드시 재처리를 하여야만 한다. 기존의 슬러지처리방법은 전체 오 폐수처리비용의 약 40% 정도를 차지하는 것으로 조사되어 졌으며, 탈수케이크의 최종처분지 반입도 2001년부터 금지되어있으며, 액상슬러지의 경우 2008년부터 시작하여 2012년에는 해양투기도 전면 금지될 예정이어서 경제성 있는 슬러지처리방법이 절실하게 요구되고 있는 실정이다.However, in such biological treatment, sludge is inevitably generated, and the sludge must be retreated to reduce the volume and stabilize the physical properties. Existing sludge treatment methods accounted for about 40% of the total wastewater treatment costs, and the final disposal basin of dewatered cakes was also banned in 2001. Liquid sludges began in 2008 and started in 2012. Since marine dumping is also to be banned, economical sludge disposal methods are urgently needed.
현재 슬러지처리방법은 감량화와 재활용으로 대별할 수 있으며, 감량화에서는 전기분해, 오존, 초음파, 고열균, 멧돌방식을 이용한 생물공정내 처리방법과 소화조를 이용한 생물공정외 처리방법이 있으며, 재활용에서는 퇴비화, 복토재활용, 시멘트원료, 경량골재, 녹생토, 연료화 등의 처리방법이 있다.At present, sludge treatment can be classified into weight reduction and recycling.In weight reduction, there are treatment methods in bioprocesses using electrolysis, ozone, ultrasonic waves, pyrolysis, and metdol method, and treatment methods outside bioprocesses using digester, and composting in recycling. , Cover soil recycling, cement raw materials, lightweight aggregate, green soil, and fuel treatment.
상기 처리방법들 중에서 재활용방법은 일단 발생된 슬러지를 처리하는 방법이며, 감량화는 슬러지발생자체를 줄이는 방법으로 가능한 한 감량화하는 방법으로 발전시켜 나가야 될 것이다. 또한 소화조를 이용한 생물공정외 처리방법보다는 근본적으로 슬러지발생자체를 줄이는 생물처리공정내의 방법이 더욱 주효하리라 본다. Among the treatment methods, the recycling method is a method of treating sludge generated once, and the reduction should be developed to reduce the sludge as much as possible by reducing the sludge itself. In addition, the method within the biological treatment process that reduces the sludge generation itself will be more effective than the treatment using the digestion tank outside the biological process.
그러나 상기와 같은 생물공정내 슬러지감량방식은 어떤 방식을 이용하던 간에 슬러지를 저분자화 하여, 미생물 반응조에서 미생물에 의해 재포식 시키면서 에너지의 소모를 촉진시켜 슬러지를 감량화하도록 한 것으로서, 기존의 슬러지감량화방법은 효율이 낮고 경제성도 좋지 않아 널리 이용되지 못하였다. 특히 전기분해를 이용한 슬러지감량의 경우 경제성면에서 적용가능한 단계에 있으나, 전기분해과정에서 미생물의 과산화에 의한 탈질 탈인 공정이 포함된 생물학적고도처리의 효율을 떨어뜨려 기존 전기분해를 이용한 슬러지감량장치는 생물학적고도처리의 도입을 위해서는 개선점을 필요로 하였다.However, the sludge reduction method in the biological process as described above is to reduce the sludge by reducing the molecular weight of the sludge, and to promote the consumption of energy while re-sowing by the microorganisms in the microbial reactor, to reduce the sludge, the conventional sludge reduction method Was not widely used due to its low efficiency and poor economic efficiency. In particular, in the case of sludge reduction using electrolysis, the sludge reduction apparatus using electrolysis is reduced because the efficiency of biological advanced treatment including denitrification and dephosphorization by microorganism peroxidation during electrolysis is reduced. Improvements are needed for the introduction of biological advanced treatment.
특히, 종래 기술 중 반류수를 전기분해처리하여 생물반응조로 재유입시키는 기술이 있으나, 이런 경우 수질에 따른 처리가 적절히 병행되지 못하므로 질산화가 저해되어 고도처리가 어려운 문제점이 있었다. In particular, there is a technique for reflowing the water into the bioreactor by electrolysis treatment in the prior art, but in this case there is a problem that advanced treatment is difficult because nitrification is inhibited because the treatment according to the water quality is not properly parallel.
본 발명은 기존의 전기분해를 이용한 유기슬러지감량장치의 가장 큰 문제점이었던 미생물의 과산화에 의한 질산화균의 감소로 질산화작용을 저해하는 등 생물학적고도처리의 효율을 떨어뜨리는 것과 같은 문제점을 해결하여, 탈질ㆍ탈인공정이 포함된 생물학적고도처리에 적용하는 장치를 제공하는데 목적이 있다. 즉, 본 발명은 처리수에 따라 전류의 세기 및 시간을 컨트롤 하여 능동적으로 전기분해를 함으로써 동일한 에너지 대비 고효율의 유기슬러지감량을 이룰 수 있도록 하는 것을 목적으로 한다. The present invention solves problems such as lowering the efficiency of biological advanced processing such as inhibiting nitrification by the reduction of nitrifying bacteria by the peroxidation of microorganisms, which was the biggest problem of the conventional organic sludge reduction apparatus using electrolysis. It is an object of the present invention to provide a device that is applied to biological advanced processing including a dephosphorization process. That is, the present invention aims to achieve a high efficiency of organic sludge reduction compared to the same energy by actively electrolyzing by controlling the intensity and time of the current according to the treated water.
또한 본 발명은 전기분해한 유기슬러지의 분해물질이 생물학적고도처리의 탄소원으로 재이용이 가능하여, 보다 경제적인 생물학적고도처리가 가능하도록 하는 기술을 제공하기 위한 것이다.In another aspect, the present invention is to provide a technology that enables the decomposition of the electrolyzed organic sludge can be reused as a carbon source of biological advanced treatment, enabling more economical biological advanced treatment.
상기 목적을 달성하기 위하여 본 발명은, 전기분해조가 포함된 유기슬러지 감량장치에 관한 것으로, 생물학적 처리과정중 반송슬러지에 전기분해를 이용하여 유기슬러지감량 및 유기슬러지의 분해물질이 생물학적고도처리의 탄소원으로 재이용이 가능하도록 하는 전기분해조가 포함된 유기슬러지 감량장치에 관한 것이다.In order to achieve the above object, the present invention relates to an organic sludge reduction apparatus including an electrolysis tank, the organic sludge reduction and decomposition material of the organic sludge by using the electrolysis to the return sludge during the biological treatment process is a carbon source of biological advanced treatment The present invention relates to an organic sludge reduction apparatus including an electrolysis tank for reusing.
그 구성을 살펴보면 먼저 유입 오ㆍ폐수에서 침전 가능한 부유물질 제거를 위하여 고ㆍ액분리조를 설치하고, 고ㆍ액분리된 오ㆍ폐수의 유기물 제거를 위하여 생물반응조를 설치하며 생물반응조에는 미생물농도를 측정할 수 있는 혼합액 부유물질 측정기(MLSS METER)와 산화ㆍ환원전위를 측정할 수 있는 산화환원전위 측정기(ORP METER)를 설치한다. 잉여슬러지 배출라인에 자동운전제어장치와 연동된 유량조정밸브를 설치하여 처리수와 분리된 슬러지를 반송슬러지와 잉여슬러지로 구분하며, 반송슬러지라인에 자동운전제어장치와 연동된 유량조정밸브를 설치하여 생물반응조와 전기분해조로 잉여슬러지를 구분하여 유입한다. 전기분해조는 유입된 반송슬러지가 직접 전해되는 전해부를 포함한 직접산화조와 전해된 슬러지의 잉여산화물질의 재산화 및 안정화를 위한 간접산화조로 구성되며, 직접산화조에는 전기분해에 필요한 직류전원을 공급하기위한 정류기가 연결되어 진다. 자동제어운전장치를 설치하여 생물반응조의 MLSS METER, ORP METER, 잉여슬러지라인 및 반송슬러지라인의 유량조정밸브, 직접산화조에 직류전원을 공급하는 정류기와 연동시켜 변화된 조건에 따른 자동운전을 가능하게 한다. In terms of its structure, first, a solid-liquid separation tank is installed to remove suspended solids that can settle in the influent wastewater, and a bioreactor is installed to remove organic matter from the solid-liquid separated waste water. A mixed liquid suspended solids measuring instrument (MLSS METER) and an redox potential measuring instrument (ORP METER) capable of measuring oxidation and reduction potential are installed. Flow rate adjustment valve interlocked with the automatic operation control device is installed in the excess sludge discharge line to classify the sludge separated from the treated water into conveying sludge and surplus sludge, and flow rate adjustment valve interlocked with the automatic operation control device is installed in the return sludge line. The excess sludge is introduced into the bioreactor and the electrolysis tank. The electrolysis tank is composed of a direct oxidation tank including an electrolytic part through which the returned conveyed sludge is directly electrolyzed, and an indirect oxidation tank for the reoxidation and stabilization of surplus oxide material of the electrolyzed sludge. The direct oxidation tank is designed to supply DC power for electrolysis. The rectifier is connected. Automatic control operation device is installed to enable automatic operation according to the changed condition by interlocking with the MLSS METER, ORP METER, surplus sludge line and return sludge line flow control valve, and rectifier supplying DC power to the direct oxidation tank. .
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본 발명에 따른 전기분해조가 포함된 유기슬러지 감량장치를 채택하는 경우, 질산화를 저해하지 않으면서도 최소의 에너지로 목적하는 슬러지 감량을 달성할 수 있다.When adopting the organic sludge reduction device including the electrolysis tank according to the present invention, it is possible to achieve the desired sludge reduction with minimal energy without inhibiting nitrification.
특히, 본 발명은 전기분해조에 의한 전기분해시 상기 자동운전제어장치에 의해 조정되는 정류기 및 타이머에 의해 전류밀도와 시간을 조절하여 유동적으로 전기분해시킴으로써, 폐수의 환경에 따라 질산화를 저해하지 않는 범위에서 최대한 슬러지 감량화를 달성할 수 있는 특징이 있다.In particular, the present invention is a range that does not inhibit the nitrification according to the environment of the wastewater by fluidly electrolyzing by adjusting the current density and time by the rectifier and the timer adjusted by the automatic operation control device during the electrolysis by the electrolysis tank There is a characteristic that can achieve maximum sludge reduction at.
즉, 유입된 오ㆍ폐수의 유기물질 및 영양염류 제거를 위하여 생물반응조로 이송된다. 생물반응조에 부착된 MLSS METER는 생물반응조내의 미생물량을 ORP METER는 생물반응조 내의 산화ㆍ환원전위를 측정, 자동운전제어장치에 운전정보를 전달한다. 생물반응조에서 미생물대사에 의해 유기물질과 영양염류가 제거된 생물처리수는 다수의 미생물이 포함된 유기슬러지와 처리수의 분리를 위하여 고ㆍ액분리조로 이송되어 처리수와 슬러지로 분리된다. 처리된 처리수는 고ㆍ액분리조에서 방류 또는 다음단계의 처리로 이송된다. 고ㆍ액분리조에서 분리된 유기슬러지는 잉여슬러지 배출라인의 유량조정밸브의 조정에 따라 잉여슬러지와 반송슬러지로 구분되며, 반송슬러지 이송라인의 유량조정밸브의 조정에 따라 직접 미생물반응조로 반송되는 슬러지와 슬러지감량 전기분해조로 이송되는 슬러지로 구분된다. 잉여슬러지 이송라인의 유량조절밸브 및 반송슬러지 이송라인의 유량조정밸브는 생물반응조에 설치된 MLSS METER와 ORP METER의 신호에 따라서 작동되는 자동운전제어장치에 의해서 자동조정된다. In other words, it is sent to the bioreactor to remove organic substances and nutrients from the introduced sewage and wastewater. The MLSS METER attached to the bioreactor gives the microbial amount in the bioreactor and the ORP METER measures the oxidation and reduction potential in the bioreactor and sends the operation information to the automatic operation control device. The biologically treated water from which organic substances and nutrients are removed by microbial metabolism in the bioreactor is transferred to the solid and liquid separation tank for separation of organic sludge and treated water containing a large number of microorganisms and separated into treated water and sludge. The treated water is discharged from the solid and liquid separation tank or transferred to the next step of treatment. The organic sludge separated from the solid and liquid separation tank is divided into surplus sludge and conveying sludge according to the adjustment of the flow adjusting valve of the excess sludge discharge line, and sludge that is directly returned to the microbial reactor according to the adjustment of the flow adjusting valve of the conveying sludge conveying line. And sludge reduction into sludge conveyed to the electrolysis tank. The flow regulating valve of the surplus sludge conveying line and the flow regulating valve of the conveying sludge conveying line are automatically adjusted by the automatic operation control device operated according to the signals of MLSS METER and ORP METER installed in the bioreactor.
특히 본 발명은 종래의 고도정수처리의 경우 질산화가 저해되어 전해반응을 하기 어려웠던 문제점을 극복하기 위하여, 생물반응조의 조건에 따라 혼합액 부유물질 측정기(MLSS METER)와 산화환원전위 측정기(ORP METER)에서 전달되는 정보를 이용하여 자동운전제어장치에서 전해반응조의 전류의 세기 및 시간을 조절함으로써 질산화가 일어나지 않는 범위에서 운전이 가능하게 됨으로써 슬러지의 발생량을 감소시킬 수 있음을 확인하였다. In particular, the present invention in order to overcome the problem that the nitrification is difficult to perform the electrolytic reaction in the case of the conventional high-purity water treatment, in the mixed liquid suspended solids measuring instrument (MLSS METER) and redox potential measuring instrument (ORP METER) according to the conditions of the bioreactor By using the transmitted information, it was confirmed that the amount of sludge generated can be reduced by operating in the range where nitrification does not occur by adjusting the intensity and time of the electrolytic reactor in the automatic operation control device.
특히, 본 발명은 상기 혼합액 부유물질 측정기(MLSS METER)를 이용하여 생물반응조 내의 미생물농도를 측정하며, 미생물농도가 높으면 정류기의 전류치를 높게 조정하고, 미생물농도가 낮으면 정류기의 전류치를 낮게 조정하여 생물반응조 내의 미생물농도가 일정하게 유지되도록 한다.In particular, the present invention measures the microbial concentration in the bioreactor using the mixed liquid suspended solids (MLSS METER), if the microbial concentration is high by adjusting the current value of the rectifier high, and if the microbial concentration is low by adjusting the current value of the rectifier low Ensure that the concentration of microorganisms in the bioreactor is kept constant.
또한 상기 산화ㆍ환원전위측정기(ORP METER)는 질산화조내의 산화ㆍ환원전위를 측정하기 위한 것으로, 산화ㆍ환원전위 전위가 높으면 잉여 및 반송슬러지 유량조정밸브를 조정하여 전기분해조로의 슬러지유량을 증가시키고, 산화ㆍ환원전위가 낮으면 잉여 및 반송슬러지 유량조정밸브를 조정하여 전기분해조로의 슬러지유량을 감소시키게 되므로 생물반응조 내의 운전조건을 조절할 수 있어 유기슬러지의 발생량을 감소시킬 수 있다.Also, the ORP METER is used to measure the oxidation and reduction potential in the nitrification tank. When the oxidation and reduction potential is high, the excess and return sludge flow rate adjusting valves are adjusted to increase the sludge flow rate into the electrolysis tank. In addition, if the oxidation and reduction potential is low, the sludge flow rate to the electrolysis tank is reduced by adjusting the surplus and return sludge flow rate adjusting valves, so that the operating conditions in the bioreactor can be adjusted to reduce the amount of organic sludge generated.
이하, 첨부된 도면을 참조하여 본 발명의 고도하폐수처리공정에 대해 상세히 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings will be described in detail with respect to the advanced wastewater treatment process of the present invention.
도 1은 본 발명의 대표도로서 유기슬러지감량 전기분해조의 정류기와 생물반응조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예를 나타낸 것이다. 1 is a representative view of the present invention, the organic sludge reduction electrolysis tank of the organic sludge reduction tank and the MLSS METER, ORP METER, surplus sludge control valve and the return sludge control valve of the bioreactor in the interlock operation of the automatic sludge reduction control system A process example is shown.
도 2는 유기슬러지감량 전기분해조의 정류기와 활성슬러지조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예도이다. 2 is a process example of the organic sludge reduction processing system in which the rectifier of the organic sludge reduction electrolysis tank and the MLSS METER, ORP METER, surplus sludge adjustment valve, and return sludge adjustment valve of the activated sludge tank are operated in conjunction with the automatic operation control device.
도 3은 유기슬러지감량 전기분해조의 정류기와 탈질소탈인 생물반응조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예도이다.3 is a process example of the organic sludge reduction processing system in which the rectifier of the organic sludge reduction electrolysis tank and the MLSS METER, ORP METER, surplus sludge control valve, and return sludge adjustment valve of the denitrification bioreactor are operated in conjunction with the automatic operation control device. .
도 4는 SBR공정에 전기분해장치가 포함된 유기슬러지감량처리시스템의 공정예도이다.4 is a process example of an organic sludge reduction treatment system including an electrolysis device in the SBR process.
도 1에 도시된 바와 같이 본 발명의 일 양태는 As shown in Figure 1 one aspect of the present invention
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전기분해조(40)에서 전기분해 처리된 전해반송슬러지 또는 고ㆍ액 분리조(20)에서 분리된 반송슬러지가 유입되어 유기물 및 영양염류를 제거하는 생물반응조(10);A bioreactor 10 for electrolytically transporting the sludge electrolytically treated in the
상기 생물반응조(10)의 일측에 구비되어 자동운전제어장치(30)로 정보를 전달하는 혼합액 부유물질 측정기(MLSS METER, 11)와 산화환원전위 측정기(ORP METER, 12);A mixed liquid suspended solids measuring device (MLSS METER 11) and a redox potential measuring device (ORP METER 12) provided at one side of the bioreactor 10 to transmit information to the automatic operation control device 30;
상기 생물반응 후 처리수와 유기물 및 영양염류가 제거된 슬러지 분리하기 위한 고ㆍ액 분리조(20);A solid /
상기 고ㆍ액분리조(20)에서 분리된 슬러지를 반송슬러지와 잉여슬러지로 분리하며, 상기 자동운전제어장치에 의해 제어되는 잉여슬러지유량조정밸브(21)와 반송슬러지유량조정밸브(22);A sludge separated from the solid /
상기 혼합액 부유물질 측정기(MLSS METER)와 산화환원전위 측정기(ORP METER)에서 전달받은 운전정보를 이용하여 전류의 세기 및 운전 시간을 조정하는 자동운전제어장치(30);An automatic operation control device (30) for adjusting the strength and operating time of the current by using the operation information received from the mixed solution suspended matter measuring unit (MLSS METER) and redox potential measuring instrument (ORP METER);
상기 자동운전제어장치(30)로부터 전달받은 정보에 따라 잉여슬러지유량조정밸브(21)와 반송슬러지유량조정밸브(22)의 유량조정에 의하여 유입될 슬러지를 전기분해하는 전기분해조(40);An
를 포함하는 것을 특징으로 하는 전기분해조가 포함된 유기슬러지 감량장치를 제공한다.It provides an organic sludge reduction device containing an electrolysis tank comprising a.
또한, 상기 전기분해조(40)는 상기 자동운전제어장치(30)에 의해 조정되어 직류전원을 공급하는 정류기(50)를 더 포함하는 것을 특징으로 한다.In addition, the
또한, 상기 본 발명의 고도하폐수처리시스템에서 생물 반응조(10)에 사용가능한 공정으로는, 도 2에 도시된 바와 같이, 활성슬러지(10-a), 도 3에 도시된 바와 같이, 탈질소탈인 공정(10-b), 및 A2/O(Anaerobic-Anoxic-Oxic)공법 또는 SBR공법에서 선택된 어느 하나로 구성될 수 있다. 상기 SBR공법은 전기분해조에서 전기분해된 전해반송슬러지와 고액분리조에서 분리된 반송슬러지가 혼합되어 유기물질이 제거되고 인이 방출되는 혐기조와; 상기 혐기조에서 배출되는 배출수의 유기물질과 질소가 제거되는 무산소조; 및 상기 무산소조에서 유입된 슬러지 내의 미처리된 유기물질과 암모니아가 제거되는 호기조;가 하나의 반응기 내에 이루어질 수 있다.In addition, the process that can be used in the biological reaction tank 10 in the advanced sewage treatment system of the present invention, as shown in Figure 2, activated sludge (10-a), as shown in Figure 3, denitrification Process (10-b), and A2 / O (Anaerobic-Anoxic-Oxic) method or SBR method can be composed of any one. The SBR method includes an anaerobic tank in which the electrolytic transport sludge electrolyzed in the electrolysis tank and the return sludge separated in the solid-liquid separation tank are mixed to remove organic substances and release phosphorus; An oxygen free tank in which organic substances and nitrogen in the effluent discharged from the anaerobic tank are removed; And an aerobic tank in which untreated organic matter and ammonia in the sludge introduced from the anoxic tank are removed.
다음으로 본 발명의 또 다른 양태로는 도 4에 도시된 바와 같이, Next, as another embodiment of the present invention, as shown in FIG.
고ㆍ액 분리조(20)에서 분리된 반송슬러지와 전기분해조(40)에서 전기분해 처리된 전해반송슬러지가 유입되어 유기물질이 제거되고 인이 방출되는 혐기조, 상기 혐기조에서 배출되는 배출수의 유기물질과 질소가 제거되는 무산소조, 및 상기 무산소조에서 유입된 슬러지 내의 미처리된 유기물질과 암모니아가 제거되는 호기조가 하나의 반응기 내에서 이루어지는 SBR 생물반응조(10-c);
상기 생물반응 후 처리수와 유기물 및 영양염류가 제거된 슬러지 분리하기 위한 고ㆍ액 분리조(20);The return sludge separated in the solid and
A solid /
상기 SBR 생물반응조(10-c)의 일측에 구비되어 자동운전제어장치(30)로 정보를 전달하는 혼합액 부유물 슬러지농도계(MLSS METER, 11)와 산화환원전위 측정기(ORP METER, 12);A mixed liquid suspended solids sludge concentration meter (MLSS METER) 11 and an
상기 SBR 생물반응조(10-c)에서 분리된 슬러지를 반송슬러지와 잉여슬러지로 분리하며, 상기 자동운전제어장치에 의해 제어되는 잉여슬러지유량조정밸브(21)와 반송슬러지유량조정밸브(22);A sludge separated from the SBR bioreactor (10-c) into a conveying sludge and a surplus sludge, and an excess sludge flow rate adjusting valve 21 and a conveying sludge flow rate adjusting valve 22 controlled by the automatic operation control device;
상기 혼합액 부유물질 측정기(MLSS METER)와 산화환원전위 측정기(ORP METER)에서 전달받은 운전정보를 이용하여 운전조건을 조정하는 자동운전제어장치(30);Automatic operation control device 30 for adjusting the operating conditions using the operation information received from the mixed solution suspended matter measuring device (MLSS METER) and the redox potential measuring device (ORP METER);
상기 자동운전제어장치(30)로부터 전달받은 정보에 따라 잉여슬러지유량조정밸브(21)와 반송슬러지유량조정밸브(22)가 잠기는 경우 유입된 슬러지를 전기분해하는 전기분해조(40);An
를 포함하는 것을 특징으로 하는 전기분해조가 포함된 유기슬러지 감량장치를 제공한다.It provides an organic sludge reduction device containing an electrolysis tank comprising a.
본 발명에서 상기 전기분해조(40)는 도 5에 도시된 바와 같이, 유기슬러지와 전해전극의 접촉을 극대화하기 위한 상향류식의 교반기가 부착된 직접산화조와 전해된 슬러지내에 포함된 과산화물질의 재산화 및 안정화를 위한 산기장치가 설치된 간접산화조를 포함하는 수로형(개방형) 슬러지감량 전기분해조 또는 도 6에 도시된 바와 같이, 관류형(밀폐형) 슬러지감량 전기분해조를 사용할 수 있다.In the present invention, the
상기 수로형(개방형) 슬러지감량조는 직접산화조와 간접산화조로 구분된다. 반송슬러지중 전기분해장치로 이송되는 슬러지는 직접산화조의 하부로 유입되어 상향류로 이동되며 직접산화조에는 교반기가 설치되어 슬러지와 전해전극의 접촉을 촉진하여 직접산화효율을 높인다. 직접산화조에서 전해된 슬러지는 전해된 슬러지 내에 포함된 과산화물질의 재산화와 안정화를 위하여 간접산화조로 이송된다. 간접산화조의 하부에는 산기장치를 설치하여 과산화물의 안정화를 촉진시킨다. The channel (open type) sludge reduction tank is divided into a direct oxidation tank and an indirect oxidation tank. The sludge conveyed to the electrolysis device in the conveying sludge is introduced into the lower part of the direct oxidation tank and moved upward. The agitator is installed in the direct oxidation tank to promote the contact between the sludge and the electrolytic electrode, thereby improving the direct oxidation efficiency. The sludge electrolyzed in the direct oxidation tank is transferred to the indirect oxidation tank for reoxidation and stabilization of peroxides contained in the electrolyzed sludge. At the bottom of the indirect oxidation tank, an acid generator is installed to promote stabilization of the peroxide.
또한 관류형의 경우 관내의 유속에 의하여 슬러지와 전해전극의 접촉이 이루어지며 관의 전단부에 전해전극이 집중배치되어 직접산화가 이루어지며, 관의 후단부에서 간접산화 및 안정화가 이루어진다. 전해전극에 직류전원을 공급하는 정류기는 생물반응조에 설치된 MLSS METER와 ORP METER의 신호에 따라서 작동되는 자동운전제어장치에 의해서 직류전원의 강도가 결정되거나 타이머에 의한 시차운전이 이루어지도록 할 수 있다. 직접, 간접산화조를 거친 전해반송슬러지는 생물반응조에 유입 오ㆍ폐수와 함께 다시 유입되어 생물학적 대사작용을 거치게 된다. In the case of the perfusion type, the sludge and the electrolytic electrode are contacted by the flow rate in the tube. The electrolytic electrode is concentrated at the front end of the tube, so that the direct oxidation is performed, and the indirect oxidation and stabilization is performed at the rear end of the tube. The rectifier for supplying the DC power to the electrolytic electrode can determine the strength of the DC power supply or the time difference operation by the timer by the automatic operation control device operated according to the signals of the MLSS METER and the ORP METER installed in the bioreactor. Electrolytic transport sludge, which has undergone direct and indirect oxidation tanks, flows back into the bioreactor with the wastewater and wastewater and undergoes biological metabolism.
도 7은 관류형(밀폐형) 슬러지감량 전기분해조 전해부 단면도이고, 도 8은 관류형(밀폐형) 슬러지감량 전기분해조 유출부 단면도이다. 상기 전기분해조에서 유기물질과 영양소를 제거하는 과정에서 사용되는 극판은 모양이 망형, 원통망형, 봉형 중의 어느 하나로 이루어지며, 극판의 재질은 양극(+극)은 티타늄모재에 산화이리듐을 코팅하며, 음극(-극)은 티타늄, 스테인리스 재질중의 한 가지를 사용할 수 있다.7 is a cross-sectional view of the once-through (sealed) sludge reduction electrolysis tank electrolytic unit, and FIG. 8 is a cross-sectional view of the through-flow (sealed) sludge reduction electrolysis tank outlet. The electrode plate used in the process of removing organic substances and nutrients from the electrolysis tank is made of any one of a mesh, a cylindrical mesh, and a rod shape. The material of the electrode plate is a positive electrode (+ pole) to coat iridium oxide on a titanium base material. The negative electrode can be made of either titanium or stainless steel.
상기와 같이 본 발명은 기존의 전기분해를 이용한 유기슬러지감량장치의 가장 큰 문제점이었던 미생물의 과산화에 의한 질산화균의 감소로 질산화작용을 저해하는 등 생물학적고도처리의 효율을 떨어뜨리는 문제점을 해결할 수 있었으며, 탈 질ㆍ탈인공정이 포함된 생물학적고도처리에 적용할 수 있는 장치를 제공할 수 있다.As described above, the present invention was able to solve the problem of lowering the efficiency of biological altitude treatment such as inhibiting nitrification by the reduction of nitrifiers by the peroxidation of microorganisms, which was the biggest problem of the conventional sludge reduction apparatus using electrolysis. It is possible to provide a device that can be applied to biological advanced treatment including denitrification and dephosphorization processes.
또한 본 발명은 전해된 유기슬러지의 감량뿐만 아니라 생성되는 분해가용물질이 생물학적고도처리의 탄소원으로 재이용되어 추가 탄소원을 줄일 수 있어 경제적인 운전이 가능하다.In addition, the present invention is economical operation is possible because it is possible to reduce the additional carbon source by reducing the amount of electrolyzed organic sludge, as well as the resulting decompositionally available material is reused as a carbon advanced biological treatment.
또한 본 발명은 전해된 잉여슬러지의 경우 일반 생물학적슬러지에 비하여 농축성 및 탈수성이 높고, 탈수 후 케익 내에 병원성 및 부패성균이 없으므로 최종처분 시 이차오염을 최소화할 수 있다.In addition, the present invention has a high concentration and dehydration in the case of the electrolytic surplus sludge, compared to the general biological sludge, there is no pathogenic and perishable bacteria in the cake after dehydration can minimize the secondary pollution at the final disposal.
본 발명의 전기분해조가 포함된 유기슬러지 감량장치를 통하여 생성된 전해반송슬러지는 미생물의 과산화에 의한 생물학적고도처리의 효율을 저하하지 않고, 또한 전기분해후 슬러지의 분해가용물질이 생물학적고도처리의 탄소원으로 재이용이 가능하여 매우 경제적인 슬러지감량장치임을 알 수 있다. The electrolytic transport sludge produced through the organic sludge reduction device including the electrolysis tank of the present invention does not reduce the efficiency of the biological advanced treatment by the peroxidation of microorganisms, and the decompositionally available material of the sludge after the electrolysis is a carbon source for biological advanced treatment. As it can be reused, it is a very economical sludge reduction device.
이하 본 발명을 첨부된 도면 및 실험결과를 참조하여 더욱 상세히 설명한다.Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings and experimental results.
[실시예 1]Example 1
도 3에 도시된 바와 같이, 탈질ㆍ탈인공정 생물반응조와 생물학적고도처리에 유기슬러지감량을 위한 전기분해조가 포함된 유기슬러지 감량장치를 이용하였다.As shown in FIG. 3, an organic sludge reduction apparatus including an electrolysis tank for organic sludge reduction in a denitrification and dephosphorization process bioreactor and a biological advanced treatment was used.
유기슬러지감량 효과를 비교하기 위하여, 전기분해조를 가동한 경우를 전해군으로 하고, 전기분해조를 가동하지 않은 경우를 대조군으로 하여 실험하였다.In order to compare the organic sludge reduction effect, the electrolysis tank was operated as an electrolytic group and the electrolysis tank was not used as a control.
하기 표1은 생물학적고도처리를 이루는 각 반응조의 용량 및 부대시설이며, 표2는 유입하수 및 각 반응조의 수질환경을 나타낸 것이다. Table 1 below shows the capacity and auxiliary facilities of each reactor for biologically advanced treatment, and Table 2 shows the influent sewage and the water environment of each reactor.
[표 1] 1차 실험장치의 각 반응조별 용량 및 부대시설 [Table 1] Capacity and Auxiliary Facilities for Each Reactor of Primary Experimental Device
[표 2]유입하수 및 각 반응조의 수질환경 [Table 2] Influent sewage and water environment of each reactor
유기슬러지감량의 산정은 전해군과 대조군에서 장시간 운전 시 생물반응조의 MLSS 농도가 동일하도록 하는 조건에서 발생되는 잉여슬러지의 배출누적량으로 측정하였다.The organic sludge reduction was measured by the accumulated accumulation of excess sludge produced under the condition that the MLSS concentration of the bioreactor was the same in the electrolyzer and the control group for a long time.
중량물재생센타에서 2004년 8월부터 2005년 1월 까지 수행된 1차 실험의 결 과는 아래표와 같다.The results of the first experiment conducted at the Heavy Regeneration Center from August 2004 to January 2005 are shown in the table below.
[표 3] 1차 실험 전해군 운전결과(내부반송율 100%, 반송율 50%, 전류밀도 1.5A/ℓ) [Table 3] Operation result of the first experimental electrolytic group (
[표 4] 1차 실험 대조군 운전결과 (내부반송율 100%, 반송율 50%) [Table 4] Results of the first experimental control operation (
상기 표3, 4 및 도 9 의 결과에서 볼 수 있듯이 전체적으로 전해군의 유기슬러지감량율은 약 45% 정도로 대조군에 비하여 슬러지의 감량율이 높은 것을 알 수 있었다. As can be seen from the results of Tables 3, 4 and 9, the overall sludge reduction rate of the electrolytic group was about 45%, and the sludge reduction rate was higher than that of the control group.
[실시예 2]Example 2
도 2에 도시된 바와 같이, 생물학적고도처리가 포함되지 않은 일반 활성슬러지공정에서의 전기분해장치가 포함된 유기슬러지감량장치를 이용하였다.As shown in FIG. 2, an organic sludge reduction device including an electrolysis device in a general activated sludge process without biological advanced treatment was used.
유기슬러지감량 효과를 비교하기 위하여, 전기분해조를 가동한 경우를 전해군으로 하고, 전기분해조를 가동하지 않은 경우를 대조군으로 하여 실험하였다.In order to compare the organic sludge reduction effect, the electrolysis tank was operated as an electrolytic group and the electrolysis tank was not used as a control.
표 5는 전기분해유기슬러지감량장치가 포함된 일반활성슬러지공정의 반응조 용량 및 부대시설이며, 표 6은 유입하수 및 각 반응조의 수질환경을 나타낸 것이다.Table 5 shows the reactor capacity and auxiliary facilities of the general activated sludge process including the electrolysis organic sludge reduction device, and Table 6 shows the influent sewage and the water quality of each reactor.
[표 5] 2차 실험장치의 각 반응조별 용량 및 부대시설 [Table 5] Capacity and Auxiliary Facilities for Each Reactor of Secondary Experiment Equipment
[표 6] 유입하수 및 각 반응조의 수질환경 [Table 6] Influent sewage and water environment of each reactor
유기슬러지감량의 산정은 전해군과 대조군에서 장기간 운전 시 생물반응조의 MLSS 농도가 동일하도록 하는 조건에서 발생되는 잉여슬러지의 배출누적량으로 측정하였다. The organic sludge reduction was measured by the accumulated accumulation of excess sludge produced under the condition that the MLSS concentration of the bioreactor was the same in the electrolyzer and the control group for a long time operation.
중량물재생센타에서 2006년 3월부터 2006년 5월 까지 수행한 2차 실험의 결과는 아래 표 7과 같다.The results of the second experiment conducted from March 2006 to May 2006 at the Heavy Water Regeneration Center are shown in Table 7 below.
[표 7] 2차 실험 전해군 운전결과(반송율 50%, 전류밀도 1.5A/ℓ) [Table 7] Second experimental electrolytic group operation result (
[표 8] 2차 실험 대조군 운전결과(반송율 50%) [Table 8] Second Experimental Control Operation Result (
위 표 7, 8 및 도 10의 결과에서 볼 수 있듯이, 전체적으로 전해군의 유기슬러지 감량율은 약 45% 정도로 우수한 것을 알 수 있었으며, BOD, CODcr, T-N, T-P, SS 등의 제거효율도 거의 비슷하게 나타났다. 이 결과로 보아 탈질, 탈인공정이 포함된 생물학적고도처리가 아닌 일반활성오니공정에서는 전기분해시 미생물의 과산화가 생물처리효율에는 큰 영향을 미치지 않음을 알 수 있었다.As can be seen from the results of Tables 7, 8 and 10 above, the overall organic sludge reduction rate was about 45%, and the removal efficiency of BOD, CODcr, TN, TP, SS, etc. was almost the same. appear. As a result, it was found that the peroxidation of microorganisms during electrolysis does not have a significant effect on the biotreatment efficiency in the general activated sludge process, which is not a biologically advanced process including denitrification and dephosphorization.
[실시예 3]Example 3
생물학적고도처리공정중 가장 일반적으로 적용되는 A2/O공법에 전기분해유기슬러지 감량장치를 적용하여 결과를 측정하였다. 유기슬러지감량 효과를 비교하기 위하여, 전기분해조를 가동한 경우를 전해군으로 하고, 전기분해조를 가동하지 않은 경우를 대조군으로 하여 실험하였다. 이때 호기조는 탈질조로 내부반송 되도록 설계하였다.The results were measured by applying the electrolysis organic sludge reduction device to the A2 / O method, which is the most commonly applied biological biological treatment process. In order to compare the organic sludge reduction effect, the electrolysis tank was operated as an electrolytic group and the electrolysis tank was not used as a control. At this time, the aerobic tank was designed to be transported internally to the denitrification tank.
표 9는 전기분해유기슬러지감량장치가 포함된 생물학적고도처리공정의 반응조 용량 및 부대시설이며, 표 10은 유입하수 및 각 반응조의 수질환경이다.Table 9 shows the reactor capacity and auxiliary facilities of the biological advanced treatment process including the electrolytic organic sludge reduction device, and Table 10 shows the influent sewage and the water environment of each reactor.
[표 9] 3차 실험장치의 각 반응조별 용량 및 부대시설[Table 9] Capacity and Auxiliary Facilities for Each Reactor of the Third Experimental Device
[표 10] 3차 실험의 유입하수 및 각 반응조의 수질환경[Table 10] Influent sewage and water quality of each reactor in the 3rd experiment
유기슬러지감량의 산정은 전해군과 대조군에서 장기간 운전 시 생물반응조의 MLSS 농도가 동일하도록 하는 조건에서 발생되는 잉여슬러지의 배출누적량으로 측정하였다. The organic sludge reduction was measured by the accumulated accumulation of excess sludge produced under the condition that the MLSS concentration of the bioreactor was the same in the electrolyzer and the control group for a long time operation.
중량물 재생센타에서 2006년 9월부터 2006년 12월까지 수행한 3차 실험의 결과는 아래표와 같다.The results of the third experiment conducted from September 2006 to December 2006 at the Heavy Goods Regeneration Center are shown in the table below.
[표 11] 3차 실험 전해군 운전결과(내부반송율 100%, 반송율 50%, 전류밀도 1A/ℓ)[Table 11] Operation results of the third experimental electrolytic group (
[표 12] 3차 실험 대조군 운전결과(내부반송율 100%, 반송율 50%) [Table 12] Third Experimental Control Results (
위 표11, 12, 도 11의 결과에서 볼 수 있듯이 전체적으로 전해군의 유기슬러지감량은 약 40% 정도이며, BOD, CODcr, T-N, T-P, SS 등의 제거율도 거의 비슷하게 나타났다. As can be seen in the results of Tables 11, 12, and 11 above, the total amount of organic sludge reduction in the electrolytic group was about 40%, and the removal rates of BOD, CODcr, T-N, T-P, and SS were almost similar.
이 결과로 보아 생물학적고도처리공정에서도 생물반응조의 MLSS 및 ORP METER의 측정에 따른 반송슬러지유량, 전해반송슬러지유량, 전기분해조의 전류밀도 등의 유기적인 조정에 의하여 미생물처리효율을 떨어뜨리지 않고, 최소의 에너지로 유기슬러지감량율을 달성할 수 있음을 확인하였다.As a result, even in the biological advanced treatment process, the microbial treatment efficiency is not reduced by the organic adjustment of the return sludge flow rate, the electrolytic return sludge flow rate, and the current density of the electrolysis tank according to the measurement of the MLSS and ORP METER of the bioreactor. It was confirmed that the organic sludge reduction rate can be achieved with the energy of.
도 1은 본 발명의 대표도로서 유기슬러지감량 전기분해조의 정류기와 생물반응조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예도.1 is a representative view of the present invention, the organic sludge reduction electrolysis tank of the organic sludge reduction tank and the MLSS METER, ORP METER, surplus sludge control valve and the return sludge control valve of the bioreactor in the interlock operation of the automatic sludge reduction control system Process illustration.
도 2는 유기슬러지감량 전기분해조의 정류기와 활성슬러지조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예도.2 is a process example of the organic sludge reduction processing system in which the rectifier of the organic sludge reduction electrolysis tank and the MLSS METER, ORP METER, surplus sludge adjustment valve, and return sludge adjustment valve of the activated sludge tank are operated in conjunction with the automatic operation control device.
도 3은 유기슬러지감량 전기분해조의 정류기와 탈질소탈인 생물반응조의 MLSS METER, ORP METER, 잉여슬러지 조정밸브 및 반송슬러지 조정밸브가 자동운전제어장치에 연동 운전되는 유기슬러지감량 처리시스템의 공정예도.3 is a process example of the organic sludge reduction processing system in which the rectifier of the organic sludge reduction electrolysis tank and the MLSS METER, ORP METER, surplus sludge regulating valve, and return sludge adjusting valve of the bioreactor in denitrification are operated in conjunction with the automatic operation control device.
도 4는 SBR공정에 전기분해장치가 포함된 유기슬러지감량처리시스템의 공정예도.Figure 4 is a process example of the organic sludge reduction treatment system including an electrolysis device in the SBR process.
도 5는 수로형(개방형) 슬러지감량 전기분해조.5 is a channel (open type) sludge reduction electrolysis tank.
도 6은 관류형(밀폐형) 슬러지감량 전기분해조.Figure 6 is a once-through (sealed) sludge reduction electrolysis tank.
도 7은 관류형(밀폐형) 슬러지감량 전기분해조 전해부 단면도.7 is a cross-sectional view of the electrolytic part of the flow through (sealed) sludge reduction electrolysis tank.
도 8은 관류형(밀폐형) 슬러지감량 전기분해조 유출부 단면도.8 is a cross-sectional view of the flow-through (sealed) sludge reduction electrolysis tank outlet.
도 9는 1차 전기분해장치에 의한 대조군과 전해군의 운전일별 잉여슬러지 발생 비교누적량 ( ◆:대조군, ▲:전해군) 9 is a comparative accumulation amount of excess sludge generation by operation day of the control group and the electrolytic group by the first electrolysis device (◆: control group, ▲: electrolytic group)
도 10은 2차 전기분해장치에 의한 유기슬러지감량결과 대조군과 전해조의운전일별 잉여슬러지 발생 비교누적량 (◆:전해군. ■:대조군) 10 is a comparative accumulation amount of excess sludge generation by operation day of the control group and the electrolyzer according to the organic sludge reduction result by the secondary electrolysis device (◆: electrolysis group. ■: control group)
도 11은 3차 전기분해장치에 의한 유기슬러지감량결과 대조군과 전해조의 운전일별 잉여슬러지 발생 비교누적량 (■:대조군, □:전해군)FIG. 11 is a comparative accumulation amount of excess sludge generation by operation days of the control group and the electrolyzer according to the organic sludge reduction result by the third electrolysis device (■: control group, □: electrolysis group)
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KR100924584B1 (en) | 2008-09-16 | 2009-10-30 | 정재형 | Device for handling waste water |
KR101494398B1 (en) | 2014-06-17 | 2015-02-23 | 주식회사 워터스 | Apparatus for wastewater treatment with submerged membrane |
KR101840592B1 (en) * | 2017-03-10 | 2018-03-21 | 한양대학교 산학협력단 | Hybrid electrolysis apparatus and electrolysis method using thereof |
KR102142882B1 (en) * | 2019-10-30 | 2020-08-10 | 송영일 | PROCESS AND APPARATUS FOR REMOVING NITROGEN AND PHOSPORUS USING Fe ELECTROLYSIS AND OZON |
US10857658B2 (en) | 2016-07-27 | 2020-12-08 | Daemo Engineering Co., Ltd. | Hydraulic percussion device and construction apparatus having the same |
KR102561763B1 (en) | 2023-02-20 | 2023-07-31 | 주식회사 인터퓨어 | Manufacturing method of composition for removing sludge |
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KR20040031359A (en) * | 2002-10-04 | 2004-04-13 | 엄태경 | Advanced treatment apparaters and method for removal of nitrogen and phosphorus inf sewage water |
KR20050099281A (en) * | 2004-04-09 | 2005-10-13 | 이병헌 | Advanced wastewater treatment system with electrolysis of sidestream |
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KR20040031359A (en) * | 2002-10-04 | 2004-04-13 | 엄태경 | Advanced treatment apparaters and method for removal of nitrogen and phosphorus inf sewage water |
KR20050099281A (en) * | 2004-04-09 | 2005-10-13 | 이병헌 | Advanced wastewater treatment system with electrolysis of sidestream |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100924584B1 (en) | 2008-09-16 | 2009-10-30 | 정재형 | Device for handling waste water |
KR101494398B1 (en) | 2014-06-17 | 2015-02-23 | 주식회사 워터스 | Apparatus for wastewater treatment with submerged membrane |
US10857658B2 (en) | 2016-07-27 | 2020-12-08 | Daemo Engineering Co., Ltd. | Hydraulic percussion device and construction apparatus having the same |
KR101840592B1 (en) * | 2017-03-10 | 2018-03-21 | 한양대학교 산학협력단 | Hybrid electrolysis apparatus and electrolysis method using thereof |
KR102142882B1 (en) * | 2019-10-30 | 2020-08-10 | 송영일 | PROCESS AND APPARATUS FOR REMOVING NITROGEN AND PHOSPORUS USING Fe ELECTROLYSIS AND OZON |
KR102561763B1 (en) | 2023-02-20 | 2023-07-31 | 주식회사 인터퓨어 | Manufacturing method of composition for removing sludge |
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