KR100805742B1 - Composition for producing seaweed forest attachment means and the attachment means produced thereby - Google Patents
Composition for producing seaweed forest attachment means and the attachment means produced thereby Download PDFInfo
- Publication number
- KR100805742B1 KR100805742B1 KR1020070008074A KR20070008074A KR100805742B1 KR 100805742 B1 KR100805742 B1 KR 100805742B1 KR 1020070008074 A KR1020070008074 A KR 1020070008074A KR 20070008074 A KR20070008074 A KR 20070008074A KR 100805742 B1 KR100805742 B1 KR 100805742B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- composition
- deforestation
- mineral powder
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3072—Iron sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
본 발명은 해중림 조성부재에 관한 것으로, 보다 구체적으로는 해조류들이 잘 착생할 수 있는 부착기질을 제공하는 해중림 조성부재 제조용 배합조성물 및 상기 배합조성물로 제조된 해중림 조성부재에 관한 것이다.The present invention relates to a deforestation composition member, and more particularly to a combination composition for producing a deforestation composition member for providing an attachment substrate that can be well grown seaweeds and a deforestation composition member made of the blend composition.
해조류는 생태계의 일차생산자로서 그 기능이 매우 중요하다. 최근 동해안에는 쿠로시오 난류의 강세와 엘리뇨 현상, 기타 환경오염 등의 원인으로 인한 해조의 천이로 기존 연안에 서식하고 있던 미역, 다시마, 대황등 유용 해조가 없어지고, 그 자리에 홍조류의 일종인 무절산호조류('석회조류'라고도 칭함)가 대량 번식하여 암반을 뒤덮는 백화현상(Whitening Event)이 많이 발생되고 있다. 이러한 백화현상은 아직까지 정확한 원인을 규명하지 못하고 있으나, 쿠로시오 난류세력의 확산 및 환경변화로 인한 수온의 상승과 조식성 동물의 과다 섭생 등을 원인으로 꼽고 있다. Algae are the primary producers of ecosystems and their function is very important. In recent years, the seashore has been transformed due to the strength of Kuroshio turbulence, the Elino phenomenon, and other environmental pollution, so that useful seaweed such as seaweed, kelp, and rhubarb inhabiting the coast has been lost. Algae (also called 'lime algae') are multiplying and whitening events are occurring. The phenomena of the bleaching have not yet been identified, but they are attributed to the increase in water temperature due to the spread of Kuroshio turbulent forces and environmental changes, and the overdose of breakfast animals.
또한, 제주도 연안어장에서도 무성했던 감태, 모자반 등의 다년생 해조군락 이 고수온, 저염분, 해양오염, 그리고 조식성동물의 과다 섭생으로 생태계가 파괴되어 백화현상이 넓은 면적에서 일어나고 있으며, 그 피해면적은 점차 확산되고 있는 실정이다. 이와 같은 백화현상이 발생한 지역에서는 조식성(藻食性) 생물의 먹이 및 어류 서식장의 소멸로 인해 먹이사슬의 구조변화와 이에 따른 생태계 변화가 초래되어 결국 연안어장이 황폐화된다. In addition, perennial algae communities such as Ecklonia cava and Mabanban, which were also grown in the coastal fishing grounds of Jeju Island, are destroyed by high water temperature, low salinity, marine pollution, and over-ingestion of breakfast animals. It is gradually spreading. In the area where such phenomena occur, the extinction of food and fish habitat of breakfast organisms leads to structural changes in the food chain and ecosystem changes, resulting in the devastation of coastal fisheries.
특히 제주도 일원에서 발생되고 있는 백화 현상은 대부분 수심 5~10m 정도의 연안어장에서 발생되고 있어서, 나잠업을 비롯한 연안어업에 큰 피해를 주어 어업인의 소득감소로 이어지고 있다. 또한, 동해안 일대에서는 백화현상이 급속하게 확산되어 연안 양식어장이 황폐화되고 있으며 미역, 다시마 등의 해중림도 급격히 파괴되어 전복, 성게등의 먹이 사슬 구조 변화와 각종 어류의 산란 및 서식환경을 포함한 해양생태계에 상당한 영향을 미치고 있는 실정이다. 이러한 백화현상은 동해안 전역에서 발생하고 있고, 연안 10m 내외의 수심까지 확산되고 있으며, 지금까지 총 어장의 넓은 면적에서 발생하여 어민들에게 큰 피해를 입히고 있는 실정이다. In particular, most of the whitening phenomena in Jeju Island occur at coastal fisheries with a depth of 5 ~ 10m, causing severe damage to coastal fisheries, including nap fishing, leading to a decrease in income of fishers. In addition, the phenomena of whitening phenomena are rapidly spreading in the east coast, and the coastal fish farms are devastated, and the marine forests such as seaweed and kelp are also destroyed rapidly. It has a significant impact on the situation. These phenomena occur all over the east coast, are spreading to depths of about 10m off the coast, and so far, they have occurred in large areas of total fishing grounds, causing great damage to fishermen.
이러한 문제를 풀어 위와 같은 황폐화된 연안어장의 생태계 회복과 어업인의 소득증대를 위해서 백화현상 발생 해역에 해중림을 조성하여 안정적인 해양생태계를 유지하는 방안이 절실히 요구되고 있다.In order to solve these problems, there is an urgent need to maintain a stable marine ecosystem by creating a marine forest in the area where the phenomena occur, in order to recover the ecosystem of the devastated coastal fisheries and increase the income of fishers.
이를 위해 다양한 인공어초가 개발되었으나, 종래의 인공어초는 다수의 프레임이나 플레이트로만 구성되어 있어 해조류의 포자나 인공종묘사가 인공어초상에 부착되어도 그 표면이 매끈하고 또한 서식할 수 있는 면적이 작아 해조류의 포자나 인공종묘사가 착상하기가 힘들었다. 그 결과, 해중림의 형성이 제대로 진행되지 못 하여 황폐화된 연안어장을 회복시키는 데 한계가 있었다. Various artificial reefs have been developed for this purpose, but the conventional artificial reefs consist of only a large number of frames or plates, so even if spores or artificial seedlings are attached to artificial reefs, their surface is smooth and the area where they can inhabit is small. I was difficult to conceive of artificial seedlings. As a result, the formation of marine forests did not proceed properly and there was a limit in restoring the devastated coastal fishery.
따라서, 바다 속에 설치된 인공구조물에 해조류가 잘 착생하고 성장할 수 있는 해조류 부착기질의 개발과 상기 기질을 이용한 해중림조성부재의 개발에 대한 당업계의 요구가 다수 존재하고 있다.Therefore, there are many demands in the art for the development of an algae attachment substrate that can grow and grow algae well in an artificial structure installed in the sea, and the development of a deforestation member using the substrate.
본 발명은 상기 문제점을 해결하기 위하여 이루어진 것으로, 본 발명의 목적은 해역에서 자연 발생된 해조류의 유주자 또는 인공 종묘된 어린 해조류가 잘 착생할 수 있는 부착기질의 배합조성물을 제공하는데 있다.The present invention has been made to solve the above problems, and an object of the present invention is to provide a composition of the adhesion substrate that can be well lived in the seaweeds or artificial seedlings of seaweeds naturally generated in the sea.
또한, 본 발명의 다른 목적은 착생된 해조류의 유주자 또는 인공종묘된 어린 해조류가 잘 성장할 수 있도록 해조류 성장에 필요한 성분을 제공할 수 있는 부착기질의 배합조성물을 제공하는데 있다.In addition, another object of the present invention is to provide a blend composition of the adhesion substrate that can provide the components necessary for the growth of algae so that the live algae or artificial seedlings of the algae can grow well.
또한, 본 발명의 다른 목적은 상기 부착기질로 제조된 해중림 조성부재를 제공하는데 있다. In addition, another object of the present invention to provide a deforestation composition member made of the adhesive substrate.
상기 목적을 달성하기 위하여, 본 발명은 합성고무 40 내지 43중량부를 기준으로, 무기충진제(filler) 6 내지 7중량부, 금속성광물분말 2 내지 4중량부, 암석성 광물분말 1 내지 2중량부, 카본블랙 15 내지 20중량부, 파라핀오일 7 내지 10중량부, 아연화(ZnO) 3 내지 4 중량부, 활성제 0.5 내지 2중량부를 포함하는 것을 특징으로 하는 해중림 조성부재용 배합조성물을 제공한다.In order to achieve the above object, the present invention is based on 40 to 43 parts by weight of synthetic rubber, inorganic filler (filler) 6 to 7 parts by weight, metallic mineral powder 2 to 4 parts by weight, mineral mineral powder 1 to 2 parts by weight, 15 to 20 parts by weight of carbon black, 7 to 10 parts by weight of paraffin oil, 3 to 4 parts by weight of zinc (ZnO), and 0.5 to 2 parts by weight of an active agent are provided.
상기 합성고무 42중량부를 기준으로 발포제 11 내지 13중량부, 가교조제 1 내지 2 중량부, 및 기타 첨가제 5 내지 10중량부를 더 포함하는 것을 특징으로 한다.11 to 13 parts by weight of blowing agent, 1 to 2 parts by weight of crosslinking aid, and 5 to 10 parts by weight of other additives, based on 42 parts by weight of the synthetic rubber.
상기 합성고무는 EPDM이고, 상기 금속성광물분말은 황산철이며, 암석성광물분말은 견운모 또는 규조토인 것을 특징으로 한다.The synthetic rubber is EPDM, the metallic mineral powder is iron sulfate, the rock mineral powder is characterized in that the mica or diatomaceous earth.
상기 첨가제는 유황, 썬녹, 촉진제, 광택제, TT, TRA, 및 노방D, RD노방 중 하나 이상인 것을 특징으로 한다.The additive is characterized in that at least one of sulfur, sun rust, accelerators, polishes, TT, TRA, and furnace D, RD furnace.
본 발명은 또한 상술한 어느 하나의 배합조성물로 제조된 해중림 조성부재를 제공한다. The present invention also provides a deforestation composition member made of any one of the combination composition described above.
상기 해중림 조성부재는 천연 해조류 형상을 갖는 것을 특징으로 한다.The marine forest composition member is characterized in that it has a natural seaweed shape.
상기 해중림 조성부재에 어린 해조류가 부착된 로프를 더 부착하는 것을 특징으로 한다.The seaweeds are characterized in that the rope further attached to the seaweed composition member.
이하, 실시예를 참조하여 본 발명의 구성을 보다 구체적으로 설명하기로 한다.Hereinafter, the configuration of the present invention will be described in more detail with reference to Examples.
먼저, 본 발명의 배합조성물은 그 배합조성을 합성고무의 중량을 기준으로 결정하게 되는데, 합성고무 40 내지 43중량부를 기준으로 다른 구성성분의 함량을 결정한다. 여기서, 합성고무의 중량기준을 40중량부보다 적게 하거나, 43중량부보다 많게 하여 배합조성물을 구성하게 되면 원하는 물성의 해중림 조성부재를 얻을 수 없다. 즉 상술한 합성고무의 배합비 기준함량은 해중림 조성부재의 성형을 용이하게 하고, 내염성 및 내인장성이 최적이 되는 함량을 수 십회 이상의 실험을 거쳐 실험적으로 결정한 것이다. 이 때 상기 합성고무는 EPDM을 사용하는 것이 바람직한데, EPDM은 에틸렌프로필렌고무 (ethylene propylene rubber)의 약칭으로 EPDM은 에틸렌과 프로필렌을 혼성중합시켜 얻은 비결정성(非結晶性) 고분자물질이다. EPDM은 화학적으로 안정하며, 가황한 것은 물리적 성질이 천연고무와 SBR의 중간성질을 보이므로, 자동차부품과 기계부품, 전기부품 등에 널리 사용되어 왔다.First, the blend composition of the present invention is to determine the blend composition based on the weight of the synthetic rubber, the content of the other components based on 40 to 43 parts by weight of the synthetic rubber. Here, if the weight basis of the synthetic rubber is less than 40 parts by weight, or more than 43 parts by weight to form a blended composition can not obtain the detrimental composition member of the desired physical properties. That is, the compounding ratio reference content of the above-described synthetic rubber facilitates the molding of the deforestation composition member, and is an experimentally determined content after several dozen or more experiments for the optimum flame resistance and tensile resistance. In this case, the synthetic rubber is preferably EPDM. EPDM is an abbreviation of ethylene propylene rubber, and EPDM is an amorphous polymer obtained by interpolymerizing ethylene and propylene. EPDM is chemically stable, and the vulcanized material has been widely used in automobile parts, machine parts, and electric parts because its physical properties show intermediate properties between natural rubber and SBR.
또한, 본 발명의 배합조성물에는 금속성광물분말이 상기 합성고무 40 내지 43중량부를 기준으로 2 내지 4중량부 포함되는데, 금속성광물분말은 해중림조성부재에 착생된 해조류의 성장을 촉진하기 위한 것으로, 함량이 2중량부보다 적게 되면, 해조류의 성장을 촉진시키는 효과가 저하되고 함량이 4중량부 보다 많아지면 해중림조성부재를 성형하는데 어려움이 있다. 여기서, 금속성광물분말은 특히 황산철이 적합하다.In addition, the compound composition of the present invention contains 2 to 4 parts by weight of the metallic mineral powder based on 40 to 43 parts by weight of the synthetic rubber, the metallic mineral powder is to promote the growth of algae engrafted in the deforestation composition, the content When the amount is less than 2 parts by weight, the effect of promoting the growth of seaweeds is lowered, and when the content is more than 4 parts by weight, it is difficult to form the marine forest composition member. The metallic mineral powder is particularly suitable for iron sulfate.
또한, 본 발명의 배합조성물은 암석성광물분말을 상기 합성고무 40 내지 43중량부를 기준으로 1 내지 2중량부 포함하는데, 암석성광물분말 또한 해중림조성부재에 착생된 해조류의 성장을 촉진하기 위한 것으로 그 함량비의 결정조건 또한 상술한 금속성광물분말의 함량비결정조건과 같다. 이 때 암석성광물분말은 특히 견운도 도는 규조토가 바람직하다.In addition, the blend composition of the present invention includes rock mineral mineral powder 1 to 2 parts by weight based on 40 to 43 parts by weight of the synthetic rubber, the rock mineral powder is also to promote the growth of seaweeds engrafted in the deforestation member The condition for determining the content ratio is also the same as the condition for determining the content of the metallic mineral powder described above. In this case, the rock mineral powder is particularly preferably fastness or diatomaceous earth.
또한, 본 발명의 배합조성물은 기 합성고무 40 내지 43중량부를 기준으로 카본블랙이 15 내지 20중량부 더 포함될 수 있는데, 카본블랙은 해중림조성부재의 색깔을 결정하고, 해중림조성부재의 성형에 관여한다. 즉 카본블랙의 함량이 20중량부보다 많이 추가되면 경도가 높아져 해중림조성부재의 성형에 어려움이 있으며 15 중량부보다 적은 경우에는 착색효과가 저하된다.In addition, the blend composition of the present invention may further include 15 to 20 parts by weight of carbon black based on 40 to 43 parts by weight of the synthetic rubber, the carbon black determines the color of the deforestation member, involved in the formation of the deforestation member do. In other words, when the carbon black content is added more than 20 parts by weight, the hardness is high, so that it is difficult to form the deforestation member, and when less than 15 parts by weight, the coloring effect is lowered.
또한, 본 발명의 배합조성물은 상기 합성고무 40 내지 43중량부를 기준으로 기준으로 무기 충진제 6 내지 7중량부, 파라핀오일 7 내지 10중량부, 아연화(ZnO) 3 내지 4 중량부, 활성제 0.5 내지 2중량부를 포함한다. 이 때 상기 구성성분들은 해중림조성부재의 물성을 보다 향상시키기 위해 포함되는 것으로 여기서 상술한 구성성분들 및 그 함량비를 벗어나면 보다 향상된 해중림조성부재의 최적물성을 얻을 수 없다.In addition, the blend composition of the present invention is based on 40 to 43 parts by weight of the synthetic rubber 6 to 7 parts by weight of inorganic filler, 7 to 10 parts by weight of paraffin oil, 3 to 4 parts by weight of zinc (ZnO), 0.5 to 2 active agents It includes parts by weight. At this time, the components are included in order to further improve the physical properties of the deforestation member, and the optimum properties of the improved deforestation member can not be obtained outside the above-described components and the content ratio.
먼저, 무기 충진제로는 탄산칼슘이 사용되는 것이 바람직한데, 해중림 조성부재의 내인장성에 영향을 주는 것으로 그 함량을 초과하면 중량이 무거워지고 물성이 떨어지며, 그 함량보다 적게 되면 원하는 물성을 얻을 수 없다. First of all, calcium carbonate is preferably used as the inorganic filler, which affects the toughness of the composition of the marine deforestation. If the content exceeds the weight, the weight becomes heavy and the physical properties fall, and if the content is less than that, the desired properties cannot be obtained. .
파라핀오일은 해중림 조성부재의 경도 및 광택을 조절하기 위한 것으로, 10중량부보다 다량 포함되면 경도가 떨어지고, 8중량부보다 소량 포함되면 원하는 경도 및 광택을 얻을 수 없다.Paraffin oil is intended to control the hardness and gloss of the desalination composition, the hardness is lowered when included in a large amount than 10 parts by weight, and when included in a small amount than 8 parts by weight can not obtain the desired hardness and gloss.
아연화(ZnO) 및 활성제는 상기 배합조성물의 배합 및 해중림조성부재의 성형을 원활하게 하기 위한 것으로 상술한 범위 내에서 다른 구성성분과 조화를 이루어 원하는 물성을 얻을 수 있다. 이 때 활성제로는 칼슘 스테아린산(Calcium Stearic acid)이 사용될 수 있다.Zincation (ZnO) and the active agent is to facilitate the blending of the formulation composition and the molding of the deforestation composition member can be achieved in harmony with other components within the above-mentioned range to obtain the desired physical properties. At this time, as the active agent, calcium stearic acid may be used.
또한, 본 발명의 배합조성물은 발포제 11 내지 13중량부, 가교조제 1 내지 2 중량부, 및 첨가제 5 내지 10중량부를 하나 이상 더 포함한다. 이 때 상기 구성성분들은 해중림 조성부재의 물성을 보다 향상시키기 위해 하나 이상 포함되는 것으 로 보다 바람직하게는 상술한 구성성분들이 모두 포함되는 것인데, 여기서 상술한 구성성분들 및 그 함량비를 벗어나면 보다 향상된 해중림 조성부재의 최적물성을 얻을 수 없다.In addition, the blend composition of the present invention further comprises one or more of 11 to 13 parts by weight of the blowing agent, 1 to 2 parts by weight of the crosslinking aid, and 5 to 10 parts by weight of the additive. At this time, the components are included in one or more to improve the physical properties of the deforestation composition member, more preferably all of the above-mentioned components are included, where the components and the content ratio outside the above It is not possible to obtain the optimum properties of the improved deforestation member.
발포제는 공지된 다수의 발포제가 사용될 수 있으나 NaHCO3, (NH4)2CO3, NH4HCO3, NH4NO2, CaN6 중에서 선택되는 하나 이상이 사용되는 것이 바람직한데 발포제는 인장강도 등을 조절하기 위해 사용된다. 발포제는 상술한 범위 밖의 함량이 포함되면 다른 구성성분과 조화되지 못하고 목적하는 해중림 조성부재의 최적물성을 얻을 수 없다.Blowing agent may be used a number of known blowing agents, but at least one selected from NaHCO 3 , (NH 4 ) 2 CO 3 , NH 4 HCO 3 , NH 4 NO 2 , CaN 6 is preferably used. It is used to adjust. If the foaming agent is included in the content outside the above-mentioned range, it is not compatible with other components and the optimum properties of the desired deforestation composition member cannot be obtained.
가교조제는 해중림 조성부재 성형시 반응을 촉진하고 상기 배합조성물의 주된 성분인 합성고무의 경화를 원활하게 하기 위한 것으로 상술한 범위 내에서 다른 구성성분과 조화를 이루어 원하는 물성을 얻을 수 있다. 이 때 가교조제로는 공지된 다수의 가교조제가 사용될 수 있으며, 트리메틸올프로판 트리메타크릴레이트가 사용될 수 있다.The crosslinking aid is for promoting the reaction during molding of the deforestation composition member and for smoothing the curing of the synthetic rubber which is the main component of the blended composition. The crosslinking assistant may be combined with other components within the above-described range to obtain desired physical properties. In this case, a number of known crosslinking aids may be used as the crosslinking aid, and trimethylolpropane trimethacrylate may be used.
첨가제는 상술한 배합조성물의 구성요소의 특성을 강화시키거나 조화시키고, 경우에 따라서는 착색효과를 얻기 위해 부가적으로 더 포함되는 것으로 유황, 썬녹, 촉진제, 광택제, TT(Tetramethylthiuram), TRA(dipentamethylene thiuram tetra sulfide), 노방D(phenyl - B - naphthyl amine), 및 RD노방(polymer of 2,2,4-trimethyl-1.2-hydro quinoline) 중 하나 이상일 수 있다.Additives are additionally included to enhance or harmonize the properties of the components of the above-mentioned blended composition, and in some cases, to obtain a coloring effect, such as sulfur, sun rust, accelerators, polishes, tetramethylthiuram (TT), and dipentamethylene (TRA). thiuram tetra sulfide), phenyl- B -naphthyl amine, and RD-vinyl (polymer of 2,2,4-trimethyl-1.2-hydro quinoline).
실시예1Example 1
EPDM 42중량부를 기준으로, 황산철 3.8중량부, 견운모 1.2중량부, 탄산칼슘 6.8중량부, 카본블랙 16중량부, 파라핀오일 7.4중량부, 아연화 3.3중량부 및 칼슘스테아린산 1.7중량부를 포함하는 배합조성물1을 성형하여 다시마 모양의 해중림조성부재1을 얻었다. 이 때 성형형태와 색은 다양하게 조합할 수 있다.Compound composition comprising 3.8 parts by weight of iron sulfate, 1.2 parts by weight of mica, 1.2 parts by weight of calcium carbonate, 16 parts by weight of carbon black, 7.4 parts by weight of paraffin oil, 3.3 parts by weight of zinc, and 1.7 parts by weight of calcium stearic acid, based on 42 parts by weight of EPDM. 1 was molded to obtain a kelp-shaped seaweed forest composition member 1. At this time, the molding form and color can be combined in various ways.
실시예2Example 2
트리메틸프로판 트리메타크릴레이트 1.4중량부, NaHCO3 11.4중량부 및 유황 3중량부, 썬녹 2중량부, 크린옥신 0.2중량부를 더 포함하는 것을 제외하면 실시예1과 동일한 구성을 갖는 배합조성물2를 성형하여 다시마 모양의 해중림조성부재2를 얻었다. A compound composition 2 having the same constitution as in Example 1 was formed except that 1.4 parts by weight of trimethylpropane trimethacrylate, 11.4 parts by weight of NaHCO 3 and 3 parts by weight of sulfur, 2 parts by weight of rust green, and 0.2 parts by weight of kryoxine were formed. To obtain a seaweed-forming member 2 in the form of a sea tangle.
실험예Experimental Example
실시예1 및 2에서 얻어진 해중림 조성부재 1 및 2의 해조류 착생 및 성장효과를 조사하기 위하여 동일조건을 가진 각각의 실내 수조 1 내지 15에 해중림조성부재1, 2, 자연석블록 및 콘크리트블록을 넣고 단년생 해조류인 다시마와 다년생 해조류인 감태, 대황의 유주자를 방출시켜 상기 해중림 조성부재1, 2, 자연석블록 및 콘크리트블록에 상기 유주자를 착생시킨 후 착생된 유주자가 어린 해조로 성장하는 것을 관찰하는 실험을 수행하였다. 단위면적당 어린 해조류의 밀집도(착생정도) 및 성장도를 평가한 후 수조 1 내지 15의 평가결과를 평균하여 표1에 나타내었다. 여기서 착생정도 및 성장정도의 평가는 매우 우수 : 5, 우수 : 4, 중간 : 3, 저조 : 2, 매우 저조 :1 로 시각적으로 비교 평가한 결과이다.In order to investigate the seaweed growth and growth effects of the marine forest composition members 1 and 2 obtained in Examples 1 and 2, the marine forest composition members 1, 2, natural stone blocks and concrete blocks were placed in each indoor tank 1 to 15 having the same conditions. An experiment was performed to observe the growth of younger algae after releasing juveniles of seaweeds, perennial seaweeds, persimmons, and rhubarb, and engrafting the jujube to the marine composition members 1, 2, natural stone blocks and concrete blocks. Was performed. After evaluating the density (growth) and growth of young algae per unit area, the evaluation results of the tanks 1 to 15 are averaged and are shown in Table 1. Here, the evaluation of engraftment and growth rate is the result of visual comparison of very good: 5, excellent: 4, medium: 3, low: 2, very low: 1.
상기 표1로부터, 본 발명에 따른 해조류 조성부재1 및 2는 일반적으로 사용되고 있는 다른 기질에 비해 유주자의 자연착상율이 매우 높을 뿐만 아니라, 그 해조류의 성장효율 또한 우수한 것을 알 수 있어, 본 발명의 배합조성물이 해조류 부착기질로서 매우 훌륭한 재료임을 알 수 있다. Table 1 shows that the algae composition members 1 and 2 according to the present invention have not only a very high natural implantation rate of the jujube compared to other substrates that are generally used, but also excellent growth efficiency of the algae. It can be seen that the composition is a very good material as an algae attachment substrate.
아울러 본 발명의 바람직한 실시예들은 예시의 목적을 위해 개시된 것이므로 상술한 특정의 실시예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형실시가 가능한 것은 물론이고, 그와 같은 변경은 청구범위 기재의 범위 내에 있게 된다.In addition, the preferred embodiments of the present invention are not limited to the specific embodiments described above because it is disclosed for the purpose of illustration, without departing from the gist of the present invention claimed in the claims, the common knowledge in the technical field to which the invention belongs. Of course, any person having a variety of modifications can be made, and such changes are within the scope of the claims.
이상에서 살펴본 바와 같이 본 발명은 다음과 같은 현저한 효과를 가진다. As described above, the present invention has the following remarkable effects.
본 발명에 의한 배합조성물로 제조된 해중림 조성부재에는 해역에서 자연 발생된 해조류의 유주자 또는 인공 종묘된 어린 해조류가 잘 착생할 수 있다. The seaweed forest composition member prepared by the composition according to the present invention can be well grown in the seaweeds or artificial seedlings of seaweeds naturally generated in the sea area.
또한, 본 발명에 의한 배합조성물로 제조된 해중림 조성부재는 착생된 해조류의 유주자 또는 인공종묘된 어린 해조류가 잘 성장할 수 있도록 해조류 성장에 필요한 성분을 제공할 수 있다. In addition, the seaweed forest composition member prepared by the composition according to the present invention can provide the ingredients necessary for the growth of algae so that the live algae or the seedlings of artificial seaweed grow well.
따라서, 본 발명에 의한 배합조성물로 제조된 해중림 조성부재는 백화현상이 발생된 어장이나 해조류가 고사 혹은 소실되어 없어진 어장에 시설하여 자연적으로 해조류를 착생 및 생장시키는 것을 촉진할 뿐만 아니라, 인위적으로 해조류를 이식하여 뿌리의 활착을 용이하게 할 수 있어, 해중림 조성 사업을 성공적으로 수행하는데 크게 기여할 수 있다.Therefore, the marine forest composition member prepared by the compound composition according to the present invention not only promotes the natural growth and growth of seaweeds by planting in the fishery where the whitening phenomenon or the algae disappeared due to the death or disappearance of the seaweeds. It is possible to facilitate root adhesion by transplanting, which can greatly contribute to the successful implementation of the deforestation project.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070008074A KR100805742B1 (en) | 2007-01-25 | 2007-01-25 | Composition for producing seaweed forest attachment means and the attachment means produced thereby |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070008074A KR100805742B1 (en) | 2007-01-25 | 2007-01-25 | Composition for producing seaweed forest attachment means and the attachment means produced thereby |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR100805742B1 true KR100805742B1 (en) | 2008-02-21 |
Family
ID=39382785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020070008074A KR100805742B1 (en) | 2007-01-25 | 2007-01-25 | Composition for producing seaweed forest attachment means and the attachment means produced thereby |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100805742B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101425979B1 (en) | 2012-05-02 | 2014-08-06 | 에스엠텍 주식회사 | A composition for inducing cohesion of seaweeds |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100335013B1 (en) | 1999-12-28 | 2002-05-03 | 김진갑 | Composition for Producing Bio-ceramic Fishing Structure |
| KR20040033533A (en) * | 2002-10-15 | 2004-04-28 | 주식회사 포스코 | Coating composition for the promotion of algae propagation |
| KR20040099727A (en) * | 2003-05-20 | 2004-12-02 | 남병현 | Composite of artificial fish-shelter |
| JP2005160414A (en) | 2003-12-04 | 2005-06-23 | Kagawa Industry Support Foundation | Artificial reef for growth of alga produced at low temperature and method for producing the same |
-
2007
- 2007-01-25 KR KR1020070008074A patent/KR100805742B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100335013B1 (en) | 1999-12-28 | 2002-05-03 | 김진갑 | Composition for Producing Bio-ceramic Fishing Structure |
| KR20040033533A (en) * | 2002-10-15 | 2004-04-28 | 주식회사 포스코 | Coating composition for the promotion of algae propagation |
| KR20040099727A (en) * | 2003-05-20 | 2004-12-02 | 남병현 | Composite of artificial fish-shelter |
| JP2005160414A (en) | 2003-12-04 | 2005-06-23 | Kagawa Industry Support Foundation | Artificial reef for growth of alga produced at low temperature and method for producing the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101425979B1 (en) | 2012-05-02 | 2014-08-06 | 에스엠텍 주식회사 | A composition for inducing cohesion of seaweeds |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Barbera et al. | Conservation and management of northeast Atlantic and Mediterranean maerl beds | |
| KR100994533B1 (en) | Forming method of eco-friendly sea forest using natural stone | |
| CN101671079B (en) | Method of constructing ntaxial system ecology for fishes, grasses and shellfishes in fresh-water substance | |
| Piller et al. | Rhodolith formation induced by reef erosion in the Red Sea, Egypt | |
| KR100835369B1 (en) | Seaweed forest attachment means | |
| CN110089410A (en) | A kind of submerged plant planting blanket and preparation method thereof | |
| KR20130104609A (en) | Algae attachment block and method for making seaweed forest for recovery of whitening event | |
| KR100805742B1 (en) | Composition for producing seaweed forest attachment means and the attachment means produced thereby | |
| ATE535587T1 (en) | METHOD FOR STABILIZING AN ENGINE COOLANT CONCENTRATE AND PREVENTING SALT FORMATION WITH HARD WATER DURING DILUTION | |
| KR100831743B1 (en) | Seaweed forest attachment means complex | |
| KR102241454B1 (en) | Environmentally friendly algae transplanting device and method the same | |
| KR100858732B1 (en) | Seaweed forest attachment means complex | |
| JP2008061568A (en) | Biodegradable eelgrass nursery bed sheet and method of restoration, reclamation and maintenance of eelgrass bed | |
| Kim et al. | Studies on technology for seaweed forest construction and transplanted Ecklonia cava growth for an artificial seaweed reef | |
| Sugianto et al. | Reef development on artificial patch reefs in shallow water of Panjang Island, Central Java | |
| CN215836569U (en) | Tree-shaped fish reef device with planting bed | |
| KR200448974Y1 (en) | A Nutrition Block Fixing Unit of transplanted of Seaweed Spore | |
| Zevenboom | Assessment of eutrophication and its effects in marine waters | |
| KR100622634B1 (en) | Submarine forest | |
| KR101821775B1 (en) | Artifical fishing reef with multi-function | |
| KR101933958B1 (en) | Coastal complex organism habitats, and bioremediation method thereof | |
| KR100903204B1 (en) | Permeability tetrapod, harbor facility for the manufacturing method | |
| KR100841394B1 (en) | Hexagonal aritificial reefs for the construction of sea forest | |
| KR101687764B1 (en) | Insertion facilitating composite of marine structure containing inositol | |
| KR20150117465A (en) | Reef block using ferronickel slag |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20130214 Year of fee payment: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20140214 Year of fee payment: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20150306 Year of fee payment: 8 |
|
| FPAY | Annual fee payment |
Payment date: 20161025 Year of fee payment: 9 |
|
| R401 | Registration of restoration | ||
| FPAY | Annual fee payment |
Payment date: 20170303 Year of fee payment: 10 |
|
| FPAY | Annual fee payment |
Payment date: 20180212 Year of fee payment: 11 |
|
| FPAY | Annual fee payment |
Payment date: 20190214 Year of fee payment: 12 |