KR100799961B1 - Carbonization-steam of garlic aging fluid and composition and process of manufacturing - Google Patents

Abstract

The present invention is to remove the odor component by using a garlic stand carbonized steam extract prepared by separating the garlic stand carbon and the garlic stand carbonized solids generated by heating the garlic stand directly or indirectly and then cooling and condensing the garlic stand carbonized steam The present invention relates to a liquid natural biodeodorant composition which can be effectively and continuously removed and a method for preparing the same.

Natural liquid bio, deodorant composition, garlic stand, carbonized steam, carbonized solid

Description

Method of manufacturing liquid natural biodeodorant containing garlic extract carbonized steam extract {CARBONIZATION-STEAM OF GARLIC AGING FLUID AND COMPOSITION AND PROCESS OF MANUFACTURING}

1 is a front view of a manufacturing apparatus for producing a composition of the present invention

2 is a plan view of the heating furnace shown in FIG.

3 is a cover of the furnace

4 is an opening and closing door of the heating part

5 is a wire mesh for the input material

* Explanation of symbols for the main parts of the drawings

1: pyrolysis furnace 2: piping

3: high pressure jet pump 4: high pressure injector

5: cooler 6: collector

7: Aging tank 8: Exhaust vent

9: pump 10: heater

11: steamer 12: cover

13: Water heating piping 14: Opening door

15: Drain valve 16: Fixed hanger

17: grid 18: lower support plate

19: Feldspar

The present invention relates to a liquid natural biodeodorant composition and a method for manufacturing the same, and more specifically, after separating the garlic bar carbonized steam and garlic bar carbonized solids generated by heating the garlic bar directly or indirectly, the garlic bar carbonized steam is cooled. The present invention relates to a liquid natural biodeodorant composition and a method for preparing the same, which can effectively and continuously remove malodorous components by using a garlic-barb carbonized steam extract prepared by condensation and extraction.

In general, a lot of odor or odor is mainly used aroma, but this is mainly due to the masking action and neutral deodorant due to the stronger aroma effect of the fragrance used than to remove the source of odor or odor. . In addition, the chemical deodorant may be harmful to the human body, livestock and plants, and in the case of a natural deodorant of a single component has a disadvantage that the deodorizing effect is not persistent.

The problem of the manufacturing process of liquid natural biodeodorant presented in Korean patent applications 10-2003-0007445 and 10-2004-0081721 is that it is good to extract the extract so that tar is mixed as little as possible in the process of producing bamboo vinegar liquor and wood vinegar liquor. However, the conventional process has a problem that the tar is excessively contaminated from the inside of the heating furnace to the pipeline and the cooling equipment after extracting the extract once or twice. In the conventional liquid natural biodeodorant manufacturing process, after adding a new green plant, excessively attached and accumulated tar causes enormous pollution to the extract extracted at a temperature from about 120 ° C to 250 ° C. There was a problem that can not be obtained due to the heavy pollution of the purpose to extract the special purpose at 200 ℃. Conventional liquid natural biodeodorant manufacturing process has to produce charcoal at a temperature of 250 ℃ or more, and the wood vinegar and bamboo vinegar produced in this way had a problem that makes people feel a sense of rejection when aged for a certain period. In addition, the conventional liquid natural biodeodorant manufacturing process has a problem that it takes 1 to 2 days to cool the entire electric furnace after producing a charcoal by heating more than 600 ℃.

The present invention is to solve the above problems as a natural plant produced by separating the garlic stand carbonized steam and the garlic stand carbonized solids generated by heating the garlic stand directly or indirectly after cooling and condensing the garlic stand carbonized steam The purpose of the present invention is to prepare a liquid natural biodeodorant composition capable of effectively and continuously removing malodorous components by using a garlic bark carbonized steam extract, which is a dry liquor extract.

The present invention comprises a garlic bar carbonized steam extract extracted by heating the garlic bar directly or indirectly to separate the garlic bar carbonized steam and the garlic bar carbonized solids generated at 100 ~ 400 ℃ and cooling and condensing the garlic bar carbonized steam It relates to a liquid natural biodeodorant composition characterized in that.

In the liquid natural biodeodorant composition of the present invention, the garlic bark steam extract is selected from bamboo, oak, juniper, cypress, ginkgo, acacia, pine, pine, pine and rice wormwood in 50-99% by weight of garlic. Characterized in that the mixture containing 1 to 50% by weight of a single green plant is directly or indirectly heated to contain a carbonized steam extract extracted by cooling and condensing the carbonized steam generated at 100 to 400 ℃. In addition, in the liquid natural biodeodorant composition of the present invention, the garlic stand carbonized solid is characterized in that separated by a soil improver.

In another aspect, the present invention comprises the step of inserting the garlic stand in the electric furnace to heat to 100 ~ 400 ℃; Separating the garlic stand carbonized garlic and the garlic stand carbonized solid; Condensing the garlic bar carbonization in the cooler; Capturing and maturing the garlic barb carbon condensate; It relates to a method for producing a liquid natural biodeodorant composition characterized in that the step of filtering and purifying the garlic carbonate carbon maturation.

In the preparation of the liquid natural biodeodorant composition of the present invention, when the garlic stand is heated directly or indirectly, the generation of carbonized steam is very low at 100 ° C. or lower, and a carbonized solid is produced at 400 ° C. or higher. If you use more than 50% by weight of green plants, deodorant performance is weakened, and less than 1% by weight is not the same as using garlic stand alone. Green plants used in the preparation of the liquid natural biodeodorant composition of the present invention is a green plant consisting of at least one selected from bamboo, oak, juniper, cypress, ginkgo, acacia, pine, pine, rice and wormwood Can be used.

Liquid natural biodeodorant composition of the present invention is a step of inserting the garlic stand in an electric furnace to heat to 100 ~ 400 ℃; Separating the garlic stand carbonized garlic and the garlic stand carbonized solid; Condensing the garlic bar carbonization in the cooler; Capturing and maturing the garlic barb carbon condensate; It is prepared by the step of filtering and purifying the garlic barb carbonized mature. The furnace 1 used in the present invention as shown in Figure 1 is made of iron and the cover 12 is located on the upper portion of the electric furnace 1, the heat insulating material 16 is covered in the center of the cover 12 to keep the top warm . In order to raise the temperature inside the electric furnace 1, the electric heater 10 is located at the lower side and the side, and the carbonized steam generated by the heating moves along the pipe 2 and is cooled and condensed in the cooler 5 to collect the collector ( After moving to 6) is aged in a aging tank (7) for a certain period of time passes through the filter (19) is produced garlic carbonate carbon maturing liquid.

In the present invention, the garlic bar carbonized solid is separated into a soil improver and is produced as charcoal. The garlic bar carbonized solid becomes charcoal when it is elevated to a high temperature of 300 ° C. after separating the garlic barb steam aging liquid. Open it and collect the charcoal.

Unlike other green plants, the garlic stand is a hollow structure like a bamboo, not a hollow structure, so it is difficult to achieve heat transfer evenly. Therefore, the garlic stand is suitable for radiant heat between multiple layers of grids (17) and the grids. Preferably, the spacing holding rods 19 are configured in duplicate for each grid in the circumferential direction so as to pass. When preparing the garlic charcoal carbon charcoal, it is preferable to collect the char by opening the lower base plate 18 of the marinated stand and unwinding the fixed hanger 16.

The outer wall of the electric furnace (1) is opened and closed insulated door 14 is located on all sides, and after the final work is opened, the heat insulating door 14 is opened, while cooling the internal temperature of the electric furnace quickly while cooling Re-insertion of is possible. However, if the temperature rises above 400 ℃, tar is generated, and the pipe and the cooler are cleaned using the waste heat after the work, and the pipe 13 is laid on the lower surface of the cover 12 and the upper steel plate, and the water is circulated by the pump 9. Then, the water heated by the waste heat flows down the inclined pipe 2 to wash away the tar inside. In this case, the tar of each part is wash | cleaned by the pressure by the high pressure injection machine 4 in the middle, and a clean piping can be managed. In addition, after the upper cover 12 is opened, after collecting charcoal, the steam generator 11 cleans the interior of the electric furnace and maintains a clean state. When the steam cleaning is completed, the pump 9 operates to operate the interior of the electric furnace 1. The residues of the oil are washed off and residues such as tar are discharged through the discharge valve 15.

The present invention can produce garlic barb carbon aging liquid and garlic barb carbonized charcoal in one process and to produce a high-purity product containing no tar and impurities in a continuous process of putting the garlic bar again production operation After the operation, the pipe can be cleaned using waste heat, and after the operation, the external insulation of the electric furnace can be opened.

The present invention is to prepare the garlic stand carbonized steam aging liquid extracted from the internal temperature of about 130 ℃ without the process of tar contamination of the entire process without separating the process, and to prepare the garlic stand carbon charcoal at the same time deodorant, water purification agent and soil improver Can be used as

<Example 1> Deodorization test for garlic extract carbonized steam

The tester used Model 801 (Gastec co, Japan) and the experimental conditions are as follows.

1) Room temperature: 21 ℃

2) Relative Humidity: 52.0%

3) Size of container (container for deodorization test): 40cm × 40cm × 60cm

4) Sample amount: 20ml of sample

Firstly, the odor source is injected into the deodorization test apparatus and measured by gastec so that the odor inside the apparatus is 50ppm for methyl mercaptan, 60ppm for hydrogen sulfide, ammonia and trimethylamine. A sample of 150 times diluted deodorant stock is sprayed through an injector into each device adjusted to the initial concentration. 30 minutes, 1 hour, 2 hours, 4 hours, 6 hours after the injection, each concentration is measured by gastec. The results are shown in Table 1.

<Deodorization ability test result of natural bio deodorant> Examination Elapsed time (hr) Analysis result (ppm) ammonia Hydrogen sulfide Trimethylamine Methyl mercaptan (NH ₃ ) (H ₂ S) ((CH ₃ ) ₃ NH ₂ ) (CH ₃ SH) Deodorization test 0 60 60 60 60 0.5 22 41 20 40 One 20 32 15 35 2 15 22 10 21 4 10 15 5 13 6 5 5 2 5

As shown in Table 1, the results of the deodorizing ability test of the natural biodeodorant of the present invention showed that the deodorizing ability for the acidic odorous hydrogen sulfide and methyl mercaptan showed 95% removal rate compared to the initial concentration after 6 hours, respectively, and the basic odorous ammonia After 6 hours, the deodorizing power of and trimethylamine showed excellent removal rate of 97% compared to the initial concentration.

<Example 2> Deodorization test for the garlic carbonized steam extract and bamboo carbonized steam extract

Deodorization test was carried out in the same manner as in Example 1 for a mixture of 50% by weight of garlic barley carbonized extract and 50% by weight of bamboo carbonized extract. As a result of the deodorizing ability test of the natural biodeodorant of the present invention, the deodorizing ability for the acidic odorous hydrogen sulfide and methyl mercaptan showed 90% removal rate after 6 hours, respectively, and the deodorizing ability for the basic odorous ammonia and trimethylamine. After 6 hours, the removal rate was 90% of the initial concentration.

<Example 3> Deodorization test for the garlic carbonized steam extract and bamboo carbonized steam extract

The deodorization test was carried out in the same manner as in Example 1 for the mixture of 75% by weight garlic garlic extract and 25% by weight bamboo carbide extract. As a result of the deodorizing ability test of the natural biodeodorant of the present invention, the deodorizing ability for the acidic odorous hydrogen sulfide and methyl mercaptan showed 93% removal rate after 6 hours, respectively, and the deodorizing ability for the basic odorous ammonia and trimethylamine. After 6 hours, the removal rate was 95% of the initial concentration.

The present invention separates the garlic stand carbon and the garlic stand carbonized solids generated by heating the garlic stand directly or indirectly, and then extract the garlic stand carbonized steam, which is a natural plant dry distillate extract prepared by cooling and condensing the garlic stand carbonized steam. It is an extremely useful invention for the environmental and chemical industries related to the manufacture of the deodorant since the odor component can be effectively and continuously removed.

Claims (4)

In the method for producing a liquid natural bio-deodorant containing garlic components, the production method is the garlic stand carbonization and the garlic stand carbonized solids generated at 100 ~ 400 ℃ by heating the garlic stand directly or indirectly after the garlic A method of producing a liquid natural biodeodorant containing garlic stand carbonaceous extract, characterized in that to prepare a deodorant by preparing a garlic stand carbonized extract extracted by cooling and condensing large carbonized steam. According to claim 1, wherein the garlic barb carbonized extract is made of any one selected from bamboo, oak, juniper, cypress, ginkgo, acacia, pine, pine, rice and wormwood in 50 ~ 99% by weight of garlic A mixture of 1 to 50% by weight of the plant is directly or indirectly heated to produce a carbonized steam extract extracted by cooling and condensing the carbonized steam generated at 100 to 400 ° C. to prepare a deodorant. Method for producing a liquid natural biodeodorant containing extracts. delete The method of claim 1, wherein the method comprises the steps of inserting a garlic stand into an electric furnace and heating it to 100 to 400 ° C; Separating the garlic stand carbonized garlic and the garlic stand carbonized solid; Condensing the garlic bar carbonization in the cooler; Capturing and maturing the garlic barb carbon condensate; And a step of filtering and purifying the garlic barb carbonized matured product.

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