KR100788258B1 - Thin-Film Type Direct-Adhering PDP Filter and Picture Display Apparatus using thereof - Google Patents
Thin-Film Type Direct-Adhering PDP Filter and Picture Display Apparatus using thereof Download PDFInfo
- Publication number
- KR100788258B1 KR100788258B1 KR1020050046985A KR20050046985A KR100788258B1 KR 100788258 B1 KR100788258 B1 KR 100788258B1 KR 1020050046985 A KR1020050046985 A KR 1020050046985A KR 20050046985 A KR20050046985 A KR 20050046985A KR 100788258 B1 KR100788258 B1 KR 100788258B1
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- KR
- South Korea
- Prior art keywords
- filter
- layer
- weight
- dyes
- hydroxy
- Prior art date
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- 239000010409 thin film Substances 0.000 title claims abstract description 24
- 239000010410 layer Substances 0.000 claims abstract description 71
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- 229920005989 resin Polymers 0.000 claims abstract description 39
- 239000011347 resin Substances 0.000 claims abstract description 39
- 230000003287 optical effect Effects 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 239000002346 layers by function Substances 0.000 claims abstract description 20
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- 229910052754 neon Inorganic materials 0.000 claims description 21
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 17
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 13
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- 239000012964 benzotriazole Substances 0.000 claims description 4
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- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
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- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 claims description 2
- VNFXPOAMRORRJJ-UHFFFAOYSA-N (4-octylphenyl) 2-hydroxybenzoate Chemical compound C1=CC(CCCCCCCC)=CC=C1OC(=O)C1=CC=CC=C1O VNFXPOAMRORRJJ-UHFFFAOYSA-N 0.000 claims description 2
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 claims description 2
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 claims description 2
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- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 claims description 2
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 claims description 2
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- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 2
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- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 claims description 2
- CSUUDNFYSFENAE-UHFFFAOYSA-N (2-methoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC=C1C(=O)C1=CC=CC=C1 CSUUDNFYSFENAE-UHFFFAOYSA-N 0.000 claims 1
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- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims 1
- OJGHSVWJYBAERP-UHFFFAOYSA-N [3-(benzotriazol-2-yl)-4-hydroxyphenyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 OJGHSVWJYBAERP-UHFFFAOYSA-N 0.000 claims 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims 1
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/34—Vessels, containers or parts thereof, e.g. substrates
- H01J11/44—Optical arrangements or shielding arrangements, e.g. filters, black matrices, light reflecting means or electromagnetic shielding means
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/20—Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel
- H01J9/205—Applying optical coatings or shielding coatings to the vessel of flat panel displays, e.g. applying filter layers, electromagnetic interference shielding layers, anti-reflection coatings or anti-glare coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/34—Vessels, containers or parts thereof, e.g. substrates
- H01J2211/44—Optical arrangements or shielding arrangements, e.g. filters or lenses
- H01J2211/446—Electromagnetic shielding means; Antistatic means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/34—Vessels, containers or parts thereof, e.g. substrates
- H01J2211/44—Optical arrangements or shielding arrangements, e.g. filters or lenses
- H01J2211/448—Near infrared shielding means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2217/00—Gas-filled discharge tubes
- H01J2217/38—Cold-cathode tubes
- H01J2217/49—Display panels, e.g. not making use of alternating current
- H01J2217/492—Details
- H01J2217/49285—Associated optical means
- H01J2217/49292—Filters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2329/00—Electron emission display panels, e.g. field emission display panels
- H01J2329/86—Vessels
- H01J2329/868—Passive shielding means of vessels
- H01J2329/869—Electromagnetic shielding
Abstract
본 발명은 전자파차폐필터 상면에 반사방지층, 저반사층 등과 같은 광학기능층을 코팅하여 형성하고, 근적외선 차폐층을 전자파차폐필터 하면에 코팅하여 형성한 초박막의 직부착 피디피필터 및 이를 이용한 화상표시장치에 관한 것이다. 본 발명은 전자파차폐필터의 상면에 광학기능층이 코팅되며, 상기 전자파차폐필터의 하면에 근적외선 차폐층이 코팅되고, 상기 근적외선 차폐층을 이루는 근적외선차폐 조성물은 자외선 경화성수지, 근적외선차폐 염료, 자와선 흡수제, 경화제 및 레벨링제를 포함하여 이루어지고, 상기 근적외선차폐 조성물 100중량%에 있어서, a) 상기 근적외선차폐 염료는 0.1중량% 내지 15중량%; b) 상기 자외선 흡수제는 0.1중량% 내지 15중량%; c) 상기 경화제는 0.1중량% 내지 15중량%; 및 d) 상기 레벨링제는 0.1중량% 내지 3중량%인 박막형 피디피필터를 제공한다.The present invention is formed by coating an optical function layer such as an antireflection layer, a low reflection layer, etc. on the upper surface of the electromagnetic shielding filter, and coating a near-infrared shielding layer on the lower surface of the electromagnetic shielding filter to form an ultra thin film directly attached PD filter and an image display apparatus using the same. It is about. The present invention is coated with an optical functional layer on the upper surface of the electromagnetic shielding filter, the near-infrared shielding layer is coated on the lower surface of the electromagnetic shielding filter, the near-infrared shielding composition constituting the near-infrared shielding layer is ultraviolet curable resin, near-infrared shielding dye, Comprising an absorbent, a curing agent and a leveling agent, 100% by weight of the near-infrared shield composition, a) the near-infrared shielding dye is 0.1% to 15% by weight; b) 0.1 wt% to 15 wt% of the ultraviolet absorbent; c) 0.1 to 15 weight percent of said curing agent; And d) the leveling agent provides a thin film PD filter of 0.1% by weight to 3% by weight.
박막, PDP, 염료, 근적외선, 반사방지 Thin film, PDP, dye, near infrared ray, antireflection
Description
도 1은 종래 PDP필터의 구조도,1 is a structural diagram of a conventional PDP filter;
도 2는 본 발명에 PDP필터의 구조도를 나타낸 것이다.2 shows a structural diagram of a PDP filter according to the present invention.
<도면 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
100 : 플라즈마 디스플레이 패널100: plasma display panel
200 : 전자파차폐필터200: electromagnetic shielding filter
300 : 광학기능층300: optical function layer
400 : 점착층400: adhesive layer
500 : 근적외선 차폐층500: near infrared shielding layer
본 발명은 박막형 직부착 피디피필터 및 이를 이용한 화상표시장치에 관한 것으로서, 보다 상세하게는 전자파차폐필터 상면에 반사방지층, 저반사층 등과 같은 광학기능층을 코팅하여 형성하고, 전자파차폐필터 하면에 근적외선 차폐층을 코팅하여 형성한 초박막의 직부착 피디피필터 및 이를 이용한 화상표시장치에 관한 것이다.The present invention relates to a thin film direct-attach PD filter and an image display device using the same, and more particularly, is formed by coating an optical function layer such as an anti-reflection layer, a low reflection layer, etc. on the upper surface of the electromagnetic shielding filter, and shielding near infrared rays from the lower surface of the electromagnetic shielding filter. The present invention relates to an ultra thin film direct-attached PD filter formed by coating a layer and an image display device using the same.
종래 반사방지, 저반사 등의 광학기능필터, 전자파차폐필터, 근적외선 차폐층을 포함하는 플라즈마 디스플레이 패널(Plazma Display Panel, 이하 'PDP')필터의 구조는 도 1과 같다. 도 1에서 보는 바와 같이 PDP필터는 투명지지체(600)에 광학기능층(300)이 도포된 광학기능필터와 전자파차폐 기능을 하는 전자파차폐필터(200)가 독립적으로 PDP(100)에 부착된다. 또한, PDP와 전자파차폐필터를 결합하는 점착층(400)에 근적외선차폐 또는 네온차폐 염료를 첨가하여 근적외선차폐 또는 네온차폐 기능을 얻을 수 있었다. The structure of a conventional plasma display panel (PDP) filter including an optical anti-reflection, low reflection and other functional filters, an electromagnetic shielding filter, and a near infrared shielding layer is shown in FIG. 1. As shown in FIG. 1, in the PDP filter, an optical functional filter coated with the optical
이러한 종래 PDP필터(공개번호 특2002-0013743)는 두 개 이상의 광학필터를 결합하는 구조이므로 두께를 박막으로 형성하는데 한계가 있었다. 또한, 생산공정면에서도 두 개의 필터를 제조하는 프로세스를 마친 후 다시 이를 결합하여 PDP에 부착하여야 하므로 생산 효율이 낮은 단점이 있었다.Since the conventional PDP filter (Publication No. 2002-0013743) has a structure in which two or more optical filters are combined, there is a limit in forming a thin film. In addition, in terms of the production process, after the process of manufacturing the two filters to combine again attached to the PDP had a disadvantage of low production efficiency.
본 발명은 박막형 직부착 피디피필터 및 이를 이용한 화상표시장치에 관한 것으로서, 전자파차폐필터의 상면과 하면에 각각 광학기능층과 근적외선 차폐층을 형성하여 하나의 PDP필터를 통하여 반사방지 기능, 저반사 기능 등 광학 기능, 전자파차폐 기능, 근적외선차폐 기능을 모두 수행하며, 근적외선 차폐 염료를 자외선 경화성수지에 혼합하여 근적외선 차폐층을 형성함으로써 염료의 열안정성을 높이는 것을 목적으로 한다. 또한, 근적외선 차폐층에 네온차폐 염료나 색보정 염료를 혼합하여 네온차폐 또는 색보정 효과를 함께 얻는 것을 목적으로 한다.The present invention relates to a thin film direct-attach PD filter and an image display device using the same, wherein an optical function layer and a near infrared shielding layer are formed on the upper and lower surfaces of the electromagnetic shielding filter, respectively, to prevent reflection and low reflection. The optical function, the electromagnetic shielding function, and the near infrared shielding function are all performed. The purpose of the present invention is to increase the thermal stability of the dye by forming the near infrared shielding layer by mixing the near infrared shielding dye with the ultraviolet curable resin. In addition, an object of the present invention is to obtain a neon shielding or color correction effect by mixing a neon shielding dye or a color correction dye with the near-infrared shielding layer.
본 발명은 전자파차폐필터를 포함하는 피디피필터에 있어서, 상기 전자파차폐필터의 상면에 광학기능층이 코팅되며, 상기 전자파차폐필터의 하면에 근적외선 차폐층이 코팅되고,The present invention is a PD filter comprising an electromagnetic shielding filter, an optical functional layer is coated on the upper surface of the electromagnetic shielding filter, a near infrared shielding layer is coated on the lower surface of the electromagnetic shielding filter,
상기 근적외선 차폐층을 이루는 근적외선차폐 조성물은 자외선 경화성수지, 근적외선차폐 염료, 자외선 흡수제, 경화제 및 레벨링제를 포함하여 이루어지고,The near-infrared shielding composition constituting the near-infrared shielding layer comprises an ultraviolet curable resin, a near-infrared shielding dye, an ultraviolet absorber, a curing agent, and a leveling agent,
상기 근적외선차폐 조성물 100중량%에 있어서,In 100% by weight of the near-infrared shield composition,
a) 상기 근적외선차폐 염료는 0.1중량% 내지 15중량%;a) the near infrared shielding dye is 0.1% to 15% by weight;
b) 상기 자외선 흡수제는 0.1중량% 내지 15중량%;b) 0.1 wt% to 15 wt% of the ultraviolet absorbent;
c) 상기 경화제는 0.1중량% 내지 15중량%; 및c) 0.1 to 15 weight percent of said curing agent; And
d) 상기 레벨링제는 0.1중량% 내지 3중량%인 박막형 직부착 피디피필터에 의하여 달성된다.d) The leveling agent is achieved by a thin film direct attachment PD filter of 0.1% by weight to 3% by weight.
이하 본 발명의 기술적 구성을 중심으로 상세히 설명한다.Hereinafter, the technical configuration of the present invention will be described in detail.
본 발명에 의한 박막형 직부착 피디피필터는 전자파차폐필터를 포함하고, 전자파차폐필터의 상면에는 광학기능층이 코팅되고, 하면에는 근적외선 차폐층이 코팅된다. 이하 상세히 살펴본다.The thin film direct attach PD filter according to the present invention includes an electromagnetic shielding filter, an optical functional layer is coated on the upper surface of the electromagnetic shielding filter, and a near infrared shielding layer is coated on the lower surface. It looks at in detail below.
(1) 전자파차폐필터(1) Electromagnetic shielding filter
전자파차폐필터는 전자파를 차폐한다. 전자파차폐필터는 도전성 금속메쉬 (mesh), ITO코팅, 도전성 섬유메쉬(mesh) 등으로 이루어질 수 있고, 본 발명에서는 금속메쉬 방식을 사용하는 것이 바람직하다.The electromagnetic shielding filter shields electromagnetic waves. Electromagnetic shielding filter may be made of a conductive metal mesh (mesh), ITO coating, a conductive fiber mesh (mesh), etc. In the present invention, it is preferable to use a metal mesh method.
본 발명에 의한 전자파차폐필터는 필름 또는 시트 형상인 것이 바람직하며, 전자파차폐필터의 상면은 하드코팅층이 형성되어 있다. 하드코팅층은 전자파차폐필터의 상면에 코팅되는 광학기능층의 종류에 따라서 두께, 성분, 함량 등이 변할 수 있다.The electromagnetic shielding filter according to the present invention is preferably in the form of a film or sheet, and a hard coat layer is formed on the upper surface of the electromagnetic shielding filter. The hard coating layer may vary in thickness, composition, content, etc. according to the type of optical functional layer coated on the upper surface of the electromagnetic shielding filter.
본 발명에서 하드코팅층을 형성하는 하드코팅 조성물은 경화성수지, 경화제, 레벨링제를 포함하여 이루어지며, 하드코팅 조성물 100중량%에 있어서, 경화성수지는 60중량% 내지 95중량%, 경화제는 1.5중량% 내지 15중량%, 레벨링제는 0.1중량% 내지 3중량%를 포함하는 것이 바람직하다.The hard coating composition forming the hard coating layer in the present invention comprises a curable resin, a curing agent, a leveling agent, in 100% by weight of the hard coating composition, the curable resin is 60% to 95% by weight, the curing agent 1.5% by weight To 15% by weight, the leveling agent preferably comprises 0.1 to 3% by weight.
하드코팅층에서 경화성수지는 근적외선 차폐층의 경화성수지와 동일하게 자외선 경화성수지를 사용하는 것이 더욱 바람직하다. 이 경우, 자외선 경화시 근적외선 차폐층과 하드코팅층의 자외선 경화성수지를 동시에 경화할 수 있다.In the hard coating layer, the curable resin is more preferably used as the curable resin of the near infrared shielding layer. In this case, the ultraviolet curable resin of the near infrared shielding layer and the hard coating layer may be cured at the same time during the ultraviolet curing.
하드코팅층의 자외선 경화성수지는 불포화 폴리에스테르 수지, 다관능 아크릴레이트 수지, 우레탄 아크릴레이트, 에폭시 아크릴 수지, 에폭시 아크릴레이트 수지 등을 단독 또는 혼합하여 사용할 수 있다. 자외선 경화성수지는 하드코팅 조성물 100중량%에 있어서 60중량% 내지 95중량%인 것이 바람직하고, 보다 바람직하게는 70중량% 내지 90중량%이다. 경화성수지가 하드코팅 조성물 100중량%에 대하여 60중량% 보다 작으면 경화에 의한 고경도를 얻기 힘들고, 95중량%보다 크면 상대적 으로 경화제와 레벨링제의 함량이 적어 원하는 수준의 물리적 물성을 얻기 힘들다.The ultraviolet curable resin of the hard coat layer may be used alone or in combination of unsaturated polyester resin, polyfunctional acrylate resin, urethane acrylate, epoxy acrylic resin, epoxy acrylate resin and the like. The ultraviolet curable resin is preferably 60% by weight to 95% by weight with respect to 100% by weight of the hard coating composition, and more preferably 70% by weight to 90% by weight. When the curable resin is less than 60% by weight relative to 100% by weight of the hard coating composition, it is difficult to obtain high hardness due to curing, and when the curable resin is greater than 95% by weight, it is difficult to obtain a desired level of physical properties because the content of the curing agent and leveling agent is relatively small.
하드코팅층에서 경화제는 자외선 경화성수지에 존재하는 관능기의 형태에 따라서 적절히 선택 및 혼합하여 사용할 수 있으며, 바람직하게는 이소시아네이트계 화합물, 에폭시계 화합물, 아지리딘계 화합물, 금속 킬레이트 화합물, 금속 알콕사이드 금속염, 아민 화합물, 히드리진 화합물 등을 단독 또는 혼합하여 사용한다.In the hard coating layer, the curing agent may be appropriately selected and mixed according to the form of the functional group present in the ultraviolet curable resin, and is preferably an isocyanate compound, an epoxy compound, an aziridine compound, a metal chelate compound, a metal alkoxide metal salt, or an amine compound. , Hydride compounds and the like are used alone or in combination.
경화제는 하드코팅 조성물 100중량%에 있어서 0.1중량% 내지 15중량% 사용하는 것이 바람직하며, 보다 바람직하게는 0.5중량% 내지 10중량%이다. 더더욱 바람직하게는 1중량% 내지 5중량%이다. 본 발명에서 경화제는 하드코팅 조성물의 분자량 또는 사슬 구조를 제어하기 위하여 사용하는 첨가제로서, 전술한 범위에서 경화제를 사용하면 상 분리 현상 등을 억제하는 효과가 두드러진다. 경화제의 함량이 0.1중량% 보다 작으면 경화제 기능을 기대하기 힘들고, 15중량% 보다 크면 경화성수지의 함량이 상대적으로 낮아 경도를 높이기 어렵다.It is preferable to use 0.1 to 15 weight% of hardening | curing agents in 100 weight% of hard-coating compositions, More preferably, it is 0.5 to 10 weight%. Even more preferably 1% to 5% by weight. In the present invention, the curing agent is an additive used to control the molecular weight or the chain structure of the hard coating composition. When the curing agent is used in the above-described range, the effect of suppressing phase separation and the like is prominent. If the content of the curing agent is less than 0.1% by weight, it is difficult to expect the function of the curing agent, if the content of more than 15% by weight it is difficult to increase the hardness of the relatively low content of the curable resin.
하드코팅층에서 레벨링제는 표면을 고르게 하기 위한 것으로서, 레벨링제는 실리콘 수지에 케톤이나 에스테르계 용제를 혼합하여 사용할 수 있다. 본 발명에 의한 레벨링제로는 실리콘 디아크릴레이트나 실리콘 폴리아크릴레이트 화합물을 단독 또는 혼합하여 사용하는 것이 바람직하다.In the hard coating layer, the leveling agent is for leveling the surface, and the leveling agent may be used by mixing a ketone or an ester solvent with a silicone resin. As a leveling agent by this invention, it is preferable to use a silicone diacrylate and a silicone polyacrylate compound individually or in mixture.
레벨링제는 하드코팅 조성물 100중량%에 있어서 0.1중량% 내지 3중량%인 것이 바람직하고, 보다 바람작하게는 0.5중량% 내지 2중량%이다. 레벨링제가 0.1중량 %보다 작으면 레벨링 효과를 기대하기 힘들고, 3중량% 보다 클 때는 경도가 약화될 우려가 있다.The leveling agent is preferably 0.1% to 3% by weight, more preferably 0.5% to 2% by weight, based on 100% by weight of the hard coating composition. If the leveling agent is less than 0.1% by weight, it is difficult to expect the leveling effect, and when it is greater than 3% by weight, the hardness may be weakened.
(2) 광학기능층(2) optical functional layer
본 발명에 의한 전자파차폐필터 상면에 광학기능층을 코팅한다. 광학기능층은 필요에 따라서 단독 또는 복수로 코팅하는 것이 가능하며, 코팅방식은 롤투롤(roll-to-roll) 코팅방식과 같은 인라인(in-line) 코팅방식을 이용할 수 있지만, 복수의 광학기능층을 코팅하기 위해서는 스핀(spin) 코팅방식을 이용하는 것이 바람직하다.The optical functional layer is coated on the upper surface of the electromagnetic shielding filter according to the present invention. The optical functional layer may be coated alone or in plurality as necessary, and the coating method may use an in-line coating method such as a roll-to-roll coating method, but a plurality of optical functions may be used. In order to coat the layer, it is preferable to use a spin coating method.
전자파차폐필터에 적층되는 광학기능층은 반사방지층, 저반사층, 미반사층, 눈부심방지층, 저굴절율층, 고굴절율층, 하드코팅층, 대전방지층 중 적어도 하나이다.The optical functional layer laminated on the electromagnetic shielding filter is at least one of an antireflection layer, a low reflection layer, an unreflective layer, an anti-glare layer, a low refractive index layer, a high refractive index layer, a hard coating layer, and an antistatic layer.
광학기능층을 형성하는 경우 광학기능층의 두께는 5㎛ 이하가 바람직하며, 보다 바람직하게는 1㎛ 이하이다. 광학기능층의 두께는 코팅하는 방식, 광학기능층의 조성물 등에 따라서 달라질 수 있다. 스핀 코팅방식을 이용하여 광학기능층을 코팅하는 경우 가장 얇은 반사방지층을 얻을 수 있다.When forming an optical function layer, the thickness of an optical function layer is 5 micrometers or less, More preferably, it is 1 micrometer or less. The thickness of the optical functional layer may vary depending on the coating method, the composition of the optical functional layer, and the like. When the optical functional layer is coated using the spin coating method, the thinnest antireflection layer can be obtained.
종래 광학기능층을 투명지지체에 코팅하여 투명지지체를 전자파차폐필터에 점착제를 이용하여 결합시키는 방식 대신, 본 발명에서는 전자파차폐필터의 상면에 광학기능층을 직접 코팅하여 투명지지체 만큼의 두께를 얇게 할 수 있다. 종래 기 술은 각각의 제조공정을 통하여 광학기능층이 코팅된 투명지지체와 전자파차폐필터를 완성한 후에 결합하였다. 종래 기술에 의한 굴절율 매칭(matching)은 굴절율이 결정된 두 개 이상의 필터를 결합하기 때문에 매칭(matching)이 어려웠다.Instead of coating the optical support layer on the transparent support and bonding the transparent support to the electromagnetic shielding filter using an adhesive, in the present invention, the optical functional layer is directly coated on the upper surface of the electromagnetic shielding filter to reduce the thickness of the transparent support. Can be. Conventional technology was combined after completing the transparent support and the electromagnetic shielding filter coated with the optical functional layer through each manufacturing process. Refractive index matching in the prior art has been difficult to match because it combines two or more filters for which the refractive index has been determined.
그러나, 본 발명에 의한 박막형 직부착 피디피필터는 굴절율 차이가 있는 2 이상의 광학기능층과 근적외선차폐층의 굴절율을 사전 조정하여 굴절율 매칭이 가장 적합한 투명수지를 광학기능층과 근적외선차폐층에 각각 사용함으로써 이러한 문제점을 해결할 수 있다. 본 발명은 스핀코팅 방식을 채택하는 경우 더욱 바람직하게 제조공정을 단순화할 수 있으며, 전자파차폐필터의 상면과 하면에 각각 별도의 코팅층을 하나의 공정으로 형성할 수 있으며, 굴절율 차이에 의한 매칭도 용이하다.However, the thin film direct-attach PD filter according to the present invention is prepared by adjusting the refractive indices of two or more optical functional layers and a near infrared shielding layer having a refractive index difference in advance, and using transparent resins having the best refractive index matching in the optical functional layer and the near infrared shielding layer, respectively. This problem can be solved. According to the present invention, when the spin coating method is adopted, the manufacturing process may be more preferably simplified. Separate coating layers may be formed on the upper and lower surfaces of the electromagnetic shielding filter in one process, and the matching may be easy due to the difference in refractive index. Do.
(3) 근적외선 차폐층(3) near infrared shielding layer
본 발명에 의한 근적외선 차폐층은 근적외선을 차폐하는 염료를 포함한다. 하지만, 염료는 열에 약하며 경화성수지를 열경화시 염료의 변성이나 기능 저하가 우려된다.The near infrared shielding layer according to the present invention includes a dye for shielding near infrared. However, dyes are susceptible to heat, and there is a concern that the denaturation or deterioration of the dyes may occur when the curable resin is thermoset.
이러한 문제점을 해결하기 위하여, 본 발명에서는 자외선 경화성수지를 베이스수지로 하여 염료를 전자파차폐필터의 하면에 코팅한다.In order to solve this problem, in the present invention, the dye is coated on the lower surface of the electromagnetic shielding filter using a UV-curable resin as a base resin.
코팅되는 근적외선 차폐층의 두께는 5㎚ 내지 40㎛인 것이 바람직하며, 더욱 바람직하게는 50㎚ 내지 12㎛이다. 스핀 코팅방식을 이용할 때 더욱 얇은 초박막의 근적외선 차폐층을 형성할 수 있다. 이 때 근적외선 차폐층의 두께는 스핀 코팅방식에서 회전속도, 회전시간, 근적외선차폐 조성물이 혼합된 유기 용매의 점도 등에 영향을 받는다.The thickness of the near-infrared shielding layer to be coated is preferably 5 nm to 40 μm, more preferably 50 nm to 12 μm. When the spin coating method is used, a thinner ultra-thin near-infrared shielding layer can be formed. At this time, the thickness of the near-infrared shielding layer is affected by the rotational speed, the rotation time, the viscosity of the organic solvent mixed with the near-infrared shielding composition in the spin coating method.
본 발명에서 근적외선차폐 조성물은 경화성수지, 근적외선차폐 염료, 경화제 자외선 흡수제 및 레벨링제을 포함하여 이루어진다. 근적외선차폐는 물론 네온차폐 또는 색보정 효과를 얻기 위해서는 상기 조성물 이외에 네온차폐 염료 또는 색보정 염료를 추가로 혼합한다. 이하에서는 근적외선차폐 조성물과 이를 전자파차폐필터에 도포시키기 위한 유기 용매에 대하여 각각 살펴본다. In the present invention, the near-infrared shielding composition comprises a curable resin, a near-infrared shielding dye, a curing agent ultraviolet absorber, and a leveling agent. In addition to the near-infrared shield, as well as neon shielding or color correction effect, in addition to the composition, a neon shielding dye or color correction dye is further mixed. Hereinafter, the near-infrared shielding composition and the organic solvent for applying the same to the electromagnetic shielding filter will be described.
① 경화성수지① Curable resin
본 발명에서 사용하는 경화성수지는 자외선 경화성수지를 사용하며, 일반적으로 알려진 공지의 수지를 사용한다. 불포화 폴리에스테르 수지, 다관능 아크릴레이트 수지, 우레탄 아크릴레이트, 에폭시 아크릴 수지, 에폭시 아크릴레이트 수지 등을 단독 또는 혼합하여 사용할 수 있다. 본 발명에서 사용가능한 자외선 경화성수지는 동일한 작용 효과를 나타낸다면 그 범위가 상기 나열된 수지에 한정되지 않음은 물론이다.The curable resin used in the present invention uses an ultraviolet curable resin, and generally known and known resins are used. An unsaturated polyester resin, a polyfunctional acrylate resin, a urethane acrylate, an epoxy acrylic resin, an epoxy acrylate resin, etc. can be used individually or in mixture. The UV curable resin usable in the present invention is, of course, not limited to the resins listed above as long as they exhibit the same effect.
근적외선 차폐층이 근적외선 차폐 효과는 물론 고경도 및 투명성 등의 물성도 함께 확보하기 위하여, 자외선 경화성수지는 자외선 경화성 다관능기 아크릴레 이트계 수지를 사용하는 것이 보다 바람직하다. 본 발명에서 자외선 경화성 다관능기 아크릴레이트계 수지는 디펜타에리트리톨 헥사아크릴레이트(dipentaerythritol hexaacrylte), 테트라메틸올메탄 테트라아크릴레이트(tetramethylolmethane tetraacrylate), 테트라메틸올메탄 트리아크릴레이트(tetramethylolmethane triacrylate), 트리메탄올프로판 트리아크릴레이트(trimethylolpropane triacrylate), 1,6-헥산디올 디아크릴레이트(1,6-hexanediol diacrylate), 1,6-비스(3-아크릴오일옥시-2-하이드록시프로필옥시)헥산[1,6-bis(3-acryloyloxy-2-hydroxypropyl)hexane] 등과 같은 다관능기 알콜 유도체, 폴리에틸렌 글라이콜 디아크릴레이트(polyethylene glycol diacrylate)와 펜타에리트리톨 트리아크릴레이트(pentaerythritol triacrylate)와 같은 우레탄 아크릴레이트, 헥사메틸렌 디이소시아네이트 우레탄 선행고분자(hexamethylene diisocyanate urethane prepolymer) 등이 단독 또는 혼합하여 사용한다.In order for the near-infrared shielding layer to secure not only the near-infrared shielding effect but also physical properties such as high hardness and transparency, it is more preferable to use an ultraviolet curable polyfunctional acrylate-based resin. In the present invention, the ultraviolet curable polyfunctional acrylate-based resin is dipentaerythritol hexaacrylte, tetramethylolmethane tetraacrylate, tetramethylolmethane triacrylate, trimethanol Propane triacrylate, 1,6-hexanediol diacrylate, 1,6-bis (3-acryloyloxy-2-hydroxypropyloxy) hexane [1, Polyfunctional alcohol derivatives such as 6-bis (3-acryloyloxy-2-hydroxypropyl) hexane], urethane acrylates such as polyethylene glycol diacrylate and pentaerythritol triacrylate, Hexamethylene diisocyanate urethane prepolymer or the like alone or mixed Use open.
전술한 자외선 경화성 다관능기 아크릴레이트계 수지는 자외선 경화성수지 100중량%에 있어서 10중량% 내지 90중량% 사용하는 것이 바람직하고, 더욱 바람직하게는 30중량% 내지 87중량%이다. 더더욱 바람직하게는 50중량% 내지 85중량% 사용하는 것이 바람직하다.It is preferable to use 10 weight%-90 weight% of said ultraviolet curable polyfunctional acrylate-type resin in 100 weight% of ultraviolet curable resin, More preferably, it is 30 weight%-87 weight%. Even more preferably, 50 to 85% by weight is used.
자외선 경화성수지 100중량%에 있어서 자외선 경화성 다관능기 아크릴레이트계 수지가 10중량% 보다 작으면 절대적인 관능기 수가 적어서 관능기의 결합에 따른 고경도를 얻기 힘들고, 90중량% 보다 많을 때는 경도는 높아지지만 근적외선차 폐 염료와 혼합성이 떨어지는 단점이 있다.When the UV-curable polyfunctional acrylate-based resin is less than 10% by weight in 100% by weight of the UV-curable resin, the absolute number of functional groups is small, resulting in high hardness due to the bonding of functional groups. It has the disadvantage of poor compatibility with waste dyes.
본 발명에서는 베이스수지로 자외선 경화성수지만 사용함으로써, 100℃ 이하에서 자외선경화가 가능하여, 근적외선차폐 염료는 물론 추가 혼합이 가능한 네온차폐 염료와 색보정 염료의 물성에 영향을 주지 않고 열안정성을 유지할 수 있다.In the present invention, by using only the UV-curable resin as the base resin, it is possible to cure UV at below 100 ℃, maintaining the thermal stability without affecting the properties of the near-infrared shielding dyes and neon shielding dyes and color correction dyes that can be further mixed. Can be.
② 근적외선차폐 염료② NIR shielding dye
본 발명에서 사용하는 근적외선차폐 염료는 일반적인 근적외선차폐 염료를 사용하는 것이 가능하다.As the near-infrared shielding dye used in the present invention, it is possible to use a general near-infrared shielding dye.
본 발명에서 사용하는 근적외선차폐 염료는 프탈로시아닌계 염료, 나프탈로시아닌계 염료, 안트라퀴논계 염료, 나프토퀴논계 염료, 시아닌계 염료, 메탈 콤플렉스계 염료, 암모늄계 염료, 아미늄계 염료, 이모늄계 염료, 디이모늄계 염료, 폴리메틴계 염료, 방향족 디티올계 염료, 방향족 디올계 염료 등을 단독 또는 혼합하여 사용한다. 근적외선 흡수 효과가 뛰어난 프탈로사아닌계 염료는 프탈로시아닌, 프탈로시아닌 착물, 프탈로시아닌 골격 벤젠 고리에 다양한 관능기를 가지는 유도체를 포함한다.Near-infrared shielding dyes used in the present invention are phthalocyanine dyes, naphthalocyanine dyes, anthraquinone dyes, naphthoquinone dyes, cyanine dyes, metal complex dyes, ammonium dyes, aluminum dyes, immonium dyes, di Immonium dyes, polymethine dyes, aromatic dithiol dyes, aromatic diol dyes and the like are used alone or in combination. Phthalocyanine-based dyes having excellent near-infrared absorption effects include phthalocyanine, phthalocyanine complexes, and derivatives having various functional groups in the phthalocyanine skeleton benzene ring.
근적외선차폐 염료는 근적외선 차폐층을 코팅한 후 건조하고 경화하는 단계에서도 열적 안정성을 유지하며, 염료의 물성을 유지하는 암모늄계 염료, 아미늄계 염료, 이모늄계 염료, 디이모늄계 염료를 단독 또는 혼합하여 사용하는 것이 더욱 바람직하다.The near-infrared shielding dye maintains thermal stability even when the near-infrared shielding layer is coated, dried and cured, and is used alone or in combination with ammonium dyes, aluminum dyes, immonium dyes, and dimonium dyes that maintain the properties of the dyes. It is more preferable to use.
본 발명에서 사용하는 근적외선차폐 염료의 함량은 근적외선차폐 조성물 100중량%에 있어서, 0.1중량% 내지 15중량%인 것이 바람직하며, 더욱 바람직하게는 0.5중량% 내지 10중량%이다. 더더욱 바람직하게는 1중량% 내지 5중량%이다.The content of the near-infrared shielding dye used in the present invention is preferably 0.1 to 15% by weight, more preferably 0.5 to 10% by weight, based on 100% by weight of the near-infrared shielding composition. Even more preferably 1% to 5% by weight.
근적외선차폐 염료의 함량이 0.1중량%보다 작을 때는, 본 발명에 의한 근적외선 흡수 효과를 얻기 힘들고 절대적인 염료의 함량이 많아야 하므로 근적외선 차폐층의 두께가 두꺼워지는 단점이 있다. 또한, 15중량%보다 클 때는 열경화 또는 자외선경화시 노출된 염료로 인하여 열안정성 또는 광안정성에 영향을 받을 수 있으며, 경제성 또한 낮다.When the content of the near-infrared shielding dye is less than 0.1% by weight, it is difficult to obtain the near-infrared absorbing effect according to the present invention, and since the amount of the absolute dye must be high, the thickness of the near-infrared shielding layer becomes thick. In addition, when greater than 15% by weight may be affected by thermal stability or light stability due to the dye exposed during thermal curing or ultraviolet curing, it is also economical low.
③ 경화제③ curing agent
본 발명에서 경화제는 자외선 경화성수지에 존재하는 관능기의 형태에 따라서 적절히 선택 및 혼합하여 사용할 수 있으며, 바람직하게는 이소시아네이트계 화합물, 에폭시계 화합물, 아지리딘계 화합물, 금속 킬레이트 화합물, 금속 알콕사이드 금속염, 아민 화합물, 히드리진 화합물 등을 단독 또는 혼합하여 사용한다.In the present invention, the curing agent may be appropriately selected and mixed according to the form of the functional group present in the ultraviolet curable resin, preferably isocyanate compound, epoxy compound, aziridine compound, metal chelate compound, metal alkoxide metal salt, amine compound , Hydride compounds and the like are used alone or in combination.
본 발명에서의 이소시아네이트계 화합물은 트리메틸렌 디이소시아네이트(trimethylene diisocyanate), 헥사메틸렌 디이소시아네이트(hexamethylene diisocyanate), 이소포론 디이소시아네이트(isophorone diisocyanate), 디페닐메탄 이소시아네이트(diphenylmethane isocyanate), 자이렌 디이소시아네이트(xylene diisocyanate) 등의 방향족 디이소시아네이트계 화합물, 헥사메틸 디이소시아네이트(hexamethyl diisocyanate) 등의 지방족 디이소시아네이트 화합물(aliphatic diisocyanate) 등을 단독 또는 혼합하여 사용한다.Isocyanate compounds in the present invention are trimethylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, diphenylmethane isocyanate, xylene diisocyanate aromatic diisocyanate compounds such as diisocyanate, aliphatic diisocyanate such as hexamethyl diisocyanate, and the like are used alone or in combination.
또한, 본 발명에서의 에폭시계 화합물은 폴리에틸렌 글리콜 디글리시딜 에테르(polyethylene glycol diglycidyl ether), 디글리시딜 에테르(diglycidyl ether), 트리메틸올 프로판 트리글리시딜 에테르(trimethylol propane triglycidyl ether) 등을 단독 또는 혼합하여 사용한다.In addition, the epoxy compound in the present invention is a polyethylene glycol diglycidyl ether (diglycidyl ether), diglycidyl ether (diglycidyl ether), trimethylol propane triglycidyl ether (trimethylol propane triglycidyl ether) and the like alone Or mixed.
본 발명에서의 경화제는 근적외선차폐 조성물 100중량%에 있어서, 0.1중량% 내지 15중량% 사용하는 것이 바람직하며, 더욱 바람직하게는 0.5중량% 내지 10중량%이다. 더더욱 바람직하게는 1중량% 내지 5중량%이다.It is preferable to use 0.1 to 15 weight% of 100% by weight of the hardening | curing agent in a near-infrared shielding composition, More preferably, it is 0.5 to 10 weight%. Even more preferably 1% to 5% by weight.
본 발명에서 경화제는 근적외선차폐 조성물의 분자량 또는 사슬 구조를 제어하기 위하여 사용하는 첨가제로서, 전술한 범위에서 경화제를 사용하면 상 분리 현상 등을 억제하는 효과가 두드러진다. 경화제의 함량이 0.1중량% 보다 작으면 경화제 기능을 기대하기 힘들고, 15중량% 보다 크면 경화성수지의 함량이 상대적으로 낮아 경도를 높이기 어렵다. In the present invention, the curing agent is an additive used to control the molecular weight or the chain structure of the near-infrared shielding composition. When the curing agent is used in the above-described range, the effect of suppressing phase separation and the like is prominent. If the content of the curing agent is less than 0.1% by weight, it is difficult to expect the function of the curing agent, if the content of more than 15% by weight it is difficult to increase the hardness of the relatively low content of the curable resin.
④ 자외선 흡수제④ UV absorber
자외선 흡수제는 자외선 경화성수지를 자외선 경화할 때 발생하는 열화를 방지하고 염료의 내구성을 향상시킨다.The ultraviolet absorber prevents deterioration caused by ultraviolet curing of the ultraviolet curable resin and improves the durability of the dye.
본 발명에서 사용하는 자외선 흡수제는 살리실레이트계 자외선 흡수제, 벤조페논계 자외선 흡수제, 벤조트라이졸계 자외선 흡수제, 시아노아크릴레이트계 자외선 흡수제, 벤조에이트계 자외선 흡수제 등을 단독 또는 혼합하여 사용하는 것이 바람직하다.The ultraviolet absorber used in the present invention is preferably used alone or mixed with a salicylate ultraviolet absorber, a benzophenone ultraviolet absorber, a benzotriazole ultraviolet absorber, a cyanoacrylate ultraviolet absorber, and a benzoate ultraviolet absorber. Do.
보다 구체적으로, 자외선 흡수제는 페닐 살리실레이트, p-tert-부틸페닐 살리실레이트, p-옥틸페닐 살리실레이트, 4-디히드록시벤조페논, 2-히드록시-4-메톡시벤조페논, 2-히드록시-4-옥톡시벤조페논, 2-히드록시-4-도데실옥시벤조페논, 2,2'-디히드록시-4-메톡시벤조페논, 2,2'-디히드록시-4-메톡시벤조페논, 2,2'-디히드록시-4,4'-디메톡시벤조페논, 2-히드록시-4-메톡시-5-술포벤조페논, 비스(2-메톡시-4-히드록시-5-벤조일페닐)메탄, 2-(2'-히드록시-5'-메틸페닐)벤조트리아졸, 2-(2'-히드록시-5'-tert-부틸페닐)벤조트리아졸, 2-(2'-히드록시-3',5'-디-tert-부틸페닐)벤조트리아졸, 2-(2'-히드록시-3'-tert-부틸-5'-메틸페닐)-5-클로로벤조트리아졸, 2-(2'-히드록시-3',5'-디-tert-부틸페닐)-5-클로로벤조트리아졸, 2-(2'-히드록시-3',5-디-tert-아밀페닐)벤조트리아졸, 2-(2'-히드록시-4'-옥톡시페닐)벤조트리아졸, 2-(2'-히드록시-3'-(3',4',5',6'-테트라히드로프탈이미도메틸)-5'-메틸페닐)벤조트리아졸, 2,2'-메틸렌비스[4-(1,1,3,3-테트라메틸부틸)-6-(2H-벤조트리아졸릴-2-일)페놀], 2-(2'-히드록시-5'-메타크릴옥시페닐)-2H-벤조트리아졸, 2,2'-메틸렌비스[4-(1,1,3,3-테트라메틸부틸)-6-[(2H-벤조트리아졸-2-일)페놀], 및 2-(2'-히드록시-3',5'-di-t-아밀페닐)벤조트리아졸, 2-에틸헥실-2-시아노-3,3'-디페닐아크릴레이트, 에틸-2-시아노-3,3'-디페닐아크릴레이트 등을 단독 또는 혼합하여 사 용한다.More specifically, the ultraviolet absorber is phenyl salicylate, p-tert-butylphenyl salicylate, p-octylphenyl salicylate, 4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2-hydroxy-4-dodecyloxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy- 4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy-4-methoxy-5-sulfobenzophenone, bis (2-methoxy-4 -Hydroxy-5-benzoylphenyl) methane, 2- (2'-hydroxy-5'-methylphenyl) benzotriazole, 2- (2'-hydroxy-5'-tert-butylphenyl) benzotriazole, 2- (2'-hydroxy-3 ', 5'-di-tert-butylphenyl) benzotriazole, 2- (2'-hydroxy-3'-tert-butyl-5'-methylphenyl) -5- Chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-di-tert-butylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3', 5-di -tert-amylphenyl) benzotriazole, 2- (2'-hydroxy-4'-octoxy Yl) benzotriazole, 2- (2'-hydroxy-3 '-(3', 4 ', 5', 6'-tetrahydrophthalimidomethyl) -5'-methylphenyl) benzotriazole, 2,2 '-Methylenebis [4- (1,1,3,3-tetramethylbutyl) -6- (2H-benzotriazolyl-2-yl) phenol], 2- (2'-hydroxy-5'-meta Krilloxyphenyl) -2H-benzotriazole, 2,2'-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6-[(2H-benzotriazol-2-yl) phenol ], And 2- (2'-hydroxy-3 ', 5'-di-t-amylphenyl) benzotriazole, 2-ethylhexyl-2-cyano-3,3'-diphenylacrylate, ethyl 2-cyano-3,3'-diphenyl acrylate or the like is used alone or in combination.
본 발명에서 자외선 흡수제의 함량은 근적외선차폐 조성물 100중량%에 있어서, 0.1중량% 내지 15중량% 사용하는 것이 바람직하며, 더욱 바람직하게는 0.5중량% 내지 10중량%이다. 더더욱 바람직하게는 1중량% 내지 5중량%이다.In the present invention, the content of the ultraviolet absorber is preferably used in an amount of 0.1 wt% to 15 wt%, more preferably 0.5 wt% to 10 wt%, in 100 wt% of the near-infrared shielding composition. Even more preferably 1% to 5% by weight.
⑤ 레벨링제⑤ Leveling agent
본 발명에서 근적외선 차폐층의 표면을 고르게 하기 위하여 근적외선차폐 조성물에 레벨링제를 혼합하여 사용한다. 레벨링제는 실리콘 수지에 케톤이나 에스테르계 용제를 혼합하여 사용할 수 있다. 본 발명에 의한 레벨링제로는 실리콘 디아크릴레이트나 실리콘 폴리아크릴레이트 화합물을 단독 또는 혼합하여 사용하는 것이 바람직하다.In the present invention, in order to even the surface of the near-infrared shielding layer, a leveling agent is mixed and used in the near-infrared shielding composition. The leveling agent can be used by mixing a ketone or an ester solvent with a silicone resin. As a leveling agent by this invention, it is preferable to use a silicone diacrylate and a silicone polyacrylate compound individually or in mixture.
레벨링제의 함량은 근적외선차폐 조성물 100중량%에 있어서, 0.1중량% 내지 3중량%인 것이 바람직하고, 보다 바람작하게는 0.5중량% 내지 2중량%이다. 레벨링제가 0.1중량%보다 작으면 레벨링 효과를 기대하기 힘들고, 3중량% 보다 클 때는 근적외선 차폐층의 표면 경도가 약화될 우려가 있다.The content of the leveling agent is preferably 0.1 wt% to 3 wt%, more preferably 0.5 wt% to 2 wt%, based on 100 wt% of the near-infrared shielding composition. When the leveling agent is less than 0.1% by weight, it is difficult to expect the leveling effect, and when the leveling agent is greater than 3% by weight, the surface hardness of the near infrared ray shielding layer may be weakened.
⑥ 유기 용매⑥ organic solvent
본 발명에서 전자파차폐필터의 하면에 근적외선 차폐층을 도포시키기 위하여 유기 용매를 사용한다.In the present invention, an organic solvent is used to apply the near-infrared shielding layer to the lower surface of the electromagnetic shielding filter.
근적외선 차폐층의 도포성, 투명지지층과의 부착성, 근적외선차폐 조성물의 차폐 기능의 제고 등을 고려하여 적정 유기 용매를 사용한다.A proper organic solvent is used in consideration of the applicability of the near infrared shielding layer, the adhesion to the transparent support layer, and the enhancement of the shielding function of the near infrared shielding composition.
본 발명에서 사용하는 유기 용매는 알콜계의 메탄올, 이소프로판올, 부탄올, t-부탄올, 이소부탄올 등의 탄소수 1 내지 8의 포화 탄화수소계 알콜, 케톤류의 아세톤, 메틸에틸케톤, 메틸이소부틸케톤 등의 탄소수 1 내지 8의 포화 탄화수소계 케톤, 아세틸 아세톤 등의 탄소수 1 내지 8의 포화 탄화수소계 디케톤, 에스테르류의 에틸아세테이트, 부틸 아세테이트 등의 탄소수 1 내지 8의 포화 탄화수소계 에스테르, 에테르 알콜류의 에틸셀로솔브, 메틸셀로솔브, 부틸셀로솔브, 1-메톡시-2-프로판올, 그 외에 N-메틸 피롤리돈, 에틸셀로솔브 아세테이트, 디아세톤 알콜 등을 단독 또는 혼합하여 사용한다.The organic solvent used in the present invention may be a C1-8 saturated hydrocarbon alcohol such as methanol, isopropanol, butanol, t-butanol, isobutanol, or acetone, methyl ethyl ketone, or methyl isobutyl ketone. Saturated hydrocarbon-based diketones having 1 to 8 carbon atoms, such as 1 to 8 saturated hydrocarbon ketones and acetyl acetone, ethyl acetate of esters, ethyl hydrocarbons of 1 to 8 carbon atoms such as butyl acetate, and ethyl alcohols of ether alcohols. Solves, methyl cellosolves, butyl cellosolves, 1-methoxy-2-propanol, and N-methyl pyrrolidone, ethyl cellosolve acetate, diacetone alcohol, and the like are used alone or in combination.
유기 용매는 도포되는 근적외선차폐 조성물 100중량부에 대하여 20중량부 내지 110중량부 사용하는 것이 바람직하며, 보다 바람직하게는 30중량부 내지 80중량부이다. 유기 용매의 함량이 근적외선차폐 조성물 100중량부에 대하여 20중량부보다 작을 때는 전자파차폐필터와의 도포성, 부착성 등이 떨어지고, 110중량부보다 클 때는 근적외선차폐 조성물에 비하여 지나치게 많아 건조단계에서 건조시간이 오래 걸리고 채산성이 떨어진다.The organic solvent is preferably used in an amount of 20 parts by weight to 110 parts by weight based on 100 parts by weight of the near-infrared shielding composition to be applied, and more preferably 30 parts by weight to 80 parts by weight. When the content of the organic solvent is less than 20 parts by weight with respect to 100 parts by weight of the near-infrared shielding composition, the coating property and adhesion with the electromagnetic shielding filter are inferior, and when the content of the organic solvent is greater than 110 parts by weight, it is too large compared to the near-infrared shielding composition and dried in the drying step. It takes a long time and is not profitable.
(4) 네온차폐 염료 및 색보정 염료(4) Neon shield dyes and color correction dyes
본 발명에서 근적외선 차폐층은 근적외선차폐 염료 뿐만 아니라, 네온차폐 염료 또는 색보정 염료를 추가로 포함하여 구성될 수 있다.In the present invention, the near-infrared shielding layer may further include not only a near-infrared shielding dye but also a neon shielding dye or a color correction dye.
네온차폐 염료 또는 색보정 염료가 단독 또는 혼합되어 추가된 경우, 근적외 선 차폐층은 근적외선 차폐 기능은 물론 네온차폐 기능 또는 색보정 기능을 동시에 할 수 있다. 네온차폐 염료 또는 색보정 염료가 추가된 경우 전자파를 차단하고 근적외선을 차폐함은 물론, 색보정 및 색재현성을 향상시키고 콘트라스트를 높이며, 플라즈마 방전시 발생하는 특유의 오렌지빛을 차단할 수 있다.When the neon shielding dye or color correction dye is added alone or in combination, the near-infrared shielding layer may simultaneously perform a near-infrared shielding function as well as a neon shielding function or color correction function. When neon shielding dye or color correction dye is added, it can block electromagnetic waves and shield near infrared rays, improve color correction and color reproducibility, increase contrast, and block the unique orange color generated during plasma discharge.
본 발명에서 사용하는 네온차폐 염료는 일반적으로 사용하는 네온차폐 염료를 모두 사용할 수 있고, 바람직하게는 시아닌계 염료, 스쿠아릴리움계 염료 또는 아조메탈계 염료 등을 단독 또는 혼합하여 사용한다. 또한 색보정 염료도 일반적으로사용하는 색보정 염료를 모두 사용할 수 있고, 보다 바람직하게는 안트라퀴논계 염료, 프탈로시아닌계 염료, 시오인디고계 염료 등을 단독 또는 혼합하여 사용한다.As the neon shielding dye used in the present invention, all of the neon shielding dyes generally used may be used. Preferably, cyanine dyes, squarylium dyes, or azometal dyes may be used alone or in combination. In addition, all of the color correction dyes commonly used for color correction dyes may be used, and more preferably, anthraquinone dyes, phthalocyanine dyes, and shiododi dyes may be used alone or in combination.
본 발명에서 사용하는 네온차폐 염료의 함량은 근적외선차폐 조성물 100중량%에 있어서, 0.05중량% 내지 3중량%인 것이 바람직하며, 더욱 바람직하게는 0.1중량% 내지 1.5중량%이다.The content of the neon shielding dye used in the present invention is preferably 0.05% to 3% by weight, more preferably 0.1% to 1.5% by weight in 100% by weight of the near-infrared shielding composition.
네온차폐 염료의 함량이 0.05중량%보다 작을 때는 본 발명에 의한 네온차폐 효과를 얻기 힘들며, 다른 조성물과 혼합된 네온차폐 염료의 절대적인 함량이 많아야 하므로 근적외선 차폐층의 두께가 두꺼워지는 단점이 있다. 또한, 3중량%보다 클 때는 다른 염료의 기능에 영향을 줄 수 있으며 경제성 또한 낮다.When the content of the neon shielding dye is less than 0.05% by weight, it is difficult to obtain the neon shielding effect according to the present invention, and since the absolute content of the neon shielding dye mixed with other compositions must be large, the thickness of the near-infrared shielding layer becomes thick. In addition, when greater than 3% by weight may affect the function of other dyes and economics are also low.
본 발명에서 사용하는 색보정 염료의 함량은 근적외선차폐 조성물 100중량%에 있어서, 0.05중량% 내지 3중량%인 것이 바람직하며, 더욱 바람직하게는 0.1중량% 내지 1.5중량%이다.The content of the color correction dye used in the present invention is preferably 0.05% to 3% by weight, more preferably 0.1% to 1.5% by weight in 100% by weight of the near-infrared shielding composition.
색보정 염료 함량이 0.05중량%보다 작을 때는 본 발명에 의한 색보정 효과를 얻기 힘들며, 다른 조성물과 혼합된 색보정 염료의 절대적인 함량이 많아야 하므로 근적외선 차폐층의 두께가 두꺼워지는 단점이 있다. 또한, 3중량%보다 클 때는 다른 염료의 기능에 영향을 줄 수 있으며 경제성 또한 낮다.When the color correction dye content is less than 0.05% by weight, it is difficult to obtain the color correction effect according to the present invention, and since the absolute content of the color correction dye mixed with other compositions must be large, there is a disadvantage that the thickness of the near-infrared shielding layer becomes thick. In addition, when greater than 3% by weight may affect the function of other dyes and economics are also low.
본 발명의 권리범위는 전술한 박막형 직부착 PDP필터가 적용되는 화상표시장치에도 미치며, 이러한 화상표시장치는 브라운관표시장치(CRT, cathode-ray tube), 액정표시장치(LCD, liquid crystal dispaly), 플라즈마표시장치(PDP, plasma display pannel) 및 유기전계발광 표시장치(OLED, organic light emitting diode)로 이루어진 그룹 중에서 적어도 하나이다.The scope of the present invention also extends to an image display device to which the above-described thin film type PDP filter is applied. Such an image display device includes a cathode-ray tube (CRT), a liquid crystal display (LCD), At least one selected from the group consisting of a plasma display panel (PDP) and an organic light emitting diode (OLED).
이하에서는 본 발명의 바람직한 실시예를 도면을 참조하여 설명한다.Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.
도 2는 본 발명에 의한 박막형 직부착 PDP필터의 구조도를 나타낸 것이다.2 shows a structural diagram of a thin film direct-attach PDP filter according to the present invention.
도 2에서 보는 바와 같이 본 발명의 PDP필터는 전자파차폐필터(200)의 상면에는 광학기능층(300)이 도포되어 있고, 하면에는 근적외선 차폐층(500)이 도포되어 PDP(100)와 결합한다. 종래 PDP필터가 2 이상의 필터를 결합하여 전자파차폐, 근적외선차폐, 반사방지와 같은 광학효과를 얻었던 것에 반하여 본 발명에서는 하나의 층으로 동일한 효과를 얻을 수 있어, 박막 PDP필터 형성이 가능하고, 생산공정도 단순화할 수 있다.As shown in FIG. 2, in the PDP filter of the present invention, an optical
이상, 본 발명의 구성을 중심으로 실시예를 참조하여 상세하게 설명하였다. 그러나 본 발명의 권리범위는 상기 실시예에 한정되는 것은 아니라 첨부된 특허청구범위내에서 다양한 형태의 실시예로 구현될 수 있다. 특허청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 누구든지 가능한 다양한 변형 가능한 범위까지 본 발명의 청구 범위 기재의 범위 내에 있는 것으로 본다.In the above, the configuration of the present invention was described in detail with reference to Examples. However, the scope of the present invention is not limited to the above embodiments but may be embodied in various forms of embodiments within the appended claims. Without departing from the gist of the invention as claimed in the claims, any person of ordinary skill in the art is considered to be within the scope of the claims described in the present invention to the extent possible to vary.
또한, 본 발명에서의 바람직한 범위, 더욱 바람직한 범위, 더더욱 바람직한 범위 한정은 그 효과를 더욱 극대화 시키기 위한 것으로서, 한정 범위가 좁혀짐으로써 더욱 만족스러운 기술적 효과를 얻을 수 있다.In addition, the preferred range, more preferred range, and even more preferred range limitation in the present invention is to maximize the effect even more, it is possible to obtain a more satisfactory technical effect by narrowing the limited range.
전술한 바와 같이 본 발명에 의한 박막형 직부착 피디피필터 및 이를 이용한 화상표시장치를 통하여, 하나의 전자파차폐필터의 상면과 하면에 각각 광학기능층과 근적외선차폐층을 형성하여 반사방지, 저반사 등의 광학 효과, 전자파차폐 효과, 근적외선차폐 효과를 모두 얻을 수 있다. 또한, 근적외선 차폐층에 근적외선차폐 염료, 네온차폐 염료, 색보정 염료를 자외선 경화성수지에 혼합하여 근적외선차폐층을 형성함으로써 저온의 자외선 경화를 할 수 있어 염료의 물성 및 기능을 저 하시키지 않고, 열안정성을 높이는 효과가 있다.As described above, the optical functional layer and the near-infrared shielding layer are formed on the upper and lower surfaces of one electromagnetic wave shielding filter through the thin film type direct-attach PD filter according to the present invention and the image display device using the same. Optical, electromagnetic shielding, and near-infrared shielding effects can all be obtained. In addition, near-infrared shielding layer, near-infrared shielding dye, neon shielding dye, and color correction dye are mixed with UV-curable resin to form a near-infrared shielding layer, so that UV curing at low temperature can be performed. It has the effect of increasing stability.
Claims (18)
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JPS6478509A (en) * | 1987-09-19 | 1989-03-24 | Tokin Corp | Block filter |
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JP2001192350A (en) * | 1999-03-05 | 2001-07-17 | Mitsubishi Chemicals Corp | Squalirium-based compound, filter for plasma display panel using the same and plasma display panel display device |
JP2001247526A (en) * | 2000-03-06 | 2001-09-11 | Toyobo Co Ltd | Near infrared absorption compound composition and near infrared absorption filter |
JP2001350013A (en) * | 2000-04-06 | 2001-12-21 | Mitsubishi Chemicals Corp | Filter for plasma display panel |
JP2004238606A (en) * | 2002-12-10 | 2004-08-26 | Mitsubishi Chemicals Corp | Squalirium-based compound, squalirium-based pigment and optical filter given by using the same |
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JPS6478509A (en) * | 1987-09-19 | 1989-03-24 | Tokin Corp | Block filter |
JP2001192350A (en) * | 1999-03-05 | 2001-07-17 | Mitsubishi Chemicals Corp | Squalirium-based compound, filter for plasma display panel using the same and plasma display panel display device |
JP2001158762A (en) * | 1999-12-02 | 2001-06-12 | Toyobo Co Ltd | Near infrared ray absorbing compound and near infrared ray absorbing filter |
JP2001247526A (en) * | 2000-03-06 | 2001-09-11 | Toyobo Co Ltd | Near infrared absorption compound composition and near infrared absorption filter |
JP2001350013A (en) * | 2000-04-06 | 2001-12-21 | Mitsubishi Chemicals Corp | Filter for plasma display panel |
JP2004238606A (en) * | 2002-12-10 | 2004-08-26 | Mitsubishi Chemicals Corp | Squalirium-based compound, squalirium-based pigment and optical filter given by using the same |
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