KR100776538B1 - Production method and apparatus for ozonide(peroxide)-containing oil - Google Patents

Abstract

An apparatus and a method for preparing an oil are provided to obtain the oil containing large amount of ozonide and peroxide in an active oxygen form by generating ozone in the oil without direct injection of ozone-oxygen gas. An apparatus for preparing an oil containing ozonide and peroxide comprises a container(1); an oil storage tank(2) which is connectively installed at a pipe at the upper one side of the container to allow oil to be flown-in; a vacuum pump(4) which is connectively installed at a pipe at the other upper side of the container to reduce the pressure in the container; an oxygen supplying device installed at one side of the container; an outlet which is connectively installed at a pipe at lower one side of the container; an observing window(5) installed at the center portion of a body in the container; an ultraviolet lamp(6) installed at the bottom in the container; and a vibration device installed at the lower of the container. A method for preparing an oil containing ozonide and peroxide comprises the steps of: (a) after making the inside of the container in a vacuum state by injecting 30L of macadamia oil into a closely sealed container and then completely removing air from the container by operating the vacuum pump, injecting medical oxygen with 99.9% purity through the oxygen supplying device into the container; and (b) operating the vibration device to make so many fine bubbles of oxygen in the oil by mixing the oil and oxygen, wherein the ozone generated by one hour operation of the ultraviolet lamp and two hours operation of the vibration device allows to be reacted with the oil and the ozone is generated by the fine-bubbles of oxygen absorbing the energy at the length of 184.9 nm and reacts with the oil to mix the oil with pure oxygen so that 30L of oil contains 3 grams of ozone and 1ml of the oil contains 100mug of the ozone.

Description

Apparatus for producing oil formulation containing ozonate and peroxide and its manufacturing method {production method and apparatus for ozonide (peroxide) -containing oil}

Figure 1 contains the ozonide and peroxide of the present invention

Oil Manufacturing Equipment

Explanation of symbols in the drawings

Vessel (1), oil storage tank (2), outlet (3), vacuum pump (4), outlet (5), ultraviolet lamp (6), vibrator (7), oxygen supply (8).

The present invention is a method for preparing an oil formulation containing a large amount of ozone and peroxide in the form of active oxygen in various natural vegetable oils such as olive oil, macadamia oil, castor oil and jojoba oil.

Until now, when making such oil preparations, ozone in the form of oxygen-ozone gas is directly dissolved in natural vegetable oils to prepare ozonized oils containing a large amount of peroxides and ozones and used as raw materials for cosmetics. In the International Cosmetic Raw Materials Collection (IDIC), olive oil, jojoba oil, sunflower seed oil and ozonated oil using castor oil are listed as cosmetic raw materials.

Although there are patents on the device and manufacturing method for three ozonated oils in Korea, all three methods are directly injecting ozone gas into natural vegetable oil. These ozonated oils have a unique function of ozonated oil by generating a large amount of ozone and peroxide in the form of active oxygen.

The present invention relates to an apparatus and a method for producing an oil formulation containing ozone in a large amount of peroxide and ozone, without directly injecting ozone gas into the natural vegetable oil.

The present invention, in order to solve the problems as described above, the present applicant filed in the domestic patent application No. 10-2004-92533 (Registration No. 10-480963), the name of the invention manufacturing agent for oil preparation containing low concentration ozone And an improved method of producing an ozone oil by directly injecting ozone-oxygen gas into natural vegetable oil, whereas ozone is generated in the oil without directly injecting ozone-oxygen gas to form an active oxygen. It is a technical object of the present invention to provide a manufacturing apparatus for producing an oil formulation containing a large amount of ozonide and peroxide, and a preparation method thereof.

In order to achieve the above object, the present invention is a container (1), the oil storage tank (2) which is connected to the pipe on the upper side of the container is introduced into the oil, the pipe of the other upper one side of the container (1) A vacuum pump (4) connected to the vessel and reducing pressure in the vessel, an oxygen supply device (8) installed at one upper side of the vessel (1), and an outlet (3) installed at one side of the lower portion of the vessel (1); A large amount of ozonide composed of an observation field 5 installed at the center of the body in the container, an ultraviolet lamp 6 installed at the bottom of the container, and a vibrator 7 installed at the bottom of the container 1; The present invention relates to an oil preparation apparatus containing peroxide and a method for producing the same.

Ultraviolet lamps installed on the inner bottom of the sealed container 1 must emit ultraviolet rays of 184.9 nm. In general, UV lamps are widely used for sterilization, with 253.7 nm germicidal lamps being used for sterilization, but UV rays of 184.9 nm generate ozone.

Ultraviolet rays generated from installed UV lamps are classified into two wavelengths. The energy of 185nm is absorbed by oxygen and forms ozone to oxidize organic materials. The energy of 254nm is absorbed by organic materials, increasing their molecular activity and reacting with ozone.

The amount of ozone generated at this time depends on the amount of ultraviolet light emitted by the UV lamp, which can generate as little as 10 ppm per hour to as much as 7.2 g of ozone per hour. For example, if the output of UV light is 15uw / ㎠, 10ppm of ozone is produced per hour, if the output of UV light is 85um / ㎠, 2.3g of ozone is produced per hour; This depends on the power of the ultraviolet light and the tube length of the UV lamp. An ultraviolet lamp is installed on the inner bottom of the container (1) that can generate 3-4 g of ozone per hour.

Ozone generated in oil reacts directly with fatty acids contained in oil, and reacts with double bonds of unsaturated fatty acids having a double bond structure among carbon atoms in fatty acids. Almost all natural vegetable oils are 50-60% oleic acid and 15-20% palmitoleic acid, which is a monounsaturated fatty acid with a single double bond structure, which is a complete component Oleic acid has a double bond structure between carbon atoms 9 and 10, and ozone is combined to form ozone.

CH ₃ (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -COOH

  Oleic acid

Linoleic acid, which is an essential fatty acid, is 2 to 3% of the total, which has two double bond structures, and Arachidonic acid has four double bond structures. Ozone reacts with the bond to form an ozone such as C ₁₀ H ₁₈ O ₃ , or C ₉ H ₁₇ O ₃ .

CH ₃ (CH ₂ ) ₄ -CH = CH-CH ₂ -CH = CH- (CH ₂ ) ₇ -COOH

: Linoleic acid

CH ₃ (CH ₂ ) ₄ -CH = CH-CH ₂ -CH = CH-CH ₂ -CH = CH-CH ₂ -CH = CH- (CH ₂ ) ₃ -COOH

Arrachidonic acid

Since the ozone prepared in this way is an unstable structure, when there is other organic matter in the oil, it reacts with the organic material to generate peroxides, and thus many organic ozonates and organic peroxides are generated in the oil.

Hereinafter, the present invention will be described in detail with reference to Examples.

Example

After injecting 30 liters of macadamia oil of pure vegetable oil into the sealed container (1) and operating the vacuum pump (4) through a vacuum pipe to remove the air inside the container (1) to make a vacuum state, oxygen supply device (8 ) Fills the container with 99.9% pure medical oxygen,

By operating the vibrator (4) at the bottom of the container (1), oil and oxygen are mixed to create a large number of microbubbles of oxygen in the oil,

In this case, the UV lamp 5 is operated for 1 hour and the vibrator 4 is operated for 2 hours to allow the generated ozone to react sufficiently with the oil, while ozone is absorbed by the microbubble oxygen with the energy of 184.9 nm wavelength irradiated. This produced and reacted with the oil to prepare an oil formulation containing a large amount of peroxide and ozone in the oil.

(In a condition where 3.0g of ozone can be produced per hour, adding 30L of oil will contain 100ug of ozone per 1ml of oil.)

Experimental Example

(test results)

Currently, we are producing beauty moisturizing products for skin troubles using this technology (trade name; Atocap, Derma Free). The peroxide index of oil used as raw material for inspection results of products is 0.5 or less. The peroxide index measured after preparation was found to increase more than 6 times to 3,47 meq / kg and 3.11 meq / kg.

As a result of requesting from March 22, 2006, application number 63-0603-96, the Center for Science and Technology Analysis obtained the following results.

table

Test Items result Remarks Acid Sample 1 Sample 2 0.65 mgKOH / g 0.57 mgKOH / g Peroxide value 3.11 meq / kg 3.4meq / kg Normal: 0.5 or less

The peroxide product value represents the number of milligrams of active oxygen contained in 1000 g,

The test method was performed by mixing 5 g of a sample with a volume of 30 times (150 g) of glacial acetic and a volume of 20 times (100 g) of chloroform and 0.5 mL of saturated potassium iodine solution with 30 mL of water. After titration until 0.01 M sodium thiosulfate is yellow and almost gone, the hydrogen peroxide value is 10v / w obtained from the equation.

v is the amount of sodium thiosulfate titrated and w represents the g of the mixture.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

Figure 1 shows an oil preparation apparatus containing the ozone and peroxide of the present invention, a container (1), an oil storage tank (2), an outlet (3), a vacuum pump (4), an outlet (5), It can be seen that the ultraviolet lamp 6, the vibrator 7, the oxygen supply device 8 is shown.

Looking at the structure, as shown in Figure 1, the container (1), the oil storage tank (2) installed in a pipe connected to the upper side of the container (1), the oil flows, and the other upper portion of the container (1) A vacuum pump 4 connected to a pipe on one side to reduce the pressure in the container, an oxygen supply device 8 installed on one side of the container 1, and a lower side of the container 1 connected to the pipe. A discharge port 3, an observation window 5 provided at the center of the body in the container 1, an ultraviolet lamp 6 provided at the lower end of the container 1, and a vibration provided at the lower part of the container 1 It is a structure of an oil preparation apparatus containing a large amount of ozonide and peroxide composed of the apparatus 7.

Each connecting pipe connected to the container 1 is a corrugated tube in a portion in contact with the container 1 to prevent breakage of each device connected to the pipe when the container 1 vibrates by a vibrating device.

As described above, the present invention is an oil preparation that generates a large amount of peroxide and ozonate by directly generating ozone in oil without using ozone gas instead of the conventional method of directly using ozone. It can be used as a raw material for cosmetic moisturizers that can be used for dermatitis.

In the conventional method of directly injecting ozone-oxygen gas, an ozone generating apparatus of up to tens of thousands of won should be used, but the present invention has the greatest advantage that the product can be effectively produced using only an ultraviolet lamp of several hundred thousand won. In addition, the UV lamp can be adjusted to produce the desired amount of ozone in the oil.

Claims (3)

In the oil preparation apparatus, The oil storage tank 2 into which the oil is introduced by being connected to the pipe on the upper side of the container 1 and the container, and the vacuum pump that is connected to the pipe on the other upper side of the upper container 1 to reduce the pressure in the container. (4), an oxygen supply device (8) installed on one side of the container (1), an outlet (3) connected to a pipe on the lower side of the container (1), and a body in the center of the container (1) Contains a large amount of ozone and peroxide, characterized in that it consists of an observation window (5) installed, an ultraviolet lamp (6) installed at the bottom of the container (1), and a vibrator (7) installed at the bottom of the container (1). Oil preparation manufacturing apparatus. In the oil preparation method, After injecting 30 liters of macadamia oil of pure vegetable oil into the sealed container (1) and operating the vacuum pump (4) through the vacuum pipe to completely remove the air in the container (1) to make a vacuum state, oxygen supply device (8 ) Fills the container with 99.9% pure medical oxygen, By operating the vibrator (4) at the bottom of the container (1), oil and oxygen are mixed to create a large number of microbubbles of oxygen in the oil, In this case, the UV lamp 5 is operated for 1 hour and the vibrator 4 is operated for 2 hours so that the generated ozone reacts with the oil. As the bubbled oxygen absorbs the energy of 184.9 nm wavelength irradiated , the ozone is released. As it forms and reacts with the oil, pure oxygen is mixed with the oil in the container, and 30L of oil contains 3g of ozone and contains a large amount of ozonide and peroxide, which is manufactured to contain 100ug of ozone per 1ml of oil. Oil preparation method. delete

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