KR100770177B1 - A algal bloom treatment method in water treatment plant - Google Patents

A algal bloom treatment method in water treatment plant Download PDF

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KR100770177B1
KR100770177B1 KR1020010083436A KR20010083436A KR100770177B1 KR 100770177 B1 KR100770177 B1 KR 100770177B1 KR 1020010083436 A KR1020010083436 A KR 1020010083436A KR 20010083436 A KR20010083436 A KR 20010083436A KR 100770177 B1 KR100770177 B1 KR 100770177B1
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algae
water treatment
activated carbon
chlorine
forced
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KR20030053260A (en
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문정기
김태훈
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주식회사 포스코
재단법인 포항산업과학연구원
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
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Abstract

본 발명은 정수처리시스템에서의 조류 처리방법에 관한 것으로, 보다 상세하게는 정수 원수를 침사지, 강제침전조 및 여과지를 순차적으로 통과시키는 정수처리시스템에 있어서, 침사지 전단에 염소를 투입하고, 강제침전지에 분말활성탄을 포함하는 슬러지층을 유지되게 하는 것을 특징으로 하는 정수처리시스템에서의 조류 처리방법에 관한 것이다.The present invention relates to a method for treating algae in a water treatment system, and more particularly, in a water treatment system in which purified water is passed through a sedimentation basin, a forced sedimentation tank, and a filter paper, in which chlorine is introduced to a front end of the settlement and a forced sedimentation cell. The present invention relates to a method for treating algae in a water treatment system, characterized by maintaining a sludge layer containing powdered activated carbon.

본 발명의 조류 처리방법에 의하면 강제침전지 방식을 수용하는 정수장에서 조류에 의한 여과사 막힘 및 악취발생과 같은 이차오염 없이 경제적으로 처리할 수 있다.According to the algae treatment method of the present invention can be economically treated without secondary pollution, such as clogged filter sand by the algae and odor generation in a water purification plant that accepts forced sedimentation method.

조류제거, 정수처리, 염소, 분말활성탄, 강제침전지, 슬러지층Algae removal, purified water treatment, chlorine, activated carbon, forced sedimentation, sludge layer

Description

정수처리시스템에서의 조류 처리방법{A ALGAL BLOOM TREATMENT METHOD IN WATER TREATMENT PLANT}Algae BLOOM TREATMENT METHOD IN WATER TREATMENT PLANT

도 1은 본 발명의 조류 처리방법을 실제 강제침전지 형식의 정수장에 적용하는 방법을 도시한 것이다.1 illustrates a method of applying the algae treatment method of the present invention to a water purification plant of an actual forced sedimentation type.

도 2는 본 발명에 따른 실시예 1 및 종래 비교예 2의 조류 처리율을 나타낸 것이다.Figure 2 shows the algae treatment rate of Example 1 and Comparative Example 2 according to the present invention.

[발명이 속하는 기술분야][TECHNICAL FIELD OF THE INVENTION]

본 발명은 정수처리시스템에서의 조류 처리방법에 관한 것으로, 보다 상세하게는 조류에 의한 여과사 막힘 및 악취발생을 이차오염 없이 경제적으로 처리할 수 있도록 정수 원수를 침사지, 강제침전조 및 여과지를 순차적으로 통과시키는 정수처리시스템에 있어서, 침사지 전단에 염소를 투입하고, 강제침전지에 분말활성탄을 포함하는 슬러지층을 유지되게 하는 것을 특징으로 하는 정수처리시스템에서의 조류 처리방법에 관한 것이다.The present invention relates to a method for treating algae in a water treatment system, and more particularly, in order to economically treat the clogged filter sand and odor generation caused by algae without secondary pollution, the raw water is sequentially settled, forced sedimentation tank and filter paper. In a water treatment system for passing, chlorine is introduced into the front of the settlement, and a sludge layer containing powdered activated carbon is maintained in the forced sedimentation system.

[종래기술] [Private Technology]                         

정수장에서 조류가 대량으로 번식시 이를 제거하기 위한 방법으로 전염소를 처리하는 방법이 있다. 그러나 전염소 처리방법은 그다지 효과적이지 못하다. 그 이유는 발생된 조류의 종이나 번식정도에 따라서 조류가 전염소 투입으로 인해 사멸되면서 세포벽이 파괴되어 세포질이 수중으로 용출됨으로 침점전효율을 오히려 저해하고 악취발생을 가속시키는 문제점을 야기시키는 문제점이 있다.The whole chlorine is treated as a way to remove algae when they are reproduced in large quantities. But the whole chlorine treatment is not very effective. The reason for this is that the algae are killed by the introduction of whole chlorine and the cell wall is destroyed and the cytosol is eluted in water according to the species of the algae and breeding. have.

조류를 제거하기 위한 다른 방법으로는 분말활성탄을 처리하는 경우가 있다. 그러나 분말활성탄을 처리하는 것을 다량의 활성탄 투입이 필요함으로 경제성이 떨어진다는 문제점과 실질적으로 여과사 막힘을 해결하지 못하는 문제점이 있다.Another method for removing algae is the treatment of powdered activated carbon. However, the treatment of powdered activated carbon requires a large amount of activated carbon input, and thus, economical efficiency is low, and there is a problem that substantially does not solve the clogged filter sand.

또 다른 방법으로 전염소와 분말활성탄을 동시에 투입하는 경우가 있으나, 이 경우 투입된 염소와 분말활성탄이 반응하여 약품비용의 상승을 초래하는 문제점이 있다. 이와 같은 현상이 발생하는 이유는 일반적인 정수장의 경우 침전지의 형식이 장방형의 경사판 침전지나 자연유하식 침전지 형식을 취함으로 전염소와 분말활성탄이 각각의 장점을 발휘할만한 접촉시간을 확보하지 못하며, 분말활성탄의 경우 치전지에서 계속적으로 침전되어 슬러지 형태로 제거됨으로 인해 그 투입량이 많아야 한다는 것에 기인한다.In another method, all chlorine and powdered activated carbon may be simultaneously added, but in this case, the chlorine and the powdered activated carbon may react, resulting in an increase in chemical cost. The reason for this phenomenon is that in the case of general water treatment plant, the sedimentation basin takes the form of a rectangular inclined plate sedimentation basin or a naturally-flowing sedimentation basin, which does not secure contact time for all chlorine and powdered activated carbon to achieve their respective advantages. This is due to the amount of the input should be large because it is continuously precipitated in the battery and removed in the form of sludge.

또한 정수장에서의 조류제거를 위한 공지기술로 대한민국 특허공개 제2001-48831호와 제2001-10801호가 있다. 이들은 각각 생물막 여과공법과 용존 공기 부상법을 이용하여 조류를 제거하는 방법을 개시하고 있으나 염소처리 또는 분말활성탄의 이용에 대하여는 개시되어 있지 않다. In addition, Korean Patent Publication Nos. 2001-48831 and 2001-10801 are known technologies for removing algae from water purification plants. They disclose methods for removing algae using biofilm filtration and dissolved air flotation, respectively, but do not disclose the use of chlorine treatment or powdered activated carbon.

본 발명은 상기 종래 기술의 문제점을 해결하기 위하여 안출된 것으로서, 강제침전지 방식을 수용하는 정수장에서 번식종류의 종에 관계없이 효과적으로 조류를 제거할 수 있는 방법을 제공하는 것을 목적으로 한다. The present invention has been made to solve the problems of the prior art, and an object of the present invention is to provide a method capable of effectively removing algae regardless of breeding species in a water purification plant that accommodates forced sedimentation.

또한 본 발명은 조류로 인한 여과사 막힘과 악취발생을 해결할 수 있는 강제침전지 방식을 수용한 정수처리시스템을 제공하는 것을 목적으로 한다.In addition, an object of the present invention is to provide a water treatment system that accommodates forced sedimentation method that can solve the clogged filter sand and odor generated by algae.

상기 목적을 달성하기 위하여, 본 발명은 정수 원수를 침사지, 강제침전조 및 여과지를 순차적으로 통과시키는 정수처리시스템에 있어서,In order to achieve the above object, the present invention provides a purified water treatment system for sequentially passing the purified water through the settling paper, forced sedimentation tank and filter paper,

침사지 전단에 염소를 투입하고, 강제침전지에 분말활성탄을 포함하는 슬러지층을 유지되게 하는 것을 특징으로 하는 정수처리시스템에서의 조류 처리방법을 제공한다.The present invention provides a method for treating algae in a water treatment system, in which chlorine is added to a front of a settlement and a sludge layer including powdered activated carbon is maintained in a forced settlement.

또한 본 발명은 조류 처리방법이 구비된 정수처리시스템을 제공한다.In another aspect, the present invention provides a water treatment system equipped with an algae treatment method.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명은 정수 원수를 침사지, 강제침전조 및 여과지를 순차적으로 통과시키는 정수처리시스템에 있어서, 침사지 전단에 염소를 투입하고, 강제침전지에 분말활성탄을 포함하는 슬러지층을 유지되게 하는 것을 특징으로 한다.The present invention is characterized in that chlorine is introduced to the front end of the settlement and the sludge layer containing the powdered activated carbon is maintained in the forced settlement.

본 발명에서 염소의 투입은 정수 원수가 정수시스템에 유입되는 부분인 침사지 전단에서 투입된다. 투입된 염소에 의하여 조류가 사멸되며, 투입된 염소는 침사지에서 충분히 반응을 한 뒤 강제침전지로 넘어가게 된다. 상기 염소의 투입은 염소가스(Cl2)를 투입하는 것이 바람직하며, 0.7 내지 1.5 ppm의 농도로 투입하면 더욱 좋다. 상기 염소의 농도가 0.7 ppm 미만이면 조류의 사멸이 잘 이루어지지 않으며, 1.5 ppm을 초과하면 경제성이 떨어진다.In the present invention, the input of chlorine is introduced at the front of the settling basin which is the portion of the purified water flowing into the water purification system. Algae are killed by the injected chlorine, and the injected chlorine reacts sufficiently in the sedimentation basin and is then passed to the forced settler. The chlorine is preferably added to the chlorine gas (Cl 2 ), it is better to add a concentration of 0.7 to 1.5 ppm. When the concentration of the chlorine is less than 0.7 ppm, algae are not killed well, and when it exceeds 1.5 ppm, economic efficiency is low.

침사지에서 충분히 염소와 반응을 한 정수는 강제침전지로 넘어가게 된다. 본 발명에서의 강제침전지는 침전지 내에 분말활성탄을 포함하는 슬러지층(sludge blanket)이 형성되어 있다. 상기 슬러지층은 초기에 다량의 분말활성탄을 투입하여 이루어진다.The purified water, which has reacted sufficiently with chlorine in the sediment, is passed on to the forced settler. In the forced precipitate in the present invention, a sludge blanket containing powdered activated carbon is formed in the sedimentation basin. The sludge layer is initially made by adding a large amount of powdered activated carbon.

강제침전지에 유입된 정수는 하부에서부터 슬러지층을 통과하여 상층으로 올라오면서 수중의 부유물이 제거된다. 본 발명에서는 강제침전지에서 정수가 하부에서 상층으로 올라오게 됨으로써 분말활성탄과의 접촉시간이 충분히 유지된다. 바람직하게는 상기 강제침전지는 슬러지 층에 함유된 활성탄이 부유물질이 흡착됨에 따라 슬러지층에서 강제침전지의 하부로 이동하게 되며, 하부로 이동한 활성탄은 제거되며, 제거되는 만큼의 활성탄만큼만을 슬러지층 상부에 넣어주는 슬러지 순환형 강제침전지가 좋다. 슬러지 순환형 강제침전지는 침전지에 형성된 슬러지 층이 장시간 체류하게 되며, 투입된 분말활성탄이 슬러지 층을 구성함으로 염소의 작용이 충분히 이루어진 후에 분말활성탄에 의한 흡착이 시작되므로 분말활성탄과 염소 사이의 상호간에 간섭현상이 없게 된다.The purified water flowing into the forced sediment is passed through the sludge layer from the bottom to the upper layer to remove the suspended matter in the water. In the present invention, the purified water is raised from the bottom to the upper layer in the forced sedimentation, thereby maintaining sufficient contact time with the powdered activated carbon. Preferably, the forced sedimentation is activated carbon contained in the sludge layer is moved to the lower portion of the forced sedimentation in the sludge layer as the suspended solids adsorbed, the activated carbon moved to the lower portion is removed, only as much activated carbon as the sludge layer Sludge circulating forced sediment that is put on the top is good. In the sludge circulation type forced sedimentation, the sludge layer formed in the sedimentation basin stays for a long time, and the activated powder activated carbon constitutes the sludge layer, so that the adsorption by the powder activated carbon starts after sufficient action of chlorine, thus interfering with each other between the powdered activated carbon and chlorine. There is no phenomenon.

본 발명에서 강제침전지의 슬러지 층의 분말활성탄의 농도는 70 내지 150 ppm의 농도로 유지시키는 것이 바람직하다. 상기 분말활성탄의 농도가 70 ppm 미 만이면 조류 흡착력이 미미하며, 150 ppm을 초과하면 경제성이 떨러진다.In the present invention, the concentration of the powdered activated carbon in the sludge layer of the forced sedimentation is preferably maintained at a concentration of 70 to 150 ppm. When the concentration of the powdered activated carbon is less than 70 ppm, the algae adsorption power is insignificant, and when the concentration of the powdered activated carbon is more than 150 ppm, economic efficiency is reduced.

상기 강체침전지의 상부로 올라온 정수는 여과지를 거치게 된다.The purified water that has risen to the top of the rigid needle battery passes through the filter paper.

또한 본 발명은 상기 조류처리방법이 구비된 정수처리시스템을 제공하는 바, 본 발명의 정수처리시스템은 염소처리와 분말활성탄에 의한 처리가 상호간섭 없이 효과적으로 이루어지게 됨으로써 조류로 인한 여과사막힘과 악취발생이 방지된다.In addition, the present invention provides a water treatment system equipped with the algae treatment method, the water treatment system of the present invention is treated by chlorine treatment and powdered activated carbon is effectively made without mutual interference filter deadlock and odor due to algae Occurrence is prevented.

이하 본 발명의 실시예를 기재한다. 그러나 하기 실시예는 본 발명을 예시하기 위한 것으로서 본 발명이 하기 실시예에 한정되는 것은 아니다.Hereinafter, examples of the present invention will be described. However, the following examples are intended to illustrate the invention and the present invention is not limited to the following examples.

[실시예 1]Example 1

정수 원수를 침사지, 강제침전조를 순차적으로 통과시키되, 침사지 전에 염소가스를 1 ppm의 농도로 투입하고, 강제침전조에는 100 ppm의 분말활성탄을 포함하는 슬러지층을 형성시켜 정수를 처리하였다.The purified water was passed through a settling basin and a forced sedimentation tank sequentially, but chlorine gas was introduced at a concentration of 1 ppm before the settling basin, and a sludge layer containing 100 ppm of powdered activated carbon was formed in the forced sedimentation tank to treat purified water.

[비교예 1]Comparative Example 1

상기 실시예 1과 동일하게 염소처리를 하되, 강제침전조에서는 분말활성탄을 포함하는 슬러지 층이 없이 정수를 처리하였다. 이 경우 악취가 매우 심하게 발생하였다.Chlorine treatment was performed in the same manner as in Example 1, but in the forced precipitation tank, the purified water was treated without a sludge layer containing powdered activated carbon. Odor was very bad in this case.

[비교예 2]Comparative Example 2

강제침전조에 염소와 분말활성탄을 동시에 투입하였다. 투입량은 상기 실시예 1과 동일하게 하였다.Chlorine and powdered activated carbon were simultaneously added to the forced sedimentation tank. The charged amount was the same as in Example 1.

상기 실시예 1 및 비교예 1 내지 2의 조류 제거율을 도 2에 나타내었다. 이때, 조류의 양은 일반적으로 이용하는 클로로필-a의 양을 측정하여 표시하였다. Algae removal rates of Example 1 and Comparative Examples 1 and 2 are shown in FIG. 2. At this time, the amount of algae was indicated by measuring the amount of chlorophyll-a generally used.                     

도 2의 결과에서 보면, 실시예 1의 경우 조류는 90% 이상 제거됨을 알 수 있다. 반면, 비교예 1 및 2의 경우 조류 제거율이 75% 정도로 본 발명에서 제시한 방법에 비해 상대적으로 처리효율이 저조함을 알 수 있다.In the results of Figure 2, in the case of Example 1 it can be seen that algae are removed more than 90%. On the other hand, Comparative Examples 1 and 2 can be seen that the treatment efficiency is relatively low compared to the method proposed in the present invention as the algae removal rate of about 75%.

이상에서 상세히 살펴본 바와 같이, 본 발명의 조류 처리방법에 의하면 강제침전지 방식을 수용하는 정수장에서 조류에 의한 여과사 막힘 및 악취발생과 같은 이차오염 없이 경제적으로 처리할 수 있다.As described in detail above, according to the algae treatment method of the present invention can be economically treated without secondary pollution, such as clogged filter sand and odor caused by algae in a water purification plant that accommodates forced sedimentation.

Claims (3)

정수 원수를 침사지, 강제침전조 및 여과지를 순차적으로 통과시키는 정수처리시스템에 있어서,In the purified water treatment system for passing the purified water through the sedimentation basin, forced sedimentation tank and filter paper sequentially, 침사지 전단에 염소를 투입하고, 강제침전지에 분말활성탄을 포함하는 슬러지층을 유지되게 하는 것을 특징으로 하는 정수처리시스템에서의 조류 제거방법.A method for removing algae in a water treatment system, characterized in that chlorine is introduced in the front of a settlement and a sludge layer containing powdered activated carbon is maintained in a forced settlement. 제 1항에 있어서, The method of claim 1, 상기 염소의 농도는 0.7 내지 1.5 ppm이고, 상기 분말활성탄의 농도는 70 내지 150 ppm인 정수처리시스템에서의 조류 제거방법.The concentration of the chlorine is 0.7 to 1.5 ppm, the concentration of the powdered activated carbon is 70 to 150 ppm algae removal method in a water treatment system. 제 1항 또는 제 2항의 조류 제거방법이 구비된 정수처리시스템.A water treatment system equipped with the algae removal method of claim 1.
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JP2693616B2 (en) * 1990-02-28 1997-12-24 阪神水道企業団 Advanced treatment method for clean water
JP2000167563A (en) * 1998-09-28 2000-06-20 Ebara Corp Method and apparatus for disinfecting waste water
JP2001276892A (en) * 2000-03-31 2001-10-09 Yoshikimi Watanabe Drain treatment device

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JP2000167563A (en) * 1998-09-28 2000-06-20 Ebara Corp Method and apparatus for disinfecting waste water
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