KR100711445B1 - A method for manu- facturing alloyed hot dip galvanized steel sheet for hot press forming having excellent plating adhesion and impact property, the method for manufacturing hot press parts made of it - Google Patents
A method for manu- facturing alloyed hot dip galvanized steel sheet for hot press forming having excellent plating adhesion and impact property, the method for manufacturing hot press parts made of it Download PDFInfo
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- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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Abstract
자동차 차체의 구조부재나 보강재로 주로 사용되고, 도금밀착성 및 충격특성이 우수한 열간성형 가공용 합금화 용융아연도금강판의 제조방법 및 이 강판을 이용한 열간성형부품의 제조방법이 제공된다.A method for producing an alloyed hot-dip galvanized steel sheet for hot forming, which is mainly used as a structural member or reinforcing material of an automobile body, and has excellent plating adhesion and impact characteristics, and a method for manufacturing hot formed parts using the steel sheet is provided.
이 강판의 제조방법은 중량%로, C: 0.1~0.5%, Si: 0.01~1.0%, Mn: 2.0~4.0%, P: 0.1% 이하, S: 0.03% 이하, 가용 Al: 0.1% 이하, N: 0.01~0.1%, W: 0.1% 이하, 나머지 Fe 및 기타 불가피한 불순물로 조성되는 강 슬라브를 1100~1300℃에서 재가열하고, Ar3 변태점 이상 1000℃ 이하에서 열간마무리압연을 종료한 다음, 500~750℃에서 권취하고, 산세 및 냉간압연한 다음, 450~470℃ 온도범위에서 10초 이하 동안 용융아연도금을 행하고, 상온까지 냉각한 다음 440~580℃의 온도범위에서 30초 이하로 합금화열처리를 행한다. The manufacturing method of this steel sheet is weight%, C: 0.1-0.5%, Si: 0.01-1.0%, Mn: 2.0-4.0%, P: 0.1% or less, S: 0.03% or less, soluble Al: 0.1% or less, Steel slabs composed of N: 0.01 to 0.1%, W: 0.1% or less, remaining Fe and other unavoidable impurities are reheated at 1100 to 1300 ° C, and hot finish rolling is finished at Ar 3 transformation point or more and 1000 ° C or less, and then 500 Winding at ~ 750 ℃, pickling and cold rolling, then hot dip galvanizing for 10 seconds or less in the temperature range of 450 ~ 470 ℃, cooled to room temperature and then heat treatment alloying for 30 seconds or less in the temperature range of 440 ~ 580 ℃ Is done.
본 발명에 따르면, 도금밀착성이 우수하고, 열간성형 후 1470MPa 이상의 초고강도 및 도장 후 100MPa 이상의 항복강도 변화율을 갖는 열간성형 가공용 합금화 용융아연도금강판의 제조방법 및 이 강판을 이용한 열간성형부품의 제조방법을 제공할 수 있다.According to the present invention, a method for producing an alloyed hot-dip galvanized steel sheet for hot forming processing having excellent plating adhesion, ultrahigh strength of 1470 MPa or more after hot forming, and yield strength change of 100 MPa or more after coating, and a method of manufacturing hot formed parts using the steel sheet Can be provided.
자동차 구조부재, 보강재, 도금밀착성, 합금화 용융아연도금강판, 충격특성 Automobile structural member, reinforcement, plating adhesion, alloyed hot dip galvanized steel sheet, impact characteristics
Description
국내 공개특허공보 2005-0062194호Korean Unexamined Patent Publication No. 2005-0062194
국내 공개특허공보 2003-0049731호Korean Unexamined Patent Publication No. 2003-0049731
일본 공개특허공보 2005-126733호Japanese Laid-Open Patent Publication 2005-126733
본 발명은 자동차 차체의 구조부재나 보강재로 주로 사용되는 강판의 제조방법에 관한 것이다. 보다 상세하게는 도금밀착성이 우수하고, 열간성형 후 1470MPa 이상의 초고강도와 도장 후 100MPa 이상의 항복강도 변화율을 갖는 열간성형 가공용 합금화 용융아연도금강판의 제조방법 및 이 강판을 이용한 열간성형부품의 제조 방법에 관한 것이다.The present invention relates to a method for producing a steel sheet mainly used as a structural member or reinforcement of an automobile body. More specifically, the method for producing a hot-dip alloyed hot-dip galvanized steel sheet having excellent plating adhesion, ultra-high strength of 1470 MPa or more after hot forming, and yield strength change of 100 MPa or more after coating, and a method of manufacturing hot formed parts using the steel sheet It is about.
최근 자동차 승객의 안전성 규제가 확산되면서 차체의 내충격성 향상을 위하여 차체 경량화 및 이에 따른 고강도 강판의 연구가 진행되고 있다. 그러나, 자동차용 강판의 고강도화는 강판의 성형성을 현저하게 저하시키는 문제점을 가지고 있다. Recently, as safety regulations of automobile passengers have spread, research on lightweighting the vehicle body and high strength steel plate accordingly has been conducted to improve impact resistance of the vehicle body. However, increasing the strength of automotive steel sheets has a problem of significantly lowering the formability of steel sheets.
이와 같은 문제점을 해결하기 위하여 성형성이 우수한 고강도 강판의 제조방법이 국내 공개특허공보 2005-0062194호에 제시되어 있다. 상기 종래기술은 잔류 오스테나이트의 마르텐사이트 변태를 이용한 TRIP(Transformation Induced Plasti- city) 강판으로서, 인장강도 980MPa급의 성형성이 우수한 강판을 제조할 수 있다. 그러나, 그 이상의 강도를 확보하기 위해서는 C, Mn 등의 원소를 첨가해야 하며, 이로 인한 제조비용 문제가 발생하고 또한, 초고강도 강판을 프레스 성형할 때 높은 강도로 인한 형상 동결성 열위 및 금형 손상 등의 제조상의 문제가 발생한다.In order to solve such a problem, a method of manufacturing a high strength steel sheet having excellent formability is proposed in Korean Unexamined Patent Publication No. 2005-0062194. The prior art is a transformation induced plasma (TRIP) steel sheet using the martensite transformation of the retained austenite, it is possible to manufacture a steel sheet excellent in formability of 980MPa class tensile strength. However, in order to secure more strength, elements such as C and Mn must be added, and thus, manufacturing cost problems occur, and shape freezing inferiority due to high strength and mold damage due to high strength when forming ultra high strength steel sheet A manufacturing problem occurs.
이와 같은 문제를 개선하기 위한 종래기술로는 국내 공개특허공보 2003-0049731호와 일본 공개특허공보 2005-126733호가 있다. 상기 종래기술들 중 국내 공개특허공보 2003-0049731호에서는 열처리 전의 낮은 강도와 높은 가공성을 이용하여 오스테나이트 단상역에서 열처리 및 프레스 성형을 행한 후, 금형에 의한 빠른 냉각을 실시함으로써 최종 제품에서 초고강도 냉연강판을 얻는 제조방법을 제 공하였다. 또한, 상기 종래기술 일본 특허공개번호 2005-126733호에서는 Mo, Nb을 단독 또는 복합으로 첨가함으로써 고온가공성이 우수한 열간 프레스용 강판을 제조하고 있다. Conventional techniques for improving such a problem include Korean Laid-Open Patent Publication No. 2003-0049731 and Japanese Laid-open Patent Publication 2005-126733. In Korean Patent Laid-Open Publication No. 2003-0049731 of the prior arts, after performing heat treatment and press molding in an austenitic single phase region using low strength and high workability before heat treatment, ultra-high strength in a final product is performed by rapid cooling by a mold. Provided is a method for producing a cold rolled steel sheet. In addition, Japanese Patent Laid-Open No. 2005-126733 discloses a hot press steel sheet having excellent high temperature workability by adding Mo and Nb alone or in combination.
그러나, 상기 종래기술들은 열간성형 가공 후, 인장강도를 향상시키는 데에 중점을 두고 있으며, 도장 후 항복강도 상승에 의한 충격특성 확보 방안에 대해서는 기술적 한계를 가지고 있다.However, the prior arts focus on improving tensile strength after hot forming, and have technical limitations on the method of securing impact characteristics by increasing yield strength after coating.
본 발명은 상기한 종래의 문제점을 개선하기 위한 것으로, 비교적 저온에서 열간성형을 실시함으로써 우수한 도금밀착성을 확보하고, 복잡한 형상의 제품으로 가공한 후 급냉을 실시하여 높은 인장강도를 확보한 후 도장 열처리 후 높은 항복강도 상승을 일으켜 우수한 충격특성을 확보한 열간성형 가공용 합금화 용융아연도금강판의 제조방법과 이 강판을 이용한 열간성형 부품의 제조방법을 제공하는데, 그 목적이 있다.The present invention is to improve the above-mentioned conventional problems, by performing hot forming at a relatively low temperature to secure excellent plating adhesion, processing into a product of a complex shape and then quenching to secure high tensile strength after coating heat treatment The present invention provides a method for producing an alloyed hot-dip galvanized steel sheet for hot forming which has a high yield strength increase and secures excellent impact characteristics, and a method for producing a hot formed part using the steel sheet.
상기한 목적을 달성하기 위한 본 발명은, 중량%로, C: 0.1~0.5%, Si: 0.01~1.0%, Mn: 2.0~4.0%, P: 0.1% 이하, S: 0.03% 이하, 가용 Al: 0.1% 이하, N: 0.01~0.1%, W: 0.1% 이하, 나머지 Fe 및 기타 불가피한 불순물로 조성되는 강 슬라 브를 1100~1300℃에서 재가열하고, Ar3 변태점 이상 1000℃ 이하에서 열간마무리압연을 종료한 다음, 500~750℃에서 권취하고, 산세 및 냉간압연한 다음, 450~470℃ 온도범위에서 10초 이하 동안 용융아연도금을 행하고, 상온까지 냉각한 다음 440~580℃의 온도범위에서 30초 이하로 합금화열처리를 행하는 도금밀착성 및 충격특성이 우수한 열간성형 가공용 합금화 용융아연도금강판의 제조방법에 관한 것이다.The present invention for achieving the above object, in weight%, C: 0.1-0.5%, Si: 0.01-1.0%, Mn: 2.0-4.0%, P: 0.1% or less, S: 0.03% or less, soluble Al : 0.1% or less, N: 0.01% to 0.1%, W: 0.1% or less, steel slab composed of remaining Fe and other unavoidable impurities is reheated at 1100 to 1300 ° C, hot rolled at an Ar 3 transformation point or more and 1000 ° C or less. After finishing, wound at 500 ~ 750 ℃, pickling and cold rolling, and then hot dip galvanized for 10 seconds or less in the temperature range of 450 ~ 470 ℃, cooled to room temperature and then in the temperature range of 440 ~ 580 ℃ The present invention relates to a method for producing an alloyed hot-dip galvanized steel sheet for hot forming, which has excellent plating adhesion and impact characteristics, which is subjected to alloying heat treatment in 30 seconds or less.
또한, 본 발명은 상기의 방법으로 제조된 합금화 용융아연도금강판을 700~850℃ 온도범위로 1~100℃/초의 속도로 승온하고 10~1000초 유지하여 열간성형한 후 이어 10~500℃/초의 속도로 급냉하는 도금밀착성 및 충격특성이 우수한 열간성형 부품의 제조방법에 관한 것이다.In addition, the present invention is heated to a temperature of 1 ~ 100 ℃ / sec to 700 ~ 850 ℃ temperature range of the alloyed hot-dip galvanized steel sheet prepared by the above method and maintained for 10 to 1000 seconds after hot forming 10 ~ 500 ℃ / The present invention relates to a method for manufacturing a hot formed part having excellent plating adhesion and impact characteristics which are rapidly cooled at a high speed.
이하, 본 발명을 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.
본 발명에서 '열간성형 부품'이란 용어는 강판을 일정형태로 가공한 가공물을 의미하는 것으로, 본 발명의 강이 갖는 물리적 특성을 이용할 수 있는 용도에 적용되는 모든 부품을 포함한다.In the present invention, the term 'hot formed part' refers to a workpiece obtained by processing a steel plate in a certain form, and includes all parts applied to applications in which the physical properties of the steel of the present invention can be used.
본 발명자는 열간성형 가공용 강판의 충격특성을 확보하기 위한 방안을 연구하던 중에, N를 적절히 첨가하면 도장 후 항복강도가 급격히 증가할 수 있다는 것 을 규명하였다. 즉, 열간성형 부품의 제조에 있어서 탄소를 적절히 첨가하여 가공 후 급냉과정에서 80% 이상의 마르텐사이트 조직을 확보함으로써 강도를 크게 향상시킨 강판에 대해 N를 적절히 첨가함으로써 도장 후 항복강도를 상승시켜 충격특성이 우수한 강판을 확보할 수 있다. The inventors of the present invention, while studying a method for securing the impact characteristics of the hot-formed steel sheet, it was found that the yield strength can be sharply increased after the addition of N properly. In other words, in the manufacture of hot-formed parts, by adding carbon appropriately and securing 80% or more martensite structure in the quenching process after processing, by adding N appropriately to the steel plate which greatly improved the strength, the yield strength after coating is increased to increase the impact characteristics. This excellent steel sheet can be secured.
또한, 본 발명은 상기 강판의 표면에 Zn도금을 행하여 비교적 저온에서 열간성형을 실시함으로써 우수한 도금밀착성을 확보할 수 있다는데 특징이 있는 것이다. 즉, 열간성형 가공 후 충분한 내식성을 확보하기 위해서 본 발명에서는 Zn도금을 행하는데, Zn도금층은 고온에서 열간성형할 경우 도금밀착성이 열화되어 강판의 내식성을 충분히 확보하지 못하는 문제점이 있다. 이러한 문제점을 해결하기 위하여 저온 열간성형에서도 충분한 강도를 확보하면서, 도금밀착성이 우수한 강판을 제조하는데 그 중요성이 있는 것이다.In addition, the present invention is characterized in that excellent plating adhesion can be ensured by performing Zn plating on the surface of the steel sheet and performing hot forming at a relatively low temperature. That is, in order to secure sufficient corrosion resistance after hot forming, Zn plating is performed in the present invention. However, when hot forming at a high temperature, the Zn plating layer has a problem in that the plating adhesion is degraded and sufficient corrosion resistance of the steel sheet is not obtained. In order to solve this problem, while maintaining sufficient strength even at low temperature hot forming, it is of importance to manufacture a steel sheet excellent in plating adhesion.
또한, 본 발명은 비교적 저온에서 복잡한 형상의 제품으로 가공한 후 급냉을 통해 고강도를 더욱 높이고자 경화능 향상원소인 Mo, Cr, B 등을 추가로 첨가할 수 있다. 먼저 본 발명의 강성분의 조성범위를 설명한다. In addition, the present invention may further add Mo, Cr, B and the like to improve the hardenability to further increase the high strength through rapid cooling after processing into a product of a complex shape at a relatively low temperature. First, the composition range of the steel component of the present invention will be described.
C: 0.1~0.5%가 바람직하다.C: 0.1 to 0.5% is preferable.
상기 C는 강판의 강도를 증가시키는 데 필수적인 원소로서, 오스테나이트 및 마르텐사이트 등의 경질상을 생성시키고, 인장강도 1470MPa 이상의 강도를 얻기 위 해서는 C의 함량을 0.1% 이상 첨가하여야 한다. 그 함량이 0.1% 미만인 경우 오스테나이트 단상역에서 열처리를 행하여도 목표로 하는 강도 확보가 어렵다. 또한, 0.5%를 초과하게 되면 인성 및 용접성의 저하가 발생될 가능성이 높아지고, 열연강판의 산세와 압연공정에서 강판의 용접을 어렵게 할 뿐만 아니라, 소둔 및 도금 공정에서 강판의 강도를 현저히 상승시킴으로써 강판의 통판성을 나쁘게 하는 등 제조공정에서 심각한 문제를 초래할 수 있다. 따라서, 상기 C의 함량은 0.1~0.5%로 제한하는 것이 바람직하다.The C is an essential element for increasing the strength of the steel sheet. In order to generate hard phases such as austenite and martensite, and to obtain a strength of 1470 MPa or more, the C content should be added at least 0.1%. If the content is less than 0.1%, it is difficult to secure the target strength even if heat treatment is performed in the austenitic single phase region. In addition, if the content exceeds 0.5%, the likelihood of deterioration of toughness and weldability increases, making it difficult to weld the steel sheet in the pickling and rolling process of the hot rolled steel sheet, and significantly increasing the strength of the steel sheet in the annealing and plating processes. This may cause serious problems in the manufacturing process, such as poor mailing performance. Therefore, the content of C is preferably limited to 0.1 to 0.5%.
Si: 0.01~1.0%가 바람직하다.Si: 0.01 to 1.0% is preferable.
상기 Si는 고용강화 원소로서 강판의 강도 상승에 기여한다. 그 함량이 0.01% 미만인 경우 열연강판의 표면 스케일(scale)을 제거하는데 어려운 반면, 1.0%를 초과하게 되면 제조원가를 상승시키는 문제점이 있으므로, 그 함량을 0.01~1.0%로 제한하는 것이 바람직하다.Si contributes to the increase in strength of the steel sheet as a solid solution strengthening element. If the content is less than 0.01%, it is difficult to remove the surface scale (scale) of the hot-rolled steel sheet, but if it exceeds 1.0%, there is a problem of increasing the manufacturing cost, it is preferable to limit the content to 0.01 ~ 1.0%.
Mn: 2.0~4.0%가 바람직하다.Mn: 2.0 to 4.0% is preferable.
상기 Mn은 고용강화 원소로 강도 상승에 크게 기여할 뿐만 아니라 오스테나이트에서 페라이트로의 변태를 지연시키는데 중요한 역할을 한다. 또한, Ac3온도를 낮추는 데 유용한 원소로서, 본 발명에서 매우 중요한 도금밀착성을 향상시키기 위해서는 열간성형 온도를 낮춰야 하기 때문에, Mn의 함량을 2.0% 이상 첨가하는 것이 바람직하다. 그 함량이 2.0% 미만인 경우 강판을 오스테나이트 단상역에서 열처 리를 하기 어려워 본 발명에서 목표로 하는 강도를 확보하기 힘든 반면, 4.0%를 초과하게 되면 용접성, 열간압연성 등의 문제가 초래하므로, 그 함량을 2.0~4.0%로 제한하는 것이 바람직하다.Mn not only contributes greatly to the strength increase as a solid solution element, but also plays an important role in delaying the transformation of austenite to ferrite. In addition, as an element useful for lowering the Ac 3 temperature, in order to improve the plating adhesion, which is very important in the present invention, the hot forming temperature must be lowered. Therefore, it is preferable to add Mn content of 2.0% or more. If the content is less than 2.0%, the steel sheet is difficult to heat-treat in the austenitic single-phase zone, and thus it is difficult to secure the target strength in the present invention. However, if the content exceeds 4.0%, problems such as weldability and hot rolling are caused. It is preferable to limit the content to 2.0 to 4.0%.
P: 0.1% 이하가 바람직하다.P: 0.1% or less is preferable.
상기 P은 강을 강화시키는 효과를 보이지만, 과잉의 P첨가로 가공성이 열화 될 수 있기 때문에 0.1% 이하로 제한하는 것이 바람직하다.The P shows the effect of strengthening the steel, but is preferably limited to 0.1% or less because the workability may be degraded by the addition of excess P.
S: 0.03% 이하가 바람직하다.S: 0.03% or less is preferable.
상기 S은 강중 불순물 원소로서 강판의 연성 및 용접성을 저해할 가능성이 높기 때문에 0.03% 이하로 제한하는 것이 바람직하다.Since S is a high impurity element in steel, it is highly desirable to limit the ductility and weldability of the steel sheet to 0.03% or less.
가용 Al: 0.1% 이하가 바람직하다.Soluble Al: 0.1% or less is preferable.
상기 가용 Al은 강의 탈산을 위해서 첨가되는 원소이다. 그 함량이 0.1%를 초과하게 되면 그 효과가 포화될 뿐만 아니라, Al2O3 등의 개재물이 과다하게 형성되어 AlN을 형성함 으로써 고용N의 감소로 항복강도 상승을 억제시키는 문제점이 있다. 따라서, 상기 가용 Al의 함량은 0.1% 이하로 제한하는 것이 바람직하다.The soluble Al is an element added for deoxidation of steel. When the content exceeds 0.1%, the effect is not only saturated, but there is a problem in that the yield strength is suppressed due to the decrease of the solid solution N by forming AlN by forming excessive inclusions such as Al 2 O 3 . Therefore, the content of the soluble Al is preferably limited to 0.1% or less.
N: 0.01~0.1%가 바람직하다.N: 0.01 to 0.1% is preferable.
상기 N는 본 발명에서 매우 중요한 성분이다. N는 고용강화 원소임과 동시에 Ti, Nb, Al 등과 결합하여 질화물을 형성함으로써 항복강도를 상승시킨다. 또한, 본 발명에서 도장 후 항복강도 상승을 위해서 충분한 N를 첨가하는데, 이는 N가 도장 전 결정립내에 고용N으로 잔류해있다가 도장 후 전위의 이동을 방해하여 항복점을 상승시킴으로써 항복강도를 급격히 상승시키는 주요인으로 작용한다. 상기 N의 함량이 0.01% 미만의 경우에는 이러한 효과를 기대하기 어렵고, 0.1%를 초과하면 강판의 용해 및 연주를 어렵게 할 뿐만 아니라, 가공성 열화나 용접시 블로우 홀(blow hall)등 제조공정에서 문제를 초래할 수 있다. 따라서, 상기 N의 함량은 0.01~0.1%로 제한하는 것이 바람직하다. 바람직하게는 N의 함량은 0.011%~0.1%이다. 보다 바람직하게는 N의 함량은 0.02~0.1%이다. N is a very important component in the present invention. N is a solid solution strengthening element and combines with Ti, Nb, Al and the like to form nitride to increase yield strength. In addition, in the present invention, sufficient N is added to increase the yield strength after coating, which causes N to remain as solid solution N in the crystal grains before coating, thereby increasing the yield point by preventing the transfer of dislocation after coating, thereby rapidly increasing the yield strength. It acts as a major factor. When the content of N is less than 0.01%, it is difficult to expect such an effect. When the content of N is more than 0.1%, it is difficult to dissolve and play the steel sheet, as well as problems in manufacturing processes such as workability degradation or blow hole during welding. May result. Therefore, the content of N is preferably limited to 0.01 ~ 0.1%. Preferably the content of N is 0.011% to 0.1%. More preferably, the content of N is 0.02 to 0.1%.
W: 0.1% 이하가 바람직하다.W: 0.1% or less is preferable.
상기 W은 강판의 열처리 경화능을 향상시키는 원소임과 동시에, W함유 석출물이 강도 확보에 유리하게 작용하기 때문에 본 발명에서 매우 중요한 원소이다. 상기 W의 함량이 0.1%를 초과하면 이러한 효과가 포화될 뿐만 아니라, 제조 비용이 높아지는 문제점이 있다. 따라서, 상기 W의 함량은 0.1% 이하로 제한하는 것이 바람직하다.W is an element which improves the heat treatment hardenability of the steel sheet, and is a very important element in the present invention because the W-containing precipitate acts advantageously to secure the strength. When the content of W exceeds 0.1%, not only this effect is saturated, but there is a problem in that the manufacturing cost increases. Therefore, the content of W is preferably limited to 0.1% or less.
상기와 같이 조성되는 강에 추가로, 경화능향상원소인 Mo과 Cr에서 선택된 1종이상, 석출강화원소인 Ti과 Nb에서 선택된 1종 이상, 강도향상원소인 Cu와 Ni에 서 선택된 1종 이상 및 B을 첨가할 수 있다.In addition to the steel formed as described above, at least one member selected from Mo and Cr as the hardenability enhancing element, at least one member selected from Ti and Nb as the precipitation enhancing element and at least one member selected from Cu and Ni as the strength enhancement element And B may be added.
Mo과 Cr에서 선택된 1종이상: 0.01~1.5%가 바람직하다.At least one selected from Mo and Cr: 0.01 to 1.5% is preferable.
상기 Mo과 Cr은 경화능을 크게 할 뿐만 아니라 열처리형 강판의 인성을 증가시키기 때문에 높은 충돌에너지 흡수성을 특징으로 하는 강판에 첨가하면 그 효과가 매우 크다. 또한 경화능을 향상시키기 때문에 고온 성형가공시 금형과 직접 접촉하지 않는 부분의 강도저하를 방지할 수 있다. Mo 또는 Cr의 함량이 0.01% 미만의 경우에는 충분한 경화능을 얻을 수 없으며, 그 첨가량이 계속 증가하여도 경화능은 크게 증가하지 않고 강판제조에 필요한 제조원가를 크게 상승시키므로 1.5%로 제한하는 것이 바람직하다. The Mo and Cr not only increases the hardenability but also increases the toughness of the heat-treated steel sheet, so that the effect of Mo and Cr is very high when added to a steel sheet characterized by high impact energy absorption. In addition, since the hardenability is improved, the strength reduction of the portion not directly contacting the mold during high temperature molding processing can be prevented. If the content of Mo or Cr is less than 0.01%, sufficient hardenability cannot be obtained. Even if the amount of the addition is continuously increased, the hardenability does not increase significantly. Therefore, it is preferable to limit the amount to 1.5% because it greatly increases the manufacturing cost required for steel sheet production. Do.
Ti과 Nb에서 선택된 1종 이상: 0.001~0.1%가 바람직하다.1 or more types chosen from Ti and Nb: 0.001 to 0.1% is preferable.
상기 Ti과 Nb은 강판의 강도 상승, 입경 미세화 및 열처리특성을 향상시키는 원소이다. 상기 Ti과 Nb의 함량이 0.001% 미만의 경우에는 이와 같은 효과를 확보할 수 없고, 그 함량이 0.1%를 초과하게 되면 제조비용 상승 및 과다한 탄, 질화물 생성으로 목표로 하는 강도 및 항복강도 확보가 어렵다. 따라서, 그 함량을 0.001~0.1%로 제한하는 것이 바람직하다.The Ti and Nb are elements that improve the strength of the steel sheet, refine the grain size and improve the heat treatment characteristics. If the content of Ti and Nb is less than 0.001%, such an effect cannot be secured. If the content exceeds 0.1%, the production cost is increased and the target strength and yield strength is secured due to excessive carbon and nitride production. it's difficult. Therefore, it is preferable to limit the content to 0.001 to 0.1%.
Cu: 0.005~1.0% 또는 Ni: 0.005~2.0%에서 선택된 1종이상이 바람직하다.At least one selected from Cu: 0.005 to 1.0% or Ni: 0.005 to 2.0% is preferred.
상기 Cu는 미세한 Cu석출물을 생성하여 강도를 향상시키는 원소이다. 상기 Cu의 함량이 0.005% 미만인 경우 충분한 강도를 얻을 수 없고, 1.0%를 초과하면 가 공성 열화를 수반하므로, 그 함량을 0.005~1.0%로 제한하는 것이 바람직하다.The Cu is an element that produces fine Cu precipitates to improve strength. When the content of Cu is less than 0.005%, sufficient strength cannot be obtained, and when the content of Cu is more than 1.0%, it is accompanied by processing deterioration. Therefore, the content is preferably limited to 0.005 to 1.0%.
상기 Ni은 강도 상승 및 열처리특성을 향상시키는 원소이다. 상기 Ni의 함량이 0.005% 미만인 경우 상기 효과가 거의 나타나지 못하고, 2.0%를 초과하면 제조비용 상승 및 가공성 열화를 초래하므로, 그 함량을 0.005~2.0%로 제한하는 것이 바람직하다.Ni is an element that improves strength and heat treatment characteristics. If the content of Ni is less than 0.005%, the effect is hardly exhibited. If the content of Ni is more than 2.0%, an increase in manufacturing cost and deterioration of workability may occur. Therefore, the content is preferably limited to 0.005 to 2.0%.
B: 0.0001~0.01%가 바람직하다B: 0.0001 to 0.01% is preferable
상기 B은 경화능이 매우 큰 원소로서, 미량 첨가하여도 열처리강에서 높은 강도를 확보할 수 있다. 상기 B의 함량이 0.0001% 미만인 경우 충분한 경화능을 얻을 수 없으며, 그 첨가량이 계속 증가하여도 경화능은 크게 증가하지 않고 열간 가공성의 열화를 초래하므로 0.01%로 제한하는 것이 바람직하다.B is an element having a very high hardenability, and even if a small amount is added, high strength can be ensured in the heat-treated steel. If the content of B is less than 0.0001%, sufficient hardenability cannot be obtained, and even if the amount thereof is continuously increased, the hardenability does not increase significantly, resulting in deterioration of hot workability.
본 발명은 상기한 성분 이외에 나머지는 Fe 및 기타 불가피한 불순물로 조성된다.The present invention is composed of Fe and other unavoidable impurities in addition to the above components.
이하, 상기와 같이 조성되는 강을 갖는 합금화 용융아연도금강판의 제조방법에 대하여 상세하게 설명한다.Hereinafter, the manufacturing method of the alloying hot-dip galvanized steel sheet which has the steel comprised as mentioned above is demonstrated in detail.
먼저, 상기와 같이 조성되는 강 슬라브를 1100~1300℃에서 재가열한다. 상기 재가열 온도가 1100℃ 미만인 경우 조직 균일화 및 Ti, Nb 등의 재고용이 충분하지 않으며, 1300℃를 초과하게 되면 강판 조직이 조대화되기 쉽고, 제조상 문제가 발 생할 가능성이 높다. 따라서, 상기 재가열 온도는 1100~1300℃로 제한하는 것이 바람직하다. First, the steel slab formed as described above is reheated at 1100 ~ 1300 ℃. When the reheating temperature is less than 1100 ° C, the tissue uniformity and re-use of Ti, Nb, etc. are not sufficient, and when the reheating temperature exceeds 1300 ° C, the steel sheet structure is easily coarsened, and manufacturing problems are likely to occur. Therefore, the reheating temperature is preferably limited to 1100 ~ 1300 ℃.
이후, Ar3 변태점 이상 1000℃ 이하에서 열간마무리압연을 종료한다. 열간마무리 압연온도 Ar3 변태점 미만에서는 열간 변형 저항이 급격히 증가될 가능성이 높고 제조상 문제가 발생할 수 있으며, 1000℃를 초과하게 되면 너무 두꺼운 산화 스케일이 발생할 뿐만 아니라, 강판이 조대화될 가능성이 높다. 따라서, 상기 열간마무리 압연온도는 Ar3 변태점 이상 1000℃이하로 제한하는 것이 바람직하다.Thereafter, hot finish rolling is terminated at an Ar 3 transformation point or more and 1000 ° C. or less. Below the hot finish rolling temperature Ar 3 transformation point, hot deformation resistance is likely to increase sharply and manufacturing problems may occur, and if it exceeds 1000 ° C., too thick oxidation scale may occur and steel sheet may be coarsened. Therefore, the hot finishing rolling temperature is preferably limited to more than Ar 3 transformation point to less than 1000 ℃.
이어, 열연강판을 500~750℃에서 권취한다. 상기 권취온도가 500℃ 미만인 경우 과다한 마르텐사이트 또는 베이나이트가 생성되어 열연강판의 과다한 강도 상승을 초래함으로써 냉간압연시 부하로 인한 형상불량 등의 제조상의 문제가 발생할 수 있다. 반면, 750℃를 초과하게 되면 과다한 Ti, Nb, Mo 등의 석출물이 조대해지므로, 상기 권취온도는 500~750℃로 제한하는 것이 바람직하다.Subsequently, the hot rolled steel sheet is wound at 500 to 750 ° C. When the coiling temperature is less than 500 ℃ excessive martensite or bainite is produced to cause an excessive increase in strength of the hot rolled steel sheet may cause a manufacturing problem such as a shape defect due to the load during cold rolling. On the other hand, if it exceeds 750 ℃ excessive precipitates such as Ti, Nb, Mo becomes coarse, it is preferable to limit the winding temperature to 500 ~ 750 ℃.
이후, 상기 권취된 열연판을 산세 및 30~80%의 압하율로 냉간압연한다. 상기 냉간압하율이 30% 미만인 경우 목표로 하는 두께를 확보하기 어렵고 강판의 형상교정이 어려운 반면, 냉간압하율이 80%를 초과하게 되면 강판 에지(edge)부의 크랙이 발생할 가능성이 높고, 냉간압연 부하를 가져오는 문제점이 있다. 따라서, 상기 냉 간압하율은 30~80%로 제한하는 것이 바람직하다. Thereafter, the wound hot rolled sheet is pickled and cold rolled at a reduction ratio of 30 to 80%. If the cold reduction rate is less than 30%, the target thickness is difficult to secure and the shape correction of the steel sheet is difficult, while if the cold reduction rate exceeds 80%, there is a high possibility of cracking at the edge of the steel sheet, and cold rolling There is a problem that brings load. Therefore, the cold reduction rate is preferably limited to 30 to 80%.
본 발명에서는 상기 냉연강판을 열간성형 전에 750~900℃ 온도범위로 연속소둔을 행할 수 있다. 상기의 소둔온도가 750℃ 미만인 경우 충분한 가공성을 확보하지 못하는 경향이 있는 반면, 900℃를 초과하는 경우에는 제조비용 상승 및 표면품질 열화가 발생할 가능성이 높다.In the present invention, the cold rolled steel sheet may be continuously annealed at a temperature range of 750 to 900 ° C. before hot forming. If the annealing temperature is less than 750 ℃ tends to not secure sufficient processability, if the temperature exceeds 900 ℃ is likely to increase the manufacturing cost and surface quality deterioration.
이어, 상기 냉연강판 또는 연속소둔한 냉연강판에 450~470℃ 온도범위에서 10초 이하 동안 용융아연도금을 행한다. 상기 용융아연도금 온도가 450℃ 미만인 경우 아연도금이 부족한 반면, 470℃를 초과하면 과다하게 아연도금이 이루어지므로, 상기 용융아연도금 온도범위는 450~470℃로 제한하는 것이 바람직하다. Subsequently, hot dip galvanizing is performed on the cold rolled steel sheet or the continuously cold-rolled cold rolled steel sheet in a temperature range of 450 to 470 ° C. for 10 seconds or less. When the hot dip galvanizing temperature is less than 450 ℃ zinc plating is insufficient, when the hot dip galvanizing excessively exceeds 470 ℃, the hot dip galvanizing temperature range is preferably limited to 450 ~ 470 ℃.
또한, 상기 용융아연도금 시간이 10초를 초과하면 아연도금이 과다해지므로, 상기 용융아연도금 시간은 10초 이하로 제한하는 것이 바람직하다.In addition, since the zinc plating becomes excessive when the hot dip galvanizing time exceeds 10 seconds, the hot dip galvanizing time is preferably limited to 10 seconds or less.
상기 용융아연도금 후, 상온까지 냉각하고 440~580℃의 온도범위에서 30초 이하로 합금화 열처리를 행함으로써 합금화 아연 도금층을 형성한다. 상기 합금화 열처리는 용융아연도금 단계에서 용융아연도금층을 합금화 시키기 위한 것으로, 상기 합금화 열처리 온도가 440℃ 미만에서는 합금화가 불안정하고, 580℃를 초과하여도 합금화가 불안정하기 때문에 상기 합금화 열처리 온도는 440~580℃로 제한하는 것이 바람직하다. After the hot dip galvanizing, it is cooled to room temperature and alloyed heat treatment for 30 seconds or less in the temperature range of 440 ~ 580 ℃ to form a galvanized alloy plating layer. The alloying heat treatment is for alloying the hot dip galvanizing layer in the hot dip galvanizing step, the alloying heat treatment temperature is less than 440 ℃ alloying unstable, the alloying heat treatment temperature is 440 ~ 580 ℃ even if it exceeds 580 ℃ It is desirable to limit to 580 ° C.
또한, 상기 합금화 열처리 시간이 30초를 초과하는 경우 합금화가 과다해지므로, 상기 합금화 열처리 시간은 30초 이하로 제한하는 것이 바람직하다.In addition, when the alloying heat treatment time exceeds 30 seconds, the alloying is excessive, it is preferable to limit the alloying heat treatment time to 30 seconds or less.
이하, 열간성형 가공용 강판을 열처리한 열간성형 부품의 미세조직에 대하여 설명한다.Hereinafter, the microstructure of the hot formed part which heat-treated the steel plate for hot forming process is demonstrated.
상기와 같이 조성되는 강을 열간성형 부품으로 적합한 열처리를 통해 그 미세조직을 관리하여 요구하는 물성을 부여할 수 있다. 본 발명에서 열간성형 부품은 마르텐사이트의 분율이 80%이상이 되도록 한다. 마르텐사이트 분율 80% 미만에서는 본 발명에서 목표로 하는 높은 인장강도를 확보할 수 없기 때문이다. 본 발명의 효과를 보이기 위한 보다 바람직한 범위로는 마르텐사이트의 분율이 90%이상이 되도록 한다. 또한, 본 발명에서 열간성형 부품은 도장처리하여 항복강도 변화율(△YS) 100MPa 이상을 확보할 수 있다.The steel formed as described above may be given a desired physical property by managing the microstructure through a suitable heat treatment as a hot formed part. In the present invention, the hot formed part has a fraction of martensite of 80% or more. If the martensite fraction is less than 80%, it is because the high tensile strength targeted in the present invention cannot be secured. A more preferable range for showing the effect of the present invention is that the fraction of martensite is 90% or more. In addition, in the present invention, the hot formed parts may be coated to secure yield strength change rate (ΔYS) of 100 MPa or more.
이하, 상기와 같이 조성되는 강과 조직을 갖는 열간성형 부품의 제조방법에 대하여 상세하게 설명한다. Hereinafter, the manufacturing method of the hot formed part which has the steel and a structure | tissue which were formed as mentioned above is demonstrated in detail.
상기와 같이 제조되는 합금화 용융아연도금강판을 700~850℃ 온도범위로 1~100℃/초의 속도로 승온하고 10~1000초 유지하여, 금형에서 열간성형을 행한 후, 이어 10~500℃/초의 속도로 급냉을 실시한다. 상기 열처리 온도가 700℃ 미만인 경우 충분한 오스테나이트가 생성되지 않아 열간성형 후 충분한 마르텐사이트가 생성 되지 않으므로 목표로 하는 강도 확보가 어렵다. 반면, 850℃를 초과하는 경우 강판 표면 산화 및 오스테나이트 조대화로 인하여 부재 인성 저하 및 깨끗한 형상을 얻기 어려울 뿐만 아니라 Zn 도금밀착성이 저해되어 강판의 내식성이 저하되는 문제점이 있으므로, 상기 열간성형 온도범위는 700~850℃로 제한하는 것이 바람직하다. The alloyed hot-dip galvanized steel sheet produced as described above was heated at a rate of 1 to 100 ° C./sec in a temperature range of 700 to 850 ° C. and maintained at 10 to 1000 sec, after hot forming in a mold, followed by 10 to 500 ° C./sec. Quench at speed. If the heat treatment temperature is less than 700 ℃ sufficient austenite is not produced, so that sufficient martensite is not produced after hot forming, it is difficult to secure the target strength. On the other hand, when the temperature exceeds 850 ° C., it is difficult to obtain member toughness and clean shape due to oxidation of the steel sheet surface and coarsening of austenite, as well as Zn plating adhesion is inhibited, which lowers the corrosion resistance of the steel sheet. It is preferable to limit to 700-850 degreeC.
또한, 상기 승온속도가 1℃/초 미만인 경우 제조 효율이 떨어지는 경향이 있고, 100℃/초를 초과하는 경우에는 과다한 제조설비가 요구된다. 또한, 상기의 열처리 시간이 10초 미만인 경우 오스테나이트 변태가 충분하지 못한 반면, 1000초를 초과하게 되면 제조 비용의 상승 및 오스테나이트의 조대화가 일어나기 쉽다. In addition, when the temperature increase rate is less than 1 ° C / sec, the manufacturing efficiency tends to fall, and when it exceeds 100 ° C / sec, excessive manufacturing equipment is required. In addition, when the heat treatment time is less than 10 seconds, the austenite transformation is not sufficient, while when the heat treatment time exceeds 1000 seconds, an increase in manufacturing cost and coarsening of austenite are likely to occur.
또한, 상기 냉각속도가 10℃/초 미만인 경우 마르텐사이트를 주상으로 하는 조직을 얻기 힘들어 목표로 하는 강도를 확보하기 어렵다. 반면, 500℃/초를 초과하는 경우에는 과다한 제조 설비 투자로 제조 비용이 상승하고, 강도는 크게 증가하지 않기 때문에 10~500℃/초로 제한하는 것이 바람직하다. 열간성형 부품은 도장후 소부(baking)처리하는 과정에서 항복강도 변화율이 100MPa 이상 상승하는 특성을 갖는다.In addition, when the cooling rate is less than 10 ° C / sec, it is difficult to obtain a structure composed of martensite as a main phase, and thus it is difficult to secure the target strength. On the other hand, when it exceeds 500 ° C / sec, it is preferable to limit the manufacturing cost to 10 to 500 ° C / sec because the manufacturing cost increases due to excessive manufacturing equipment investment and the strength does not increase significantly. The hot formed part has a characteristic that the yield strength change rate increases by 100 MPa or more during the baking process after coating.
이하, 실시예를 통하여 본 발명을 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail with reference to Examples.
[실시예]EXAMPLE
하기 표1과 같이 조성되는 강 슬라브를 진공용해하고, 가열로에서 재가열온도 1150~1250℃ 온도범위에서 1시간 가열하고 열간압연을 실시한 후 권취하였다. 이때, 열간압연은 850~950℃ 온도범위에서 열간압연을 종료하였으며, 권취온도는 650℃로 하였다. 열간압연한 강판을 이용하여 산세를 실시하고 냉간압하율을 50%로 하여 냉간압연을 실시하였다. 냉간압연된 강판은 800℃에서 소둔한 후 과시효온도를 400℃로 하여 연속소둔을 실시하였다. The steel slab formed as shown in Table 1 was vacuum-dissolved, heated in a reheating temperature of 1150 ~ 1250 ° C for 1 hour in a heating furnace and wound up after hot rolling. At this time, the hot rolling was finished hot rolling in the temperature range of 850 ~ 950 ℃, the winding temperature was set to 650 ℃. Pickling was performed using a hot rolled steel sheet and cold rolling was performed at a cold rolling reduction of 50%. The cold rolled steel sheet was annealed at 800 ° C. and then subjected to continuous annealing with an overage temperature of 400 ° C.
이후, 460℃로 가열하여 5초 동안 용융아연도금한 후, 도금층의 합금화를 위하여 500℃에서 10초 동안 합금화 처리 후, 상온까지 냉각하여 합금화 용융아연도금강판을 제조하였다. 이어, 상기와 같이 제조된 도금 강판을 표2와 같은 열처리온도 조건으로 10℃/초의 속도로 승온하고 5분간 가열한 뒤, 가열된 강판을 가공하기 위하여 금형으로 옮겨 강판이 가열된 상태에서 가공을 실시하였고, 가공과 동시에 80℃/초의 속도로 급냉처리되었다.Thereafter, after hot-dip galvanizing for 5 seconds by heating to 460 ℃, after the alloying treatment for 10 seconds at 500 ℃ for alloying of the plating layer, and cooled to room temperature to produce an alloyed hot-dip galvanized steel sheet. Subsequently, the plated steel sheet manufactured as described above was heated at a rate of 10 ° C./sec under the heat treatment temperature conditions as shown in Table 2 and heated for 5 minutes, and then transferred to a mold to process the heated steel sheet. And quenched at the rate of 80 ° C./sec concurrently with processing.
그리고 가공이 끝난 후 인장시편의 절취가 가능한 부위를 절단하여 JIS 5호 인장시험편을 제작하였다. 도금밀착성은 90도 벤딩 열간성형 가공된 부위에서 Zn 도금층과 강판의 밀착성 정도를 광학현미경을 통하여 관찰하였다. 또한, 자동차용 구조부재에서 도장 후 재질을 모사하기 위하여, 위와 같이 제작된 인장 시편을 170℃에서 20분간 오일에 끓인 후 인장시험을 행하였다.And after the end of the processing was cut to the portion that can be cut tensile specimens to prepare a JIS No. 5 tensile test piece. The adhesion of the Zn plated layer and the steel sheet was observed through the optical microscope at the 90 degree bending hot forming site. In addition, in order to simulate the material after the coating in the structural member for automobiles, the tensile test prepared above was boiled in oil at 170 ° C. for 20 minutes and then subjected to a tensile test.
표2는 본 발명강과 비교강의 열간성형 가공후 조직 및 기계적 성질을 나타낸 것이다.Table 2 shows the structure and mechanical properties after hot forming processing of the inventive steel and comparative steel.
표 1 및 2에서 나타난 바와 같이, 본 발명의 성분범위 및 제조조건을 만족하는 발명재(1~6)의 경우 최종제품에서 인장강도 1470MPa 이상의 초고강도를 나타낸다. 또한, 170℃에서 20분간 도장 모사 후 항복강도의 변화는 발명재(1~6) 모두 100MPa 이상으로 증가함에 따라 충격특성이 우수한 자동차 차체의 구조부재와 보강재로 사용될 수 있다. 그리고 우수한 도금밀착성도 나타내었다.As shown in Table 1 and 2, in the case of the invention material (1 ~ 6) that satisfies the component range and manufacturing conditions of the present invention exhibits an ultra high strength of 1470 MPa or more in the final product. In addition, the change in yield strength after 20 minutes coating simulation at 170 ℃ can be used as a structural member and reinforcement of the vehicle body excellent in impact characteristics as the invention materials (1-6) all increase to 100MPa or more. And excellent plating adhesion was also shown.
그러나, 본 발명의 열간성형 열처리조건을 만족하지 않는 비교재(1~3, 5 및7)의 경우, 고온에서 열간성형을 행하여 모두 불량한 도금밀착성을 나타내었다. However, the comparative materials (1 to 3, 5, and 7) which did not satisfy the hot forming heat treatment conditions of the present invention exhibited poor plating adhesion by performing hot forming at high temperature.
또한, Mn 및 N의 함량이 본 발명이 제한하는 범위를 벗어난 비교강D를 이용하여 제조된 비교재 4의 경우 목표로 하는 마르텐사이트의 분율을 확보하지 못할 뿐만 아니라, 인장강도와 항복강도 상승이 부족하였다. 비교강D를 이용하여 제조된 비교재5의 경우, 고온에서 열처리하여 강도는 확보되었지만, 도금밀착성은 떨어졌다. In addition, in the case of the comparative material 4 prepared using the comparative strength D in which the content of Mn and N is outside the range limited by the present invention, not only the fraction of the target martensite is secured, but also the tensile strength and the yield strength increase are increased. Shortage. In the case of Comparative Material 5 manufactured using Comparative Steel D, the strength was secured by heat treatment at high temperature, but the plating adhesion was inferior.
또한, C 및 N의 함량이 본 발명이 제한하는 범위를 벗어난 비교강E를 이용하여 제조된 비교재 6,7의 경우 탄소의 첨가량이 낮기 때문에 열처리 및 금형가공 후 충분히 강한 마르텐사이트 조직을 확보하지 못하여 최종 제품에서 높은 인장강도를 확보할 수 없었으며, 질소의 첨가량이 낮기 때문에 항복강도 상승이 부족하였다.In addition, in the case of the comparative material 6,7 manufactured by using the comparative steel E whose contents of C and N are outside the range limited by the present invention, the addition amount of carbon is low, so that the martensite structure is sufficiently secured after heat treatment and mold processing. As a result, high tensile strength could not be secured in the final product, and the yield strength was insufficient due to the low nitrogen content.
상술한 바와 같이, 본 발명에 따르면, 합금화 용융아연도금강판은 저온 열간성형에서도 1470MPa 이상의 강도를 확보하면서, 우수한 도금밀착성을 확보할 수 있 다. 또한, 도장 후 항복강도 100MPa 이상의 상승으로 인한 충격특성이 우수한 열간성형 가공용 강판을 제공할 수 있는 효과가 있다.As described above, according to the present invention, the alloyed hot-dip galvanized steel sheet can secure excellent plating adhesion while securing strength of 1470 MPa or more even at low temperature hot forming. In addition, there is an effect that can provide a hot forming steel sheet for excellent impact characteristics due to the rise in yield strength of 100MPa or more after coating.
Claims (13)
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KR1020050125207A KR100711445B1 (en) | 2005-12-19 | 2005-12-19 | A method for manu- facturing alloyed hot dip galvanized steel sheet for hot press forming having excellent plating adhesion and impact property, the method for manufacturing hot press parts made of it |
PCT/KR2006/005155 WO2007064172A1 (en) | 2005-12-01 | 2006-12-01 | Steel sheet for hot press forming having excellent heat treatment and impact property, hot press parts made of it and the method for manufacturing thereof |
DE112006003169T DE112006003169B4 (en) | 2005-12-01 | 2006-12-01 | Steel sheets for hot press forming with excellent heat treatment and impact properties, hot pressed parts produced therefrom and process for their production |
SK5061-2008A SK288275B6 (en) | 2005-12-01 | 2006-12-01 | Hot rolled steel sheet having excellent heat treatment and impact property, hot press parts made of it and the method for manufacturing thereof |
US12/092,342 US20080286603A1 (en) | 2005-12-01 | 2006-12-01 | Steel Sheet for Hot Press Forming Having Excellent Heat Treatment and Impact Property, Hot Press Parts Made of It and the Method for Manufacturing Thereof |
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