KR100686197B1 - Preparing method of packable fabric having excellent dry property and durability and fabric thereby - Google Patents

Preparing method of packable fabric having excellent dry property and durability and fabric thereby Download PDF

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KR100686197B1
KR100686197B1 KR1020050030100A KR20050030100A KR100686197B1 KR 100686197 B1 KR100686197 B1 KR 100686197B1 KR 1020050030100 A KR1020050030100 A KR 1020050030100A KR 20050030100 A KR20050030100 A KR 20050030100A KR 100686197 B1 KR100686197 B1 KR 100686197B1
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fabric
packable
waterproof
wear
resin composition
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KR1020050030100A
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Korean (ko)
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KR20060107876A (en
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박명수
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박명수
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/70Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
    • D06M15/705Embossing; Calendering; Pressing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/70Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
    • D06M15/71Cooling; Steaming or heating, e.g. in fluidised beds; with molten metals
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/08Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • D10B2401/021Moisture-responsive characteristics hydrophobic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments

Abstract

본 발명은 원단에 발수가공을 행하는 제1단계; 상기 발수원단에 투습방수코팅가공을 행하는 제2단계; 상기 투습방수코팅가공되어 롤상으로 공급되어 온 원단에 음각롤 표면처리 방식에 의해 그라스펄이 함유된 표면처리제 수지조성물을 전사코팅하는 제3단계; 상기 전사코팅된 원단을 건조하는 제4단계;로 이루어지는 방법에 의해 건조감이 우수한 패커블 내마모 투습방수포의 제조방법을 제공한다. The present invention is the first step of performing a water-repellent process on the fabric; A second step of performing a waterproof coating on the water repellent fabric; A third step of transferring and coating the surface treatment agent resin composition containing glass pearl on the fabric which has been supplied to the roll by the moisture-permeable waterproof coating; The fourth step of drying the transfer-coated fabric; provides a method of manufacturing a packable wear-resistant moisture-proof waterproof cloth excellent in dry feeling.

본 발명에 따르면, 표면처리제 수지조성물을 음각무늬롤로부터 원단 코팅면에 효과적으로 견고하게 전사시킴으로써 코팅면의 요철감, 건조감 및 내마모성을 극대화시키는 효과가 있다. 따라서, 본 발명에 의해 제조된 투습방수원단은 가볍고, 부피가 작아 일반 캐주얼, 스포츠용, 일시적인 방수 방풍용의 패커블 의류에 적합하다.According to the present invention, the surface treatment agent resin composition is effectively and firmly transferred from the intaglio pattern roll to the fabric coating surface, thereby maximizing the unevenness, dryness and wear resistance of the coating surface. Therefore, the moisture-permeable waterproof fabric produced by the present invention is light and small in volume, and is suitable for general casual, sports, and temporary waterproof windproof clothing.

투습방수, 원단, 섬유, 롤코팅, 그라스펄, 항균방취 Breathable, Fabric, Fiber, Roll Coating, Glass Pearl, Antibacterial

Description

건조감이 우수한 패커블 내마모성 투습방수포의 제조방법 및 그에 의해 제조된 투습방수포{Preparing method of packable fabric having excellent dry property and durability and fabric thereby}Manufacture method of packable wear-resistant moisture-resistant waterproof fabric and excellent moisture-proof waterproof fabric produced by the present invention {Preparing method of packable fabric having excellent dry property and durability and fabric

본 발명은 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법 및 그에 의해 제조된 투습방수포에 관한 것으로, 보다 상세하게는, 특정 조성의 표면처리제 수지조성물을 직접 코팅방식 또는 전사코팅방식에 의해 섬유포에 코팅함으로써 피부에의 접촉시 내마모성, 건조감 및 쾌적감을 극대화시키고, 안감을 생략할 수 있도록 함으로써 경량성과 패커블성을 향상시킨 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법 및 그에 의해 제조된 투습방수포에 관한 것이다.The present invention relates to a manufacturing method of a packable wear-resistant moisture-proof waterproof fabric excellent in dryness and a moisture-permeable waterproof foam produced by the present invention, and more particularly, coating the surface treatment agent resin composition of a specific composition on the fabric by direct coating or transfer coating method The present invention relates to a method for producing a packable wear-resistant moisture-permeable foam having excellent dryness and improved lightness and packability by maximizing abrasion resistance, dryness and comfort when contacting the skin, and thus eliminating lining. .

투습방수 코팅원단은 스키, 골프웨어, 하이킹, 등산, 죠깅복 등 각종 액티브 스포츠웨어 및 캐쥬얼웨어에 널리 사용되고 있는 소재로서 겉감지 섬유 원단은 주로 두껍지 않은 합성섬유원단에 투습방수코팅을 하여 제조되는 것이 일반적이다. 또한, 상기 투습방수원단은 외부로부터의 수분을 배척하기 위해 통상적으로 발수가공이 적용되는데 선발수(투습방수 코팅전에 실시) 또는 후발수(투습방수코팅 후 실시)가 적용된다.The waterproof coating fabric is widely used in various active sportswear and casual wear such as skiing, golf wear, hiking, mountain climbing, jogging clothes, etc. The outer textile fabric is mainly manufactured by the waterproof coating of non-thick synthetic fiber fabric. It is common. In addition, the water-repellent waterproof fabric is usually applied to water repellent in order to reject moisture from the outside is applied to the water repellent (executed before the moisture-repellent waterproof coating) or after water repellent (after the moisture-repellent waterproof coating) is applied.

일반적으로 종래의 투습방수 원단은 섬유층과 코팅층으로 구성된 2층구조와 섬유층(겉감), 코팅층 및 섬유층(안감) 으로 구성된 3층 구조로 되어 있는데, 2층 구조의 원단은 봉제시 별도로 안감지를 사용함으로써 결국 3층 구조의 원단으로 되게 마련이다. 따라서, 안감지 부가로 인하여 그만큼 촉감이 둔탁해지고, 부피 및 중량이 커지게 되며, 제조원가도 올라가는 단점이 있어 왔다.In general, the moisture-permeable waterproof fabric has a two-layer structure consisting of a fiber layer and a coating layer, and a three-layer structure consisting of a fiber layer (outer fabric), a coating layer, and a fiber layer (lining). In the end, it will be a three-layer fabric. Therefore, due to the addition of the lining paper, the touch becomes dull, the volume and weight are increased, and the manufacturing cost has been disadvantageous.

또한, 여름 또는 일시적 방수 방풍용으로 간헐적인 사용을 위한 휴대를 위해 접어서 패킹할 때 부피 및 중량이 커지게 되어 매우 불편하게 되는 문제점이 있어 왔다.In addition, there has been a problem that the volume and weight becomes very uncomfortable when folded and packed for portable for intermittent use for summer or temporary waterproof windproof.

종래에 상술한 바와 같은 목적을 위해 패커블(packable)용으로 2층구조의 코팅원단에 그라비아방식으로 인쇄를 하거나 음각무늬 표면처리를 한 제품들이 고안되기는 하였었으나, 이것들은 요철감이 없거나 내마모성, 내스크래치성이 약하고, 특유의 매끄럽고 건조한 감이 부족하여 목적에 충분히 부합 하지 못하였다.Conventionally, products for which the gravure printing or the intaglio pattern surface treatment were designed on a two-layer coating fabric for packable purposes for the purpose as described above, but these have no unevenness or wear resistance, It is not scratch-resistant and lacks the peculiar smooth and dry feeling.

또한, 요철감을 준 것이라 하더라도 내마모성이나 내스크래치성이 약하여 세탁내구성이 미흡하고 코팅면의 항균방취 성능등이 열악하여 운동시 땀등에 의한 악취의 발생을 예방하지 못하는 단점들이 있어왔다. In addition, even if given the unevenness, there is a weak wear resistance or scratch resistance due to insufficient washing durability and poor antibacterial deodorization performance of the coating surface, there is a disadvantage that can not prevent the occurrence of odor due to sweat during exercise.

예를 들어 대한민국 공개특허공보 제 2004-0004301호에서는 요철감을 부여키 위해 표면처리 약제를 발포제로 발포시키는 방법을 사용하였으나 표면에 발포셀이 형성됨으로 인하여 내마모성이 열악하게 되고, 스크래치시 자국을 남기게 되는 문제점을 안고 있다. 또한 요철부제로 사용하는 돌가루, 규소토, 탄산칼슘 등은 가공후 표면의 슬립성을 부여하기 곤란하며, 세탁이나 드라이크리닝에 대해서 견뢰하지 못 한 단점을 지니고 있다.For example, in Korean Patent Laid-Open Publication No. 2004-0004301, a method of foaming a surface treatment agent with a foaming agent is used to give an unevenness, but since a foam cell is formed on the surface, abrasion resistance is poor, leaving marks on scratches. I have a problem. In addition, stone powder, silicon earth, calcium carbonate, etc., which are used as an uneven subsidiary, have difficulty in providing slip property of the surface after processing, and have a disadvantage in that they are not robust to washing or dry cleaning.

제판롤러의 설계에 의한 요철감 발현 측면에서도 상기 특허에서와 같이 필름부식방법에 의해 7~12미크론 정도의 심도로 설계를 할 경우 표면처리제 배합물의 고유 고형분이 존재하며, 통상적으로 그라비아 롤상에서 원단으로의 전이율이 70%이상을 넘기기가 현실적으로 곤란하여 표면처리 가공후 실제 코팅원단의 표면으로부터의 부착 높이는 제판상 심도의 30% 이하 수준 정도로 매우 미흡하다.In terms of the appearance of unevenness by the design of the plate making roller, when designing with a depth of about 7 to 12 microns by the film corrosion method as in the patent, there is an intrinsic solid content of the surface treatment agent formulation, and usually from gravure roll to fabric It is practically difficult for the transition rate of to exceed 70%, so the adhesion height from the surface of the actual coating fabric after the surface treatment is very low, about 30% or less of the depth on the plate making.

본 발명은 상술한 바와 같은 종래기술의 문제점을 해결하고자 안출된 것으로서, 본 발명의 목적은 건조감 및 내마모성이 우수하여 착용감이 좋을 뿐만 아니라 경량이고 접었을 때 부피가 작아 패커블성이 우수하여 봉제시 안감지를 필요로 하지 않는 투습방수포의 제조방법을 제공함에 있다.The present invention has been made to solve the problems of the prior art as described above, the object of the present invention is not only good wear feeling due to excellent dry feeling and wear resistance, but also light weight and small volume when folded, excellent packable properties when sewing lining paper It is to provide a method of manufacturing a moisture-proof waterproof cloth that is not required.

본 발명의 다른 목적은 상기 방법에 의해 제조되는 건조감 및 내마모성이 우수한 패커블 투습방수포를 제공함에 있다.Another object of the present invention is to provide a packable moisture-proof waterproof fabric excellent in the dry feeling and wear resistance produced by the above method.

본 발명의 또다른 목적은 상기 제조방법에 사용되고 제품에 우수한 건조감 및 내마모성을 부여할 수 있는 코팅 표면처리제 수지조성물을 제공함에 있다.Another object of the present invention is to provide a coating surface treatment resin composition that is used in the manufacturing method and can impart excellent dry feeling and wear resistance to the product.

본 발명의 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법은 원단에 발수가공을 행하는 제1단계; 상기 발수원단에 투습방수코팅가공을 행하는 제2단계; 상기 투습방수코팅가공되어 롤상으로 공급되어 온 원단에 음각롤 표면처리 방식에 의해 그라스펄이 함유된 표면처리제 수지조성물을 전사코팅하는 제3단계; 상기 전 사코팅된 원단을 건조하는 제4단계;로 이루어진다.The manufacturing method of the packable wear-resistant moisture-proof waterproof fabric excellent in the dryness of the present invention comprises the first step of performing a water-repellent process on the fabric; A second step of performing a waterproof coating on the water repellent fabric; A third step of transferring and coating the surface treatment agent resin composition containing glass pearl on the fabric which has been supplied to the roll by the moisture-permeable waterproof coating; And a fourth step of drying the precoated fabric.

본 발명에 있어서, 상기 제3단계의 전사코팅은 음각롤의 표면위에 상기 표면처리제 수지조성물을 공급하여 양변부를 막아 수지조성물의 변부 이탈을 막고, 스크랩퍼로 롤표면을 균일하게 스크랩핑하여 음각이외의 부위에 있는 수지조성물을 제거한 후 방수원단의 코팅면에 소정의 두께로 전사코팅이 이루어지도록 수행되는 것이 바람직하다.In the present invention, the transfer coating of the third step is to supply the surface treatment agent resin composition on the surface of the intaglio roll to block both sides to prevent the deviation of the resin composition, scraping the surface of the roll uniformly with a scraper outside the intaglio After removing the resin composition in the region of the coating is preferably performed to the transfer coating to a predetermined thickness on the surface of the waterproof fabric.

본 발명에 있어서, 상기 음각롤의 심도는 100 내지 300 미크론인 것이 바람직하다.In the present invention, the depth of the intaglio roll is preferably 100 to 300 microns.

또한, 본 발명에 있어서, 상기 표면처리제 수지조성물은 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물인 것이 바람직하다.In addition, in the present invention, the surface treating agent resin composition is 10 to 100 parts by weight of mixed organic solvent, 10 to 100 parts by weight of glass pearl, and 0 to 2 parts by weight of pigment pigment based on 100 parts by weight of the liquid polyurethane resin in a weight ratio. And a mixture of 0.5 to 5 parts by weight of the antiblocking agent.

상기 표면처리제 조성물에는 무기항균제 또는 바이오세라믹계 소취제가 10중량부이하로 더 포함되는 것이 바람직하다.It is preferable that the surface treating agent composition further include an inorganic antibacterial agent or a bioceramic deodorant to 10 parts by weight or less.

상기 무기항균제는 무기계 세라믹물질 제올라이트계인 것이 바람직하다.The inorganic antimicrobial agent is preferably an inorganic ceramic material zeolite.

또한, 상기 표면처리제 조성물에 있어서, 상기 그라스펄은 입경분포가 5 내지 100 미크론이고 구형인 것이 바람직하며, 산화바륨, 산화티탄 및 실리카(SiO2) 중 어느하나 또는 둘이상의 혼합물인 것이 바람직하다. 또한, 상기 블록킹 방지제는 실리카 미분말인 것이 바람직하다.In addition, in the surface treating agent composition, the glass pearl may have a particle size distribution of 5 to 100 microns and a spherical shape, and may be any one or a mixture of two or more of barium oxide, titanium oxide, and silica (SiO 2 ). In addition, the blocking agent is preferably a fine silica powder.

상기 표면처리제 조성물에 있어서, 폴리우레탄 수지는 1-컴포넌트형 폴리우레탄수 지인 것이 바람직하다.In the surface treatment agent composition, the polyurethane resin is preferably a 1-component polyurethane resin.

또한, 상기 표면처리제 조성물에 있어서, 상기 혼합유기용제는 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤, 에틸아세테이트로 이루어지는 군중에서 선택되는 하나 또는 둘이상의 혼합물인 것이 바람직하다.In the surface treating agent composition, the mixed organic solvent is one or two or more mixtures selected from the group consisting of toluene, methyl ethyl ketone, dimethylformamide, isopropyl alcohol, xylene, perchloroethylene, acetone, and ethyl acetate. It is preferable.

상기 표면처리제 수지조성물의 점도는 2000 cps 이상인 것이 바람직하다.It is preferable that the viscosity of the said surface treating agent resin composition is 2000 cps or more.

또한, 본 발명에 있어서, 상기 제4단계의 건조 공정에 채용되는 열처리챔버는 간접열풍식 또는 직접복사열방식으로 할 수 있다.In the present invention, the heat treatment chamber employed in the drying step of the fourth step may be an indirect hot air type or a direct radiation heat method.

본 발명에 있어서, 상기 표면처리제 수지조성물중 고형분은 30%이상으로 하는 것이 바람직하다.In the present invention, the solid content in the surface treating agent resin composition is preferably 30% or more.

본 발명의 또다른 형태에 따르면, 본 발명은 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물로 이루어지는 섬유원단 표면처리제를 제공한다.According to another aspect of the present invention, the present invention is based on a weight ratio of 100 parts by weight of the liquid polyurethane resin, 10 to 100 parts by weight of mixed organic solvent, 10 to 100 parts by weight of glass pearl, 0 to 2 parts by weight of pigment pigment And it provides a fiber fabric surface treatment agent consisting of a mixture of 0.5 to 5 parts by weight of the antiblocking agent.

본 발명은 또한, 상기 제조방법에 의해 제조된 것을 특징으로 하는 건조감이 우수한 패커블 내마모성 투습방수포 및 상기 투습방수포가 채용된 의류를 제공한다.The present invention also provides a packable wear-resistant moisture-resistant waterproof fabric and clothes having the moisture-permeable waterproof foam excellent in dryness, characterized in that produced by the manufacturing method.

이하에서 본 발명을 보다 상세히 설명할 것이다.The present invention will be described in more detail below.

본 발명의 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법은 원단에 발수가공을 행하는 제1단계; 상기 발수원단에 투습방수코팅가공을 행하는 제2단계; 상기 투습방수코팅가공되어 롤상으로 공급되어 온 원단에 음각롤 표면처리 방식에 의해 그라스펄이 함유된 표면처리제 수지조성물을 전사코팅하는 제3단계; 상기 전사코팅된 원단을 건조하는 제4단계;로 이루어진다.The manufacturing method of the packable wear-resistant moisture-proof waterproof fabric excellent in the dryness of the present invention comprises the first step of performing a water-repellent process on the fabric; A second step of performing a waterproof coating on the water repellent fabric; A third step of transferring and coating the surface treatment agent resin composition containing glass pearl on the fabric which has been supplied to the roll by the moisture-permeable waterproof coating; And a fourth step of drying the transfer coated fabric.

투습방수포는 원단을 직조한 후 염색 및 발수 가공처리 한 후, 합성수지 코팅액으로 다이렉트 또는 트랜스퍼 코팅 방법으로 코팅처리한 다음, 롤링된 상태로 공급되거나, 원단 직조후 염색 후에 발수가공을 생략하고, 합성수지 코팅액으로 코팅처리하여 발수가공 처리 한 후(후발수) 역시 롤링된 상태로 제 3단계의 전사코팅공정에 공급될 수 있다.The moisture-permeable waterproof cloth is dyed and water-repellent processed after weaving the fabric, coated with a direct or transfer coating method with a synthetic resin coating solution, and then supplied in a rolled state, or after water dyeing after fabric weaving, the water-repellent processing is omitted, and the synthetic resin coating solution After the coating treatment to the water-repellent treatment (post-water repellent) can also be supplied to the transfer coating process of the third step in a rolled state.

상기 제1단계와 제2단계의 투습방수 코팅과 발수가공은 전후를 바꾸어 할 수 있는 것으로 방수원단에서 합성수지 코팅액으로 코팅 하기전에 발수가공하면 선발수, 발수가공을 합성수지 코팅액으로 코팅을 한후에 실시하면 후발수 가공이라 한다. Water-repellent coating and water-repellent coating of the first and second steps can be changed back and forth. If water-repellent processing before coating with synthetic resin coating solution from waterproofing fabric It is called hand processing.

상기 제3단계의 음각롤 표면처리방식에 의해 전사코팅한 후에 표면처리제 수지조성물의 건조 과정이 포함되는데, 이것은 열풍이 공급되는 챔버안에서 이루어진다.After the transfer coating by the intaglio roll surface treatment method of the third step, a drying process of the surface treatment agent resin composition is included, which is performed in a chamber to which hot air is supplied.

한편 상기 음각롤 표면처리 방식을 구체적으로 설명하면 음각롤의 표면위에 표면처리제 수지조성물을 공급하여 양변부를 막아 수지조성물의 변부 이탈을 방지 하고, 스크랩퍼로 롤표면을 균일하게 스크랩핑하여, 즉, 고정된 스크랩퍼에 롤의 회전에 의해 음각 이외의 부위에 있는 수지조성물을 제거한 후 방수원단의 코팅면에 소정의 두께로 전사코팅이 이루어지도록 하는 것이다.On the other hand, when describing the surface treatment method of the intaglio roll in detail, the surface treatment agent resin composition is supplied on the surface of the intaglio roll to prevent both sides from being separated from the edge of the resin composition, and scraping the roll surface uniformly with a scraper, that is, After the removal of the resin composition in the portion other than the intaglio by the rotation of the roll to the fixed scraper to transfer coating to a predetermined thickness on the coating surface of the waterproof fabric.

상기 코팅 방식은 표면처리제 수지조성물의 점도를 고려한 것으로, 물론 이러한 코팅 방식은 종래와 마찬가지로 약제팬에 수지조성물을 채우고 롤이 회전하면서 수지조성물을 묻혀 올려오면 독타나이프로 스크래핑하여 적도의 픽업량을 조절하는 방 식으로 이루어지는 종래의 방식도 채용될 수 있음은 당업자에게 이해되어질 수 있을 것이다.The coating method is to take into account the viscosity of the surface treatment resin composition, of course, this coating method is to fill the resin composition in the pharmaceutical pan as in the prior art, when the roll is rotated and buried the resin composition scraped with a dog knife to adjust the pickup amount of the equator It will be understood by those skilled in the art that a conventional method may be employed.

즉, 상기 표면처리제 수지조성물을 약제팬에 담아 그라비아롤로 이송하여 처리하는 경우도 가능하지만 고점도, 즉 고고형분의 약제는 작업특성상 난점이 있으므로 상기와 같이 음각롤상에 약제를 공급하여 처리함으로써 고점도(약2,000∼50,000 cps)의 수지조성물을 균일하게 효과적으로 전사고착시킬 수 있게 된다.That is, the surface treating agent resin composition may be transferred to a gravure roll for processing, but the high viscosity, that is, a solid drug may have a high viscosity due to its difficulty in working characteristics. 2,000 to 50,000 cps) resin composition can be uniformly and effectively transfer-fixed.

표면처리제의 전사 고착 원리는 음각롤과 쿳션롤 사이에 피착체를 통과시키면서 압착을 해줌으로서 음각롤에 묻어있던 표면처리제 수지조성물을 피착체 쪽으로 전사시키는 원리인데, 통상 쿳션롤을 하단부에 위치시키는 경우와 상단부에 위치시키는 경우 모두 가능한 방법이지만 전사의 안정성 측면에서 쿳션롤을 하단부에 위치시키는 것이 더욱 바람직하다.The transfer fixation principle of the surface treatment agent transfers the adherend between the intaglio roll and the cushion roll while passing the adherend, and transfers the surface treatment resin composition on the intaglio roll to the adherend. In the case where both the upper and upper ends are possible, it is more preferable to position the cushion roll at the lower end in view of the stability of the transfer.

이러한 전사코팅 방법으로 해야 하는 이유는 방수 원단의 코팅 표면에 요철감을 부여키 위한 것이며 이를 위해 표면 처리제 수지조성물의 고형분을 최대한 높이는 것이 요구되고, 수지특성상 고형분의 증가에 따라 자연스럽게 표면처리제 수지조성물의 점도도 높아지게 됨은 당업자에게 있어서 용이하게 이해되어질 수 있을 것이다.The reason for the transfer coating method is to impart the unevenness to the coating surface of the waterproof fabric. To this end, the solid content of the surface treatment resin composition is required to be as high as possible, and the viscosity of the surface treatment resin composition is naturally increased due to the increase in the solid content. The higher will be readily understood by those skilled in the art.

이와 같이 고점도로 하는 경우에 건조 열처리 과정에서 증발되는 양을 최소화할 수 있게 되고, 나아가 음각롤에서 전사되는 수지조성물을 일정 두께로 전사 고착시킬 수 있게 되는 것이다.As such, when the high viscosity is achieved, the amount of evaporation during the dry heat treatment process can be minimized, and further, the resin composition transferred from the intaglio roll can be transferred and fixed to a predetermined thickness.

본 발명에 있어서, 음각롤코팅시 상기 음각롤의 심도는 100 내지 300 미크론인 것 이 바람직하다. 상기 음각롤의 심도가 100보다 얕으면 요철감 발현이 미흡하게 되고, 300미크론을 초과하여 깊게 제판할 경우는 수지조성물의 균일한 전사가 어렵게 되거나 전사무늬형태가 일그러지는 문제가 발생할 수있다. 즉, 무늬 크기에 비해 지나치게 심도가 깊을 경우 전이율이 불량해질 우려가 있다.In the present invention, when the intaglio roll coating, the depth of the intaglio roll is preferably 100 to 300 microns. If the depth of the intaglio roll is shallower than 100, the unevenness is insufficient, and when deeply plated more than 300 microns, uniform transfer of the resin composition may be difficult or the transfer pattern may be distorted. That is, when the depth is too deep compared to the size of the pattern, there is a fear that the transfer rate is poor.

상기 제3단계의 음각롤 표면처리 단계에서 사용되는 표면처리제 수지조성물은 안료 피그먼트, 폴리우레탄수지, 무기항균제, 블록킹방지제, 그라스 펄 및 혼합유기 용제를 포함하여 이루어진다.The surface treatment agent resin composition used in the intaglio roll surface treatment step of the third step comprises a pigment pigment, a polyurethane resin, an inorganic antibacterial agent, an antiblocking agent, a glass pearl, and a mixed organic solvent.

바람직하게는 상기 표면처리제 수지조성물은 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물인 것이 바람직하다.Preferably, the surface treating agent resin composition is contained in a weight ratio of 100 parts by weight of the liquid polyurethane resin, 10 to 100 parts by weight of mixed organic solvent, 10 to 100 parts by weight of glass pearl, 0 to 2 parts by weight of pigment pigment, and blocking. It is preferably a mixture of 0.5 to 5 parts by weight of the inhibitor.

상기 표면처리제 조성물에는 무기항균제 또는 바이오세라믹계 소취제가 10중량부이하로 더 포함되는 것이 바람직하다.It is preferable that the surface treating agent composition further include an inorganic antibacterial agent or a bioceramic deodorant to 10 parts by weight or less.

상기 무기항균제로는 무기계 세라믹물질인 제올라이트계로 은(Ag) 과 아연(Zn)을 이온 형태로 담지시킨 제올라이트계 무기항균제가 인체에 무해하며 인체에서 발생하는 땀 등의 부패를 방지하는 살균력, 항균력이 뛰어나 바람직하다.The inorganic antimicrobial agent is a zeolite-based inorganic antimicrobial agent, which is an inorganic ceramic material and contains a silver (Ag) and zinc (Zn) in an ionic form. Excellent and desirable.

상기 표면처리제 조성물에는 또한 공지의 음이온 방출을 위한 물질이 부가될 수도 있을 것이다. The surface treating agent composition may also be added with a substance for known anion release.

건조감, 내마모성, 요철감 및 슬립성 등 복합 기능성을 위한 조제로 사용하는 상기 그라스 펄은 지름 5 내지 100미크론의 구상형태가 바람직하며, 더욱 바람직하기로는 8 내지 40 미크론으로 되는 것이고, 그 조성예로서는 BaO 45%, TiO2 40% 및 SiO2 15%의 혼합물을 들 수 있다.The glass pearl used as a preparation for complex functionalities such as dryness, abrasion resistance, unevenness and slipperiness is preferably a spherical form having a diameter of 5 to 100 microns, more preferably 8 to 40 microns, and as a composition example, BaO 45%, 40% TiO 2 , and 15% SiO 2 .

상기 그라스펄의 직경이 5미크론 미만이면 복합기능성의 효과가 미흡하고 100미크론을 초과하면 표면터치가 거칠어 착용감이 불량하고, 표면처리제 수지조성물의 점도가 2,000cps 이하이면 구상 그라스 펄의 자중에 의해 침전하는 문제가 발생하며, 이렇게 되어 구상의 그라스펄이 침전할 경우 표면처리제 수지조성물의 처리에 의한 복합기능성의 물성이 불균일해질 가능성이 있어서 상기 수지조성물의 점도는 2000 cps 이상인 것이 바람직하다.If the diameter of the glass pearl is less than 5 microns, the effect of complex functionalities is insufficient, and if the diameter of the glass pearl exceeds 100 microns, the surface touch is rough, and the wearability is poor. If the viscosity of the surface treatment resin composition is 2,000 cps or less, precipitation of spherical glass pearl is caused In this case, when spherical glass pearls are precipitated, the physical properties of the complex functionalities due to the treatment of the surface treating agent resin composition may be uneven, so that the viscosity of the resin composition is preferably 2000 cps or more.

또한, 상기 그라스펄의 형상은 구상인 것이 바람직한데, 표면의 돌출된 부분이 반구 또는 구상으로 되면 마찰에 의한 슬립성이 우수하게 되고, 피부에 접했을 경우 끈적임 촉감을 느낄수 없고 건조하고 쾌적한 느낌을 부여 할 수 있게 된다. In addition, it is preferable that the shape of the glass pearl is spherical. If the protruding portion of the surface becomes hemispherical or spherical, the slipperiness due to friction is excellent, and when the skin is in contact with the skin, it is not sticky and feels dry and comfortable. It can be given.

건조감의 상승 효과를 위해서 채용되는 브록킹 방지제로는 시판의 실리카계 미분말이 채용될 수 있다.A commercially available fine silica-based powder may be employed as the antiblocking agent employed for the synergistic effect of drying.

상기 표면처리제 조성물에 있어서, 폴리우레탄 수지는 1-컴포넌트형 폴리우레탄수지인 것이 바람직하다.In the surface treatment agent composition, the polyurethane resin is preferably a 1-component type polyurethane resin.

또한, 상기 표면처리제 조성물에 있어서, 상기 표면처리제 수지조성물의 용해 및 점도 조절을 위해 사용하는 혼합 유기용제로는 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤, 에틸아세테이트 등의 단독 또는 2종 이상의 혼합용제로 사용하되 수지등 부재료의 용해성등을 감안하여 적의 조정 사용 하는 것이 좋다.In addition, in the surface treating agent composition, mixed organic solvents used for dissolving and controlling the viscosity of the surface treating agent resin composition may include toluene, methyl ethyl ketone, dimethylformamide, isopropyl alcohol, xylene, perchloroethylene, acetone, It can be used alone or in combination of two or more solvents such as ethyl acetate.

상기 표면처리제 수지조성물은 주제 수지바인더로서 1-콤포넘트형 폴리우레탄 수지를 사용하는 것이 음각롤에서의 전이성이 양호하며 건조후 표면 끈적임 현상도 없앨 수 있어서 바람직하다.The surface treating agent resin composition is preferably one-component polyurethane resin used as the main resin binder because it has good transferability in the intaglio roll and also eliminates surface stickiness after drying.

상기 안료 피그먼트는 안감지 사용을 하지 않는 관계로 심미적 관점에서 사용되는 것이다.The pigment pigment is used from an aesthetic point of view since no lining paper is used.

또한, 본 발명에 있어서, 상기 표면처리제 수지조성물의 점도는 2000 cps 이상인 것이 바람직하다. 상기 점도가 2000 cps미만에서는 그라스펄의 침전이 발생하고 전사코팅시 전사되는 무늬의 치수안정성이 무너질 수 있기 때문에 바람직하지 못하다.Moreover, in this invention, it is preferable that the viscosity of the said surface treating agent resin composition is 2000 cps or more. If the viscosity is less than 2000 cps, it is not preferable because precipitation of glass pearl occurs and the dimensional stability of the pattern to be transferred during transfer coating may be destroyed.

코팅면에 요철감을 줄 수 있는 또다른 효과적인 방법은 최종 배합된 수지조성물의 고형분을 작업성을 저해하지 않는 범위내에서 높게 설계하는 것인데, 구체적으로 고형분 30% 이상이면 효과 발현에 유용할 것이다.Another effective way to impart unevenness to the coating surface is to design a high solids content of the final blended resin composition within a range that does not impair workability, specifically, if the solid content of more than 30% will be useful for expressing the effect.

요철감 부여를 위해 상기 배합약제의 고형분 조정과 더불어 롤제판시 조각의 심도에 의해 그 효과의 상승을 기대 할수 있을 것이다.In addition to adjusting the solid content of the formulation to impart a sense of unevenness, the effect of the increase in the depth of engraving at the time of roll engraving can be expected.

통상 롤무늬 제판 방법은 필름부식제판과 조각제판으로 구분 될 수 있는데, 필름부식제판은 동을 도금한 실린더에 감광액을 도포한 후, 필름을 현상하는 방식으로 약 5~20미크론 심도로 부식이 되어 음각 무늬를 표현하는 방식이고 일반적으로 낮은 심도의 무늬형성이 가능하다. Usually, the rolled plate making method can be divided into a film corrosion plate and engraving plate, the film corrosion plate is subjected to corrosion by about 5 ~ 20 micron depth by applying a photosensitive solution to the copper plated cylinder, then developing the film. It is a way of expressing the intaglio pattern, and generally low depth pattern formation is possible.

한편 조각제판 방식은 밀을 사용하여 음각 무늬를 롤실린더에 표현하며, 통상 100~500미크론의 심도 표현이 가능하여, 표면처리제 수지조성물의 도포 전이량을 극대화 하기가 용이할 것이다. 물론 무늬의 크기 즉, 목(目)수에 따른 적도의 심도를 조정해야 함은 당해업자로서는 용이하게 이해되어질 것이다.On the other hand, engraving engraving method using the mill to express the intaglio pattern on the roll cylinder, and can usually express a depth of 100 ~ 500 microns, it will be easy to maximize the amount of coating transfer of the surface treatment agent resin composition. Of course, it will be readily understood by those skilled in the art that the size of the pattern, that is, the depth of the equator according to the number of necks, must be adjusted.

본 발명의 안감지 대용의 표면처리된 코팅원단을 봉제할 경우 특히 방수 또는 투습방수 원단의 경우 심미적 관점에서 심실링 테이프에도 본 원단과 같은 무늬로 표면처리를 해주어야 함은 당연하다.When sewing the surface-treated coating fabric instead of the lining paper of the present invention, in particular, in the case of waterproof or breathable waterproof fabric, it is natural that the surface treatment should be treated with the same pattern as the fabric even in the asymmetrical tape.

본 발명에 있어서, 상기 제4단계의 건조 공정에 채용되는 열처리챔버는 간접열풍식 또는 직접복사열방식으로 할 수 있다.In the present invention, the heat treatment chamber employed in the drying process of the fourth step may be an indirect hot air type or a direct radiation heat method.

상기와 같은 방법으로 배합된 표면처리제 수지조성물을 음각롤코팅 또는 통상의 전면코팅 방법으로 표면 처리한 후, 반드시 열처리 챔버를 통과시켜 사용한 용제를 증발시키고 수지바인더를 경화시켜 원단에 고착시키는 공정이 필요하다. 여기서 열처리 챔버는 간접열풍식 또는 직접 복사열 방식으로 해도 무관할 것이다. 그러나 직접 열복사 방식은 화재등의 관점에서 각별한 주의가 요망 되는 바, 바람직하기로는 간접 열풍 방식이 좋다.After surface-treating the surface-treated resin composition blended by the above method by intaglio roll coating or conventional front coating method, it is necessary to pass the heat treatment chamber to evaporate the used solvent, harden the resin binder and fix it to the fabric. Do. The heat treatment chamber may be indirect hot air or direct radiant heat. However, the direct heat radiation method requires special attention from the viewpoint of fire, etc., and preferably an indirect hot air method is preferable.

한편, 표면처리제 수지조성물의 처리시 피처리 원단에는 표면장력을 떨어뜨리는 물질, 예를 들면, 발수제, 유연제, 왁스류 등의 사용은 수지조성물의 전이율을 떨어뜨릴 뿐만 아니라 불균일도를 증가 시키는 원인이 되므로 피하는것이 좋다.On the other hand, the use of a material that reduces the surface tension, for example, water repellents, softeners, waxes, etc. in the treated fabric during the treatment of the resin composition of the surface treatment agent not only reduces the transfer rate of the resin composition but also causes an increase in unevenness. This is good to avoid.

본 발명의 또다른 형태에 따르면, 본 발명은 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물로 이루어지는 섬유원단 표면처리제를 제공한다.According to another aspect of the present invention, the present invention is based on a weight ratio of 100 parts by weight of the liquid polyurethane resin, 10 to 100 parts by weight of mixed organic solvent, 10 to 100 parts by weight of glass pearl, 0 to 2 parts by weight of pigment pigment And it provides a fiber fabric surface treatment agent consisting of a mixture of 0.5 to 5 parts by weight of the antiblocking agent.

본 발명은 또한, 상기 제조방법에 의해 제조된 것을 특징으로 하는 건조감이 우수한 패커블 내마모성 투습방수포를 제공한다.The present invention also provides a packable wear-resistant moisture-permeable waterproof cloth excellent in the dry feeling, characterized in that produced by the manufacturing method.

이하에서 본 발명의 바람직한 실시예가 기술되어질 것이나, 이하의 실시예는 어디까지나 본 발명을 예증하기 위한 것으로서 본 발명의 범위를 국한시키는 것으로 해석되어서는 안 될 것이다.Hereinafter, preferred embodiments of the present invention will be described, but the following examples are only intended to illustrate the present invention and should not be construed as limiting the scope of the present invention.

(실시예)(Example)

실시예1 (방수원단 코팅면의 표면처리)Example 1 (Surface Treatment of Waterproof Fabric Coating Surface)

(1) 표면처리제 수지조성물의 준비(1) Preparation of Surface Treatment Resin Composition

액상 폴리우레탄수지100kg, 그라스펄 40kg, 안료피그먼트 토너(안료고형분 2%) 20kg, 제올라이트계 무기항균제 5kg, 및 실리카 분말 2kg을 25kg 의 혼합용제(디메틸포름아마이드:톨루엔:메틸에틸케톤=1:5:2 로 혼합한 혼합용제)에 넣고 분말이 완전히 혼합될 때까지 교반하고, 100메쉬의 거름망으로 필터링하여 두었다. 100 kg of liquid polyurethane resin, 40 kg of glass pearl, 20 kg of pigment pigment toner (2% of pigment solids), 5 kg of zeolite inorganic antimicrobial agent, and 2 kg of silica powder were mixed solvents (dimethylformamide: toluene: methylethylketone = 1: Mixed in a 5: 2 mixture), stirred until the powder was completely mixed, and filtered through a 100 mesh sieve.

단,그라스펄은 구상으로 입경분포 8~20미크론의 것을 사용하였다.However, glass pearl was used as a spherical particle size distribution of 8 to 20 microns.

(2) 음각롤에 의한 표면처리제 수지조성물의 전사코팅(2) Transfer coating of resin composition of surface treatment agent by intaglio roll

나이론 원사를 립스탑 조직으로 제직 및 염색, 발수 가공후, 투습방수 기능성 폴리우레탄수지로 코팅처리된 방수원단이 벳칭기 롤에 감긴 상태로 준비 되었으며, 이것을 음각롤 코팅기에 걸고, 전자조각 제판(심도200미크론, 선수30, 격자형 4각무늬)의 음각롤에 의한 전사코팅 작업을 수행하였다.After weaving, dyeing, and water repellent processing of nylon yarns with a ripstop structure, the waterproof fabric coated with a moisture-permeable waterproof polyurethane resin was prepared in a state of being wound on a betting machine roll. The transfer coating was performed by the negative roll of the micron, the player 30, and the lattice-square pattern.

표면처리제 수지조성물은 상기(1)에서 제조된 수지조성물을 사용하였다. As the surface treating agent resin composition, the resin composition prepared in (1) above was used.

롤에서 풀린 방수원단이 음각롤의 코팅헤드부를 통과하면서 방수원단의 투습방수 기능성 폴리우레탄수지가 코팅된 필름면에 표면처리제 수지조성물이 전사되도록 하였다. 그런다음 표면처리된 방수원단을 열풍에 의한 건조챔버를 통과시켜 표면처리제를 건조시켰다. 챔버의 열풍 온도는 120 ℃로 하였고, 챔버를 통과하는 속도는 10m/min. 이었다.As the waterproof fabric released from the roll passes the coating head of the intaglio roll, the surface treatment resin composition is transferred to the film surface coated with the waterproof moisture-permeable functional polyurethane resin. Then, the surface-treated waterproof fabric was passed through a drying chamber by hot air to dry the surface treatment agent. The hot air temperature of the chamber was 120 ° C., and the rate of passage through the chamber was 10 m / min. It was.

실시예 2Example 2

실시예 1에서 전자조각제판 음각롤 대신 필름부식제판에 의한 심도 30미크론의 음각롤로 전사코팅 작업을 수행하는 것을 제외하고는, 실시예1과 동일한 방법으로 방수원단의 표면처리 작업을 하였다.The surface treatment of the waterproof fabric was carried out in the same manner as in Example 1, except that the transfer coating was performed on the intaglio roll having a depth of 30 microns by the film corrosion plate instead of the engraved roll on the electronic engraving plate.

실시예 3Example 3

실시예 1에서 알루미노실리케이트계 소취제 10kg을 추가하는 것 외에는 실시예1과 동일한 방법으로 전사코팅을 수행하였다.Transfer coating was carried out in the same manner as in Example 1 except for adding 10kg of the aluminosilicate deodorant in Example 1.

비교예 1 Comparative Example 1

그라스펄 대신에 탄산칼슘을 넣는 것을 제외하고, 실시예 1 과 동일한 방법으로 방수원단의 전사코팅 작업을 수행하였다. Transfer coating of the waterproof fabric was carried out in the same manner as in Example 1, except that calcium carbonate was added instead of glass pearl.

비교예 2 Comparative Example 2

그라스펄을 첨가하지 않고, 실시예1 과 동일한 방법으로 방수원단의 전사코팅 작업을 수행 하였다. Without the addition of glass pearl, the transfer coating of the waterproof fabric was carried out in the same manner as in Example 1.

상기와 같이 실시예와 비교예를 실시하여 그 결과물에 대하여 각각 촉감, 내마모성, 착용감, 항균방취 성능, 및 소취성능을 시험하여 아래의 [표1] 내지 [표5]에 나타내었다. Examples and Comparative Examples were carried out as described above, and the results were tested for touch, abrasion resistance, wearing comfort, antibacterial deodorization performance, and deodorizing performance, respectively, and are shown in Tables 1 to 5 below.

시험 1 (손에 의한 촉감 테스트, hand feel test)Test 1 (hand feel test)

각각의 결과물에 대해 손에 의한 관능검사에 의해 촉감을 테스트하고 그 결과를 아래의 표1에 나타내었다.For each result, the sensory test was performed by hand and the results are shown in Table 1 below.

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 요철감 Unevenness OO XX OO XX XX 슬립성Slip OO OO OO XX XX 건조감Dryness OO OO OO XX XX

O ; 좋음  O; good

X ; 나쁨  X; Bad

시험 2 (내마모성 시험)Test 2 (wear resistance test)

각각의 결과물에 대해 동전으로 20회 왕복 마찰운동을 실시하여 코팅 필름의 벗겨짐 여부로 내마모성을 평가하였다.Each result was subjected to 20 reciprocating friction movements with a coin to evaluate the wear resistance of the coating film peeling.

실시예 1Example 1 실시예 2 Example 2 실시예 3 Example 3 비교예 1 Comparative Example 1 비교예 2Comparative Example 2 내마모성Wear resistance O    O O    O O    O X    X X   X

O ; 20회 왕복후에도 전혀 벗겨지지 않음  O; No peel after 20 round trips

X ; 20회 왕복 운동후에 코팅필름이 벗겨져 때처럼 밀림   X; The coating film is peeled off after 20 round trips

시험 3 (착용감)Test 3 (wearing)

착용감을 비교하기 위하여 상기의 실시예와 비교예에서 표면처리된 투습방수원단으로 옷을 만들어 착용감 시험을 실시하였다. In order to compare the feeling of wearing a cloth made of a waterproof waterproof fabric treated in the above Examples and Comparative Examples was subjected to the fit test.

이때, 상기 방수원단들에 별도의 안감지를 대지 않고 제작하였다. In this case, the waterproof fabrics were produced without applying a separate lining paper.

실시예1  Example 1 실시예2Example 2 실시예3Example 3 비교예1Comparative Example 1 비교예 2Comparative Example 2 착용감Fit O O OO XX XX

* 착용자가 피부에 닿는 면을 중심으로 관능검사를 실시하였으며, △는 보통, O 는 쾌적한 느낌, X 는 불쾌한 느낌을 나타냄. * Sensory tests were performed with the wearer touching the skin. △ is normal, O is pleasant and X is unpleasant.

시험 4 (항균 방취 성능) Test 4 (antibacterial deodorization performance)

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 정균감소율Bacteriostatic rate 99.90%99.90% 99.90%99.90% 99.90%99.90% xx xx

* 주) 표준포의 종류 (KSK 0905-1996 ): 면  * Note) Type of standard fabric (KSK 0905-1996): Cotton

사용공시균주 : 균주1 - staphylococcus aureus ATCC 6538 Test strain used: Strain 1-staphylococcus aureus ATCC 6538

균주2 - Klebsiella pneumoniae ATCC 4352                        Strain 2-Klebsiella pneumoniae ATCC 4352

시험 5 (소취 성능) Test 5 (deodorant performance)

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 탈취율Deodorization Rate 30.00%30.00% 30.00%30.00% 60.00%60.00% 10%10% 30%30%

* 탈취율 (가스검지관법) : % * Deodorization rate (gas detection tube method):%

암모니아   ammonia

주) 시험편 : 10 * 10 cm2 Note) Test piece: 10 * 10 cm 2

가스백 : 5L       Gas Bag: 5L

가스백내 가스량 : 3L       Gas volume in gas bag: 3L

측정시간 : 2시간 경과후       Measurement time: After 2 hours

초기농도 :암모니아(100 ppm)       Initial concentration: Ammonia (100 ppm)

탈취율 % = (C b - C s )/ C b)* 100       Deodorization% = (C b-C s) / C b) * 100

C b; blank, 2시간 경과후 시험용기안에 남아있는 시험가스의 농도C b; blank, concentration of test gas remaining in test container after 2 hours

C s; 시료, 2시간 경과후 시험용기안에 남아있는 시험가스의 농도C s; Sample, concentration of test gas remaining in test container after 2 hours

본 발명의 처리 방법에 의하면, 표면처리제 수지조성물을 음각무늬롤로부터 원단 코팅면에 효과적으로 견고하게 전사시킴으로써 요철감, 건조감 및 내마모성을 극대화시키는 효과가 있다.According to the treatment method of the present invention, by effectively and firmly transferring the surface treatment agent resin composition from the intaglio pattern roll to the fabric coating surface, there is an effect of maximizing unevenness, dryness and wear resistance.

본 발명에 따르면, 또한, 봉제품을 만들 경우 별도의 안감지가 필요하지 않게 되어 의류제품이 경량화되고 부피감이 작아지며, 잘 접어지므로 패커블(Packable)하게 되는 효과가 있다. According to the present invention, there is no need for a separate lining paper when making the sewing product, the clothing product is lighter, the volume is smaller, and because it is folded well, there is an effect that can be packable (Packable).

또한, 본 발명의 코팅방법에 따르면, 코팅면의 내구성이 강하여 피부와 접촉시 내스크래치성이 좋고 건조감이 우수하여 쾌적한 착용감을 부여하는 효과가 있어서 더운 날씨에도 시원한 감이 부여되는 효과가 있다.In addition, according to the coating method of the present invention, the durability of the coating surface is strong scratch resistance when in contact with the skin and excellent drying feeling has the effect of providing a comfortable wearing effect has a cool feeling even in hot weather.

또한, 본 발명에 따르면, 전사코팅에 있어서, 전사효율이 우수하게 되는 효과가 있다.Further, according to the present invention, in the transfer coating, there is an effect that the transfer efficiency is excellent.

따라서 본 발명에 의해 제조된 투습방수원단은 가볍고,부피가 작아 일반 캐주얼, 스포츠용, 일시적인 방수 방풍용의 패커블 의류에 매우 유용하게 채용될 수 있다.Therefore, the moisture-permeable waterproof fabric manufactured by the present invention is light and has a small volume, so that it can be very usefully employed for packable clothing for general casual, sports, and temporary waterproof windproof.

또한, 본 발명에 따르면 항균방취성, 소취성, 음이온방출 기능 등 복합 기능성이 부가되는 효과가 있다.In addition, according to the present invention has the effect of adding complex functionality such as antibacterial deodorant, deodorant, anion release function.

Claims (14)

원단에 발수가공을 행하여 발수원단을 제조하는 제1단계; A first step of manufacturing a water repellent fabric by performing water repellent on the fabric; 상기 발수원단에 투습방수코팅가공을 행하여 방수원단을 제조하는 제2단계; A second step of manufacturing a waterproof fabric by performing a waterproof coating on the water-repellent fabric; 상기 투습방수코팅가공되어 롤상으로 공급되어 온 원단에 그라스펄이 함유된 표면처리제 수지조성물을 음각롤의 표면상에서 공급하여 양변부를 막아 수지조성물의 변부 이탈을 막고, 스크랩퍼로 롤표면을 균일하게 스크랩핑하여 음각이외의 부위에 있는 수지조성물을 제거한 후 방수원단의 코팅면에 전사코팅하여 전사코팅된 원단을 제조하는 제3단계; 및 The surface-treatment resin composition containing glass pearl was supplied to the fabric supplied with the moisture-permeable waterproof coating on the surface of the intaglio roll to block both sides to prevent deviation of the edge of the resin composition, and scrap the roll surface uniformly with a scraper A third step of manufacturing a transfer-coated fabric by transferring the coating composition of the waterproof fabric after removing the resin composition in portions other than the intaglio by ping; And 상기 전사코팅된 원단을 건조하는 제4단계;로 이루어지는 것을 특징으로 하는 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법.The fourth step of drying the transfer-coated fabric; manufacturing method of packable wear-resistant moisture-resistant waterproof excellent waterproofing, characterized in that consisting of. 삭제delete 제 1 항에 있어서,The method of claim 1, 상기 음각롤의 심도는 100 내지 300 미크론인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법.Depth of the intaglio roll is 100 to 300 microns, characterized in that the packable wear-resistant moisture-proof waterproof fabric excellent in dry feeling. 제 1 항에 있어서,The method of claim 1, 상기 표면처리제 수지조성물은 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법.The surface treating agent resin composition is 10 to 100 parts by weight of mixed organic solvent, 10 to 100 parts by weight of glass pearl, 0 to 2 parts by weight of pigment pigment, and 0.5 to 1 part by weight, based on 100 parts by weight of the liquid polyurethane resin. The manufacturing method of the packable wear-resistant moisture-proof waterproof cloth excellent in the dry feeling, characterized in that 5 parts by weight of the mixture. 제 4 항에 있어서,The method of claim 4, wherein 상기 표면처리제 조성물에는 무기항균제 또는 바이오세라믹계 소취제가 1 내지 10중량부로 더 포함되는 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. The surface treating agent composition is an inorganic antimicrobial agent or bioceramic deodorant further comprises 1 to 10 parts by weight of the packable wear-resistant moisture-proof waterproof fabric excellent in dry feeling, characterized in that it further comprises. 제 5 항에 있어서,The method of claim 5, 상기 무기항균제는 무기계 세라믹물질 제올라이트계인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법.The inorganic antimicrobial agent is an inorganic ceramic material zeolite type, characterized in that the packable wear-resistant moisture-proof waterproof fabric excellent in the dry feeling. 제 4 항에 있어서,The method of claim 4, wherein 상기 그라스펄은 입경분포가 5 내지 100 미크론이고, 구형이며, 산화바륨, 산화티탄 및 실리카(SiO2) 중 어느하나 또는 둘이상의 혼합물인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. The glass pearl has a particle size distribution of 5 to 100 microns, a spherical shape, the manufacturing of the packable wear-resistant moisture-proof waterproof foam having excellent dry feeling, characterized in that any one or a mixture of two or more of barium oxide, titanium oxide and silica (SiO 2 ). Way. 제 4 항에 있어서,The method of claim 4, wherein 상기 표면처리제 수지조성물에 있어서, 상기 혼합유기용제는 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤, 에틸아세테이트로 이루어지는 군중에서 선택되는 하나 또는 둘이상의 혼합물인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. In the surface treating agent resin composition, the mixed organic solvent is one or two or more mixtures selected from the group consisting of toluene, methyl ethyl ketone, dimethylformamide, isopropyl alcohol, xylene, perchloroethylene, acetone, and ethyl acetate. The manufacturing method of the packable wear-resistant moisture-proof waterproof fabric excellent in the dry feeling. 제 1 항에 있어서,The method of claim 1, 상기 제4단계의 건조 공정에 채용되는 열처리챔버는 간접열풍식 또는 직접복사열방식인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. The heat treatment chamber employed in the drying step of the fourth step is a method of manufacturing a packable wear-resistant moisture-resistant waterproof excellent waterproofing, characterized in that the indirect hot air type or direct radiation heat method. 제 1 항에 있어서,The method of claim 1, 상기 표면처리제 수지조성물의 점도는 2,000 ∼ 50,000 cps인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. The viscosity of the surface treatment agent resin composition is 2,000 to 50,000 cps, characterized in that the packable wear-resistant moisture-proof waterproof fabric excellent in the dry feeling. 제1항에 있어서,The method of claim 1, 상기 표면처리제 수지조성물중 고형분이 30% ∼ 50%인 것을 특징으로 하는 상기 건조감이 우수한 패커블 내마모성 투습방수포의 제조방법. Solid content is 30% -50% in the said surface treating agent resin composition. The manufacturing method of the packable wear-resistant moisture-proof waterproof fabric excellent in the dryness characterized by the above-mentioned. 중량비율로 액상폴리우레탄수지 100 중량부에 대하여, 혼합유기용제 10 내지 100 중량부, 그라스펄 10 내지 100 중량부, 안료피그먼트 0 내지 2 중량부, 및 블록킹 방지제 0.5 내지 5 중량부의 혼합물로 이루어지는 것을 특징으로 하는 제1항의 투습방수원단 가공을 위한 섬유원단 표면처리제.It consists of 10-100 weight part of mixed organic solvents, 10-100 weight part of glass pearls, 0-2 weight part of pigment pigments, and 0.5-5 weight part of antiblocking agents with respect to 100 weight part of liquid polyurethane resins by weight ratio. Fiber fabric surface treatment agent for processing the water-permeable waterproof fabric of claim 1. 제1항, 제3항 내지 제11항 중 어느 한 항의 제조방법에 의해 제조된 건조감이 우수한 패커블 내마모성 투습방수포.The packable wear-resistant moisture-permeable waterproof cloth which is excellent in the dry feeling manufactured by the manufacturing method of any one of Claims 1, 3-11. 제13항의 투습방수포가 채용되어 봉제된 건조감이 우수한 패커블 의류. The packable garment which is excellent in the dry feeling sewn by adopting the moisture-permeable waterproof cloth of claim 13.
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