KR100634194B1 - A pole for battrry and the product methode - Google Patents

A pole for battrry and the product methode Download PDF

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KR100634194B1
KR100634194B1 KR1020030058396A KR20030058396A KR100634194B1 KR 100634194 B1 KR100634194 B1 KR 100634194B1 KR 1020030058396 A KR1020030058396 A KR 1020030058396A KR 20030058396 A KR20030058396 A KR 20030058396A KR 100634194 B1 KR100634194 B1 KR 100634194B1
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calcium
silver
lithium
substrate
plate
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KR20050020438A (en
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박대석
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박대석
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/14—Electrodes for lead-acid accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

본 발명은 밧데리의 극판 및 그 제조방법에 관한 것으로써, 고용량 및 고수명을 가지는 밧데리용 극판을 제공하여 일반 가정이나 사무실에서 사용되는 가전제품에 적용 사용될 수 있는 밧데리용 극판을 제공하므로써 야간(심야전력)에 충전하여 사용함으로써 에너지 세이브 및 에너지 절약을 이룰 수 있도록 하려는 목적으로 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분말 100kg당 황산 6리터와 물 8리터, 은과 칼슘 및 리듐분말을 전체성분의 0.05% 첨가하고 약 25-35분동안 믹싱하여 은,칼슘,리듐혼합액을 형성하는 제1공정과, 상기한 제1공정 후 칼슘기판(Pb+Ca)의 외주면에 상기 은,칼슘,리듐혼합액을 도포하는 제2공정과, 상기한 제2공정 후 상기 은,칼슘,리듐혼합액이 도포된 칼슘기판을 120℃ 상에서 1차 건조하여 표면에 잔존하는 물과 황산분을 제거하는 제3공정과, 상기 제3공정후 1차 건조된 기판을 습도 80-95%, 온도 45-55℃ 상에서 18-20시간정도 보존하는 제4공정과, 상기 제4공정후 보관된 기판을 습도 0%, 온도 40-50℃ 상에서 10시간정도 2차건조하여 극판을 완성하는 제5공정을 통하여 판상의 칼슘기판(Pb+Ca)의 외주면에 은,칼슘,리듐혼합액(ACL=Ag+Ca+Li)이 코팅이 된 밧데리용 극판을 제공한다.The present invention relates to a battery pole plate and a method of manufacturing the same, providing a battery pole plate having a high capacity and a long life, by providing a battery pole plate that can be applied to home appliances used in general home or office (nighttime Pure lead (Pb) is pulverized into powder (80-120 mesh) for the purpose of energy saving and energy saving by charging and using it, and 6 liters of sulfuric acid, 8 liters of water, silver And calcium and lithium powder are added at 0.05% of the total ingredients and mixed for about 25-35 minutes to form a mixture of silver, calcium and lithium, and the outer peripheral surface of the calcium substrate (Pb + Ca) after the first process. The second step of applying the silver, calcium, lithium mixture to the second step, and after the second step the calcium substrate coated with the silver, calcium, lithium mixture is first dried at 120 ℃ water remaining on the surface and sulfuric acid powder Article A third step of removing the first step; and a fourth step of preserving the first dried substrate after the third step at a humidity of 80-95% and a temperature of 45-55 ° C. for about 18-20 hours, and a substrate stored after the fourth step. The second step of drying the electrode plate at 0% humidity and 40-50 ℃ for 10 hours to complete the electrode plate, the silver, calcium, and lithium mixture (ACL = Ag +) on the outer circumferential surface of the plate-shaped calcium substrate (Pb + Ca) Ca + Li) to provide a battery plate with a coating.

밧데리, 극판, 심야전기, 충전, 은,칼슘,리듐혼합액.Batteries, pole plates, late-night electricity, charging, silver, calcium, lithium mixtures.

Description

밧데리용 극판 및 그 제조방법{A pole for battrry and the product methode}A pole for battrry and the product methode

도 1은 본 발명이 적용된 밧데리를 보인 개략 단면 예시도,1 is a schematic cross-sectional view showing a battery to which the present invention is applied,

[도면중 중요한 부분에 대한 부호의 설명][Explanation of symbols for important parts of the drawings]

1 : 밧데리, 2 : 공간부,1: battery, 2: space,

3 : 하우징, 4 : 양극판,3: housing, 4: positive plate,

5 : 음극판, 6 : 세퍼레이터,5: negative electrode plate, 6: separator,

7 : 젤 전해액.7: gel electrolyte solution.

본 발명은 밧데리의 극판 및 그 제조방법에 관한 것으로써, 보다 상세하게는 가정용 밧데리에 사용되는 극판으로 고용량 및 고수명을 가지는 밧데리의 극판 및 그 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a battery pole plate and a method for manufacturing the same, and more particularly, to a battery plate having a high capacity and a long life, and a method for manufacturing the same, which is used for household batteries.

일반적으로 밧데리는 하우징의 내부에 (-)극판과 (+)극판이 내장된 구조를 가지고 있으며 하우징의 내부에는 황산이 충진되어 있다.In general, the battery has a structure in which a negative electrode plate and a positive electrode plate are built in a housing, and sulfuric acid is filled in the housing.

이와 같은 밧데리는 자동차의 엔진 점화용으로 널리 사용되어 지고 있다.Such batteries are widely used for engine ignition of automobiles.

그러나 상기와 같은 종래의 밧데리는 그 수명이 짧고 용량이 적어 일반가정이나 사무실 등의 가전제품에는 사용이 어려워 그 사용이 제한 되는 문제점이 있었다.However, the conventional battery as described above has a problem that its use is limited because its life is short and its capacity is difficult to use in home appliances such as general homes or offices.

본 발명은 상기와 같은 종래의 문제점들을 해결하기 위하여 안출된 것으로서, 본 발명의 목적은 고용량 및 고수명을 가지는 밧데리용 극판을 제공하여 일반 가정이나 사무실에서 사용되는 가전제품에 적용 사용될 수 있는 밧데리용 극판을 제공하므로써 야간(심야전력)에 충전하여 사용함으로써 에너지 세이브 및 에너지 절약을 이룰 수 있도록 하는데 있다.The present invention has been made to solve the above-mentioned conventional problems, the object of the present invention is to provide a battery plate having a high capacity and long life for the battery that can be applied to home appliances used in general home or office By providing the pole plate, it is possible to achieve energy saving and energy saving by charging and using it at night (night power).

상기와 같은 본 발명의 목적을 달성하기 위한 본 발명의 극판 및 그 제조방법은 판상의 칼슘기판(Pb+Ca)의 외주면에 은,칼슘,리듐혼합액(ACL=Ag+Ca+Li)(이하 '은혼합액'이라 약칭한다)이 코팅이 된 것으로 그 제조는 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분쇄된 분말 100kg당 황산 6리터와 물 8리터에 은과 칼슘 및 리듐분말을 전체성분의 0.05% 첨가하고 약 25-35분동안 믹싱하여 은혼합액을 형성하는 제1공정과, 상기한 제1공정 후 칼슘기판(Pb+Ca)의 외주면에 상기 은혼합액을 도포하는 제2공정과, 상기한 제2공정 후 상기 은혼합액이 도포된 칼슘기판을 120℃ 상에서 1차 건조하여 표면에 잔존하는 물과 황산분을 제거하는 제3공정과, 상기 제3공정후 1차 건조된 기판을 습도 80-95%, 온도 45-55℃ 상에서 18-20시간정도 보존하는 제4공정과, 상기 제4공정후 보관된 기판을 습도 0%, 온도 40-50℃ 상에서 10시간정도 2차건조하여 극판을 완성하는 제5공정을 포함하고 있다In order to achieve the object of the present invention as described above, the electrode plate of the present invention and a manufacturing method thereof have a silver, calcium, and lithium mixture (ACL = Ag + Ca + Li) (hereinafter '' The silver mixture is coated), and its manufacture is pulverizing lead lead (Pb) into powder (80-120 mesh), and 6 liters of sulfuric acid and 8 liters of water and calcium per 100 kg of the ground powder And adding a lithium powder of 0.05% of the total ingredients and mixing the mixture for about 25-35 minutes to form a silver mixture, and applying the silver mixture to the outer circumferential surface of the calcium substrate (Pb + Ca) after the first process. And a third step of first drying the calcium substrate coated with the silver mixture solution at 120 ° C. after the second step to remove water and sulfuric acid remaining on the surface, and after the third step. A fourth step of preserving the first dried substrate at a humidity of 80-95% and a temperature of 45-55 ° C. for about 18-20 hours, and storing after the fourth step The fifth step is to complete the electrode plate by secondary drying the substrate on 0% humidity and 40-50 ℃ for 10 hours.

이하, 본 발명의 밧데리용 극판과 그 제조방법을 상세히 설명하면 다음과 같다.Hereinafter, the battery pole plate of the present invention and a manufacturing method thereof will be described in detail.

본 발명의 밧데리용 극판은 판상의 칼슘기판(Pb+Ca)의 외주면에 상기한 은혼합액(=Ag+Ca+Li 이하 'ACL'이라 한다)이 코팅된 것으로 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분쇄된 분말 100kg당 황산 6리터와 물 8리터에 은과 칼슘 및 리듐분말을 전체성분의 0.05% 첨가하고 약 25-35분동안 믹싱하여 은혼합액을 형성하는 제1공정과, 상기한 제1공정 후 칼슘기판(Pb+Ca)의 외주면에 상기 은혼합액을 도포하는 제2공정과, 상기한 제2공정 후 상기 은혼합액이 도포된 칼슘기판을 120℃ 상에서 1차 건조하여 표면에 잔존하는 물과 황산분을 제거하는 제3공정과, 상기 제3공정후 1차 건조된 기판을 습도 80-95%, 온도 45-55℃ 상에서 18-20시간정도 보존하는 제4공정과, 상기 제4공정후 보관된 기판을 습도 0%, 온도 40-50℃ 상에서 10시간정도 2차건조하여 극판을 완성하는 제5공정을 통해 제조된다.
상기에서 제5공정의 2차건조는 제습이 완료되어 습도가 0%환경을 유지하는 별도의 건조실에서 수행을 하도록 되어 있다.
상기에서 "은혼합액" 이란 은(Ag)과 칼슘(Ca)와 리듐(Li)을 혼합한 혼합물질을 의미하는 것으로 별도의 학술용어가 없어 본 발명에서는 은(Ag)과 칼슘(Ca)와 리듐(Li)을 혼합한 혼합물질을 "은혼합물"이라 칭하여 본 발명을 설명한 것이다.Battery electrode plate of the present invention is coated with the above-described silver mixture (= Ag + Ca + Li or 'ACL') on the outer circumferential surface of the plate-shaped calcium substrate (Pb + Ca) lead (Pb) of pure lead powder ( 80-120 mesh), and 6 liters of sulfuric acid and 8 liters of water per 100 kg of the pulverized powder are added with 0.05% of silver, calcium and lithium powder, and mixed for about 25-35 minutes to form a silver mixture. A first step, a second step of applying the silver mixture to the outer circumferential surface of the calcium substrate (Pb + Ca) after the first step, and a calcium substrate coated with the silver mixture after the second step at 120 ° C. A third step of removing the water and sulfuric acid remaining on the surface by primary drying, and storing the first dried substrate for about 18-20 hours at a humidity of 80-95% and a temperature of 45-55 ° C after the third step. A fifth step of second step drying the substrate stored after the fourth step and the fourth step at a humidity of 0% and a temperature of 40-50 ° C. for about 10 hours to complete the electrode plate; It is produced through the process.
The secondary drying of the fifth step is to be carried out in a separate drying room in which the dehumidification is completed and the humidity maintains 0% environment.
The term "silver mixture" refers to a mixture of silver (Ag), calcium (Ca), and lithium (Li). In the present invention, there is no separate terminology so that silver (Ag), calcium (Ca) and lithium are used. The mixture of the mixture of (Li) is referred to as "silver mixture" to explain the present invention.

상기와 같은 공정을 통해 본 발명의 양극판이 형성되며 본 발명의 음극판은 상기한 제1공정이 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분말 100kg당 황산 6리터와 물 8리터에 은과 칼슘 및 리듐분말을 전체성분의 0.05%을 첨가하고 산화방지오일을 0.5리터 첨가하여 약 25-35분동안 믹싱하여 은혼합액을 형성하는 것으로 이루어진다.
상기에서 은혼합액은 은과 칼슘과 리듐이 일정 비율로 혼합된 액상의 혼합물을 의미한다.The positive electrode plate of the present invention is formed through the above-described process, and the negative electrode plate of the present invention is the first step in which the lead lead (Pb) is ground into powder (80-120 mesh), and 6 liters of sulfuric acid per 100 kg of powder To 8 liters of water, 0.05% of silver, calcium and lithium powder are added and 0.5 liters of antioxidant oil is added and mixed for about 25-35 minutes to form a silver mixture.
In the above, the silver mixture means a mixture of a liquid in which silver, calcium, and lithium are mixed at a predetermined ratio.

이와 같이 이루어지는 본 발명의 밧데리용 극판은 도1에서와 같이 밧데리를 구성하는데 사용되며 본 발명이 적용되는 밧데리(1)는 내부에 일정한 공간부(2)를 가지는 하우징(3)과, 상기 하우징(3)의 공간부(2)에 배열 마련되는 판상의 양극판(4) 및 음극판(5)과, 상기 양극판(4)의 외측부에 양극판(4)이 내재되도록 일정한 간격을 가지고 상하가 개방되며 상기 양극판(4)과 음극판(5)이 서로 접촉되는 것을 방지하도록 마련되는 관상의 세퍼레이터(6)와, 상기 하우징(3)의 내부에 충전(充塡)되는 젤상의 전해액(7)을 가지고 있다.
상기에서 양극판(4)은 본 발명에 의해 제조되는 은혼합물(ACL: Ag+Ca+Li)과 산화연(PbO2)의 결합으로 이루어지며 상기 음극판은 은혼합물(ACL: Ag+Ca+Li)과 순연(Pb)의 결합으로 이루어저 있다.The battery pole plate of the present invention made as described above is used to construct a battery as shown in FIG. 1, and the battery 1 to which the present invention is applied has a housing 3 having a constant space portion 2 therein, and the housing ( 3) the plate-shaped positive electrode plate 4 and the negative electrode plate 5 arranged in the space part 2 of the space, and the upper and lower sides are opened at regular intervals so that the positive electrode plate 4 is embedded in the outer portion of the positive electrode plate 4 and the positive electrode plate (4) and the negative electrode plate (5) are provided with a tubular separator (6) provided to prevent contact with each other, and a gel electrolyte (7) filled in the housing (3).
The positive electrode plate 4 is made of a combination of a silver mixture (ACL: Ag + Ca + Li) and lead oxide (PbO 2 ) prepared by the present invention, the negative plate is a silver mixture (ACL: Ag + Ca + Li) And pure lead (Pb).

상기와 같은 본 발명이 적용된 밧데리(1)는 충전은 야간(심야전력)시에 사용되며 음극판(5)과 양극판(4) 그리고 젤전해질(7)에 투입되는 전기에너지를 점차적으로 가역 시키면 양극판(4)은 은혼합물과 산화연(ACL+PbO2)으로 이온화 되어가며, 음극판(5)은 은혼합물과 연(ACL+Pb)으로 이온화되면서 기전력이 저장된다.
이때 젤상의 전해액(7)에 의해 기전력의 흐름이 원활하게 된다.The battery (1) to which the present invention is applied as described above is used for charging at night (night power), and gradually reverses the electrical energy input to the negative electrode plate 5, the positive electrode plate 4, and the gel electrolyte 7. 4) is ionized with a silver mixture and lead oxide (ACL + PbO 2 ), and the negative electrode plate 5 is ionized with a silver mixture and lead (ACL + Pb) to store electromotive force.
At this time, the electromotive force flows smoothly by the gel electrolyte 7.

그리고 방전시에는 음극판(5)과 양극판(4) 모두는 은혼합액과 젤과 연(ACL+gel+PbSO4)으로 변화하면서 에너지가 빠저나가게 된다.
이때 젤상의 전해액(7)은 전해액의 비중저하로 생기는 전류의 감소 및 저하를 최대한 억제하기 때문에 그 용량의 변화가 적어 오랫동안 전압을 안정적으로 유지시켜 주므로 가정용 전기제품에 안전하게 사용할 수 있도록 용량이 증대되며 수명이 증대됨을 알 수있다.At the time of discharge, both the negative electrode plate 5 and the positive electrode plate 4 are changed into a silver mixture, a gel, and a lead (ACL + gel + PbSO 4 ).
At this time, since the gel-like electrolyte 7 suppresses the decrease and decrease of the current caused by the specific gravity decrease of the electrolyte as much as possible, the capacity is increased so that it can be safely used for household electrical appliances because the voltage is kept small for a long time. It can be seen that the service life is increased.

이와 같이 본 발명은 고용량 및 고수명을 가지는 밧데리용 극판을 제공하여 일반 가정이나 사무실에서 사용되는 가전제품에 적용 사용될 수 있는 밧데리용 극판을 제공하므로써 야간(심야전력)에 충전하여 사용함으로써 에너지 세이브 및 에너지 절약을 이룰 수 있도록 하는 효과가 있는 유용한 발명이다.As such, the present invention provides a battery pole plate having a high capacity and a long life, and thus provides a battery pole plate that can be applied to home appliances used in homes or offices. It is a useful invention that has the effect of achieving energy savings.

Claims (3)

판상의 칼슘기판(Pb+Ca)의 외주면에 은,칼슘,리듐혼합액(ACL=Ag+Ca+Li)이 코팅된 것을 특징으로 하는 밧데리용 극판.A battery plate, characterized in that the outer surface of the plate-shaped calcium substrate (Pb + Ca) is coated with a silver, calcium, lithium mixture (ACL = Ag + Ca + Li). 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분말 100kg당 황산 6리터와 물 8리터에 은과 리듐분말을 전체성분의 0.05% 첨가하고 약 25-35분동안 믹싱하여 은,칼슘,리듐혼합액을 형성하는 제1공정과,Pure lead (Pb) is ground into a powder (80-120 mesh), and 6 liters of sulfuric acid and 8 liters of water are added to 0.05 liters of silver and lithium powder per 100 kg of the powder, followed by mixing for about 25-35 minutes. A first step of forming a silver, calcium and lithium mixture, 상기한 제1공정 후 칼슘기판(Pb+Ca)의 외주면에 상기 은,칼슘,리듐혼합액을 도포하는 제2공정과,A second step of applying the silver, calcium, and lithium mixture to the outer circumferential surface of the calcium substrate (Pb + Ca) after the first step; 상기한 제2공정 후 상기 은,칼슘,리듐혼합액이 도포된 칼슘기판을 120℃ 상에서 1차 건조하여 표면에 잔존하는 물과 황산분을 제거하는 제3공정과,A third step of firstly drying the calcium substrate coated with the silver, calcium, and lithium mixtures at 120 ° C. after the second step to remove water and sulfuric acid remaining on the surface; 상기 제3공정후 1차 건조된 기판을 습도 80-95%, 온도 45-55℃ 상에서 18-20시간정도 보존하는 제4공정과,A fourth step of preserving the first dried substrate after the third step at a humidity of 80-95% and a temperature of 45-55 ° C. for about 18-20 hours; 상기 제4공정후 보관된 기판을 습도 0%, 온도 40-50℃ 상에서 10시간정도 2차건조하여 극판을 완성하는 제5공정을 포함하는 것을 특징으로 하는 밧데리용 극판 제조방법.And a fifth step of completing the pole plate by secondary drying the substrate stored after the fourth step at a humidity of 0% and a temperature of 40 to 50 ° C. for about 10 hours. 제 2항에 있어서,The method of claim 2, 상기한 제1공정은 순연의 납(Pb)을 분말(80-120 메시)로 분쇄하고, 상기 분말 100kg당 황산 6리터와 물 8리터에 은과 리듐분말을 전체성분의 0.05%을 첨가하고 산화방지오일을 0.5리터 첨가하여 약 25-35분동안 믹싱하여 은,칼슘,리듐혼합액을 형성하는 것을 특징으로 하는 밧데리용 극판 제조방법.In the first step, pure lead (Pb) is pulverized into powder (80-120 mesh), and 6 liters of sulfuric acid and 8 liters of water are added to 0.05 liters of silver and lithium powder per 100 kg of powder, followed by oxidation. A method for producing a battery plate for a battery, comprising adding 0.5 liter of prevention oil and mixing for about 25 to 35 minutes to form a mixture of silver, calcium, and lithium.
KR1020030058396A 2003-08-22 2003-08-22 A pole for battrry and the product methode KR100634194B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101199025B1 (en) 2011-03-17 2012-11-08 주식회사 웰스텍 Method for regenerating electrode plate of waste battery

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101199025B1 (en) 2011-03-17 2012-11-08 주식회사 웰스텍 Method for regenerating electrode plate of waste battery

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