KR100629205B1 - Exhaust gas cleaning device for engine - Google Patents
Exhaust gas cleaning device for engine Download PDFInfo
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- KR100629205B1 KR100629205B1 KR1020050027048A KR20050027048A KR100629205B1 KR 100629205 B1 KR100629205 B1 KR 100629205B1 KR 1020050027048 A KR1020050027048 A KR 1020050027048A KR 20050027048 A KR20050027048 A KR 20050027048A KR 100629205 B1 KR100629205 B1 KR 100629205B1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N9/00—Electrical control of exhaust gas treating apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/0842—Nitrogen oxides
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
- F01N3/0885—Regeneration of deteriorated absorbents or adsorbents, e.g. desulfurization of NOx traps
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/021—Introducing corrections for particular conditions exterior to the engine
- F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
- F02D41/024—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to increase temperature of the exhaust gas treating apparatus
- F02D41/025—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to increase temperature of the exhaust gas treating apparatus by changing the composition of the exhaust gas, e.g. for exothermic reaction on exhaust gas treating apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/021—Introducing corrections for particular conditions exterior to the engine
- F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
- F02D41/027—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
- F02D41/0275—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus the exhaust gas treating apparatus being a NOx trap or adsorbent
- F02D41/028—Desulfurisation of NOx traps or adsorbent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/04—Introducing corrections for particular operating conditions
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2430/00—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics
- F01N2430/06—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics by varying fuel-air ratio, e.g. by enriching fuel-air mixture
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/04—Sulfur or sulfur oxides
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/14—Nitrogen oxides
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/36—Arrangements for supply of additional fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B29/00—Engines characterised by provision for charging or scavenging not provided for in groups F02B25/00, F02B27/00 or F02B33/00 - F02B39/00; Details thereof
- F02B29/04—Cooling of air intake supply
- F02B29/0406—Layout of the intake air cooling or coolant circuit
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/02—Input parameters for engine control the parameters being related to the engine
- F02D2200/08—Exhaust gas treatment apparatus parameters
- F02D2200/0802—Temperature of the exhaust gas treatment apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/02—EGR systems specially adapted for supercharged engines
- F02M26/04—EGR systems specially adapted for supercharged engines with a single turbocharger
- F02M26/05—High pressure loops, i.e. wherein recirculated exhaust gas is taken out from the exhaust system upstream of the turbine and reintroduced into the intake system downstream of the compressor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/23—Layout, e.g. schematics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Combined Controls Of Internal Combustion Engines (AREA)
- Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
Abstract
본 발명의 목적은 리치 스파이크 제어와 S퍼지 운전을 효율 좋게 실시할 때에 리치 스파이크 동작에 따른 촉매의 과승온을 방지하는 것에 있다.An object of the present invention is to prevent overheating of the catalyst due to the rich spike operation when the rich spike control and the S purge operation are performed efficiently.
이를 위해, 엔진(20)의 배기통로(40)에 설치된 NOx흡장촉매(42)와, 배기통로(40) 내에 리치 스파이크 동작 또는 S퍼지 운전시에 HC를 포함하는 환원제 성분을 공급하는 배기 경유 첨가 인젝터(41)와, 공연비를 리치측으로 제어하는 리치 스파이크 동작을 소정 시간마다 행하고, NOx흡장촉매(42)에 HC성분을 가함과 아울러 S퍼지 온도(T)이상으로 가열함으로써 NOx흡장촉매(42)에 흡장된 유황분을 제거하는 S퍼지 운전을 행하는 제어부(100)와, NOx흡장촉매(42)의 온도를 계측하는 촉매온도 계측센서(101)를 구비하고, 제어부(100)는 촉매온도 계측센서(101)에 의해 계측된 온도에 대한 S퍼지 온도(T)와의 편차에 근거해서 리치 스파이크 동작의 동작 주기를 제어한다.To this end, the NOx storage catalyst 42 installed in the exhaust passage 40 of the engine 20 and the exhaust gas oil supplying the reducing agent component including HC during the rich spike operation or the S purge operation are added to the exhaust passage 40. The injector 41 and the rich spike operation for controlling the air-fuel ratio to the rich side are performed at predetermined times, and the HC component is added to the NOx storage catalyst 42 and the NOx storage catalyst 42 is heated above the S purge temperature T. And a catalyst temperature measuring sensor 101 for measuring the temperature of the NOx storage catalyst 42, and a control unit 100 for performing an S purge operation for removing sulfur content stored therein. The operating cycle of the rich spike operation is controlled based on the deviation from the S purge temperature T with respect to the temperature measured by 101).
엔진, 배가스 정화장치 Engine, Flue Gas Purifier
Description
도 1은 본 발명의 일실시형태에 의한 엔진의 배가스 정화장치의 구성을 도시하는 블록도,BRIEF DESCRIPTION OF THE DRAWINGS The block diagram which shows the structure of the exhaust-gas purification apparatus of the engine by one Embodiment of this invention.
도 2는 단위 시간당의 CO, HC공급량과 촉매온도의 관계를 나타내는 도면,2 is a diagram showing a relationship between a supply temperature of CO and HC per unit time and a catalyst temperature;
도 3은 리치 스파이크 주기 및 리치 스파이크 기간과 단위 시간당의 CO, HC공급량의 관계를 나타내는 도면,3 is a diagram showing the relationship between the rich spike period, the rich spike period, and the amount of CO and HC supplied per unit time;
도 4는 동(同)엔진의 배가스 정화장치에 있어서의 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍, 배기배관 중에 공급되는 CO, HC공급량, 및 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 설명도,Fig. 4 shows the timing of the rich spike signal in the exhaust gas purifying apparatus of the same engine, the timing of the S purge signal for performing the S purge operation, the amount of CO and HC supplied in the exhaust pipe, and the catalyst temperature (catalyst outlet). Explanatory drawing showing time change of gas temperature),
도 5는 동엔진의 배가스 정화장치에 있어서의 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍, 배기배관 중에 공급되는 CO, HC공급량, 및 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 설명도,Fig. 5 shows the timing of the rich spike signal in the exhaust gas purifying apparatus of the same engine, the timing of the S purge signal for performing the S purge operation, the amount of CO and HC supplied in the exhaust pipe, and the catalyst temperature (catalyst outlet gas temperature). An explanatory diagram showing a time change of
도 6은 종래의 배가스 정화장치에 있어서의 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍, 배기배관 중에 공급되는 CO, HC공급량, 및 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 설명도.6 shows the timing of the rich spike signal in the conventional exhaust gas purifier, the timing of the S purge signal for performing the S purge operation, the amount of CO and HC supplied in the exhaust pipe, and the catalyst temperature (catalyst outlet gas temperature). Explanatory diagram showing time change.
[부호의 설명][Description of the code]
10 : 엔진 시스템 20 : 디젤 엔진10: engine system 20: diesel engine
30 : 흡기배관 40 : 배기배관30: intake pipe 40: exhaust pipe
41 : 배기 경유 첨가 인젝터 42 : NOx흡장촉매41: injector with exhaust gas oil 42: NOx storage catalyst
50 : EGR배관 52 : EGR밸브50: EGR piping 52: EGR valve
60 : 과급기 100 : 제어부60: supercharger 100: control unit
101 : 촉매온도 계측센서101: catalytic temperature measurement sensor
본 발명은 내연기관의 배기(排氣)에 포함된 유해 성분을 정화하는 배기 정화기능을 갖춘 엔진의 배가스 정화장치에 관한 것으로, 특히 S퍼지 운전시의 촉매 승온제어에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an exhaust gas purification apparatus for an engine having an exhaust purification function for purifying harmful components contained in exhaust gas of an internal combustion engine.
종래, 엔진의 배기관에 NOx흡장촉매가 설치된 배가스 정화장치가 알려져 있다. 이러한 NOx촉매를 사용한 배가스 정화장치는 흡장한 NOx를 방출ㆍ환원하기 위해서 NOx환원 촉매의 배기 상류측에 경유 등의 환원제를 공급함으로써 촉매에 들어가는 가스의 공기과잉율(이하, 「촉매전λ」라고 함)을 1이하로 저하시키는 리치 스파이크(rich spike)를 정기적(예를 들면, 1분에 1회)으로 행할 필요가 있다. 구체적으로는 엔진의 흡기계의 제어나 포스트 분사(post injection) 등에 의해 λ를 저하시킴과 아울러 촉매 상류의 배기관에 연료를 분사해서 리치 스파이크가 행해진다.2. Description of the Related Art [0002] An exhaust gas purifying apparatus is known in which a NOx storage catalyst is installed in an exhaust pipe of an engine. The exhaust gas purifier using such a NOx catalyst supplies a reducing agent such as light oil to the exhaust upstream side of the NOx reduction catalyst in order to release and reduce the NOx occluded. It is necessary to periodically perform a rich spike that lowers the value to 1 or less (for example, once per minute). Specifically, λ is reduced by controlling the engine intake system, post injection, or the like, and fuel is injected into the exhaust pipe upstream of the catalyst to reach rich spikes.
또한, 리치 스파이크를 실시할 경우에 촉매온도에 따라서 린 연소의 정도와 리치 연소의 정도를 변경하는 기술이 알려져 있다(예를 들면, 특허문헌1 참조).Moreover, when performing rich spikes, the technique of changing the grade of lean combustion and the grade of rich combustion according to a catalyst temperature is known (for example, refer patent document 1).
한편, NOx흡장촉매는 연료 중의 유황분에 의해 유황 피독이 발생한다. 이 유황의 제거를 위해 정기적(예를 들면, 5000km주행에 1회)으로 유황분을 제거하기 위한 방출의 S퍼지 운전을 1분 정도 행할 필요가 있다. S퍼지 운전은, 예를 들면 600℃(S퍼지 온도)이상(以上)의 촉매온도가 필요하다. 이 때문에 배기배관 중에 경유를 첨가하거나, 포스트 분사 등에 의해 HC의 공급을 행함으로써 NOx흡장촉매의 온도를 상승시키는 기술이 알려져 있다(예를 들면, 특허문헌1 참조).On the other hand, in the NOx storage catalyst, sulfur poisoning is caused by sulfur content in fuel. In order to remove this sulfur, it is necessary to carry out the S purge operation of discharge | emission for removing sulfur content regularly (for example, once every 5000 km run) for about 1 minute. S purge operation requires a catalyst temperature of, for example, 600 ° C. (S purge temperature) or more. For this reason, the technique of raising the temperature of a NOx storage catalyst by adding light oil to exhaust pipe or supplying HC by post injection etc. is known (for example, refer patent document 1).
[특허문헌1] 일본 특허 공개 평11-270382호 공보[Patent Document 1] Japanese Patent Application Laid-Open No. 11-270382
상술한 엔진의 배가스 정화장치에서는 다음과 같은 문제가 있었다. 도 6의 그래프 H1∼그래프 H4는, 배가스 정화장치에 있어서의 리치 스파이크 동작을 행하기 위한 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍과, 배기배관 중에 공급되는 CO,HC공급량과, 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 그래프이다. The exhaust gas purification device of the engine described above has the following problems. The graphs H1 to H4 in FIG. 6 are timings of the rich spike signals for performing the rich spike operation in the exhaust gas purifying apparatus, timings of the S purge signals for performing the S purge operation, CO supplied to the exhaust pipe, It is a graph which shows the time change of HC supply amount and catalyst temperature (catalyst outlet gas temperature).
그래프 Hl, H2로부터 알 수 있는 바와 같이, 리치 스파이크 제어와 S퍼지 제어는 독립적으로 행해지고 있기 때문에 리치 스파이크 동작과 S퍼지 운전이 동시에 행해지는 것이었다. 리치 스파이크 동작과 S퍼지 운전은 모두 배기 경유 첨가나 포스트 분사에 의한 HC공급에 의한 것이기 때문에 타이밍에 따라서는 촉매에 공급되는 HC공급이 과잉이 되고, 촉매의 과승온이 생길 우려가 있었다.As can be seen from the graphs H1 and H2, since the rich spike control and the S purge control are performed independently, the rich spike operation and the S purge operation are simultaneously performed. Since both the rich spike operation and the S purge operation are caused by HC supply by addition of exhaust gas oil or post injection, the HC supply to the catalyst may be excessive depending on the timing, resulting in excessive heating of the catalyst.
이 때문에, S퍼지 운전시의 CO,HC공급량을 줄임으로써 HC공급이 과잉이 되지 않도록 하는 것이 생각되지만, 반대로 S퍼지 온도에 도달하는 시간이 길어지거나, S퍼지 온도에 도달하지 않는다고 하는 문제가 있었다.For this reason, it is thought that HC supply will not become excessive by reducing CO and HC supply amount at the time of S purge operation, On the contrary, there existed a problem that the time to reach S purge temperature became long, or S purge temperature did not reach. .
여기에서, 본 발명은 리치 스파이크 제어와 S퍼지 운전을 효율 좋게 행함과 아울러, 리치 스파이크 동작에 따른 촉매의 과승온을 방지할 수 있는 엔진의 배가스 정화장치를 제공하는 것을 목적으로 하고 있다.Here, an object of the present invention is to provide an exhaust gas purifying apparatus for an engine capable of efficiently performing rich spike control and S purge operation and preventing overheating of the catalyst due to rich spike operation.
상기 과제를 해결하여 목적을 달성하기 위해서, 본 발명의 엔진의 배가스 정화장치는 다음과 같이 구성되어 있다.In order to solve the said subject and achieve the objective, the exhaust gas purification apparatus of the engine of this invention is comprised as follows.
(1) 엔진의 배기통로에 설치되어 상기 배기통로에 유입되는 배가스 중의 NOx를 흡장하고 상기 배가스의 공연비가 리치가 될 때에 NOx가 환원 처리되는 촉매와, 상기 배기통로 내에 HC를 포함하는 환원제 성분을 공급하는 환원제 공급부와, 상기 환원제 공급부를 작동시켜서 공연비를 일시적으로 리치측으로 제어하는 리치 스파이크 동작을 소정 시간마다 행하는 리치 스파이크 제어부와, 상기 촉매에 HC성분을 가함과 아울러 소정의 온도이상으로 가열함으로써 촉매에 흡장된 유황분을 제거하는 S퍼지 운전의 필요와 불필요를 판정하는 S퍼지 제어부와, 상기 촉매의 온도를 계측하는 촉매온도 계측센서를 구비하고, 상기 S퍼지 제어부에 의해 S퍼지가 필요하다고 판정되었을 경우에 상기 리치 스파이크 제어부는 상기 촉매온도 계측센서에 의해 계측된 온도에 대한 상기 소정 온도와의 편차에 근거해서 상기 리치 스파이크 동작의 동작 주기를 제어하는 것을 특징으로 한다.(1) a catalyst installed in the exhaust passage of the engine to occlude NOx in the exhaust gas flowing into the exhaust passage and to reduce NOx when the air-fuel ratio of the exhaust gas becomes rich, and a reducing agent component containing HC in the exhaust passage; A rich spike control unit for supplying a reducing agent supplying unit, a rich spike control unit operating the reducing agent supply unit to temporarily control the air-fuel ratio to the rich side at a predetermined time, and adding a HC component to the catalyst and heating the catalyst at a predetermined temperature An S purge control unit for determining the need and unnecessary S purge operation for removing the sulfur content stored in the catalyst, and a catalyst temperature measuring sensor for measuring the temperature of the catalyst, and the S purge control unit has determined that S purge is necessary. In this case, the rich spike control unit measures the temperature measured by the catalyst temperature measuring sensor. To about based on the deviation from the predetermined temperature characterized by controlling the operation period of the rich-spike operation.
(2) 상기 (1)에 기재된 엔진의 배가스 정화장치로서, 상기 편차가 큰 만큼 상기 주기를 짧게 하는 것을 특징으로 한다.(2) An exhaust gas purifying apparatus for an engine according to (1), wherein the cycle is shortened as the deviation is large.
(3) 엔진의 배기통로에 설치되어 상기 배기통로에 유입되는 배가스 중의 NOx를 흡장하고 상기 배가스의 공연비가 리치가 될 때에 NOx가 환원처리되는 촉매와, 상기 배기통로 내에 HC를 포함하는 환원제 성분을 공급하는 환원제 공급부와, 상기환원제 공급부를 작동시켜서 공연비를 일시적으로 리치측으로 제어하는 리치 스파이크 동작을 소정 시간마다 행하는 리치 스파이크 제어부와, 상기 촉매에 HC성분을 가함과 아울러 소정의 온도이상으로 가열함으로써 촉매에 흡장한 유황분을 제거하는 S퍼지 운전의 필요와 불필요를 판정하는 S퍼지 제어부와, 상기 촉매의 온도를 계측하는 촉매온도 계측센서를 구비하고, 상기 S퍼지 제어부에 의해 S퍼지가 필요하다고 판정되었을 경우에 상기 리치 스파이크 제어부는 상기 촉매온도 계측센서에 의해 계측된 온도에 대한 상기 소정 온도와의 편차에 근거해서 상기 리치 스파이크 동작의 동작 기간을 제어하는 것을 특징으로 한다.(3) a catalyst installed in the exhaust passage of the engine to occlude NOx in the exhaust gas flowing into the exhaust passage and to reduce NOx when the air-fuel ratio of the exhaust gas becomes rich, and a reducing agent component containing HC in the exhaust passage; A reducing spike control unit for supplying the reducing agent supplying unit, a rich spike operation for controlling the air-fuel ratio to the rich side temporarily by operating the reducing agent supplying unit every predetermined time, and adding a HC component to the catalyst and heating the catalyst at a predetermined temperature The S purge control unit for determining the need and unnecessary S purge operation for removing the sulfur content occupied by the catalyst, and a catalyst temperature measuring sensor for measuring the temperature of the catalyst, have been determined to be necessary by the S purge control unit. In this case, the rich spike control unit controls the temperature measured by the catalyst temperature measuring sensor. The operation period of the rich spike operation is controlled based on the deviation from the predetermined temperature.
(4) 상기 (3)에 기재된 엔진의 배가스 정화장치로서, 상기 편차가 큰 만큼 상기 주기를 길게 하는 것을 특징으로 한다.(4) An exhaust gas purifying apparatus for the engine according to (3), wherein the cycle is lengthened as the deviation is large.
도 1은 본 발명의 일실시형태에 의한 엔진의 배가스 정화장치(10)의 구성을 도시하는 도면, 도 2는 단위 시간당의 CO, HC공급량과 촉매온도의 관계를 나타내는 도면, 도 3은 리치 스파이크 주기 및 리치 스파이크 기간과 단위 시간당의 CO, HC공급량의 관계를 나타내는 도면, 도 4의 그래프 G1∼그래프 G4는 배가스 정화장치에 있어서의 리치 스파이크 동작을 행하기 위한 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍과, 배기배관 중에 공급되는 CO, HC 공 급량과, 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 그래프이다.BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a diagram showing the configuration of an exhaust gas purifying
엔진 시스템(10)은 디젤 엔진(20)을 구비하고 있다. 디젤 엔진(20)의 흡기측에는 흡기배관(30)이 접속되고 배기측에는 배기배관(40)이 접속되어 있다. 또한, 디젤 엔진(20)의 배기측과 흡기배관(30)은 배가스(EGR가스)를 흡기배관(30)에 환류하는 EGR배관(50)으로 접속되어 있다. 또한, 도 3 중 60은 과급기, 100은 제어장치를 나타내고 있다.The
흡기배관(30)에는 흡기측으로부터 에어플로우 센서(31), 과급기(60)의 컴프레서(61)와, 인터쿨러(32)와, 흡기 스로틀(33)과, EGR배관(50)의 접속부(34)가 설치되어 있다.The
배기배관(40)에는 디젤 엔진(20)측으로부터 과급기(60)의 터빈(62)과, 배기배관(40) 내에 경유를 공급하는 배기 경유 첨가 인젝터(41)와, NOx흡장촉매(42)가 설치되어 있다. NOx흡장촉매(42)는 배기배관(40)에 유입되는 배가스 중의 NOx를 흡장하고, 배가스가 리치로 될 때에 흡장한 NOx를 환원 처리한다.The
EGR배관(50)에는 배기배관(40)측으로부터 배가스를 냉각하는 EGR쿨러(51)와, 배가스의 유량을 조절하는 EGR밸브(52)가 설치되어 있다.The EGR
제어부(100)에는 배기배관(40)의 NOx흡장촉매(42)의 출구측에 배치된 촉매온도 계측센서(101)의 출력이 접속되고, NOx흡장촉매(42)의 촉매온도가 항상 피드백되고 있다.The
이와 같이 구성된 엔진 시스템(10)에서는 다음과 같은 동작으로 S퍼지 운전을 행한다. 즉, 통상의 엔진 운전 중에는 소정의 간격으로 리치 스파이크 동작이 행해지고 있고, 엔진의 연소제어 및 배기 경유 첨가 인젝터(41)로부터 배기배관(40) 내부에 HC를 포함하는 경유 첨가에 의해 실시된다. 이 때, S퍼지 운전의 요구가 있으면, 배기배관(40) 내에 배기 경유 첨가 인젝터(41)로부터 HC공급을 행함으로써 NOx흡장촉매(42)의 승온을 행한다. 이 때, 촉매온도가 S퍼지 온도(T에) 도달하지 않고 있을 경우에는 승온속도가 증대하는 방향, 즉 리치 스파이크 동작의 주기(도 4 중 M)가 짧아지는 바와 같이 리치 스파이크 동작이 제어된다.In the
촉매온도가 S퍼지 온도(T)에 도달하면, 리치 스파이크 동작을 원래의 간격으로 되돌린다. 이 때문에, 촉매온도가 S퍼지 온도(T) 전후를 추이하고, 과승온이 되지 않는다. 또한, 촉매온도가 S퍼지 온도(T)보다 높을 경우에는 리치 스파이크 주기를 길게 하는 바와 같이 제어해도 좋다. 또한, S퍼지 운전이 종료해 통상의 엔진 운전으로 되돌아가면, 리치 스파이크 동작은 통상의 주기로 되돌아가게 된다.When the catalyst temperature reaches the S purge temperature T, the rich spike operation is returned to the original interval. For this reason, catalyst temperature changes before and after S purge temperature T, and it does not become over temperature. Moreover, when catalyst temperature is higher than S purge temperature T, you may control so that a rich spike period may be lengthened. In addition, when the S purge operation ends and returns to the normal engine operation, the rich spike operation returns to the normal cycle.
상술한 바와 같이, 본 실시형태에 의한 엔진 시스템(10)에 있어서는, S퍼지 운전이 개시되면, S퍼지 온도(T)에 대한 촉매온도의 편차가 큰 만큼 리치 스파이크 주기를 짧게 함으로써 HC공급을 늘리고, 단시간에 촉매온도가 S퍼지 온도(T)에 도달하도록 제어할 수 있다. As described above, in the
이것은 도 2 및 도 3으로부터 알 수 있는 바와 같이, 리치 스파이크 주기를 짧게 하는 만큼 단위 시간당의 CO,HC의 공급량이 증대하고, 결과적으로 촉매의 온도상승량을 크게 할 수 있는 것을 의미한다. 이 때문에, 리치 스파이크를 실시하면서 S퍼지 운전에 의한 NOx흡장촉매(42)에 흡장된 유황분 제거를 원활하게 행할 수 있음과 아울러 과승온을 방지할 수 있다.As can be seen from Figs. 2 and 3, the shorter the rich spike period means that the supply amount of CO and HC per unit time increases, and as a result, the temperature increase of the catalyst can be increased. For this reason, while performing rich spikes, the sulfur content stored in the
도 5의 그래프 L1∼L4는 엔진 시스템(10)의 변형예에 의한 배가스 정화장치에 있어서의 리치 스파이크 동작을 행하기 위한 리치 스파이크 신호의 타이밍, S퍼지 운전을 행하기 위한 S퍼지 신호의 타이밍과, 배기배관 중에 공급되는 CO, HC공급량과, 촉매온도(촉매 출구 가스 온도)의 시간변화를 나타내는 그래프이다.The graphs L1 to L4 in FIG. 5 are the timings of the rich spike signals for performing the rich spike operation in the exhaust gas purifying apparatus according to the modification of the
상술한 예에서는 리치 스파이크 동작의 주기를 조정하도록 하고 있지만, 본 변형예에서는 리치 스파이크 기간(1회당의 리치 스파이크를 행하고 있는 시간)을 조정하는 것이다. 즉, 통상의 엔진 운전 중에는 소정의 간격으로, 그리고 일정한 기간의 리치 스파이크 동작이 행해지고 있다. 이 때, S퍼지 운전의 요구가 있으면, 배기배관(40) 내에 HC공급을 행함으로써 NOx흡장촉매(42)의 승온을 행한다. 이 때, 촉매온도가 S퍼지 온도(T)에 도달하지 않고 있을 경우에는, 승온속도가 증대하는 방향, 즉 리치 스파이크 동작의 기간(도 5 중 N)이 길어지는 바와 같이 리치 스파이크 동작이 제어된다.In the above-described example, the period of the rich spike operation is adjusted, but in the present modification, the rich spike period (time during which rich spikes are performed per one time) is adjusted. That is, the rich spike operation | movement of predetermined period and a fixed period is performed during normal engine operation. At this time, when the S purge operation is requested, the temperature of the
촉매온도가 S퍼지 온도(T)에 도달하면, 리치 스파이크 기간이 원래의 길이로 되돌아간다. 이 때문에, 촉매온도가 S퍼지 온도(T) 전후를 추이하고, 과승온이 되지 않는다. 또한, 촉매온도가 S퍼지 온도(T)보다 높을 경우에는 리치 스파이크 기간을 짧게 하도록 제어해도 좋다. 또한, S퍼지 운전이 종료해 통상의 엔진 운전으로 되돌아오면, 리치 스파이크 기간은 통상의 길이로 되돌아가게 된다. 본 변형예에 있어서도, 상술한 리치 스파이크 주기를 제어할 경우와 같은 효과를 얻을 수 있다.When the catalyst temperature reaches the S purge temperature T, the rich spike period returns to its original length. For this reason, catalyst temperature changes before and after S purge temperature T, and it does not become over temperature. In addition, when the catalyst temperature is higher than the S purge temperature T, it may be controlled to shorten the rich spike period. In addition, when the S purge operation ends and returns to normal engine operation, the rich spike period returns to the normal length. Also in this modification, the same effects as in the case of controlling the rich spike period described above can be obtained.
또한, 본 발명은 상기 실시형태에 한정되는 것이 아니다. 예를 들면, 상술한 예에서는 리치 스파이크 주기, 리치 스파이크 기간의 어느 하나를 제어하고 있지만, 양자를 동시에 제어하도록 해도 좋다. 이 외에, 본 발명의 요지를 일탈하지 않는 범위에서 여러가지 변형 실시 가능한 것은 물론이다.In addition, this invention is not limited to the said embodiment. For example, in the above example, either the rich spike period or the rich spike period is controlled, but both may be controlled at the same time. In addition, of course, various deformation | transformation is possible in the range which does not deviate from the summary of this invention.
본 발명에 의하면, 리치 스파이크 제어와 S퍼지 운전을 효율 좋게 실시할 수 있음과 아울러 리치 스파이크 동작에 따른 촉매의 과승온을 방지하는 것이 가능해진다.According to the present invention, the rich spike control and the S purge operation can be performed efficiently, and the overheating of the catalyst due to the rich spike operation can be prevented.
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JP4241784B2 (en) * | 2006-08-30 | 2009-03-18 | トヨタ自動車株式会社 | Exhaust gas purification system for internal combustion engine |
DE102007004602B4 (en) * | 2007-01-30 | 2009-05-28 | Continental Automotive Gmbh | A heating device for heating a complex salt storage |
US20090199547A1 (en) * | 2008-02-08 | 2009-08-13 | Gm Global Technology Operations, Inc. | Method and apparatus for exhaust aftertreatment in a spark-ignition direct-injection internal combustion engine |
US20110036077A1 (en) * | 2008-04-25 | 2011-02-17 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purification system for internal combustion engine |
US8161731B2 (en) * | 2008-05-12 | 2012-04-24 | Caterpillar Inc. | Selective catalytic reduction using controlled catalytic deactivation |
US8650863B2 (en) | 2009-03-31 | 2014-02-18 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purification system for an internal combustion engine |
EP2538045A1 (en) * | 2010-02-17 | 2012-12-26 | Toyota Jidosha Kabushiki Kaisha | Exhaust purification device for an internal combustion engine |
GB2478721B (en) * | 2010-03-15 | 2017-07-05 | Gm Global Tech Operations Llc | Method for managing a desulphurization phase of a catalyst device of an internal combustion engine. |
JP2011252447A (en) * | 2010-06-02 | 2011-12-15 | Mitsubishi Heavy Ind Ltd | Internal combustion engine with denitration part and ship having the same |
KR101619184B1 (en) * | 2010-11-03 | 2016-05-10 | 현대자동차 주식회사 | System for desulfurization of oxidation catalyst and method thereof |
JP2013036393A (en) * | 2011-08-08 | 2013-02-21 | Hitachi Constr Mach Co Ltd | Engine control system of work machine |
JP5768607B2 (en) * | 2011-09-05 | 2015-08-26 | 三菱自動車工業株式会社 | Exhaust gas purification device for internal combustion engine |
JP6733651B2 (en) * | 2017-12-27 | 2020-08-05 | トヨタ自動車株式会社 | Exhaust gas purification device for internal combustion engine |
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US6758035B2 (en) * | 2002-09-18 | 2004-07-06 | Arvin Technologies, Inc. | Method and apparatus for purging SOX from a NOX trap |
US6779339B1 (en) * | 2003-05-02 | 2004-08-24 | The United States Of America As Represented By The Environmental Protection Agency | Method for NOx adsorber desulfation in a multi-path exhaust system |
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