KR100610905B1 - Manufacturing method for pellet of activated humic substances - Google Patents

Manufacturing method for pellet of activated humic substances Download PDF

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KR100610905B1
KR100610905B1 KR1020050000001A KR20050000001A KR100610905B1 KR 100610905 B1 KR100610905 B1 KR 100610905B1 KR 1020050000001 A KR1020050000001 A KR 1020050000001A KR 20050000001 A KR20050000001 A KR 20050000001A KR 100610905 B1 KR100610905 B1 KR 100610905B1
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active
injected
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water
corrosive
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서희동
서영준
서영진
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서희동
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632—Organic additives

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

본 발명은 부식토(腐植土) 중에서 풀브산(Fulvic acid) 및 이의 금속착체(金屬錯體)가 유리(遊離)의 상태로 유도되어 있는 활성부식물질(活性腐植物質)의 펠리트(Pellet)를 제조하는 방법을 제시하는 것이 목적이다.The present invention relates to pellets of active corrosive substances in which fulvic acid and metal complexes thereof are induced in a free state in humus soil. It is an object to present a method of preparation.

이를 위하여 해안지역에서 해양성 규조류, 해초, 플랑크톤(Plankton)과 같은 해양성 동·식물이나 수생식물이 퇴적되어 풀브산 및 이의 금속착체가 유리의 상태로 유도되어 생성된 산성상태의 천연활성부식물질이나 일반 부식질토양에 산을 주입하여 pH를 2이하로 조정하여 풀브산을 유리의 상태로 유도한 다음 황산제일철(FeSO4)과 과산화수소(H2O2)를 주입하여 산화환원전위(ORP ; Oxidation Reduction Potential)값을 +300mV∼+350mV로 조정하여 자체산화기능을 가지는 산화효소(Oxidase)를 생성토록 한 다음에 유문암(流紋巖)이나 대사이드(Dacite)질의 부석(浮石)이나 알로페인(Allophane)질 토양을 혼합하여 인공 제조된 활성부식물질의 분말에 바인더(Binder)로 천연의 옻 수지를 주입하고, 이들에 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화하고, 이를 환상(環狀)의 펠리트(Pellet)형태로 성형 가공하여 건조하여 활성부식물질의 펠리트를 제조한다.For this purpose, marine animals, plants and aquatic plants such as marine diatoms, seaweeds, and plankton have been deposited in coastal areas, and fulvic acid and its metal complexes are induced in the state of glass, resulting in acidic natural active corrosion substances or general Acid is injected into the humus soil to adjust the pH to 2 or less to induce fulvic acid to the glass state, and then ferrous sulfate (FeSO 4 ) and hydrogen peroxide (H 2 O 2 ) are injected to reduce the oxidation reduction potential (ORP). ) Value is adjusted from + 300mV to + 350mV to generate Oxidase which has self-oxidation function, and then pyrite or allophane of Rhyolite or Dacite Natural lacquer resin is injected into the powder of artificially prepared active corrosive by mixing the soil with a binder, and water is added thereto to adjust the water content to 40 to 45 wt%, followed by stirring and mixing. The dried molded into pellets (Pellet) in the form of 狀) to produce the pellets of the active material corrosion.

활성부식물질, 풀브산(Fulvic acid), 과산화수소, 해양성규조류, 산화환원전위(ORP), 알로페인(Allophane), 킬레이트(Chelate), 미네랄(Minerals).Active corrosive, fulvic acid, hydrogen peroxide, marine diatoms, redox potential (ORP), allophane, chelate, minerals.

Description

활성부식물질의 펠리트 제조방법{Manufacturing method for pellet of activated humic substances}Manufacturing method for pellet of activated humic substances

본 발명은 유문암(流紋巖)이나 대사이드(Dacite)질의 화산회토가 해양성 규조류, 해초, 플랑크톤(Plankton)과 같은 해양성 동·식물이 퇴적되어 풀브산 및 이의 금속착체가 유리의 상태로 유도되어 생성된 산성(pH 3이하)상태의 천연에서 활성화된 부식물질(이하 "활성부식물질"이라 칭함)이나 일반 부식질토양에 산을 주입하여 pH를 2이하로 조정하여 풀브산을 유리의 상태로 유도한 다음 황산제일철(FeSO4)과 과산화수소(H2O2)를 주입하여 산화환원전위(ORP ; Oxidation Reduction Potential)값을 +300mV∼+350mV로 조정하여 자체산화기능을 가지는 산화효소(Oxidase)를 생성하도록 한 다음에 유문암이나 대사이드질의 부석의 분말이나 알로페인(Allophane)질 토양을 혼합하여 인공적으로 제조된 활성부식물질의 분말에 바인더(Binder)로 천연의 옻 수지와 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화하여 환상(環狀)의 펠리트(Pellet)형태로 성형 가공하여 건조하여 활성부식물질(活性腐植物質)의 펠리트를 제조하는 방법에 관한 것이다.According to the present invention, rhyolite or dacite volcanic ash is deposited on marine fauna and flora such as marine diatoms, seaweeds, and plankton, and fulvic acid and its metal complexes are induced in a glass state. Induce acid to the state of glass by injecting acid into the generated acidic (pH 3 or less) natural activated corrosive (hereinafter referred to as “active corrosive”) or general humus soil, adjusting pH to 2 or below Then, ferrous sulfate (FeSO 4 ) and hydrogen peroxide (H 2 O 2 ) are injected to adjust the Oxidation Reduction Potential (ORP) value from + 300mV to + 350mV. After mixing, it is mixed with rhyolite, large-scale pumice powder or allophane soil, and artificial lacquer and water are added to the powder of artificially produced active corrosive material as binder to add water content. By mixing with stirring to adjust to 45wt% and then it dried to obtain molded into pellets (Pellet) in the form of cyclic (環狀) relates to a process for producing the pellets of active substance corrosion (活性 腐植 物質).

활성부식물질(Activated humic substances)은 부식질(腐植質) 토양이 산성(酸性)상태(pH 3이하)에서 풀브산(Fulvic acid)이 유리(遊離)된 상태에서 토양 중에서 활성화된 미네랄(Activated minerals ; 반응성이 높은 미네랄성분의 함량이 많이 함유한 광물질)과 풀브산 및 부식산(腐植酸)과 반응하여 착염(錯鹽) 상태로 존재하는 부식질토양(腐植質土壤)으로 자연상태에서 천연적으로 출토되는 곳은 일본 나가사키현(長崎縣)의 가라고(唐比) 저습지(低濕地), 나가노현(長野縣)의 남알푸스 시오가와(鹽川)계곡의 산중턱, 캐나다(Canada), 페루(Peru) 등 세계에서 4∼5개 지역에서 출토되는 희귀한 물질로 이 중에서 나가사키현의 가라고습지의 부식토(이탄)는 활성이 아주 우수한 것으로 알려저 이를 하·폐수처리, 사료 첨가제, 정수기, 유기농법, 화장품 첨가제, 토양 개량제, 악취 제거제 등으로 상품화되어 있으며, 이 활성부식물질의 특성, 화학적인 조성에 관해서는 식품산업을 위한 최신바이오수처리기술(食品産業のための最新バイオ水處理技術, 恒星社厚生閣 發行), 식품산업을 위한 미생물이용수처리기술(食品産業のための微生物利用水處理技術, 恒星社厚生閣 發行), 자연정화처리의 실제(自然淨化處理の實際), 토양유기물(土壤有機物, 農文協 發行), 축산의 연구(畜産の硏究 VOL. 46, 47) 등의 문헌에 상세하게 언급되어 있다. Activated humic substances are activated minerals in the soil in which humic soils are free from pulvic acid in an acidic state (pH 3 or lower); Natural minerals containing highly reactive minerals) and humic soils that react with fulvic acid and humic acid to form complex salts. It is located in the Karago Low Wetlands of Nagasaki Prefecture, Japan, the mountain slopes of the Southern Alps Shiogawa Valley in Nagano Prefecture, Canada, Peru It is a rare substance that is excavated from 4 to 5 regions of the world such as Peru. Among them, the humus soil (peat) of Kago Wetland in Nagasaki Prefecture is known to have excellent activity. Law, cosmetic additives, soil improvers, odors It is commercialized as Geoje, and the characteristics of this active corrosive substance and chemical composition are the latest bio water treatment technologies for the food industry, the food industry, and the food industry. Research on Microbial Use Water Treatment Technology, Realization of Natural Purification Process, Soil Organic Matter, Livestock Production (VOL. 46, 47) et al.

가라고 저습지는 일본 나가사키현의 시마하라(島原)반도 운젠(雲仙) 화산군의 북서쪽 다치바나만(橋灣)의 해안에 인접해 있으며, 길이가 약 1.5Km 폭이 0.5Km인 습지로 대략 6000년 전에 출구가 폐쇄되어 작은 호수가 되었으며, 출구가 폐쇄되기 전에는 작은 만(灣)으로 해양성 규조류, 어패류, 해초, 플랑크톤(Plankton) 등이 인근 운젠후컨타게(普賢岳)의 화산군(火山群)에서 배출된 유문암내지는 대사이드질의 화산회토와 함께 혼합 퇴적되어 pH가 2.5이하의 산성상태에서 활성화된 부식질토양으로 존재하고 있다. Karago Wetland is adjacent to the coast of Tachibana Bay, northwest of the Unzen volcanic group of Shimahara Peninsula in Nagasaki Prefecture, Japan.The wetland is about 1.5 km long and 0.5 km wide. Was closed to become a small lake, and before the exit was closed, it was a small bay where marine diatoms, seafood, seaweed, and Plankton were discharged from the volcanic group of nearby Unzen-Fucontage. It is mixed and deposited with volcanic ash of side quality and exists as activated humus soil in acid state with pH below 2.5.

이 가라고습지의 주변목장에서 축산폐수가 제대로 처리되지 않은 상태에서 습지호수에 유입이 되었는데도 다른 하천이나 호수에 비해서 훨씬 빠른 자정작용이 일어나며 수중에 서식하는 송사리, 뱀장어와 같은 어류 및 갈대, 연꽃, 양치류 등의 식물의 생육도 다른 하천이나 호수에 비해서 빠르게 성장이 되었다.Although the livestock wastewater has not been properly treated in the wetlands of this Gargo Wetland, it has a much faster self-cleaning effect than other rivers and lakes, and it has a much faster midnight action than other rivers and lakes. The growth of these plants also grew faster than other rivers and lakes.

이 습지 주변의 농민들은 습지의 부식토를 가축에 급여한 결과 질병에 대한 내성이 강화되면서 성장이 빠르고 육질도 양호하였으며, 또한, 배설분뇨에서 악취가 저감되어 축사환경이 개선되면서 배출폐수의 오염부하도 저감되는 것을 발견하게 되어 일본특허공보 평(平) 5-66199에서는 활성화된 부식물질을 이용하여 축산폐수, 축산물가공공장폐수, 식품가공공장 배출폐수, 농산물가공공장 배출폐수, 오수 등과 같은 유기성물질을 함유한 폐수처리를 한 결과 일반 활성오니공법에 비해 처리효율이 아주 우수한 결과를 가져와 "자연정화법"이라는 명칭으로 오·폐수처리에 응용하고 있다.Farmers around the marsh fed the wetland humus to livestock, resulting in increased resistance to disease and faster growth, and better meat quality. Japanese Patent Publication No. Hei 5-66199 found that the use of activated corrosive substances can reduce organic matters such as livestock wastewater, livestock processing plant wastewater, food processing plant wastewater, agricultural product processing plant wastewater and sewage. As a result of treating wastewater containing, it has a very good treatment efficiency compared to general activated sludge process and is applied to wastewater treatment under the name of "natural purification method".

그러나 습지의 생태계의 보호 및 희귀물질(활성부식토)의 보전을 위해 자연박물원으로 지정하여 채굴을 제한하고 있는 실정에 있어 공급이 원활하지 못하면서 공급가격이 고가이기 때문에 경제적인 문제가 있어, 천연으로 출토되는 활성부식토보다 활성도가 우수하면서 저렴하게 공급할 수 있는 활성부식물질의 인공적으로 제조하는 방법이 대한민국 특허 제 0453560호에 제시되어 있다.However, in order to protect wetland ecosystems and preserve rare substances (active corrosive soils), they are designated as natural museums to limit mining. A method of artificially preparing an active corrosive material which can be supplied at a lower cost than an active corrosive soil is proposed in Korean Patent No. 0453560.

상술한 활성부식물질의 분말을 환상의 펠리트(Pellet)를 제조하는 종래의 방법으로는 대한민국 특허 제0453561호의 경우는 바인더(Binder)로 벤토나이트(Bentonite)와 고화제(시멘트, 페놀수지...등)를 주입하고, 이들에 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화한 다음에 환상의 펠리트형태로 성형한 다음에 건조하여 활성부식물질의 펠리트를 제조하는 방법이 제시되어 있으며, 일본특허 공개번호 2002-101871호에서는 부식물질 20~80wt%와 부석(浮石)이나 제올라이트(Zeolite), 규조토(硅藻土), 점토(粘土) 등의 광물의 분말 80~20 wt%를 (바람직하게는 그 혼합물에 철분이나 알루미늄가루 등의 금속 분말을 5wt%를 한다.) 가하거나 알긴산소다(Sodium alginate)나 셀룰로오스(Cellulose) 분말과 같은 수용성 바인더를 10wt%를 가하고, 적당량의 물을 가해 혼합한 후 성형하고 나서 2~3일 자연건조한 다음에 200~400℃에 가열하여 부식물질의 펠리트를 제조하는 방법이 제시되어 있으며, 일본 특허 공개 평(平)11-169897호에서는 부식토의 분상에 철, 마그네슘(Magnesium)화합물과 셀룰로오스 및 키친(Chitin)질의 바인더를 배합하여 펠리트를 제조하는 방법 등이 제시되어 있으나, 이들 대부분 종래의 기술은 수중에서 충전탑(생물반응기, 미네랄 충전탑 등으로 용도에 따라 부르고 있음)에 충전하고 송풍기로부터 공기를 공급하여 폭기를 하면서 사용하였을 때 2∼3개월이 경과하면서 팽윤(澎潤)현상이 야기되면서 일시에 소멸되어 사용기간 짧으면서 부식질미네랄착염을 수중에 일정한 농도로 용출하지 못하는 문제점이 있었다. As a conventional method for producing annular pellets from the powder of the active corrosive material described above, in the case of Korean Patent No. 0453561, a binder is used as bentonite and a solidifying agent (cement, phenolic resin). Etc.), water is added thereto to adjust the water content to 40 to 45 wt%, stirred and mixed, molded into annular pellets, and then dried to produce pellets of active corrosive materials. In Japanese Patent Laid-Open No. 2002-101871, 20 to 80 wt% of corrosive substances and 80 to 20 wt of mineral powders such as pumice, zeolite, diatomaceous earth, and clay % (Preferably 5% by weight of metal powder such as iron or aluminum powder to the mixture) or 10% by weight of water-soluble binder such as sodium alginate or cellulose powder. Add water and mix After drying for 2 to 3 days and then heating to 200 ~ 400 ℃, there is a method for producing a pellet of corrosive substance. Japanese Patent Laid-Open No. 11-169897 discloses iron and magnesium in the form of corrosive soil. (Magnesium) compound and a method of preparing pellets by combining cellulose and chitin (Bintin) binder, etc. have been proposed, but most of these conventional techniques in water in a packed tower (bioreactor, mineral packed tower, etc.) When used in aeration after supplying air from the blower and causing a swelling phenomenon as 2 ~ 3 months elapse, and it disappears at a time and has a constant concentration of humic mineral complex salt in water. There was a problem that can not be eluted.

본 발명의 목적은 수중에서 부식질미네랄착염을 일정한 농도로 용출하도록 하면서 사용기간을 최대한 장시간 사용할 수 있는 활성부식물질 펠리트를 제조하는 방법을 제시하는 것이다.An object of the present invention is to provide a method for producing an active corrosive pellet which can be used for a long time as long as possible to elute the humic mineral complex salt in a constant concentration in water.

본 발명은 상기와 같은 문제점을 해소하기 위해 활성부식물질의 분말에 천연의 옻나무에서 채취한 수지를 사용하여 수중에서 일정한 농도로 부식질미네랄착염을 용출할 수 있는 활성부식물질 펠리트를 제조하는 방법을 제공하는 데 본 발명의 목적이 있는 것이다.The present invention is to prepare a method for producing an active corrosive material pellets that can elute the corrosive mineral complex salt in a certain concentration in water using a resin collected from the natural lacquer in the powder of the active corrosion material to solve the above problems. It is an object of the present invention to provide.

이와 같은 목적을 달성하기 위한 본 발명은, 일본 나가사키현(長崎縣)의 가라고(唐比) 저습지(低濕地), 나가노현(長野縣)의 남알푸스 시오가와(鹽川)계곡의 산중턱, 캐나다(Canada), 페루(Peru) 등의 천연에서 채취 가공한 활성부식물질의 분말이나 대한민국 특허 제0453560호에서 인공적으로 제조한 활성부식물질의 분말에 옻나무에서 채취한 천연의 옻 수지를 혼합하는 단계, 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 환상의 펠리트형태로 가공하는 단계, 자연건조한 다음에 120~400℃의 열풍으로 가열가열 건조하여 활성부식물질 펠리트를 제조하는 단계로 이루어진 것에 특징이 있다.The present invention for achieving the above object is a mountain in the Kagora Low Wetlands of Nagasaki Prefecture, Japan, and the Southern Alps Shiogawa Valley of Nagano Prefecture. Natural lacquer from lacquer is mixed with powder of active corrosive material collected from nature such as middle jaw, Canada, Peru, etc. or powder of active corrosive material artificially manufactured by Korean Patent No. 0453560. The water content is adjusted to 40 to 45wt% by adding water, followed by processing into an annular pellet form, followed by natural drying, followed by heating and drying with hot air at 120 to 400 ° C. to produce an active corrosive pellet. It is characterized by consisting of steps.

본 발명에서 사용하는 활성부식물질(活性腐植物質)은 일본 나가사키현(長崎縣)의 가라고(唐比) 저습지(低濕地), 나가노현(長野縣)의 남알푸스 시오가와(鹽川)계곡의 산중턱, 캐나다(Canada), 페루(Peru) 등의 천연에서 채굴하여 자연 건조한 분말이나 대한민국 특허 제0453560호에서 제조된 활성부식물질의 분말을 사용한다.The active corrosive substance used in the present invention is Kago lowland in Nagasaki Prefecture, Japan, and Southern Alps Shiogawa in Nagano Prefecture. Mountain dried valley, Canada (Canada), Peru (Peru), such as mined from the natural dry powder or the active corrosive powder prepared in Korean Patent No. 0453560.

활성부식물질은 동·식물에 미네랄공급을 용이하게 특성과 수중에서 물분자 의 수소결합(水素結合)을 부분적으로 단절하여 물분자의 집단을 소집단화(小集團化)하여 소집단수(集團水 ; Microclustered water)로 전환하므로서 동·식물 및 미생물의 대사활동을 활발하게 하는 특성이 있어 미생물의 배양, 물의 개질(改質), 토양개량제 등으로 다양하게 이용되고 있다.Active corrosives are characterized by easy mineral supply to animals and plants, and small groups of water molecules by partially breaking the hydrogen bonds of water molecules in water. As it converts to microclustered water, it has a characteristic of activating metabolic activity of animals, plants and microorganisms, and is used in various ways for cultivating microorganisms, reforming water, and soil improving agents.

활성부식물질의 펠리트(Pellet)는 미생물의 배양공정에서는 생물반응기(Bio-reactor)에 활성미네랄함량이 높은 광물의 괴(塊)와 함께 충전(充塡)하여 사용하며, 소집단수의 생산공정에서도 미네랄반응탑에 활성미네랄함량이 높은 광물의 괴, 마이너스(Minus ion) 및 원적외선을 방사하는 광물, 자성광물(자화된 자철광) 등과 함께 충전하여 물을 개질하는데 주로 사용한다.Pellet of active corrosive material is used in the process of culturing microorganisms by filling the bio-reactor with the mineral mass with high active mineral content. Also in the mineral reaction tower is mainly used to reform the water by filling with minerals with high active mineral content, minus (Minus ion) and minerals emitting far infrared rays, magnetic minerals (magnetized magnetite).

그리고 본 발명에서 사용하는 옻 수지는 옻나무 표피에 상처를 내어 상처로부터 유회백색의 유액상의 수지가 나오는데, 옻 수지의 주성분은 우루시올(Urushiol)이며, 기타 수분과 소량의 고무질 및 함질소물(含窒素物)을 함유하고 있으며, 조성은 산지에 따라 약간의 차이가 있으나, 국내 원주-횡성지역에서 채취되는 옻 수액의 화학적조성은 지방질의 우루시올이60-80wt%, 고무질이 7~8wt%, 함질소물이 1.4~2.8wt%, 라카아제(Laccase)효소가 0.1wt%정도, 물이 10~30wt%포함되어 있으면서 에멀션(Emulsion)을 형성하고 있으며, 채취 직후의 칠은 공기와 접하면 흑색을 나타내며, 용기 내에서 상온(常溫)으로 휘저어 섞은 후 38∼45℃에서 보존하면 빛깔이 검게 변한다. In addition, lacquer resin used in the present invention is wound on the skin of the lacquer tree, and an oily white milky resin comes out from the wound. The main component of the lacquer resin is urushiol, and other moisture and a small amount of rubber and nitrogenous substances (含 窒 素). The composition of the lacquer sap collected from Wonju-Hoengseong, Korea is 60-80wt% of fatty urushiol, 7-8wt% of rubber, nitrogen-containing Emulsion is formed with 1.4 ~ 2.8wt% of water, 0.1wt% of Lacase enzyme, and 10 ~ 30wt% of water. After stirring at room temperature in the container and mixing at 38-45 ℃, the color turns black.

옻 수지의 주성분인 우루시올은 페놀유도체의 하나로 화학식은 C21H34O2인 점 성(粘性)이 있는 무색 액체이며, 끓는점 210∼222℃이며, 공기 중에서는 검게 변하며, 진득하게 되어 응고하며, 1종류의 화합물이 아니라, 2가(價)페놀의 혼합물이다.Urushiol, the main component of the lacquer resin, is a phenol derivative, a viscous, colorless liquid with a chemical formula of C 21 H 34 O 2 , a boiling point of 210-222 ° C, which turns black in the air, and solidifies. It is not a single compound but a mixture of dihydric phenols.

라카아제는 p-디페놀(Di-phenol ; Hydroquinone)을 산소에 의하여 산화하여 p-퀴논(Quinone)으로 만드는 페놀산화효소(Phenoloxidase)의 일종으로 옻나무의 수액(樹液) 속에서 옻을 산화시키고 경화(硬化)하는 효소로서 역할을 하며, 구리단백질의 일종으로 청색을 띤다. Lacase is a kind of phenol oxidase that oxidizes p-diphenol (Di-phenol; Hydroquinone) with oxygen to make p-quinone. It oxidizes and hardens lacquer in the sap of lacquer tree. It acts as an enzyme, which is a kind of copper protein, which is colored blue.

옻 수지는 공기 중에서 주성분인 우루시올이 라카아제의 촉매작용에 의해 분자가 산화중합반응을 일으켜 흑갈색으로 되면서 화학적으로 견고한 결합과 강한 접착제로서 뛰어난 기능을 가지게 되는 특성을 이용하여 본 발명에서는 바인더(Binder)로 사용한다. Lacquer resin is a binder in the present invention using the characteristic that urushiol, which is a main component in the air, becomes blackish brown due to the oxidation reaction of the polymerase by the reaction of laccase, and has the excellent function as a chemically strong bond and a strong adhesive. Used as.

이하 사용되는 조제의 양을 나타내는 "부"는 중량 부를 말한다."Part" which shows the quantity of the preparation used hereafter means a weight part.

본 발명은 상기에서 설명한 천연의 활성부식물질이나 인공적으로 제조한 활성부식물질의 분말과 옻 수지를 이용하여 활성부식물질의 펠리트(Pellet)의 제조방법을 구체적으로 언급하면 다음과 같다.The present invention specifically refers to a method of preparing pellets of active corrosive materials using a powder of a natural active corrosive substance or artificially prepared active corrosive substance and lacquer resin as described above.

천연적으로 출토되는 활성부식물질이나 인공적으로 제조된 활성부식물질의 분말 100부를 혼화기에 주입하고 바인더(Binder)로는 화산의 폭발시 화산회가 퇴적하여 형성된 스멕 타이트군(Smectite group)의 점토광물로 구성된 벤토나이트(Bentonite)를 10∼20부와 옻 수지를 10∼15부를 주입하고, 이들에 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화한 것을 환상의 펠리트(Pellet)형태로 성형한 다음에 그늘진 응달에서 10∼15일간 자연건조한 다음 90∼150℃열풍으로 함수율이 12wt%이하가 되게 건조하여 활성부식물질의 펠리트(Pellet)를 제조한다.100 parts of powders of naturally occurring active or artificially produced active corrosion materials are injected into the admixture, and the binder consists of smectite group clay minerals formed by volcanic ash deposited during volcanic eruption. 10 to 20 parts of bentonite and 10 to 15 parts of lacquer resin are injected, and water is added thereto to adjust the water content to 40 to 45 wt%, followed by stirring and mixing to form an annular pellet. Then, natural drying in shaded shade for 10 to 15 days, and then dried to a water content of 12wt% or less by hot air at 90-150 ℃ to prepare a pellet of the active corrosion material.

옻 수지는 자외선에 의해서 분자가 파괴되어 옻 수지의 특징인 내구성이 떨어지기 때문에 자연건조과정에서 햇빛이 비치지 않은 응달에서 건조하여야 한다. Lacquer resin should be dried in the shade that is not exposed to sunlight during the natural drying process because the molecule is destroyed by ultraviolet rays and its durability is inferior.

[실시 예1]Example 1

일본 나가사키현 가라고습지에서 출토되는 천연의 활성부식토 100부(건량기준)에 바인더로 벤토나이트(Bentonite)를 15부와 횡성에서 채취한 함수율이 15wt%인 옻 수지를 10부를 주입하고, 이들에 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화한 것을 환상의 펠리트(Pellet)형태로 성형한 다음에 그늘진 응달에서 18∼25℃에서 15일간 자연건조한 다음에 110∼120℃의 열풍으로 함수율이 10wt%로 건조한 활성부식물질의 펠리트(Pellet)를 제조하여 P아파트단지에서 400∼500㎥/일로 배출되는 오수처리공정의 미생물활성화조에 설치된 생물반응기(Bio-reactor)에 활성부식물질 펠리트 30㎏과 유문암질 부석 60㎏을 충전하여 부식화 미생물을 배양하여 처리한 결과 처리효율은 표 1의 내용과 같았으며, 생물반응기에 충전한 활성부식물질의 펠리트는 6개월 동안 안정적으로 사용할 수 있었다.15 parts of bentonite as a binder and 10 parts of lacquer with a water content of 15wt% taken from Hoengseong were injected into 100 parts of natural activated corrosion soil (dry basis) excavated from Kagoga Wetland, Nagasaki Prefecture, Japan. The water content was adjusted to 40 to 45 wt%, and then stirred and mixed into a circular pellet form, followed by natural drying at 18 to 25 ° C for 15 days in shaded shade, followed by hot air at 110 to 120 ° C. Pellet of dried active corrosive material with water content of 10wt% is produced and discharged from 400 to 500㎥ / day at P apartment complex. The treatment efficiency was as shown in Table 1, and the pellets of the active corrosives charged into the bioreactor were inactive for 6 months. It could ever use.

표1 생활오수처리에서 활성부식물질과 유문암질 부석을 생물반응기에 충전하여 처리한 결과 처리효율 비교표 Table 1 Comparative Table of Treatment Efficiency by Filling Bioreactor with Active Corrosive Material and Rhyolite Rock

항 목    Item 유입수의 수질   Influent Water Quality 일반 활성오니공정 으로 처리시 수질  Water quality when treated by general activated sludge process 활성부식물질과 부석을 생물반응기에 충전하고 처리시 수질Filling the bioreactor with active corrosive and pumice BOD5(㎎/ℓ)BOD 5 (mg / L) 410∼462     410-462 25∼30    25-30 4∼ 5    4 to 5 CODMn(㎎/ℓ)COD Mn (mg / L) 360∼386     360-386 40∼60    40-60 6∼12    6-12

전술한 기술내용에서와 같이 활성부식물질 펠리트와 활성미네랄성분이 많은 광물(부석)을 충전한 생물반응기를 생활오수, 하·폐수처리공저에 설치하였을 때는 처리효율이 월등히 향상되며, 특히 옻 수지를 바인더로 사용하여 제조된 활성부식물질 펠리트는 장시간 안정적으로 사용할 수 있기 때문에 이들 분야에 널리 보급될 것으로 기대된다.As described in the above description, when a bioreactor filled with pellets of active corrosive substances and minerals containing a large amount of active minerals (pumice) is installed in living sewage and sewage and wastewater treatment facilities, the treatment efficiency is significantly improved. It is expected that the active corrosive material pellets prepared using the binder will be widely used in these fields because they can be stably used for a long time.

Claims (1)

천연적으로 출토되는 활성부식물질이나 인공적으로 제조된 활성부식물질의 분말 100부를 혼화기에 주입하고 바인더(Binder)로는 화산의 폭발시 화산회가 퇴적하여 형성된 스멕 타이트군(Smectite group)의 점토광물로 구성된 벤토나이트(Bentonite)를 10∼20부와 옻 수지를 10∼15부를 주입하고, 이들에 물을 가해서 함수율을 40∼45wt%로 조정한 다음에 교반 혼화한 것을 환상의 펠리트(Pellet)형태로 성형한 다음에 그늘진 응달에서 10∼15일간 자연건조한 다음 90∼150℃열풍으로 함수율이 12wt%이하가 되게 건조하여 활성부식물질의 펠리트(Pellet)를 제조하는 방법.100 parts of powders of naturally occurring active or artificially produced active corrosion materials are injected into the admixture, and the binder consists of smectite group clay minerals formed by volcanic ash deposited during volcanic eruption. 10 to 20 parts of bentonite and 10 to 15 parts of lacquer resin are injected, and water is added thereto to adjust the water content to 40 to 45 wt%, followed by stirring and mixing to form an annular pellet. And then dried naturally in shaded shade for 10 to 15 days and then dried to a water content of 12 wt% or less with 90-150 ° C. hot air to produce pellets of active corrosive materials.
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JPH08309394A (en) * 1996-01-16 1996-11-26 Enzaimu Kk Deodorization of organic sludge and manufacture of property change inhibiting agent
KR100202004B1 (en) 1996-05-27 1999-06-15 임병건 Coffon and its production method utilizing the yellow earth
KR20010070600A (en) * 2001-05-26 2001-07-27 김형준 Polyolefin composite resin containing natural lacquer, and process for preparing the same
JP2002101871A (en) 2000-09-27 2002-04-09 Aoki Denki Kogyo Kk Pellet containing humic matter
KR100453561B1 (en) 2003-12-26 2004-10-21 서희동 Manufacturing method for pellet of activated humic substances

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08309394A (en) * 1996-01-16 1996-11-26 Enzaimu Kk Deodorization of organic sludge and manufacture of property change inhibiting agent
KR100202004B1 (en) 1996-05-27 1999-06-15 임병건 Coffon and its production method utilizing the yellow earth
JP2002101871A (en) 2000-09-27 2002-04-09 Aoki Denki Kogyo Kk Pellet containing humic matter
KR20010070600A (en) * 2001-05-26 2001-07-27 김형준 Polyolefin composite resin containing natural lacquer, and process for preparing the same
KR100453561B1 (en) 2003-12-26 2004-10-21 서희동 Manufacturing method for pellet of activated humic substances

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