KR100601154B1 - Coating compounds for imitation pearl - Google Patents

Coating compounds for imitation pearl Download PDF

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Publication number
KR100601154B1
KR100601154B1 KR1020040004641A KR20040004641A KR100601154B1 KR 100601154 B1 KR100601154 B1 KR 100601154B1 KR 1020040004641 A KR1020040004641 A KR 1020040004641A KR 20040004641 A KR20040004641 A KR 20040004641A KR 100601154 B1 KR100601154 B1 KR 100601154B1
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South Korea
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composition
acetate
celluloid
weight
ethyl acetate
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KR1020040004641A
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Korean (ko)
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KR20050077069A (en
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이영남
이상민
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이영남
이상민
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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47C—CHAIRS; SOFAS; BEDS
    • A47C21/00—Attachments for beds, e.g. sheet holders, bed-cover holders; Ventilating, cooling or heating means in connection with bedsteads or mattresses
    • A47C21/04—Devices for ventilating, cooling or heating
    • A47C21/048—Devices for ventilating, cooling or heating for heating
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47C—CHAIRS; SOFAS; BEDS
    • A47C31/00—Details or accessories for chairs, beds, or the like, not provided for in other groups of this subclass, e.g. upholstery fasteners, mattress protectors, stretching devices for mattress nets
    • A47C31/004—Means for protecting against undesired influence, e.g. magnetic radiation or static electricity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00—Details
    • F24D19/10—Arrangement or mounting of control or safety devices
    • F24D19/1006—Arrangement or mounting of control or safety devices for water heating systems
    • F24D19/1009—Arrangement or mounting of control or safety devices for water heating systems for central heating
    • F24D19/1015—Arrangement or mounting of control or safety devices for water heating systems for central heating using a valve or valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00—Hot-water central heating systems
    • F24D3/02—Hot-water central heating systems with forced circulation, e.g. by pumps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00—Hot-water central heating systems
    • F24D3/12—Tube and panel arrangements for ceiling, wall, or underfloor heating
    • F24D3/16—Tube and panel arrangements for ceiling, wall, or underfloor heating mounted on, or adjacent to, a ceiling, wall or floor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • F24H1/0018—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters using electric energy supply
    • G—PHYSICS
    • G05—CONTROLLING; REGULATING
    • G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D23/00—Control of temperature
    • G05D23/19—Control of temperature characterised by the use of electric means
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/40—Heating elements having the shape of rods or tubes

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Automation & Control Theory (AREA)
  • Adornments (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 인조 진주 도장용 조성물에 관한 것으로, 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 초도용 조성물(A); 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 중도용 조성물(B); 혹은 셀룰로이드를 에틸아세테이트와 부틸아세테이트에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 상도용 조성물(C)에 관한 것이다.The present invention relates to a composition for artificial pearl coating, comprising: a first composition (A) obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, a mixture of butyl acetate and amyl acetate, and then adding a pigment thereto; A neutral composition (B) obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, and a mixture of butyl acetate and amyl acetate, and then adding a pigment thereto; Or it relates to the composition for top coats (C) obtained by dissolving a celluloid in ethyl acetate and butyl acetate, and then adding a pigment to it.

상기 본 발명의 조성물은 염기성 탄산납을 사용하는 종래의 방법에 비해 인체에 무해하고 친 환경적이면서, 기존의 이산화티탄이나 에틸아세테이트 조성물에 비해서는 사용 후의 색상과 광택이 뛰어난 효과가 있다.The composition of the present invention is harmless to the human body and environmentally friendly compared to the conventional method using a basic lead carbonate, and has an excellent color and gloss after use as compared to a conventional titanium dioxide or ethyl acetate composition.

인조진주, 도장, 조성물, 셀룰로이드, 부틸아세테이트, 아밀아세테이트Artificial Pearl, Paint, Composition, Celluloid, Butyl Acetate, Amyl Acetate

Description

인조 진주 도장용 조성물{COATING COMPOUNDS FOR IMITATION PEARL}Composition for artificial pearl coating {COATING COMPOUNDS FOR IMITATION PEARL}

본 발명은 인조 진주 도장용 조성물에 관한 것으로, 좀더 상세하게는, 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 초도용 조성물(A); 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 중도용 조성물(B); 혹은 셀룰로이드를 에틸아세테이트와 부틸아세테이트에 용해한 다음, 여기에 안료를 가하여 얻어지는 것을 특징으로 하는 상도용 조성물(C)에 관한 것이다.The present invention relates to a composition for artificial pearl coating, and more particularly, to a composition for preparing an acrylic composition, which is obtained by dissolving a celluloid in a mixture of acetone and ethyl acetate, a mixture of butyl acetate and amyl acetate, and then adding a pigment thereto. (A); A neutral composition (B) obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, and a mixture of butyl acetate and amyl acetate, and then adding a pigment thereto; Or it relates to the composition for top coats (C) obtained by dissolving a celluloid in ethyl acetate and butyl acetate, and then adding a pigment to it.

상기 본 발명의 조성물은 염기성 탄산납을 사용하는 종래의 방법에 비해 인체에 무해하고 친 환경적이면서, 기존의 이산화티탄이나 에틸아세테이트 조성물에 비해서는 사용 후의 색상과 광택이 뛰어난 효과가 있다.The composition of the present invention is harmless to the human body and environmentally friendly compared to the conventional method using a basic lead carbonate, and has an excellent color and gloss after use as compared to a conventional titanium dioxide or ethyl acetate composition.

산업이 발달하고 생활이 윤택해지면서, 인간이 착용하거나 걸치는 장신구에도 다양한 변화가 일고 있다.As the industry develops and life becomes more lucrative, various changes are happening to the jewelry worn or worn by humans.

그 가운데, 천연 진주의 질감을 재현하면서 대량 생산이 가능한 인조 진주는 액세서리나 목걸이, 반지, 브로치, 장난감 등 그 활용의 범위가 다양하다.Among them, artificial pearls, which reproduce the texture of natural pearls and can be mass-produced, have a wide range of applications such as accessories, necklaces, rings, brooches and toys.

통상, 장신구 등에 사용되고 있는 인조 진주는, 질산섬유소인 셀룰로오스를 각종 용제로 용해하고 여기에 안료를 배합하여 수지 비드에 도장하여 완성된다.Usually, artificial pearls used for jewelry and the like are dissolved by dissolving cellulose, which is fiber nitrate, in various solvents, blending pigments therein, and coating the resin beads.

여기서, 상기 배합되는 안료로서 대부분 납(Pb) 성분을 함유한 중성염과 수산화물의 복합염인 염기성 탄산납(2PbCO3·Pb(OH)2)을 사용하기 때문에, 이를 사용할 때에는 상당한 질감과 광택을 낼 수 있지만, 사용 후에는 인체에 치명적이고 환경을 오염시키는 주 요인으로 되고 있다.Here, as the pigment to be blended, basic lead carbonate (2PbCO 3 · Pb (OH) 2 ), which is a complex salt of a neutral salt and a hydroxide containing mostly lead (Pb) components, is used. After use, it is fatal to human body and polluting environment after use.

따라서, 최근에는 질산섬유소를 아세톤이나 부틸아세테이트 등으로 용해하면서, 상기 기존의 안료를 인체에 무해한 비스무스옥시클로라이드(BiOCl) 등으로 대체하는 연구가 보고되고 있다.Therefore, in recent years, while research has been made to dissolve fiber nitrate with acetone, butyl acetate and the like and replace the conventional pigment with bismuth oxychloride (BiOCl) which is harmless to the human body.

예컨대, 대한민국 특허공고 제1996-13573호(1996.10.9.공고)에는 무독성 인조 진주의 제조방법으로서, 니트로셀룰로오스를 아세톤과 부틸아세테이트, 에틸아세테이트로 용해한 다음, 이산화티탄, 비스무스옥시클로라이드를 사용하여 마무리하는 기술이 개시되어 있다.For example, Korean Patent Publication No. 1996-13573 (published on Jan. 1, 1996) discloses a method for producing a non-toxic artificial pearl, in which nitrocellulose is dissolved in acetone, butyl acetate and ethyl acetate, and then finished using titanium dioxide and bismuth oxychloride. The technique which makes it is disclosed.

그러나, 상기 기술은 니트로셀룰로오스 자체를 사용하여 인조 진주용 안료의 용해도와 분산성이 나쁘고, 자외선에 약해 도장 후에는 시간이 지나면서 누렇게 변색이 되는 취약성이 있으며, 또한, 이산화티탄과 특정안료(그린 하이라이트펄)를 혼합하여 원하는 광택과 물성을 얻고자 하나, 제조공정이 번잡하고 각 구성 성분과 이들의 함량 조건이 맞지 않아, 천연 진주와 같이 은은하고 영롱한 질감이 부족하여 전체적인 상품성이 떨어지며, 특히 최종 제품에 납 함량이 50ppm 미만으로 존재하여 여전히 독성이 우려되는 문제가 있었다.However, the above technique has a poor solubility and dispersibility of artificial pearl pigment using nitrocellulose itself, and is weak to ultraviolet rays, so that it discolors over time after coating, and furthermore, titanium dioxide and specific pigments (green Highlight pearls) to achieve the desired gloss and physical properties, but the manufacturing process is complicated and each component and their content conditions are not matched, the overall softness of the product is poor due to the lack of a soft and shiny texture like natural pearls. The lead content in the product is less than 50ppm still had a problem of toxicity concerns.

따라서, 본 발명에서는 상기 종래의 문제점을 개선한 것으로, 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 소정의 비율로 안료를 가하여 얻어지는 초도용 조성물(A) 및 중도용 조성물(B), 혹은 셀룰로이드를 에틸아세테이트와 부틸아세테이트에 용해한 다음, 여기에 안료를 가하여 얻어지는 상도용 조성물(C)을 개발함으로써,Accordingly, in the present invention, the above-mentioned conventional problems are improved, and the first composition (A) obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, a mixture of butyl acetate and amyl acetate, and then adding a pigment at a predetermined ratio thereto. And by developing a composition for neutral coating (B) or a composition for coating (C) obtained by dissolving celluloid in ethyl acetate and butyl acetate and then adding a pigment thereto.

염기성 탄산납을 사용하는 종래의 방법에 비해 인체에 무해하고 친 환경적이면서, 기존의 이산화티탄이나 에틸아세테이트 조성물에 비해서는 사용 후의 색상과 광택이 뛰어난 효과가 있는 새로운 인조 진주 도장용 조성물을 제공하고자 한다.
To provide a new artificial pearl coating composition which is harmless to the human body and environmentally friendly compared to the conventional method using basic lead carbonate, and has an excellent effect on color and gloss after use compared to conventional titanium dioxide or ethyl acetate compositions. do.

이하, 본 발명의 구성에 대해 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, the structure of this invention is demonstrated.

본 발명은, 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 소정의 비율로 안료를 가하여 얻어지는 초도용 조성물(A) 및 중도용 조성물(B), 혹은 셀룰로이드를 에틸아세테이트와 부틸아세테이트에 용해한 다음, 여기에 안료를 가하여 얻어지는 상도용 조성물(C)을 특징으로 한다.The present invention provides a composition (A) and an intermediate composition (B) or celluloid obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, a mixture of butyl acetate and amyl acetate, and then adding a pigment at a predetermined ratio thereto. It is characterized by the composition for top coat obtained by dissolving in ethyl acetate and butyl acetate, and then adding a pigment to it.

즉, 본 발명의 제1의 발명에서는, 인조 진주 도장의 초도용 조성물(A)로서, 셀룰로이드 22~33중량%를 아세톤과 에틸아세테이트 3:7 혼합물 33~38중량%, 부틸아세테이트와 아밀아세테이트 7:3 혼합물 33~38중량%에 용해한 다음, 여기에 안료 1~5중량%를 가하여 얻어지는 것을 특징으로 한다.That is, in the first invention of the present invention, as the composition (A) for the application of artificial pearl coating, 22 to 33% by weight of a celluloid is 33 to 38% by weight of a mixture of acetone and ethyl acetate 3: 7, butyl acetate and amyl acetate 7 It is obtained by melt | dissolving in 33-38 weight% of 3: 3 mixtures, and adding 1-5 weight% of pigments here.

또한, 본 발명의 제2의 발명에서는, 인조 진주 도장의 중도용 조성물(B)로서, 셀룰로이드 22~33중량%를 아세톤과 에틸아세테이트 3:7 혼합물 25~29중량%, 부틸아세테이트와 아밀아세테이트 7:3 혼합물 40~44중량%에 용해한 다음, 여기에 안료 1~5중량%를 가하여 얻어지는 것을 특징으로 한다.Furthermore, in the second invention of the present invention, as an intermediate composition (B) for artificial pearl coating, the celluloid 22 to 33% by weight of 25 to 29% by weight of acetone and ethyl acetate 3: 7 mixture, butyl acetate and amyl acetate 7 It is obtained by melt | dissolving in 40-44 weight% of 3: 3 mixtures, and adding 1-5 weight% of pigments here.

또한, 본 발명의 제3의 발명에서는, 인조 진주 도장의 상도용 조성물(C)로서, 셀룰로이드 22~33중량%를 에틸아세테이트 19~22중량%와 부틸아세테이트 47~53중량%에 용해한 다음, 여기에 안료 0.1~1중량%를 가하여 얻어지는 것을 특징으로 한다.Further, in the third invention of the present invention, as a composition (C) for the top coat of artificial pearl coating, 22 to 33% by weight of celluloid is dissolved in 19 to 22% by weight of ethyl acetate and 47 to 53% by weight of butyl acetate, and then It is obtained by adding 0.1-1 weight% of pigments to the film.

상기 제1 및 제2발명에 있어서, 상기 아세톤과 에틸아세테이트의 배합비율은 3:7이 바람직한데, 그 이유는 아세톤을 너무 많이 사용하면 아세톤 특유의 역겨운 냄새가 강하고, 조성물 도장 후 너무 빨리 건조가 되어 다른 작업과의 발란스 조절이 어려우며, 반대로 에틸아세테이트를 너무 많이 사용하면 셀룰로이드의 완전 용해까지 시간이 걸리고 광택이 좋지 않다.
또한, 상기 제1 내지 제3 발명에 있어서, 각 성분의 한정이유는 다음과 같다.
셀룰로이드의 함량이 22중량% 미만이면 너무 묽어서 표면이 균일하게 도장하기 어렵고, 반대로 33중량%를 넘으면 너무 굳어지고 고화되어 건조가 불량하고 건조 과정에서 조성물이 흘러내릴 우려가 있어 좋지 않다.
아세톤과 에틸아세테이트의 혼합물의 함량이 너무 적으면 셀룰로이드 용해성이 나빠져 좋지 않고 반대로 너무 많아도 건조가 너무 빨라져 광택이 나지 않고 융도 불충분하게 되어 좋지 않다.
부틸아세테이트와 아밀아세테이트의 혼합물의 함량이 너무 적으면 건조시간이 길어지고, 반대로 너무 많아도 흘러내릴 염려가 있어 좋지 않다.
비스무스옥시클로라이드를 주성분으로 하는 액체 진주 안료의 함량이 너무 적으면 원하는 색의 발현이 어렵고, 반대로 너무 많아도 색 배열이 좋지않게 된다.In the first and second invention, the mixing ratio of acetone and ethyl acetate is preferably 3: 7, because if too much acetone is used, the disgusting smell peculiar to acetone is strong, and drying too soon after coating the composition It is difficult to control balance with other work, and on the contrary, when too much ethyl acetate is used, it takes time until complete dissolution of celluloid and poor gloss.
In addition, in the said 1st thru | or 3rd invention, the reason for limitation of each component is as follows.
If the content of celluloid is less than 22% by weight is too thin to difficult to uniformly coat the surface, on the contrary, if the content exceeds 33% by weight is too hard and solidified poor drying and there is a risk that the composition flows during the drying process is not good.
Too low a content of the mixture of acetone and ethyl acetate is not good, solubility in celluloid is not good, on the contrary too much drying is too fast, it is not good gloss and insufficient fusion.
If the content of the mixture of butyl acetate and amyl acetate is too small, the drying time may be long, and on the contrary, too much may be caused to flow.
When the content of the liquid pearl pigment containing bismuth oxychloride as a main component is too small, it is difficult to express a desired color, and on the contrary, even if too large, the color arrangement becomes poor.

상기 본 발명에서는 기존의 니트로셀룰로오스 대신에 가소제로서 장뇌를 함유하는 수지인 셀룰로이드를 사용하고, 이를 용해하는 용제로서 기존의 아세톤과 부틸아세테이트, 에틸아세테이트를 이용하되, 여기에 아세트산과 아밀알코올의 에스테르화합물이면서 윤활성이 있는 아밀아세테이트를 사용함과 동시에, 이들의 비율을 특정함으로써, 천연 진주에 가까운 최적의 조건을 형성하고 있다.In the present invention, using a celluloid, a resin containing camphor as a plasticizer instead of conventional nitrocellulose, and using acetone and butyl acetate, ethyl acetate as a solvent for dissolving it, wherein the ester compound of acetic acid and amyl alcohol At the same time, by using lubricated amyl acetate and specifying these ratios, optimum conditions close to natural pearls are formed.

또한 초도용 조성물(A)과 중도용 조성물(B)에 있어서 상기 부틸아세테이트와 아밀아세테이트의 비율이 7:3이나, 필요에 따라 부틸아세테이트만으로 구성할 수도 있다.Moreover, although the ratio of the said butyl acetate and an amyl acetate is 7: 3 in an initial composition (A) and an intermediate composition (B), you may comprise only butyl acetate as needed.

또한, 상기 본 발명에서 사용하는 안료로는 진주 광택(펄)의 발현에 가장 적합한 비스무스옥시클로라이드를 주성분으로 하는 액체 진주안료를 사용하되, 굳이 이산화티탄과 결합할 필요는 없고, 안료 입자의 크기는 5~25μ로 하는 것이 좋다.In addition, as the pigment used in the present invention, a liquid pearl pigment containing bismuth oxychloride which is most suitable for the expression of pearl luster (pearl) is used, but it does not necessarily need to be combined with titanium dioxide, and the size of the pigment particles It is good to set it to 5-25 micrometers.

이하, 실시예를 통하여 본 발명의 구성을 좀더 상세히 설명한다.Hereinafter, the configuration of the present invention through the embodiment in more detail.

실시예 1(초도용 조성물 A)Example 1 (First Composition A)

20ℓ의 용기에 셀룰로이드 원판을 칩 상태로 8kg을 유입하고 여기에 아세톤 3kg, 에틸아세테이트 7kg을 가한다.Into a 20 liter container, 8 kg of celluloid discs are introduced into chips, and 3 kg of acetone and 7 kg of ethyl acetate are added thereto.

교반을 계속하면서 부틸아세테이트 7kg과 아밀아세테이트3kg을 가하게 되면 약간 끈적 끈적한 상태에서 교반이 된다.While continuing stirring, 7 kg of butyl acetate and 3 kg of amyl acetate are added, and the stirring becomes slightly sticky.

이어서, 비스무스옥시클로라이드를 주성분으로 하는 액체안료 1.2kg을 첨가 교반하여 안료 입자를 용액속에 현탁시켜 점성이 있는 액상의 초도용 조성물을 얻는다.Subsequently, 1.2 kg of a liquid pigment containing bismuthoxychloride as a main component is added and stirred to suspend the pigment particles in a solution to obtain a viscous liquid coating composition.

실시예 2(중도용 조성물 B)Example 2 (intermediate composition B)

상기 실시예 1과 같은 방법으로 혼합, 반응시키되, 아세톤과 에틸아세테이트를 각각 2.4kg, 5.6kg로 하고, 부틸아세테이트와 아밀아세테이트를 각각 8.4kg, 3.6kg 투입하고, 이어서 비스무스옥시클로라이드를 주성분으로 하는 액체안료 1.2kg을 첨가하여 중도용 조성물을 얻는다.The mixture was mixed and reacted in the same manner as in Example 1, with 2.4 kg and 5.6 kg of acetone and ethyl acetate, 8.4 kg and 3.6 kg of butyl acetate and amyl acetate, respectively, followed by bismuth oxychloride. 1.2 kg of liquid pigment is added to obtain an intermediate composition.

실시예 3(상도용 조성물 C)Example 3 (Compositional Composition C)

20ℓ의 용기에 셀룰로이드 원판을 칩 상태로 8kg을 유입하고 여기에 에틸아세테이트 6kg을 가한다.Into a 20 liter container, 8 kg of celluloid discs are introduced into a chip state, and 6 kg of ethyl acetate is added thereto.

교반을 계속하면서 부틸아세테이트 14kg을 가한 다음, 비스무스옥시클로라이드를 주성분으로 하는 액체안료 0.1~1kg을 첨가 교반하여 상도용 조성물을 얻는다.14 kg of butyl acetate is added while stirring is continued, and 0.1-1 kg of liquid pigment containing bismuth oxychloride as a main component is added and stirred to obtain a composition for top coat.

실시예 4(응용예)Example 4 (Application Example)

인조 진주 비드를 상기 실시예 1에서 얻은 초도용 조성물에 침지 도장한 다음 45℃에서 20분 건조시킨 후, 실시예 2에서 얻은 중도용 조성물에 침지 도장하여 다시 건조시킨다.Artificial pearl beads were immersed and coated in the initial composition obtained in Example 1 and then dried at 45 ° C. for 20 minutes, and then dipped in the intermediate composition obtained in Example 2 and dried again.

이어서, 상기 실시예 3에서 얻어진 상도용 조성물에 침지하여 도장한 다음 건조시켜 최종 제품을 얻는다.Subsequently, it is immersed and coated in the top coat composition obtained in Example 3, and then dried to obtain a final product.

이와 같이 하여 얻어진, 본 발명의 각 조성물을 도장한 인조 진주는, 납 함량은 0.0025ppm 이하이고, 여기에 원하는 색상 발현을 위해 색소를 투입하면 은은 하게 반짝이면서 화사하고 신비로운 천연 진주와 같은 색감과 광택을 나타낸다.The artificial pearls coated with the compositions of the present invention obtained in this manner have a lead content of 0.0025 ppm or less, and when a pigment is added thereto for the desired color expression, the pearls are shimmery and bright and have the same color and luster as natural pearls. Indicates.

한편, 본 발명의 각 조성물을 사용할 때에는, 상기 초도용 조성물(A), 중도용 조성물(B) 및 상도용 조성물(C)을 순서대로 연속적으로 사용하는 것이 가장 바람직하지만, 이들 가운데 어느 하나를 생략하거나 다른 하나를 반복사용하는 것도 가능하다.On the other hand, when using each composition of this invention, although it is most preferable to continuously use the said composition for initial application (A), the composition for intermediate | middle (B), and the composition for top coats (C) sequentially, one of these is abbreviate | omitted. It is also possible to repeat one or the other.

예를들면, 사용 환경에 따라서는 상기 초도용 조성물(A)을 생략하고 중도용 조성물(B)을 사용한 후, 이를 기재로하여 상도용 조성물(C)을 사용하여 곧바로 마무리할 수도 있고, 또는 상기 초도용 조성물(A) 및 중도용 조성물(B) 모두를 생략하고 상도용 조성물(C)만 3~4회 반복사용할 수도 있는 것이다.For example, depending on the use environment, the initial composition (A) may be omitted, and then the intermediate composition (B) may be used, and then the composition may be immediately finished using the composition for coating (C). Both the initial composition (A) and the intermediate composition (B) may be omitted, and only the top composition (C) may be repeatedly used 3 to 4 times.

또한, 상기 본 발명의 각 조성물을 사용하는 방법으로는 분무(스프레이), 침지, 붓칠 등의 통상의 방법으로 사용가능하다.Moreover, as a method of using each composition of the said invention, it can be used by normal methods, such as spraying (spraying), dipping, and brushing.

상기 셀룰로이드의 사용 형태에 있어서도, 상기 아세톤이나 에틸아세테이트에 미리 용해해 놓은 상태에서 적치, 보관한 다음, 필요에 따라 나머지 성분을 소정의 비율로 첨가하여 사용할 수도 있는데, 이는 모두 본 발명의 범위에 속한다 하겠다.Also in the use form of the celluloid, it may be stored and stored in a state previously dissolved in the acetone or ethyl acetate, and then the remaining ingredients may be added at a predetermined ratio, if necessary, all belonging to the scope of the present invention. would.

또한, 상기 본 발명에서는 각 구성 성분을 소정의 비율로 적시하고는 있으나, 본 발명은 이들에 특정되는 것은 아니며 필요에 따라서 구성 성분이나 구성 비율의 가감도 가능함은 물론이다.In addition, although each component is timely indicated by the said ratio in the said invention, this invention is not specific to these, Of course, addition or addition of a component or a component ratio is also possible.

특히, 상기 본 발명에서는 인체에 무해한 비스무스옥시클로라이드를 안료로 사용하고 있으나 일부 특수한 경우에는 상기 비스무스옥시클로라이드 대신에 기존의 탄산납도 사용 가능함은 물론이다.Particularly, in the present invention, bismuth oxychloride which is harmless to the human body is used as a pigment, but in some special cases, conventional lead carbonate may also be used instead of the bismuth oxychloride.

이상 설명한 바와 같이, 본 발명에 따르면, 셀룰로이드를 아세톤과 에틸아세테이트의 혼합물, 부틸아세테이트와 아밀아세테이트의 혼합물에 용해한 다음, 여기에 소정의 비율로 안료를 가하여 얻어지는 초도용 조성물(A) 및 중도용 조성물(B), 혹은 셀룰로이드를 에틸아세테이트와 부틸아세테이트에 용해한 다음, 여기에 인체에 무해한 안료를 가하여 얻어지는 상도용 조성물(C)로서, 염기성 탄산납을 사용하는 종래의 방법에 비해 인체에 무해하고 친 환경적이면서, 기존의 이산화티탄이나 에틸아세테이트 조성물에 비해서는 사용 후의 색상과 광택이 뛰어나, 관련 분야에의 이용 및 응용이 기대된다 하겠다.As described above, according to the present invention, the first composition (A) and the intermediate composition obtained by dissolving celluloid in a mixture of acetone and ethyl acetate, a mixture of butyl acetate and amyl acetate, and then adding a pigment at a predetermined ratio thereto. (B) or a coating composition (C) obtained by dissolving celluloid in ethyl acetate and butyl acetate, and then adding a pigment that is harmless to the human body, which is harmless to the human body and is more environmentally friendly than a conventional method using basic lead carbonate. In addition, it is excellent in color and gloss after use as compared with the existing titanium dioxide and ethyl acetate composition, and is expected to be used and applied in related fields.

Claims (3)

하기 (A)~(C)의 조성물로 이루어진 것을 특징으로 하는 인조 진주 도장용 조성물Composition for artificial pearl coating, comprising the composition of the following (A) ~ (C) 셀룰로이드 22~33중량%를 아세톤과 에틸아세테이트 3:7 혼합물 33~38중량%, 부틸아세테이트와 아밀아세테이트 7:3 혼합물 33~38중량%에 용해한 다음, 여기에 비스무스옥시클로라이드를 주성분으로 하는 액체 진주 안료 1~5중량%를 가하여 얻어지는 초도용 조성물(A),22-33% by weight of celluloid was dissolved in 33-38% by weight of acetone and ethyl acetate 3: 7 mixture, and 33-38% by weight of butyl acetate and amyl acetate 7: 3 mixture, which was then used as a liquid pearl based on bismuthoxychloride. A composition for coating (A) obtained by adding 1 to 5% by weight of pigment, 셀룰로이드 22~33중량%를 아세톤과 에틸아세테이트 3:7 혼합물 25~29중량%, 부틸아세테이트와 아밀아세테이트 7:3 혼합물 40~44중량%에 용해한 다음, 여기에 비스무스옥시클로라이드를 주성분으로 하는 액체 진주 안료 1~5중량%를 가하여 얻어지는 중도용 조성물(B), 및22-33% by weight of celluloid was dissolved in 25-29% by weight of acetone and ethyl acetate 3: 7 mixture, and 40-44% by weight of butyl acetate and amyl acetate 7: 3 mixture, followed by a liquid pearl mainly composed of bismuthoxychloride. Intermediate composition (B) obtained by adding 1-5 weight% of pigments, and 셀룰로이드 22~33중량%를 에틸아세테이트 19~22중량%와 부틸아세테이트 47~53중량%에 용해한 다음, 여기에 비스무스옥시클로라이드를 주성분으로 하는 액체 진주 안료 0.1~1중량%를 가하여 얻어지는 상도용 조성물(C).22-33% by weight of celluloid was dissolved in 19-22% by weight of ethyl acetate and 47-53% by weight of butyl acetate, followed by adding 0.1-1% by weight of a liquid pearl pigment mainly composed of bismuthoxychloride. C). 삭제delete 삭제delete
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