KR100584846B1 - An insecticide containing coriander oil and its chemical composition - Google Patents
An insecticide containing coriander oil and its chemical composition Download PDFInfo
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- KR100584846B1 KR100584846B1 KR1020040011412A KR20040011412A KR100584846B1 KR 100584846 B1 KR100584846 B1 KR 100584846B1 KR 1020040011412 A KR1020040011412 A KR 1020040011412A KR 20040011412 A KR20040011412 A KR 20040011412A KR 100584846 B1 KR100584846 B1 KR 100584846B1
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- terpinene
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
- H04M1/026—Details of the structure or mounting of specific components
- H04M1/0266—Details of the structure or mounting of specific components for a display module assembly
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04B—TRANSMISSION
- H04B1/00—Details of transmission systems, not covered by a single one of groups H04B3/00 - H04B13/00; Details of transmission systems not characterised by the medium used for transmission
- H04B1/38—Transceivers, i.e. devices in which transmitter and receiver form a structural unit and in which at least one part is used for functions of transmitting and receiving
- H04B1/3827—Portable transceivers
- H04B1/3888—Arrangements for carrying or protecting transceivers
Abstract
종래의 인체에 유해한 유기합성 살충제와는 달리 순식물성이며 인체나 가축에 무해하면서도 위생해충의 살충력이 뛰어난 살충제가 개시된다. Unlike conventional synthetic synthetic pesticides harmful to humans, pesticides are disclosed that are pure vegetative and harmless to humans or livestock, but have excellent insecticidal properties.
본 발명에 의하면,According to the invention,
리모넨(limonene), 감마-테르피넨(γ-terpinene), 로우-사이멘(ρ-cymene), 알파-테르피네올렌(α-terpineolene), 캠퍼(camphor), 리날로올(linalool), 알파-테르피네올(α-terpineol) 등을 구성성분으로 하는 코리앤더오일을 유효성분으로 함유함을 특징으로 하는 살충제를 제공함으로서 그 목적이 달성된다.Limonene, gamma-terpinene, γ-terpinene, ρ-cymene, α-terpineolene, camphor, linalool, alpha- The object is achieved by providing a pesticide characterized in that it contains a coriander oil containing a terpineol (α-terpineol) and the like as an active ingredient.
Description
본 발명은 바퀴, 모기, 파리, 개미 등 가정 위생 해충에 대한 구제효과를 나타내는 살충제에 관한 것으로서, 보다 상세하게는 식물성 코리앤더오일과 그 유효성분을 함유하는 것을 살충용도로 사용하기 위한 용도에 관한 것이다.The present invention relates to a pesticide exhibiting a control effect against domestic hygiene pests such as wheels, mosquitoes, flies, ants, etc. More specifically, relates to the use for containing vegetable coriander oil and its active ingredient as a pesticidal use .
종래 가정 위생 해충 구제용 살충제로는 피레스로이드계 살충제인 알레트린(allethrin), 사이퍼메트린(cypermethrin), 레트스메트린(retsmethrin), 델타메트린(deltamethrin), 페르메트린(permethrin) 등과, 유기인계 살충제인 디클로르보스(dichlorvos), 클로르파이리포스(chlorpyrifos), 펜티온(fenthion), 디메토에이트(dimethoate), 페니트로치온(fenitrothion) 등이 사용되고 있으며, 이들 살충제의 효과를 상승시키기 위해 파이퍼로니 부톡사이드(piperony butoxide) 등과 같은 상승제 및 페로몬 등을 첨가하여 사용하기도 한다.Conventional pesticides for home hygiene pest control include allerthrin (allethrin), cypermethrin, letsmethrin, deltamethrin, permethrin, and the like, which are pyrethroid insecticides. Insecticides dichlorvos, chlorpyrifos, fenthion, dimethoate, fenitrothion, etc. are used, and piperonironi to increase the effectiveness of these insecticides Synergists such as butyoxide (piperony butoxide) and pheromone may be used in addition.
그러나 이러한 종래의 유기합성 살충재는 잔류독성, 인체에 미치는 영항, 여러 해충 종에서의 저항성 획득 등이 문제되고 있다. 따라서 최근 이러한 문제를 해결하기 위한 방안으로 환경친화적이고 인체나 가축에 대한 독성이 약한 천연 식물 성 물질을 해충구제제로 이용하려는 연구가 이루어지고 있다.However, such conventional organic synthetic insecticides have problems such as residual toxicity, effects on the human body, and obtaining resistance from various pest species. Therefore, as a way to solve these problems, researches are being conducted to use natural plant materials that are environmentally friendly and have low toxicity to humans or livestock as pest control agents.
식물정유성분들은 논-타켓(non-target) 미생물과 환경에 부작용이 적거나 없으며, 선택적이고(Arnason, 1989), 또한 해충에 대한 독성을 나타내고 있으나, 향수, 향료, 화장품의 원료로 사용될 만큼 안전한 것으로 알려져 있다.Plant essentials have little or no adverse effects on non-target microorganisms and the environment, are selective (Arnason, 1989), and also toxic to pests, but are safe enough to be used as ingredients for perfumes, perfumes and cosmetics. It is known.
이러한 식물성 정유 가운데 어떤 것은 급성 독성을 보이는 반면, 어떤 것들은 기피-유인효과, 산란 저해 그리고 생육과 발육에 영향을 보인다고 알려졌다. 이런 식물성정유의 독성 기작은 아직 밝혀지지 않았지만 증상의 발병은 빠르게 나타나며, 흥분(agitation), 활동과다(hyper-activity), 빠른 녹-다운(knock-down) 등이 수반된다.Some of these vegetable essential oils are known to be acutely toxic, while others have been shown to have repelling-attracting effects, spawning inhibition, and growth and development. The toxic mechanism of these essential oils is not yet known, but the onset of symptoms is rapid, with agitation, hyper-activity, and rapid knock-down.
더욱이, 대부분 식물성 정유는 포유동물에 대해 무독하며, 일반적으로 많은 식물성 정유성분들이 미국식품의약청(U.S Food and Drug Administration)에 의하여 안전하다고 알려져 있다. 또한 이러한 식물정유는 곤충에 독성을 보이는 곤충방제제로의 이용이 보고 되었다.Moreover, most vegetable essential oils are non-toxic to mammals and in general many vegetable essential oils are known to be safe by the U.S. Food and Drug Administration. In addition, these plant essential oils have been reported to be used as insect control agents that are toxic to insects.
이들과 관련하여 대한민국 공개특허 제 2003-33722 호에서는 살충성을 가지는 식물정유 및 화합물을 공개하고 있다. 그러나 상기 공개특허에서는 구체적인 식물의 살충유효성분 등에 대하여는 개시하고 있지 못하고 있고, 아직까지 식물정유를 이용하여 바퀴, 모기, 파리, 개미 등의 가정 위생 해충의 구제제로 효과적으로 이용한 사례는 찾아볼 수 없다.In connection with these, Korean Patent Publication No. 2003-33722 discloses plant essential oils and compounds having insecticidal properties. However, the above-mentioned patent does not disclose a specific pesticidal active ingredient of the plant, and there are no examples of effectively using the plant essential oil as a remedy for domestic hygiene pests such as wheels, mosquitoes, flies, and ants.
따라서 본 발명의 목적은 종래의 살충제가 갖고 있는 잔류독성 및 위생 해충 종에서의 저항성 증가 등의 문제를 해결하기 위하여 친환경적이고, 잔류독성이 없어서 인체와 가축에 안정한 살충활성 물질을 코리앤더오일 및 그 유효성분으로부터 이용하는 살충제를 제공함에 있다.Accordingly, an object of the present invention is to provide a pesticide active material that is environmentally friendly and does not have residual toxicity to solve problems such as increased residual toxicity and resistance to hygienic pest species of conventional insecticides, and is effective in coriander oil and its effectiveness. In providing an insecticide to be used from the component.
본 발명에서 사용하는 천연식물인 코리앤더오일과 그 구성성분은 바퀴, 모기, 파리, 개미 등 가정 위생 해충의 구제효과가 탁월하면서도 인체 등에 해가 없어서 종래의 유기살충제를 대체할 수 있는 살충물질이다.Coriander oil and its components, which are natural plants used in the present invention, are excellent insect repellents such as wheels, mosquitoes, flies, ants, etc.
상기와 같은 본 발명의 목적을 달성하기 위하여 본 발명은,In order to achieve the object of the present invention as described above,
리모넨(limonene), 감마-테르피넨(γ-terpinene), 로우-사이멘(ρ-cymene), 알파-테르피네올렌(α-terpineolene), 캠퍼(camphor), 리날로올(linalool), 알파-테르피네올(α-terpineol) 등을 구성성분으로 하는 코리앤더오일을 유효성분으로 함유함을 특징으로 하는 살충제를 제공한다.Limonene, gamma-terpinene, γ-terpinene, ρ-cymene, α-terpineolene, camphor, linalool, alpha- It provides a pesticide characterized in that it contains a coriander oil containing a terpineol (α-terpineol) and the like as an active ingredient.
본 발명은 또한 상기 코리앤더오일의 구성성분 중 감마-테르피넨 및/또는 제라닐 아세테이트를 유효성분으로 함유함을 특징으로 하는 살충제를 제공한다.The present invention also provides an insecticide characterized in that it contains gamma-terpinene and / or geranyl acetate as an active ingredient in the components of the coriander oil.
상기에서 유효성분의 농도는 1-5㎕로 함이 바람직하다.In the above, the concentration of the active ingredient is preferably 1-5 μl.
본 발명에서 사용하는 코리앤더오일과 그 구성화합물의 가정 위생 해충 구제효과가 있음을 밝혔다. 이 식물정유와 그 구성성분은 방향성이 있는 물질로 이들 방향성 물질은 종래부터 조미로, 화장품, 세제 등의 방향산업과 풍미산업에서 사용되어 온 것으로 환경과 인체에 대해 안전하며 잔류독성이 없다.It was found that the coriander oil used in the present invention and its constituent compounds have a home hygiene pest control effect. This plant essential oil and its constituents are aromatic substances. These aromatic substances have been used in flavoring industry such as cosmetics and detergents and flavor industries since they are conventionally seasoned, and are safe for the environment and human body and have no residual toxicity.
코리앤더오일은 리모넨, 감마-테르피넨, 로우-사이멘, 알파-테르피네올렌, 캠퍼, 리날로울, 알파-테르피네올, 제라닐 아세테이트, 제라니올감마-테르피넨과 제라니올 아세테이트가 주요성분으로 구성되어 있다. 이들 성분은 휘발성이 강한 정유로 훈증과 기피효과가 있다.Coriander oils include limonene, gamma-terpinene, low-simen, alpha-terpineolene, camphor, linalool, alpha-terpineol, geranyl acetate, geraniolgamma-terpinene and geraniol acetate. Consists of main ingredients. These ingredients are highly volatile essential oils and have a fumigation and repelling effect.
이하, 실시예를 통해 본 발명의 보다 구체적으로 설명한다. 그러나 다음의 실시예에 의해 본 발명의 기술적 범위가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples. However, the technical scope of the present invention is not limited by the following examples.
실시예Example
코리앤더오일의 분석Analysis of Coriander Oil
가스크로매토그라피(Gas chromatography; GC, DS 6200)와 가스크로매토그라피-매스 스펙트로메트리(gas chromatography-mass spectrometry; GC/MS, Hewlett Packard 5890)를 이용하여 분석하였다. 실험에 이용된 콜룸(column)은 DB-WAX (0.25㎜ ×30㎜)와 DB-1 (0.25㎜ ×30㎜)을 이용하였고 캐리어가스(carrier gas)는 N2를 이용하였으며, 오븐(oven) 온도는 30℃~180℃ (2℃/min)로 하였다. 또한 주입구의 온도는 200℃로 하였고 검출기 온도는 210℃의 조건 하에서 프레임 이오니제이션 딕텍터(flame ionization detector)로 검출했으며, 이온화는 70 eV에서 수행하였다. 정유의 구성성분은 GC/MS로부터 시료의 토탈이온 크로매토그람(total ion chromatogram)을 얻은 후, WILEY138 라이브러리(library)의 자료(Hewlett Packard)와 비교하여 확인하였다.Analysis was performed using gas chromatography (GC, DS 6200) and gas chromatography-mass spectrometry (GC / MS, Hewlett Packard 5890). The column used in the experiment was DB-WAX (0.25 mm x 30 mm) and DB-1 (0.25 mm x 30 mm), and the carrier gas was N 2 , and an oven was used. The temperature was made into 30 degreeC-180 degreeC (2 degreeC / min). In addition, the temperature of the inlet was 200 ° C. and the detector temperature was detected by a frame ionization detector under the condition of 210 ° C., and ionization was performed at 70 eV. The constituents of the essential oils were obtained from GC / MS by obtaining a total ion chromatogram of the sample, and compared with the Hewlett Packard in the WILEY138 library.
바퀴, 집파리, 빨간집모기, 애집개미에 대한 훈증효과 시험Test of fumigation effects on wheels, house flies, red mosquitoes, and pet ants
바퀴, 집파리 ,빨간집모기, 애집개미에 대한 식물정유의 훈증독성은 수컷성 충을 10마리씩 투명한 원통형아크릴용기(9 ×15㎝)에 넣고, 각 화합물 원액을 필터페이퍼(filter paper)(Ø5.5㎝/2)에 적정량을 처리하여 원통형 아크릴용기 바닥에 놓고, 화합물의 휘발성분이 용기 밖으로 휘발되는 것을 막기 위해 페트리디쉬(Ø9㎝)를 뚜껑으로 사용하여, 파라필름(parafilm)으로 밀봉하였다. 처리 24시간, 48시간 후에 사충수를 조사하였으며, 모든 시험은 3반복 이상으로 수행하였다. 시험 조건은 온도 26∼28℃, 광주기 12Ｌ: 12Ｄ, 상대습도 40∼60%로 하였다.The fumigation toxicity of plant essential oils against wheels, house flies, red mosquitoes, and antler ants was measured by putting 10 male larvae in a transparent cylindrical acrylic container (9 × 15 cm), and each stock solution of the filter paper (Ø5. 5 cm / 2) was applied to the bottom of the cylindrical acrylic container and sealed with parafilm using Petri dish (Ø9 cm) as a lid to prevent volatilization of the compound from being volatilized out of the container. The larvae were examined 24 hours and 48 hours after the treatment, and all the tests were performed at least 3 repetitions. The test conditions were set to the temperature of 26-28 degreeC, the photoperiod 12L: 12D, and the relative humidity 40-60%.
[표 1] 위생해충 성충과 유충에 대한 코리앤더오일과 그 성분의 훈증효과 [Table 1] Fumigation Effects of Coriander Oil and Its Components on Sanitary Pests and Larvae
코리앤더오일과 그 성분의 바퀴, 집파리, 빨간집모기, 애집개미에 대한 훈증효과를 실험한 결과는 상기 표 1과 같다. 상기표에서 확인할 수 있듯이 코리앤더오일과 그 성분은 대조약제인 페르메트린(permethrin)보다 우수한 살충효과를 나타내었다. The results of experimenting with the fumigation effect on the coriander oil and its components, wheel flies, red mosquitoes, and ant ants are shown in Table 1 above. As can be seen from the above table, coriander oil and its components showed a superior insecticidal effect than the control drug permethrin.
상기한 바와 같이 본 발명에 의하면 식물성인 코리앤더오일과 그 주요성분으로 인해 인체에는 무해하고 살충효과는 종래의 것보다 탁월한 살충제를 얻을 수가 있다. 특히 코리앤더오일과 그 성분 중 감마-테르피넨 및/ 또는 제라닐 아세테이트는 바퀴, 집파리, 모기, 개미 등의 위생해충에 탁월한 효과를 나타내고 있으므로 종래의 유해한 유기합성 살충제를 대체하는 살충제로 유용하게 사용할 수 있다. As described above, according to the present invention, the vegetable coriander oil and its main components are harmless to the human body, and the insecticidal effect is superior to that of the conventional one. In particular, coriander oil and gamma-terpinene and / or geranyl acetate have excellent effects on hygienic pests such as wheels, house flies, mosquitoes and ants, and thus can be useful as insecticides replacing conventional harmful organic synthetic insecticides. have.
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