KR100568095B1 - 에폭시 수지의 수성 분산액 및 이의 제조방법 - Google Patents
에폭시 수지의 수성 분산액 및 이의 제조방법 Download PDFInfo
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- KR100568095B1 KR100568095B1 KR1020017000623A KR20017000623A KR100568095B1 KR 100568095 B1 KR100568095 B1 KR 100568095B1 KR 1020017000623 A KR1020017000623 A KR 1020017000623A KR 20017000623 A KR20017000623 A KR 20017000623A KR 100568095 B1 KR100568095 B1 KR 100568095B1
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- South Korea
- Prior art keywords
- resin
- epoxy resin
- epoxy
- aqueous dispersion
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 71
- 239000006185 dispersion Substances 0.000 title claims abstract description 54
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- 239000011347 resin Substances 0.000 claims abstract description 68
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- 239000000203 mixture Substances 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 22
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- 230000001804 emulsifying effect Effects 0.000 claims abstract description 3
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- 239000004593 Epoxy Substances 0.000 claims description 26
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- 239000001257 hydrogen Substances 0.000 claims description 7
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
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- 229920002025 Pluronic® F 88 Polymers 0.000 description 4
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- 239000002562 thickening agent Substances 0.000 description 3
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 3
- VRRDONHGWVSGFH-UHFFFAOYSA-N 2,5-diethylcyclohexane-1,4-diamine Chemical compound CCC1CC(N)C(CC)CC1N VRRDONHGWVSGFH-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
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- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
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- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- JQTFRJBBUHWNME-UHFFFAOYSA-N [I+].C(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [I+].C(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 JQTFRJBBUHWNME-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- NJYZCEFQAIUHSD-UHFFFAOYSA-N acetoguanamine Chemical compound CC1=NC(N)=NC(N)=N1 NJYZCEFQAIUHSD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- SZOHULOJLBUVSJ-UHFFFAOYSA-K aluminum;zinc;phosphate;hydrate Chemical class O.[Al+3].[Zn+2].[O-]P([O-])([O-])=O SZOHULOJLBUVSJ-UHFFFAOYSA-K 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical class [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- VAWSWDPVUFTPQO-UHFFFAOYSA-N calcium strontium Chemical compound [Ca].[Sr] VAWSWDPVUFTPQO-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical group C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920001303 methylated polymer Polymers 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QQWAKSKPSOFJFF-UHFFFAOYSA-N oxiran-2-ylmethyl 2,2-dimethyloctanoate Chemical compound CCCCCCC(C)(C)C(=O)OCC1CO1 QQWAKSKPSOFJFF-UHFFFAOYSA-N 0.000 description 1
- 238000010951 particle size reduction Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical class O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- QRUBYZBWAOOHSV-UHFFFAOYSA-M silver trifluoromethanesulfonate Chemical compound [Ag+].[O-]S(=O)(=O)C(F)(F)F QRUBYZBWAOOHSV-UHFFFAOYSA-M 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/07—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/116,922 | 1998-07-17 | ||
| US09/116,922 US6143809A (en) | 1998-07-17 | 1998-07-17 | Process to prepare aqueous dispersions of epoxy resins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010079534A KR20010079534A (ko) | 2001-08-22 |
| KR100568095B1 true KR100568095B1 (ko) | 2006-04-07 |
Family
ID=22370052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020017000623A Expired - Lifetime KR100568095B1 (ko) | 1998-07-17 | 1999-07-12 | 에폭시 수지의 수성 분산액 및 이의 제조방법 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6143809A (https=) |
| EP (1) | EP1117728B1 (https=) |
| JP (1) | JP2002520462A (https=) |
| KR (1) | KR100568095B1 (https=) |
| AR (1) | AR019399A1 (https=) |
| AT (1) | ATE268348T1 (https=) |
| AU (1) | AU5037299A (https=) |
| BR (1) | BR9912135A (https=) |
| CA (1) | CA2337389C (https=) |
| DE (1) | DE69917792T2 (https=) |
| DK (1) | DK1117728T3 (https=) |
| ES (1) | ES2219035T3 (https=) |
| NO (1) | NO20010262L (https=) |
| WO (1) | WO2000004077A1 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6525115B2 (en) * | 2000-12-05 | 2003-02-25 | Eastman Kodak Company | Method of making an aqueous dispersion of particles comprising an epoxy material for use in coatings |
| JP4694110B2 (ja) * | 2003-06-18 | 2011-06-08 | ユニチカ株式会社 | ポリ乳酸樹脂水性分散体の製造方法 |
| US20100040888A1 (en) * | 2008-08-13 | 2010-02-18 | Vacumet Corp. | Metallized barrier material |
| WO2010147262A1 (ko) * | 2009-06-15 | 2010-12-23 | 태산엔지니어링 주식회사 | 수성 에폭시 수지 모르타르 조성물, 이를 포함하는 수성 접착제 및 수성 코팅제 |
| CN101899163B (zh) * | 2010-08-14 | 2012-07-25 | 武汉工程大学 | 一种自乳化非离子型水性酚醛环氧树脂乳液的制备方法 |
| US8586704B2 (en) * | 2010-12-13 | 2013-11-19 | Momentive Specialty Chemicals Inc. | Epoxy systems and amine polymer systems and methods for making the same |
| US8580871B2 (en) | 2010-12-13 | 2013-11-12 | Momentive Specialty Chemicals Inc. | Epoxy systems and amine polymer systems and methods for making the same |
| PL2652039T3 (pl) * | 2010-12-13 | 2020-05-18 | Hexion Research Belgium Sa | Polepszone układy epoksydowe i układy polimeru aminowego oraz sposoby ich wytwarzania |
| CN104271630B (zh) | 2012-05-31 | 2017-07-28 | 陶氏环球技术有限公司 | 用于水性分散体的环氧树脂 |
| US10000643B1 (en) * | 2014-10-03 | 2018-06-19 | The United States Of America As Represented By The Secretary Of The Navy | Waterborne corrosion resistant organic primer compositions |
| CN106867405B (zh) * | 2017-03-03 | 2019-05-21 | 北京理工大学 | 一种基于聚酰胺-胺树形分子的疏水涂料及其制备方法 |
| JP7368938B2 (ja) * | 2017-12-22 | 2023-10-25 | 関西ペイント株式会社 | 防食性に優れた水性塗料組成物 |
| WO2021099056A1 (en) | 2019-11-18 | 2021-05-27 | Basf Se | Emulsifiers for epoxy resins, aqueous epoxy resin dispersions comprising the same, and methods for preparation thereof |
| CN110951082B (zh) * | 2019-12-06 | 2022-02-15 | 万华化学集团股份有限公司 | 梳状阴-非离子型活性环氧乳化剂的制备方法及环氧树脂乳液的制备方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE629845A (https=) * | 1962-03-20 | |||
| DE1494525C3 (de) * | 1963-09-19 | 1978-08-17 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Härtbare Kunststoffmischungen |
| CH603713A5 (https=) * | 1972-07-25 | 1978-08-31 | Hoechst Ag | |
| US4197389A (en) * | 1977-07-18 | 1980-04-08 | Hoechst Aktiengesellschaft | Hardening agent for aqueous epoxy resin compositions |
| US4122067A (en) * | 1977-10-07 | 1978-10-24 | Celanese Polymer Specialties Company | Process of reacting a polyepoxide compound with a phenol in aqueous medium |
| US4315044A (en) * | 1980-11-05 | 1982-02-09 | Celanese Corporation | Stable aqueous epoxy dispersions |
| US4423166A (en) * | 1981-07-20 | 1983-12-27 | Ppg Industries, Inc. | Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition |
| DE3901279A1 (de) * | 1989-01-18 | 1990-07-19 | Hoechst Ag | Verwendung von polyamidoaminen als haerter fuer epoxidharze und diese enthaltende haertbare mischungen |
| GB9000564D0 (en) * | 1990-01-10 | 1990-03-14 | Dow Rheinmuenster | Modified polyoxyethlene epoxy resin amphiphiles and stable aqueous epoxy dispersions thereof |
| DE4128487A1 (de) * | 1991-08-28 | 1993-03-04 | Hoechst Ag | Verfahren zur herstellung von waessrigen epoxidharz-dispersionen |
| US5166423A (en) * | 1991-08-30 | 1992-11-24 | Shell Oil Company | Process for the oxidation of alcohols to acids |
| JPH05178967A (ja) * | 1991-12-26 | 1993-07-20 | Mitsubishi Gas Chem Co Inc | 水性エポキシ樹脂組成物 |
| DE4206392A1 (de) * | 1992-02-29 | 1993-09-02 | Hoechst Ag | Haertungsmittel fuer epoxidharze |
| US5250727A (en) * | 1992-12-23 | 1993-10-05 | Shell Oil Company | Preparation of alkoxyalkanoic acids |
| JPH06287276A (ja) * | 1993-04-05 | 1994-10-11 | Sanyo Chem Ind Ltd | 水性エポキシ樹脂組成物 |
| DE69426371T2 (de) * | 1993-05-07 | 2001-05-17 | Nippon Paint Co., Ltd. | Wässrige Polyoxyalkylene Oberflachenbehandlungslösungen |
| US5565505A (en) * | 1993-06-30 | 1996-10-15 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| WO1996006876A1 (en) * | 1994-09-01 | 1996-03-07 | Henkel Corporation | Self-dispersing epoxy resins and coatings therefrom |
| US5576416A (en) * | 1994-12-13 | 1996-11-19 | Air Products And Chemicals, Inc. | Amide-containing self-emulsifying epoxy curing agent |
| WO1996020970A1 (en) * | 1994-12-29 | 1996-07-11 | Henkel Corporation | Aqueous self-dispersible epoxy resin based on epoxy-amine adducts |
| US5643976A (en) * | 1994-12-29 | 1997-07-01 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| US5750595A (en) * | 1994-12-29 | 1998-05-12 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| DE19520854A1 (de) * | 1995-06-08 | 1996-12-12 | Hoechst Ag | Selbstemulgierende wäßrige Epoxidharzdispersionen |
| DE19536381A1 (de) * | 1995-09-29 | 1997-04-03 | Hoechst Ag | Reaktivverdünner-haltige Epoxid- und Epoxid-Polyacrylat-Dispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5602193A (en) * | 1995-10-31 | 1997-02-11 | Shell Oil Company | Aqueous dispersions of epoxy resins |
| US5741835A (en) * | 1995-10-31 | 1998-04-21 | Shell Oil Company | Aqueous dispersions of epoxy resins |
| US5786429A (en) * | 1996-04-18 | 1998-07-28 | Hercules Incorporated | Highly branched polyamidoamines and their preparation |
| ATE229994T1 (de) * | 1997-08-14 | 2003-01-15 | Resolution Res Nederland Bv | Wässrige dispersionen von epoxidharzen |
| US6277928B1 (en) * | 1998-03-03 | 2001-08-21 | Charles J. Stark | Epoxy-functional amidoamine reacted with excess polyamine and monoepoxy as epoxy curative |
-
1998
- 1998-07-17 US US09/116,922 patent/US6143809A/en not_active Expired - Lifetime
-
1999
- 1999-07-12 AT AT99934681T patent/ATE268348T1/de active
- 1999-07-12 CA CA002337389A patent/CA2337389C/en not_active Expired - Lifetime
- 1999-07-12 BR BR9912135-2A patent/BR9912135A/pt not_active IP Right Cessation
- 1999-07-12 ES ES99934681T patent/ES2219035T3/es not_active Expired - Lifetime
- 1999-07-12 WO PCT/EP1999/004925 patent/WO2000004077A1/en not_active Ceased
- 1999-07-12 EP EP99934681A patent/EP1117728B1/en not_active Expired - Lifetime
- 1999-07-12 KR KR1020017000623A patent/KR100568095B1/ko not_active Expired - Lifetime
- 1999-07-12 AU AU50372/99A patent/AU5037299A/en not_active Abandoned
- 1999-07-12 JP JP2000560181A patent/JP2002520462A/ja active Pending
- 1999-07-12 DK DK99934681T patent/DK1117728T3/da active
- 1999-07-12 DE DE69917792T patent/DE69917792T2/de not_active Expired - Lifetime
- 1999-07-15 AR ARP990103474A patent/AR019399A1/es unknown
-
2001
- 2001-01-16 NO NO20010262A patent/NO20010262L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1117728B1 (en) | 2004-06-02 |
| NO20010262D0 (no) | 2001-01-16 |
| JP2002520462A (ja) | 2002-07-09 |
| CA2337389A1 (en) | 2000-01-27 |
| WO2000004077A1 (en) | 2000-01-27 |
| DE69917792T2 (de) | 2005-06-23 |
| DE69917792D1 (de) | 2004-07-08 |
| DK1117728T3 (da) | 2004-10-04 |
| ES2219035T3 (es) | 2004-11-16 |
| BR9912135A (pt) | 2001-04-10 |
| EP1117728A1 (en) | 2001-07-25 |
| ATE268348T1 (de) | 2004-06-15 |
| AU5037299A (en) | 2000-02-07 |
| NO20010262L (no) | 2001-03-16 |
| CA2337389C (en) | 2008-02-26 |
| KR20010079534A (ko) | 2001-08-22 |
| AR019399A1 (es) | 2002-02-20 |
| US6143809A (en) | 2000-11-07 |
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