KR100547028B1 - Method for manufacturing bricks of traditional black and gray color utilizing oxzdation-reduction reacting oxides - Google Patents
Method for manufacturing bricks of traditional black and gray color utilizing oxzdation-reduction reacting oxides Download PDFInfo
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- KR100547028B1 KR100547028B1 KR1020030072002A KR20030072002A KR100547028B1 KR 100547028 B1 KR100547028 B1 KR 100547028B1 KR 1020030072002 A KR1020030072002 A KR 1020030072002A KR 20030072002 A KR20030072002 A KR 20030072002A KR 100547028 B1 KR100547028 B1 KR 100547028B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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Abstract
본 발명은 흑색 내지 재색계통의 전통미가 있는 전돌 제품을 기존의 이부식 소성방식에 비해 월등히 높은 생산효율 및 저렴한 가격으로 대량생산해낼 수 있는, 금속산화물 및 착색산화물을 이용한 흑색 벽돌 및 보도블록 제조방법에 관한 것이다.The present invention provides a method for producing black brick and sidewalk blocks using metal oxides and colored oxides, which can mass-produce black and red-colored traditional stone products at a much higher production efficiency and lower price than conventional two-coating firing methods. It is about.
본 발명은 60~70 중량%의 점토와, 20~30 중량%의 마사와, 3~10 중량%의 산화철과, 3~10 중량%의 이산화망간과, 1~3 중량%의 산화크롬 및 기타 필요한 성분으로 혼합조성된 원료를 마련하는 단계와; 상기 원료를 사용하여 제조하고자 하는 제품모양대로의 성형물을 제작하는 단계와; 상기 성형물들을 대차(20)에 실어 예열대(11)와 소성대(12) 및 냉각대(13)가 구비된 터널식 연속소성가마(10)를 통과시켜 소성하는 단계를 포함하는 것을 특징으로 하는 금속산화물 및 착색산화물을 이용한 흑색 벽돌 및 보도블럭 제조방법을 제공한다.The present invention provides 60 to 70 weight percent clay, 20 to 30 weight percent masa, 3 to 10 weight percent iron oxide, 3 to 10 weight percent manganese dioxide, 1-3 weight percent chromium oxide and other necessary Preparing a raw material mixed with the components; Manufacturing a molded product according to a product shape to be manufactured using the raw material; And a step of firing the moldings in the trolley 20 to pass through the tunnel-type continuous firing kiln 10 having the preheating zone 11, the firing zone 12, and the cooling zone 13. Provided are a method for producing black bricks and sidewalk blocks using oxides and colored oxides.
Description
도1은 기존의 이부식 소성방식에 의한 전돌 제조시설의 개요도,1 is a schematic diagram of a conventional stone manufacturing facility according to a two-piece plastic firing method,
도2는 본 발명의 방법에 의한 전돌 제조시설의 개요도,2 is a schematic view of a stone manufacturing facility according to the method of the present invention,
도3은 기존의 이부식 소성방식에 의한 전돌 제조공정의 블럭도,Figure 3 is a block diagram of a process for producing a projection by a conventional two-coating plastic method,
도4는 본 발명의 방법에 의한 전돌 제조공정의 블럭도,4 is a block diagram of a process for producing a stone according to the method of the present invention;
* 도면중 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings
1 : 철가마 2 : 문1: iron kiln 2: door
3 : 연돌 10 : 터널식 연속소성가마3: stack 10: tunnel type continuous firing kiln
11 : 예열대 12 : 소성대11: preheating table 12: firing table
13 : 냉각대 20 : 대차13: cooling stand 20: bogie
본 발명은 벽돌 및 보도블럭 제조방법에 관한 것으로, 특히 금속산화물 및 착색산화물을 이용하여 흑색계통의 벽돌 및 보도블럭을 높은 생산성으로 용이하게 제조해낼 수 있도록 연구된, 금속산화물 및 착색산화물을 이용한 흑색 벽돌 및 보도블럭 제조방법에 관한 것이다.The present invention relates to a brick and sidewalk block manufacturing method, in particular black metal using a metal oxide and colored oxide, which has been studied to easily produce a brick and sidewalk block of a black system with high productivity using metal oxides and colored oxides. The present invention relates to a brick and a sidewalk block manufacturing method.
한옥이나 사찰, 궁궐과 같은 전통 가옥의 건축 및 조경에는 소위 전돌이라 하여 흑색계통의 벽돌 및 보도블럭이 많이 사용되게 되는데, 이러한 전돌은 흑색계통 특유의 차분하고 중후한 장식미와 분위기를 제공하기 때문에 근래에도 그러한 장식미와 분위기가 요구되는 건축물의 건축현장에서 많이 쓰이고 있다.In the construction and landscaping of traditional houses such as hanoks, temples, and palaces, so-called masonry are often used as black bricks and sidewalk blocks. These masonry provide a calm and dignified decoration and atmosphere unique to the black system. It is widely used in architectural sites where such decoration and atmosphere are required.
현재, 일반적인 점토 벽돌 및 보도블럭은 반자동화내지 자동화된 생산시설을 통해 연속 대량으로 제조 생산이 가능하나, 본 발명이 관련된 상술한 전돌은 아직까지 전통재래식의 소성(구워내기) 방법에 의존하여 제조되고 있기 때문에 생산성이 현저히 뒤떨어지고 생산단가가 높아 점차 사양화되고 있는 실정에 직면하고 있다.Currently, general clay bricks and sidewalk blocks can be manufactured and produced in a continuous mass through semi-automated or automated production facilities, but the above-described projections related to the present invention are manufactured by relying on traditional methods of baking (baking). As a result, productivity is remarkably inferior, and production costs are high, thus facing a situation that is gradually being specified.
즉, 기존의 전돌 제조방법은 도1에서 보는 바와 같이 한번에 약 일만장 정도의 전돌을 구워낼 수 있는 사각의 철가마(1)내에 성형물을 쌓아 넣고 가마의 문(2)을 닫아 밀폐시킨 상태에서 불을 때서 소성한 후 냉각시켜 꺼내도록 하는 방법으로서 일주일에 보통 한 가마정도밖에 생산할 수 없는 방법인 바, 철가마(1) 내에서 1000℃~1050℃정도의 온도까지 산화염소성을 한 후 연돌(굴뚝)(3)을 막아 놓고 온도를 계속 유지하면서 불을 때면 연료의 탄소성분이 성형물에 침탄되어 흑색 내지 재색의 색상을 가진 성형물로 소성되어지는 것이다. 이러한 소성방식을 일명 이부식 소성방식이라 칭하는데, 전통의 떡짓는 시루나 흑색 내지 재색의 토기들이 모두 이 방법으로 제조되었다.That is, in the conventional method for manufacturing a stone, as shown in Figure 1 stacked moldings in a square iron kiln (1) capable of baking about 10,000 pieces of stone at a time, and closed the door (2) of the kiln closed It is a method to be fired at the time of firing and then to be cooled and taken out. It is a method that can only produce about one kiln a week. When the chimney (3) is blocked and the fire is kept while maintaining the temperature, the carbon component of the fuel is carburized in the molding to be fired into a molding having black to red color. This firing method is referred to as a so-called two-sided firing method, all traditional rice cake siru or black to red earthenware was produced by this method.
본 발명은 상술한 바와 같은 전통의 이부식 소성방식에 의존한 기존의 전돌 제조방법이 생산단가가 높고 생산성이 저조하여 갈수록 제품 생산 및 수요가 줄어 들고 있는 문제점이 있음을 감안하여 이를 효과있게 해소할 수 있는 새로운 제조방법을 제공하기 위해 연구발명된 것으로, 전통의 멋과 품격을 지닌 흑색 계통의 벽돌 및 보도블럭을 높은 생산성으로 저렴하게 제조공급할 수 있게 하려는 것이다.The present invention can be effectively solved in view of the problem that the existing production process for the existing stone, which relies on the conventional two-side plasticity method as described above has a problem that the production cost and production is decreasing due to high production cost and low productivity. It was researched to provide a new manufacturing method, and it is intended to be able to manufacture and supply black bricks and sidewalk blocks of tradition and style with high productivity at low cost.
이하에서, 상기의 목적을 달성하기 위한 본 발명을 첨부도면을 참조하여 상세히 설명한다.Hereinafter, with reference to the accompanying drawings, the present invention for achieving the above object will be described in detail.
전술한 이부식 소성방식에 의한 종래의 흑색벽돌 및 보도블럭 제조방법은 성형물 소성을 위한 철가마 내부전체를 동일한 연소분위기로 연소유지시켜야 하고, 또 온도를 정도이상으로 상승시키지 않으면서 장시간 침탄 소성시켜야 하는 제조상의 난점이 따르기 때문에 생산성이 매우 저조한 단점이 있는 바, 본 발명은 이러한 종래의 단점을 지양하여 성형물을 일반 점토 벽돌의 제조공정에서와 같은 터널식 연속소성가마를 통해 연속 대량으로 높은 생산효율로 소성 제조해낼 수 있으면서 그 소성 제품의 표면에 본 발명이 의도하는 흑색계통의 전통미가 있는 색상 및 질감이 양호하게 표출되게 할 수 있는 제조방법을 제공하려는 것이다.The conventional method of manufacturing black brick and sidewalk block by the two-corrosion firing method is to maintain the entire inside of the iron kiln for the molding firing in the same combustion atmosphere, and to carry out carburizing firing for a long time without raising the temperature above. Due to manufacturing difficulties, there is a disadvantage in that the productivity is very low. The present invention avoids this conventional disadvantage, and the molded product is fired at a high yield in continuous mass through a tunnel type continuous firing kiln as in the manufacturing process of ordinary clay brick. The present invention aims to provide a manufacturing method capable of producing a satisfactory color and texture of the black system traditionally intended by the present invention on the surface of the fired product.
이를 달성하기 위해 본 발명은 60~70 중량%의 점토와, 20~30중량%의 가는 모래(보명토) 또는 마사와, 금속산화물로서 3~10중량%의 산화철과, 착색산화물로서 3~10 중량%의 이산화망간 및 1~3 중량%의 산화크롬과, 기타 필요한 성분으로 혼합 조성된 원료를 마련하는 단계와; 상기 원료를 사용하여 벽돌이나 보도블럭등 제조하고자 하는 제품모양대로의 성형물을 제작하는 단계와; 상기 성형물들을 대차에 실어 예열대와 소성대 및 냉각대가 구비된 통상적인 터널식 연속소성가마를 통과시켜 연속적으로 예열, 소성, 냉각, 취출하는 단계를 포함하는 것을 특징으로 하는 금속산화물 및 착색산화물을 이용한 흑색 벽돌 및 보도블럭 제조방법을 제공한다.In order to achieve this, the present invention provides 60 to 70% by weight of clay, 20 to 30% by weight of fine sand or martha, 3 to 10% by weight of iron oxide as metal oxide, and 3 to 10 as colored oxide. Preparing a raw material mixed with manganese dioxide by weight and 1-3% by weight of chromium oxide and other necessary ingredients; Manufacturing a molded article according to a product shape to be manufactured using the raw material such as a brick or a sidewalk block; The moldings are loaded on a trolley and passed through a conventional tunnel-type continuous firing kiln equipped with a preheating zone, a baking zone, and a cooling zone to continuously preheat, fire, cool, and take out the metal oxides and colored oxides. It provides a black brick and sidewalk block manufacturing method.
상기 성형물의 조성원료중 산화철로 이루어진 금속산화물과, 이산화망간 및 산화크롬으로 이루어진 착색산화물은 상기 성형물이 터널식 연속소성가마의 소성대를 지나면서 소성될 때 산화, 환원 반응을 일으켜서 성형물로 하여금 본 발명이 의도하는 흑색 내지 재색계통의 색상을 지니도록 하여 주는 성분인 바, 이는 쇠가 1000℃이상의 고온에서 타게 되면 그 표면색상이 전돌의 색상과 유사한 재색내지 은색계통의 색상으로 나타나게 되는 것과 같은 원리이다.The metal oxide made of iron oxide and the colored oxide made of manganese dioxide and chromium oxide in the composition material of the molding cause oxidation and reduction reaction when the molding is fired while passing through the firing zone of the tunnel type continuous firing kiln. It is a component that has the color of the intended black to red color system, which is the same principle that when the iron is burned at a high temperature of more than 1000 ℃ the surface color is represented by the color of the recolor or silver system similar to the color of the projection.
이와 같은 본 발명의 방법은 전술한 이부식 소성방법에 의존한 기존의 제조방법에 비해 보다 균일한 색상의 제품을 얻어낼 수 있고 또 흡수율, 압축강도 등의 품질면에서도 우수한 제품을 제조해낼 수 있으면서도, 성형물이 종래와 같이 철가마내에 고정적치된 상태에서 장시간 침탄 소성되는 것이 아니라 도2에서 보는 바와 같이 대차(20)상에 실려 예열대(11)와 소성대(12), 냉각대(13)등이 구비된 터널식 연속소성가마(10)를 통해 연속 이동되면서 소성되어지기 때문에 그 생산능률이 종전과 비교되지 않을 정도로 높은 장점이 있으며, 또한 이에 따라 제품의 생산단가를 크게 낮출 수 있는 잇점도 있는 것이다.Such a method of the present invention can produce a product of more uniform color than the conventional manufacturing method based on the above-described two-corrosive baking method, and can also produce a product having excellent quality in terms of absorption rate, compressive strength, The molded product is not carburized for a long time in a state where it is fixedly placed in an iron kiln as in the prior art, and is loaded on the
이는 즉, 본 발명의 방법은 상기 금속산화물 및 착색산화물을 점토에 적합한 비율로 혼합조성하여 제품 원료를 마련하는 것에서 통상적인 점토 벽돌의 제조공정과 다를 뿐, 성형물을 대차(20)에 쌓아 터널식 연속소성가마(10)를 통해 연속적으로 예열, 소성, 냉각시켜 제품을 제조하도록 하는 나머지 공정들은 위 통상적인 점토 벽돌 제조공정과 동일한 것으로, 생산성 및 생산단가면에서 이부식 소성방식에 의한 종래 전통의 전돌 제조방법과 몇배의 차이가 나는 것이다.In other words, the method of the present invention differs from the conventional clay brick manufacturing process in that the metal oxide and the colored oxide are mixed in a ratio suitable for clay to prepare a product raw material. The remaining processes for continuously preheating, firing, and cooling the product through the
도3은 기존의 이부식 소성방식에 의한 전돌 제조공정을 블럭도로 나타낸 것이고, 도4는 본 발명의 방법에 의한 전돌 제조공정을 블럭도로 나타낸 것인 바, 상기 기존의 기술에 의한 전돌 제조와 본 발명의 기술에 의한 전돌 제조상의 차이점을 도표로 비교하여 보면 다음 <표1>과 같다.Figure 3 is a block diagram showing a conventional process for producing a projection according to a two-side corrosion firing method, Figure 4 is a block diagram showing a process for producing a projection according to the method of the present invention, the production of a projection by the existing technology and the present invention The following table compares the differences in stone manufacturing by the technology of Table 1.
<표1><Table 1>
따라서, 본 발명은 상술한 바와 같은 제조방법을 통해 이러한 흑색계통의 전통적인 전돌 제품을 종전보다 월등히 저렴한 가격 및 높은 생산효율로 대량생산해낼 수 있게 된 신규유용한 효과를 제공한 것이다.Therefore, the present invention provides a new useful effect that can be mass-produced such a traditional system of the black system through a manufacturing method as described above at a significantly lower price and higher production efficiency than before.
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