KR100540387B1 - Fuel dope for combustion promotion of liquid fuel and manufacturing process of the same - Google Patents

Fuel dope for combustion promotion of liquid fuel and manufacturing process of the same Download PDF

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KR100540387B1
KR100540387B1 KR1020030067564A KR20030067564A KR100540387B1 KR 100540387 B1 KR100540387 B1 KR 100540387B1 KR 1020030067564 A KR1020030067564 A KR 1020030067564A KR 20030067564 A KR20030067564 A KR 20030067564A KR 100540387 B1 KR100540387 B1 KR 100540387B1
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raw material
fuel
solvent
oil
aspartic acid
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KR20050031306A (en
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서만귀
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주식회사 이씨에스
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0407Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0415Light distillates, e.g. LPG, naphtha
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0407Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/043Kerosene, jet fuel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/26Composting, fermenting or anaerobic digestion fuel components or materials from which fuels are prepared

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

광합성 발효방법에 의하여 제조되며, 자동차 엔진 같은 내연기관, 보일러 등의 연소기관에 사용되는 원유, 중유, 등유, 경유, 휘발유 및 디이젤유 등의 액체연료에 소정의 비율로 첨가되어 연소효율을 현저하게 높여 연료를 절감시킬 수 있도록 하고, 배기가스중에 함유되는 대기오염물질양을 대폭 저감시킬 수 있도록 함은 물론, 배기가스의 배출온도를 낮춰 대기온도의 저하를 유발시킬 수 있도록 하며, 소음을 저감시키고, 벙커-C유에 첨가되는 경우 분진발생을 현저하게 억제시킬 수 있도록 한 액체연료 연소촉진용 연료첨가제 및 그 제조방법이 개시된다.Manufactured by photosynthetic fermentation method, it is added to liquid fuels such as crude oil, heavy oil, kerosene, light oil, gasoline and diesel oil in internal combustion engines such as automobile engines, combustion engines such as boilers, and the combustion efficiency is remarkably improved. To reduce fuel consumption, to significantly reduce the amount of air pollutants in exhaust gas, to lower the exhaust temperature of exhaust gas, to reduce the atmospheric temperature, to reduce noise, The present invention discloses a fuel additive for promoting the combustion of a liquid fuel and a method for producing the same, which are capable of significantly suppressing dust generation when added to bunker-C oil.

본 발명에 의한 연료첨가제는 감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합하여 광합성 발효시킨 원료액을 등유, 경유, 휘발유 등에서 선택된 하나의 용매와 1(원료액) : 250(용매)의 비율로 혼합된 것이다.The fuel additive according to the present invention is 8-12wt% persimmon leaf powder, 9-11wt% of sorghum wool powder, 1-3wt% ferrous chloride, 0.5-1.5wt% aspartic acid, 0.5-1.5wt% iodine, isopropyl alcohol 70- Photosynthesis fermented by mixing the mixture at 80wt% of a solvent selected from kerosene, diesel, gasoline, etc. and 1 (raw material): 250 (solvent).

본 발명에 따른 연료첨가제의 제조방법은 소정의 입자크기를 갖는 감나무잎사귀분말, 견운모분말, 염화제1철과 아스파라긴산, 요도, 이소프로필알코올을 준비하는 원료준비단계와; 소정의 용적을 갖는 용기에 상기 감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합된 원료혼합물을 투입하고 30-50℃의 온도를 유지하도록 가열 및 교반하면서 광원을 이용 9,000-12,000Lux의 조도로 40-60시간 동안 빛을 조사(照謝)하는 광합성 발효단계와; 상기 광합성 발효단계 를 거친 원료액중 찌꺼기는 버리고, 상등액만을 취하여 유리병에 담아 암실에서 일정 시간 정치(定置)시키는 단계와; 상기 원료액과 등유, 경유, 휘발유 중에서 선택된 어느 하나의 용매를 1 : 250의 비율로 혼합하는 단계와; 용매와 혼합된 원료액을 용기에 넣고, 상온에서 800-1,200Lux의 조도로 40-60시간 빛을 조사하면서 숙성시키는 숙성단계를 포함한다. The method for preparing a fuel additive according to the present invention includes preparing a raw material for preparing persimmon leaf powder, cultivars, ferrous chloride, aspartic acid, aspartic acid, urethra, and isopropyl alcohol; 8-12wt% of persimmon leaf powder, 9-11wt% of chorionic yam powder, 1-3wt% ferrous chloride, 0.5-1.5wt% aspartic acid, 0.5-1.5wt% iodine, and isopropyl alcohol 70 in a container having a predetermined volume. Photosynthesis by injecting the mixed raw material mixture at a ratio of -80wt% and irradiating light for 40-60 hours with 9,000-12,000Lux illuminance using a light source while heating and stirring to maintain a temperature of 30-50 ° C. Fermentation step; Discarding the residue in the raw material solution, which has undergone the photosynthetic fermentation step, taking only the supernatant and placing it in a glass bottle for a fixed time in a dark room; Mixing the raw material solution with any one solvent selected from kerosene, diesel oil and gasoline in a ratio of 1: 250; The raw material solution mixed with the solvent is put into a container, and the maturation step of aging while irradiating light for 40-60 hours at an ambient light of 800-1,200Lux at room temperature.

Description

액체연료 연소촉진용 연료첨가제 및 그 제조방법{FUEL DOPE FOR COMBUSTION PROMOTION OF LIQUID FUEL AND MANUFACTURING PROCESS OF THE SAME} FUEL DOPE FOR COMBUSTION PROMOTION OF LIQUID FUEL AND MANUFACTURING PROCESS OF THE SAME}

도 1은 본 발명에 따른 액체연료 연소촉진용 연료첨가제의 제조방법을 나타내는 플로우차트이다. 1 is a flowchart showing a method of manufacturing a fuel additive for promoting fuel combustion according to the present invention.

** 도면의 주요 부분에 대한 부호의 설명 **** Description of symbols for the main parts of the drawing **

ST1 :원료준비단계 ST2 :광합성 발효단계ST1: Raw material preparation stage ST2: Photosynthetic fermentation stage

ST3 : 정치(定置)단계 ST4 : 용매와 원료액의 혼합단계ST3: Fixed step ST4: Mixing step of solvent and raw material liquid

ST5 : 숙성단계. ST5: ripening step.

본 발명은 액체연료 연소촉진용 연료첨가제 및 그 제조방법에 관한 것으로, 보다 상세하게는 광합성 발효방법에 의하여 제조되며, 자동차 엔진 같은 내연기관, 보일러 등의 연소기관에 사용되는 원유, 중유, 등유, 경유, 휘발유 및 디이젤유 등의 액체연료에 소정의 비율로 첨가되어 연소효율을 현저하게 높여 연료를 절감시킬 수 있도록 하고, 배기가스중에 함유되는 대기오염물질양을 대폭 저감시킬 수 있도록 함은 물론, 배기가스의 배출온도를 낮춰 대기온도의 저하를 유발시킬 수 있도록 하며, 소음을 저감시키고, 벙커-C유에 첨가되는 경우 분진발생을 현저하게 억제시킬 수 있도록 한 액체연료 연소촉진용 연료첨가제 및 그 제조방법에 관한 것이다. The present invention relates to a fuel additive for promoting the combustion of liquid fuel and a method of manufacturing the same, and more particularly, to a crude oil, heavy oil, kerosene, manufactured by a photosynthetic fermentation method, used in a combustion engine such as an internal combustion engine such as an automobile engine, a boiler, It is added to liquid fuels such as diesel oil, gasoline and diesel oil at a predetermined ratio to significantly increase the combustion efficiency to save fuel, and significantly reduce the amount of air pollutants contained in the exhaust gas. Fuel additive for promoting fuel combustion and its manufacture to reduce exhaust temperature of exhaust gas, to reduce the atmospheric temperature, to reduce noise, and to significantly suppress dust generation when added to bunker-C oil. It is about a method.

종래, 연료첨가제는 사용목적에 따라 황산화물(SOx), 질소산화물(NOX) 등의 유해성분의 발생억제제, 슬러지 분산제, 에멀션파괴제, 부식방지제, 연료회류의 퇴적방지제, 연소촉진제, 매연방지제, 착화촉진제, 세탄가 향상제, 응고점 강하제 등으로서 알려져 있다.Conventionally, fuel additives include inhibitors for the generation of harmful components such as sulfur oxides (SOx) and nitrogen oxides (NO X ), sludge dispersants, emulsion breakers, corrosion inhibitors, fuel ash deposition inhibitors, combustion accelerators, and smoke inhibitors depending on the purpose of use. , Ignition accelerators, cetane number improvers, solidification point lowering agents and the like.

이들 연료첨가제의 형태는 무기금속, 금속산화물, 금속수산화물, 탄산염 등 미세분말을 계면활성제를 주성분으로 하는 분산제와 함께 물에 혼합하여 슬러리 (Slurry)상으로 한 것이다.In the form of these fuel additives, fine powders such as inorganic metals, metal oxides, metal hydroxides, and carbonates are mixed with water with a dispersant containing a surfactant as a main component to form a slurry.

그러나, 이와 같은 종래의 연료첨가제에서는 조성물로 포함되는 무기물이 보존중에 침전또는 분리되거나 혹은 연료유에 첨가하였을 때 배관부분이나 버어너 부분에서 침전하여 폐쇄시킨다든가 버어너 노즐부분을 마모시키는 경우가 있다.However, in such conventional fuel additives, the inorganic matter contained in the composition may be precipitated or separated during storage, or when added to the fuel oil, may be precipitated in the piping or burner section and closed, or the burner nozzle may be worn.

또한, 상기한 종래 연료첨가제의 경우 조성물중에 포함되는 무기물의 입경이 상대적으로 크며, 더구나 분산성이 불량하므로 연소화염이나 배기가스 등에 존재하는 유해물질과의 접촉효과가 불충분하여 첨가제로서의 충분한 효과를 기대할 수 없다는 문제가 있다.In addition, in the case of the conventional fuel additive, the particle size of the inorganic material included in the composition is relatively large, and furthermore, since the dispersibility is poor, the contact effect with the harmful substances present in the combustion flame or the exhaust gas is insufficient, so that sufficient effect as an additive can be expected. There is a problem that can not be.

또한, 종래로부터 유용성의 금속화합물을 석유계 용제 등에 용해한 연료첨가제도 알려져 있다.Moreover, the fuel additive which melt | dissolved oil-soluble metal compound in petroleum solvent etc. is known conventionally.

이들 연료첨가제는 연료유와 균일하게 혼합용해되기 때문에 안전성도 양호하 며, 연소가스 및 배기가스에 존재하는 유해성분과 접촉효율도 양호하지만 유용성 금속화합물중의 유효성분인 금속성분의 함유량이 적고 또한 값이 비싸다는 문제점이 있다.These fuel additives have good safety because they are mixed and dissolved uniformly with fuel oil, and have good contact efficiency with harmful components present in combustion gas and exhaust gas, but the content of metal components, which is an active ingredient in oil-soluble metal compounds, is also low and value. There is a problem of this expensive.

한편, 자동차의 엔진이나 기타 연소장치에 공급되는 연료를 완전연소시키기 위하여 공기를 많이 공급하면, 연소는 잘 이루어지지만 실화현상(불꽃이 튀는 현상)이 발생되기 때문에 배출가스의 온도가 높아진다.On the other hand, when a large amount of air is supplied to completely burn fuel supplied to an engine or other combustion apparatus of an automobile, combustion is performed well, but since the ignition phenomenon occurs, the temperature of the exhaust gas is increased.

한편, 배출가스의 온도를 낮추기 위하여 공기의 공급비를 줄이면 연소가 상대적으로 불완전하게 이루어짐에 따라 많은 양의 카본이 발생됨으로 부득이 공기비를 높일 수 밖에 없는 실정이다.On the other hand, if the air supply ratio is reduced in order to lower the temperature of the exhaust gas, as the combustion is relatively incomplete, a large amount of carbon is generated, which inevitably increases the air ratio.

그러나, 이와 같이 공기의 공급비를 높이게 되는 경우에 배출가스의 온도가 높아지기 때문에 대기의 온도가 높아진다는 문제가 있다.However, when the air supply ratio is increased in this way, there is a problem that the temperature of the exhaust gas is high because the temperature of the exhaust gas is high.

따라서, 단순한 공기 공급비의 조절만으로는 배출가스의 온도를 낮춤과 동시에 연소시 발생되는 카본의 양을 줄일 수 없다는 문제가 있다. Therefore, there is a problem that simply adjusting the air supply ratio can not reduce the temperature of the exhaust gas and at the same time reduce the amount of carbon generated during combustion.

본 발명은 이와 같은 문제점을 해결하기 위한 것으로, 그 목적은 광합성 발효방법에 의하여 제조되며, 자동차 엔진 같은 내연기관, 보일러 등의 연소기관에 사용되는 원유, 중유, 등유, 경유, 휘발유 및 디이젤유 등의 액체연료에 소정의 비율로 첨가되어 연소효율을 현저하게 높여 연료를 절감시킬 수 있도록 하고, 배기가스중에 함유되는 대기오염물질양을 대폭 저감시킬 수 있도록 함은 물론, 배기가스의 배출온도를 낮춰 대기온도의 저하를 유발시킬 수 있도록 하며, 소음을 저감시키 고, 벙커-C유에 첨가되는 경우 분진발생을 현저하게 억제시킬 수 있도록 한 새로운 액체연료 연소촉진용 연료첨가제를 제공하는 것이다.The present invention is to solve such a problem, the purpose of which is manufactured by the photosynthetic fermentation method, crude oil, heavy oil, kerosene, diesel, gasoline and diesel oil, etc. used in combustion engines such as internal combustion engines, boilers, etc. Is added to the liquid fuel at a predetermined ratio to significantly increase the combustion efficiency, thereby reducing fuel consumption, significantly reducing the amount of air pollutants contained in the exhaust gas, and lowering the exhaust temperature of the exhaust gas. It is to provide a new fuel additive for promoting the combustion of liquid fuel, which can cause a decrease in atmospheric temperature, reduce noise, and significantly suppress dust generation when added to bunker-C oil.

본 발명의 다른 목적은 자동차 엔진 같은 내연기관, 보일러 등의 연소기관에 사용되는 원유, 중유, 등유, 경유, 휘발유 및 디이젤유 등의 액체연료에 소정의 비율로 첨가되어 연소효율을 현저하게 높여 연료를 절감시킬 수 있도록 하고, 배기가스중에 함유되는 대기오염물질양을 대폭 저감시킬 수 있도록 함은 물론, 배기가스의 배출온도를 낮춰 대기온도의 저하를 유발시킬 수 있도록 하며, 소음을 저감시키고, 벙커-C유에 첨가되는 경우 분진발생을 현저하게 억제시킬 수 있도록 한 새로운 액체연료 연소촉진용 연료첨가제의 제조방법을 제공하는 것이다.Another object of the present invention is to add a predetermined ratio to liquid fuels such as crude oil, heavy oil, kerosene, diesel, gasoline and diesel oil used in combustion engines such as internal combustion engines, boilers, such as automobile engines to significantly increase the combustion efficiency fuel To reduce the amount of air pollutants contained in the exhaust gas, as well as lower the exhaust temperature of the exhaust gas, which can lead to a decrease in the atmospheric temperature, reduce noise, and bunker It is to provide a new method for producing fuel additives for promoting the combustion of liquid fuel that can significantly suppress dust generation when added to oil.

이와 같은 목적을 달성하기 위하여, 본 발명의 액체연료 연소촉진용 연료첨가제는 감나무잎사귀분말 8-12wt%, 견(백)운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산(Asparagine acid) 0.5-1.5wt%, 요드(Iodine) 0.5-1.5wt%, 이소프로필알코올{Iso-propyl alcohol :(CH3)2CHOH) 70-80wt%의 비율로 혼합하여 광합성 발효시킨 원료액을 등유, 경유, 휘발유 등에서 선택된 하나의 용매와 1(원료액) : 250(용매)의 비율로 혼합하여 된 특징을 갖는다. In order to achieve the above object, the fuel additive for promoting the combustion of the liquid fuel of the present invention is 8-12wt% persimmon leaf powder, 9-11wt% silk mica powder, 1-3wt% ferrous chloride, asparagine (Asparagine) acid) 0.5-1.5wt%, Iodine 0.5-1.5wt%, Iso-propyl alcohol (Iso-propyl alcohol: (CH 3 ) 2 CHOH) 70-80wt% of the mixture by mixing photosynthetic fermentation , Light oil, gasoline, etc., and a solvent selected from 1 (raw material): 250 (solvent) in a ratio of mixing.

상기 다른 목적을 달성하기 위하여, 본 발명의 액체연료 연소촉진용 연료첨가제의 제조방법은 소정의 입자크기를 갖는 감나무잎사귀분말, 견운모분말, 염화제1철과 아스파라긴산, 요도, 이소프로필알코올을 준비하는 원료준비단계와; 소정의 용적을 갖는 용기에 상기 감나무잎사귀분말 8-12wt%, 견(백)운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합된 원료혼합물을 투입하고 30-50℃의 온도를 유지하도록 가열 및 교반하면서 광원을 이용 9,000-12,000Lux의 조도로 40-60시간 동안 빛을 조사(照謝)하는 광합성 발효단계와; 상기 광합성 발효단계를 거친 원료액중 찌꺼기는 버리고, 상등액만을 취하여 유리병에 담아 암실에서 일정 시간 정치(定置)시키는 단계와; 상기 원료액과 등유, 경유, 휘발유 중에서 선택된 어느 하나의 용매를 1 : 250의 비율로 혼합하는 단계와; 용매와 혼합된 원료액을 용기에 넣고, 상온에서 800-1,200Lux의 조도로 40-60시간 빛을 조사하면서 숙성시키는 숙성단계를 포함한다.In order to achieve the above another object, the method for preparing a fuel additive for promoting the combustion of liquid fuel of the present invention is to prepare a persimmon leaf powder, cultivars, powder of ferrous chloride and ferrous chloride and aspartic acid, urethra, isopropyl alcohol having a predetermined particle size Raw material preparation step; 8-12wt% of persimmon leaf powder, 9-11wt% silk mica powder, 1-3wt% ferrous chloride, 0.5-1.5wt% aspartic acid, 0.5-1.5wt% iodine in a container having a predetermined volume, Isopropyl alcohol was mixed with 70-80wt% of the raw material mixture, and heated and stirred to maintain a temperature of 30-50 ° C. using a light source and irradiated with light of 9,000-12,000 Lux for 40-60 hours. Photosynthetic fermentation step; Discarding the residue in the raw material solution, which has undergone the photosynthetic fermentation step, taking only the supernatant and placing it in a glass bottle for a fixed time in a dark room; Mixing the raw material solution with any one solvent selected from kerosene, diesel oil and gasoline in a ratio of 1: 250; The raw material solution mixed with the solvent is put into a container, and the maturation step of aging while irradiating light for 40-60 hours at an ambient light of 800-1,200Lux at room temperature.

이하, 첨부된 도면에 의하여 본 발명의 바람직한 실시예를 보다 상세하게 설명한다.Hereinafter, with reference to the accompanying drawings will be described in detail a preferred embodiment of the present invention.

본 발명에 따른 액체연료 연소촉진용 연료첨가제는 감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합하여 광합성발효시킨 원료액을 등유, 경유, 휘발유 등에서 선택된 하나의 용매와 1(원료액) : 250(용매)의 비율로 혼합된다. Fuel additive for promoting the combustion of liquid fuel according to the present invention is 8-12wt% persimmon leaf powder, 9-11wt% of mica, powder of ferrous chloride 1-3wt%, 0.5-1.5wt% of aspartic acid, 0.5-1.5wt% of iodine, Photosynthetic fermentation is carried out by mixing 70-80 wt% of isopropyl alcohol with a solvent selected from kerosene, diesel, gasoline, etc. and 1 (raw material): 250 (solvent).

도 1은 본 발명에 따른 액체연료 연소촉진용 연료첨가제의 제조방법을 나타내는 플로우차트이다. 1 is a flowchart showing a method of manufacturing a fuel additive for promoting fuel combustion according to the present invention.

이를 참조하면, 본 발명의 연료첨가제 제조방법은 원료준비단계(ST1)와, 일 정비율로 혼합된 원료혼합물을 용기에 넣어 광합성발효시키는 광합성발효단계(ST2)와, 광합성발효된 원료액을 정치시키는 정치단계(ST3)와, 정치과정을 거친 원료액과 용매를 일정 비율로 혼합하는 용매와 원료액의 혼합단계(ST4) 및 용매와 원료액의 혼합액을 다시 숙성시키는 숙성단계(ST5)를 포함한다.Referring to this, the fuel additive manufacturing method of the present invention, the raw material preparation step (ST1), the photosynthetic fermentation step (ST2) to put the photosynthetic fermentation mixed in a container at a maintenance rate, and the photosynthetic fermented raw material liquid To a stationary step (ST3), a step of mixing the solvent and the raw material solution (ST4) for mixing the solvent and the raw material solution, and the ripening step (ST5) of remixing the mixed solution of the solvent and the raw material solution to a certain ratio do.

상기 원료준비단계(ST1)에서는 소정의 입자크기를 갖는 감나무잎사귀분말, 소정의 입자크기를 갖는 견운모분말, 소정의 입자크기를 갖는 염화제1철 및 과 아스파라긴산, 요도, 이소프로필알코올을 준비한다. In the raw material preparation step (ST1) to prepare persimmon leaf powder having a predetermined particle size, mica hair powder having a predetermined particle size, ferrous chloride and aspartic acid having a predetermined particle size, aspartic acid, urethra, isopropyl alcohol.

상기 광합성발효단계(ST2)에서는 소정의 용적을 갖는 용기에 상기 감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합된 원료혼합물을 투입하고 30-50℃의 온도를 유지하도록 가열 및 교반하면서 광원을 이용 10,000Lux의 조도로 40-60시간 동안 빛을 조사(照謝)한다.In the photosynthetic fermentation step (ST2), 8-12 wt% of persimmon leaf powder, 9-11 wt% of mica, powder of ferrous chloride 1-3wt%, aspartic acid 0.5-1.5wt%, and iodine 0.5- in a container having a predetermined volume. Inject the mixed raw material mixture at the ratio of 1.5wt% and isopropyl alcohol 70-80wt%, and irradiate the light for 40-60 hours with 10,000Lux illuminance by heating and stirring to maintain the temperature of 30-50 ℃. (照 謝)

상기 광합성 발효단계에서 감나무 잎사귀 분말에 빛이 조사되면, '분말엽에서도 광합성이 일어난다'는 몰리쉬-힐반응에 의하여 감나무잎사귀 분말로부터 산소가 방출되어 원료액 내부에 용존된다. When light is irradiated on the persimmon leaf powder in the photosynthetic fermentation step, oxygen is released from the persimmon leaf powder by the Molish-Hill reaction that 'the photosynthesis occurs in the powder leaf' and is dissolved in the raw material solution.

상기 정치단계(ST3)에서는 광합성 발효단계(ST2)를 거친 원료액중 찌꺼기는 버리고, 상등액만을 취하여 유리병에 담아 암실에서 일정 시간 정치(定置)시킨다.In the stationary step ST3, the residue in the raw material solution that has undergone the photosynthetic fermentation step ST2 is discarded, and only the supernatant is taken and placed in a glass bottle for a fixed time in the dark room.

상기 용매와 원료액의 혼합단계(ST4)에서는 상기 원료액과 등유, 경유, 휘발유 중에서 선택된 어느 하나의 용매를 1(원료액) : 250(용매)의 비율로 혼합한다.In the mixing step (ST4) of the solvent and the raw material liquid, any one solvent selected from the raw material liquid, kerosene, diesel oil, and gasoline is mixed at a ratio of 1 (raw material liquid): 250 (solvent).

상기 숙성단계(ST5)에서는 용매와 혼합된 원료액을 용기에 넣고, 상온에서 1,000Lux의 조도로 40-60시간 빛을 조사하여 숙성시킨다.In the aging step (ST5), the raw material mixed with the solvent is put into a container, and aged at room temperature by irradiation with light of 1,000Lux for 40 to 60 hours.

이와 같이 제조된 본 발명의 연료첨가제는 자동차의 엔진 같은 내연기관이나 보일러 등의 연소장치에 사용되는 액체연료, 예로서 휘발유, 디이젤유 또는 벙커C유에 일정한 비율로 첨가되어 사용되는데, 대략 500(액체연료) : 1(연료첨가제)의 비율로 첨가되어 사용된다.The fuel additive of the present invention prepared as described above is added to a liquid fuel, such as gasoline, diesel oil, or bunker C oil, which is used in a combustion apparatus such as an internal combustion engine such as an engine of an automobile or a boiler, and is used at a constant rate, and is approximately 500 (liquid Fuel): It is added in the ratio of 1 (fuel additive) and used.

예로서, 보일러의 연료로 사용되는 중질유는 C, H, S, O2, H2O, + 회분(V, Na, Si, Pb, Mg 등)과 잔류탄소분으로 구성되어 있는 바, 연소의 특성상 위의 구성요소가 연소할 때면 열과 CO, CO2, NOx, SOx, H2O 및 분진이 생성되어 대기오염에 큰 영향을 미치게 되며, 특히 회분 등이 연관에 흡착되어 보일러의 수명을 단축시키키고 열효율을 상당부분 감소시키게 된다.For example, heavy oil used as fuel for a boiler is composed of C, H, S, O 2 , H 2 O, + ash (V, Na, Si, Pb, Mg, etc.) and residual carbon content. When the above components burn, heat and CO, CO 2 , NO x, SO x , H 2 O and dust are generated, which greatly affects the air pollution. Especially ash is adsorbed to the furnace to shorten boiler life. And considerably reduce thermal efficiency.

이와 같은 중질유에 본 발명에 따른 연료첨가제를 소정의 비율{1(첨가제) : 500(중질유)}로 첨가하여 연소시키는 경우에 회분과 잔류탄소분 50-90%이상을 가연성 물질로 전환시켜 저부하 운전과 저과잉 공기 운전이 가능하게 된다.When the fuel additive according to the present invention is added to such heavy oil at a predetermined ratio {1 (additive): 500 (heavy oil)}, the ash and the residual carbon content are converted into a combustible material at low load operation. Excessive excess air operation is possible.

따라서, NOx, SOx 분진 등이 효과적으로 감소되며, 보일러 전열면을 항상 청결하게 유지시켜주므로 열전도율이 현저히 상승된다. Therefore, NO x , SO x dust, etc. are effectively reduced, and the thermal conductivity is significantly increased since the boiler heat transfer surface is always kept clean.

이와 같이 상기 연료첨가제가 액체연료에 첨가되어 사용되는 경우 외부로부터 공급되는 공기량을 조절하지 않아도 광합성 발효작용에 따라 방출되어 첨가제 내에 용존하는 산소에 의하여 연소의 촉진이 이루어짐에 따라 연료가 절감되는 것은 물론, 배기가스의 배출온도가 평균 2-3℃정도 낮춰진다.As such, when the fuel additive is used in addition to the liquid fuel, fuel is saved as the fuel is promoted by the oxygen dissolved in the additive which is released by photosynthetic fermentation without adjusting the amount of air supplied from the outside. In this case, the exhaust temperature of the exhaust gas is lowered by an average of 2-3 ℃.

또한, 소음이 저감되며, 벙커-C유에 첨가되는 경우 분진발생이 70%이상 저감된다.In addition, noise is reduced, and when added to bunker-C oil, dust generation is reduced by more than 70%.

실시예1Example 1

본 발명에 따른 액체연료 연소촉진용 연료첨가제를 실제 승용차의 연료에 첨가하여 주행하고 연소후 배출되는 유해물질 및 배출가스 검사를 하고, 그 결과를 각각 표1과 표2에 나타내었다.The liquid fuel combustion promoting fuel additive according to the present invention was added to the fuel of an actual passenger vehicle and tested for harmful substances and exhaust gases discharged after combustion, and the results are shown in Table 1 and Table 2, respectively.

측정물질Measured substance AlAl FeFe NiNi CdCD MnMn CuCu ZnZn CrCr PbPb PP 첨가후 농도 ㎎/ℓConcentration ㎎ / ℓ after addition 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected 불검출 Not detected

표1 본 발명에 따른 연료첨가제의 유해물질검사 결과Table 1 Results of hazardous substance test of fuel additive according to the present invention

시험항목Test Items 배출가스농도(CVS-75)Exhaust Gas Concentration (CVS-75) 매연smoke CO(g/Km)CO (g / Km) HC(g/Km)HC (g / Km) NOx(g/Km)NO x (g / Km) PM(g/Km)PM (g / Km) (%)(%) 첨가전Before addition 0.330.33 0.050.05 0.130.13 -- -- 첨가후After addition 0.220.22 0.030.03 0.120.12 -- -- 증.감 %increase % 33.3 ↓33.3 ↓ 40.0 ↓40.0 ↓ 7.7 ↓7.7 ↓ -- --

표2 본 발명에 따른 연료첨가제의 배출가스검사 결과Table 2 Exhaust gas test results of fuel additives according to the present invention

상기한 배출가스 검사에 적용된 차량의 차종은 아반테 XD(2001년도 생산) 이었으며, 시험전 누적주행거리는 6365Km, 시험 후 누적주행거리는 6828Km이었다.The vehicle model used for the exhaust gas inspection was Avante XD (produced in 2001), and the cumulative driving distance before the test was 6365 km, and the cumulative driving distance after the test was 6828 km.

상기 시험차종의 연료에 첨가된 본 발명에 따른 연료첨가제의 양은 2.0㎖/ℓ(연료)이었다. The amount of the fuel additive according to the present invention added to the fuel of the test vehicle was 2.0 ml / l (fuel).

실시예2Example 2

본 발명에 따른 연료첨가제를 벙커-C유에 첨가하여 사용한 다음, 본 발명에 따른 연료첨가제의 첨가 전과 첨가 후의 인화점, 잔류탄소분, 회분, 황분 및 발열량을 비교 측정하고 그 결과를 표 3에 나타내었다. After the fuel additive according to the present invention was added to the bunker-C oil and used, the flash point, residual carbon content, ash, sulfur content and calorific value before and after the addition of the fuel additive according to the present invention were measured and the results are shown in Table 3.

시험항목Test Items 시험치Test value 시험방법Test Methods 벙커-C유Bunker-C 벙커-C유 + 연료첨가제Bunker-C oil + fuel additive 인화점(C.O.C) (℃)Flash point (C.O.C) (° C) 204204 192192 KS M 2010 ('99.12.29 개정)KS M 2010 (Revised '99 .12.29) 잔류탄소분 (무게%)Residual Carbon (Weight%) 4.844.84 4.824.82 KS M 2017 ('01.11.27 개정)KS M 2017 ('01 .11.27 revised) 회분(무게%)Ash content (% by weight) 0.2790.279 0.2780.278 KS M 2044 ('00.12.30 개정)KS M 2044 (Revised '00 .12.30) 황분(무게%)Sulfur (weight%) 0.470.47 0.460.46 KS M 2027 ('98.06.08 개정)KS M 2027 (revised '98 .06.08) 발열량 (cal/g),{MJ/Kg}Calorific value (cal / g), {MJ / Kg} 10,750 {45.00}10,750 {45.00} 10,780 {45.12}10,780 {45.12} KS M 2057 ('97.12.31 개정)KS M 2057 (Revised '97 .12.31)

표3 본 발명에 따른 연료첨가제를 벙커-C유에 적용한 시험결과 Table 3 Test results of applying the fuel additive according to the present invention to bunker-C oil

상기 표3에서 알 수 있는 바와 같이 본 발명에 따른 연료첨가제가 벙커-C유에 적용된 경우 그렇지 않은 벙커-C유에 비하여 인화점이 낮고, 잔류탄소분, 회분 및 황분의 양이 감소됨을 알 수 있다. As can be seen in Table 3, when the fuel additive according to the present invention is applied to the bunker-C oil, the flash point is lower than that of the bunker-C oil, and the amount of residual carbon, ash and sulfur is reduced.

이와 같은 본 발명을 적용하면, 광합성 발효작용에 의하여 첨가제내에 일정양의 산소가 용존되어 있기 때문에 별도로 공기의 공급비를 높이지 않더라도 연소효율이 향상됨으로 연료를 절감할 수 있으며, 배기가스의 배출온도를 낮춰 대기온도가 저하되는 효과를 얻을 수 있다.Applying the present invention, because a certain amount of oxygen is dissolved in the additive by the photosynthetic fermentation action, even if the supply ratio of air is not increased, the combustion efficiency is improved, and the fuel can be saved, and the exhaust temperature of the exhaust gas. By lowering the effect of lowering the atmospheric temperature can be obtained.

또, 연료의 연소효율이 높아지면서 배기가스중에 함유되는 대기오염물질양이 대폭 저감되며, 소음이 줄어들고, 벙커-C유에 첨가되는 경우 분진발생이 현저하게 억제된다.In addition, as the combustion efficiency of the fuel increases, the amount of air pollutants contained in the exhaust gas is greatly reduced, noise is reduced, and dust generation is significantly suppressed when added to the bunker-C oil.

Claims (2)

감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합하여 광합성 발효시킨 원료액을 등유, 경유, 휘발유 등에서 선택된 하나의 용매와 1(원료액) : 250(용매)의 비율로 혼합된 것을 특징으로 하는 액체연료 연소촉진용 연료첨가제. Persimmon leaf powder 8-12wt%, Cicada root powder 9-11wt%, Ferrous chloride 1-3wt%, Aspartic acid 0.5-1.5wt%, Iodine 0.5-1.5wt%, Isopropyl alcohol 70-80wt% A fuel additive for promoting fuel combustion of liquid fuel, characterized in that the photosynthetic fermented raw material liquid is mixed with one solvent selected from kerosene, diesel oil, gasoline, etc. at a ratio of 1 (raw material liquid): 250 (solvent). 소정의 입자크기를 갖는 감나무잎사귀분말, 견운모분말, 염화제1철과 아스파라긴산, 요도, 이소프로필알코올을 준비하는 원료준비단계와; A raw material preparation step of preparing persimmon leaf powder, sorghum bran powder, ferrous chloride and aspartic acid, urethra, and isopropyl alcohol having a predetermined particle size; 소정의 용적을 갖는 용기에 상기 감나무잎사귀분말 8-12wt%, 견운모분말 9-11wt%, 염화제1철 1-3wt%, 아스파라긴산 0.5-1.5wt%, 요드 0.5-1.5wt%, 이소프로필알코올 70-80wt%의 비율로 혼합된 원료혼합물을 투입하고 30-50℃의 온도를 유지하도록 가열 및 교반하면서 광원을 이용 9,000-12,000Lux의 조도로 40-60시간 동안 빛을 조사(照謝)하는 광합성 발효단계와; 8-12 wt% of persimmon leaf powder, 9-11 wt% of chorionic yam powder, 1-3 wt% ferrous chloride, 0.5-1.5 wt% aspartic acid, 0.5-1.5 wt% iodine, and isopropyl alcohol 70 in a container having a predetermined volume. Photosynthesis by injecting the mixed raw material mixture at a ratio of -80wt% and irradiating light for 40-60 hours with 9,000-12,000Lux illuminance using a light source while heating and stirring to maintain a temperature of 30-50 ° C. Fermentation step; 상기 광합성 발효단계를 거친 원료액중 찌꺼기는 버리고, 상등액만을 취하여 유리병에 담아 암실에서 일정 시간 정치(定置)시키는 단계와; Discarding the residue in the raw material solution, which has undergone the photosynthetic fermentation step, taking only the supernatant and placing it in a glass bottle for a fixed time in a dark room; 상기 원료액과 등유, 경유, 휘발유 중에서 선택된 어느 하나의 용매를 1(원료액) : 250(용매)의 비율로 혼합하는 단계와; Mixing the raw material liquid with any one solvent selected from kerosene, diesel oil, and gasoline at a ratio of 1 (raw material liquid): 250 (solvent); 용매와 혼합된 원료액을 용기에 넣고, 상온에서 800-1,200Lux의 조도로 40- 60시간 빛을 조사하면서 숙성시키는 숙성단계를 포함하는 것을 특징으로 하는 액체연료 연소촉진용 연료첨가제의 제조방법.A method of producing a fuel additive for promoting fuel combustion, comprising the step of putting a raw material solution mixed with a solvent into a container and aging while irradiating with light at a temperature of 800-1,200 Lux at 40-60 hours at room temperature.
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