KR100536460B1 - The manufacturing method of sinter using zirconia - Google Patents

The manufacturing method of sinter using zirconia Download PDF

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KR100536460B1
KR100536460B1 KR10-2002-0078931A KR20020078931A KR100536460B1 KR 100536460 B1 KR100536460 B1 KR 100536460B1 KR 20020078931 A KR20020078931 A KR 20020078931A KR 100536460 B1 KR100536460 B1 KR 100536460B1
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sintered body
kneaded
zirconia
sintered
thin film
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KR20040051092A (en
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이호진
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N2/00—Magnetotherapy
    • A61N2/06—Magnetotherapy using magnetic fields produced by permanent magnets
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38—Fibrous materials; Whiskers
    • C04B14/46—Rock wool ; Ceramic or silicate fibres
    • C04B14/4637—Zirconia or zircon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/56—Using constraining layers before or during sintering
    • C04B2237/565—Using constraining layers before or during sintering made of refractory metal oxides, e.g. zirconia

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Radiology & Medical Imaging (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Magnetic Treatment Devices (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

본 발명은 파스, 의료기기 등에 사용되는 지르코니아에 페라이트를 투입하여 혼련하고, 소결조제를 첨가하여 소결한 후, 착자하고 이온프레이팅법으로 티타늄이온박막이 형성되게 함으로써, 소결체를 파스, 의료기기 등에 이용하면 전자가 환부의 표피로 이동하여 피부 전위를 정상적으로 변화시켜 통증을 제거해 줄 수 있을 뿐만 아니라 혈액순환이 원활히 될 수 있으며, 영구자석에너지를 이용할 수 있게 되어 경직된 근육을 이완시킬 수 있도록 한 것으로, 지르코니아에 페라이트를 투입하여 1차 혼련하는 단계(S1)와; 1차 혼련된 혼련물에 탄화규소를 2차 혼련하는 단계(S2)와, 2차 혼련된 혼련물에 소결조제를 투입하는 단계(S3)와; 소결조제가 투입된 혼련물을 가압하여 성형하는 단계(S4)와; 성형된 성형물을 진공소성로에서 소결하는 단계(S5)와; 소결된 소결체를 연마하는 단계(S6)와; 연마된 소결체를 가우스 착자기에 투입하고 착자하는 단계(S7)와; 착자된 소결체를 이온프레이팅법으로 티타늄이온박막 증착하는 단계(S8)와, 티타늄이온박막 증착된 소결체의 중앙에 일정크기의 관통홈을 형성시키고, 형성된 관통홈에 영구자석을 설치하는 단계(S9) 포함하는 것을 특징으로 하는 지르코니아를 이용한 소결체의 제조방법이다.In the present invention, ferrite is mixed into zirconia used for pars, medical devices, and the like, kneaded, and sintered with the addition of a sintering aid, and then magnetized and a titanium ion thin film is formed by an ion frying method. When used, the electrons move to the epidermis of the affected area to change the skin potential normally to remove the pain as well as to facilitate blood circulation, and to use the permanent magnet energy to relax the rigid muscles. Injecting ferrite into the zirconia to knead first (S1); Secondly kneading silicon carbide into the first kneaded kneaded product (S2), and adding a sintering aid to the second kneaded kneaded product (S3); Pressing and kneading the kneaded product into which the sintering aid is added (S4); Sintering the molded article in a vacuum firing furnace (S5); Polishing the sintered sintered body (S6); Injecting the polished sintered compact into a Gaussian magnetizer and magnetizing it (S7); Step of depositing a titanium ion thin film of the magnetized sintered body by the ion plating method (S8), and forming a through hole of a predetermined size in the center of the titanium ion thin film deposited sintered body, and installing a permanent magnet in the formed through groove (S9) ) Is a method for producing a sintered body using zirconia.

Description

지르코니아를 이용한 소결체의 제조방법{ The manufacturing method of sinter using zirconia}Manufacturing method of sintered body using zirconia {The manufacturing method of sinter using zirconia}

본 발명은 파스, 의료기기 등에 사용되는 지르코니아를 이용한 소결체의 제조방법에 관한 것으로, 더욱 상세하게는 지르코니아에 페라이트를 투입하여 혼련하고, 소결조제를 첨가하여 소결한 후, 착자하고 이온프레이팅법으로 티타늄이온박막이 형성되게 함으로써, 소결체를 파스, 의료기기 등에 이용하면 전자가 환부의 표피로 이동하여 피부 전위를 정상적으로 변화시켜 통증을 제거해 줄 수 있을 뿐만 아니라 혈액순환이 원활히 될 수 있으며, 영구자석에너지를 이용할 수 있게 되어 경직된 근육을 이완시킬 수 있도록 한 것이다.The present invention relates to a method for producing a sintered body using zirconia used in pars, medical devices, etc. More specifically, ferrite is mixed with zirconia and kneaded, sintered by adding a sintering aid, and then magnetized and ion-flected. By forming the titanium ion thin film, if the sintered body is used for the pars, medical equipment, etc., the electrons move to the epidermis of the affected area to change the skin potential and remove the pain as well as smooth the blood circulation and permanent magnet energy. Will be available to relax the stiff muscles.

일반적으로 인체에는 30∼50mV의 전류가 흐르고 있는데 이것을 생체전류라고 하고, 심장에서 발생하는 생체전류를 이용하여 심전도를 그려냄으로써 심장병을 진단하며 뇌에서 발생하는 전류를 이용해서 뇌파검사의 진단을 받을 수 있는 등 인체의 전류와 전압을 이용하여 건강을 측정할 수 있는 것으로, 인체의 전류와 전압이 불균형이 되면 이것이 통증으로 나타나게 되고 건강을 해치게 되는 것이다.In general, 30 ~ 50mV current flows through the human body, which is called biocurrent, and it is possible to diagnose heart disease by drawing an electrocardiogram using the biocurrent generated in the heart and to diagnose EEG using the current generated in the brain. You can measure your health using the human body's current and voltage. If the human body's current and voltage are imbalanced, this will appear as pain and harm your health.

인체는 통증이 없는 정상적인 경우 세포의 이온 균형이 정상적으로 작용하여 세포 외액의 나트륨플러스이온(Na+)은 세포 내액의 약 10배의 농도를 보전하고 있고, 이것을 전기적으로 보면 피부의 진피는 세포 외액의 나트륨플러스이온으로 되어 20∼30mV의 전위를 띄고 있는 것이다.Normally, the human body has no pain, and the cell's ionic balance works normally, so sodium plus ion (Na + ) in the extracellular fluid holds about 10 times the concentration of the intracellular fluid. Sodium plus ions have a potential of 20 to 30mV.

즉, 어깨나 어깨에서 팔까지의 부분이 아프고 저린 신경통인 견비통의 경우와 같은 통증은 전위적으로 보면 세포막 전위의 변화가 생겨서 세포막의 균형이 깨지게 되어 세포 내에 나트륨 이온이 유입되면 일시적으로 전위가 역전되는 현상이 일어나게 되고, 이것은 다시 나트륨의 작용으로 바깥으로 나가게 되는데, 이것이 반복되면 진피의 전위는 (+) (-) (+) (-)로 변화하여 통증으로 뇌에 전달되어 지는 것이다.In other words, pain, such as in the case of shoulder pain or scab pain, which is a painful and painful neuralgia, causes a change in cell membrane potential, resulting in a breakdown of the cell membrane, and a temporary inversion of sodium ions in the cell. This happens again, which is the outward action of sodium again, when repeated, the translocation of the dermis changes to (+) (-) (+) (-) and is transmitted to the brain as pain.

이러한 상태에서 세라믹 소결체를 이용하면 진피의 전위가 표피 및 세라믹 소결체의 부분에 대전현상을 일으키게 되어, 표피는 진피이 반대로 되고 세라믹 소결체는 표피의 반대가 되어 결국 진피와 동일한 전위를 띄게 되는 것이다.In such a state, when the ceramic sintered body is used, the dislocation of the dermis causes charging to the epidermis and the portion of the ceramic sintered body, the epidermis is reversed to the dermis, and the ceramic sintered body is reversed to the epidermis and eventually has the same potential as the dermis.

그러나 이러한 작용을 위해 안출된 국내 공개특허공보 제1999-30385호는 '파스조성물'에 관한 것으로, 금속티타늄과 규소를 주원료로 한 소결체에 금을 코팅함으로써 통증을 완화시킴과 동시에 1∼2년간 재사용이 가능하도록 하였으나, 금속티타늄과 규소의 혼합 및 소결만으로는 전자를 충분히 방출하지 못하는 문제점이 있었다.However, Korean Patent Publication No. 1999-30385, which was devised for such a function, relates to a `` parse composition, '' which relieves pain by coating gold on a sintered body composed mainly of metal titanium and silicon, and reuses it for one to two years. Although this was possible, there was a problem in that electrons were not sufficiently emitted only by mixing and sintering of metal titanium and silicon.

따라서 본 발명의 목적은 인체의 전위변화에 그다지 도움을 줄 수 없었던 종래의 세라믹 소결체가 지닌 제반 문제점을 해결하기 위하여, 지르코니아에 페라이트를 투입하여 혼련하고, 소결조제를 첨가하여 소결한 후, 착자하고 이온프레이팅법으로 티타늄이온박막이 형성되게 함으로써, 소결체를 파스, 의료기기 등에 이용하면 전자가 환부의 표피로 이동하여 피부 전위를 정상적으로 변화시켜 통증을 제거해 줄 수 있을 뿐만 아니라 혈액순환이 원활히 될 수 있으며, 영구자석에너지를 이용할 수 있게 되어 경직된 근육을 이완시킬 수 있도록 한 지르코니아를 이용한 소결체의 제조방법을 제공함에 있다.Accordingly, an object of the present invention is to inject and kneaded by adding ferrite to zirconia, and to sinter after adding a sintering aid, in order to solve the problems of the conventional ceramic sintered body that could not help much to change the potential of the human body By forming the titanium ion thin film by ion plating method, if the sintered body is used for the pars, medical equipment, etc., the electrons move to the epidermis of the affected area to change the skin potential and remove the pain as well as smooth the blood circulation. The present invention also provides a method of manufacturing a sintered body using zirconia, which can use permanent magnet energy to relax rigid muscles.

상기한 목적을 달성하기 위하여 본 발명에 의한 지르코니아를 이용한 소결체의 제조방법은, 지르코니아 65∼75중량％에 페라이트 25∼35중량％를 투입하여 1차 혼련하는 단계(S1)와; 1차 혼련된 혼련물 75∼80중량％에 탄화규소 20∼25중량％를 2차 혼련하는 단계(S2)와, 2차 혼련된 혼련물 85∼97중량％에 소결조제 3∼15중량％를 투입하는 단계(S3)와; 소결조제가 투입된 혼련물을 금형에 투입하고 가압하여 일정형태로 성형하는 단계(S4)와; 성형된 성형물을 1800∼2100℃의 진공소성로에서 소결하는 단계(S5)와; 소결된 소결체를 연마하는 단계(S6)와; 연마된 소결체를 가우스 착자기에 투입하고 100∼5000가우스의 범위로 착자하는 단계(S7)와; 착자된 소결체를 이온프레이팅법으로 티타늄이온박막 증착하는 단계(S8)와, 티타늄이온박막 증착된 소결체의 중앙에 일정크기의 관통홈을 형성시키고, 형성된 관통홈에 영구자석을 설치하는 단계(S9)를 포함하는 것을 특징으로 한다.In order to achieve the above object, the method for producing a sintered body using zirconia according to the present invention comprises the steps of first kneading by adding 25 to 35% by weight of ferrite to 65 to 75% by weight of zirconia (S1); Secondly kneading 20-25 wt% of silicon carbide to 75-80 wt% of the first kneaded kneaded product, and 3-15 wt% of a sintering aid to 85-97 wt% of the second kneaded kneaded material Putting step (S3); Inserting the kneaded product into which the sintering aid is added, and pressing the mold to form a predetermined shape (S4); Sintering the molded article in a vacuum firing furnace at 1800 to 2100 ° C. (S5); Polishing the sintered sintered body (S6); Putting the polished sintered compact into a Gaussian magnetizer and magnetizing it in a range of 100 to 5000 gauss (S7); Step of depositing a titanium ion thin film of the magnetized sintered body by the ion plating method (S8), and forming a through hole of a predetermined size in the center of the titanium ion thin film deposited sintered body, and installing a permanent magnet in the formed through groove (S9) It characterized by including).

이하 본 발명이 속하는 기술분야에서 통상의 지식을 가진자가 본 발명을 용이하게 실시할 수 있을 정도로 본 발명의 바람직한 실시예를 첨부된 도면을 참조하여 상세하게 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings such that those skilled in the art can easily implement the present invention.

도 1은 본 발명에 의한 지르코니아를 이용한 소결체의 제조공정도로서, 1차 혼련(S1), 2차 혼련(S2) 소결조제 투입(S3), 성형(S4), 소결(S5), 연마(S6), 착자(S7), 티타늄이온박막 증착단계(S8) 및 관통홈 형성, 연구자석 설치단계(S8)로 된다.1 is a manufacturing process chart of the sintered body using the zirconia according to the present invention, primary kneading (S1), secondary kneading (S2) sintering aid input (S3), molding (S4), sintering (S5), polishing (S6), Magnetization (S7), titanium ion thin film deposition step (S8) and through groove formation, the research magnet installation step (S8).

먼저, 지르코니아에 페라이트를 투입하여 1차 혼련하되(S1), 지르코니아의 배합비가 65중량％ 미만이면 피부 전위의 변화가 어려우며, 75중량％를 초과하면 과량이 되어 경제적이지 못하므로 65∼75중량％에 페라이트 25∼35중량％를 혼련시킨다.First, ferrite is added to zirconia and kneaded first (S1), but if the blending ratio of zirconia is less than 65% by weight, it is difficult to change the skin potential, and if it exceeds 75% by weight, it is excessive and not economical, so it is 65 to 75% by weight. 25 to 35% by weight of ferrite is kneaded.

상기 지르코니아(ZrO2)는 분자량 123.22, 녹는점 약 2,700℃로, 굴절률이 크고 녹는점이 높아서 내식성이 우수하기 때문에, 고온반도체, 고온구조재료, 반도체용부재 등으로의 응용이 가능한 재료로서, 반도체적 성질을 지닌 지르코니아로 인하여 티타늄이온박막의 전기적 특성을 더욱 효과적으로 발휘할 수 있도록 하는 것이고, 페라이트(Ferrite)는 900℃ 이하에서 안정한 체심입방결정(體心立方結晶)의 철에 합금원소 또는 불순물이 녹아서 된 고용체로서 지르코니아의 작용을 돕는 것이다.1차 혼련(S1) 후, 1차 혼련물 75∼80중량％에 탄화규소(SiC) 20∼25중량％를 2차 혼련(S2)하면, 탄화규소가 갖는 우수한 내열성, 내식성, 내산화성, 내열충격성 등으로 인해 고온반도체로서의 응용이 가능하여 지르코니아의 작용을 도울 수 있게 된다.The zirconia (ZrO 2 ) has a molecular weight of 123.22 and a melting point of about 2,700 ° C., and has a high refractive index and a high melting point, which is excellent in corrosion resistance, and thus is a material capable of being applied to high temperature semiconductors, high temperature structural materials, semiconductor members, and the like. Due to its zirconia, ferrite is an alloy element or impurity dissolved in iron of stable body-centered cubic crystal below 900 ℃. The function of zirconia as a solid solution is aided. After primary kneading (S1), when secondary kneading (S2) of 20 to 25% by weight of silicon carbide (SiC) is performed on 75 to 80% by weight of the first kneaded material, the silicon carbide has Excellent heat resistance, corrosion resistance, oxidation resistance, thermal shock resistance, etc. can be applied as a high-temperature semiconductor to help the action of zirconia.

2차 혼련된 혼련물에 일정량의 소결조제를 투입(S3)하여 혼련물의 소결성을 증가시키되, 소결조제의 투입량이 3중량％미만이면 액상량이 불충분하여 치밀한 소결체의 생성이 어렵고 15중량％를 초과하면 더 이상 소결성이 크게 증가하지 않으므로 과량이 되어 비경제적이므로, 혼련된 혼련물 85∼97중량％에 소결조제 3∼15중량％를 투입하도록 하며, 소결조제로는 산화알루미늄(Al2O3), 산화이투륨(Y2O3), 브롬(B), 카본(C) 중 어느 한 종을 선택하여 사용한다.When a certain amount of sintering aid is added to the second kneaded kneaded product (S3) to increase the sinterability of the kneaded product, but when the amount of the sintering aid is less than 3% by weight, the amount of liquid phase is insufficient to form a dense sintered compact and exceeds 15% by weight. Since the sinterability does not increase significantly any more, it is excessive and uneconomical, so that 3 to 15% by weight of the sintering aid is added to 85 to 97% by weight of the kneaded kneaded product, and aluminum oxide (Al 2 O 3 ), One of yttrium oxide (Y 2 O 3 ), bromine (B), and carbon (C) is selected and used.

소결조제가 투입된 혼련물을 금형에 투입하고 가압하여 일정형태로 성형(S4)하고, 성형된 성형물을 진공소성로에서 소결(S5)한다.The kneaded product into which the sintering aid is added is put into a mold and pressurized to be molded (S4) in a predetermined shape, and the molded product is sintered in a vacuum firing furnace (S5).

상기 성형방법이나 소결방법은 통상의 방법을 사용하는 것으로, 그 형태나 방법을 제한하는 것은 아니나, 소결온도가 1800℃ 미만이면 소결조제가 액상으로 형성되지 않아 소결이 진행되기 어려우며, 2100℃를 초과하면 경제성이 좋지 못하므로 1800∼2100℃의 진공소성로에서 소결하도록 한다.The molding method or the sintering method is to use a conventional method, and the form or method is not limited, but if the sintering temperature is less than 1800 ℃ sintering aid is not formed in the liquid phase, it is difficult to proceed sintering, exceeding 2100 ℃ If it is not economical, it is sintered in a vacuum firing furnace at 1800 ~ 2100 ℃.

소결 후, 소결된 소결체를 연마(S6)하여 소결체의 표면에 생성된 미세한 기공을 제거하도록 하고, 연마된 소결체를 가우스착자기에 투입하고 100∼5000가우스의 범위로 착자(S7)하면 순간 대전류를 방전함으로써 자장을 발생시키게 되어 영구자석의 성질을 갖게 되는 것이다.After sintering, the sintered sintered body is polished (S6) to remove the fine pores generated on the surface of the sintered body, and the polished sintered body is put into a Gaussian magnetizer and magnetized (S7) in the range of 100 to 5000 gauss. By discharging, the magnetic field is generated to have the properties of permanent magnets.

이 때 가우스착자기가 100가우스 미만이면 순간적으로 방전되는 전류의 양이 부족하여 영구자석의 성질을 획득하지 못하므로 착자된 소결체를 이온프레이팅법으로 티타늄이온박막 증착(S8)하여 소결체에 티타늄박막을 형성하도록 하며, 티타늄이온은 인체 통증부위의 정체된 전위를 다시 활성화 및 정상화시켜 세포의 기능을 정상화함으로써 염증 및 통증을 해소시키고, 노폐물을제거하여 체내의 막힌 혈을 뚫어줌으로써 혈액순환을 촉진시킬 뿐만 아니라, 신진대사를 증진시키는 효과를 갖는다.At this time, if the Gaussian magnetizer is less than 100 gauss, the amount of current discharged momentarily is insufficient to obtain the properties of the permanent magnet. Therefore, the titanium sintered body is deposited by titanium ion thin film (S8) by ion plating method. Titanium ions reactivate and normalize the dislocation potential of human body pain to normalize the function of cells to relieve inflammation and pain, and remove wastes to promote blood circulation by removing clogged blood in the body. In addition, it has the effect of promoting metabolism.

본 발명의 다른 실시예로서 티타늄이온박막 증착(S8) 후, 티타늄이온박막 증착된 소결체의 중앙에 일정크기의 관통홈을 형성시키고 형성된 관통홈에 영구자석을 설치(S9)하면, 더욱 우수한 영구자석을 형성시킬 수 있는 것이며, 연마된 소결체를 가우스착자기에 투입하고 100∼5000가우스의 범위로 착자하는 단계(S7)를 생략하는 방법도 가능한 것이다.As another embodiment of the present invention, after the titanium ion thin film deposition (S8), if the through-hole of a predetermined size is formed in the center of the titanium ion thin film deposited sintered body and the permanent magnet is installed in the formed through groove (S9), a more excellent permanent magnet It is also possible to form a method, and the method of adding the polished sintered body to the Gaussian magnetizer and magnetizing it in the range of 100 to 5000 gauss may be omitted.

삭제delete

상기와 같은 방법으로 제조된 본 발명의 지르코니아를 이용한 소결체는 파스, 의료기기 등에 사용되어 피부 전위를 정상적인 상태로 변화시켜 줌과 동시에, 세포막 전위의 변화에 의해 발생되는 통증을 빠른 시간 내에 완화시켜 줄 수 있고, 혈액순환이 원활히 되도록 할 뿐만 아니라, 팬티, 브래이지어, 축구용 스타킹, 모자, 장신구, 매트, 벨트, 마스크 등에 부착하여 사용할 수 도 있는 것으로 그 사용에 제한을 두는 것은 아니다.The sintered body using the zirconia of the present invention prepared by the above method is used in the pars, medical equipment, etc. to change the skin potential to a normal state and at the same time relieve the pain caused by the change of the cell membrane potential It can be used not only to facilitate blood circulation, but also to attach to panties, bras, soccer stockings, hats, ornaments, mats, belts, masks, and the like, without restricting the use thereof.

이상에서와 같이 본 발명은 비록 상기의 실시예에 한하여 설명하였지만 반드시 여기에만 한정되는 것은 아니며, 본 발명의 범주와 사상을 벗어나지 않는 범위 내에서 다양한 변형실시가 가능함은 물론이다.As described above, although the present invention has been described with reference to the above embodiments, it is not necessarily limited thereto, and various modifications can be made without departing from the scope and spirit of the present invention.

이상의 설명에서 분명히 알 수 있듯이 본 발명의 지르코니아를 이용한 소결체의 제조방법에 의하면, 지르코니아에 페라이트를 투입하여 혼련하고, 소결조제를 첨가하여 소결한 후, 착자하고 이온프레이팅법으로 티타늄이온박막이 형성되게 함으로써, 소결체를 파스, 의료기기 등에 이용하면 전자가 환부의 표피로 이동하여 피부 전위를 정상적으로 변화시켜 통증을 제거해 줄 수 있을 뿐만 아니라 혈액순환이 원활히 될 수 있으며, 영구자석에너지를 이용할 수 있게 되어 경직된 근육을 이완시킬 수 있도록 하는 등의 유용한 효과를 제공한다.As apparent from the above description, according to the method for producing a sintered body using the zirconia of the present invention, the ferrite is mixed with zirconia, kneaded, and sintered with the addition of a sintering aid, and then magnetized and a titanium ion thin film is formed by ion fritting. By using the sintered body, such as a pars, a medical device, the electrons move to the epidermis of the affected area to change the skin potential normally to remove the pain, and to facilitate blood circulation, and to use permanent magnet energy. It can help you relax your stiff muscles.

도 1은 본 발명에 의한 지르코니아를 이용한 소결체의 제조공정도1 is a manufacturing process diagram of a sintered body using zirconia according to the present invention

Claims (3)

소결체의 제조방법에 있어서In the manufacturing method of the sintered compact 지르코니아 65∼75중량％에 페라이트 25∼35중량％를 투입하여 혼련하는 단계(S1)와; 1차 혼련된 혼련물 75∼80중량％에 탄화규소 20∼25중량％를 2차 혼련하는 단계(S2)와, 2차 혼련된 혼련물 85∼97중량％에 소결조제 3∼15중량％를 투입하는 단계(S3)와; 소결조제가 투입된 혼련물을 금형에 투입하고 가압하여 일정형태로 성형하는 단계(S4)와; 성형된 성형물을 1800∼2100℃의 진공소성로에서 소결하는 단계(S5)와; 소결된 소결체를 연마하는 단계(S6)와; 연마된 소결체를 가우스 착자기에 투입하고 100∼5000가우스의 범위로 착자하는 단계(S7)와; 착자된 소결체를 이온프레이팅법으로 티타늄이온박막 증착하는 단계(S8)와, 티타늄이온박막 증착된 소결체의 중앙에 일정크기의 관통홈을 형성시키고, 형성된 관통홈에 영구자석을 설치하는 단계(S9)를 포함하는 것을 특징으로 하는 지르코니아를 이용한 소결체의 제조방법.Adding and mixing 25-35% by weight of ferrite in 65-75% by weight of zirconia (S1); Secondly kneading 20-25 wt% of silicon carbide to 75-80 wt% of the first kneaded kneaded product, and 3-15 wt% of a sintering aid to 85-97 wt% of the second kneaded kneaded material Putting step (S3); Inserting the kneaded product into which the sintering aid is added, and pressing the mold to form a predetermined shape (S4); Sintering the molded article in a vacuum firing furnace at 1800 to 2100 ° C. (S5); Polishing the sintered sintered body (S6); Putting the polished sintered compact into a Gaussian magnetizer and magnetizing it in a range of 100 to 5000 gauss (S7); Step of depositing a titanium ion thin film of the magnetized sintered body by the ion plating method (S8), and forming a through hole of a predetermined size in the center of the titanium ion thin film deposited sintered body, and installing a permanent magnet in the formed through groove (S9) Method for producing a sintered body using zirconia, characterized in that it comprises a). 삭제delete 삭제delete
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63311968A (en) * 1987-06-16 1988-12-20 Toyo Iryo Kenkyusho:Kk Medical far infrared ray emitting magnet
JPH04260658A (en) * 1991-02-15 1992-09-16 Tokin Corp Sintered ferrite and its production
JPH08172006A (en) * 1994-12-16 1996-07-02 Yamauchi Corp Composition for magnet, magnetic medical treatment device, and device for stimulating growth of living thing
KR20010040354A (en) * 1998-01-19 2001-05-15 메드퀘스트 프러덕츠 인코퍼레이티드 Method and apparatus for providing a conductive, amorphous non-stick coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63311968A (en) * 1987-06-16 1988-12-20 Toyo Iryo Kenkyusho:Kk Medical far infrared ray emitting magnet
JPH04260658A (en) * 1991-02-15 1992-09-16 Tokin Corp Sintered ferrite and its production
JPH08172006A (en) * 1994-12-16 1996-07-02 Yamauchi Corp Composition for magnet, magnetic medical treatment device, and device for stimulating growth of living thing
KR20010040354A (en) * 1998-01-19 2001-05-15 메드퀘스트 프러덕츠 인코퍼레이티드 Method and apparatus for providing a conductive, amorphous non-stick coating

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