KR100506156B1 - painting steel sheet and manufacturing method thereof - Google Patents

painting steel sheet and manufacturing method thereof Download PDF

Info

Publication number
KR100506156B1
KR100506156B1 KR10-2002-0022925A KR20020022925A KR100506156B1 KR 100506156 B1 KR100506156 B1 KR 100506156B1 KR 20020022925 A KR20020022925 A KR 20020022925A KR 100506156 B1 KR100506156 B1 KR 100506156B1
Authority
KR
South Korea
Prior art keywords
weight
steel sheet
layer
coating
coated steel
Prior art date
Application number
KR10-2002-0022925A
Other languages
Korean (ko)
Other versions
KR20030084278A (en
Inventor
이연재
홍차근
이승정
여주한
Original Assignee
(주)세아제강
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)세아제강 filed Critical (주)세아제강
Priority to KR10-2002-0022925A priority Critical patent/KR100506156B1/en
Publication of KR20030084278A publication Critical patent/KR20030084278A/en
Application granted granted Critical
Publication of KR100506156B1 publication Critical patent/KR100506156B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/24Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

본 발명은, 하도도장층을 갖는 도장강판에 관한 것으로서, 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함하며, 상기 하도도장층의 적어도 일부 표면에 도포되는 방향도장층 갖는 것을 특징으로 한다. 이에 의하여, 본 발명에 따른 도장강판을 사용한 제품이 실내에 배치되었을 경우에는, 방향입자가 대기 중에 노출되면서 향이 실내에 확산되므로 실내에 불쾌한 냄새를 제거하며 또한 정서적으로 안정감을 느낄 수 있는 쾌적한 실내환경을 제공 수 있다. The present invention relates to a coated steel sheet having a undercoat layer, comprising: 54.2% by weight of polymer polyester resin, 33.2% by weight of pigment, 5% by weight of melamine resin, and 5.6% by weight of fragrance-producing substance Particles, comprising 2% by weight of polypropylene wax and polyamide wax, characterized in that it has an aromatic coating layer applied to at least part of the surface of the undercoat layer. Accordingly, when the product using the coated steel sheet according to the present invention is placed indoors, the fragrance diffuses into the room while the fragrance particles are exposed to the air, thereby removing unpleasant odors in the room and also feeling emotionally comfortable. Can be provided.

Description

도장강판 및 도장강판의 제조방법{painting steel sheet and manufacturing method thereof}Painting steel sheet and manufacturing method

본 발명은, 도장강판 및 도장강판의 제조방법에 관한 것으로서, 보다 상세하게는, 대기 중으로 향을 발산시킬 수 있는 도장강판 및 도장강판의 제조방법에 관한 것이다.The present invention relates to a method for producing a coated steel sheet and a coated steel sheet, and more particularly, to a method for manufacturing a coated steel sheet and a coated steel sheet capable of releasing incense to the atmosphere.

일반적으로 강판은 강도가 우수하고 가공이 용이하여 가전제품 및 건자재용으로 많이 사용되고 있다. 그러나 강판은 쉽게 부식된다는 취약점을 지니고 있어 이를 보완하고자 강판 표면에 아연이나 알루미늄을 도금하고 크롬산염처리를 하여 내식성을 향상시키고 있다. 특히 건물의 내/외장재 및 TV, 오디오, 컴퓨터를 비롯한 가전제품의 외장 케이스 등에 사용되는 강판의 경우, 색상의 아름다움 및 입체질감의 부여 등 외관의 미려함이 요구에 따라, 도금과 크롬산염처리를 거친 강판에 도장처리를 하여 강판의 내식성을 향상시킴과 동시에 도료가 가지고 있는 다양한 색상을 이용하여 장식의 효과를 높여 사용하고 있으며, 최근에는 수요자의 요구에 따라 일정한 형태의 인쇄를 실시하거나, 특수한 질감을 부여하는 등의 다양한 기능이 부여된 제품들이 개발되고 있다.In general, steel sheet is excellent in strength and easy to process, and is used for home appliances and building materials. However, the steel sheet has a weakness that it is easily corroded, and to compensate for this, zinc or aluminum is plated on the surface of the steel sheet and chromated to improve corrosion resistance. In particular, steel sheets used in interior / exterior materials of buildings and exterior cases of home appliances such as TVs, audios, computers, etc., have undergone plating and chromate treatments as required for the beauty of colors and the appearance of the three-dimensional texture. The steel plate is coated to improve the corrosion resistance of the steel plate and at the same time use the various colors of the paint to enhance the effect of decoration. Recently, a certain type of printing or special texture is applied according to the demand of the consumer. Products that are endowed with various functions, such as endowment, are being developed.

전술한 바와 같이, 건물의 내/외장재 및 TV, 오디오, 컴퓨터를 비롯한 가전제품의 외장 케이스 등에 사용되는 강판에 외관의 미려함 및 특수질감 등이 부여된 제품들이 제시되고 있긴 하나, 건물의 내/외장재 및 TV, 오디오, 컴퓨터를 비롯한 가전제품의 외장 케이스 등에 방향기능이 부여된 본 발명에 따른 도장강판이 사용된다면, 대기 중으로 향이 발산되면서 실내에 불쾌한 냄새를 제거하며 또한 정서적으로 안정감을 느낄 수 있는 쾌적한 실내환경을 제공 수 있을 것이다. As mentioned above, although the interior and exterior materials of buildings are provided with the beauty of the exterior and the special texture to steel sheets used for exterior cases of home appliances such as TVs, audio, computers, etc. And if the coated steel sheet according to the present invention has been applied to the external case of home appliances, such as TV, audio, computer, etc. is used, it is pleasant to remove the unpleasant odors in the room while feeling the sense of stability as the smell is emitted into the atmosphere It will be able to provide an indoor environment.

따라서, 본 발명의 목적은, 대기 중으로 향을 발산시킬 수 있는 도장강판 및 도장강판의 제조방법을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a coated steel sheet and a method for producing a coated steel sheet capable of releasing fragrance into the atmosphere.

상기 목적은, 본 발명에 따라, 하도도장층을 갖는 도장강판에 있어서, 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함하며, 상기 하도도장층의 적어도 일부 표면에 도포되는 방향도장층 갖는 것을 특징으로 하는 도장강판에 의해 달성된다.The above object is, according to the present invention, in a coated steel sheet having a undercoat layer, comprising: 54.2% by weight of a polymeric polyester resin, 33.2% by weight of a pigment, 5% by weight of a melamine resin, and a odor generating substance. Achieved by a coated steel sheet comprising any one of weight percent aromatic particles, 2 weight percent polypropylene wax and polyamide wax, and having an aromatic coating layer applied to at least a part of the surface coating layer do.

삭제delete

한편, 상기 방향입자는, 허브향, 꽃향, 과일향, 조미료향을 발생하는 물질 중 어느 하나를 함유하고 있는 것이 바람직하다. On the other hand, the aroma particles, it is preferable to contain any one of the substances that generate the herbal flavor, floral flavor, fruit flavor, seasoning flavor.

그리고, 상기 방향도장층은, 18 내지 22㎛의 두께를 갖도록 구성할 수 있다. In addition, the aromatic coating layer can be configured to have a thickness of 18 to 22㎛.

한편, 상기 목적은 본 발명의 다른 측면에 따라, 소지강판 위에 도금처리하여 합금도금층을 형성하는 단계; 상기 합금도금층 위에 크롬산염 롤코팅 한 후 80 내지 120℃에서 건조시켜 15 내지 45㎎/㎡의 크롬산염층을 형성하는 단계; 상기 크롬산염층 위에 폴리에스테르 수지를 포함하는 도료를 롤코팅 한 후 216 내지 224℃에서 건조시켜 4 내지 8㎛의 하도도장층을 형성하는 단계; 상기 하도도장층 위에 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함하는 도료를 롤코팅 한 후 소정의 온도에서 가열하여 건조시켜 방향도장층을 형성하는 단계를 포함하는 것을 특징으로 하는 도장강판의 제조방법에 의해서도 달성된다. On the other hand, the object according to another aspect of the invention, the step of forming a plating layer on the steel plate by plating; Forming a chromate layer of 15 to 45 mg / m 2 by performing chromate roll coating on the alloy plating layer and drying at 80 to 120 ° C .; Roll coating a coating material comprising a polyester resin on the chromate layer and drying at 216 to 224 ° C. to form a 4 to 8 μm undercoat layer; 54.2% by weight of polymeric polyester resin, 33.2% by weight of pigment, 5% by weight of melamine resin, 5.6% by weight of aromatic particles containing fragrance-producing substances, 2% by weight of polypropylene wax on the undercoat layer It is also achieved by a method for producing a coated steel sheet comprising a step of forming a directional coating layer by roll coating a paint comprising any one of the polyamide-based wax and then heated and dried at a predetermined temperature.

삭제delete

한편, 상기 방향입자는, 허브향, 꽃향, 과일향, 조미료향을 발생하는 물질 중 어느 하나를 함유하고 있는 것이 바람직하다. On the other hand, the aroma particles, it is preferable to contain any one of the substances that generate the herbal flavor, floral flavor, fruit flavor, seasoning flavor.

그리고, 상기 방향도장층은, 232 내지 241℃에서 가열하여 건조시켜 18 내지 22㎛의 두께로 형성되도록 할 수 있다. The aromatic coating layer may be heated to dry at 232 to 241 ° C. to form a thickness of 18 to 22 μm.

이하에서는 첨부도면을 참조하여 본 발명에 대해 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 도장강판의 부분단면도이고, 도 2는 본 발명에 따른 도장강판의 방향도장층의 단면도이다. 이들 도면에 도시된 바와 같이, 본 발명에 따른 도장강판(1)은, 소지강판(2)과, 소지강판(2) 위에 순차적으로 도포되는 합금도금층(3), 크롬산염층(4), 하도도장층(5)과, 상도도장층인 방향도장층(6)을 갖는다. 1 is a partial cross-sectional view of a coated steel sheet according to the present invention, Figure 2 is a cross-sectional view of the directional coating layer of the coated steel sheet according to the present invention. As shown in these figures, the coated steel sheet 1 according to the present invention, the steel plate 2, the alloy plating layer (3), the chromate layer (4), sequentially coated on the steel plate 2 It has the coating layer 5 and the directional coating layer 6 which is a top coat layer.

소지강판(2)은, 냉간압연강판, 용융아연도금강판, 전기아연도금강판, 알루미늄강판 등으로 다양하게 마련될 수 있으며, 여기서는, Al, Zn로 이루어지는 합금용융 도금 욕조 내에 소지강판(2)을 통과시켜 에어와이법에 의해 도금피복량을 조절하여, 소지강판(2) 상에 합금도금층(3)을 형성하게 된다. The holding steel sheet 2 may be variously provided as a cold rolled steel sheet, a hot dip galvanized steel sheet, an electrogalvanized steel sheet, an aluminum steel sheet, and the like. Here, the holding steel sheet 2 is placed in an alloy molten plating bath made of Al and Zn. By passing through to adjust the coating coating amount by the air wipe method, to form the alloy plating layer 3 on the base steel sheet (2).

합금도금층(3)의 표면에 존재하는 녹 유분, 먼지 등의 오염물을 알카리액을 이용하여 완전히 제거한 후, 롤코팅 방법을 이용하여 얇은 막으로 크롬산 염을 도포한 다음, 80 내지 120℃의 온도에서 건조시켜 함금도금층 위에 15 내지 45㎎/㎡의 크롬산염층(4)을 형성시킨다.Contaminants such as rust oil and dust present on the surface of the alloy plating layer 3 are completely removed by using an alkaline liquid, and then the chromic acid salt is coated with a thin film using a roll coating method, and then at a temperature of 80 to 120 ° C. By drying, a chromate layer 4 of 15 to 45 mg / m 2 was formed on the plating layer.

한편, 크롬산염층(4) 위에는 고분자 폴리에스테르 도막층이 형성되며, 폴리에스테르 도막층은, 하도인 하도도장층(5)과, 하도도장층(5) 위에 상도인 방향도장층(6)으로 2층 구조로 이루어진다. On the other hand, a polymeric polyester coating layer is formed on the chromate layer 4, and the polyester coating layer is the undercoat layer 5 which is the undercoat, and the aromatic coating layer 6 which is the top coat on the undercoat layer 5. It consists of a two-layer structure.

하도도장층(5)은, 건조도막두께는 4-8㎛로 크롬산염층(4) 위에 작업을 실시하나, 5-7㎛으로 작업하는 것이 바람직하며, 소부 온도는 216-224℃ (PMT; Pick Metal Temperature 기준)에서 실시하게 된다.The undercoat layer 5 works on the chromate layer 4 with a dry coating thickness of 4-8 μm, but preferably at 5-7 μm, and the baking temperature is 216-224 ° C. (PMT; Pick Metal Temperature).

또한, 하도도장층(5)은, 방향도장층(6)의 고분자 폴리에스테르 수지와의 소재 부착성 및 유연성을 유지시키기 위해서 부착성이 우수한 엑폭시수지를 브랜딩하고 폴리이소시네이트 수지를 가교제로 한 우레탄 수지를 결합함으로써, 하도도장층(5) 자체의 기본물성인 일반적인 내식성 및 방향도장층(6)과 도금강판과의 부착성 강화 외에 충분한 연신율을 부여하여, 가공시 발생되는 소재의 균열을 방향도장층(6)까지 전달되지 않고 흡수될 수 있도록 마련된다.In addition, in order to maintain the material adhesion and flexibility of the aromatic coating layer 6 with the polymeric polyester resin, the undercoat layer 5 is branded with an epoxy resin having excellent adhesion and a polyisocyanate resin as a crosslinking agent. By combining the urethane resin, it provides general corrosion resistance, which is the basic property of the undercoat layer 5 itself, and strengthens the adhesion between the aromatic coating layer 6 and the plated steel sheet, and provides sufficient elongation to prevent cracking of the material generated during processing. It is provided to be absorbed without being transferred to the coating layer (6).

방향도장층(6)은, 하도도장층(5)이 완전경화한 후 하도도장층(5) 위에 건조도막두께가 18-22㎛이 되도록 롤코팅 방식으로 도장한 후, 오븐에서 롤코팅 된 강판을 232-241℃ (PMT; Pick Metal Temperature 기준)로 가열하여 건조시킨다. The direction coating layer 6 is a steel sheet roll coated in an oven after coating the coating layer 5 is completely cured and coated on the coating layer 5 with a dry coating thickness of 18-22 μm. It is dried by heating to 232-241 ℃ (PMT; Pick Metal Temperature).

여기서, 상도도장층인 방향도장층(6)은 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함한다. Here, the fragrance coating layer 6, which is a top coat layer, is a 5.6 wt% fragrance particle containing 54.2 wt% polymer polyester resin, 33.2 wt% pigment, 5 wt% melamine resin, and a substance generating aroma, It comprises any one of 2% by weight of polypropylene wax and polyamide wax.

즉, 방향도장층(6)은 고분자 폴리에스테르 수지를 포함함으로써, 폴리프로필렌계의 안료입자에 의한 돌출형성 및 도료의 열경화 밀도 차이를 이용하여 2중의 입체질감을 부여하는 방법으로 본 발명에 따른 도장강판(1)이 완성된다.That is, the fragrance coating layer 6 includes a high molecular polyester resin, thereby providing a dual three-dimensional texture by using protrusions formed by polypropylene pigment particles and differences in thermosetting density of the paint. The coated steel sheet 1 is completed.

이와 같이, 하도도장층(5)과 방향도장층(6)으로 구성된 고분자 폴리에스테르 도막층은, 수요자의 사용 용도에 따른, 가공시 나타나는 가공부위의 도막균열(크랙)이나, 사용 중 발생되는 표면오염 방지 등의 제반 요구사항을 해결하기 위하여 도막의 연신율이 우수하고 내오염이 우수하게 하였다. As described above, the polymer polyester coating layer composed of the undercoat layer 5 and the aromatic coating layer 6 has a coating film crack (cracks) at the processing site that appears during processing or a surface generated during use according to the use purpose of the consumer. In order to solve various requirements such as pollution prevention, the elongation of the coating film was excellent and the pollution resistance was excellent.

또한, 여기서 방향도장층(6)은, 도막표면에 나타나는 질감을 나타내기 위해서는 10-30㎛의 폴리프로필렌계 왁스에 의해 질감을 부여되며, 향을 발생하는 물질을 마이크로 캡슐화한 방향입자(10)가 첨가되어 있음으로써, 제조된 본 발명에 따른 도장강판(1)의 표면에는 방향입자(10)가 방향도장층(6)의 표면에 부상되어 있게 되어 본 발명에 따른 도장강판(1)의 표면을 손이나 걸레 등으로 문지를 경우 방향입자(10) 내에 향을 발생하는 물질이 대기 중에 노출되면서 냄새가 확산되는 특성을 가지고 있다.In addition, the aromatic coating layer 6 is provided with a texture by polypropylene wax of 10-30㎛ in order to exhibit the texture appearing on the surface of the coating film, and the aromatic particles 10 which microencapsulates the substance generating the aroma. By the addition, the surface of the coated steel sheet 1 according to the present invention is allowed to float on the surface of the direction coating layer 6 on the surface of the coated steel sheet 1 according to the present invention. In the case of rubbing with a hand or a mop, the smell-producing substance is exposed to the atmosphere while the fragrance-producing substance 10 is exposed to the air.

여기서, 본 발명에 따른 도장강판(1)으로부터 발산되는 향은, 각종 허브향, 각종 꽃향, 각종 과일향, 각종 맛을 내는 조미료의 향,(예를 들어 커피향, 초컬릿향, 바닐라향), 각종 음식 향, 그 외 한약재 향, 페로몬 향, 등으로 다양할 수 있다.Here, the flavor emitted from the coated steel sheet 1 according to the present invention is a variety of herb flavors, various flower flavors, various fruit flavors, flavors of various flavors (for example, coffee flavor, chocolate flavor, vanilla flavor), Various food flavors, other herbal flavors, pheromone flavors, etc. can vary.

여기에서, 본 발명에 따른 도장강판(1)으로부터 발산되는 향의 종류에 대해 기재하였으나, 본 발명에 따른 도장강판(1)으로부터 발산될 수 있는 향은 상기에 기재된 향에 국한되는 것이 아니며, 사람이 인식할 수 있는 향이면 모두 본 발명에 따른 도장강판(1)에 적용가능하다. Here, although the kind of incense emitted from the coated steel sheet 1 according to the present invention has been described, the incense that may be emitted from the coated steel sheet 1 according to the present invention is not limited to the incense described above, and All of these recognizable incense is applicable to the coated steel sheet 1 according to the present invention.

한편, 전술한 실시예에서는 방향도장층(6)을 구성하는 상도도료에 폴리프로필렌계 왁스가 포함되었으나, 폴리프로필린계 왁스 대신에 폴리아마이드계 왁스를 포함할 수도 있다. Meanwhile, in the above-described embodiment, the polypropylene wax is included in the top coat constituting the fragrance coating layer 6, but polyamide wax may be included instead of the polypropylene wax.

이상 설명한 바와 같이, 본 발명에 따른 도장강판을 사용한 제품이 실내에 배치되었을 경우에는, 방향입자가 대기 중에 노출되면서 향이 실내에 확산되므로 실내에 불쾌한 냄새를 제거하며 또한 정서적으로 안정감을 느낄 수 있는 쾌적한 실내환경을 제공할 수 있다. As described above, when the product using the coated steel sheet according to the present invention is placed in the room, the fragrance diffuses into the room while the fragrance particles are exposed to the air, thereby removing unpleasant odors in the room and also feeling emotionally comfortable. It can provide an indoor environment.

도 1은 본 발명에 따른 도장강판의 부분단면도, 1 is a partial cross-sectional view of a coated steel sheet according to the present invention,

도 2는 본 발명에 따른 도장강판의 방향도장층의 단면도이다. 2 is a cross-sectional view of the direction coating layer of the coated steel sheet according to the present invention.

* 도면의 주요 부분에 대한 부호의 설명* Explanation of symbols for the main parts of the drawings

1 : 도장강판 2 : 소지강판1: painted steel sheet 2: holding steel sheet

3 : 합금도금층 4 : 크롬산염층3: alloy plating layer 4: chromate layer

5 : 하도도장층 6 : 방향도장층5: undercoat layer 6: direction coating layer

10 : 방향입자10: aromatic particles

Claims (8)

하도도장층을 갖는 도장강판에 있어서,In the coated steel sheet having a coating layer, 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함하며, 상기 하도도장층의 적어도 일부 표면에 도포되는 방향도장층 갖는 것을 특징으로 하는 도장강판.54.2% by weight of polymeric polyester resin, 33.2% by weight of pigment, 5% by weight of melamine resin, 5.6% by weight of aromatic particles containing fragrant substances, 2% by weight of polypropylene wax and polyamide wax Painted steel sheet comprising any one of, having a direction coating layer applied to at least part of the surface of the undercoat layer. 삭제delete 제1항에 있어서,The method of claim 1, 상기 방향입자는, 허브향, 꽃향, 과일향, 조미료향을 발생하는 물질 중 어느 하나를 함유하고 있는 것을 특징으로 하는 도장강판.The fragrant particles, the coated steel sheet, characterized in that it contains any one of the herbs, flowers, fruits, seasonings. 제1항 또는 제3항에 있어서,The method according to claim 1 or 3, 상기 방향도장층은, 18 내지 22㎛의 두께를 갖는 것을 특징으로 하는 도장강판. The direction coating layer, the coated steel sheet, characterized in that it has a thickness of 18 to 22㎛. 소지강판 위에 도금처리하여 합금도금층을 형성하는 단계;Plating the base steel plate to form an alloy plating layer; 상기 합금도금층 위에 크롬산염 롤코팅 한 후 80 내지 120℃에서 건조시켜 15 내지 45㎎/㎡의 크롬산염층을 형성하는 단계;Forming a chromate layer of 15 to 45 mg / m 2 by performing chromate roll coating on the alloy plating layer and drying at 80 to 120 ° C .; 상기 크롬산염층 위에 폴리에스테르 수지를 포함하는 도료를 롤코팅 한 후 216 내지 224℃에서 건조시켜 4 내지 8㎛의 하도도장층을 형성하는 단계;Roll coating a coating material comprising a polyester resin on the chromate layer and drying at 216 to 224 ° C. to form a 4 to 8 μm undercoat layer; 상기 하도도장층 위에 54.2중량%의 고분자 폴리에스테르수지, 33.2중량%의 안료, 5중량%의 멜라민수지, 향을 발생하는 물질을 함유한 5.6중량%의 방향입자, 2중량%의 폴리프로필렌계 왁스와 폴리아마이드계 왁스 중 어느 하나를 포함하는 도료를 롤코팅 한 후 소정의 온도에서 가열하여 건조시켜 방향도장층을 형성하는 단계를 포함하는 것을 특징으로 하는 도장강판의 제조방법.54.2% by weight of polymeric polyester resin, 33.2% by weight of pigment, 5% by weight of melamine resin, 5.6% by weight of aromatic particles containing fragrance-producing substances, 2% by weight of polypropylene wax on the undercoat layer And after coating the paint comprising any one of polyamide waxes, heating and drying at a predetermined temperature to form an aromatic coating layer. 삭제delete 제5항에 있어서,The method of claim 5, 상기 방향입자는, 허브향, 꽃향, 과일향, 조미료향을 발생하는 물질 중 어느 하나를 함유하고 있는 것을 특징으로 하는 도장강판의 제조방법.The fragrance particles, a method for producing a coated steel sheet, characterized in that it contains any one of the herbs, flowers, fruits, seasonings. 제5항 또는 제7항에 있어서,The method according to claim 5 or 7, 상기 방향도장층은, 232 내지 241℃에서 가열하여 건조시켜 18 내지 22㎛의 두께로 형성되는 것을 특징으로 하는 도장강판의 제조방법.The aromatic coating layer is heated to 232 to 241 ℃ dried to form a thickness of 18 to 22 ㎛ characterized in that the manufacturing method of the steel sheet.
KR10-2002-0022925A 2002-04-26 2002-04-26 painting steel sheet and manufacturing method thereof KR100506156B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR10-2002-0022925A KR100506156B1 (en) 2002-04-26 2002-04-26 painting steel sheet and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR10-2002-0022925A KR100506156B1 (en) 2002-04-26 2002-04-26 painting steel sheet and manufacturing method thereof

Publications (2)

Publication Number Publication Date
KR20030084278A KR20030084278A (en) 2003-11-01
KR100506156B1 true KR100506156B1 (en) 2005-08-08

Family

ID=32380499

Family Applications (1)

Application Number Title Priority Date Filing Date
KR10-2002-0022925A KR100506156B1 (en) 2002-04-26 2002-04-26 painting steel sheet and manufacturing method thereof

Country Status (1)

Country Link
KR (1) KR100506156B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040035282A (en) * 2002-10-19 2004-04-29 윤명중 Manufacturing method of the coating grater which has a scent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR930009370A (en) * 1991-10-22 1993-05-22 강진구 How to Quick Focus and Zoom on Your Camcorder
JPH07171497A (en) * 1993-12-22 1995-07-11 Kawasaki Steel Corp Precoated steel sheet having excellent corrosion resistance
JPH08266999A (en) * 1995-03-31 1996-10-15 Nippon Steel Corp Guard film-free type precoated steel panel excellent in punching resistance and pressure mark resistance
KR100253818B1 (en) * 1997-07-31 2000-04-15 이철우 Galvalume painting steel plate covered with transparent film and method of manrfacturing the same
KR20010048771A (en) * 1999-11-29 2001-06-15 이원목 Composite Material Containing Encapsulated Perfume
KR20020041099A (en) * 2000-11-27 2002-06-01 윤대근 Environment affinitive color clear coated steel sheet

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR930009370A (en) * 1991-10-22 1993-05-22 강진구 How to Quick Focus and Zoom on Your Camcorder
JPH07171497A (en) * 1993-12-22 1995-07-11 Kawasaki Steel Corp Precoated steel sheet having excellent corrosion resistance
JPH08266999A (en) * 1995-03-31 1996-10-15 Nippon Steel Corp Guard film-free type precoated steel panel excellent in punching resistance and pressure mark resistance
KR100253818B1 (en) * 1997-07-31 2000-04-15 이철우 Galvalume painting steel plate covered with transparent film and method of manrfacturing the same
KR20010048771A (en) * 1999-11-29 2001-06-15 이원목 Composite Material Containing Encapsulated Perfume
KR20020041099A (en) * 2000-11-27 2002-06-01 윤대근 Environment affinitive color clear coated steel sheet

Also Published As

Publication number Publication date
KR20030084278A (en) 2003-11-01

Similar Documents

Publication Publication Date Title
DE60332632D1 (en) METHOD FOR PRODUCING A STORAGE STABLE, EDIBLE SNACK PRODUCT WITH AN OUTER TEAS
DE602004007894T2 (en) METHOD FOR DECORATING A CONTAINER
CN100469674C (en) Lift veneer and its surface treating method
KR100506156B1 (en) painting steel sheet and manufacturing method thereof
CA2797470C (en) Method and use of a binder for providing a metallic coat covering a surface
EP1149635A3 (en) A process for the preparation of multi-layer coatings of the water-borne base coat/powder clear coat type
US1772743A (en) Coated metal article and process of applying coatings thereof
JP5238015B2 (en) Antibacterial / antifungal coated metal products
US3338732A (en) Porcelain enamel coating
JP2003533368A (en) Use of a coated substrate and product comprising a coated substrate having a metallic surface impression, a method for adhesively coating a substrate with a corrosive optical layer and a method for adhesively coating a substrate with a corrosive optical layer
JP2001295069A (en) Decorative resin coated metallic sheet
JPH0767784A (en) Cooking plate of cooker
JP4086141B2 (en) Painted metal plate with excellent insect repellent
KR100498766B1 (en) changes in temperature a color sheet and a manufacturing process of it
RU2111126C1 (en) Method of artistic-decorative modification of article surfaces
CN107538864A (en) A kind of aluminizer and tectorial color steel plate with wire-drawing effect
JP2009179673A (en) Antibacterial coating film
US5342670A (en) Process for simulating a chaotic pattern on a surface by applying to the surface a nonuniform multilayered coating
JP3220788U (en) Tableware painted with paint containing bamboo charcoal powder
GB2257929A (en) Distressed paint finishes
JPH0151547B2 (en)
JPH0838993A (en) Surface coating method
JP5329595B2 (en) Decorative metal products and their manufacturing methods
TW201800611A (en) Coated-plated metal plate
CA2277830A1 (en) Multilayer coating film formation process

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20120716

Year of fee payment: 8

FPAY Annual fee payment

Payment date: 20130716

Year of fee payment: 9

FPAY Annual fee payment

Payment date: 20140725

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20150714

Year of fee payment: 11

FPAY Annual fee payment

Payment date: 20160726

Year of fee payment: 12

FPAY Annual fee payment

Payment date: 20170727

Year of fee payment: 13

FPAY Annual fee payment

Payment date: 20190729

Year of fee payment: 15