KR100505503B1 - Manufacturing method of gastric nylon Taesodo company by Piowai method - Google Patents
Manufacturing method of gastric nylon Taesodo company by Piowai method Download PDFInfo
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- KR100505503B1 KR100505503B1 KR10-1998-0052159A KR19980052159A KR100505503B1 KR 100505503 B1 KR100505503 B1 KR 100505503B1 KR 19980052159 A KR19980052159 A KR 19980052159A KR 100505503 B1 KR100505503 B1 KR 100505503B1
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
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Abstract
본 발명은 위사용 나이론 210데니어사의 제조방법으로서, POY공법으로 3,500 ∼ 4,000m/분의 속도로 권취하여 위사용 나이론사를 제조함에 있어서, 연신비를 1.20 ∼ 1.40으로 하고 릴렉스율을 4 ∼ 6%로 하여 제조함을 특징으로 함.The present invention is a manufacturing method of the nylon 210 denier for gastric use, in the production of gastric nylon yarn by winding at a speed of 3,500 to 4,000 m / min by POY method, the draw ratio is 1.20 to 1.40 and the relaxation rate is 4 to 6% Characterized in that manufactured by.
본 발명으로 제조된 나이론사는 강도가 4.6 ∼5.0g/d, 신도가 55 ∼ 60%이고 지연수축성이 없으므로 직물의 위사로 사용할 경우에 위단을 발생시키지 않음.Nylon yarn prepared by the present invention has a strength of 4.6 ~ 5.0g / d, elongation is 55 ~ 60% and does not delay delay when used as the weft of the fabric because there is no delay shrinkage.
Description
본 발명은 POY(Partially Oriented Yarn)공법에 의한 위사용 나이론 태섬도사의 제조방법에 관한 것으로, 보다 상세하게는 황산 상대점도(황산 농도 96%)가 2.0 ∼ 2.8수준의 나이론 6 칩을 POY공법으로 직접 방사연신하여 섬도가 210데니어 정도인 위사용 나이론사의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a gastric nylon Taesumdo Co., Ltd. by POY (Partially Oriented Yarn) method, and more specifically, a nylon 6 chip having a sulfuric acid relative viscosity (96% sulfuric acid concentration) of 2.0 to 2.8 level as a POY method. The present invention relates to a method for producing gastric nylon yarn having a degree of fineness of 210 deniers by direct radial drawing.
일반적으로 POY공법에 의하여 생산되는 나이론원사는 물성이 불안정하므로, 별도의 연신공정을 통하여 물성을 안정화 시킨 후 후가공 업체에 공급되거나, 혹은 제한된 용도 혹은 제직속도내에서 사용되는 조건으로 POY사 그대로 공급되기도 한다. 그러나, POY사 상태로 공급되는 원사는 현재와 같은 고속화(800rpm 이상)된 제직속도에 적합하지 못한 물성(강도, 신도 및 수축율등)을 갖고 있기 때문에 경사로 사용되는 경우에는 당김줄형태의 경사반(경사방향으로 발생된 결점)발생으로 가공품위가 저하되는 결점 및 경사파열에 의한 직기가동률 저하등의 문제점이 있으며, 위사로 사용되는 경우에는 변부에 늘어난 줄 형태의 위근(위사방향으로 발생된 결점)이 발생되어 가공품위가 크게 저하되는 치명적인 결함을 갖고 있다.In general, nylon yarns produced by the POY process are unstable in physical properties, so they may be supplied to post-processing companies after stabilizing their properties through a separate drawing process, or may be supplied as they are under conditions of limited use or weaving speed. do. However, the yarn supplied in the state of POY yarn has properties (strength, elongation, shrinkage, etc.) that are not suitable for the speed of weaving (800 rpm or more) as it is currently, so when it is used as a warp yarn, Defects in the direction of inclination), such as defects in the quality of the processed product and degradation of the weaving rate due to the rupture of the warp, and when used as weft yarns, wefts in the form of elongated edges (defects in the weft direction) Has a fatal defect in which the work quality is greatly reduced.
물론 연신공정을 거쳐 공급되는 POY사의 경우에는 상기한 바와 같은 문제점이 다소 완화되지만 이 경우 원사 생산업체의 입장에서는 별도의 공정을 거치는데 따른 제조비용의 상승과 생산성 저하등의 문제점이 있으므로 바람직스럽지 못하였다.Of course, in the case of POY, which is supplied through the stretching process, the above-mentioned problems are alleviated somewhat. However, in this case, it is not desirable for the yarn producer because there are problems such as an increase in manufacturing cost and a decrease in productivity due to a separate process. It was.
현재 경편용 또는 직물용으로 사용되며, POY공법에 의해 생산되는 나이론 원사는 40, 70 내지는 100데니어가 주종을 이루고 있고 통상의 (Conventional)공법보다는 고속의 방사속도로 제조하는 것이므로 생산성이 높은 장점이 있으나 최근의 FDY(Fully Oriented Yarn)공법으로 제조되는 나이론사에 비해서는 품질 및 연신성 측면에서 크게 미흡하다. Currently used for warp knitting or woven fabrics, nylon yarn produced by POY method is mainly 40, 70 or 100 denier, and is produced at a higher spinning speed than conventional method, so it has high productivity. However, compared to nylon, which is manufactured by the recent FDY (Fully Oriented Yarn) method, the quality and elongation are greatly inferior.
POY공법으로 제조되는 나이론원사를 직물의 경, 위사로 사용하는 경우에 가장 심각한 문제점은 상기 나이론원사의 저강도 및 고신도 때문에 고속화 직기에는 사용할 수 없다는 점이다. 그러나 POY 생산설비는 고뎃로울러(Godet Roller)의 유무와 관계없이 연신비(Draw Ratio)를 높힐 경우에는 나이론의 높은 지연 수축률 때문에 권취된 원사케이크(Cake)를 빼내기가 곤란하기 때문에 일정수준이상으로 강력을 높히고 신도를 낮추기가 매우 어렵다.The most serious problem in the case of using nylon yarn manufactured by the POY method as the light and weft of the fabric is that it cannot be used in a high-speed loom because of the low strength and high elongation of the nylon yarn. However, POY production equipment is more powerful than a certain level because it is difficult to pull out the wound cake due to the high delay shrinkage of nylon when the draw ratio is increased regardless of the presence or absence of a Goet Roller. It is very difficult to increase and decrease elongation.
이런 이유 때문에 POY사의 품질을 개선하는 것이 대단히 어려운 실정이며, 현재의 POY설비를 FDY설비로 대체하면 물성개선은 가능하지만 그럴 경우 고비용의 투자비가 소요되는 문제점이 있다.For this reason, it is very difficult to improve the quality of POY, and replacing the current POY facilities with FDY facilities can improve the properties, but there is a problem of costly investment.
본 발명은 상기와 같은 문제점을 해결한 것으로서, POY설비를 이용하되 통상적인 POY공법의 연신비보다 높은 연신비로 연신하여 나이론원사를 고모듈러스화함으로서 변부에 늘어난 줄형태의 위근발생을 방지함과 동시에 응력에 대한 변형의 절대크기를 줄임으로써 직물조직상 우수한 형태안정성을 갖도록함과 동시에 많은 릴렉스를 부여하여 지연수축에 의한 문제점이 발생하지 않는 위사용 나이론 태섬도사를 효과적으로 제조하는 방법을 제공하는데 그 목적이 있다.The present invention solves the problems as described above, by using a POY facility, but at a draw ratio higher than the draw ratio of the conventional POY method by high-modulus nylon yarn to prevent the occurrence of elongated form of the elongated edge and at the same time stress The purpose of this invention is to provide a method of effectively producing a weaving nylon tasman yarn that does not cause any problems due to delayed shrinkage by providing excellent shape stability at the same time as reducing the absolute size of the deformation of the fabric. have.
본 발명을 도면에 의하여 상세히 설명하면 다음과같다. 황산상대점도(황산농도 96%)가 2.0 ∼ 2.8이고, 수분율이 0.05%이하인 나이론 6 칩을 250 ∼ 255℃의 온도에서 용융방사하되 최적의 방사 드래프트(Draft)가 걸리도록 구멍의 크기는 0.3 ∼ 0.4mm, L/D(길이/직경)가 2.5 ∼ 3.0정도인 방사구금(1)을 사용하고, 방사구금(1)을 빠져나온 폴리머를 냉각풍 공급장치(3)에서 냉각풍의 속도가 0.4 ∼ 0.6m/초, 냉각풍의 온도가 14 ∼ 18℃인 냉각풍으로 냉각해서 냉각을 최적화하고, 퀀칭구간을 통과시킨 사조에 상, 하 2단의 오일링로울러(4),(5)를 통해 8 ∼ 12%의 유제를 부여한 후 3,000 ∼ 3,800m/분의 속도로 운전되는 제 1 고뎃로울러(6)를 통과시킨후 제 2 고뎃로울러(7)와의 사이에서 1.20 ∼ 1.40의 연신비로 연신한다. 연신된 연신사는 4 ∼ 6%의 릴렉스를 부여하고, 권취로울러(8)에서 3,500 ∼ 4,000m/분으로 권취한다.The present invention will be described in detail with reference to the drawings. Sintered nylon 6 chips with a sulfuric acid relative viscosity (96% sulfuric acid concentration) of 2.0 to 2.8 and a moisture content of 0.05% or less are melt spun at a temperature of 250 to 255 ° C. Using a spinneret (1) having a diameter of 0.4 mm and a L / D (length / diameter) of about 2.5 to 3.0, the polymer having exited the spinneret (1) was subjected to a cooling wind velocity of 0.4 to Optimized cooling by cooling with a cooling wind with a cooling wind temperature of 14 to 18 ° C at 0.6 m / sec., Through the upper and lower two-stage oil ring rollers (4) and (5) through the quench section. After imparting an emulsion of 8 to 12%, it is passed through a first go roller 6, which is operated at a speed of 3,000 to 3,800 m / min, and is drawn at an elongation ratio of 1.20 to 1.40 between the second go rollers 7. The drawn yarn is given a relaxation of 4 to 6% and is wound at 3,500 to 4,000 m / min in the winding roller 8.
본 발명은 냉각고화된 사조를 연신하기 쉽도록 충분한 량의 유제로 처리한 다음에 통상의 POY공법보다 높게 1.20 ∼ 1.40의 연신비로 연신한 후 권취전에 충분하게 4 ∼ 6%의 릴랙스를 부여하였으므로 고강도 및 저신도가 발현되어서 직물용 위사로 사용하였을 때 위근을 발생시키지 않는다.The present invention is treated with a sufficient amount of emulsion so as to easily stretch the cooled solid yarn, and then stretched at a draw ratio of 1.20 to 1.40 higher than that of the conventional POY method, and then gives sufficient relaxation of 4 to 6% before winding. And low elongation is expressed and does not generate gastric muscle when used as a weft for fabrics.
아울러 본 발명으로 제조된 나이론원사는 지연수축현상도 발생시키지 않는다.In addition, the nylon yarn produced by the present invention does not generate a delay shrinkage phenomenon.
또 본 발명은 FDY 설비와 같은 고가의 설비를 요함이 없이 상기 설비로 제조한 원사의 물성에 버금가는 나이론원사를 경제적으로 제조할 수 있다. In addition, the present invention can economically produce a nylon yarn comparable to the physical properties of the yarn produced by the facility without the need for expensive equipment such as FDY facilities.
실시예 1Example 1
황산 상대점도가 2.5인 나이론 칩을 255℃의 온도에서 용융하여 구멍의 갯수가 34개이고 L/D가 2.8이며 구멍직경이 0.30mm인 방사구금을 통하여 용융방사한 후 0.5m/초 속도의 냉각풍으로 냉각고화시킨다음 냉각된 사조(2)를 상단 및 하단 오일링로울러(4), (5)를 통해 11%의 유제를 부여한후 3,000m/분의 속도로 운전되는 제 1 고뎃로울러(6)를 통과시킨후 제 2 고뎃로울러(7)사이에서 1.30의 연신비로 연신한후 5%의 릴렉스를 부여하여 3,700m/분으로 권취하여 210데니어 원사를 제조하였다. 제조된 나이론 원사의 물성 및 직물용 위사로 사용하였을때의 가공품위는 표 1 과 같았다.A nylon chip with a sulfuric acid relative viscosity of 2.5 was melted at a temperature of 255 ° C, followed by melt spinning through spinnerets having 34 holes, L / D of 2.8, and hole diameter of 0.30 mm. The first gourd roller (6) operated at a speed of 3,000 m / min after the cooled thread (2) was imparted with 11% emulsion through the upper and lower oil ring rollers (4) and (5). After passing through the second high roller (7) was stretched at a draw ratio of 1.30, and then given a 5% relaxation, wound at 3,700m / min to produce 210 denier yarn. The physical properties of the nylon yarn and the processed product when used as the weft for the fabric were shown in Table 1.
실시예 2Example 2
상단 및 하단 오일링 로울러(4), (5)에 8.0 ∼ 9.0%의 유제를 부여하는 것을 제외하고는 실시예 1 과 동일하게 사를 제조하였고, 제조된 나이론 원사의 물성 및 직물용 위사로 사용하였을때의 가공품위는 표 1 과 같았다.The yarns were manufactured in the same manner as in Example 1 except that the upper and lower oiling rollers (4) and (5) were provided with an emulsion of 8.0 to 9.0%, and used as the physical properties of the nylon yarn and the weft for the fabric. The processed product was as in Table 1.
실시예 3Example 3
구멍의 개수가 48개이고, 방사구금(1)직하 2m되는 지점에 제트오일링(Jet-Oiling)장치를 취부하여 유제부여 장치를 1개 더 추가한 것을 제외하고는 실시예 1 과 동일하게 사를 제조하였고, 제조된 나이론 원사의 물성 및 직물용 위사로 사용하였을때의 가공품위는 표 1 과 같았다.The number of holes is 48, and the jet oiling device is installed at the point 2m directly below the spinneret 1, and one more oil emulsifying device is added. It was prepared, the physical properties of the nylon yarn and the processed product when used as a weft for the fabric was shown in Table 1.
비교예 1Comparative Example 1
연신비가 1.03 ∼ 1.10인 것을 제외하고는 실시예 1 과 동일하게 사를 제조하였고, 제조된 나이론 원사의 물성 및 직물용 위사로 사용하였을때의 가공품위는 표 1 과 같았다.Except for the draw ratio is 1.03 to 1.10 except that the yarn was prepared in the same manner as in Example 1, the physical properties of the nylon yarn and the processed product when used as a weft for the fabric was as Table 1.
비교예 2Comparative Example 2
연신비가 1.03 ∼ 1.10, 상단 오일링로울러(4)에서 2.0 ∼ 4.0%의 유제를 부여하는 것을 제외하고는 실시예 1 과 동일하게 사를 제조하였고, 제조된 나이론 원사의 물성 및 직물용 위사로 사용하였을때의 가공품위는 표 1 과 같았다.The yarn was manufactured in the same manner as in Example 1 except that the draw ratio was 1.03 to 1.10, and the upper oil ring roller gave an emulsion of 2.0 to 4.0%. The nylon yarn was used as a physical property and a weft for the fabric. The processed product was as in Table 1.
단, 1) 수축율은 비수수축율(BWS)임.1) Shrinkage rate is non-shrinkage rate (BWS).
2) 가공품위는 아래와 같이 평가하였음.2) The processed product was evaluated as follows.
· W2 - W3' ; 어느것이든 코팅가능(직물의 결점이 거의 없는 상태)W2-W3 '; Any coating is possible (with few defects of fabric)
· W3' ; 제한된 용도로 코팅가능(직물의 결점이 일부있으나 전반적W3 '; Can be coated for a limited use (some fabric defects but overall
으로 양호한 상태)In good condition)
· 불단 ; 직물의 결점이 너무 심해서 사용이 불가능한 상태Buddhist altar; The fabric is too bad to be used
본 발명으로 제조된 나이론 원사는 통상적인 POY공법으로 생산된 기존의 원사에 비하여 고강도 및 저신도이므로 직물의 위사로 사용할 때 위사방향의 결점, 즉 위근을 발생시키지 않았으며 권취시 많은 릴렉스를 부여하였으므로 지연수축에 의한 문제점도 발생되지 않았다.Since the nylon yarn manufactured by the present invention has high strength and low elongation compared to conventional yarns produced by the conventional POY method, it does not generate a defect in the weft direction, that is, the gastrocnemius when it is used as the weft of the fabric, and gives a lot of relaxation when winding up. There was no problem caused by delayed contraction.
본 발명으로 제조된 나이론원사는 210데니어/34 ∼ 48필라멘트(단사섬도 4 ∼ 6데니어)사로서, 강도가 4.6 ∼ 4.96g/d, 신도가 55 ∼ 60%이고 수축율은 7 ∼10%이었다.The nylon yarn produced by the present invention was 210 denier / 34 to 48 filament (single yarn fineness of 4 to 6 denier) yarn, the strength was 4.6 to 4.96 g / d, the elongation was 55 to 60%, and the shrinkage was 7 to 10%.
도 1 은 본 발명의 공정개략도1 is a process schematic diagram of the present invention
< 도면의 주요부분에 대한 부호설명 ><Explanation of Signs of Major Parts of Drawings>
1 : 방사구금, 2 : 필라멘트, 3 : 냉각풍 공급장치,1: spinneret, 2: filament, 3: cooling wind supply device,
4 : 상단 오일링로울러, 5 : 하단 오일링로울러, 6 : 제 1 고뎃로울러,4: upper oil ring roller, 5: lower oil ring roller, 6: 1st high roller,
7 : 제 2 고뎃로울러, 8 : 권취로울러7: 2nd roller, 8: winding roller
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KR10-1998-0052159A KR100505503B1 (en) | 1998-12-01 | 1998-12-01 | Manufacturing method of gastric nylon Taesodo company by Piowai method |
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KR10-1998-0052159A KR100505503B1 (en) | 1998-12-01 | 1998-12-01 | Manufacturing method of gastric nylon Taesodo company by Piowai method |
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KR20000037545A KR20000037545A (en) | 2000-07-05 |
KR100505503B1 true KR100505503B1 (en) | 2005-11-30 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101371386B1 (en) | 2012-03-06 | 2014-03-07 | 주식회사 다운나라 | Method of manufacturing thick-denier fiber |
Families Citing this family (1)
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CN104018242B (en) * | 2014-04-23 | 2016-05-25 | 浙江方圆聚合纤有限公司 | The preparation method of polyamide fibre 6 ultra micro fine denier POY long filaments |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR920008963A (en) * | 1990-10-30 | 1992-05-28 | 김광호 | Channel Doping Method of MOS Transistor |
JPH07216642A (en) * | 1994-01-20 | 1995-08-15 | Unitika Ltd | Method for direct spinning and drawing of nylon 6 yarn |
KR970043363A (en) * | 1995-12-27 | 1997-07-26 | 백영배 | Manufacturing method of high-density 210 denier nylon yarn by high-speed spinning method |
KR0174309B1 (en) * | 1995-12-21 | 1999-02-18 | 백영배 | High speed spinning method of large fineness nylon |
KR20000025049A (en) * | 1998-10-08 | 2000-05-06 | 구광시 | Method for producing drawn yarn of nylon filament |
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1998
- 1998-12-01 KR KR10-1998-0052159A patent/KR100505503B1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR920008963A (en) * | 1990-10-30 | 1992-05-28 | 김광호 | Channel Doping Method of MOS Transistor |
JPH07216642A (en) * | 1994-01-20 | 1995-08-15 | Unitika Ltd | Method for direct spinning and drawing of nylon 6 yarn |
KR0174309B1 (en) * | 1995-12-21 | 1999-02-18 | 백영배 | High speed spinning method of large fineness nylon |
KR970043363A (en) * | 1995-12-27 | 1997-07-26 | 백영배 | Manufacturing method of high-density 210 denier nylon yarn by high-speed spinning method |
KR20000025049A (en) * | 1998-10-08 | 2000-05-06 | 구광시 | Method for producing drawn yarn of nylon filament |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101371386B1 (en) | 2012-03-06 | 2014-03-07 | 주식회사 다운나라 | Method of manufacturing thick-denier fiber |
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