KR100499588B1 - Aromatic controlling exhalation, strength and duration of fragrance using a catalytic action - Google Patents
Aromatic controlling exhalation, strength and duration of fragrance using a catalytic action Download PDFInfo
- Publication number
- KR100499588B1 KR100499588B1 KR10-2002-0029615A KR20020029615A KR100499588B1 KR 100499588 B1 KR100499588 B1 KR 100499588B1 KR 20020029615 A KR20020029615 A KR 20020029615A KR 100499588 B1 KR100499588 B1 KR 100499588B1
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- South Korea
- Prior art keywords
- fragrance
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- parts
- photocatalyst
- microcapsule
- Prior art date
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- 239000003205 fragrance Substances 0.000 title claims abstract description 56
- 125000003118 aryl group Chemical group 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000003094 microcapsule Substances 0.000 claims abstract description 24
- 239000011941 photocatalyst Substances 0.000 claims abstract description 20
- 239000011973 solid acid Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 9
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000002304 perfume Substances 0.000 claims abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000796 flavoring agent Substances 0.000 claims description 8
- 235000019634 flavors Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 244000246386 Mentha pulegium Species 0.000 description 3
- 235000016257 Mentha pulegium Nutrition 0.000 description 3
- 235000004357 Mentha x piperita Nutrition 0.000 description 3
- 235000001050 hortel pimenta Nutrition 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 238000013032 photocatalytic reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000000222 aromatherapy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- -1 ganbanite Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/18—Radiation
- A61L9/20—Ultraviolet radiation
- A61L9/205—Ultraviolet radiation using a photocatalyst or photosensitiser
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Catalysts (AREA)
Abstract
본 발명은 향기의 발산속도 및 강도의 조절이 가능한 향료에 관한 것으로, 더욱 상세하게는 기준이 되는 물과, 마이크로 캡슐향, 빛에 의한 촉매로서 기능을 나타내는 광촉매제, 조절 가능한 Ho 산성도 함수를 가지며 산으로서 기능을 하는 고체산을 비롯하여 계면활성제와, 실리콘 충진제, 우레탄수지를 함유하는 향료 조성물로서, 향기가 일정하면서도 지속적으로 분해되도록 하여 향기의 발산속도 및 강도의 조정이 인위적으로 이루어질 수 있고, 향기가 분무되는 장소 및 시간, 그리고 지속시간이 감안되어 이용의 편리성이 증가되면서 그 활용도 역시 극대화되도록 된 향료에 관한 것이다.The present invention relates to a perfume that can control the rate and intensity of the fragrance, and more particularly, has a water, a microcapsule, a photocatalyst which functions as a catalyst by light, and an adjustable Ho acidity function. A fragrance composition containing a solid acid, which functions as an acid, and a surfactant, a silicone filler, and a urethane resin, wherein the fragrance is continuously and continuously decomposed to adjust the rate and intensity of fragrance artificially. It is related to the fragrance that is maximized as the convenience of use is increased in consideration of the place and time and the duration of spraying.
Description
본 발명은 향료에 관한 것으로서, 보다 상세하게는 마이크로 캡슐향이 포함되는 향료에 빛에 의한 촉매로서 기능을 나타내는 광촉매제 및, 일정한 Ho 값을 가지며 산으로서 기능을 하는 고체산을 비롯하여 계면활성제, 실리콘 충진제, 우레탄수지를 첨가하여 지속적인 향기의 발산속도, 시간 및 강도 조절이 인위적으로 가능하도록 된 향료에 관한 것이다.The present invention relates to a fragrance, and more particularly, a photocatalyst which functions as a catalyst by light to a fragrance containing microcapsule and a solid acid having a constant Ho value and functions as an acid, and a surfactant and a silicone filler. The present invention relates to a perfume that is artificially enabled to control the rate, time and intensity of the continuous fragrance by adding urethane resin.
일반적으로 향기란 악취와 같은 휘발성 화합물이지만 악취와는 다른 구조와 기능기로 구성되어, 꽃이나 향수로부터 발산되는 좋은 냄새를 말한다. 이러한 향기는 단순히 악취를 중화하여 제거하거나 방향제로서 이용되어 오면서 현대에 이르러서는 아로마테라피(Aroma therapy)라는 개념이 확립되어 향기를 인체의 각종 질병 및 스프레스 치료에 활용하기에 이르렀다.In general, fragrance is a volatile compound such as malodor, but is composed of a structure and a functional group different from malodor, and refers to a good smell emitted from a flower or perfume. These fragrances have simply been neutralized to remove odors or used as fragrances, and in modern times, the concept of aroma therapy has been established, and the fragrance has been used to treat various diseases and stresses of the human body.
그러나, 일반에 유통되어 분무 또는 분사되어 이용되고 있는 향기는 그 지속시간이 짧을 뿐만 아니라, 향기의 강도 역시 시간의 경과에 따라 현저히 저하되기 때문에 이용에 있어 빈번한 분무 또는 분사를 하여야 하는 문제점이 있었다.However, the fragrance that is distributed and sprayed or sprayed in general is not only short in duration, but also has a problem of frequent spraying or spraying in use since the intensity of the fragrance is significantly lowered over time.
특히, 인위적으로 제조된 조화(造花)의 경우 제조 기술이 발전하면서 색상과 느낌이 거의 자연상태의 것과 흡사하게 되었고, 이러한 조화에 향기가 분무되어 더욱 더 자연의 상태를 모방하기에 이르렀지만, 향기의 발산(發散) 역시 단시간에 휘발되어 짧은 간격으로 재 분무를 해주어야 하는 불편함이 있었다. In the case of artificially manufactured artificial flowers, in particular, with the development of the manufacturing technology, the color and the feeling are almost similar to those of the natural state, and the fragrance was sprayed on the artificial flower to imitate the natural state. The divergence of was also volatilized in a short time, there was an inconvenience to re-spray at short intervals.
또한, 일반적으로 향료에는 향의 발산을 지속시키기 위해 마찰 또는 기타 사유에 의해 분해되는 마이크로 캡슐향이 이용되고 있으며, 이를 이용하여 향기의 발산시간이 장시간 유지되도록 하고는 있지만, 상기 마이크로 캡슐향은 앞서 언급한 바와 같이, 마찰이나 다른 인위적 작용에 의해 분해시켜야만 향기가 효과적으로 발산되는 이유로 발산의 시간 및 강도의 조절이 불가능하다는 다른 문제점도 있었다.In addition, in order to sustain the fragrance of the fragrance is generally used microcapsule which is decomposed by friction or other reasons, by using it to maintain the divergence time of the fragrance for a long time, the microcapsule fragrance is mentioned above As described above, there is another problem that it is impossible to control the time and intensity of the shedding because the fragrance is effectively released only by decomposition or other artificial action.
이에 본 발명은 상기와 같은 문제점을 감안하여 안출된 것으로, 마이크로 캡슐향의 분해를 빛에 의한 산화반응으로 조절하는 광촉매제와, 마이크로 캡슐 표면을 적당한 산의 강도조절에 의해 부식 또는 분해시킬 수 있는 고체산이 향기의 발산속도, 시간 및 강도조절이 가능하다는 기본적인 사상을 토대로, 향료에 포함되는 마이크로 캡슐향의 표면을 용도에 따라 산화하여 분해하기 위해 광촉매제와 고체산이 적정한 배합으로 첨가되도록 하여 마이크로 캡슐향이 일정한 분해속도를 유지하게 하고, 그 결과 향기의 발산되는 속도 및 강도, 그리고 지속시간의 조절이 가능한 향료를 제공하는데 그 목적이 있다.Accordingly, the present invention has been made in view of the above problems, and the photocatalyst which controls the decomposition of the microcapsule fragrance by the oxidation reaction by light, and the surface of the microcapsule can be corroded or decomposed by the appropriate acid strength control. Based on the basic idea that the solid acid can control the rate, time and intensity of fragrance, the microcapsule is added in an appropriate combination so that the photocatalyst and the solid acid are added in order to oxidize and decompose the surface of the microcapsule flavor included in the perfume according to the use. The purpose is to provide a fragrance capable of maintaining a constant rate of decomposition and, as a result, controlling the rate and intensity of the fragrance and duration.
상기와 같은 목적을 달성하기 위한 본 발명은, 마이크로 캡슐향이 포함되는 향료에 있어서, 상기 향료에는 마이크로 캡슐향이 집적된 상태에서는 물론 분무된 상태에서도 지속적으로 분해되도록 광촉매제와 고체산이 포함되어 이루어져 향기의 발산속도 및 강도조절이 가능하게 된다.The present invention for achieving the above object, in the fragrance containing microcapsule flavor, the fragrance is composed of a photocatalyst and a solid acid so as to continuously decompose in the sprayed state as well as the microcapsule agglomerate of the fragrance It is possible to control the divergence rate and intensity.
상기 향료는 물 100 중량부를 기준으로하여 a)마이크로 캡슐향이 1∼100 중량부, b) 광촉매제가 0.0001∼5 중량부, c) Ho가 -3∼-16인 고체산이 0.0001∼5 중량붕) 계면활성제가 0.1∼1.5 중량부, e) 실리콘 충진제 0.5∼5중량부, f) 우레탄수지 20∼100 중량부가 적절한 배합으로 이루어지고, 상기 성분들의 상호 혼합 배합율에 따라 향기의 발산속도, 강도 및 지속시간에 대한 인위적 조작이 가능하게된다.The fragrance is based on 100 parts by weight of water a) 1 to 100 parts by weight of microcapsule, b) 0.0001 to 5 parts by weight of photocatalyst, c) 0.0001 to 5 parts by weight of solid acid with Ho of -3 to 16). 0.1 to 1.5 parts by weight of active agent, e) 0.5 to 5 parts by weight of silicone filler, and f) 20 to 100 parts by weight of urethane resin, and the rate, intensity and duration of fragrance of the fragrance according to the blending ratio of the above components. Artificial manipulations are made possible.
상기 광촉매제는 산화티탄, 산화지르코늄, 산화아연, 산화바나듐, 산화주석 중 단일개 또는 2이상 다수개가 포함되어 이루어지는 것을 특징으로 한다.The photocatalyst is characterized in that it comprises a single or two or more of titanium oxide, zirconium oxide, zinc oxide, vanadium oxide, tin oxide.
이하, 본 발명에 따른 향료를 상세히 설명한다.Hereinafter, the perfume according to the present invention will be described in detail.
본 발명에 의한 향료는 물과 마이크로 캡슐향을 비롯하여 광촉매제, 고체산, 계면활성제, 실리콘 충진제, 그리고 우레탄수지가 적절하게 배합(配合)되어 이루어진다.The fragrance according to the present invention is made up of water, microcapsule flavors, photocatalysts, solid acids, surfactants, silicone fillers, and urethane resins.
상기 광촉매제와 고체산은 상기 물과 혼합된 계면활성제, 실리콘 충진제, 우레탄수지, 마이크로 캡슐향 중 상기 마이크로 캡슐향을 분해하기 위한 외부환경으로 작용하면서 그 분해속도를 조정하기 위한 부가적 기능이 부여된 성분인 것이다.The photocatalyst and the solid acid are provided with an additional function for adjusting the decomposition rate while acting as an external environment for decomposing the microcapsule flavor among the surfactant, silicone filler, urethane resin, and microcapsule flavor mixed with the water. It is an ingredient.
상기 광촉매제는 빛을 흡수하여 화학적 반응이 일어나도록 도와주는 물질을 말하는데, 이것은 광조사(光照射) 하에서 산소나 물 등을 산화제로 하여 유독성 물질을 이산화탄소와 물로 완벽하게 산화시킨다. 또한, 다른 공정에 비하여 비교적 값싸고, 재생 가능한 에너지원과 화학적으로 유용한 물질을 얻을 수 있을 뿐만 아니라, 난분해성 유기물의 산화 분해 반응에 응용될 수 있는 새로운 방법으로서 인식되고 있다. 이러한 광촉매 반응공정은 다양한 무기화합물들을 보다 위험성이 적은 물질들로 바꾸어 처분과 재생이 용이하게 하고, 유독성 유기화합물을 완전히 분해하는데 이용되기도 한다. 일반적인 결과에 의하면, 산화물 반도체의 광촉매 반응에 대한 활성은 산화티탄 > 산화아연 > 산화지르코늄 > 산화주석 > 산화바나듐의 순으로 알려져 있다. 또한, 광촉매제에 의한 반응은 일반 항균제와는 달리 2차적으로 발생하는 독소도 모두 분해할 수 있는 살균, 항균, 탈취기능 및 물질표면에 부착될 수 있는 담배연기 및 기름찌꺼기, 유기불순물 등 여러 오염물질조차도 분해함으로써 특별한 세척을 필요로 하지 않는 반영구적인 오염방지기능까지 가지고 있다.The photocatalyst refers to a substance that absorbs light and helps a chemical reaction to occur, which completely oxidizes toxic substances into carbon dioxide and water using oxygen or water as an oxidizing agent under light irradiation. In addition, it is recognized as a novel method that can be applied to the oxidative decomposition reaction of hardly decomposable organic materials as well as obtain a relatively cheap, renewable energy source and chemically useful materials compared to other processes. The photocatalytic reaction process is used to convert various inorganic compounds into less dangerous substances, to facilitate disposal and regeneration, and to completely decompose toxic organic compounds. According to the general results, the activity for the photocatalytic reaction of the oxide semiconductor is known in the order of titanium oxide> zinc oxide> zirconium oxide> tin oxide> vanadium oxide. In addition, the reaction by the photocatalyst, unlike the general antibacterial agent, sterilization, antibacterial, deodorizing function that can decompose all secondary toxins, and smoke, oil residue, organic impurities, which can be attached to the surface of the substance. Even decomposition of the material has a semi-permanent anti-pollution function that does not require special cleaning.
한편, 고체산의 성질을 보면, 고체가 산성을 나타내는 이유는 액체와 동일하다. 대부분의 산화물 표면은 수산기(-OH)로 덮여 있으며, 이 수산기의 수소가 용이하게 떨어질 수 있으면 산으로의 특성을 보이는 것이다. 양성자를 방출해 줄 수 있는 물질뿐만 아니라 비공유 전자쌍을 받을 수 있는 자리(Site)를 가진 물질도 산성을 나타낸다. 복합산화물이 산성을 보이는 것은 구성원소의 전하 불균형과 관련이 있다. 이러한 설명은 어느 산화물에서나 만족되는 것은 아니나, 복합산화물의 경우에는 타당하게 받아들여지고 있다. 고체산의 산성으로의 특성을 정량적으로 나타내기 위해 또는 산촉매 반응에서의 활성이나 선택성과 관련을 짓기 위해서는 산으로서의 강도와 이에 해당하는 산점의 양을 알아야 한다. 이를 '산성도(Acidity)'라고 한다. 고체 표면의 산 강도를 비교하는 가장 보편적인 기준은 중성 염기에 양성자를 주어 이를 산으로 전화시키는 정도이다. 이 과정은 표면의 산점으로부터 흡착된 중성염기에 양성자가 전달되는 반응으로 볼 수 있는데, 이는 산점에 흡착된 중성염기가 산점으로부터 양성자를 받아들이는 반응이며 반응의 진행 정도가 산점의 세기를 나타낸다. 이러한 산점의 세기를 정량적으로 나타낼 때 가장 보편적으로 쓰이는 것은 Hammet 산성도 함수(Ho)이다.On the other hand, in view of the properties of the solid acid, the reason why the solid is acidic is the same as that of the liquid. Most of the oxide surface is covered with hydroxyl (-OH), and if the hydrogen of this hydroxyl can easily fall, it is characterized by acid. In addition to materials that can release protons, materials that have sites that can accept lone pairs are acidic. The acidity of complex oxides is associated with charge imbalances in the elements. This description is not satisfactory in any oxide, but in the case of a composite oxide, it is reasonably accepted. In order to quantitatively characterize the acidity of a solid acid or to associate it with activity or selectivity in an acid catalyst reaction, the strength as an acid and the amount of acid point corresponding thereto must be known. This is called 'Acidity'. The most common criterion for comparing the acid strength of solid surfaces is the degree of protonation of neutral bases and their conversion into acids. This process can be seen as a reaction in which protons are transferred to the neutral base adsorbed from the acidic point on the surface, which is the reaction of the neutral base adsorbed to the acidic point to accept the protons from the acidic point. The most commonly used quantitative representation of these scatter points is the Hammet acidity function (Ho).
상기에 언급된 각 성분들 간의 성분비율을 자세히 설명하자면, 중량부 100의 물을 기준으로 하여 산화티탄, 산화지르코늄, 산화아연, 산화바나듐, 산화주석 등의 일부 또는 전부를 포함하는 광촉매제 0.0001∼5 중량부와, Ho가 -3∼-16이고, 대한민국 특허출원 제2001-0067887호에 개시된 제올라이트, 맥반석, 옥, 벤토나이트, 카올린, 몬모리로나이트 등의 점토, 광물류 및 실리카, 활성탄 등의 흡착제류를 지지체로 하여 황산, 인산, 불화수소, 탄화불소화합물, 황산암모늄 및 헤테로폴리하합물 등으로 처리한 것을 특징으로 하는 고체산 0.0001∼5 중량부, 여기서 계면활성제가 0.1∼1.5 중량부, 실리콘 충진제 0.5∼5 중량부, 우레탄수지 20∼100중량부가 적절하게 배합되어 제조된다. To describe the component ratio between the above-mentioned components in detail, the photocatalyst including a part or all of titanium oxide, zirconium oxide, zinc oxide, vanadium oxide, tin oxide, etc. based on 100 parts by weight of water 0.0001 to 5 parts by weight, and Ho, -3 to -16, and the adsorbents of clays, minerals such as zeolite, ganban stone, jade, bentonite, kaolin and montmorillonite disclosed in Korean Patent Application No. 2001-0067887 As a support, 0.0001 to 5 parts by weight of a solid acid, wherein 0.1 to 1.5 parts by weight of a surfactant, and a silicone filler are treated with sulfuric acid, phosphoric acid, hydrogen fluoride, fluorocarbon compounds, ammonium sulfate and heteropolypolymers. 0.5-5 weight part and 20-100 weight part of urethane resins are mix | blended suitably, and it is manufactured.
여기에서 상기 광촉매제는 태양광이나 형광등에서 방출되는 자외선/가시광선 영역의 파장을 이용하며, 상기 고체산은 본 출원인이 출원한 대한민국 특허출원 제2001-0067887호에 개시된 물질을 근간으로 하며 자체의 산 강도를 조절하여 사용된다. Here, the photocatalyst uses a wavelength in the ultraviolet / visible light region emitted from sunlight or fluorescent light, and the solid acid is based on a material disclosed in Korean Patent Application No. 2001-0067887 filed by the present applicant, and has its own acid. Used to adjust the intensity.
상기 화학식에서 A는 티탄, 아연, 지르코늄, 바나듐, 텅스템 및 세륨 중에서 선택된 1종 이상의 원소이고; D는 철, 주석, 바나듐, 크롬, 알루미늄, 은, 구리, 몰리브덴, 안티몬, 니오브 및 실리콘 중에서 선택된 1종 이상의 원소이고; E는 황산, 인산, 붕산, 불화수소, 황산암모늄, 탄화불소화합물 및 헤테로폴리화합물 중에서 선택된 1종 이상의 화합물이고; a, d 및 e는 각 성분원소의 몰비를 나타낸 것으로 a/(d+e)는 0.001∼100이고, 이때 d는 0∼1의 범위이며; e는 0∼1의 범위이며; a≥0의 값이며; y/z > 0; x는 원자가를 맞추기 위해 정해지는 값이다. 또한, 상기 지지체는 제올라이트, 맥반석, 옥, 벤토나이트, 카올린, 몬모리로나이트 등의 점토, 광물류 및 실리카, 활성탄 등의 흡착제류이다.A in the formula is at least one element selected from titanium, zinc, zirconium, vanadium, tungstem and cerium; D is at least one element selected from iron, tin, vanadium, chromium, aluminum, silver, copper, molybdenum, antimony, niobium and silicon; E is at least one compound selected from sulfuric acid, phosphoric acid, boric acid, hydrogen fluoride, ammonium sulfate, fluorocarbon compounds and heteropoly compounds; a, d and e represent the molar ratios of the respective element elements, where a / (d + e) is 0.001 to 100, where d is in the range of 0 to 1; e is in the range of 0 to 1; a value of a ≧ 0; y / z> 0; x is a value determined to fit the valence. In addition, the support is clay, minerals such as zeolite, ganbanite, jade, bentonite, kaolin, montmorillonite, and adsorbents such as silica and activated carbon.
여기서, 상기 고체산은 Ho -3∼-16 정도 범위에서 이용되며, 본 발명에서는 Ho가 -3∼-12가 이용됨이 가장 바람직하다. 또한, 상기 고체산은 자외선/가시광선을 이용한 광촉매제의 기능이 현저히 격감되는 실내에서 상기 마이크로 캡슐향을 분해하는 외부환경을 조성하게 된다.Herein, the solid acid is used in the range of about Ho -3 to -16, and in the present invention, it is most preferable that Ho is -3 to -12. In addition, the solid acid creates an external environment that decomposes the microcapsule fragrance in a room where the function of the photocatalyst using ultraviolet rays / visible rays is significantly reduced.
이와 같이, 상기 언급된 각 성분들이 정해진 중량부에 의거 적절히 배합되어 분사 또는 분무되면 상기 마이크로 캡슐향에 내재된 향기의 발산(發散)속도 및 향기의 지속시간이 인위적으로 조작된, 즉 이용자의 요구와 용도에 충족하는 향료를 제공할 수 있게 된다.As such, when each of the above-mentioned components are properly blended and sprayed or sprayed based on a predetermined weight part, the rate of emission and duration of fragrance inherent in the microcapsule are artificially manipulated, that is, the user's request. And it will be possible to provide a fragrance to meet the purpose.
상기 각 성분들이 조합된 향료에 대한 이해를 용이하기 위한 성분 배합이 표 1, 2에 실시 예로 제시되어 있고, 그에 따른 결과가 다음과 같다. 여기에서 상기 마이크로 캡슐향에는 박하향기가 내재되었다.In order to facilitate understanding of the fragrance combined with each of the components is shown in Tables 1 and 2 as an example, the results are as follows. Herein, the microcapsule has a peppermint scent.
표 1Table 1
표 1에서의 각 성분이 배합된 향료가 분사 또는 분무되면 은은한 강도의 박하향기가 90일 이상 발산시간을 보유하게 되었고, When the fragrance blended with each ingredient in Table 1 is sprayed or sprayed, the peppermint fragrance with a gentle strength has a divergence time of 90 days or more.
표 2TABLE 2
표 2에서 보는 바와 같이, 각 성분이 배합된 향료가 분사 또는 분무되면 강한 강도의 박하향기가 30일 이상 발산시간을 보유하는 결과를 얻게 되었다. As shown in Table 2, when the fragrance in which each component is blended is sprayed or sprayed, the result is that a strong strength peppermint fragrance has a divergence time of 30 days or more.
상기에서 언급된 표 1과 표 2의 실험 예는 본 고안에 의한 향료의 성분 배합비율에 따른 향기의 강도와 발산시간을 제공하여 본 발명의 이해를 돕고자 한 것으로, 각 성분들 간의 배합은 향의 강도와 발산시간을 사용장소와 시간 및 날씨에 따라 적당한 향료가 사용될 수 있도록 자유로이 변경시킬 수 있으므로 상기의 예에 한정되는 것은 아니다. Experimental examples of Table 1 and Table 2 mentioned above are intended to help the understanding of the present invention by providing the strength and divergence time of the fragrance according to the ingredient ratio of the fragrance according to the present invention, the formulation between each component is fragrance It is not limited to the above example because the intensity and the divergence time of the can be changed freely so that a suitable fragrance can be used according to the use place and time and weather.
상기와 같이 구성된 본 발명에 따르면, 마이크로 캡슐향이 포함되는 향료에 광촉매제와 고체산이 부가 배합되어 상기 향료가 분무된 상태에서 마이크로 캡슐향이 일정하면서도 지속적으로 분해되도록 하여 향기의 발산속도 및 강도, 시간의 조절이 조정이 인위적으로 이루어질 수 있고, 향기가 분무되는 장소와 시간, 그리고 향기의 지속시간이 감안되어 이용의 편리성이 증가되면서 그 활용도 역시 극대화되는 효과가 있다.According to the present invention configured as described above, the photocatalyst and the solid acid are added to the fragrance containing the microcapsule fragrance so that the microcapsule fragrance is constantly and continuously decomposed in the sprayed state of the fragrance so that the fragrance rate, intensity and time of the fragrance The adjustment can be artificially made, the location and time the fragrance is sprayed, and the duration of the fragrance in consideration of the convenience of use is increased, the utilization is also maximized.
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JPH0252661A (en) * | 1988-08-12 | 1990-02-22 | Tokyo Houraishiya:Kk | Marking material having deodorant or deodorant exhalation function |
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