KR100494585B1 - Coating composition for steering wheel of automobile - Google Patents

Coating composition for steering wheel of automobile Download PDF

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KR100494585B1
KR100494585B1 KR10-2002-0046923A KR20020046923A KR100494585B1 KR 100494585 B1 KR100494585 B1 KR 100494585B1 KR 20020046923 A KR20020046923 A KR 20020046923A KR 100494585 B1 KR100494585 B1 KR 100494585B1
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weight
steering wheel
parts
coating composition
fine powder
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KR10-2002-0046923A
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Korean (ko)
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KR20040013836A (en
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정은영
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현대자동차주식회사
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2262Oxides; Hydroxides of metals of manganese
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)

Abstract

본 발명은 자동차의 스티어링 휠용 도료 조성물에 관한 것으로서, 특히 기존에 스티어링 휠에 사용된 우레탄 도료에 고경도 재료인 가넷 미세분말과 각종 첨가제를 함유시킴으로써, 기존의 도료 조성물에 비해 마찰 계수가 높기 때문에 운전 시, 운전자의 손과 스티어링 휠 표층 사이의 마찰력을 증가시켜 미끄럼을 방지할 수 있는 새로운 자동차의 스티어링 휠용 도료 조성물에 관한 것이다. The present invention relates to a coating composition for a steering wheel of an automobile, and in particular, by containing a high-hardness garnet fine powder and various additives in a urethane coating conventionally used in a steering wheel, the driving coefficient is higher than that of a conventional coating composition. The present invention relates to a coating composition for a steering wheel of a new vehicle, which can prevent slippage by increasing friction between the driver's hand and the steering wheel surface layer.

Description

자동차의 스티어링 휠용 도료 조성물{Coating composition for steering wheel of automobile} Coating composition for steering wheel of automobile

본 발명은 자동차의 스티어링 휠용 도료 조성물에 관한 것으로서, 더욱 상세하게는 기존의 스티어링 휠에 적용되었던 우레탄 도료에 고경도 재료인 가넷 미세분말과 각종 첨가제를 함유시킴으로써, 기존의 도료 조성물에 비해 마찰 계수가 높기 때문에 운전 시, 운전자의 손과 스티어링 휠 표층 사이의 마찰력을 증가시켜 미끄럼을 방지할 수 있도록 개선된 자동차의 스티어링 휠용 도료 조성물에 관한 것이다. The present invention relates to a coating composition for a steering wheel of an automobile, and more particularly, by containing a high-hardness garnet fine powder and various additives in a urethane coating applied to a conventional steering wheel, a friction coefficient is higher than that of a conventional coating composition. It relates to a coating composition for a steering wheel of a vehicle, which is improved to prevent slipping by increasing friction between the driver's hand and the steering wheel surface layer when driving.

일반적으로, 스티어링 장치(steering system)란 자동차의 진행 방향을 변경하기 위해 사용되는 장치로 스티어링 휠, 스티어링 축 및 컬럼 등으로 이루어진 조작기구, 워엄 섹터형, 워엄 섹터롤러형, 볼너트형, 가변 기어비형, 래크 피니언형 등의 스티어링 기어기구 및 피트먼 아암, 스티어링 링크, 스티어링 너클 등으로 이루어진 링크기구로 구성되어 스티어링 휠의 회전을 스티어링 기어를 통하여 구동휠로 전달하는 기계식의 스티어링 장치와, 조작력 경감을 위하여 동력 실린더를 사용하는 파워 스티어링(Power Steering)방식이 사용되고 있다.In general, a steering system is a device used to change the direction of travel of a vehicle. An operating mechanism consisting of a steering wheel, a steering shaft, and a column, a worm sector type, a worm sector roller type, a ball nut type, and a variable gear ratio Mechanical steering device which consists of steering gear mechanisms such as type and rack pinion type, and link mechanisms composed of Pitman arm, steering link, steering knuckle, etc. to transmit the rotation of the steering wheel to the driving wheel through the steering gear, and to reduce operation force For this purpose, a power steering method using a power cylinder is used.

여기서, 상기 스티어링 휠(10)은 도 2에 도시된 바와 같이, 단면을 기준으로 내부에는 보강재로서, 탄소강재(STKM)로 된 파이프(11)가 있으며, 그 위에 운전자의 촉감 향상용으로 우레탄 및 PVC foam재(12)가 덮고 있다. Here, as shown in Figure 2, the steering wheel 10, as a reinforcement on the basis of the cross section, there is a pipe 11 made of carbon steel (STKM), thereon urethane and for improving the driver's touch The PVC foam material 12 is covered.

이러한 우레탄 혹은 PVC 경화 시, 가장 바깥 부분이 열에 의해 우레탄 및 PVC표층(13)을 형성하며, 현재 주위부품과의 색상 조화를 위하여 주변 부품과 동일한 색상을 우레탄 및 PVC표층(13)위에 도장을 하고 있다. When the urethane or PVC is cured, the outermost part forms the urethane and PVC surface layer 13 by heat, and paints the same color on the urethane and PVC surface layer 13 as the peripheral parts for color harmony with the current peripheral parts. have.

종래의 스티어링 휠은 우레탄 및 PVC 표층에 단순히 외관미의 향상 및 주변과의 색상조화를 위하여 2액형 우레탄 도장을 하고 있다.    Conventional steering wheel has a two-component urethane coating on the urethane and PVC surface layer simply to improve the appearance and color coordination with the surroundings.

이러한 도장면을 가진 스티어링 휠은 운전자의 땀이나 습기로 인하여 미끄럼을 발생시키기 쉬우며, 특히 경질 PVC를 휠의 재료로 적용할 시에는 이런 문제점이 더욱 부각된다. The steering wheel having such a painted surface is easy to generate slip due to sweat or moisture of the driver, especially when the rigid PVC is applied as the material of the wheel.

일부 차종에서는 외관미의 향상과 미끄럼을 방지하기 위하여 표층에 미세한 엠보싱 처리를 하기도 하지만, 이 자체가 재료의 마찰력을 증대시켜 주기에는 한계가 있는 문제점이 있다. In some models, fine embossing is applied to the surface layer in order to improve appearance and prevent slippage, but there is a problem in that it increases the frictional force of the material.

이런 이유로인해 운전 시, 상기 스티어링 휠의 미끄러짐은 운전자를 포함한 승객의 생명 및 재산에도 직결되는 중요한 문제이므로 이에 따른 개선이 시급한 실정이다.For this reason, when driving, the sliding of the steering wheel is an important problem directly related to the life and property of passengers, including the driver, and thus the urgent improvement is necessary.

따라서, 본 발명은 상기와 같은 문제점을 해결하기 위해 안출한 것으로서, 운전자의 손에 의한 마모를 방지할 수 있도록 하기 위해 고경도 재료이고 도장 후에 색상 변화가 없도록 입자의 크기가 일정 크기 이하로 미세하여야 하며, 마찰력을 증대시킬 수 있는 물성을 가지는 재질로서, 도장하고자 하는 도막의 두께에 대해 약 60% 크기의 입도를 가지는 입자가 전체 입자 중에 약 60% 이상 함유되어 있는 미세분말을 우레탄 도료에 첨가하게 되면 물성이 우수하고, 마찰력이 향상된다는 사실을 알게되어 본 발명을 완성하였다. Therefore, the present invention has been made to solve the above problems, in order to prevent wear by the hand of the driver is a high hardness material and the size of the particles should be fine to a certain size or less so that there is no color change after coating. In addition, it is a material having physical properties that can increase the frictional force, so that the particles having a particle size of about 60% with respect to the thickness of the coating film to be coated are added to the urethane paint with fine powder containing about 60% or more of the total particles. When the physical properties are excellent, the friction force is improved to complete the present invention.

따라서, 본 발명은 경도가 높고, 색상의 변화가 없으며, 마찰계수가 높아 미끄럼을 방지할 수 있는 자동차의 스티어링 휠용 도료 조성물을 제공하는데 그 목적이 있다. Accordingly, an object of the present invention is to provide a coating composition for a steering wheel of a vehicle that is high in hardness, no change in color, and high in friction, thereby preventing slippage.

이하, 상기와 같은 목적을 달성하기 위한 본 발명의 특징에 대해 설명하면 다음과 같다. Hereinafter, the features of the present invention for achieving the above object are as follows.

본 발명은 자동차의 스티어링 휠용 도료 조성물에 있어서, The present invention is a coating composition for a steering wheel of an automobile,

아크릴 수지 15~35 중량부, 가넷 미세분말 3~7 중량부, 경화제 5~15 중량부, 표면조정제 0.3~1.2 중량부, 분산제 1.5~2.5 중량부, 열안정제 1.2~2.5 중량부, 용제 40~80 중량부가 함유되어 있는 스티어링 휠용 도료 조성물을 특징으로 한다. 15 to 35 parts by weight of acrylic resin, 3 to 7 parts by weight of garnet fine powder, 5 to 15 parts by weight of hardener, 0.3 to 1.2 parts by weight of surface conditioner, 1.5 to 2.5 parts by weight of dispersant, 1.2 to 2.5 parts by weight of heat stabilizer, solvent 40 to It is characterized by a paint composition for a steering wheel containing 80 parts by weight.

특히, 본 발명에서 특징적으로 사용되는 상기 가넷 미세분말의 조성은 이산화규소(SiO2) 37.0±3.0중량%, 산화알루미늄(Al2O3) 20.0±4.0중량%, 산화제이철(Fe2O3) 31.5±5.0중량%, 이산화망간(MnO2) 0.1~2.0중량%, 산화마그네슘(MgO) 8.0±2.0중량%, 산화칼슘(CaO) 0.1~2.5중량%, 이산화티타늄(TiO2) 0.1~2.0중량%, 물(H2O) 0.1~0.2중량%인 것을 특징으로 한다.In particular, the composition of the garnet fine powder used in the present invention is 37.0 ± 3.0% by weight of silicon dioxide (SiO 2 ), 20.0 ± 4.0% by weight of aluminum oxide (Al 2 O 3 ), ferric oxide (Fe 2 O 3 ) 31.5 ± 5.0% by weight, manganese dioxide (MnO 2 ) 0.1-2.0% by weight, magnesium oxide (MgO) 8.0 ± 2.0% by weight, calcium oxide (CaO) 0.1-2.5% by weight, titanium dioxide (TiO 2 ) 0.1-2.0% by weight , Water (H 2 O) is characterized in that 0.1 to 0.2% by weight.

또한, 상기 가넷 미세분말은 경도가 8.5의 고경도 재료이고, 입자의 크기가 최대 7㎛이며, 평균 5㎛의 크기 이하로 미세하며, 마찰력을 증대시킬 수 있는 물성을 가질 수 있도록 도장하고자 하는 도막의 두께에 비해 60% 크기의 입도를 가진 입자가 전체 입자 중에 60% 이상 함유되어 있는 것을 특징으로 한다. In addition, the garnet fine powder is a material of high hardness of 8.5, the size of the particles up to 7㎛, fine to the size of less than 5㎛ average, the coating film to be painted to have a physical property to increase the friction force 60% or more of the particles having a particle size of 60% compared to the thickness of the total particles is characterized in that it is contained.

이하, 첨부도면을 참조하여 본 발명에 대해 상세하게 설명하면 다음과 같다. Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명에 따른 도료는 에폭시, 아크릴, 폴리에스테르 등 다른 유기물과 이소시아네이트의 2액형 우레탄 도료로 구성될 수 있는 바, 미세분말의 이탈, 도장면 자체의 균열, 노화를 방지하기 위해 반드시 어느 정도 이상의 인성을 확보할 수 있는 고가교 밀도의 도료를 선택해야 하며, 연필경도 기준(JIS K 5400)으로 모오스 경도 1H 이상의 경도를 가져야 한다. The paint according to the present invention may be composed of two-component urethane paint of isocyanate and other organic materials such as epoxy, acrylic, polyester, etc., to prevent the separation of fine powder, the cracking of the coating surface itself, and a certain degree of toughness. The high crosslinking density paint should be selected and the hardness should be more than 1H of Mohs hardness based on pencil hardness standard (JIS K 5400).

본 발명은 아크릴 수지 15~35 중량부, 가넷 미세분말 3~7 중량부, 경화제 5~15 중량부, 표면조정제 0.3~1.2 중량부, 분산제 1.5~2.5 중량부, 열안정제 1.2~2.5 중량부, 용제 40~80 중량부가 함유되어 있는 자동차의 스티어링 휠용 도료 조성물로써, 이때 미끄럼 방지를 위한 조성물로 사용되는 가넷 미세분말은 운전자의 손에 의한 마모를 방지할 수 있도록 모오스 경도가 8.5인 고경도 재료이고, 도장 후에 색상 변화가 없도록 입자의 크기가 최대 7㎛이며, 평균 5㎛의 크기 이하(분말의 90%이상)로 미세하여야 하며, 마찰력을 증대시킬 수 있는 물성을 가질 수 있도록 도장하고자 하는 도막의 두께 대비, 약 60%의 입도를 입자 내에 약 60% 이상 첨가하여 마찰력을 증대시켜 미끄럼을 방지할 수 있는 효과를 얻을 수 있다. The present invention is 15 to 35 parts by weight of acrylic resin, 3 to 7 parts by weight of garnet fine powder, 5 to 15 parts by weight of curing agent, 0.3 to 1.2 parts by weight of surface conditioner, 1.5 to 2.5 parts by weight of dispersant, 1.2 to 2.5 parts by weight of heat stabilizer, A paint composition for steering wheels of automobiles containing 40 to 80 parts by weight of solvent, wherein the garnet fine powder used as the anti-slip composition is a high hardness material having a MOS hardness of 8.5 to prevent wear by the driver's hand. The size of the particles should be up to 7㎛, so that there is no color change after painting, and should be fine below the average size of 5㎛ (90% or more of the powder), and have the properties to increase the frictional force. About 60% or more of the particle size compared to the thickness may be added in the particle to increase the frictional force, thereby preventing slippage.

본 발명에서 사용되는 가넷 미세분말의 입자 크기가 7㎛를 초과하면 가넷 고유의 색상인 자두색 빛이 남고, 도막 두께 대비, 완성 도막으로부터 입자 이탈에 의한 도막 손상이 유발되는 문제점이 있다. When the particle size of the garnet fine powder used in the present invention exceeds 7㎛, the purple light, which is a garnet inherent color, is left, and there is a problem in that the coating film is damaged due to particle detachment from the finished film in comparison with the coating film thickness.

가넷 분말은 고경도의 보석으로서, 브라운관의 연마제로 사용되는데, 본 발명에 따른 가넷 미세분말은 연마제 제조 후에 남은 부산물로 이용가능한 것이다.Garnet powder is a hard jewel, used as an abrasive of a CRT. The garnet fine powder according to the present invention can be used as a by-product remaining after the preparation of the abrasive.

색상은 덩어리로 존재 시, 자두빛을 띠나, 미세분말일수록 백색을 띤다. The color is purplish when present in lumps, but the finer the powder, the more white it is.

상기와 같은 특성을 가지는 가넷 미세분말을 3~7중량부를 도료 조성물에 첨가하는데, 이때 첨가량이 3 중량부 미만이면 마찰력 증대를 기대하기 어렵고, 첨가량이 7중량부를 초과하여 첨가할 시에는 도료내의 혼합이 어렵고, 미세분말 자체의 색상 발현으로 주위 부품과 색상 상이(相異)현상이 발생하여 적용하기가 어려워진다. 3 to 7 parts by weight of the garnet fine powder having the above characteristics is added to the coating composition, but when the addition amount is less than 3 parts by weight, it is difficult to expect an increase in frictional force, and when the addition amount is more than 7 parts by weight, it is mixed in the paint. This difficult and color development of the fine powder itself causes color differences with surrounding parts, making it difficult to apply.

한편, 이러한 가넷 미세분말의 조성은 이산화규소(SiO2) 37.0±3.0중량%, 산화알루미늄(Al2O3) 20.0±4.0중량%, 산화제이철(Fe2O3) 31.5±5.0중량%, 이산화망간(MnO2) 0.1~2.0중량%, 산화마그네슘(MgO) 8.0±2.0중량%, 산화칼슘(CaO) 0.1~2.5중량%, 이산화티타늄(TiO2) 0.1~2.0중량%, 물(H2O) 0.1~0.2중량%이다.Meanwhile, the composition of the garnet micropowder is 37.0 ± 3.0 wt% of silicon dioxide (SiO 2 ), 20.0 ± 4.0 wt% of aluminum oxide (Al 2 O 3 ), 31.5 ± 5.0 wt% of ferric oxide (Fe 2 O 3 ), manganese dioxide (MnO 2 ) 0.1-2.0 wt%, magnesium oxide (MgO) 8.0 ± 2.0 wt%, calcium oxide (CaO) 0.1-2.5 wt%, titanium dioxide (TiO 2 ) 0.1-2.0 wt%, water (H 2 O) 0.1-0.2 weight%.

이하, 본 발명을 실시예에 의거하여 더욱 상세하게 설명하겠는 바, 본 발명이 실시예에 의하여 한정되는 것은 아니다. Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited by Examples.

실시예Example

다음 표 1에 나타낸 구성성분으로 이루어진 도료 조성물을 통상의 도료를 만드는 방법으로 제조하였다. The coating composition consisting of the components shown in the following Table 1 was prepared by a method of making a conventional paint.

시험예Test Example

본 발명에 따른 스티어링 휠용 도료 조성물을 사용하여 약 70℃에서 경화하여 도막을 완성시킨 다음, 상기 도막에 대하여 물성 시험을 실시하였으며, 그 평가 방법은 다음과 같다. Using the coating composition for a steering wheel according to the present invention was cured at about 70 ℃ to complete the coating film, and then carried out a physical property test for the coating film, the evaluation method is as follows.

(1)경도(1) hardness

연필 경도기(JIS K 5400)를 이용한 방법으로 경도를 측정하였다.Hardness was measured by the method using the pencil hardness tester (JIS K 5400).

(2)60도(度) 광택(2) 60 degree gloss

BYK사(社) 글로스 미터(GLOSS METER)를 이용하여 광택을 측정하였다. Gloss was measured using a BYK Corporation gloss meter (GLOSS METER).

(3)부착성(3) adhesion

폭 2mm 바둑목(CROSS CUT)방법으로 부착성을 측정하였다. Adhesion was measured by a 2 mm wide cross cut method.

(4)내약품성(4) chemical resistance

염산 3% 혹은 황산 2% 용액을 도막에 떨어뜨려 도막의 침식 유무를 확인하는 방법으로 내약품성을 측정하였다. The chemical resistance was measured by dropping a 3% hydrochloric acid or 2% sulfuric acid solution onto the coating film to confirm the erosion of the coating film.

(5)색차(5) color difference

X-LIGHT사(社) 색차 시험기로 색차를 측정하였다. Color difference was measured by the X-LIGHT company color difference tester.

(6)내수성(6) water resistance

50℃ 이온수에 240시간 침적한 후, 외관 관찰 및 부착성을 평가하여 내수성을 측정하였다. After 240 hours of immersion in 50 ° C. ionized water, water resistance was measured by appearance observation and adhesion evaluation.

(7)마찰계수(7) Friction coefficient

도막을 300/300mm SHEET상으로 제작한 후, 평가하였다. The coating film was produced on 300/300 mm sheet, and evaluated.

그리고 나서, 상기 실험방법을 거쳐 도출된 물성 측정 결과를 표 2에 나타내었다. Then, the measurement results of the physical properties derived through the experimental method are shown in Table 2.

상기 표 2에 나타낸 바와 같이, 본 발명에 따라 제조된 실시예의 경우, 기존의 스티어링 휠 대비, 정지 마찰계수의 변화값이 0.2로 나타나서 그 값만큼의 미끄럼 방지를 예상할 수 있다. As shown in Table 2, in the case of the embodiment manufactured according to the present invention, the change value of the static friction coefficient compared to the conventional steering wheel is shown as 0.2, it can be expected to prevent the slip as much as that value.

상술한 바와 같이, 본 발명에 따른 자동차의 스티어링 휠용 도료 조성물은 운전 시, 스티어링 휠과, 손 또는 장갑면의 미끄럼을 방지할 수 있고, 첨가되는 가넷 미세분말은 연마제 제조 시에 공정상 남는 재료로서 저가의 재료이며, 고경도의 미세분말이므로 장기간의 내구성능을 지니는 효과가 있다. As described above, the coating composition for the steering wheel of the vehicle according to the present invention can prevent the sliding of the steering wheel, the hand or the glove surface during driving, and the added garnet fine powder is a material remaining in the process during the manufacture of the abrasive It is an inexpensive material and has a long-term durability since it is a high hardness fine powder.

도 1은 본 발명에 따른 자동차의 스티어링 휠을 나타내는 부분 종단면도이고,1 is a partial longitudinal cross-sectional view showing a steering wheel of a vehicle according to the present invention,

도 2는 종래의 자동차의 스티어링 휠을 나타내는 횡단면도이다. 2 is a cross-sectional view showing a steering wheel of a conventional vehicle.

〈도면의 주요 부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>

10 : 스티어링 휠 11 : 탄소강재 파이프10: steering wheel 11: carbon steel pipe

12 : 우레탄 및 PVC foam재 13 : 우레탄 및 PVC표층12: urethane and PVC foam material 13: urethane and PVC surface layer

Claims (3)

자동차의 스티어링 휠용 도료 조성물에 있어서, In the coating composition for a steering wheel of an automobile, 아크릴 수지 15~35 중량부, 가넷 미세분말 3~7 중량부, 경화제 5~15 중량부, 표면조정제 0.3~1.2 중량부, 분산제 1.5~2.5 중량부, 열안정제 1.2~2.5 중량부, 용제 40~80 중량부가 함유되어 있는 것을 특징으로 하는 자동차의 스티어링 휠용 도료 조성물.15 to 35 parts by weight of acrylic resin, 3 to 7 parts by weight of garnet fine powder, 5 to 15 parts by weight of hardener, 0.3 to 1.2 parts by weight of surface conditioner, 1.5 to 2.5 parts by weight of dispersant, 1.2 to 2.5 parts by weight of heat stabilizer, solvent 40 to A coating composition for a steering wheel of a vehicle, characterized in that it contains 80 parts by weight. 제1항에 있어서, 상기 가넷 미세분말의 조성은 이산화규소(SiO2) 37.0±3.0중량%, 산화알루미늄(Al2O3) 20.0±4.0중량%, 산화제이철(Fe2O3) 31.5±5.0중량%, 이산화망간(MnO2) 0.1~2.0중량%, 산화마그네슘(MgO) 8.0±2.0중량%, 산화칼슘(CaO) 0.1~2.5중량%, 이산화티타늄(TiO2) 0.1~2.0중량%, 물(H2O) 0.1~0.2중량%인 것을 특징으로 하는 자동차의 스티어링 휠용 도료 조성물.According to claim 1, wherein the composition of the garnet fine powder is silicon dioxide (SiO 2 ) 37.0 ± 3.0 wt%, aluminum oxide (Al 2 O 3 ) 20.0 ± 4.0 wt%, ferric oxide (Fe 2 O 3 ) 31.5 ± 5.0 Weight%, manganese dioxide (MnO 2 ) 0.1-2.0 weight%, magnesium oxide (MgO) 8.0 ± 2.0 weight%, calcium oxide (CaO) 0.1-2.5 weight%, titanium dioxide (TiO 2 ) 0.1-2.0 weight%, water ( H 2 O) Paint composition for steering wheel of the vehicle, characterized in that 0.1 to 0.2% by weight. 제1항 또는 제2항에 있어서, 상기 가넷 미세분말은 경도가 8.5의 고경도 재료이고, 입자의 크기가 최대 7㎛이며, 평균 5㎛의 크기 이하로 미세하며, 마찰력을 증대시킬 수 있는 물성을 가질 수 있도록 도장하고자 하는 도막의 두께에 비해 60% 크기의 입도를 가진 입자가 전체 입자 중에 60% 이상 함유되어 있는 것을 특징으로 하는 자동차의 스티어링 휠용 도료 조성물.According to claim 1 or claim 2, wherein the garnet fine powder is a high hardness material of 8.5, the particle size is up to 7㎛, fine to less than the average size of 5㎛, physical properties that can increase the friction force The coating composition for a steering wheel of a vehicle, characterized in that the particles having a particle size of 60% compared to the thickness of the coating film to be coated so as to have 60% or more of the total particles.
KR10-2002-0046923A 2002-08-08 2002-08-08 Coating composition for steering wheel of automobile KR100494585B1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08269372A (en) * 1995-03-31 1996-10-15 Nissan Shatai Co Ltd Coating material for forming protecting film on coated surface and protection of coated surface of car body
KR970001489A (en) * 1995-06-23 1997-01-24 황선두 Synthetic resin packaging material with high discoloration resistance
KR19980701243A (en) * 1995-01-06 1998-05-15 워렌 알. 보비 Conformable Surface Finishing Articles and Methods for Making the Same
KR19980049737A (en) * 1996-12-20 1998-09-15 한정국 Pavement method to prevent slipping on pavement using non slip plate
JP2000038523A (en) * 1998-07-23 2000-02-08 Dainippon Toryo Co Ltd Clear powder coating composition for aluminum wheel
KR20020008805A (en) * 2001-08-23 2002-01-31 이성환 Anti-skid surface and spattered pattern line coating material and method of coating road surface using the material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19980701243A (en) * 1995-01-06 1998-05-15 워렌 알. 보비 Conformable Surface Finishing Articles and Methods for Making the Same
JPH08269372A (en) * 1995-03-31 1996-10-15 Nissan Shatai Co Ltd Coating material for forming protecting film on coated surface and protection of coated surface of car body
KR970001489A (en) * 1995-06-23 1997-01-24 황선두 Synthetic resin packaging material with high discoloration resistance
KR19980049737A (en) * 1996-12-20 1998-09-15 한정국 Pavement method to prevent slipping on pavement using non slip plate
JP2000038523A (en) * 1998-07-23 2000-02-08 Dainippon Toryo Co Ltd Clear powder coating composition for aluminum wheel
KR20020008805A (en) * 2001-08-23 2002-01-31 이성환 Anti-skid surface and spattered pattern line coating material and method of coating road surface using the material

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