KR100488860B1 - Compostion for variable continuously transmission fluid - Google Patents

Compostion for variable continuously transmission fluid Download PDF

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KR100488860B1
KR100488860B1 KR10-2002-0043939A KR20020043939A KR100488860B1 KR 100488860 B1 KR100488860 B1 KR 100488860B1 KR 20020043939 A KR20020043939 A KR 20020043939A KR 100488860 B1 KR100488860 B1 KR 100488860B1
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weight
continuously variable
variable transmission
transmission oil
oil composition
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KR20040010904A (en
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배대윤
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현대자동차주식회사
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16Ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

본 발명은 무단변속기유 조성물에 관한 것으로서, 더욱 상세하게는 기유 50 ∼ 95 중량%, 내마모제 0.01 ∼ 2 중량%, 금속계 청정분산제 0.05 ∼ 5 중량%, 마찰조정제 0.01 ∼ 3 중량% 및 점도지수향상제를 포함한 기타 첨가제 0.05 ∼ 20중량%로 구성됨으로써 변속성능과 내구성이 우수한 무단변속기유 조성물에 관한 것이다.The present invention relates to a continuously variable transmission oil composition, and more specifically, 50 to 95% by weight of base oil, 0.01 to 2% by weight of abrasion resistant agent, 0.05 to 5% by weight of metal-based clean dispersant, 0.01 to 3% by weight of friction modifier and viscosity index improver. It is related with the continuously variable transmission oil composition which is excellent in a shift performance and durability by consisting of 0.05-20 weight% of other additives included.

Description

무단변속기유 조성물{Compostion for variable continuously transmission fluid}Continuously variable oil composition

본 발명은 무단변속기유 조성물에 관한 것으로서, 더욱 상세하게는 기유 50 ∼ 95 중량%, 내마모제 0.01 ∼ 2 중량%, 금속계 청정분산제 0.05 ∼ 5 중량%, 마찰조정제 0.01 ∼ 3 중량% 및 점도지수향상제를 포함한 기타 첨가제 0.05 ∼ 20중량%로 구성됨으로써 변속성능과 내구성이 우수한 무단변속기유 조성물에 관한 것이다.The present invention relates to a continuously variable transmission oil composition, and more specifically, 50 to 95% by weight of base oil, 0.01 to 2% by weight of abrasion resistant agent, 0.05 to 5% by weight of metal-based clean dispersant, 0.01 to 3% by weight of friction modifier and viscosity index improver. It is related with the continuously variable transmission oil composition which is excellent in a shift performance and durability by consisting of 0.05-20 weight% of other additives included.

자동차의 성능과 내구성 및 편의성 향상을 위해 자동차 기어유의 요구조건이 엄격해지고 있으며, 특히, 운전자의 편의성을 향상시키기 위해 수동변속기 보다는 자동변속기 장착 차량이 증대되고 있다. 그러나, 자동변속기는 구조상 수동변속기 대비 연비가 저하되는 문제가 있어 연비향상과 편의성 향상을 목적으로 무단변속기(Variable Continuously Transmission)가 개발되어 창착되고 있다.In order to improve the performance, durability and convenience of the vehicle, the requirements of the automobile gear oil are becoming strict, and in particular, in order to improve the driver's convenience, vehicles with automatic transmissions are increasing rather than manual transmissions. However, the automatic transmission has a problem in that the fuel economy is lowered compared to the manual transmission due to its structure, and a continuously variable transmission (Variable Continuously Transmission) has been developed and created for the purpose of improving fuel efficiency and convenience.

현재 무단변속기는 고토크 차량에는 장착되지 않으며, 보통 2,000 cc 이하 차량에 장착되어 있다. 구조상 무단변속기는 자동변속기의 토크컨버터와 클러치는 같으나 동력전달과 기어의 구조는 다르게 설계된다. 따라서, 무단변속기유는 자동변속기유의 요구특성인 STEEL-PAPER 클러치 마찰특성이 유사하기 때문에 무단변속기유는 기존의 자동변속기유와 공용으로 사용하기도 하나 고토크 차량에 사용하거나 동력전달능력을 향상시키기 위해 일부 MAKER에서는 전용유를 사용하고 있다.Currently, continuously variable transmissions are not installed on high-torque vehicles, and are usually mounted on vehicles under 2,000 cc. In terms of structure, the continuously variable transmission has the same torque converter and clutch as the automatic transmission, but the power transmission and gear structure are designed differently. Therefore, the continuously variable transmission oil has similar characteristics to the STEEL-PAPER clutch friction characteristics, which are required characteristics of the automatic transmission oil. Therefore, the continuously variable transmission oil can be used in common with the existing automatic transmission oil, but it can be used in high torque vehicles or to improve power transmission capability. Some makers use proprietary oils.

무단변속기의 동력전달 능력과 승차감 향상이 요구됨에 따라 무단변속기유의 요구특성도 상향되고 있다. 일반적으로 밸트-풀리에 의해 동력전달과 변속이 이루어지는 무단변속기유는 자동변속기유의 요구특성외 밸트와 풀리의 마찰특성이 추가로 요구된다.As the transmission power of the continuously variable transmission and the improvement of ride comfort are required, the required characteristics of the continuously variable transmission oil are also being raised. In general, continuously variable transmission oil in which power transmission and shifting are performed by a belt-pulley requires additional friction characteristics between the belt and the pulley in addition to the required characteristics of the automatic transmission oil.

일반적으로 밸트-풀리는 STEEL로 이루어져 있으며, 변속원리는 프라이머리 풀리의 구폭변화에 대응하여 자동적으로 세컨드 풀리의 구폭을 무단계로 변화시킴으로써 변속이 이루어진다. 따라서, 무단변속기유는 풀리의 구폭이 변경될 때 금속밸트가 풀리축의 수직방향으로 이동시 오일의 전단이 가장 많이 발생되며, 이때 마찰계수가 낮으면 밸트가 미끄러지면서 금속밸트의 마모가 발생되며,금속밸트의 과도한 마모방지를 위해서는 마찰계수는 0.1 이상 유지되어야 한다. 밸트-풀리형 무단변속기 차량이 출발할 때나 멈출 때 μ-V 특성이 나쁘면 스크레치 소음이 발생된다. 소음은 밸트가 풀리의 수직방향으로 움직일 때 마찰계수(μ)가 밸트가 수직으로 움직이는 속도(V) 증가됨에 따라 마찰계수도 같이 증가 되면 밸트는 정상적으로 동력을 전달하나 속도가 증가할 때 마찰계수가 낮으면 밸트와 풀리가 미끄러져 소음이 발생된다. 즉, 정상적인 동력전달이 이루어질려면 정마찰계수(μs) / 동마찰계수(μd) 비가 0.9 ∼ 1.0로 유지되어야 한다. 따라서, 무단변속기유는 밸트와 풀리 사이의 금속-금속 접촉시 높은 마찰계수와 우수한 μ-V 특성이 요구된다.In general, the belt-pulley consists of STEEL, and the shifting principle is shifted automatically by changing the width of the second pulley steplessly in response to the change of the width of the primary pulley. Therefore, in the continuously variable base oil, when the metal belt moves in the vertical direction of the pulley shaft when the width of the pulley is changed, the shear of oil is most generated. At this time, when the friction coefficient is low, the belt slips and the wear of the metal belt occurs. In order to prevent excessive wear of the belt, the coefficient of friction should be maintained above 0.1. Scratch noise is generated when the μ-V characteristic is bad when the belt-pull type CVT vehicle starts or stops. If the friction coefficient (μ) increases as the belt moves vertically (V) as the belt moves in the vertical direction of the pulley, the belt transmits power normally, but when the speed increases, the coefficient of friction increases. When low, the belt and pulleys will slip and generate noise. In other words, the normal friction coefficient (μs) / dynamic friction coefficient (μd) ratio must be maintained at 0.9 ~ 1.0 in order to achieve normal power transfer. Thus, continuously variable transmission oils require high coefficients of friction and good μ-V characteristics in metal-to-metal contact between belts and pulleys.

일반적으로 무단변속기에 사용되는 전용유는 징크디티오포스페이트(Zn-DTP)와 금속청정분산제를 사용하는데 금속염으로 이루어진 ASH TYPE 첨가제는 ASHLESS TYPE 대비 금속-금속간 마찰계수가 높으나 μ-V 특성을 향상시키기는 한계가 있어 산화안정성이 좋지 않아 교환주기를 연장하는데는 어려움이 있으며, STEEL-PAPER가 적용된 클러치 내구수명을 연장시키지 못하는 문제가 있다.Generally, the exclusive oil used in continuously variable transmission uses zinc dithiophosphate (Zn-DTP) and metal cleansing dispersant. The ASH TYPE additive made of metal salt has higher metal-metal friction coefficient than ASHLESS TYPE but improves μ-V characteristics. It is difficult to extend the exchange cycle because there is a limit to the oxidation stability is not good, there is a problem that does not extend the clutch durability life applied STEEL-PAPER.

이에, 본 발명자들은 징크디티오포스페이트(Zn-DTP)와 금속청정분산제를 사용한 무단변속기유보다 변속성능과 내구성이 우수한 무단변속기유 제조를 위하여 연구한 결과, 내열성이 우수하며, 금속-금속간 마찰계수가 높으며, μ-V 특성이 우수한 마찰조정제, 내열성과 내마모성이 우수한 내마모 첨가제와, 금속청정분산제를 적절히 조합하여 변속성능과 내구성이 우수한 자동차용 무단변속기유를 개발함으로써 본 발명을 완성하였다.Accordingly, the present inventors have studied for producing a continuously variable transmission oil having excellent shifting performance and durability than a continuously variable transmission oil using zinc dithiophosphate (Zn-DTP) and a metal cleansing dispersant, and have excellent heat resistance and friction between metals and metals. The present invention has been completed by developing a continuously variable transmission oil having excellent transmission performance and durability by appropriately combining a friction modifier having high coefficient, excellent µ-V characteristics, an anti-wear additive having excellent heat and wear resistance, and a metal cleansing dispersant.

따라서, 본 발명은 기유, 내마모제, 금속계 청정분산제, 마찰조정제 및 점도지수향상제를 포함한 기타 첨가제로 구성되어 변속성능과 내구성이 우수한 무단변속기유 조성물을 제공하는데 그 목적이 있다. Accordingly, an object of the present invention is to provide a continuously variable transmission oil composition having excellent shift performance and durability, which is composed of other additives including a base oil, an anti-wear agent, a metal-based dispersant, a friction modifier, and a viscosity index improver.

본 발명은 기유와, 금속청정분산제 및 첨가제를 함유하는 무단변속기유 조성물에 있어서, (1) 기유 86 ∼ 95 중량%;(2) MoDTC(Molybdenum Ditiocarbamate) 및 MoDTP(Molybdenum Ditiophosphate)의 단독 또는 조합한 유기몰리브텐계 내마모제 0.05 ∼ 5 중량%;(3) 전염기가가 200 이상인 마그네슘 슬포네이트의 금속염 청정분산제 0.05 ∼ 5 중량%; 및(4) 글리세린폴리올레익에테르(Glycerin poly-oleic Ether)의 마찰조정제 0.01 ∼ 3 중량%를 포함하여 이루어진 무단변속기유 조성물에 그 특징이 있다.The present invention provides a continuously variable base oil composition containing a base oil, a metal cleansing dispersant and an additive, comprising: (1) 86 to 95 wt% of a base oil; 0.05 to 5% by weight of an organic molybdenum antiwear agent; (3) 0.05 to 5% by weight of a metal salt cleansing dispersant of magnesium sulfonate having a total salt value of 200 or more; And (4) 0.01 to 3% by weight of a friction modifier of glycerin poly-oleic ether.

이와 같은 본 발명을 상세히 설명하면 다음과 같다.The present invention will be described in detail as follows.

상기 조성물에 있어서, 기유는 100 ℃ 동점도가 3 ∼ 10 cSt 이고 점도지수가 100 이상인 고정제 광유 또는 합성유를 86 ∼ 95 중량% 사용하는 것이 바람직하다. In the above composition, it is preferable to use 86 to 95% by weight of a fixed mineral oil or a synthetic oil having a kinematic viscosity of 3 to 10 cSt and a viscosity index of 100 or more at 100 ° C.

내마모제는 내마모첨가제로 징크디티오포스페이트(ZnDTP) 및 유기몰리브텐계 내마모제로 MoDTC(Molybdenum Ditiocarbamate), MoDTP(Molybdenum Ditiophosphate)를 단독 또는 조합하여 사용하는 것이 바람직하고, 유기몰리브덴은 밸트-풀리의 금속-금속간 정마찰계수를 일정하게 유지시키는 역할을 하기 때문에 MoDTC : MoDTP 의 혼합비가 2 : 1 내지 3: 1 비율(중량비)로 혼합하는 것이 바람직하다. 유기몰리브덴이 0.01 중량% 미만인 경우 기어 내구성이 저하되며 2 중량% 초과할 경우는 밸트-풀리의 금속-금속간 정마찰계수가 저하되는 문제가 있다. 내마모제의 전체 함량은 0.05 ∼ 5 중량% 가 바람직하며, 0.05 중량% 미만일 경우에는 기어 및 베어링 부품이 마모 또는 파손되는 문제점이 있으며, 5 중량% 초과할 경우에는 밸트-풀리간의 마찰특성 저하로 변속이 나빠지는 문제점이 있다.The antiwear agent is a zinc dithiophosphate (ZnDTP) and an organic molybdenum antiwear agent, and MoDTC (Molybdenum Ditiocarbamate) and MoDTP (Molybdenum Ditiophosphate) alone or in combination. It is preferable to mix the MoDTC: MoDTP in a 2: 1 to 3: 1 ratio (weight ratio) because it serves to keep the static friction coefficient between metals constant. When the organic molybdenum is less than 0.01% by weight, the gear durability is lowered. When the organic molybdenum is more than 2% by weight, the metal-to-metal static friction coefficient of the belt-pull is lowered. The total content of the anti-wear agent is preferably 0.05 to 5% by weight. If the content is less than 0.05% by weight, the gears and bearing parts may be worn or broken. If the amount is more than 5% by weight, the shift of the belt-pulley may be reduced due to a decrease in friction characteristics of the belt-pull. There is a problem that goes bad.

또한, 금속계 청정분산제는 전염기가가 200 이상인 마그네슘 슬포네이트와 칼슘 슬포네이트, 마크네슘피네이트를 단독 또는 조합하여 사용하는 것이 바람직하다. 금속계 청정분산제는 밸트-풀리의 금속-금속간 동마찰계수를 높게 유지시키는 역할을 하며, 0.05 중량% 미만이면 밸트-풀리의 금속-금속간 동마찰계수가 낮아지고 5 중량% 초과하면 산화안정성과 기어 및 베어링의 내구성이 저하되는 문제가 있다.In addition, the metal-based clean dispersant is preferably used alone or in combination with magnesium sulfonate having a total base value of 200 or more, calcium sulfonate, and magnesium pinate. The metal-based clean dispersant keeps the metal-metal dynamic friction coefficient of the belt-pulley high. If it is less than 0.05% by weight, the metal-metal dynamic friction coefficient of the belt-pulley is lowered. There is a problem that the durability of the gear and bearing is lowered.

마찰조정제로는 글리세린폴리올레익에테르(Glycerin poly-oleic Ether)를 사용하는 것이 바람직한데, 글리세린폴리올레익에테르는 금속-금속간 동마찰계수를 높이고 정마찰계수는 낮추는 효과를 가진다. 상기 마찰조정제는 0.01 ∼ 3 중량%를 사용하는 것이 바람직하고, 함량이 0.01 중량% 미만이면 원하는 효과가 나타나지 않으며 3 중량%을 초과하면 내마모성에 문제가 있다.As a friction modifier, it is preferable to use glycerin poly-oleic ether, which has the effect of increasing the coefficient of dynamic friction between metals and metals and decreasing the coefficient of static friction. Preferably, the friction modifier is used in an amount of 0.01 to 3% by weight. If the content is less than 0.01% by weight, the desired effect is not achieved.

기타 첨가제로는 점도지수향상제, 유동성 향상제, 소포제, 녹부식방지제 등이 사용되는데, 이의 함량은 0.05 ∼ 20 중량%가 바람직하다.As other additives, a viscosity index improver, a fluidity improver, an antifoaming agent, an anticorrosive agent, and the like are used, and the content thereof is preferably 0.05 to 20% by weight.

이와 같은 무단변속기유 조성물은 변속성능이 좋으며, 내구수명을 연장시킬 수 있다. 또한, 밸트-풀리간의 동, 정마찰계수 특성이 향상되는 장점을 가지기 때문에 고토크 차량에 장착된 무단변속기의 성능과 소음방지에 탁월한 효과가 있다.Such continuously variable transmission oil composition has good shifting performance and can extend the service life. In addition, since the dynamic coefficient of static and static friction between the belt and the pulley is improved, there is an excellent effect on the performance and noise prevention of the continuously variable transmission mounted on a high torque vehicle.

이하, 본 발명은 다음 실시예에 의거하여 상세히 설명하겠는 바, 본 발명이 다음 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail based on the following examples, but the present invention is not limited by the following examples.

실시예 1 ~ 3 및 비교예 1 ~ 2Examples 1-3 and Comparative Examples 1-2

다음 표 1과 같은 조성으로 무단변속기유를 제조하였다. 이때 각 성분의 단위는 중량%를 나타낸다.Next, continuously variable transmission oil was prepared in the composition shown in Table 1. At this time, the unit of each component represents the weight%.

시험예Test Example

상기 실시예 1 내지 3 및 비교예 1 내지 2의 조성물을 ASTM D 2714 시험방법에 따라 BLOCK-ON-RING 시험을 110 ℃에서 실시하였으며 그 결과는 다음 표 2에 나타내었다. 동마찰계수 1.0 m/s에서 측정하였으며, 정마찰계수는 0.05 m/s에서 측정하였다.The compositions of Examples 1 to 3 and Comparative Examples 1 and 2 were subjected to the BLOCK-ON-RING test at 110 ° C according to ASTM D 2714 test method and the results are shown in Table 2 below. The dynamic friction coefficient was measured at 1.0 m / s, and the static friction coefficient was measured at 0.05 m / s.

상기 표 2에 나타낸 바와 같이 실시예 2, 3의 조성물이 마찰계수가 높고, 정/동 마찰계수비가 적절하게 유지되며 마찰조정제를 사용 하더라도 TIMKEN OK 하중이 저하되는 문제가 없는 것으로 보아 내마모성도 요구수준을 달성할 수 있다는 것을 알 수 있었다, As shown in Table 2, the composition of Examples 2 and 3 has a high coefficient of friction, maintains a proper coefficient of static / dynamic friction, and does not show a problem that the TIMKEN OK load is lowered even when a friction modifier is used. Was able to achieve

따라서, 기유 50 ∼ 95 중량%, 내마모제 0.05 ∼ 5 중량%, 금속염 청정분산제 0.05 ∼ 5 중량%, 마찰조정제로 글리세린폴리올레익에테르(Glycerin poly-oleic Ether) 0.01 ∼ 3 중량%로 이루어진 조성물은 금속-밸트의 마찰계수를 높힘으로써 고토크 차량의 무단변속기에 사용이 가능하며 변속성능이 좋으며, 내구수명을 연장시킬 수 있다. 또한, 소음방지에도 효과가 있다.Therefore, the composition consisting of 50 to 95% by weight of base oil, 0.05 to 5% by weight of antiwear agent, 0.05 to 5% by weight of metal salt dispersant, and 0.01 to 3% by weight of glycerin poly-oleic ether as friction modifier -By increasing the coefficient of friction of the belt, it can be used for continuously variable transmission of high torque vehicles, and it has good shifting performance and extends the durability life. In addition, it is effective in preventing noise.

Claims (4)

기유와, 금속청정분산제 및 첨가제를 함유하는 무단변속기유 조성물에 있어서, In the continuously variable transmission oil composition comprising a base oil, a metal clean dispersion and an additive, (1) 기유 86 ∼ 95 중량%;(1) 86 to 95% by weight of base oil; (2) MoDTC(Molybdenum Ditiocarbamate) 및 MoDTP(Molybdenum Ditiophosphate)의 단독 또는 조합한 유기몰리브텐계 내마모제 0.05 ∼ 5 중량%;(2) 0.05 to 5% by weight of an organic molybdenum antiwear agent alone or in combination of MoDTC (Molybdenum Ditiocarbamate) and MoDTP (Molybdenum Ditiophosphate); (3) 전염기가가 200 이상인 마그네슘 슬포네이트의 금속염 청정분산제 0.05 ∼ 5 중량%; 및(3) 0.05 to 5% by weight of a metal salt clean dispersant of magnesium sulfonate having a total salt value of 200 or more; And (4) 글리세린폴리올레익에테르(Glycerin poly-oleic Ether)의 마찰조정제 0.01 ∼ 3 중량%(4) 0.01-3% by weight of friction modifier of glycerin poly-oleic ether 를 포함하여 이루어진 것을 특징으로 하는 무단변속기유 조성물.Continuously variable transmission oil composition comprising a. 제 1 항에 있어서, 상기 기유는 100 ℃ 동점도가 3 ∼ 10 cSt이고 광유 또는 합성유인 것을 특징으로 하는 무단변속기유 조성물.The continuously variable transmission oil composition according to claim 1, wherein the base oil has a 100 ° C kinematic viscosity of 3 to 10 cSt and is mineral or synthetic oil. 제 1 항에 있어서, 상기 유기몰리브텐계 내마모제는 징크디티오포스페이트(ZnDTP)의 내마모첨가제를 추가로 혼합하여 사용하는 것을 특징으로 하는 무단변속기유 조성물. The continuously variable transmission oil composition according to claim 1, wherein the organomolybdenum antiwear agent is further mixed with an antiwear additive of zinc dithiophosphate (ZnDTP). 제 1 항에 있어서, 상기 금속염 청정분산제는 칼슘 슬포네이트를 추가로 혼합하여 사용하는 것을 특징으로 하는 무단변속기유 조성물.The continuously variable transmission oil composition according to claim 1, wherein the metal salt clean dispersant is further mixed with calcium sulfonate.
KR10-2002-0043939A 2002-07-25 2002-07-25 Compostion for variable continuously transmission fluid KR100488860B1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064546A (en) * 1987-04-11 1991-11-12 Idemitsu Kosan Co., Ltd. Lubricating oil composition
JPH05331477A (en) * 1992-05-30 1993-12-14 Tonen Corp Hydraulic oil composition
KR960705009A (en) * 1993-09-13 1996-10-09 수잔 제인 플레처 와츠 LUBRICANT COMPOSITION CONTAINING ANTIWEAR ADDITIVE COMBINATION
JPH1129766A (en) * 1997-07-09 1999-02-02 Hitachi Ltd Refrigerator and coolant compressor
KR20030090891A (en) * 2002-05-22 2003-12-01 현대자동차주식회사 Composition of gear oil for automobiles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064546A (en) * 1987-04-11 1991-11-12 Idemitsu Kosan Co., Ltd. Lubricating oil composition
JPH05331477A (en) * 1992-05-30 1993-12-14 Tonen Corp Hydraulic oil composition
KR960705009A (en) * 1993-09-13 1996-10-09 수잔 제인 플레처 와츠 LUBRICANT COMPOSITION CONTAINING ANTIWEAR ADDITIVE COMBINATION
JPH1129766A (en) * 1997-07-09 1999-02-02 Hitachi Ltd Refrigerator and coolant compressor
KR20030090891A (en) * 2002-05-22 2003-12-01 현대자동차주식회사 Composition of gear oil for automobiles

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