KR100486659B1 - Transfering method of transfer film using pressing mould to polypropylene edge and polypropylene plate - Google Patents
Transfering method of transfer film using pressing mould to polypropylene edge and polypropylene plate Download PDFInfo
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- KR100486659B1 KR100486659B1 KR10-2002-0006249A KR20020006249A KR100486659B1 KR 100486659 B1 KR100486659 B1 KR 100486659B1 KR 20020006249 A KR20020006249 A KR 20020006249A KR 100486659 B1 KR100486659 B1 KR 100486659B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
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- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
본 발명은 폴리프로필렌(polypropylene: PP)엣지와 PP평판 압출을 이용한 전사필름의 전사방법에 관한 것으로, a)PET 필름층; b)아크릴 공중합체(acrylic copolymer), 합성 왁스, 톨루엔, 메틸 에틸 케톤(methyl ethyl ketone)을 구성성분으로 하는 이형재층; c)폴리우레탄 수지(polyurethane resin), 변성 아크릴 수지(modified acrylic resin), 실리카 분말(silica powder), 메틸 에틸 케톤을 구성성분으로 하는 탑 프라이마층; d)합성 수지, 합성 왁스, 안료(pigment), 톨루엔, 메틸 에틸 케톤, 에틸 아세테이트을 구성성분으로 하는 인쇄층; 및 e)폴리프로필렌 공중합체(polypropylene copolymer), 합성 왁스, 톨루엔을 구성성분으로 하는 접착제층을 순차로 도포하여 수득한 전사지를 압출기에서 PP엣지 또는 PP평판 압출 시 동시에 전사함을 특징으로 한다.The present invention relates to a transfer method of a transfer film using a polypropylene (PP) edge and PP flat extrusion, a) a PET film layer; b) a release layer composed of acrylic copolymer, synthetic wax, toluene, methyl ethyl ketone as a component; c) a top primer layer composed of polyurethane resin, modified acrylic resin, silica powder, and methyl ethyl ketone; d) a printing layer composed of synthetic resins, synthetic waxes, pigments, toluene, methyl ethyl ketone, ethyl acetate; And e) a transfer sheet obtained by sequentially applying an adhesive layer composed of polypropylene copolymer, synthetic wax, and toluene as a constituent in sequence to be simultaneously transferred at the time of extrusion of PP edge or PP flat plate in an extruder.
상기 구성에 따른 본 발명은 가구의 엣지 또는 문구류의 평판에 폴리프로필렌을 사용하여 환경오염의 우려를 미연에 방지하며 PP엣지 또는 PP평판의 압출작업 시 본 발명에 따른 전사지를 동시에 전사하여 생산성 향상 및 원가절감에 기여할 수 있을 뿐 아니라, 전사된 표면이 강하여 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 월등히 우수하여 가공 후 별도의 표면처리를 요하지 않는 유용한 발명이다.The present invention according to the above configuration by using polypropylene on the edge of the furniture or the plate of stationery in advance to prevent the risk of environmental pollution and at the same time transfer the transfer paper according to the present invention during the extrusion operation of the PP edge or PP flat plate to improve productivity and It is a useful invention that not only contributes to cost reduction but also has excellent transfer resistance, which is excellent in abrasion resistance, chemical resistance, solvent resistance, light resistance and scratch resistance, and does not require a separate surface treatment after processing.
Description
본 발명은 폴리프로필렌(polypropylene: PP)엣지와 PP평판 압출을 이용한 전사필름의 전사방법에 관한 것으로서, 보다 자세하게는 충격에 강하고 가공성이 뛰어난 PP엣지와 PP평판에 전사지를 용이하게 직접 전사하는 전사방법에 관한 것이다.The present invention relates to a transfer method of a transfer film using a polypropylene (PP) edge and PP flat extrusion, and more particularly, a transfer method for directly transferring a transfer paper directly to a PP edge and a PP flat having excellent impact resistance and processability. It is about.
종래 씽크대 및 일반가구의 문틀 옆모서리나 파일,앨범, 바인더, 명함철, 서류가방 등의 문구용품의 표면지로 사용되어온 PVC엣지나 PVC평판은 인체에 치명적인 악성 발암물질이 함유되어 있어 사용자들이 폐기물 처리에 어려움이 있었다. 또한, 이러한 PVC엣지나 PVC평판 표면에 원하는 무늬를 넣기 위해 각종 무늬가 인쇄된 필름지를 열과 압을 가하여 전사하는데, 이러한 종래의 일반 전사필름은 전사된 표면이 강하지 않아서 메틸 에틸 케톤, 에틸 아세테이트 등의 각종 용재로 4-5회만 닦아도 인쇄된 무늬가 지워질 뿐 아니라, 조그마한 긁힘에도 쉽게 스크래치가 발생하는 단점이 있었다. 즉 종래의 일반 전사지는 PET필름 내면에 이형층 - 인쇄층 - 통상의 접착제층의 구조로 되어 있으며 이 전사지를 기생산된 PVC엣지나 PVC평판 표면에 후 전사하기 때문에 전사 과정이 번거로워 작업효율이 저하되고, 또한 이형층 만이 인쇄층의 보호층으로 작용하여 유기 용재에 쉽게 인쇄층이 지워지고 내광성이 열등하며 인쇄컬러가 쉽게 변색될 뿐 아니라 스크래치성도 약하다는 단점이 있었다.PVC edge or PVC flat plate, which has been used as the surface of stationery, files, albums, binders, business card holders, briefcases, etc. in the side of door frames of sinks and general furnitures, contains harmful carcinogens that can be harmful to humans. There was a difficulty. In addition, in order to put a desired pattern on the surface of the PVC edge or PVC flat plate, various pattern printed film paper is applied by applying heat and pressure. Such conventional transfer film has a strong transfer surface, such as methyl ethyl ketone, ethyl acetate, etc. Even if you wipe only 4-5 times with various materials, the printed pattern is not only erased, but there is a disadvantage that scratches occur easily even on small scratches. In other words, the conventional transfer paper has a structure of release layer-printing layer-normal adhesive layer on the inner surface of PET film, and transfer the transfer paper to the pre-produced PVC edge or PVC flat surface. In addition, only the release layer acts as a protective layer of the printing layer, so that the printing layer is easily removed from the organic solvent, the light resistance is inferior, the printing color is easily discolored, and scratches are also weak.
반면 PP는 환경 친화적 제품으로 충격에 강하고 가공성이 뛰어나 엣지가 깨어지는 것을 방지하며 접착력이 뛰어나 씽크대 및 일반가구의 문틀 옆모서리나 파일,앨범, 바인더, 명함철, 서류가방 등의 문구용품의 표면지로 유용하게 사용될 수 있다. PP, on the other hand, is an environmentally friendly product that is strong in impact, and has excellent processability to prevent cracking of the edges. It also has excellent adhesion and is a surface paper for stationery, such as edges of files and albums, binders, business cards, briefcases, etc. It can be usefully used.
따라서, 본 발명의 목적은 상기한 문제점을 해결하여 환경오염의 우려를 제거할 뿐 아니라 강도가 보다 강하고, 더불어 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 우수한 열 전사필름을 엣지와 평판에 보다 용이하게 전사하는 방법을 제공하기 위한 것이다. Accordingly, an object of the present invention is to solve the above problems, not only to remove the concern of environmental pollution, but also to the strength and strength, and also to the heat transfer film having excellent wear resistance, chemical resistance, solvent resistance, light resistance and scratch resistance, edge and flat plate. To provide a method for easier transfer to the.
상기와 같은 본 발명의 목적은 폴리에틸렌테레프탈레이트(PET) 필름층, 인쇄층의 분리를 용이하게 하는 이형재층, 탑 프라이머층, 인쇄층, 접착제층으로 구성된 전사지를 엣지와 평판을 압출할 때 동시에 전사하는 방법을 제공함으로서 달성되어질 수 있다.As described above, the object of the present invention is a polyethylene terephthalate (PET) film layer, a transfer sheet composed of a release material layer, a top primer layer, a printing layer, and an adhesive layer to facilitate separation of the printing layer, and simultaneously transferring the edges and flat plates. It can be achieved by providing a method.
상기 목적을 달성하기 위한 본 발명은 The present invention for achieving the above object
a)PET 필름층;a) PET film layer;
b)아크릴 공중합체(acrylic copolymer), 합성 왁스, 톨루엔, 메틸 에틸 케톤(methyl ethyl ketone)을 구성성분으로 하는 이형재층;b) a release layer composed of acrylic copolymer, synthetic wax, toluene, methyl ethyl ketone as a component;
c)폴리우레탄 수지(polyurethane resin), 변성 아크릴 수지(modified acrylic resin), 실리카 분말(silica powder), 메틸 에틸 케톤을 구성성분으로 하는 탑 프라이마층;c) a top primer layer composed of polyurethane resin, modified acrylic resin, silica powder, and methyl ethyl ketone;
d)합성 수지, 합성 왁스, 안료(pigment), 톨루엔, 메틸 에틸 케톤, 에틸 아세테이트을 구성성분으로 하는 인쇄층; 및d) a printing layer composed of synthetic resins, synthetic waxes, pigments, toluene, methyl ethyl ketone, ethyl acetate; And
e)폴리프로필렌 공중합체(polypropylene copolymer), 합성 왁스, 톨루엔을 구성성분으로 하는 접착제층을 순차로 도포하여 수득한 전사지를 압출기에서 폴리프로필렌(PP)엣지 또는 PP평판 압출 시 동시에 전사함을 특징으로 한다.상기 이형재층은 왁스, 충전제 등과 같은 통상의 부가제를 포함할 수 있다. 또한, 상기 접착제층도 통상의 부가제, 예를 들면 충전재 등을 포함할 수 있다.e) Transfer paper obtained by sequentially applying an adhesive layer composed of polypropylene copolymer, synthetic wax, and toluene as a component is transferred simultaneously in the extrusion of polypropylene (PP) edge or PP plate in an extruder. The release material layer may include conventional additives such as wax, filler, and the like. In addition, the adhesive layer may also contain a conventional additive, for example a filler.
상기 탑 프라이마층을 제조할 때 제품의 최종 표면의 내열성, 내광성, 내습성, 내스크래치성을 보다 강하게 하기 위해서는 폴리우레탄 수지, 변성 아크릴 수지 및 실리카 분말을 메틸 에틸 케톤에 서서히 투입하여 약 3분 정도 교반한 후 일시 중지하고 나서 다시 약 1780RPM 이상의 속도로 약 10∼15분간 교반을 계속하여 제조함이 보다 바람직하다. In order to make the heat resistance, light resistance, moisture resistance, and scratch resistance of the final surface of the product stronger when preparing the top priming layer, a polyurethane resin, a modified acrylic resin, and a silica powder were gradually added to methyl ethyl ketone for about 3 minutes. It is more preferable to continue stirring for about 10 to 15 minutes at a speed of about 1780 RPM or more after pausing after stirring about.
상기와 같이 구성된 접착제층은 그라비아 인쇄 방법에 의하여 도포하는데 건조 온도는 80∼100℃로 하고 온도에 따라 도포 속도를 다양하게 할 수 있고 원적외선(Far-IR)과 핫 에어 브로윙 시스템(hot air blowing system)을 이용하여 열을 공급함으로 해서 보다 속도를 높일 수 있다. 특히, 상기 접착제층은 2회 도포함이 바람직하다. The adhesive layer configured as described above is applied by a gravure printing method, the drying temperature is 80 ~ 100 ℃ and can vary the application speed according to the temperature, far-IR and hot air blowing system (hot air blowing) The speed can be increased by supplying heat using the system. In particular, the adhesive layer is preferably coated twice.
본 발명의 일 구성인 상기 PET필름은 평활도가 고르고 열에 잘 견디며 신축성이 강한 필름을 사용하여 전사지를 엣지의 굴곡면에 전사 시에도 찢어지거나 쉽게 변형이 가지 않는 작용효과가 있다. The PET film, which is one configuration of the present invention, has a smooth and even heat resistance, and uses a stretchable film, which does not easily tear or deform even when transferred to the curved surface of the edge.
또한, 이형재층을 형성시킴으로서, 전사 시 열과 압이 가해지더라도 PP엣지 나 평판에 인쇄층만 붙이고 PET필름은 용이하게 분리를되게 하여 전사작업을 원활히 하게 할 수 있으며, 탑 프라이마층은 전사된 인쇄층을 보호하여 유기용재나 마모 또는 스크래치에 잘 견딜 수 있게 한다.Also, by forming a release material layer, even if heat and pressure are applied during transfer, only the printing layer is attached to the PP edge or the flat plate, and the PET film can be easily separated to facilitate the transfer operation. The layer is protected to resist organic materials, abrasion or scratches.
인쇄층에는 다양한 무늬와 색상을 실현시킬 수 있으며, 접착제층은 PP엣지 나 PP평판에 전사 필름을 보다 견고하고 용이하게 접착되게 한다.The printing layer can realize various patterns and colors, and the adhesive layer makes the transfer film more firmly and easily adhered to the PP edge or the PP flat plate.
이하, 본 발명의 바람직한 실시형태를 도면을 참고로 보다 자세히 설명하지만, 본 발명이 여기에 한정되는 것은 아니다.Hereinafter, although preferred embodiment of this invention is described in detail with reference to drawings, this invention is not limited to this.
먼저 열에 강하고 신축성이 강한 유광 또는 무광의 필름을 사용하여 형성한 제1층인 PET 필름층(1)에 인쇄층이 잘 분리될 수 있게 아크릴 공중합체 18%, 합성 왁스 1%, 톨루엔 40%, 메틸 에틸 케톤 36% 및 부가제 5%로 구성된 이형재층(2)을 동판 175호 목(目)으로 제작하여 이형재통에 넣고 그라비아 방식으로 1차 이형재층(2)을 도포한 후, 여기에 폴리우레탄 수지 20%, 변성 아크릴 수지 10% 및 실리카 분말 2%를 메틸 에틸 케톤 68%에 서서히 투입하여 약 3분 정도 교반한 후 일시 중지하고 나서 다시 약 1780RPM 이상의 속도로 약 10-15분간 교반을 계속하여 제조한 코터(coater)를 같은 방식으로 도포하여 탑 프라이마층(3)을 형성한다. 상기 탑 프라이마층을 제조할 때 용제의 휘발을 방지하기 위해 반드시 용기의 뚜껑을 덮고 작업을 함으로서 제품의 최종 표면의 내열성, 내광성, 내습성, 내스크래치성이 보다 강하게 된 탑 프라이마층(3)을 얻을 수 있다. 이렇게 형성된 탑 프라이마층(3)에 다양한 문양과 무늬로 자연목 그대로의 질감을 표현한 동판을 걸고 원하는 컬러를 인쇄한 인쇄층(4)을 형성한다. 이때 인쇄층(4)의 잉크성분은 합성 수지 25%, 합성 왁스 2%, 안료 25%, 톨루엔 25%, 메틸 에틸 케톤 20%, 에틸 아세테이트 3%로 구성된다. 이 인쇄층(4)에 폴리프로필렌 공중합체 20%, 합성 왁스 2%, 톨루엔 75% 및 부가제 3%를 약 3분 정도 교반한 후 어느 정도 혼합이 완결되면 2차 교반은 1780RPM 이상의 강한 속도로 약 10∼15분간 교반을 계속하여(이때 용제의 휘발을 방지하기 위해 교반기의 뚜껑을 덮고 작업을 함) 수득한 접착제를 도포한다. 접착제층의 도포는 80-90℃의 고온에서 롤러로 두께 25∼30㎛ 정도의 두께로 도포한다.First, 18% of acrylic copolymer, 1% of synthetic wax, 1% of toluene, 40% of methyl, so that the printing layer can be separated on the PET film layer (1), which is the first layer formed by using heat-resistant, elastic or matte film. A release material layer (2) consisting of 36% ethyl ketone and 5% additive was made of copper plate No. 175, placed in a release container, and coated with a primary release material layer (2) in a gravure manner, followed by polyurethane 20% of resin, 10% of modified acrylic resin and 2% of silica powder were slowly added to 68% of methyl ethyl ketone, stirred for about 3 minutes, paused, and then stirred for 10-15 minutes at a speed of about 1780 RPM or more. The coater (coater) thus prepared is applied in the same manner to form the top primer layer (3). In order to prevent the volatilization of the solvent when manufacturing the top prima layer, the top prima layer (3) which has stronger heat resistance, light resistance, moisture resistance, and scratch resistance of the final surface of the product by working. ) Can be obtained. The printed layer 4 printed with the desired color is formed by hanging the copper plate expressing the texture of natural wood in various patterns and patterns on the top prima layer 3 thus formed. At this time, the ink component of the printing layer 4 is composed of 25% synthetic resin, 2% synthetic wax, 25% pigment, toluene 25%, methyl ethyl ketone 20%, ethyl acetate 3%. After stirring 20% of polypropylene copolymer, 2% of synthetic wax, 75% of toluene, and 3% of additive in the printing layer 4 for about 3 minutes, when the mixing was completed to some extent, the secondary stirring was performed at a strong speed of 1780 RPM or more. Stirring is continued for about 10 to 15 minutes (at which time the cover of the stirrer is worked to prevent volatilization of the solvent) and the obtained adhesive is applied. Application of the adhesive layer is applied to a thickness of about 25 to 30㎛ with a roller at a high temperature of 80-90 ℃.
PP엣지 또는 PP평판은 폴리프로필렌을 원료로 압출기계에서 열과 압력을 가하여 몰딩을 통과하면서 엣지와 평판을 제작하는데 이때, 상기와 같이 하여 수득한 전사지를 압출기에 넣어 PP엣지 또는 PP평판 압출 시 동시에 전사하여 원하는 무늬와 색상의 제품을 얻을 수 있다. PP edges or PP flat plates are made of polypropylene as raw materials and subjected to heat and pressure in the extrusion machine to produce edges and plates while passing through the molding. You can get the product of the desired pattern and color.
상기 실시형태에서와 같이 원하는 무늬와 색상이 전사된 PP엣지 또는 PP평판의 완성품을 1차의 공정으로 얻을 수 있을 뿐 만 아니라, 탑 프라이마층이 인쇄층을 효과적으로 보호함으로 하여 유기용제, 마모 및 습기에 강하다. As in the above embodiment, not only the finished product of the PP edge or PP flat plate to which the desired pattern and color have been transferred can be obtained by the first process, but also the top prima layer effectively protects the printed layer, thereby preventing organic solvents, abrasion and Resistant to moisture
상기 구성에 따른 본 발명은 가구의 엣지 또는 문구류의 평판에 폴리프로필렌을 사용하여 환경오염의 우려를 미연에 방지하며 PP엣지 또는 PP평판의 압출작업 시 본 발명에 따른 전사지를 동시에 전사하여 생산성 향상 및 원가절감에 기여할 수 있을 뿐 아니라, 전사된 표면이 강하여 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 월등히 우수하여 가공 후 별도의 표면처리를 요하지 않는 유용한 발명이다. The present invention according to the above configuration by using polypropylene on the edge of the furniture or the plate of stationery in advance to prevent the risk of environmental pollution and at the same time transfer the transfer paper according to the present invention during the extrusion operation of the PP edge or PP flat plate to improve productivity and It is a useful invention that not only contributes to cost reduction but also has excellent transfer resistance, which is excellent in abrasion resistance, chemical resistance, solvent resistance, light resistance and scratch resistance, and does not require a separate surface treatment after processing.
도 1은 본 발명에 따라 PP엣지와 PP평판 압출을 이용하여 전사된 전사 필름의 층 상 구조를 나타내는 개략도이다. 1 is a schematic diagram showing the layered structure of a transfer film transferred using a PP edge and a PP flat extrusion according to the present invention.
*도면의 주요 부호의 설명 * Explanation of the main signs in the drawings
1...PET필름층. 2...이형재층. 1 ... PET film layer. 2. Release material layer.
3...탑 프라이머층. 4...인쇄층. 3 ... top primer layer. 4 ... print layer.
5...접착제층. 6...PP 엣지 및 평판 5. Adhesive layer. 6.PP edge and flatbed
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2002-0006249A KR100486659B1 (en) | 2002-02-04 | 2002-02-04 | Transfering method of transfer film using pressing mould to polypropylene edge and polypropylene plate |
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| Application Number | Priority Date | Filing Date | Title |
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| KR10-2002-0006249A KR100486659B1 (en) | 2002-02-04 | 2002-02-04 | Transfering method of transfer film using pressing mould to polypropylene edge and polypropylene plate |
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| KR20030066086A KR20030066086A (en) | 2003-08-09 |
| KR100486659B1 true KR100486659B1 (en) | 2005-05-03 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH038966A (en) * | 1989-06-02 | 1991-01-16 | Goyo Shiko Kk | Interior material and its manufacture |
| JPH111656A (en) * | 1997-06-12 | 1999-01-06 | Hodogaya Kenzai Kogyo Kk | Aqueous primer composition |
| KR100272202B1 (en) * | 1998-07-29 | 2000-12-01 | 정종석 | Heating transcription film and method copyig of direct on the mdf plane and the edge part |
| KR200211973Y1 (en) * | 2000-08-25 | 2001-02-01 | 황석화 | Transfer paper |
| KR100282701B1 (en) * | 1996-12-03 | 2001-02-15 | 정종석 | Gravure transcripts used for nonabsorbable surfaces such as metal plates and transfer methods using them |
| KR20020019942A (en) * | 2002-02-01 | 2002-03-13 | 주식회사 신성퍼니처 | Edge for furniture |
-
2002
- 2002-02-04 KR KR10-2002-0006249A patent/KR100486659B1/en not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH038966A (en) * | 1989-06-02 | 1991-01-16 | Goyo Shiko Kk | Interior material and its manufacture |
| KR100282701B1 (en) * | 1996-12-03 | 2001-02-15 | 정종석 | Gravure transcripts used for nonabsorbable surfaces such as metal plates and transfer methods using them |
| JPH111656A (en) * | 1997-06-12 | 1999-01-06 | Hodogaya Kenzai Kogyo Kk | Aqueous primer composition |
| KR100272202B1 (en) * | 1998-07-29 | 2000-12-01 | 정종석 | Heating transcription film and method copyig of direct on the mdf plane and the edge part |
| KR200211973Y1 (en) * | 2000-08-25 | 2001-02-01 | 황석화 | Transfer paper |
| KR20020019942A (en) * | 2002-02-01 | 2002-03-13 | 주식회사 신성퍼니처 | Edge for furniture |
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| KR20030066086A (en) | 2003-08-09 |
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