KR100486092B1 - Cleasing agent having the effects of antibiotic and deodorization - Google Patents

Abstract

The present invention relates to a cleaning agent having an antibacterial and deodorizing effect, which is 0.1 to 0.5% by weight of anionic surfactant; 0.2 to 0.5% by weight of natural apricot flavor; 5-30% by weight of ethyl alcohol; 0.002-0.007 wt% chloromethyl isociazoline; 0.001-0.008% by weight methyl isocyazoline; 0.05 to 0.15 wt% magnesium salt; And the remainder are integers.

Such detergents can be used as a tissue by using a cleaning agent used as a liquid itself, a detergent used for spraying, and a liquid detergent such as papers or textiles cut to a predetermined size to be used as tissues, furniture, Kitchen goods, toilet (toilet) and toiletries, there is an advantage that can be widely used in electrical and electronic equipment.

Description

Cleaning agent having the effects of antibiotic and deodorization

The present invention relates to a cleaning agent having an antibacterial and deodorizing effect, and more particularly, to anionic surfactant, natural apricot flavor and ethyl alcohol, chloromethyl isociazoline, methyl isociazoline, magnesium salt, and purified water. It is intended to provide a cleaning agent having antibacterial and deodorizing effect to make the cleaning agent harmless to the human body and apply it to various indoor and outdoor, as well as bed mattresses, various textile products, kitchen utensils to have antibacterial and deodorizing power.

Generally used antibacterial and deodorant is a chlorine-based disinfectant Rox (Rox) is a representative, Lax exhibits a strong antibacterial activity because it exhibits antibacterial and deodorant effect by the generator oxygen generated from hypochlorous acid (HClO).

However, these antibacterial and deodorizing agents are harmful to the skin due to their high alkalinity, and they are reluctant to be used due to the anxiety about the safety of users due to their toxicity. Sea interest is gradually increasing.

The object of antibacterial and deodorization in the above living environment is various indoor spaces (rooms, kitchens, toilets, and other furnitures), bed mattresses, various textile products, kitchen appliances, home appliances (hereinafter referred to as "sources of pollution"). Their pollutants include not only insect excretion and decay, but also amine compounds such as basic ammonia and trimethylamine, sulfide compounds such as acidic hydrogen sulfide and methylmecaptan, and aldehyde compounds such as acetaldehyde having a low volatile point. Various methods have been used in the past for the purpose of removing the substance.

First, the chemical removal method is to change the antibacterial and odorous substances into decomposed or odorless compounds by acting highly reactive substances to antibacterial and odorous components using chemical reactions such as neutralization, addition, polymerization, oxidation, reduction, and hydrolysis. It is a method of removing the antibacterial and odorous substances as a way to make.

Secondly, the physicochemical removal method is a compound having strong adsorption and trapping ability such as activated carbon, silica and cyclodextrin, which adsorbs or collects antibacterial and odor components on the surface, or absorbs by high boiling point solvent, surfactant, etc. It is a method to remove antibacterial and odorous substances by using higher alcohol and synthetic resin.

Third, the biochemical removal method is to block the generation of odor components by bacteria by sterilizing action by amphoteric surfactants, fungicides, etc., or by decomposing organic acids as odor components by using digestive enzymes, bacteria, yeast, etc. How to remove.

Fourth, as a sensory antibacterial and deodorizing method, mainly ammonia, Amines, acids, alcohols, aldehydes, ketones, phenolics, polycyclics, indoles, aromatics, polyaromatics Basic compounds such as c) or volatilized compounds, and sulfide compounds such as thiol, mercaptane, and sulfide.

Until now, antimicrobial and deodorization technology has focused on masking method that prevents the development of odor, etc., mainly by using fragrance, but the odor component remains as it is when the fragrance is volatilized. Will remain.

Recently, researches on antibacterial and deodorant which can fundamentally eliminate antibacterial and deodorant have been actively conducted, and representative examples thereof include cyclodextrine, which is a cyclic polysaccharide, and a metal mineral component. It has been introduced to deodorize by spraying on the surface of clothing and textiles by adding incense (U.S. Patent Nos. 5,534,165, 5,593,670, 5,668,097, 5,714,137, 5,882,638), which mask the incense. While metal ions chemically decompose malodorous substances and cyclo dextrine decomposes while moisture is dried, it describes a method of removing antibacterial and malodorous substances.

This technology has almost no damage to the fiber and shows excellent deodorizing effects on basic odors such as ammonia and amine compounds and volatilized odorants such as tobacco odors, but acidic odors such as kimchi vegetable odor and food odor. There is a drawback that almost no effect.

Cyclodextrins composed of glucose can cause microorganisms to multiply without proper use of antimicrobial agents and preservatives, and mold can easily grow even if they remain for a long time, causing odor or discoloration. There is also a bad problem.

The present invention is an anionic surfactant that removes the general time and gives the stability of the detergent, natural apricot flavor and ethyl alcohol that gives the aromatic and deodorizing power, chloromethyl isociazoline, methyl isociazoline, magnesium It is an object of the present invention to provide a detergent having a good antibacterial and deodorizing effect, which is harmless to the human body, neutral, volatile and degradable by using salt and purified water.

Characteristic technical configuration of the cleaning agent having an antibacterial and deodorizing effect of the present invention for achieving the above object is anionic surfactant, natural apricot flavor, ethyl alcohol, chloromethyl isociazoline, methyl isociazoline, magnesium salt, water purification It consists of, and it is made to maintain pH 6-8. In addition, 0.15 to 0.5% by weight of Na ₂ CO ₃ was added to improve the cleaning power of the cleaning agent.

And, the cleaning agent of the present invention can be divided into three uses, the first is a cleaning agent used as a liquid itself, the second is a cleaning agent used for spraying, the third is cut to a predetermined size It is liquid in paper or textile materials The detergent can be used to make a tissue.

The use of the cleaner as the liquid itself means that the liquid detergent is metal. PVC. Surface treated (varnished) wood. Glass. It means that it is used by directly buried in a hard place, and used for spraying means spraying in a sealed container in the air or using a spray nozzle, etc. it means. In addition, the tissue is literally packaged by rinsing a liquid detergent with paper or textile material cut to a predetermined size.

Referring to the role of each component and the amount used thereof to form a cleaning agent having an antibacterial and deodorizing effect of the present invention as described above are as follows.

Anionic surfactant (Sudinm Louryl Ether Sulfate: SLES) among the components forming the detergent according to the present invention is a high alcohol type synthesized from vegetable oils such as palm oil or palm oil, and has a short biodegradation period, and serves to remove surface activation and general time. The amount of the used detergent is 0.1 to 0.5% by weight of the total amount of the detergent.

Product name of the anionic surfactant is MICOLIN ES-430 (Sodium laureth (3) sulfate),

The molecular structure is CH _3- (CH ₂ ) ₁₀ -CH _2- (CH ₂ CH ₂ O) ₃ -O-SO ₃ Na,

Physical properties Solubility (water): Solubility. pH: 6.0-7.0 (3% aqueous solution).

The amount of the anionic surfactant is 0.1 to 0.5% by weight of the total amount of the detergent, First, when used as a liquid itself is preferably 0.3 to 0.5% by weight, and when used for spraying is preferably 0.15 to 0.5% by weight, when used for tissues, the detergent used as the liquid itself is a water content of 200 It is used to hydrate paper or textile materials to less than%.

The reason for using 0.1 to 0.5% by weight of the anionic surfactant is that less than (0.1% by weight) lowers the surfactant activity and the general removal ability, and when more than (0.5% by weight) is used The rate is good but there is a problem that can not exhibit the efficacy of the detergent pursuant to the present invention because other components should be used relatively less. Therefore, the amount of the anionic surfactant in the composition forming the detergent according to the present invention is preferably 0.1 to 0.5% by weight.

In addition, natural apricot (Appicot) fragrance plays a role to give the cleaning agent aroma, which is apricot scent with good volume and sustainability by combining Musk with Green Sweet Appicot,

cis-3-Hexenol CFR 172.515

r-Decalactone CFR 172.515

ALD C-14 CFR 172.515

cis-3-Hexenyl Salicylate RIFM ID NO. 595

Galaxolide RIFM ID NO. It consists of 628.

The amount of the natural apricot fragrance composed of the above components is 0.2 to 0.5% by weight, and when used as the liquid itself, it is preferably 0.2 to 0.5% by weight. When used for spraying, it is preferable to use 0.3 to 0.5% by weight, and when used for tissue, it is preferable to use the cleaning agent used as the liquid itself as water in papers or textile materials.

The reason why the amount of the natural apricot flavor used is 0.2 to 0.5% by weight is less than that (0.2% by weight). There is a problem in that the concentration is too thick to reverse. Therefore, the amount of natural apricot flavor is preferably used 0.2 to 0.5% by weight.

In addition, ethyl alcohol is a deodorant that is mixed with natural apricot flavor and removes unpleasant odors to maintain indoor and outdoor comfort and cleanliness. The amount of the ethyl alcohol is 5 to 30% by weight, preferably 5 to 10% by weight when used as a liquid itself, 25 to 30% by weight when used for spraying, and used for tissue In this case, it is preferable to use the cleaning agent used as the liquid itself as water in papers or fibers.

When the ethyl alcohol is used at 5% by weight or less, the deodorizing effect is lowered, and when 30% by weight or more is used, the deodorizing effect may be improved, but other components should be used relatively little to maintain the balance of efficacy of the detergent required in the present invention. Failure to do so may occur. Therefore, the amount of ethyl alcohol is preferably used 5 to 30% by weight.

The cleaning agent contains chloromethyl isociazoline (Chloro methyl) as an antibacterial agent. isothiazolin) 0.002 to 0.007% by weight, methyl isothiazolin (0.001% to 0.008%) and magnesium salts 0.05 to 0.15% by weight.

The reason for limiting the use range of each of the antimicrobial agents is that there is a problem that the antimicrobial activity is lowered when using less than that, the antimicrobial power may be improved when using more than that, but the compatibility of the surfactant is not good, and the stability is lowered have.

Such antimicrobial agents are used for indoor and outdoor, fungal yeasts, such as bed mattresses, various textile products and kitchen utensils, for the purpose of growth control and antibacterial, and the effect is maintained at room temperature for more than one year, pH is 2 It is stable at -9 and does not contain formaldehide.

In the antimicrobial agent, the composition of chloromethyl isociazoline is 5-Chloro-2-methyl-4- isothiazolin-3-one, methyl isociazoline is Methyl-4- isothiazolin-3-one, and magnesium salt is an additive. Used.

In addition, Na ₂ CO ₃ of the present invention functions to easily wash when there is a thin time in the article to be cleaned in the efficacy of the cleaning agent, the amount of use is preferably 0.15 to 0.5% by weight of the entire cleaning agent Do. However, Na ₂ CO ₃ is preferably used by adding to the cleaning agent used as the liquid itself.

The remainder other than the composition forming the detergent described above is pure water, that is, purified water, and the pH value of the manufactured detergent is maintained at 6 to 8, which is neutral, and is a non-toxic cleaner.

As described above, the detergent of the present invention is a surfactant synthesized in a vegetable oil such as palm oil or palm oil, an apricot flavor with excellent aromaticity and an antibacterial agent with high biodegradability, and ethyl alcohol synthesized with the apricot flavor to exert deodorizing power. By using it, the pH is maintained at 6-8, which is close to neutral, and it is harmless to human body because it is not toxic, and it has the advantages of excellent biodegradability as well as cleaning and antibacterial function and deodorizing function to maintain a pleasant atmosphere indoors and outdoors. There is a distinctive effect.

In addition, the cleaning agent of the present invention can be used as a tissue by the use of the liquid cleaning agent to be used as a liquid itself, a cleaning agent used for spraying and paper or textile materials cut to a predetermined size, There is an advantage that can be widely used in furniture, kitchenware, washroom (toilet) and toiletries, electrical and electronic equipment.

Claims (4)

0.1 to 0.5% by weight of anionic surfactant; 0.2 to 0.5% by weight of natural apricot flavor; 5-30% by weight of ethyl alcohol; 0.002-0.007 wt% chloromethyl isociazoline; 0.001-0.008% by weight methyl isocyazoline; 0.05 to 0.15 wt% magnesium salt; 0.15 to 0.5% by weight of Na ₂ CO ₃ and the remainder of the clean water, and has a liquid antibacterial and deodorizing efficacy of maintaining a pH of 6 to 8. The method of claim 1, wherein the anionic surfactant 0.15 to 0.5% by weight; 0.3 to 0.5% by weight of natural apricot flavor; 25-30 wt% ethyl alcohol; 0.006-0.007% by weight of chloromethyl isociazoline; 0.001% to 0.003% by weight methyl isocyazoline; Magnesium salt 0.1 to 0.15% by weight and the remainder is made of purified water, a detergent having an antibacterial and deodorizing effect for indoor spray to maintain pH 6-8. delete According to claim 1, wherein the antimicrobial and deodorizing efficacy of the antibacterial and deodorizing effect, characterized in that the tissue is cut to a predetermined size so that the moisture content of 200% or less Cleaning tissues having high performance.