KR100466397B1 - Manufacturing method of semiconductor device - Google Patents
Manufacturing method of semiconductor device Download PDFInfo
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- KR100466397B1 KR100466397B1 KR10-1998-0045441A KR19980045441A KR100466397B1 KR 100466397 B1 KR100466397 B1 KR 100466397B1 KR 19980045441 A KR19980045441 A KR 19980045441A KR 100466397 B1 KR100466397 B1 KR 100466397B1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims abstract description 23
- 229910021417 amorphous silicon Inorganic materials 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- 239000012535 impurity Substances 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 230000004913 activation Effects 0.000 claims abstract description 8
- 150000002500 ions Chemical class 0.000 claims abstract description 6
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 5
- 229920005591 polysilicon Polymers 0.000 claims abstract description 5
- 238000000059 patterning Methods 0.000 claims abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 238000001039 wet etching Methods 0.000 claims description 2
- 239000010408 film Substances 0.000 abstract description 29
- 238000009792 diffusion process Methods 0.000 abstract description 5
- 239000010409 thin film Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/08—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/0843—Source or drain regions of field-effect devices
- H01L29/0847—Source or drain regions of field-effect devices of field-effect transistors with insulated gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/26506—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
- H01L21/26513—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors of electrically active species
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
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- Engineering & Computer Science (AREA)
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- Power Engineering (AREA)
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- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
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Abstract
본 발명은 소오스 및 드레인의 형성시 채널쪽으로의 확산을 효과적으로 방지하여 균일한 접합을 형성할 수 있는 반도체 소자의 제조방법을 제공한다.The present invention provides a method for manufacturing a semiconductor device capable of forming a uniform junction by effectively preventing diffusion into the channel when forming the source and drain.
본 발명에 따른 반도체 소자의 제조방법은 필드 산화막이 형성된 반도체 기판 상에 게이트 산화막 및 비정질 실리콘막을 형성하는 단계; 비정질 실리콘막 및 게이트 산화막을 패터닝하여 비정질 실리콘 게이트를 형성하는 단계; 기판으로 소오스 및 드레인용 불순물 이온을 이온주입하여 상기 비정질 실리콘 게이트를 도핑시킴과 동시에 비정질 실리콘 게이트 양 측의 기판을 비정질화시켜 도핑된 비정질화 영역을 형성하는 단계; 기판 전면에 불순물 활성화 촉매용 금속막을 초박막으로 형성하는 단계; 기판을 저온에서 열처리하여 도핑된 폴리실리콘 게이트를 형성함과 동시에 결정화된 소오스 및 드레인 영역을 형성하는 단계; 및, 열처리시 미반응된 촉매용 금속막을 제거하는 단계를 포함한다.A method of manufacturing a semiconductor device according to the present invention includes forming a gate oxide film and an amorphous silicon film on a semiconductor substrate on which a field oxide film is formed; Patterning the amorphous silicon film and the gate oxide film to form an amorphous silicon gate; Implanting impurity ions for a source and a drain into a substrate to dope the amorphous silicon gate and at the same time to amorphous the substrate on both sides of the amorphous silicon gate to form a doped amorphous region; Forming a metal film for the impurity activation catalyst into an ultra-thin film on the entire surface of the substrate; Heat treating the substrate at a low temperature to form a doped polysilicon gate and simultaneously forming crystallized source and drain regions; And removing the unreacted metal film for the catalyst during the heat treatment.
Description
본 발명은 반도체 소자의 제조방법에 관한 거스올, 특히 얕은 접합을 가지는 고집적 반도체 소자의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a semiconductor device, in particular a method for manufacturing a highly integrated semiconductor device having a shallow junction.
반도체 소자의 고집적화에 따라, MOS 소자의 소오스 및 드레인 간의 채널길이가 짧아지면서 높은 전류하에서도 신뢰성을 유지할 수 있는 소자에 대한 연구가 지속되고 있다. 한편, 짧은 채널길이를 갖는 MOS 소자는 드레인 전압이 증가함에 따라, 핀치오프(pinch-off) 보다는 펀치쓰루(punch-through)가 발생하므로, 채널 내의 전기적 포텐셜과 전기장을 결정하는 것이 소자의 특성을 좌우하게 된다. 이러한 단채널 효과(short channel effect)에 의한 소자의 특성저하를 방지하기 위하여, 소오스 및 드레인의 접합깊이를 얕게 형성하는 방법이 제시되었다. 즉, 측면확산 정도는 접합깊이에 비례하기 때문에, 접합깊이를 얕게 함으로써 단채널 효과를 감소시킨다.As semiconductor devices become more integrated, research on devices capable of maintaining reliability under high current while reducing channel length between sources and drains of MOS devices continues. On the other hand, in a MOS device having a short channel length, as the drain voltage increases, punch-through occurs rather than pinch-off. Therefore, determining the electric potential and the electric field in the channel may determine the characteristics of the device. It will depend. In order to prevent device deterioration due to such a short channel effect, a method of forming a shallow junction depth between the source and the drain has been proposed. That is, since the side diffusion is proportional to the junction depth, the short channel effect is reduced by making the junction depth shallow.
그러나, 상기한 바와 같은 종래의 소오스 및 드레인은 불순물을 고온에서 활성화시키기 때문에, 채널쪽으로의 원치않는 확산등이 발생되어 소오스 및 드레인의 균일한 접합을 형성하기가 어려울 뿐만 아니라, 단채널 효과에 의한 소자 특성 저하를 유발하게 된다.However, the conventional sources and drains as described above activate impurities at a high temperature, so that unwanted diffusion and the like toward the channel occur, making it difficult to form a uniform junction of the source and drain, and also due to the short channel effect. Deterioration of device characteristics is caused.
따라서, 본 발명은 상기한 종래의 문제점을 해결하기 위한 것으로서, 소오스 및 드레인의 형성시 채널쪽으로의 확산을 효과적으로 방지하여 균일한 접합을 형성할 수 있는 반도체 소자의 제조방법을 제공함에 그 목적이 있다.Accordingly, an object of the present invention is to provide a method of manufacturing a semiconductor device capable of forming a uniform junction by effectively preventing diffusion into a channel when forming a source and a drain. .
상기 목적을 달성하기 위한 본 발명에 따른 반도체 소자의 제조방법은 필드 산화막이 형성된 반도체 기판 상에 게이트 산화막 및 비정질 실리콘막을 형성하는 단계; 비정질 실리콘막 및 게이트 산화막을 패터닝하여 비정질 실리콘 게이트를 형성하는 단계; 기판으로 소오스 및 드레인용 불순물 이온을 이온주입하여 상기 비정질 실리콘 게이트를 도핑시킴과 동시에 비정질 실리콘 게이트 양 측의 기판을 비정질화시켜 도핑된 비정질화 영역을 형성하는 단계; 기판 전면에 불순물 활성화 촉매용 금속막을 초박막으로 형성하는 단계; 기판을 저온에서 열처리하여 도핑된 폴리실리콘 게이트를 형성함과 동시에 결정화된 소오스 및 드레인 영역을 형성하는 단계; 및, 열처리시 미반응된 촉매용 금속막을 제거하는 단계를 포함한다.A semiconductor device manufacturing method according to the present invention for achieving the above object comprises the steps of forming a gate oxide film and an amorphous silicon film on a semiconductor substrate on which a field oxide film is formed; Patterning the amorphous silicon film and the gate oxide film to form an amorphous silicon gate; Implanting impurity ions for a source and a drain into a substrate to dope the amorphous silicon gate and at the same time to amorphous the substrate on both sides of the amorphous silicon gate to form a doped amorphous region; Forming a metal film for the impurity activation catalyst into an ultra-thin film on the entire surface of the substrate; Heat treating the substrate at a low temperature to form a doped polysilicon gate and simultaneously forming crystallized source and drain regions; And removing the unreacted metal film for the catalyst during the heat treatment.
본 실시예에서, 불순물 활성화 촉매용 금속막은 Ni, Pd, Pt, W, Cr, Co, Cu, Al, Sn, P, As, Sb, Ag, In의 단일원소 또는 2종류 이상의 혼합원소로 이루어진 그룹으로부터 선택되는 하나의 원소를 이용하여 형성하고, 바람직하게 3 내지 100Å의 두께로 형성한다. 또한, 열처리는 350 내지 600℃의 온도에서, 엑시머 레이저 열처리 방법, UV 열처리 방법, 급속 열처리 방법 또는 저항가열식 노열처리 방법등을 이용하여 진행한다.In this embodiment, the metal film for impurity activation catalyst is a group consisting of a single element of Ni, Pd, Pt, W, Cr, Co, Cu, Al, Sn, P, As, Sb, Ag, In, or two or more kinds of mixed elements. It is formed using one element selected from, and is preferably formed in a thickness of 3 to 100 kPa. In addition, heat treatment is performed using an excimer laser heat treatment method, a UV heat treatment method, a rapid heat treatment method or a resistance heating furnace treatment method at a temperature of 350 to 600 ℃.
이하, 첨부된 도면을 참조하여 본 발명의 실시예를 설명한다.Hereinafter, with reference to the accompanying drawings will be described an embodiment of the present invention.
도 1a 내지 도 1c는 본 발명의 실시예에 따른 반도체 소자의 제조방법을 설명하기 위한 단면도이다.1A to 1C are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with an embodiment of the present invention.
도 1a를 참조하면, 실리콘을 포함하는 반도체 기판(10) 상에 공지된 LOCOS(LOCal Oxidation of Silicon) 기술로 소자간 분리를 위한 필드 산화막(11)을 형성한다. 기판 전면에 게이트 산화막(12)을 증착하고, 게이트 산화막(12) 상에 비정질 실리콘막을 증착한다. 그런 다음, 비정질 실리콘막 및 게이트 산화막(12)을 패터닝하여 게이트 산화막(12)이 개재된 비정질 실리콘 게이트(13)를 형성한다. 그런 다음, 기판으로 소오스 및 드레인용 불순물 이온을 주입하여, 상기 비정질 실리콘 게이트 양 측의 기판을 비정질화시켜 도핑된 비정질화 영역(14a, 14b)을 형성함과 동시에, 상기 비정질 실리콘 게이트(13)를 도핑시킨다. 즉, 불순물 이온의 주입시 데미지(damage)에 의해 결정체 실리콘이 비정질화된다.Referring to FIG. 1A, a field oxide layer 11 is formed on a semiconductor substrate 10 including silicon by a known LOCOS (LOCal Oxidation of Silicon) technique. A gate oxide film 12 is deposited on the entire surface of the substrate, and an amorphous silicon film is deposited on the gate oxide film 12. Then, the amorphous silicon film and the gate oxide film 12 are patterned to form an amorphous silicon gate 13 with the gate oxide film 12 interposed therebetween. Thereafter, source and drain impurity ions are implanted into the substrate to amorphousize the substrate on both sides of the amorphous silicon gate to form doped amorphous regions 14a and 14b, and at the same time, the amorphous silicon gate 13 Doping That is, crystalline silicon is amorphous by damage during implantation of impurity ions.
도 1b를 참조하면, 도 1a의 구조 상에 초박막(ultra thin film), 바람직하게 3 내지 100Å의 두께로 불순물 활성화 촉매용 금속막(15)을 증착한다. 여기서, 촉매용 금속막은 Ni, Pd, Pt, W, Cr, Co, Cu, Al, Sn, P, As, Sb, Ag, In의 단일원소 또는 2종류 이상의 혼합원로소로 이루어진 그룹으로부터 선택되는 하나의 원소를 이용하여 형성한다. 이러한 촉매용 금속막(15)은 열처리시 비정질화영역과만 반응하고, 비정질화 영역을 결정화시키는데 촉매(catalyst)로서 작용하여, 낮은 온도의 열처리에서 불순물의 활성화 및 결정화를 가능하게 한다.Referring to FIG. 1B, the metal film 15 for impurity activation catalyst is deposited on the structure of FIG. 1A to an ultra thin film, preferably 3 to 100 kPa. Here, the catalyst metal film is one selected from the group consisting of a single element of Ni, Pd, Pt, W, Cr, Co, Cu, Al, Sn, P, As, Sb, Ag, In, or two or more types of mixed elements. It is formed using the element of. The catalyst metal film 15 reacts only with an amorphous region during heat treatment and acts as a catalyst to crystallize the amorphous region, thereby enabling activation and crystallization of impurities in a low temperature heat treatment.
도 1c를 참조하면, 상기 촉매용 금속막(15)이 증착된 기판을 저온, 바람직하게 350 내지 600℃의 온도에서 열처리시켜, 도핑된 비정질 실리콘 게이트(13) 및 도핑된 비정질화 영역(14a, 14b; 도 1a 참조)을 결정화시킴으로써, 도핑된 폴리실리콘 게이트(17)를 형성함과 동시에 결정화된 소오스 및 드레인 영역(16a, 16b)을 형성한다. 여기서, 열처리는 엑시머 레이저 열처리 방법, UV 열처리 방법, 급속 열처리 방법 또는 저항가열식 노열처리 방법등을 이용하여 진행한다. 그런 다음, 미반응된 촉매용 금속막(15)을 습식식각으로 제거한다. Referring to FIG. 1C, the substrate on which the catalyst metal film 15 is deposited is heat-treated at a low temperature, preferably at a temperature of 350 to 600 ° C., so that the doped amorphous silicon gate 13 and the doped amorphous region 14a, Crystallizing 14b (see FIG. 1A) to form a doped polysilicon gate 17 and simultaneously crystallized source and drain regions 16a and 16b. Here, the heat treatment is performed using an excimer laser heat treatment method, UV heat treatment method, rapid heat treatment method or resistance heating type heat treatment method. Then, the unreacted catalyst metal film 15 is removed by wet etching.
상기한 본 발명에 의하면, 소오스 및 드레인 영역의 형성시 불순물 이온을 주입하여 비정질화시키고, 결정화를 돕는 촉매를 이용하여 낮은 온도에서 열처리를 진행하기 때문에, 원치않는 채널영역으로의 불순물 확산을 효과적으로 방지할 수 있다. 이에 따라, 단채널 효과에 의한 소자의 특성저하를 방지할 수 있으므로 고집적 소자에 적용하기가 용이해진다. 또한, 게이트의 도핑을 소오스 및 드레인의 형성시 동시에 진행할 수 있기 때문에 공정이 단순해짐과 더불어 원가절감의 효과를 얻을 수 있다.According to the present invention described above, since impurity ions are implanted and amorphous during implantation of the source and drain regions, heat treatment is performed at a low temperature using a catalyst that helps crystallization, thereby effectively preventing the diffusion of impurities into unwanted channel regions. can do. As a result, deterioration of the characteristics of the device due to the short channel effect can be prevented, so that application to the highly integrated device is facilitated. In addition, since the doping of the gate can be simultaneously performed at the time of forming the source and the drain, the process can be simplified and the cost reduction effect can be obtained.
또한, 본 발명은 상기 실시예에 한정되지 않고, 본 발명의 기술적 요지를 벗어나지 않는 범위내에서 다양하게 변형시켜 실시할 수 있다.In addition, this invention is not limited to the said Example, It can variously deform and implement within the range which does not deviate from the technical summary of this invention.
도 1a 내지 도 1c는 본 발명의 실시예에 따른 반도체 소자의 제조방법을 설명하기 위한 단면도.1A to 1C are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with an embodiment of the present invention.
〔도면의 주요 부분에 대한 부호의 설명〕[Description of Code for Major Parts of Drawing]
10 : 반도체 기판 11 : 필드 산화막10 semiconductor substrate 11 field oxide film
12 : 게이트 산화막 13 : 비정질 실리콘 게이트12 gate oxide film 13 amorphous silicon gate
14a, 14b : 도핑된 비정질화 영역14a, 14b doped amorphous region
15 : 불순물 활성화 촉매용 금속막15 metal film for impurity activation catalyst
16a, 16b : 결정화된 소오스 및 드레인 영역16a, 16b: crystallized source and drain regions
17 : 도핑된 폴리실리콘 게이트17: doped polysilicon gate
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