KR100452934B1 - Method for preparing high-quality bamboo-salt-fermented pollack roe products - Google Patents

Method for preparing high-quality bamboo-salt-fermented pollack roe products Download PDF

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KR100452934B1
KR100452934B1 KR10-2002-0027084A KR20020027084A KR100452934B1 KR 100452934 B1 KR100452934 B1 KR 100452934B1 KR 20020027084 A KR20020027084 A KR 20020027084A KR 100452934 B1 KR100452934 B1 KR 100452934B1
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salt
bamboo
bamboo salt
salted
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KR20030089625A (en
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오광수
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대한민국 (경상대학교 총장)
정찬홍
강수태
최철용
최주은
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/65Addition of, or treatment with, microorganisms or enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/02Preserving by means of inorganic salts
    • A23B4/023Preserving by means of inorganic salts by kitchen salt or mixtures thereof with inorganic or organic compounds
    • A23B4/0235Preserving by means of inorganic salts by kitchen salt or mixtures thereof with inorganic or organic compounds with organic compounds or biochemical products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/30Fish eggs, e.g. caviar; Fish-egg substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • A23L27/105Natural spices, flavouring agents or condiments; Extracts thereof obtained from liliaceae, e.g. onions, garlic
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30Artificial sweetening agents
    • A23L27/33Artificial sweetening agents containing sugars or derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/358Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/10Preserving against microbes

Abstract

본 발명은 기존의 천일염을 사용하여 제조한 수산 발효 식품에 비해 제품의 조직감, 지질의 산화억제, 고도불포화지방산의 잔존율, 제품의 냄새 측면에서 훨씬 우수하고, 죽염이 갖는 약리 효과 등을 고려할 때 고품질의 수산 발효 식품을 제조할 수 있고, 저장 유통 기간도 4개월 이상으로 연장이 가능한 3회 및 9회 죽염을 이용한 명란 젓갈의 제조 방법을 제공하기 위한 것이다.The present invention is much better in terms of texture of the product, oxidation inhibition of lipids, residual ratio of polyunsaturated fatty acids, odor of the product, and the pharmacological effects of bamboo salt compared to the conventional fermented food prepared using sun salt. To provide a high-quality fish fermented seafood, and to provide a method for producing spicy cod roe salt using bamboo salt 3 times and 9 times can be extended to 4 months or more.

Description

고품질의 죽염 명란 젓갈의 제조 방법{Method for preparing high-quality bamboo-salt-fermented pollack roe products}Method for preparing high-quality bamboo salt cod roe salt {Method for preparing high-quality bamboo-salt-fermented pollack roe products}

본 발명은 고품질의 죽염 명란 젓갈의 제조 방법에 관한 것이다. 더욱 상세하게는 죽염을 이용하여 기존의 수산 발효 식품, 예를 들면 명란 젓갈 등을 고품질화하고, 저장 유통 기간도 연장시킨 죽염 명란 젓갈 제품의 제조 방법에 관한 것이다.The present invention relates to a method for producing high quality bamboo salt cod roe salt. More specifically, the present invention relates to a method for producing a bamboo salt fermented salted fish product, which is made of bamboo salt, which has been used to increase the quality of existing fish fermented foods, for example, spicy cod roe salt, and also extends shelf life.

최근 소득 향상에 따른 식생활의 개선으로 인해 천연 자연 식품에 대한 관심이 높아지면서 민간 요법으로 내려오는 우리나라 전통의 소재에 대하여 많은 관심이 모아지고 있다.Recently, as interest in natural foods has increased due to the improvement of diet due to income improvement, much attention has been paid to the material of Korean tradition that comes down to folk remedies.

그 중 대표적 기능성 소재의 하나인 죽염(竹鹽, Bamboo salt)은 옛날부터 우리 조상들이 대나무나 도자기 등에 소금을 넣고 고온에서 구워 소화제나 양치용 소금 등으로 사용하여 왔던 일종의 민속 의약품으로, 지금까지 그 효능과 가치가 제대로 알려지지 못하였으나, 최근 들어 전통 비법을 통해 제조한 죽염의 약리 효능 등 그 기능 특성에 관한 연구가 조금씩 수행되고 있으며, 그 연구 결과가 일부 학술지에 발표되고 있다.Bamboo salt, one of the representative functional materials, is a kind of folk medicine that our ancestors have been using in the past to add salt to bamboo or pottery and bake it at high temperatures. Efficacy and value are not well known, but researches on its functional characteristics, such as pharmacological efficacy of bamboo salt prepared by traditional methods, have been conducted little by little, and the results of the research have been published in some journals.

소금의 종류는 크게 천일염과 정제염으로 나누어지며, 정제염은 다시 제재염과 가공염으로 분류된다. 제재염은 원료 소금을 용해, 탈수, 건조 등의 과정을 거쳐 다시 재결정화시켜 제조한 소금을 말하며, 가공염은 배소 등 가공 공정을 거친 식염을 말하는 것으로, 800℃ 이상의 고온에서 구워 식염 중의 유해 성분을 제거한 죽염이 여기에 속한다. 죽염은 대나무에 채워 굽고 분쇄하는 횟수 및 굽는 온도에 따라 일반적으로 3회, 9회 죽염, 단염, 자죽염 등으로 나눌 수 있다.즉, 850 내지 1,000℃의 굽는 온도에서 굽기를 3회 반복하여서 된 것을 3회 죽염, 1,300 내지 1,500℃의 굽는 온도에서 굽기를 9회 반복하여서 된 것을 9회 죽염이라고 한다.Salt is divided into natural salt and refined salt, and refined salt is classified into lumber salt and processed salt. Sanction salt refers to salt prepared by recrystallizing the raw material salt after dissolving, dehydrating and drying. Process salt refers to salt that has been processed through roasting, etc. Removed bamboo salt belongs to this. Bamboo salt can be generally divided into three times, nine times bamboo salt, mono salt, porridge salt, etc., depending on the number of times the baking and grinding and filling temperature in the bamboo, i.e. by baking three times at a baking temperature of 850 to 1,000 ℃ It is called nine bamboo salts by three times of bamboo salt and nine times of baking at the baking temperature of 1,300-1,500 degreeC.

순수 소금(Sigma Co.과 Merck Co.) 2종, 3회 및 9회 죽염의 X-선 회절분석기(X-ray diffractometer :XRD) 분석 결과를 도 1에 나타내었다. 측정 조건은 Riguku D/Max-3C 분석기를 이용하여 30kV, 40mA의 출력과 Cu를 양극의 타겟으로 이용하였고, 측정 범위는 2 시타(Theta)가 20 ~ 80°, 10°/min씩 0.01 간격으로 스캔하여 연속적인 조건으로 측정하였다.X-ray diffractometer (XRD) analysis results of two, three and nine bamboo salts of pure salt (Sigma Co. and Merck Co.) are shown in FIG. 1. The measurement conditions were 30kV, 40mA output and Cu as the target of the anode using Riguku D / Max-3C analyzer, and the measurement range was 2 theta at 20 ~ 80 ° and 10 ° / min in 0.01 steps. Scanning was performed under continuous conditions.

이러한 조건에 의해 측정된 소금과 죽염(3회 및 9회)들의 X-선 회절분석기(XRD) 분석 패턴을 보면 결정면에 대하여 회절된 X-선이 나타난 회절 각도의 위치는 같았고, 상대적인 강도 차이만 조금씩 있었으나, 대체로 순수 소금과 죽염간의 X-선 회절분석기(XRD) 패턴상의 차이는 없었다. X-선 회절분석기(XRD) 상에 나타난 피크들의 2 시타 위치와 면간 거리를 참조하여 Hanawalt 법으로 동정한 결과 표준 물질의 데이터베이스화 된 JCPDS(Joint Committee on Powder Diffraction Standards) 카드 번호 5-628인 염화나트륨(NaCl) 물질임을 확인할 수 있었다.The X-ray diffractometer (XRD) analysis patterns of salt and bamboo salt (three and nine times) measured by these conditions showed that the diffraction angles of the diffracted X-rays with respect to the crystal plane were the same, and only the relative intensity difference was observed. Little by little, there was generally no difference in X-ray diffractometer (XRD) pattern between pure salt and bamboo salt. Sodium Chloride, JCPDS (Joint Committee on Powder Diffraction Standards) Card No. 5-628, a database of standards, identified by the Hanawalt method with reference to the 2 theta positions and the interplanar distances of the peaks shown on an X-ray diffractometer (XRD) It was confirmed that the (NaCl) material.

JCPDS 카드 5-628에서의 XRD 측정결과와 상대강도에 따른 회절각도 2시타에 대한 위치가 일치함을 확인할 수 있었으며, 측정 분석 결과 죽염의 제조 공정에 따라 미량의 불순물이 생길 수 있겠으나, 죽염의 기본적인 염화나트륨(NaCl) 결정 구조의 변화에는 영향을 미치지 않음을 확인할 수 있었다. 한편, 소량의 연화나트륨(NaCl) 외 성분은 결정화가 되지 않아 X-선 회절분석기(XRD)상에서 검출되지 않았다.The XRD measurement results of JCPDS card 5-628 and the position of diffraction angle 2 theta according to the relative intensity were confirmed to be identical.As a result of the measurement analysis, trace impurities may be generated depending on the manufacturing process of bamboo salt. It was confirmed that the change in the basic sodium chloride (NaCl) crystal structure was not affected. On the other hand, a small amount of sodium softening (NaCl) and other components did not crystallize and were not detected on the X-ray diffractometer (XRD).

또한, 천일염과 죽염의 무기질 함량을 ICP-AES를 이용하여 측정한 결과는 다음 표 1과 같다. 표 1에 의하면, 천일염은 Ca(1,728 ppm), K(2,017 ppm), Mg(9,290 ppm) 그리고 S(3,098 ppm)가 많고, 그 외 Mn, Fe, Al, Si, P 및 Pb 등이 소량 검출되었다. 그리고, 죽염 역시 Ca(2,239 ~ 3,120 ppm), K(3,138 ~ 6,336 ppm), Mg(6,681 ~ 5,520 ppm) 및 S(4,124 ~ 8,970 ppm)가 주성분이었고, Mn, Fe, Al, Si, P 및 Pb 등이 소량 검출되었다.In addition, the results of measuring the mineral content of the sun salt and bamboo salt using ICP-AES are shown in Table 1 below. According to Table 1, natural salts are high in Ca (1,728 ppm), K (2,017 ppm), Mg (9,290 ppm) and S (3,098 ppm), and other small amounts of Mn, Fe, Al, Si, P and Pb are detected. It became. Bamboo salts were also Ca (2,239 ~ 3,120 ppm), K (3,138 ~ 6,336 ppm), Mg (6,681 ~ 5,520 ppm) and S (4,124 ~ 8,970 ppm), and Mn, Fe, Al, Si, P and Pb A small amount was detected.

K, Ca, Fe, Si, P 및 S 등은 죽염이 천일염에 비해 함량이 월등히 많았고, 구운 횟수가 증가할수록 상대적으로 농도가 증가하였다. 반면 Mg는 천일염이 죽염에 비해 함량이 많아 용융 횟수에 따라 Mg가 고온에 의해 연소되어 감소되었으며, 구운 횟수가 증가할수록 농도가 감소하였다. Ge의 경우 미량이기는 하나 죽염 쪽이 함량이 많았고, 구운 횟수가 증가할수록 함량이 증가하는 경향을 나타내었다.The contents of K, Ca, Fe, Si, P, and S were much higher in bamboo salt than sun salt, and the concentration increased with increasing number of roasts. On the other hand, Mg has a higher content of sun salt than bamboo salt, so Mg is burned by high temperature depending on the number of melting, and the concentration decreases as the number of roasts increases. In the case of Ge, the content of bamboo salt was higher in the case of trace, and the content increased as the number of roasts increased.

Na 함량은 죽염의 경우 32.92 ~ 33.21%로서 천일염에 비해 약간 감소하는것으로 나타났다. 식염 중에 존재하는 K, P, Si, Al, Mn 및 Fe등 일부 무기질 성분은 항고 혈압, 혈액 속의 삼투압의 조절, 신경 자극 전달, 신경 조직의 활성화 등 체내에서 생리활성을 가지는 것으로 알려져 있다.Na content was 32.92 ~ 33.21% for bamboo salt, showing a slight decrease compared to sun salt. Some minerals such as K, P, Si, Al, Mn and Fe present in salt are known to have physiological activities in the body such as antihypertensive blood pressure, control of osmotic pressure in blood, transmission of nerve stimulation, activation of nerve tissues.

그리고, 시료 소금물의 pH를 보면, 천일염은 7.89인데 비해 3회 죽염은 9.35, 9회 죽염은 9.80으로 구운 횟수가 증가할수록 점차 알칼리화 되는 경향을 나타내었다. 이같은 죽염의 알칼리화는 가공 식품에 첨가시 식품의 물성 등 품질에 영향을 미치게 된다.In addition, the pH of the sample brine showed that natural salts were 7.89, whereas three bamboo salts were 9.35, and nine bamboo salts were 9.80. This alkalinization of bamboo salt affects the quality of the food when added to the processed food.

표 1Table 1

무기질성분Inorganic components 천일염(%)Natural salt (%) 3회 죽염(%)3 bamboo salts (%) 9회 죽염(%)9 bamboo salts (%) NaMgKCaMnCrFeCoNiCuZnAlSiPSSeGeBaAsPbCdHgNaMgKCaMnCrFeCoNiCuZnAlSiPSSeGeBaAsPbCdHg 34.909,2902,0171,7384.8-5.1--0.10.612.724.745.73,098-2.60.20.045.50.090.0134.909,2902,0171,7384.8-5.1--0.10.612.724.745.73,098-2.60.20.045.50.090.01 33.216,6813,1382,2395.92.723.4-0.20.31.315.137.262.74,1240.94.60.50.02NDNDND33.216,6813,1382,2395.92.723.4-0.20.31.315.137.262.74,1240.94.60.50.02NDNDND 32.925,5206,3363,1209.50.597.5-12.12.27.117.4110.1242.28,9701.26.41.90.03NDNDND32.925,5206,3363,1209.50.597.5-12.12.27.117.4110.1242.28,9701.26.41.90.03NDNDND pHpH 7.897.89 9.359.35 9.809.80

1) ND는 검출되지 않음1) ND not detected

현재 시중에는 여러 종류의 죽염이 시판되고 있으며, 죽염에 대한 순도, 미네랄 조성, 구조 분석 및 죽염의 약리 효과 등을 규명한 연구들이 점차적으로 발표되고 있다. 최근의 건강 지향성 식생활 변화 패턴으로 볼 때, 식염 농도를 낮추어 섭취하려는 경향이 지배적이고, 식염의 단점을 보완할 수 있는 기능성 소재인 죽염을 첨가한 가공 식품들이 시장에 일부 등장하고 있으나, 이에 관련한 연구들은 거의 이루어지고 있지 않다. 즉, 우리나라 전통 식품 중 죽염을 첨가한 김치나 장류에 관한 연구가 일부 수행되고 있을 뿐, 정작 다량의 식염이 첨가되는 수산 염장품이나 젓갈류에 대한 죽염의 첨가 및 제품에 관련한 연구는 전무한 실정이다. 그러나, 우리나라 식생활의 패턴 변화, 죽염의 약리 효과와 기능성 등을 고려해 볼 때, 죽염을 이용한 이런 제품의 고품질화는 반드시 필요하고, 이와 관련한 연구들도 필히 수행되어야 할 것으로 생각된다.Currently, various types of bamboo salts are available on the market, and studies are being gradually conducted to investigate the purity, mineral composition, structural analysis, and pharmacological effects of bamboo salts on bamboo salts. In view of the recent health-oriented dietary patterns, there is a tendency to lower the concentration of salt and consume it, and there are some processed foods added with bamboo salt, a functional material that can compensate for the weakness of salt. Are rarely done. In other words, there are only a few studies on kimchi or jang with bamboo salt added to Korean traditional foods, and there is no research on the addition of bamboo salt to seafood salt products or salted fish which are added with a large amount of salt. . However, considering the changes in Korean dietary patterns, the pharmacological effects and functionality of bamboo salts, the high quality of these products using bamboo salts is essential, and related researches must be carried out.

한편, 명란 젓갈은 명태(Theragra chalcogramma)의 알을 수거하여 염장ㆍ발효시켜 만든 것으로, 아미노산 조성이 우수하고, 고도 불포화지방산 및 비타민 A가 많이 함유되어 있는 기호성이 뛰어난 고급 수산 발효 식품이다. 명란 젓갈은 매년 4,000톤 내외를 생산하고 있으며, 생산품의 대부분은 식염을 10% 정도 첨가한 저염 제품으로 공장에서 나름대로의 노-하우(Know-how)로서 대량 생산되나, 일부는 소규모 생산 업체에서 위생 관리상의 문제로 다량의 식염을 첨가하여 가공한 제품도 시장에 출하되고 있다.On the other hand, salted cod roe is made from salted and fermented eggs from Theragra chalcogramma , which is a high-quality fermented food with excellent amino acid composition and high taste of polyunsaturated fatty acids and vitamin A. Salted cod roe salt produces about 4,000 tons per year, and most of the products are low-salt products with 10% salt added. They are mass-produced as their own know-how in the factory, but some are hygienic by small producers. Due to management problems, products processed with a large amount of salt are also shipped to the market.

따라서, 명란 젓갈의 대부분이 저염 제품이기 때문에 위생적 저염화 제조 기술이 확립되어야 하며, 또한 원료 명란이 상당히 고가인 점을 고려할 때 앞으로 기능성 식품 소재인 죽염을 첨가하여 숙성ㆍ발효시킨 고품질의 죽염 명란 젓갈 제품을 생산할 필요가 있다.Therefore, since most of the salted cod roe is low salt product, hygienic low salt manufacturing technology should be established, and considering that the raw material cod is quite expensive, the high-quality bamboo salt cod roe salt ripened and fermented by adding bamboo salt, a functional food material, in the future You need to produce a product.

그래서, 본 발명자들은 죽염의 약리 효과를 이용한 고품질의 수산 발효 식품을 개발하고, 이의 산업화를 위하여, 예의 연구를 거듭한 결과, 죽염의 첨가 조건, 위생적 저온 숙성 발효 조건 등 고품질 죽염 명란 젓갈을 위한 최적 가공 공정을 확립함으로써 죽염 명란 젓갈의 저염화를 이룩함은 물론 저온 숙성 중의 성분 변화나 맛 성분 그리고 관능적 특성 등이 우수하고, 포장 및 동결 저장 중의 품질 안정성도 향상시킬 수 있는 고품질의 죽염 명란 젓갈의 제조 방법을 제공하는데 그 목적이 있는 것이다.Therefore, the present inventors have developed a high-quality fish fermented food using the pharmacological effect of bamboo salt, and for the industrialization thereof, as a result of intensive research, it is optimal for high-quality bamboo salt cod roe salt, such as bamboo salt addition conditions, hygienic low-temperature fermentation conditions By establishing a processing process, it is possible to achieve low salting of bamboo salted cod roe, as well as excellent ingredient change, taste component and sensory characteristics during low temperature aging, and high quality bamboo salted cod roe salt which can improve quality stability during packing and freezing storage. The purpose is to provide a manufacturing method.

도 1은 소금과 죽염(3회 및 9회)의 XRD 분석 결과를 나타낸 그래프이다.1 is a graph showing the results of XRD analysis of salt and bamboo salt (3 times and 9 times).

도 2은 본 발명의 죽염 명란 젓갈 제품을 촬영한 사진이다.Figure 2 is a photograph of bamboo salt spawned salted products of the present invention.

도 3는 본 발명의 죽염 명란 젓갈 제품을 포장하여 촬영한 사진이다.Figure 3 is a photograph taken by packing the bamboo salt cod roe salted products of the present invention.

도 4은 본 발명에 따른 죽염 명란 젓갈의 이화학적 및 관능적 특성을 비교ㆍ분석결과를 도시한 그래프이다.Figure 4 is a graph showing the results of comparing and analyzing the physicochemical and sensory characteristics of bamboo salt cod roe salted according to the present invention.

본 발명은 동결 명란을 실온에서 20시간 동안 해동하고, 10% 천일염 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별하는 단계; 상기 선별된 명란을 3회 죽염을 19.5중량% 포함하는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 식염 수용액 중에서 다시 수세 및 탈수하는 단계; 상기 과정으로 처리된 명란에다 3회 또는 9회 죽염을 6.8중량% 포함하는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10일 내지 15일간 숙성시키는 단계; 이어서 상기와 같이 처리된 명란 젓갈을 정형, 표면 건조 및 동결 처리하고, 진공 포장된 상태 하에서 -22℃ 내지 -18℃의 온도에서 동결 저장 및 유통시키는 것을 특징으로 하는 고품질의 죽염 명란 젓갈 제품의 제조 방법인 것이다.The present invention comprises thawing frozen frozen eggs for 20 hours at room temperature, washing and dehydrating in a 10% aqueous salt solution of sodium salt, and then screening the eggs; Immersing the selected eggs for 3 hours at a temperature of 4 ° C. in a primary seasoning solution containing 19.5% by weight of bamboo salt three times, and washing and dehydrating again in a 10% aqueous salt solution; Mixing a second seasoning liquid containing 6.8 wt% of bamboo salt three or nine times to the egg treated in the above process, and then aging at a temperature of 4 to 6 ° C. for 10 to 15 days; Subsequently, the high-quality bamboo salt cod roe salted product is characterized in that the dried cod roe salt treated as described above is frozen, surface-dried and freeze-treated and frozen stored and circulated at a temperature of -22 ° C to -18 ° C under vacuum-packed condition. It is a way.

또한, 본 발명은 염지가 끝난 명란에 3회 죽염을 19.5중량% 포함하는 1차 조미액과 3회 또는 9회 죽염을 6.8중량% 포함하는 2차 조미액으로 처리하여서 제조된 염도가 8% 미만이고, 진공 포장 상태하에서 -22℃ 내지 -18℃의 온도에서 동결 저장 및 유통시키는 것을 특징으로 하는 고품질의 죽염 명란 젓갈 제품인 것이다.In addition, the present invention is less than 8% salinity prepared by treating with the first seasoning solution containing 19.5% by weight of bamboo salt three times and the second seasoning solution containing 6.8% by weight of bamboo salt three times or nine times in the salted finished egg; It is a high-quality bamboo salt cod roe salted product characterized by freezing storage and distribution at a temperature of -22 ℃ to -18 ℃ under vacuum packaging.

이하 본 발명을 단계별로 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail step by step.

(제 1단계)(Step 1)

본 발명은 고품질의 죽염 명란 젓갈의 제조 방법에 대한 것으로 먼저 동결 명란을 실온에서 20시간 동안 해동하고, 10% 천일염 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별한다.The present invention relates to a method for producing high-quality bamboo salt spicy cod roe, first thawing the frozen sprig at room temperature for 20 hours, washing with water and dehydrating in a 10% salt solution of sodium salt, and then selecting the spicy egg.

본 발명에서 사용하는 원료 명란의 수분 함량은 70.1중량%, 조단백질은 25.3중량%, 조지방은 1.4중량%, 조회분은 2.5중량%이고, 휘발성염기질소(VBN)의 함량은 14.3mg%로써 선도는 아주 양호한 것이다.The moisture content of the raw cod roe used in the present invention is 70.1% by weight, crude protein is 25.3% by weight, crude fat is 1.4% by weight, crude ash is 2.5% by weight, and volatile basic nitrogen (VBN) is 14.3mg%. Very good one.

(제 2단계)(Step 2)

상기 선별된 명란을 3회 죽염을 19.5중량% 포함하는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 천일염 식염 수용액 중에서 다시 수세 및 탈수한다.The selected eggs are immersed for 24 hours at a temperature of 4 ° C. in a primary seasoning solution containing 19.5% by weight of bamboo salt three times, and washed and dehydrated again in a 10% salt solution of sun salt.

본 발명에서 사용하는 1차 조미액의 조성은 정제수 72중량%, 3회 죽염 19.5중량%, 설탕 3.6중량%, 솔비톨 3.6중량%, 에탄올 0.8중량%, 아스코르빈산 0.1중량%, 알라닌 0.2중량% 및 글로탐산나트륨 0.2중량%로 구성되어 있다.The composition of the primary seasoning liquid used in the present invention is 72% by weight purified water, 19.5% by weight three times bamboo salt, 3.6% by weight sugar, 3.6% by weight sorbitol, 0.8% by weight ethanol, 0.1% by weight ascorbic acid, 0.2% by weight alanine and Sodium glotamate is composed of 0.2% by weight.

(제 3단계)(Step 3)

죽염 명란 젓갈의 최적 저온 숙성 기간을 결정하기 위해 염지가 끝난 명란에 3회 또는 9회 죽염을 6.8중량% 포함하는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10 내지 15일간 숙성시킨다.To determine the optimal low-temperature maturation period of bamboo salted cod roe, a second seasoning solution containing 6.8% by weight of bamboo salt was mixed with the salted cod roe and then aged for 10 to 15 days at a temperature of 4 to 6 ° C. .

본 발명에서 사용하는 2차 조미액의 조성은 정제수 40.0중량%, 3회 죽염 또는 9회 죽염 6.8중량%, 고춧가루 20.0중량%, 설탕 4.5중량%, 솔비톨 8.8중량%, 다시마 엑기스분 2.2중량%, 물엿 13.5중량%, 글리신 1.0중량%, 마늘가루 2.2중량% 및 청주 1.0중량%로 구성되어 있다.The composition of the secondary seasoning liquid used in the present invention is 40.0% by weight of purified water, 6.8% by weight of three bamboo salts or 9 times of bamboo salt, red pepper powder 20.0% by weight, sugar 4.5% by weight, sorbitol 8.8% by weight, kelp extract powder 2.2% by weight, starch syrup 13.5 weight%, glycine 1.0 weight%, garlic powder 2.2 weight%, and sake 1.0 weight%.

(제 4단계)(Step 4)

이어서 상기와 같이 처리된 명란 젓갈을 정형, 표면 건조 및 동결 처리하여서 고품질의 죽염 명란 젓갈을 제조한다[도 2 참조].Subsequently, the high-quality bamboo salt cod roe salt is prepared by forming, surface drying, and freezing the cod roe salt treated as described above (see FIG. 2).

그리고, 위와 같은 방법으로 제조한 명란 젓갈 제품을 예를 들면 도 3과 같이 폴리프로필렌(Polypropylene:PP)/폴리염화비닐리덴(Polyvinylidene:PVDC)/폴리에틸렌(Polyethylene:PE) 적층 플라스틱 봉지로 진공 포장된 상태 하에서 -22℃ 내지 -18℃의 온도에서 동결 저장 및 유통시키는 것이 바람직하다.Then, the dried cod roe salt product manufactured by the above method is vacuum-packed with a polypropylene (PP) / polyvinylidene (PVDC) / polyethylene (PE) laminated plastic bag as shown in FIG. It is preferred to freeze store and circulate at a temperature of -22 ° C to -18 ° C under conditions.

이하, 본 발명을 실시예에 의거하여 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to Examples.

실시예 1Example 1

북태평양산 동결품(Pollack's Roe)으로 20시간 동안 해동하고, 10% 천일염 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별하였다. 상기 선별된 명란을 청학동 삼선당(주)에서 제조한 3회 죽염을 19.5중량% 포함하고, 정제수 72중량%, 설탕 3.6중량%, 솔비톨 3.6중량%, 에탄올 0.8중량%, 아스코르빈산 0.1중량%, 알라닌 0.2중량% 및 글로탐산나트륨 0.2중량%로 조성되어 있는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 식염 수용액 중에서 다시 수세 및 탈수하였다.After thawing with a North Pacific frozen product (Pollack's Roe) for 20 hours, washed with water and dehydrated in 10% natural salt saline solution, and the egg was selected. 19.5% by weight of three times bamboo salt prepared by Cheonghak-dong Samseondang Co., Ltd. was selected, and 72% by weight of purified water, 3.6% by weight of sugar, 3.6% by weight of sorbitol, 0.8% by weight of ethanol, and 0.1% by weight of ascorbic acid. , Immersed for 24 hours at a temperature of 4 ° C. in a primary seasoning solution composed of 0.2% by weight of alanine and 0.2% by weight of sodium glotamate, and washed with water and dehydrated again in a 10% aqueous solution of salt.

상기 과정으로 처리된 명란에다 역시 청학동 삼선당(주)에서 제조한 3회 죽염을 6.8중량% 포함하면서 정제수 40.0중량%, 고춧가루 20.0중량%, 설탕 4.5중량%, 솔비톨 8.8중량%, 다시마 엑스분 2.2중량%, 물엿 13.5중량%, 글리신 1.0중량%, 마늘가루 2.2중량% 및 청주 1.0중량%로 조성되어 있는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10일 내지 15일간 숙성시켜서 죽염 명란 젓갈 제품을 제조하였다.In addition to the above-mentioned cod roe, 6.8 wt% of three bamboo salts prepared by Cheonghak-dong Samseondang Co., Ltd. were purified water 40.0 wt%, red pepper powder 20.0 wt%, sugar 4.5 wt%, sorbitol 8.8 wt%, kelp extract powder 2.2 After mixing a secondary seasoning liquid composed of 1% by weight, 13.5% by weight starch, 1.0% by weight glycine, 2.2% by weight garlic powder and 1.0% by weight sake, and then aged at a temperature of 4 to 6 ℃ for 10 days to 15 days Cod roe salted product was prepared.

실시예 2Example 2

북태평양산 동결품(Pollack's Roe)으로 구입한 원료 명란을 실온에서 20시간 동안 해동하고, 10% 천일염 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별하였다. 상기 선별된 명란을 청학동 삼선당(주)에서 제조한 3회 죽염을 19.5중량% 포함하고, 정제수 72중량%, 설탕 3.6중량%, 솔비톨 3.6중량%, 에탄올 0.8중량%, 아스코르빈산 0.1중량%, 알라닌 0.2중량% 및 글로탐산나트륨 0.2중량%로 조성되어 있는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 식염 수용액 중에서 다시 수세 및 탈수하였다.The raw cod roe purchased as a North Pacific frozen product (Pollack's Roe) was thawed at room temperature for 20 hours, washed with water and dehydrated in a 10% salt solution, and the coated roe were selected. 19.5% by weight of three times bamboo salt prepared by Cheonghak-dong Samseondang Co., Ltd. was selected, and 72% by weight of purified water, 3.6% by weight of sugar, 3.6% by weight of sorbitol, 0.8% by weight of ethanol, and 0.1% by weight of ascorbic acid. , Immersed for 24 hours at a temperature of 4 ° C. in a primary seasoning solution composed of 0.2% by weight of alanine and 0.2% by weight of sodium glotamate, and washed with water and dehydrated again in a 10% aqueous solution of salt.

상기 과정으로 처리된 명란에다 역시 청학동 삼선당(주)에서 제조한 9회 죽염을 6.8중량% 포함하면서 정제수 40.0중량%, 고춧가루 20.0중량%, 설탕 4.5중량%, 솔비톨 8.8중량%, 다시마 엑기스분 2.2중량%, 물엿 13.5중량%, 글리신 1.0중량%, 마늘가루 2.2중량% 및 청주 1.0중량%로 조성되어 있는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10일 내지 15일간 숙성시켜서 죽염 명란 젓갈 제품을 제조하였다.In addition to the above-mentioned spicy cod roe, 6.8 wt% of 9 th bamboo salt prepared by Cheonghak-dong Samseondang Co., Ltd. was purified water 40.0 wt%, red pepper powder 20.0 wt%, sugar 4.5 wt%, sorbitol 8.8 wt%, kelp extract powder 2.2 After mixing a secondary seasoning liquid composed of 1% by weight, 13.5% by weight starch, 1.0% by weight glycine, 2.2% by weight garlic powder and 1.0% by weight sake, and then aged at a temperature of 4 to 6 ℃ for 10 days to 15 days Cod roe salted product was prepared.

비교예 1Comparative Example 1

북태평양산 동결품(Pollack's Roe)으로 명란을 실온에서 20시간 동안 해동하고, 10% 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별하였다. 상기 선별된 명란을 전북 부안에서 채취한 서해안산 천일염을 19.5중량% 포함하고, 정제수72중량%, 설탕 3.6중량%, 솔비톨 3.6중량%, 에탄올 0.8중량%, 아스코르빈산 0.1중량%, 알라닌 0.2중량% 및 글로탐산나트륨 0.2중량%로 조성되어 있는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 식염 수용액 중에서 다시 수세 및 탈수하였다.The eggs were thawed for 20 hours at room temperature with a North Pacific frozen product (Pollack's Roe), washed with water and dehydrated in a 10% saline solution, and the eggs were selected. 19.5% by weight of the west coast acid salt, collected from Buan, Jeonbuk, the selected splendid egg, purified water 72% by weight, sugar 3.6% by weight, sorbitol 3.6% by weight, ethanol 0.8% by weight, ascorbic acid 0.1% by weight, alanine 0.2% by weight % And sodium glutamate were immersed in a primary seasoning solution at a temperature of 4 ° C. for 24 hours, washed with water and dewatered again in a 10% aqueous salt solution.

상기 과정으로 처리된 명란에다 역시 전북 부안의 천일염을 6.8중량% 포함하면서 정제수 40.0중량%, 고춧가루 20.0중량%, 설탕 4.5중량%, 솔비톨 8.8중량%, 다시마 엑기스분 2.2중량%, 물엿 13.5중량%, 글리신 1.0중량%, 마늘가루 2.2중량% 및 청주 1.0중량%로 조성되어 있는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10일 내지 15일간 숙성시켜서 명란 젓갈 제품을 제조하였다.In addition to lanthanum salt 6.8% by weight in the above process, 40.0% by weight of purified water, 20.0% by weight of red pepper powder, 4.5% by weight of sugar, 8.8% by weight of sorbitol, 2.2% by weight of kelp extract, 13.5% by weight of starch syrup, After preparing a secondary seasoning liquid composed of 1.0% by weight of glycine, 2.2% by weight of garlic powder, and 1.0% by weight of sake, it was aged at a temperature of 4 to 6 ° C for 10 to 15 days to prepare a spicy salted fish product.

비교예 1의 명란 젓갈 제품, 실시예 1의 3회 죽염 명란 젓갈 제품, 실시예 2의 9회 죽염 명란 젓갈 제품의 일반 성분 조성과 이화학적 성분 특성을 분석한 결과, 실시예 1과 2의 제품은 비교예 1의 제품에 비해 염도와 pH가 약간 높았고, 수분 활성도와 아미노질소량, 휘발성염기질소량은 약간 낮았다. 일반 성분의 조성은 별 차이를 보이지 않았다.As a result of analyzing the general component composition and physicochemical component characteristics of the spicy cod roe salt product of Comparative Example 1, the three times bamboo salt cod roe salt product of Example 1, and the nine colic salted salt cod roe salt product of Example 2, the products of Examples 1 and 2 Compared with the product of Comparative Example 1, the salinity and pH were slightly higher, and the water activity, the amount of amino nitrogen and the amount of volatile basic nitrogen were slightly lower. The composition of the general ingredient showed no difference.

구성 지방산의 조성은 실시예 1과 2의 제품 모두 16 : 0, 18 : 1, 20 : 5 및 22 : 6 등이 주요 구성 지방산이었으나, 가공 중 고도불포화지방산의 잔존율은 실시예 1과 2가 비교예 1의 제품에 비해 월등히 높았다(표 3 내지 5 참조).The constituent fatty acids were composed of 16: 0, 18: 1, 20: 5, and 22: 6 in the products of Examples 1 and 2, but the residual ratios of polyunsaturated fatty acids were It was much higher than the product of Comparative Example 1 (see Tables 3 to 5).

표 2TABLE 2

구분division 조성(%)Furtherance(%) 수분moisture 조단백질Crude protein 조지질Geography 회분Ash 탄수화물carbohydrate 비교예 1Comparative Example 1 67.267.2 20.420.4 0.90.9 6.56.5 5.05.0 실시예 1Example 1 66.066.0 20.220.2 0.80.8 7.77.7 5.35.3 실시예 2Example 2 66.266.2 20.120.1 0.90.9 7.57.5 5.25.2

표 3TABLE 3

구분division 염도(%)Salinity (%) pHpH AwAw NH2-N(mg%)NH 2 -N (mg%) VBN(mg%)VBN (mg%) 산도(mL%)Acidity (mL%) 비교예 1Comparative Example 1 6.26.2 5.725.72 0.930.93 242.6242.6 26.626.6 125.0125.0 실시예 1Example 1 6.86.8 6.366.36 0.910.91 225.0225.0 21.321.3 84.684.6 실시예 2Example 2 6.76.7 6.426.42 0.910.91 227.5227.5 22.822.8 84.084.0

표 4Table 4

지방산fatty acid 비교예 1Comparative Example 1 실시예 1Example 1 실시예 2Example 2 14:015:016:016:1n716:1n516:2n916:2n417:018:018:1n918:1n718:1n518:2n618:2n418:3n318:4n318:4n120:1n920:1n720:2NMID20:2n620:4n620:4n320:5n322:1n1122:1n921:5n322:5n622:5n322:6n314: 015: 016: 016: 1n716: 1n516: 2n916: 2n417: 018: 018: 1n918: 1n718: 1n518: 2n618: 2n418: 3n318: 4n318: 4n120: 1n920: 1n720: 2NMID20: 2n620: 4n620: 4n320: 5n322: 1n1122: 1n921: 5n322: 5n622: 5n322: 6n3 3.30.321.46.30.30.20.80.21.910.65.10.80.80.10.20.50.21.71.8-0.31.00.418.70.90.30.1-1.120.83.30.321.46.30.30.20.80.21.910.65.10.80.80.10.20.50.21.71.8-0.31.00.418.70.90.30.1-1.120.8 3.10.420.55.90.20.30.70.21.59.74.40.70.70.10.80.40.81.60.30.2-1.30.420.71.40.20.30.21.321.73.10.420.55.90.20.30.70.21.59.74.40.70.70.10.80.40.81.60.30.2-1.30.420.71.40.20.30.21.321.7 2.60.420.74.50.30.11.10.21.99.44.60.31.10.10.30.41.21.70.21.10.21.30.520.61.60.30.30.11.221.82.60.420.74.50.30.11.10.21.99.44.60.31.10.10.30.41.21.70.21.10.21.30.520.61.60.30.30.11.221.8 20:5+22:6/16:01) 20: 5 + 22: 6/16: 0 1) 1.821.82 2.072.07 2.052.05

1) 고도불포화지방산(PUFA)의 잔존율1) Residual Rate of Polyunsaturated Fatty Acid (PUFA)

표 5Table 5

구분division 조직감1) Texture 1) 최대중량(g)Weight (g) 강도(g/㎠)Strength (g / ㎠) 경도(g/㎠)Hardness (g / ㎠) 비교예 1Comparative Example 1 409±39409 ± 39 52,075±5,21552,075 ± 5,215 7,842±718.07,842 ± 718.0 실시예 1Example 1 662±20662 ± 20 84,525±1,27384,525 ± 1,273 12,244±1,41012,244 ± 1,410 실시예 2Example 2 619±19619 ± 19 78,813±2,94078,813 ± 2,940 11,647±84911,647 ± 849

1) 강도 : 최대 중량(g)/시료 면적(㎠)1) Strength: Maximum weight (g) / Sample area (㎠)

경도 : 강도(g/㎠)×시료 높이(cm)/거리(cm)Hardness: strength (g / cm 2) x sample height (cm) / distance (cm)

실시예 1, 2와 비교예 3의 제품의 조직감을 물성측정기를 사용하여 전단 압력 시험을 한 결과, 실시예 제품들이 비교예 제품에 비해 월등히 조직감이 우수하였다(표 5 참조).As a result of shear pressure test using the physical properties of the products of Examples 1 and 2 and Comparative Example 3, the Example products were much better in texture than the Comparative Example products (see Table 5).

또한, 죽염 명란 젓갈 제품의 맛과 영양 특성에 관여하는 유리아미노산의 조성을 분석한 결과, 본 발명의 실시예 1, 2의 제품과 비교예 1의 제품 모두 원료 명란에 비해 유리 아미노산의 총량이 적었는데, 이는 염지 공정 때 일어나는 탈수과정에서 30% 이상의 유리아미노산류(Tau 등)가 유실되기 때문이다. 그리고, 원료 명란과 비교하여 함량이 많은 유리아미노산들은 저온 숙성 중 구성 아미노산의 일부가 분해되어 다시 그 함량이 증가하는 것으로 추정되었다. 유리아미노산의 총량은 실시예 1의 제품과 비교예 1의 제품 사이에 별 차이가 없었으며, 주요유리아미노산의 조성도 서로 비슷하였다.In addition, as a result of analyzing the composition of the free amino acid involved in the taste and nutritional characteristics of bamboo salt cod roe salt products, the total amount of free amino acids in the product of Examples 1, 2 and Comparative Example 1 of the present invention was less This is because more than 30% of free amino acids (Tau, etc.) are lost during the dehydration process during the dyeing process. In addition, it was estimated that free amino acids having a high content compared to raw material eggs are decomposed to a part of constituent amino acids during low temperature aging and increase in content again. The total amount of free amino acid was not significantly different between the product of Example 1 and the product of Comparative Example 1, the composition of the main free amino acid was similar to each other.

원료 명란과 실시예 1과 2, 비교예 1의 제품의 유리아미노산의 평균 함량(mg/100g)은 다음 표 6과 같다.The average content (mg / 100g) of the raw material and the free amino acids of the products of Examples 1 and 2 and Comparative Example 1 are shown in Table 6 below.

표 6Table 6

아미노산amino acid 원료명란Raw material name column 제품product 실시예1Example 1 실시예 2Example 2 비교예 1Comparative Example 1 포스포세린(Phosphoserine)타우린(Taurine)포스포에탄올아민(Phosphoethanolamine)히드록시프롤린(Hydroxyproline)트레오닌(threonine)세린(Serine)아스파라긴산(Aspartic acid)글루타민산(Glutamic acid)프롤린(Proline)글리신(Glycine)알라닌(Alanine)시트룰린(Citrulline)α-아미노이소부틸산(α-Aminobutyric acid)바린(Valine)시스틴(Cystine)메티오닌(Methionine)아이소루신(Isoleucine)루신(Leucine)티로신(Tyrosine)β-알라닌(β-Alanine)페닐알라닌(Phenylalanine)γ-아미노이소부틸산(γ-Aminoisobutyric acide)(NH3)오르니틴(Ornithine)리신(Lysine)히스티딘(Histidine)안세린(Anserine)아르지닌(Arginine)Phosphoserine Taurine Phosphoethanolamine Hydroxyproline Threonine Serine Aspartic acid Glutamic acid Glycine Allene Citrulline α-Aminobutyric acid Valine Cystinine Methionine Isoleucine Leucine Tyrosine β-Alanine Phenylalanine γ-Aminoisobutyric acid (NH 3 ) Ornithine Lysine Histidine Anserine Anserine Arginine 10.1368.724.0306.233.523.185.3182.522.241.286.370.23.238.1tr19.038.269.130.534.225.230.85.63.451.015.9tr32.610.1368.724.0306.233.523.185.3182.522.241.286.370.23.238.1tr19.038.269.130.534.225.230.85.63.451.015.9tr32.6 8.2227.417.0251.445.830.484.3145.135.337.755.652.12.738.8tr11.933.984.433.429.532.823.33.42.356.412.7tr46.38.2227.417.0251.445.830.484.3145.135.337.755.652.12.738.8tr11.933.984.433.429.532.823.33.42.356.412.7tr46.3 9.8221.318.4251.245.227.586.1142.233.540.256.254.33.040.4tr10.336.082.734.231.324.826.43.62.457.612.0tr47.89.8221.318.4251.245.227.586.1142.233.540.256.254.33.040.4tr10.336.082.734.231.324.826.43.62.457.612.0tr47.8 8.2217.717.6244.537.328.084.3150.138.749.165.558.42.341.9tr11.643.484.143.528.931.123.84.43.261.914.5tr50.48.2217.717.6244.537.328.084.3150.138.749.165.558.42.341.9tr11.643.484.143.528.931.123.84.43.261.914.5tr50.4 합계Sum 1617.51617.5 1402.11402.1 1398.41398.4 1444.41444.4

실시예 제품과 비교예 제품의 맛, 냄새, 조직감, 색조 및 종합 평가 등 관능적 특성에 대하여 7인의 패널을 조직하여 관능 검사를 한 결과, 실시예의 제품은 비교예의 제품과 비교하여 맛과 색조는 서로 비슷하였으나, 냄새와 조직감의 경우는 실시예의 제품이 비교예의 제품에 비해 높은 점수를 얻었다. 실시예 1의 제품과 실시예 2의 제품 사이에 관능적 차이는 거의 없었다(도 4 참조).As a result of organoleptic testing of seven panelists for sensory characteristics such as taste, smell, texture, color tone, and comprehensive evaluation of the Example product and Comparative Example product, the product of Example was compared with the product of Comparative Example, and the taste and color tone were different from each other. Similar, but in the case of smell and texture, the product of the Example obtained a high score compared to the product of the comparative example. There was little sensory difference between the product of Example 1 and the product of Example 2 (see FIG. 4).

구명된 최적 가공 조건하에서 가공한 죽염 명란 젓갈(실시예 1)을 먼저 동결시켜 고정화한 후 폴리프로필렌(PP)/폴리염화비닐리덴(PVDC)/폴리에틸렌(PE) 적층 플라스틱 봉지에 일정량씩 담아 진공 포장한 후, -20±2℃에서 동결저장하면서 실시예 제품의 동결저장 중 품질 안정성에 대해 실험하였다(표 7 참조).Frozen bamboo salted salted fish salt (Example 1) processed under the optimized optimum processing conditions were first frozen and immobilized, and then vacuum packed in a predetermined amount in a polypropylene (PP) / polyvinylidene chloride (PVDC) / polyethylene (PE) laminated plastic bag. Afterwards, the freeze storage at -20 ± 2 ℃ was tested for the quality stability of the Example product during freeze storage (see Table 7).

동결저장 4개월 동안 제품의 수분 함량의 변화는 거의 없었고, 드립의 경우는 동결저장 중 약간씩 증가하는 경향을 나타내었으며, pH는 동결저장 중 유리지방산과 젖산이 일부 생성됨에 따라 약간씩 감소하는 경향을 나타내었다. 휘발성 염기질소와 TBA값은 동결저장 중 약간씩 증가하나 큰 변화를 보이지 않아 폴리프로필렌(PP)/폴리염화비닐리덴(PVDC)/폴리에틸렌(PE) 적층 필름 백에 진공포장한 명란 젓갈 제품은 동결저장 4개월 동안 품질이 안정하게 유지되고 있음을 알 수 있었다.During 4 months of freezing, there was little change in the moisture content of the product, and the drip tended to increase slightly during freezing, and the pH tended to decrease slightly as free fatty acid and lactic acid were formed during freezing. Indicated. Volatile basic nitrogen and TBA values slightly increased during freezing storage, but did not show significant change, so the freezing and storage of dried codfish products packaged in polypropylene (PP) / polyvinylidene chloride (PVDC) / polyethylene (PE) laminated film bags It was found that the quality remained stable for 4 months.

표 7TABLE 7

구분division 저장기간(월)Storage period (month) 00 1One 22 33 44 수분함량(%)유리드립(%)pHVBN(mg%)TBA 값Water content (%) Glass drip (%) pH VBN (mg%) TBA value 66.09.86.3421.30.03966.09.86.3421.30.039 65.59.76.3122.00.04165.59.76.3122.00.041 66.210.56.1724.10.04466.210.56.1724.10.044 65.812.06.1225.90.05165.812.06.1225.90.051 65.614.85.9128.30.05565.614.85.9128.30.055 종합평가1)맛색상Overall evaluation 1) Taste color 4.54.5 4.54.5 4.34.3 4.04.0 3.63.6 4.54.5 4.34.3 4.14.1 3.83.8 3.53.5

1) 5 : 매우 좋음, 4 : 좋음, 3 : 괜찮음, 2 : 안좋음, 1 : 불량함1) 5: Very good, 4: Good, 3: OK, 2: Poor, 1: Poor

이상과 같이 본 발명에 따른 실시예의 제품들은 비교예의 제품에 비해 맛과 색조는 서로 비슷하였으나, 제품의 조직감이나, 지질의 산화억제, 고도불포화지방산의 잔존율, 제품의 냄새 면세서 실시예의 제품들이 비교예의 제품에 비해 훨씬 우수하였으며, 죽염이 갖는 약리 효과 등 기능적 특성을 고려할 경우 고품질의 수산 발효 식품이 제조될 수 있다.As described above, the products of the examples according to the present invention have similar taste and color to each other than the products of the comparative examples, but the texture of the products, the oxidation inhibition of lipids, the residual ratio of polyunsaturated fatty acids, and the odors of products are Compared with the product of the comparative example was much better, considering the functional properties, such as pharmacological effects of bamboo salt can be produced high-quality seafood fermented foods.

본 발명에 따른 죽염 명란 젓갈은 염도가 8% 미만인 저염 젓갈이므로 그대로 저온 저장하거나 저온 유통시킬 경우 유통 저장 중 숙성의 진행에 따라 연화와 부패의 우려가 있으므로 이를 방지하고, 자기 수명을 연장시키기 위해 소비될 때까지 동결 저장하는 것이 바람직하다.Bamboo salt spaghetti salted salt according to the present invention is low salted salted fish with less than 8% salinity as it is stored at low temperature or low temperature as it may cause softening and decay as the aging proceeds during distribution storage, to prevent it, consumed to prolong its life It is preferable to store the product until freezing.

본 발명의 방법에 의해서 제조된 죽염 명란 젓갈 제품은 기존에 천일염을 사용하여 제조된 명란 젓갈 제품에 비해 맛과 색조는 서로 비슷하지만, 제품의 조직감이나 지질의 산화억제, 고도불포화지방산의 잔존율, 제품의 냄새 면에서 훨씬 우수하며, 죽염이 갖는 약리 효과 등 기능적 특성을 고려할 경우 상품적 가치가 뛰어난 고품질의 수산 발효 식품이라고 할 수 있다.Bamboo salt spicy salted salted salt products prepared by the method of the present invention have similar taste and color tone to salted salted salted salted salt products, but the texture of the product, the inhibition of lipid oxidation, the residual ratio of polyunsaturated fatty acids, It is much better in terms of smell of products, and considering the functional characteristics such as the pharmacological effect of bamboo salt, it can be said to be a high quality seafood fermented food with excellent commercial value.

유통과 관련하여 본 발명의 죽염 명란 젓갈을 먼저 동결시킨 후, 폴리프로필렌(PP)/폴리염화비닐리덴(PVDC)/폴리에틸렌(PE) 적층 플라스틱 봉지로 진공 포장하고, -20 ±2℃의 동결고에 저장할 경우 자기 수명이 4개월 이상으로 연장 가능할 뿐 아니라 4개월 동안 수분 함량의 변화도 거의 없고, 드립의 경우 동결 저장 중 약간씩 증가하는 경향을 나타내긴 하지만, pH는 동결 저장 중 유리 지방산과 젖산이 일부 생성됨에 따라 약간씩 감소하는 경향을 나타내게 된다.In relation to distribution, the bamboo salt cod roe salt of the present invention was first frozen, and then vacuum-packed in a polypropylene (PP) / polyvinylidene chloride (PVDC) / polyethylene (PE) laminated plastic bag, and frozen at -20 ± 2 ° C. In addition to the fact that the shelf life can be extended to more than 4 months, there is little change in moisture content during 4 months, and drip tends to increase slightly during freezing storage. As some of them are produced, they tend to decrease slightly.

특히, 휘발성 염기 질소와 TBA값은 동결 저장 중 약간씩 증가하나 큰 변화를 보이지 않아 폴리프로필렌(PP)/폴리염화비닐리덴(PVDC)/폴리에틸렌(PE) 적층 플라스틱 봉지에 진공 포장한 명란 젓갈 제품은 동결 저장 4개월 동안 품질이 안정하게 유지되고 있을 뿐 아니라 해동 후에도 고품질을 그대로 유지할 수 있는 장점이 있다.In particular, the volatile basic nitrogen and TBA values slightly increased during freezing storage, but did not show any significant changes, so the dried salted products in vacuum-packed polypropylene (PP) / polyvinylidene chloride (PVDC) / polyethylene (PE) laminated plastic bags Freezing Storage Not only is the quality stable for four months, but it also has the advantage of maintaining high quality after thawing.

Claims (4)

동결 명란을 수세 및 탈수하고, 죽염이 포함된 조미액을 이용하여 2단계에 걸쳐 발효 및 숙성시킨 후 동결처리하여서 되는 고품질의 죽염 명란젓갈을 제조하는 방법에 있어서, 해동한 명란을 10% 천일염 식염수 수용액 중에서 수세 및 탈수한 후 명란을 선별하는 단계; 상기 선별된 명란을 3회 죽염을 19.5중량% 포함하는 1차 조미액 중에서 4℃의 온도에서 24시간 동안 침지시키고, 10% 천일염 식염 수용액 중에서 다시 수세 및 탈수하는 단계; 추가로 3회 또는 9회 죽염을 6.8중량% 포함하는 2차 조미액을 혼합시킨 후, 4 내지 6℃의 온도에서 10일 내지 15일간 숙성시켜 염도가 8% 미만이 되게 하는 단계; 이어서 상기와 같이 처리된 명란 젓갈을 정형, 표면 건조 및 동결 처리하여서 됨을 특징으로 하는 고품질의 죽염 명란 젓갈의 제조 방법.In the method of producing high-quality bamboo salt spicy cod roe salt which is washed and dehydrated with frozen salt and fermented and aged in two stages using a seasoning solution containing bamboo salt, and then frozen. Screening the egg after washing and dehydration in water; Immersing the selected cod roe for 3 hours at a temperature of 4 ° C. in a primary seasoning solution containing 19.5% by weight of bamboo salt three times, and washing and dehydrating again in a 10% aqueous salt solution; Further mixing the second seasoning liquid containing 6.8 wt% of bamboo salt three or nine times, and then aging at a temperature of 4 to 6 ° C. for 10 to 15 days to bring the salinity to less than 8%; Subsequently, the method of producing high-quality bamboo salt spicy salted salted salted fish characterized in that the above-mentioned treated salted salted fish salted fish is fixed, surface dried and frozen. 제 1항에 있어서, 상기 1차 조미액은 정제수 72중량%, 3회 죽염 19.5중량%, 설탕 3.6중량%, 솔비톨 3.6중량%, 에탄올 0.8중량%, 아스코르빈산 0.1중량%, 알라닌 0.2중량% 및 글로탐산나트륨 0.2중량%로 조성되어 있는 것을 특징으로 하는 고품질의 죽염 명란 젓갈의 제조 방법.The method of claim 1, wherein the first seasoning is 72% by weight purified water, 19.5% by weight three times bamboo salt, 3.6% by weight sugar, 3.6% by weight sorbitol, 0.8% by weight ethanol, 0.1% by weight ascorbic acid, 0.2% by weight alanine and A method for producing high-quality bamboo salt spicy cod roe salt, which is composed of 0.2% by weight sodium glutamate. 제 1항에 있어서, 상기 2차 조미액은 정제수 40.0중량%, 3회죽염 또는 9회 죽염 6.8중량%, 고춧가루 20.0중량%, 설탕 4.5중량%, 솔비톨 8.8중량%, 다시마 엑기스분 2.2중량%, 물엿 13.5중량%, 글리신 1.0중량%, 마늘가루 2.2중량% 및 청주 1.0중량%로 조성되어 있는 것을 특징으로 하는 고품질의 죽염 명란 젓갈의제조 방법.The method of claim 1, wherein the second seasoning solution is 40.0% by weight purified water, 6.8% by weight three times or 9 times bamboo salt, red pepper powder 20.0%, 4.5% by weight sugar, 8.8% by weight sorbitol, 2.2% by weight of kelp extract, 13.5 starch syrup A method for producing high-quality bamboo salt spicy cod roe salt, wherein the composition is composed of 1% by weight, 1.0% by weight glycine, 2.2% by weight garlic powder and 1.0% by weight sake. 삭제delete
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