KR100427554B1 - PVC Carpet Tile Using Carbon Black and the Method of Manufacturing thereof - Google Patents
PVC Carpet Tile Using Carbon Black and the Method of Manufacturing thereof Download PDFInfo
- Publication number
- KR100427554B1 KR100427554B1 KR10-2000-0071469A KR20000071469A KR100427554B1 KR 100427554 B1 KR100427554 B1 KR 100427554B1 KR 20000071469 A KR20000071469 A KR 20000071469A KR 100427554 B1 KR100427554 B1 KR 100427554B1
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- South Korea
- Prior art keywords
- vinyl chloride
- chloride resin
- layer
- weight
- parts
- Prior art date
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- 239000006229 carbon black Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000011347 resin Substances 0.000 claims abstract description 82
- 229920005989 resin Polymers 0.000 claims abstract description 82
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 19
- 239000004917 carbon fiber Substances 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000003365 glass fiber Substances 0.000 claims abstract description 17
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 17
- 239000004020 conductor Substances 0.000 claims abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000003490 calendering Methods 0.000 claims description 2
- 241000872198 Serjania polyphylla Species 0.000 claims 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 2
- 230000007257 malfunction Effects 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 abstract description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 7
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 3
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- OMVSWZDEEGIJJI-UHFFFAOYSA-N 2,2,4-Trimethyl-1,3-pentadienol diisobutyrate Chemical compound CC(C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)C OMVSWZDEEGIJJI-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000009408 flooring Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/16—Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/06—PVC, i.e. polyvinylchloride
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
본 발명은 아래로부터 차례대로 카본 블랙이 함유된 염화비닐수지 졸층(1), 유리섬유층(3), 카본 블랙이 함유된 염화비닐수지 졸층(1), 부직포층(4) 및 카본 섬유가 함유된 원사를 제직한 섬유층(5)이 적층된 구조를 가지거나, 또는 아래로부터 차례대로 카본 블랙이 함유된 염화비닐수지 시트층(2), 카본 블랙이 함유된 염화비닐수지 졸층(1), 유리섬유층(3), 카본 블랙이 함유된 염화비닐수지 졸층(1), 부직포층(4) 및 카본 섬유가 함유된 원사를 제직한 섬유층(5)이 적층된 구조를 가지는 제품 전체에 전도성이 부여된 염화비닐수지 카펫 타일 및 그 제조방법에 관한 것이다.The present invention sequentially contains a carbon black vinyl chloride resin sol layer (1), a glass fiber layer (3), a carbon chloride-containing vinyl chloride resin sol layer (1), a nonwoven fabric layer (4), and a carbon fiber. A fiber layer 5 woven from yarn, or a vinyl chloride resin sheet layer 2 containing carbon black sequentially from the bottom, a vinyl chloride resin sol layer 1 containing carbon black, and a glass fiber layer (3) Chloride having conductivity applied to the entire product having a structure in which a vinyl chloride resin sol layer 1 containing carbon black, a nonwoven fabric layer 4, and a fiber layer 5 woven from a yarn containing carbon fibers were laminated. A vinyl resin carpet tile and a method of manufacturing the same.
이러한 본 발명의 염화비닐수지 카펫 타일은 전도성 물질인 카본 블랙을 함유한 염화비닐수지층에 전도성 카본 섬유를 부착하여 제품 전체에 전도성 기능을 부여함으로써 보행감이 좋고 흡음성이 있으며 산업현장, 사무공간등에서 정전기 장애에 의해 발생될 수 있는 고가의 전자장비의 오작동, 화재, 인체의 불쾌감등을 해소할 수 있게 되었다.The vinyl chloride resin carpet tile according to the present invention attaches the conductive carbon fiber to the vinyl chloride resin layer containing the carbon black, which is a conductive material, and gives a conductive function to the entire product. It is possible to solve the malfunction of expensive electronic equipment, fire, and the discomfort of human body, which can be caused by static electricity disturbance.
Description
본 발명은 전도성 물질인 카본 블랙을 함유하는 염화비닐수지층과 카본 섬유가 함유된 원사를 제직한 섬유층을 부착함으로써 제품 전체에 전도성 기능을 부여한 염화비닐수지 카펫 타일 및 그 제조방법에 관한 것이다.The present invention relates to a vinyl chloride resin carpet tile having a conductive function applied to an entire product by attaching a vinyl chloride resin layer containing a carbon black, which is a conductive material, and a fiber layer woven from a yarn containing carbon fibers, and a method of manufacturing the same.
일반적으로 전도성을 가지는 제품의 기능은 전기저항치로 표현될 수 있는데, 미국화재방지협회 99 규정에 의해 표면, 체적 저항이 100,000-10,000,000옴(Ohm)일때에 전도성을 가지는 것으로 규정되고 있으며, 또한 반도체 조립공장등 정전기 장애에 의해서 문제가 발생될 수 있는 장소에서는 상기의 요구품질이 만족되어야만 사용할 수 있는 것으로 규정화되어 있다.In general, the function of a product having conductivity can be expressed as an electrical resistance value. According to the American Fire Protection Association 99, it is defined as having conductivity when the surface and volume resistance is 100,000-10,000,000 Ohm. In a place where a problem may occur due to an electrostatic disturbance such as a factory, it is prescribed that it can be used only when the above required quality is satisfied.
상기의 요구 품질을 만족시키는 종래의 전도성 기능을 가지는 제품을 살펴보면, 각 층에 전도성 물질인 카본 블랙을 일정량 첨가하여 라미네이팅(Laminating)한 제품이 있고, 일정한 형태의 칩에 전도성 물질인 카본 블랙을 코팅하여 압착 후 표면을 갈아낸 제품이 있는데, 이들 제품은 모두 전층이 염화비닐수지로만 이루어진 염화비닐수지 바닥재였다.Looking at a product having a conventional conductive function that satisfies the above required quality, there is a product laminated by adding a certain amount of conductive material carbon black to each layer, coating a carbon black of a conductive material on a certain type of chip After pressing, there was a product whose surface was ground, and all of these products were vinyl chloride resin flooring materials whose entire layer consisted only of vinyl chloride resin.
또한 본 발명과 유사하게 염화비닐수지층과 섬유층으로 이루어진 염화비닐수지 카펫 타일의 경우 전도성 기능을 가지는 제품은 제품 전체에 전도성 기능이 부여된 형태가 아니었고, 제품의 일부분에만 전도성 기능이 부여된 것이었다.In addition, similar to the present invention, in the case of the vinyl chloride resin carpet tile made of a vinyl chloride resin layer and a fibrous layer, the product having a conductive function was not provided with a conductive function to the whole product, and only a part of the product had a conductive function. .
이에 본 발명에서는 전도성 물질인 카본 블랙을 함유하는 염화비닐수지층과 카본 섬유가 함유된 원사를 제직한 섬유층을 부착함으로써 제품 전체에 전도성 기능을 부여한 염화비닐수지 카펫 타일 및 그 제조방법을 제공하고자 한다.Accordingly, the present invention is to provide a vinyl chloride resin carpet tile and a method of manufacturing the same by attaching a vinyl chloride resin layer containing a carbon black as a conductive material and a fiber layer woven from a yarn containing carbon fibers. .
도 1은 본 발명에 따른 염화비닐수지 카펫 타일의 단면도.1 is a cross-sectional view of a vinyl chloride resin carpet tile according to the present invention.
도 2는 본 발명에 따른 다른 염화비닐수지 카펫 타일의 단면도.2 is a cross-sectional view of another vinyl chloride resin carpet tile according to the present invention.
(도면의 주요부분에 대한 부호의 설명)(Explanation of symbols for the main parts of the drawing)
1 : 카본 블랙이 함유된 염화비닐수지 졸층1: vinyl chloride resin sol layer containing carbon black
2 : 카본 블랙이 함유된 염화비닐수지 시트층2: vinyl chloride resin sheet layer containing carbon black
3 : 유리섬유층3: glass fiber layer
4 : 부직포층4: nonwoven fabric layer
5 : 카본 섬유가 함유된 원사를 제직한 섬유층5: fiber layer woven from yarn containing carbon fiber
이하 첨부도면에 의거하며 본 발명을 설명하면 다음과 같다.Hereinafter, the present invention will be described with reference to the accompanying drawings.
도 1은 본 발명에 따른 염화비닐수지 카펫 타일의 단면도로서, 아래로부터 차례대로 카본 블랙이 함유된 염화비닐수지 졸층(1), 유리섬유층(3), 카본 블랙이 함유된 염화비닐수지 졸층(1), 부직포층(4) 및 카본 섬유가 함유된 원사를 제직한 섬유층(5)이 적층된 구조의 염화비닐수지 카펫 타일을 보여준다.1 is a cross-sectional view of a vinyl chloride resin carpet tile according to the present invention, a vinyl chloride resin sol layer 1 containing carbon black, a glass fiber layer 3, and a carbon chloride resin layer containing carbon black 1 ), A vinyl chloride resin carpet tile having a structure in which a nonwoven fabric layer 4 and a fiber layer 5 woven from a yarn containing carbon fibers are laminated.
이러한 도 1의 염화비닐수지 카펫 타일의 제조방법은 다음과 같다.The manufacturing method of the vinyl chloride resin carpet tile of Figure 1 is as follows.
먼저, 이형 캐리어 상부에 전도성 물질인 카본 블랙이 함유된 액상의 염화비닐수지졸을 일정 두께로 코팅하여 카본 블랙이 함유된 염화비닐수지 졸층(1)을 형성시킨다.First, the vinyl chloride resin sol layer 1 containing carbon black is formed by coating a liquid vinyl chloride sol containing a conductive material carbon black on a release carrier to a predetermined thickness.
이때 카본 블랙이 함유된 염화비닐수지 졸층(1)의 염화비닐수지 졸의 조성은 중합도가 1300 또는 1700인 염화비닐수지 100중량부에 가소제인 디옥틸프탈레이트 90중량부, 부틸벤질프탈레이트 10중량부, TXIB 10중량부 및 DDB 20중량부, 안정제인 바륨-아연계 화합물 7중량부, 충전제인 중탄산칼슘 100중량부 및 전도성 물질인 카본 블랙 33중량부가 배합된 것이다.At this time, the composition of the vinyl chloride resin sol of the vinyl chloride resin sol layer 1 containing carbon black is 100 parts by weight of vinyl chloride resin having a polymerization degree of 1300 or 1700, 90 parts by weight of dioctylphthalate, 10 parts by weight of butylbenzylphthalate, 10 parts by weight of TXIB and 20 parts by weight of DDB, 7 parts by weight of a barium-zinc compound as a stabilizer, 100 parts by weight of calcium bicarbonate as a filler, and 33 parts by weight of carbon black as a conductive material.
다음, 염화비닐수지 졸층(1)의 상부에 치수안정성이 있는 유리섬유층(3)을 적층한 후, 유리섬유층(3)의 상부에 상기의 염화비닐수지 졸의 조성과 같은 염화비닐수지 졸을 코팅하여 카본 블랙이 함유된 염화비닐수지 졸층(1)을 형성시킨 다음, 다시 치수안정성이 있는 부직포층(4)을 적층한다.Next, after laminating the dimensional stability glass fiber layer (3) on top of the vinyl chloride resin sol layer (1), and coated with a vinyl chloride resin sol such as the composition of the above-mentioned vinyl chloride resin sol on the glass fiber layer (3) Then, the vinyl chloride resin sol layer 1 containing carbon black was formed, and then the nonwoven fabric layer 4 having dimensional stability was laminated.
마지막으로, 부직포층(4) 상부에 전도성 카본 섬유가 함유된 원사를 제직한섬유층(5)을 적층한 후, 130 - 150℃의 열풍에 3 - 5분간 건조하여 염화비닐수지 카펫 타일을 완성한다.Finally, after laminating the fibrous layer 5 woven from the yarn containing conductive carbon fibers on the nonwoven fabric layer 4, it is dried for 3 to 5 minutes in hot air at 130 to 150 ° C. to complete the vinyl chloride resin carpet tile. .
이때 카본 섬유가 함유된 원사를 제직한 섬유층(5)은 일반섬유 100중량부에 카본섬유 20중량부가 배합된 것이다.At this time, the fiber layer 5 woven from the yarn containing the carbon fiber is a blend of 20 parts by weight of carbon fiber to 100 parts by weight of normal fiber.
즉, 상기의 염화비닐수지 카펫 타일은 카본 블랙이 함유된 액상의 염화비닐수지 졸이 다공질 물질인 유리섬유층(3)과 부직포층(4)에 스며들게 되어 제품 전체에 전도성을 부여할 수 있는 것이다.That is, in the vinyl chloride resin carpet tile, the liquid vinyl chloride sol containing carbon black is impregnated into the glass fiber layer 3 and the nonwoven fabric layer 4, which are porous materials, to impart conductivity to the entire product.
도 2는 본 발명에 따른 다른 염화비닐수지 카펫 타일의 단면도로서, 아래로부터 차례대로 카본 블랙이 함유된 염화비닐수지 시트층(2), 카본 블랙이 함유된 염화비닐수지 졸층(1), 유리섬유층(3), 카본 블랙이 함유된 염화비닐수지 졸층(1), 부직포층(4) 및 카본 섬유가 함유된 원사를 제직한 섬유층(5)이 적층된 구조의 염화비닐수지 카펫 타일을 보여준다.Figure 2 is a cross-sectional view of another vinyl chloride resin carpet tile according to the present invention, the vinyl chloride resin sheet layer (2) containing carbon black in order from the bottom, the vinyl chloride resin sol layer (1), glass fiber layer containing carbon black (3) A vinyl chloride resin carpet tile in which a vinyl chloride resin sol layer 1 containing carbon black, a nonwoven fabric layer 4, and a fiber layer 5 woven from a yarn containing carbon fibers are laminated.
이러한 도 2의 염화비닐수지 카펫 타일의 제조방법은 다음과 같다.The method for producing the vinyl chloride resin carpet tile of Figure 2 is as follows.
먼저, 칼렌더링 공법으로 전도성 물질인 카본 블랙이 함유된 염화비닐수지 시트층(2)을 제조한다.First, a vinyl chloride resin sheet layer 2 containing carbon black, which is a conductive material, is manufactured by a calendering method.
이때 카본 블랙이 함유된 염화비닐수지 시트층(2)의 염화비닐수지의 조성은 중합도가 100 또는 800인 염화비닐수지 100중량부에 가소제인 디옥틸프탈레이트 40중량부, 안정제인 바륨-아연계 화합물 4중량부, 충전제인 중탄산칼슘 100중량부 및 전도성 물질인 카본 블랙 25.5중량부를 배합한 것이다.At this time, the composition of the vinyl chloride resin of the vinyl chloride resin sheet layer 2 containing carbon black is 40 parts by weight of dioctylphthalate as a plasticizer and a barium-zinc compound as a stabilizer in 100 parts by weight of a vinyl chloride resin having a polymerization degree of 100 or 800. 4 parts by weight, 100 parts by weight of calcium bicarbonate as a filler and 25.5 parts by weight of carbon black as a conductive material are blended.
다음, 염화비닐수지 시트층(2)의 상부에 전도성 물질인 카본 블랙이 함유된액상의 염화비닐수지 졸을 코팅하여 염화비닐수지 졸층(1)을 형성시킨 다음, 치수안정성이 있는 유리섬유층(3)을 적층한다.Next, a vinyl chloride resin sol layer 1 is formed by coating a liquid vinyl chloride sol containing carbon black, which is a conductive material, on the upper part of the vinyl chloride resin sheet layer 2, and then the dimensional stability glass fiber layer 3 )).
이때 카본 블랙이 함유된 염화비닐수지 졸층(1)의 염화비닐수지 졸의 조성은 중합도가 1300 또는 1700인 염화비닐수지 100중량부에 가소제인 디옥틸프탈레이트 90중량부, 부틸벤질프탈레이트 10중량부, TXIB 10중량부 및 DDB 20중량부, 안정제인 바륨-아연계 화합물 7중량부, 충전제인 중탄산칼슘 100중량부 및 전도성 물질인 카본 블랙 33중량부가 배합된 것이다.At this time, the composition of the vinyl chloride resin sol of the vinyl chloride resin sol layer 1 containing carbon black is 100 parts by weight of vinyl chloride resin having a polymerization degree of 1300 or 1700, 90 parts by weight of dioctylphthalate, 10 parts by weight of butylbenzylphthalate, 10 parts by weight of TXIB and 20 parts by weight of DDB, 7 parts by weight of a barium-zinc compound as a stabilizer, 100 parts by weight of calcium bicarbonate as a filler, and 33 parts by weight of carbon black as a conductive material.
다음, 유리섬유층(3)의 상부에 상기의 염화비닐수지 졸의 조성과 같은 염화비닐수지 졸을 코팅하여 카본 블랙이 함유된 염화비닐수지 졸층(1)을 형성시킨 다음, 다시 치수안정성이 있는 부직포층(4)을 적층한다.Next, a vinyl chloride resin sol such as the composition of the vinyl chloride resin sol is coated on the glass fiber layer 3 to form a vinyl chloride resin sol layer 1 containing carbon black, and then the nonwoven fabric having dimensional stability again. Layer 4 is laminated.
마지막으로, 부직포층(4) 상부에 전도성 카본 섬유가 함유된 원사를 제직한 섬유층(5)을 적층한 후, 130 - 150℃의 열풍에 3 - 5분간 건조하여 염화비닐수지 카펫 타일을 완성한다.Finally, after laminating the fibrous layer 5 woven from the yarn containing the conductive carbon fibers on the nonwoven fabric layer 4, it is dried for 3 to 5 minutes in a hot air of 130-150 ℃ to complete the vinyl chloride resin carpet tile. .
이때 카본 섬유가 함유된 원사를 제직한 섬유층(5)은 일반섬유 100중량부에 카본섬유 20중량부가 배합된 것이다.At this time, the fiber layer 5 woven from the yarn containing the carbon fiber is a blend of 20 parts by weight of carbon fiber to 100 parts by weight of normal fiber.
즉, 상기의 염화비닐수지 카펫 타일은 카본 블랙이 함유된 액상의 염화비닐수지 졸이 다공질 물질인 유리섬유층(3)과 부직포층(4)에 스며들게 되어 제품 전체에 전도성을 부여할 수 있는 것이다.That is, in the vinyl chloride resin carpet tile, the liquid vinyl chloride sol containing carbon black is impregnated into the glass fiber layer 3 and the nonwoven fabric layer 4, which are porous materials, to impart conductivity to the entire product.
이러한 본 발명의 염화비닐수지 카펫 타일은 전도성 물질인 카본 블랙을 함유한 염화비닐수지층에 전도성 카본 섬유를 부착하여 제품 전체에 전도성 기능을 부여함으로써 보행감이 좋고 흡음성이 있으며 산업현장, 사무공간등에서 정전기 장애에 의해 발생될 수 있는 고가의 전자장비의 오작동, 화재, 인체의 불쾌감등을 해소할 수 있게 되었다.The vinyl chloride resin carpet tile according to the present invention attaches the conductive carbon fiber to the vinyl chloride resin layer containing the carbon black, which is a conductive material, and gives a conductive function to the entire product. It is possible to solve the malfunction of expensive electronic equipment, fire, and the discomfort of human body, which can be caused by static electricity disturbance.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100716712B1 (en) * | 2005-11-17 | 2007-05-09 | 이문수 | Anti-static proof tile |
| EP2080792A2 (en) | 2008-01-17 | 2009-07-22 | Chae-Ho Kim | Water soluble photo-curable antistatic composition with improved wear resistance and high transparency, and conductive hard tile flooring material coated with the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100367885B1 (en) * | 2002-05-27 | 2003-01-14 | 이문수 | Static-electricity proof tile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4061811A (en) * | 1975-03-05 | 1977-12-06 | Toray Industries Inc. | Antistatic carpet and production thereof |
| US4913952A (en) * | 1988-11-14 | 1990-04-03 | Milliken Research Corporation | Carpet composites, having improved static electricity characteristics |
| JPH02286233A (en) * | 1989-04-26 | 1990-11-26 | Reitetsuku Kk | Tile carpet |
| KR19990077272A (en) * | 1996-01-16 | 1999-10-25 | 이노우에 노리유끼 | Duplex felt, member made of duplex felt and method of manufacturing double felt |
| KR100261351B1 (en) * | 1998-10-02 | 2000-07-01 | 마상만 | A material, resin and mat for absolution and interception of electromagnetic waves |
-
2000
- 2000-11-29 KR KR10-2000-0071469A patent/KR100427554B1/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4061811A (en) * | 1975-03-05 | 1977-12-06 | Toray Industries Inc. | Antistatic carpet and production thereof |
| US4913952A (en) * | 1988-11-14 | 1990-04-03 | Milliken Research Corporation | Carpet composites, having improved static electricity characteristics |
| JPH02286233A (en) * | 1989-04-26 | 1990-11-26 | Reitetsuku Kk | Tile carpet |
| KR19990077272A (en) * | 1996-01-16 | 1999-10-25 | 이노우에 노리유끼 | Duplex felt, member made of duplex felt and method of manufacturing double felt |
| KR100261351B1 (en) * | 1998-10-02 | 2000-07-01 | 마상만 | A material, resin and mat for absolution and interception of electromagnetic waves |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100716712B1 (en) * | 2005-11-17 | 2007-05-09 | 이문수 | Anti-static proof tile |
| EP2080792A2 (en) | 2008-01-17 | 2009-07-22 | Chae-Ho Kim | Water soluble photo-curable antistatic composition with improved wear resistance and high transparency, and conductive hard tile flooring material coated with the same |
| DE102008019623A1 (en) | 2008-01-17 | 2009-07-23 | Kim, Chae-Ho, Gwacheon | A water-soluble photocurable antistatic composition having improved wear resistance and high transparency, and conductive hard floor panel material coated therewith |
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