KR100423841B1 - Multi-layered flooring materials comprising conductive filler in bottom layer and having property of blocking electrowaves and harmful groundwater vein waves - Google Patents

Multi-layered flooring materials comprising conductive filler in bottom layer and having property of blocking electrowaves and harmful groundwater vein waves Download PDF

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KR100423841B1
KR100423841B1 KR1019970071213A KR19970071213A KR100423841B1 KR 100423841 B1 KR100423841 B1 KR 100423841B1 KR 1019970071213 A KR1019970071213 A KR 1019970071213A KR 19970071213 A KR19970071213 A KR 19970071213A KR 100423841 B1 KR100423841 B1 KR 100423841B1
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layer
parts
weight
conductive filler
flooring
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KR1019970071213A
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Korean (ko)
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KR19990051817A (en
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남광현
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고려화학 주식회사
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/04Tiles for floors or walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties

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  • Laminated Bodies (AREA)
  • Floor Finish (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)

Abstract

PURPOSE: Provided is a multi-layered flooring material comprising conductive fillers in the raw blend material to block harmful groundwater vein waves and electrowaves and to emit absorbed electrowaves effectively as heat energy. CONSTITUTION: The multi-layered flooring material includes a substrate layer(1), a top layer(2), printing pattern(3), transparent skin layer(4), a UV surface preparation layer(5), a bottom layer(6), chip layer(7) and a back layer(8). The bottom layer comprises magnetite-contained ceramic powder as conductive filler and the back layer comprises antioxidative copper powder coated with nickel or silver as conductive filler. Particularly, the magnetite-contained ceramic powder forms weak magnetic field barriers preventing harmful waves from penetrating by generating magnetic field. The content of the conductive filler is 10 to 50 parts by weight per 100 parts by weight of PVC resin.

Description

전자파 및 수맥파 차단 기능을 갖는 바닥재Flooring with electromagnetic and water wave blocking function

본 발명은 바닥재의 배합원료에 전도성을 갖는 필러(Filler)를 투입하여 비전도체인 비닐 바닥재에 전도성을 갖게 하여 전자파를 차단하거나 시공바닥면과 접지효과를 갖게하여 흡수된 전자파가 효과적으로 열에너지 등으로 방출될 수 있도록 하며, 또한 유해 수맥파를 차단할 수 있는 바닥재에 관한 것이다.In the present invention, a conductive filler is added to the raw material of the flooring material to make the vinyl flooring material conductive, thereby blocking electromagnetic waves or having a grounding effect with the ground floor. The present invention relates to a flooring material which can be used and can block harmful water waves.

일반적인 PVC 바닥재는 소재 자체의 절연성이 우수하여 절연효과는 있으나, 유해한 전자파와 수맥파를 차단할 수는 없다.In general, PVC flooring material has excellent insulation property, so it has insulation effect, but it cannot block harmful electromagnetic waves and water waves.

전자파란 전기 및 자기의 흐름속에 발생하는 광범위한 주파수 영역을 갖는 전자기 에너지로, 전기에 진동이 일어날 때 그 주위에는 전기력과 자기력이 동시에 발생하며 이것이 주기적으로 바뀌면서 발생하는 파동을 전자파라 한다. 전자파는 전원주파수 60Hz을 포함하는 극저주파(0∼1000Hz), 저주파(1∼500 KHz), 통신주파 (500 KHz∼3000 MHz), 마이크로 웨이브(300 MHz∼300 GHz)로 분류된다.Electromagnetic waves are electromagnetic energy with a wide frequency range occurring in the flow of electricity and magnetism. When vibrations occur in electricity, electric and magnetic forces are generated at the same time, and the waves generated by periodic changes are called electromagnetic waves. Electromagnetic waves are classified into ultra low frequency (0 to 1000 Hz) including power frequency 60 Hz, low frequency (1 to 500 KHz), communication frequency (500 KHz to 3000 MHz), and microwave (300 MHz to 300 GHz).

최근 전자기기의 사용과 고전압 송·배전선에서 발생하는 유해 전자파의 인체노출로 인하여 그 유해성 여부로 사회적인 문제가 되고 있다. 전자파 노출로 인한 유해성이 확실히 밝혀진 것은 아니나 최근 그 유해성이 조금씩 밝혀지고 있으며 전자파의 방출한계를 법적으로 규제하고 있다. 이러한 전자파는 특성상 도체에 의해 차단될 수 있다. 보통의 전자파는 도체의 다른 전하와 닿으면 쉽게 멈추어 차단된다.Recently, due to the use of electronic devices and human exposure of harmful electromagnetic waves generated from high-voltage transmission and distribution lines, social problems have arisen due to their harmfulness. Although the hazards from exposure to electromagnetic waves have not been clearly identified, the hazards have recently been revealed little by little and the emission limits of electromagnetic waves are legally regulated. Such electromagnetic waves may be blocked by conductors due to their characteristics. Normal electromagnetic waves are easily stopped and blocked when they come in contact with other charges in the conductor.

지금까지 바닥재분야에서 알려진 전자파 차폐기술은 원적외선 방사세라믹을 이용한 바닥재에 있어서 원적외선의 방사에 의해 전자파를 일부 차폐하는 기능이 있는 것으로 알려져 있을 뿐이다. 그러나 원적외선 방사세라믹을 이용한 바닥재는 인체에 유익한 원적외선의 방사를 주목적으로 하는 것이고 전자파 차폐기능은 부가적인 것으로서 충분한 전자파 차폐기능을 기대할 수는 없다.The electromagnetic shielding technology known so far in the field of flooring is known to have a function of partially shielding electromagnetic waves by radiation of far infrared rays in flooring using far-infrared radiation ceramics. However, the flooring material using far-infrared radiation ceramics mainly aims to emit far-infrared rays, which are beneficial to the human body, and the electromagnetic wave shielding function is additional, and thus, sufficient electromagnetic shielding function cannot be expected.

한편, 지구상에는 강물과 같은 지표소가 있고 땅속을 흐르는 지하수가 있으며, 이 지하수가 투수성이 좋은 흙 또는 암반 사이로 층을 이루어 서서히 움직이고있는 것을 수맥이라 한다. 독일의 물리학자 슈만(W.O Schumann)은 1952년 처음으로 지구에 전자기장이 발생한다는 것을 알렸고, 이것은 인체의 뇌파와 비슷하다고 했다. 지구의 고유진동 주파수는 7.8Hz이고 이는 인체에 해롭지 않은 땅의 주파수이다. 그러나, 수맥과 흙의 경계면에서 나오는 수맥파는 이런 정상주파수가 아니고 대지의 고유한 진동파가 수맥에 의해 교란되어 파형이 변조·증폭된 불안정한 전혀 다른 종류의 전자파이다. 따라서, 사람이 숙면을 취할시 대지의 고유진동파가 수맥에 의해 상하로 복잡하게 진동하면 그 위에 있는 사람의 뇌파도 그와 함께 공명되어 숙면상태인 4Hz이하로 내려가지 못하고 7∼8Hz 상태로 머물러 있게 되는 것이다. 이는 마치 TV 옆에 자동차가 지나가면 간섭전파가 들어와 화면이 흔들리는 것과 같은 이치이다. 따라서 수맥파를 예방하지 않으면 우리의 뇌파가 비정상적인 수맥파와 간섭되어 생체고유리듬을 잃게 된다. 이런 수맥파는 건물의 1층에만 영향을 주는 것이 아니라 20층 이상까지도 수맥파의 수직 영향을 주게 된다.On the other hand, on the earth, there are surface stations like rivers and underground water flowing through the ground, and this groundwater is gradually moving in layers between layers of permeable soil or rocks. German physicist W.O Schumann first reported the creation of an electromagnetic field on Earth for the first time in 1952, saying it resembles the brainwaves of the human body. Earth's natural vibration frequency is 7.8 Hz, which is the harmless frequency of the earth. However, the water wave coming out of the interface between the water veins and the soil is not such a normal frequency, but a completely different type of unstable electromagnetic wave in which the unique vibration wave of the earth is disturbed by the water vein and the waveform is modulated and amplified. Therefore, if the natural vibration wave of the earth vibrates up and down by water vein when a person takes a good night's sleep, the brain wave of the person on it also resonates with him, so that it stays in the state of 7-8 Hz without falling below the deep sleep state of 4 Hz. Will be. It's as if the car is passing by next to the TV and the radio wave enters and the screen shakes. Therefore, if you do not prevent the water wave, our brain wave interferes with abnormal water wave and loses the high vitreous rhythm. This water wave not only affects the first floor of the building but also vertically affects the water wave up to 20 floors or more.

이런 수맥파를 예방하는 방법으로는 동판을 바닥에 깔아주는 방법이 알려져 있다. 수맥파 역시 비정상적인 파동의 전자파이므로 도체에 닿으면 열에너지등으로 변하여 쉽게 차단될 수 있다. 그러므로 순동판을 깔아주면 대부분의 수맥파는 차단되어 수맥의 피해를 줄일 수 있다는 것이다. 그러나 동판 자체의 가격이 고가여서 상용화의 어려운 점이 있으며 시공시 별도로 동판을 깔아준 후 그위에 바닥재를 다시 시공해야 하는 번거로운 작업이 필요하게 된다. 이와같이 동판과 바닥재를 각각 별도로 시공하지 않고 박막의 동판을 바닥재 자체에 부착시킨 바닥재도 있으나, 이러한 동판을 부착한 바닥재의 경우 역시 바닥재를 제작한 후 별도의 동판을 바닥재에 부착해야 하는 번거로운 공정을 거쳐야 하며, 바닥재의 시공이 통상의 바닥재에 비해 불편한 문제점이 있다. 또한 순동판의 경우 공기, 습기와 접촉하면 산화하게 되고 산화가 진행될수록 전자파, 수맥파 차단효과가 떨어지게 된다.As a method of preventing such water wave, it is known to lay a copper plate on the floor. Water waves are also electromagnetic waves of abnormal waves, so when they touch a conductor, they can be easily cut off by turning into thermal energy. Therefore, if the copper plate is laid, most of the water waves will be blocked, which can reduce the damage of the water veins. However, due to the high price of the copper plate itself, there is a difficulty in commercialization, and it requires a cumbersome task of re-installing the flooring material after laying the copper plate separately during construction. As such, there is a flooring material in which a thin copper plate is attached to the flooring material itself without separately constructing the copper plate and the flooring material, but in the case of the flooring material to which the copper plate is attached, a separate copper plate must be attached to the flooring material after manufacturing the flooring material. And, there is a problem in that the construction of the flooring is inconvenient compared to the conventional flooring. In addition, the pure copper plate is oxidized in contact with air and moisture, and as the oxidation proceeds, the electromagnetic and water wave blocking effect is reduced.

이상과 같이 기존에는 통상의 바닥재 제조기술 및 시공기술을 그대로 응용하여 지속적인 효과를 나타내는 전자파 및 수맥파 차단용 바닥재가 개발되지 못한 실정이었다.As described above, the conventional flooring manufacturing technology and construction technology were applied as it is, the situation for the electromagnetic wave and water wave blocking flooring material showing a continuous effect has not been developed.

따라서 본 발명의 목적은 통상의 바닥재 제조기술 및 시공기술을 그대로 응용하여 제조공정 및 시공작업이 용이하여 작업성을 크게 향상시키며 효과 또한 지속적으로 나타내는 전자파 및 수맥파 차단 바닥재를 제공하는 것이다.Accordingly, an object of the present invention is to provide an electromagnetic wave and water-wave blocking flooring material by applying a conventional flooring manufacturing technology and construction technology as it is, making the manufacturing process and the construction work easier and greatly improving workability.

도 1 내지 도 3은 본 발명이 적용되는 예시적인 바닥재들의 단면도를 나타내는 것으로서,1 to 3 are cross-sectional views of exemplary floorings to which the present invention is applied.

도 1 과 도 2는 하부층과 이면층을 가지는 경보행 제품의 단면도이고,1 and 2 are cross-sectional views of an alert line product having a lower layer and a back layer,

도 3은 하부층과 이면층 및 칩층을 갖는 경보행 제품의 단면도이다.3 is a cross-sectional view of an alert line product having a lower layer, a back layer, and a chip layer.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

1 기재층, 2 상부층,1 base layer, 2 top layers,

3 인쇄무늬, 4 투명스킨층,3 printed patterns, 4 transparencies,

5 UV표면처리층, 6 하부층,5 UV surface treatment layers, 6 underlayers,

7 칩층, 8 이면층.7 chip layer, 8 back layer.

본 발명자는 상기의 목적을 달성할 수 있는 바닥재를 개발하고자 예의 연구한 결과, 전도성 필러를 바닥재의 배합원료에 첨가하므로써 바닥재가 전도성을 갖게 하여 전자파 및 수맥파를 흡수하고, 바닥면을 통한 접지효과를 갖게하여 전자파와 수맥파를 효과적, 지속적으로 차단할 수 있으며, 제조공정 및 시공상의 번거로움도 해소할 수 있다는 것을 밝혀내어 본 발명을 완성하게 되었다.The present inventors earnestly researched to develop a flooring material that can achieve the above object, and by adding a conductive filler to the blending material of the flooring material, the flooring material becomes conductive, absorbs electromagnetic waves and water waves, and improves the grounding effect through the floor surface. The present invention was completed by revealing that the electromagnetic wave and the water wave can be effectively and continuously blocked, and also the manufacturing process and construction trouble can be eliminated.

본 발명의 전자파 및 수맥파 차단 바닥재는 다층구조의 바닥재에 있어서 하부층과 이면층에 각각 다른 성분의 전도성 필러를 함유시켜 제조된 것을 특징으로 한다.Electromagnetic wave and water-wave blocking flooring material of the present invention is characterized in that it is prepared by containing a conductive filler of different components in the lower layer and the back layer in the flooring of the multi-layer structure.

본 발명에 사용되는 전도성 필러로는 판상동가루(Cu분말)와 자철광 함유 세라믹 분말등이 있으며, 이중 자철광 함유 세라믹 분말은 자장을 발생시켜 유해파가 통과하지 못하도록 약한 자장막을 형성하므로 수맥차단효과를 더욱 극대화할 수 있다. 또한 판상동가루는 산화되는 단점을 보완키 위해 니켈이나 은 코팅을 하여 산화방지처리가 되어 있어 반영구적인 전자파 및 수맥파 차폐 성능을 갖는다. "자철광 함유 세라믹 분말"은 "에버프리"((주)휴먼테크사제품)를 사용할 수 있고 산화방지 처리가 된 판상동가루는 MD150(미국, M.D. BOTH사 제품)을 사용할 수 있다.Conductive fillers used in the present invention include plate-like copper powder (Cu powder) and magnetite-containing ceramic powder, etc., the double magnetite-containing ceramic powder generates a magnetic field to form a weak magnetic film to prevent harmful waves pass through the water vein blocking effect It can be maximized. In addition, plate-like copper powder has a semi-permanent electromagnetic and water wave shielding performance because it is treated with an anti-oxidation treatment by coating nickel or silver to compensate for the disadvantage of being oxidized. "Magnetite-containing ceramic powder" can use "Everfree" (manufactured by Human Tech Co., Ltd.) and MD150 (manufactured by M.D.

본 발명의 바닥재에서 하부층과 이면층에 배합되는 전도성 필러의 함량의 범위는 각층별로 10∼50중량부가 적합하다. 따라서 바닥재에 배합되는 전도성 필러의 총량은 20∼100중량부가 적합하며, 20중량부 미만이면 전자파와 수맥파의 차단효과가 미미하고, 100중량부를 초과하면 필러자체가 고체분말이므로 PVC 수지의 점도가 상승하므로 바람직하지 않다.In the flooring of the present invention, the content of the conductive filler blended into the lower layer and the back layer is preferably 10 to 50 parts by weight for each layer. Therefore, the total amount of the conductive filler blended to the flooring material is suitable 20 to 100 parts by weight, less than 20 parts by weight of the electromagnetic wave and water wave blocking effect is insignificant, if the content of more than 100 parts by weight of the filler itself is a solid powder, the viscosity of the PVC resin increases Therefore, it is not preferable.

본 발명에 따른 전자파 및 수맥파 차단 바닥재는 일반적인 바닥재의 제조공정과 동일한 공정으로 생산할 수 있으며, 이를 일반적인 가정용 바닥재를 일예로 들어 설명하면 다음과 같다.Electromagnetic wave and water-wave blocking flooring according to the present invention can be produced in the same process as the manufacturing process of the general flooring, this will be described as an example of a typical household flooring.

도 1에 도시된 구조를 갖는 일반적인 가정용 경보행 바닥재는 기재층(1) 위에 발포 또는 비발포 상부층(2)을 합판하여 로타리 스크린이나 그라비아와 같은 다양한 인쇄무늬(3)를 형성하여 투명스킨층(4)를 적층하고, 하부층(6) 및 이면층(8)을 적층하여 얻은 반제품 위에 UV표면처리층(5)을 적층하여 제조된다.The general household alarm line flooring having the structure shown in FIG. 1 is formed of various printed patterns 3 such as rotary screens and gravures by laminating a foamed or non-foamed upper layer 2 on the substrate layer 1 to form a transparent skin layer ( 4) is laminated and the UV surface treatment layer 5 is laminated on the semi-finished product obtained by laminating the lower layer 6 and the back layer 8.

기재층(1)은 부직포형태로 이루어진 유리섬유매트에 PVC페이스트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3중량부, 충진제 50∼200중량부를 넣어 배합한 페이스트졸을 함침시켜 140∼200℃의 겔링드럼이나 오븐을 이용, 가열건조하여 제조한다.The base material layer 1 is impregnated with a paste sol mixed with 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, and 50 to 200 parts by weight of filler to a glass fiber mat composed of a nonwoven fabric. It is prepared by heating and drying using a gelling drum at ˜200 ° C. or an oven.

상기 기재층(1) 위에 발포상부층(2)을 적층하는 방법은 공지의 나이프코타, 리버스코타, 바코타, 스크린 코타등을 이용하여 코팅한 후 140∼170℃의 겔링드럼이나 오븐을 이용하여 충분히 겔링하는 방법이나 카렌다를 이용한 압연가공이나 T다이를 이용한 압출가공으로 시트를 제작하여 가열 합판하는 방법으로 제조가 가능하다.The method of laminating the foamed upper layer 2 on the base layer 1 is coated using a well-known knife coater, river coater, bar coater, screen coater, etc., and then sufficiently using a gelling drum or oven at 140 to 170 ° C. The sheet may be manufactured by a method of gelling, rolling by calendering, or extrusion using T-die, followed by heating plywood.

상기 발포 또는 비발포상부층(2)은 PVC 페이스트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3 중량부, 발포제 0∼5중량부, 충진제 10∼50중량부, Zn계 촉진제 1∼5중량부를 정량투입하여 고속 임펠러가 있는 믹서기에서 10∼40분간 믹싱하여 내부 온도를 40℃ 이하가 되게 유지하는 졸가공 방법이나, PVC 스트레이트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3중량부, 발포제 1∼5중량부, 충진제 10∼50중량부, Zn계 촉진제 1∼5중량부를 정량투입하여 슈퍼 믹서기에서 5∼20분간 믹싱하여 카렌다에서 압연가공하거나 T다이에서 압출 가공한 시트를 가열 합판하므로써 얻을 수 있다.The foamed or non-foamed upper layer 2 is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, 0 to 5 parts by weight of blowing agent, 10 to 50 parts by weight of filler, Zn-based accelerators 1 to 5 parts by weight of quantitatively mixed in a mixer with a high-speed impeller for 10 to 40 minutes to maintain the internal temperature to 40 ℃ or less, 100 parts by weight of PVC straight resin, 40 to 70 parts by plasticizer, stabilizer 1 ~ 3 parts by weight, 1 to 5 parts by weight of blowing agent, 10 to 50 parts by weight of filler, and 1 to 5 parts by weight of Zn-based accelerator are metered in, mixed in a super mixer for 5 to 20 minutes, rolled in calender or extruded in T die. It can be obtained by heating plywood.

이와같이 기재층(1)에 상부층(2)을 적층하여 제조한 반제품위에 다양한 무늬와 색상의 인쇄(3)를 하게 되는데, 인쇄는 공지의 그라비아 인쇄, 옵셋인쇄, 로타리 스크린 인쇄공법을 이용하며, 이때 이용되는 잉크는 PVC계 공중합체 10∼40중량부, 유기용제 30∼70중량부, 미분산된 유기계 또는 무기계 안료 1∼20중량부를 투입하여 고속 믹서로 혼합하여 적용할 수 있다.In this way, various patterns and colors can be printed (3) on the semi-finished product manufactured by laminating the upper layer (2) on the base layer (1), and the printing uses a known gravure printing, offset printing, and rotary screen printing method. The ink used may be applied by mixing 10-40 parts by weight of a PVC copolymer, 30-70 parts by weight of an organic solvent, 1-20 parts by weight of an undispersed organic or inorganic pigment, and mixing with a high speed mixer.

상기 과정에 의해 인쇄가 완료되면 그 인쇄된 상부에 투명스킨층(4)을 적층하게 되는데, 투명스킨층은 PVC 페이스트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3중량부, 자외선을 흡수할 수 있는 자외선 흡수제 0.1∼1 중량부를 상기 상부층(2)과 같이 고속 임펠러가 있는 믹서기에서 10∼40분간 믹싱하여 내부 온도를 40℃ 이하가 되게 유지하는 졸가공 방법이나, PVC 스트레이트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3중량부, 자외선 흡수제 0.1∼1 중량부를 정량투입하여 슈퍼 믹서기에서 5∼20분간 믹싱한 다음 카렌다에서 압연가공을 하거나 T다이에서 압출가공을 하므로써 시트를 얻을 수 있고, 이를 가열 합판하는 방법으로 적층이 가능하다.When the printing is completed by the above process, the transparent skin layer 4 is laminated on the printed upper part. The transparent skin layer is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, and ultraviolet ray. 0.1-1 parts by weight of a UV absorber capable of absorbing a sol processing method of mixing in a mixer with a high-speed impeller as in the upper layer 2 for 10 to 40 minutes to maintain an internal temperature of 40 ° C. or less, or a PVC straight resin 100 By weight, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, 0.1 to 1 part by weight of ultraviolet absorber are mixed and mixed in a super mixer for 5 to 20 minutes, followed by rolling on a calendar or extrusion on a T die. A sheet can be obtained, which can be laminated by heating plywood.

이렇게 얻어진 반제품에 쿳션성을 부여하기 위한 하부층(6)을 적층 발포하는데, 하부층(6)은 PVC 페이스트 수지 100중량부, 가소제 40∼70중량부, 안정제 1∼3중량부, 발포제 1∼5중량부, 충진제 10∼50중량부, Zn계 촉진제 1∼5중량부, 자철광 함유 세라믹분말 10∼50 중량부를 정량 투입하여 고속 임펠러가 있는 믹서기에서 10∼40분간 믹싱하는 졸 가공방법이나, 또는 PVC 스트레이트 수지를 이용하여 카렌다에서 압연가공하거나 T다이에서 압출가공한 시트를 가열 합판하여 180∼250℃의 발포오븐을 거치므로써 발포체를 얻는 일반적인 방법에 의해 형성될 수 있다.The bottom layer 6 is laminated and foamed to give cushioning property to the semi-finished product thus obtained, and the lower layer 6 is 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 3 parts by weight of stabilizer, and 1 to 5 parts by weight of foaming agent. 10 to 50 parts by weight of filler, 1 to 5 parts by weight of Zn-based accelerator, 10 to 50 parts by weight of magnetite-containing ceramic powder, and a sol processing method for mixing for 10 to 40 minutes in a mixer with a high speed impeller, or PVC straight The sheet may be formed by a general method of obtaining a foam by heating a sheet of the sheet which is rolled in a calendar or extruded in a T die using a resin and passing through a foam oven at 180 to 250 ° C.

또한 하부층(6) 밑에는 이면층(8)을 적층하는데, 이면층(8)에는 PVC 페이스트수지 100중량부, 가소제 40∼70중량부, 안정제 1∼5중량부, 충진제 10∼50중량부, 산화방지처리가 된 판상동가루 10∼50중량부를 정량 투입하여 고속 임펠러가 있는 믹서기 내에서 10∼40분간 믹싱하는 졸 가공방법이나 또는 PVC 스트레이트 수지를 이용하여 카렌다에서 압연가공하거나 T다이에서 압출가공을 함으로써 시트를 얻을 수 있고 이를 가열합판하는 방법으로 적층이 가능하다.In addition, under the lower layer 6, the back layer 8 is laminated. In the back layer 8, 100 parts by weight of PVC paste resin, 40 to 70 parts by weight of plasticizer, 1 to 5 parts by weight of stabilizer, 10 to 50 parts by weight of filler, 10 to 50 parts by weight of plated copper powder subjected to antioxidant treatment is added and mixed in a sol processing method in a mixer with a high speed impeller for 10 to 40 minutes, or rolled in a calendar using PVC straight resin, or extruded in a T die. The sheet can be obtained by laminating and lamination can be performed by heating and plywood.

이와같이 제조된 바닥재의 표면을 자외선 경화타입 도료로 표면처리하여 UV 표면처리층(5)을 형성하므로써 본 발명의 바닥재가 완성된다.The flooring material of the present invention is completed by forming a UV surface treatment layer 5 by surface-treating the surface of the flooring material thus prepared with an ultraviolet curing paint.

본 발명은 상기와 같은 도 1의 일반적인 가정용 바닥재외에도 도 2와 같이 기재층(1) 위에 상부층(2)을 적층하고 그위에 인쇄무늬(3)를 인쇄한 다음 접착층을 형성하는 페이스트졸층을 도포하고 정형 또는 무정형의 칩을 산포하여 칩층(7)을 형성한 바닥재에도 적용된다. 또한 도 3과 같이 인쇄층이 없는 즉, UV표면 처리층 (5), 스킨층(4), 상부층(2), 기재층(1), 하부층(6), 이면층(8)으로 구성된 바닥재 등에도 적용가능하다.The present invention, in addition to the general home flooring of FIG. 1 as described above, as shown in FIG. 2, the upper layer (2) is laminated on the base layer (1), and the printed pattern (3) is printed thereon and then a paste sol layer is formed to form an adhesive layer. The same applies to the flooring material on which the chip layer 7 is formed by dispersing amorphous chips or amorphous chips. In addition, as shown in FIG. 3, that is, a floor covering composed of a UV surface treatment layer 5, a skin layer 4, an upper layer 2, a base layer 1, a lower layer 6, and a back layer 8 as shown in FIG. 3. Is also applicable.

본 발명은 상기예에 한정되지 않으며 하부층과 이면층을 가지고 있는 모든 바닥재에 적용할 수 있으며, 하부층과 이면층 이외의 기타층을 선택하여 전도성 필러의 적용이 가능하다.The present invention is not limited to the above examples and can be applied to all flooring materials having a lower layer and a back layer, and the conductive filler can be applied by selecting other layers other than the lower layer and the back layer.

또한 본 발명은 비닐 시트상의 바닥재뿐 아니라 비닐 타일계 상재에도 적용될 수 있다.In addition, the present invention can be applied to vinyl tile-based floorings as well as vinyl sheet floorings.

이하 적용예를 통하여 본 발명의 효과를 상세하게 설명한다.Hereinafter, the effects of the present invention will be described in detail through application examples.

적용예 1Application example 1

도 1과 같은 구조의 바닥재에 있어서 하부층(6)에 자철광 함유 세라믹 분말 (MD150, 미국, M.D. BOTH사 제품)을 첨가하여 상술한 통상의 방법으로 바닥재를 제조하였고, 제조된 바닥재의 20℃에서의 표면저항값을 표면저항계(Megaresta (HT-301), 일본 SHISHIDO ELECTRIC CO.사 제품)를 사용하여 측정하였다. 표면저항값의 의미는, 전자파 또는 수맥파가 도체에 닿으면 열에너지 등으로 소모되므로 저항값이 작아야 좋은 도체이고, 따라서 저항값이 작을수록 전자파 및 수맥파 차단능력이 우수하다는 것을 의미한다.In the flooring having the structure as shown in FIG. 1, magnetite-containing ceramic powder (MD150, manufactured by MD BOTH Co., Ltd.) was added to the lower layer 6, and the flooring was manufactured by the conventional method described above. Surface resistance values were measured using a surface resistance meter (Megaresta (HT-301), manufactured by Shishido Electric Co., Ltd., Japan). The meaning of the surface resistance value is a good conductor when the electromagnetic wave or the water wave touches the conductor and is consumed by thermal energy, etc., and thus the smaller the resistance value, the better the electromagnetic and water wave blocking ability.

표면저항값 측정결과는 표 1과 같다.Surface resistance measurement results are shown in Table 1.

표 1.Table 1.

Figure pat00001
Figure pat00001

적용예 2Application example 2

도 1과 같은 구조의 바닥재에 있어서 이면층(8)에 전도성 필러로서 판상동가루를 첨가하여 바닥재를 제조하였고, 적용예 1에서와 같이 표면저항값을 측정하였다.In the flooring having the structure as shown in FIG. 1, plate-like copper powder was added to the back layer 8 as a conductive filler to prepare a flooring, and the surface resistance value was measured as in Application Example 1.

결과는 표 2와 같다.The results are shown in Table 2.

표 2.Table 2.

Figure pat00002
Figure pat00002

적용예 3Application example 3

도 1과 같은 구조의 바닥재에 있어서 하부층(6)에 자철광 함유 세라믹 분말을, 이면층(8)에 판상동가루를 적용하여 바닥재를 제조하였고, 적용예 1에서와 같이 표면저항값을 측정하였다.In the flooring having the structure as shown in FIG. 1, the flooring was prepared by applying magnetite-containing ceramic powder to the lower layer 6 and plate-like copper powder to the backing layer 8, and the surface resistance value was measured as in Application Example 1.

결과는 표 3과 같다.The results are shown in Table 3.

표 3.Table 3.

Figure pat00003
Figure pat00003

본 발명에 따른 바닥재는 기존의 전자파 또는 수맥파를 방지하기 위하여 시공하던 동판과는 달리 통상의 바닥재 제조공정에 따라 간편하게 제조할 수 있어 제조공정상의 번거로움 및 시공상의 번거로움을 피할 수 있어 제조공정의 용이성의면에서 커다란 장점이 있으며, 시공후 전자파 및 수맥파 차단효과를 지속적으로 유지할 수 있어 효과적이다. 본 발명에 따라 제조된 바닥재는 판상동가루를 바닥재의 이면에 형성, 동판을 형성한 것과 같은 이치로 전자파 및 수맥파를 차단하며 차단원리는 이면층(8)의 판상동가루에 닿은 전자파 및 수맥파가 통과를 하지 못하고 전기전도성이 좋은 동가루를 따라 맴돌이전류 또는 열에너지 등으로 변해 지면으로 방출된다.The flooring according to the present invention can be easily manufactured in accordance with the conventional flooring manufacturing process, unlike the conventional copper plate to prevent the electromagnetic or water wave can be avoided in the manufacturing process hassle and construction hassle It has great advantages in terms of ease of use, and it is effective because it can continuously maintain the electromagnetic and water wave blocking effects after construction. The flooring manufactured according to the present invention blocks electromagnetic waves and water waves by forming plate-like copper powder on the back surface of the flooring material, and forms a copper plate, and the blocking principle is that electromagnetic and water-wave waves that touch the plate-like powder of the back layer 8 pass. It can't be released and changes to eddy current or heat energy along with copper powder with good electrical conductivity.

동은 전기전도성이 뛰어난 비자성체 금속으로 전자파 및 수맥파와 같은 저주파의 차단에 매우 효과적이다.Copper is a non-magnetic metal with excellent electrical conductivity, and is very effective in blocking low frequencies such as electromagnetic waves and water waves.

또한 하부층(6)에 자철광 함유 세라믹분말을 사용하여 바닥면에 자장을 형성, 전자파 및 수맥파가 통과하지 못하도록 이중으로 차단하여, 전자파 및 수맥파의 차단효과를 극대화 하였다. 이때 사용하는 자철광 함유 세라믹분말은 지표나 건축물의 콘크리트면에 에너지장을 전달, 형성함으로써 그 에너지 파장벽을 수맥파가 통과하지 못하도록 분산파괴 시킴으로써 전자파 및 수맥파를 차단하는 효과를 갖는다.In addition, a magnetite-containing ceramic powder was used in the lower layer 6 to form a magnetic field on the bottom surface, thereby blocking the electromagnetic wave and the water wave twice, thereby maximizing the blocking effect of the electromagnetic wave and the water wave. The magnetite-containing ceramic powder used in this case has an effect of blocking electromagnetic waves and water waves by dispersing and breaking the energy wavewalls so that the water waves cannot pass through the energy field by transmitting and forming an energy field on the surface of a surface or concrete of a building.

또한 동판은 시간이 지남에 따라 자연적인 산화로 인한 효과의 감소가 있으나 본 발명에서 사용하는 판상동가루는 산화방지처리를 하여 시공후 반영구적인 전자파 및 수맥파 차단 효과를 갖는다.In addition, the copper plate has a decrease in effect due to natural oxidation over time, but the plate-like copper powder used in the present invention has an anti-oxidation treatment and has a semi-permanent electromagnetic and water wave blocking effect after construction.

또한 판상동가루나 자철광 함유 세라믹 분말을 이면층과 하부층 이외의 기타층에 적용하여 사용하는 것도 가능하다.It is also possible to apply plate-like copper powder or magnetite-containing ceramic powder to other layers other than the back layer and the lower layer.

Claims (2)

다층구조로 이루어진 바닥재에 있어서, 상기 바닥재의 하부층에 전도성 필러로서 자철광 함유 세라믹 분말이 함유되고, 이면층에 전도성 필러로서 니켈 또는 은을 코팅하여 산화방지처리가 된 판상동가루가 함유되어 있는 것을 특징으로 하는 전자파 및 수맥파 차단기능을 갖는 바닥재.In the flooring having a multi-layer structure, the lower layer of the flooring contains a magnetite-containing ceramic powder as a conductive filler, and the back layer contains plate-like copper powder which has been subjected to oxidation treatment by coating nickel or silver as a conductive filler. Flooring having electromagnetic and water wave blocking function. 제 1항에 있어서, PVC 수지 100중량부에 대하여 전도성 필러의 함유량은 각각 10∼50중량부 임을 특징으로 하는 바닥재.The flooring material according to claim 1, wherein the content of the conductive filler is 10 to 50 parts by weight based on 100 parts by weight of the PVC resin.
KR1019970071213A 1997-12-20 1997-12-20 Multi-layered flooring materials comprising conductive filler in bottom layer and having property of blocking electrowaves and harmful groundwater vein waves KR100423841B1 (en)

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KR20020011826A (en) * 2000-08-04 2002-02-09 김용구 Might of water-vein proof floor, used seven precious stone
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62185729A (en) * 1986-02-10 1987-08-14 Hitachi Cable Ltd Electroconductive resin composition and electroconductive floor sheet
JPH0216259A (en) * 1988-07-04 1990-01-19 Shimizu Corp Constructing method for electromagnetic shielding floor
KR970033807A (en) * 1997-04-04 1997-07-22 홍순군 Sheet paper laminated with metal film
KR0117789Y1 (en) * 1994-06-10 1998-04-24 도상국 Floor sheet
KR980010084U (en) * 1996-07-04 1998-04-30 손동창 Long cardboard with electromagnetic shielding material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62185729A (en) * 1986-02-10 1987-08-14 Hitachi Cable Ltd Electroconductive resin composition and electroconductive floor sheet
JPH0216259A (en) * 1988-07-04 1990-01-19 Shimizu Corp Constructing method for electromagnetic shielding floor
KR0117789Y1 (en) * 1994-06-10 1998-04-24 도상국 Floor sheet
KR980010084U (en) * 1996-07-04 1998-04-30 손동창 Long cardboard with electromagnetic shielding material
KR970033807A (en) * 1997-04-04 1997-07-22 홍순군 Sheet paper laminated with metal film

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