KR100403057B1 - Cellulose-binding fibres - Google Patents

Abstract

The present invention relates to a drylay nonwoven fabric, wherein the drylay nonwoven fabric comprises bicomponent fibers composed of a low melt polyolefin component and a high melt polyolefin component, wherein the low melt polyolefin component constitutes at least a part of the surface of the fiber and is grafted. Consisting of a grafted polyolefin component and an grafted polyolefin component, wherein the grafted polyolefin component is grafted with unsaturated dicarboxylic acid or its anhydrides such as maleic acid or maleic anhydride, and the bicomponent fibers are combined with cellulose pulp fibers It is possible to produce airlay nonwovens with good binding affinity for the same natural fibers, with reduced dust generation and improved strength properties during the production process.

Description

Cellulose binding fiber {CELLULOSE-BINDING FIBRES}

Hygiene absorbent products, such as disposable diapers, with a permeable coverstock, an impervious backsheet, and one or more liquid dispersion layers, are made from natural fibers such as cellulose fuzz pulp fibers, such as polyolefins and / or polyesters. Synthetic fibers based on and absorbent cores containing superabsorbent polymer (SAP) materials. In this type of absorbent core, the synthetic fibers, which are bicomponent fibers such as polypropylene / polyethylene or polyester / polyethylene and the like, are thermally bonded to each other to form a support network for the core. In principle, not only the synthetic fibers are bonded to each other, but also the natural structure and the SAP are combined so that the core structure is as tightly adhered as possible, and the natural fiber and the SAP are fixed at a position in the structure.

However, synthetic fibers are currently used in the manufacture of drylays such as airlays, and nonwoven fabrics have the disadvantage of being suboptimally bonded to, for example, cellulose fibers. This problem is generally exacerbated by the fact that natural fibers are relatively short, such as but not limited to fine hairy pulp fibers having a length of at most 3 mm when compared to fairly long synthetic fibers. As a result, the performance of the nonwoven is suboptimal because dust problems arise during the manufacturing process, and because a large proportion of natural fibers are bonded by a structure that does not bind to synthetic fibers or is formed by the bonding of synthetic fibers.

It is an object of the present invention to provide a bicomponent synthetic fiber having an improved binding affinity for natural fibers such as cellulose fine pulp fibers and particularly suitable for the production of drylay nonwovens which are a mixed construction of natural and synthetic fibers.

EP 0465203-B1 discloses 0.94-0.965 g grafted with a first component of polypropylene, polyamide or polyester and maleic anhydride or maleic acid for providing succinic anhydride groups or succinic acids according to HDPE polymers. thermally bonded fibrous comprising a bicomponent fiber consisting of a second component of grafted high density polyethylene (HDPE) with a density of / cc and linear low density polyethylene (LLDPE) with a density of 0.88-0.945 g / cc The wet laid web of is known.

European Patent No. 0421734-B1 discloses thermally bondable bicomponent fibers composed of two different polyolefins with melting points that differ by at least 20 ° C., low melt polyolefins are monoglycerides of fatty acids bound by at least 12 carbon atoms. 3-10% by weight of the ride. It has been reported that this fiber proceeds easily without the emulsion applied during spinning or drawing.

US Pat. No. 4,950,541 discloses succinic and succinic anhydride grafts of linear ethylene polymers obtained by grafting male anhydride or maleic acid with low density polyethylene (LDPE), LLDPE or HDPE polymers. The grafted polymer is dyeable and can be used, for example, as the seed component of bicomponent fibers.

U.S. Pat. No. 4,684,576 discloses a grafted product of grafted LLDPE or LDPE and grafted HDPE, which is grafted with maleic anhydride or maleic acid to provide succinic anhydride groups or succinic acids according to HDPE polymers. Will be Mixtures are known for use in the production of laminate structures.

Polyolefin bicomponent fibers having a low melting point component are grafted with unsaturated dicarboxylic acids or their anhydrides, which have advantages when used in the production of drylay nonwovens, with improved strength and improved binding to cellulose pulp fibers in the resulting nonwovens. It is surprisingly understood that it consists of a polyolefin component that has been grafted and an grafted polyolefin component.

The present invention relates to drylaid nonwoven materials comprising polyolefin bicomponent fibers having good binding affinity for natural fibers such as cellulose fibers.

Brief description of the invention

In one aspect of the invention, the invention is directed to a drylay nonwoven fabric comprising bicomponent fibers consisting of a low melting polyolefin component and a high melting polyolefin component, wherein the low melting polyolefin component is at least above the melting point of the high melting polyolefin component. With a low melting point of 4 ° C., the low melting polyolefin component constitutes part of the surface of the fiber and consists of grafted polyolefin components and ungrafted polyolefin components, where the grafted polyolefin component is unsaturated dicarboxylic acid or It is grafted with anhydride.

Another aspect of the invention relates to a method for producing a drylay nonwoven fabric, comprising forming a fibrous web using a drylay nonwoven device, the web comprising a low melting point polyolefin component and a high melting point polyolefin component Wherein the low melting polyolefin component has a melting point about 4 ° C. lower than the melting point of the high melting polyolefin component, the low melting polyolefin component forming part of the fiber surface, and the grafted polyolefin component An grafted polyolefin component, wherein the grafted polyolefin component combines the fibrous web resulting from the drylay nonwoven and is grafted with unsaturated dicarboxylic acids and anhydrides thereof.

Another aspect of the invention relates to bicomponent fibers as described above for the production of drylay nonwovens.

Detailed description of the invention

The term "polyolefin component" for the purposes of the present invention refers to the largest portion of polyolefin-containing polymers making up a single or interpolymer of monoolefins such as ethylene, propylene, 1-butene, 4-methyl-1-pentene and the like. it means. Examples of such polymers are polyethylenes of different densities, such as homo- or regular-arranged polypropylene, low density polyethylene, high density polyethylene and linear low density polypropylene, and mixtures thereof. The polymer can be mixed with other non-polyolefin polymers, such as polyamides or polyesters, to provide the polyolefins that make up the largest portion of the compound. Melts used to produce polyolefin-containing fibers include bleaches and colorants such as TiO ₂ and the like, and may include various conventional fiber additives such as pigments, compounding agents, process stabilizers, antioxidants and calcium stear.

The specification of the present invention refers to chopped staple fibers as “fibers” for the sake of simplicity, and it is understood that the present invention is also applicable to the continuous production of polyolefin filaments such as spunbonded filaments.

The term "drylay" nonwoven refers to a nonwoven produced by a dry process, including carded nonwovens, airlay nonwovens, and the like.

The bicomponent fibers can be seed-cored or parallel with cores located eccentrically (out of center) or concentrically (usually centered), each of which typically has a semi-circle cross section. Have Bicomponent fibers with irregular fiber profiles are envisioned as splittable fibers as well as ovals, ellipses, deltas, stars, multiglobals, or other irregular intersections. Bicomponent fibers will typically have a polyolefin component having a high melting point and a low melting point, each of which is polypropylene / polyethylene (polyethylene includes HDPE, LDPE and / or LLDPE), high density polyethylene / linear low density polyethylene, polypropylene random air Copolymers / polyethylene, or polypropylene / polypropylene random copolymers.

In any case, for example, when the bicomponent fiber comprises a high density polyethylene / linear low density polyethylene or a polypropylene / polypropylene random copolymer, the difference in melting point between the two polyolefins is in some cases about 7-8 ° C., It can even be very small, about 4-5 ° C. However, the two components have a melting point that differs by at least about 20 ° C. and preferably differs by about 25 ° C., most preferably at least about 28 ° C., for example about 30 ° C.

As mentioned above, a preferred aspect of the present invention relates to a drylay nonwoven fabric containing polyolefin bicomponent fibers in a low melting polyolefin comprising an grafted component and a grafted component, wherein the grafted component is unsaturated dicarboxyl. Grafted with acid or its anhydride Examples of the acid and anhydride include maleic acid, maleic anhydride and derivatives thereof such as citraconic acid, citraconin anhydride and pyrosineconine anhydride; Fumaric acid and its derivatives; Unsaturated derivatives of malonic acid such as 3-butene-1, 1-dicarboxylic acid, benzylidene malonic acid and isopropylidene malonic acid; And succinic unsaturated derivatives such as itaconic anhydride and itaconic acid.

It is especially preferable that maleic acid and maleic anhydride are dicarboxylic acid or its anhydride. When the compound is grafted with a polyolefin chain, the resulting chain is provided with succinic acid or succinic anhydride groups and grafted onto them, respectively. The grafting of dicarboxylic acids or their anhydrides to polyolefins can be carried out by known methods, see above mentioned European Patent EP 0465203, US Pat. No. 4,950,541 and US Pat. No. 4,684,576.

The mass ratio of polyolefins grafted with ungrafted polyolefins in the low melting point polyolefin component of the bicomponent fiber is about 1:99 to 50:50, typically about 1.5: 98.5 to 30:70, more typically about 5:95 To about 10:90 but about 3:97 to 15:85.

In the grafted polyolefin, the content of carboxylic acid or its anhydride is in the range of about 1-30% (weight), typically about 2-20%, more typically 3-15%, such as 5-10% Is in.

The mass ratio between the high and low melting polyolefin components is about 30:70 to 70: 10:90 to 90:10, typically 20:80 to 80:20, more typically 35:65 to 65:35. It will be in the range of 30.

As described above, the drylay nonwoven fabric according to the present invention comprising natural fibers and polyolefin bicomponent fibers reflects the quality of bonding between the two types of fibers into natural fibers as determined by standard dust testing. It is characterized by improved binding of bicomponent fibers. In this standard test, a drylay nonwoven sample having a thickness of about 1.1 and a basis mass of about 85 g / m 2 was 25% by mass of the synthetic fibers tested and 75% by mass of cellulose pulp fibers (eg, Weyerhauser NB 416). It is prepared at a line speed of 20 to 40 m / min by mixing. The nonwovens to be tested are made using a series of different bonding temperatures (eg, hot air or calender bonding, typically hot air ovens) to optimize the properties of a given nonwoven.

The determination of the dust value of the nonwoven is determined as follows. Before the measurement is performed, the nonwoven sample tested is adjusted for at least 12 hours to ensure that all samples remain at the same temperature and humidity conditions. As described below, the results are expressed in relative values compared to control values, and the exact temperature and relative humidity for the state of the sample is not critical, and all compared samples will remain the same for as long as possible. Ambient temperature and humidity conditions are used for this. Before being adjusted, the nonwoven is cut into samples having a size of 12 × 30 cm. After being adjusted, a cardboard strip with a width of 5 mm is attached to the short cross section of the sample, and the sample to which the cardboard strip is adhered is measured in an experimental device having a precision of ± 0.1 mg. The nonwoven samples tested were fastened to two clamps having a length of 12 cm and then each was installed on the arm. The exposed area of the fixed nonwoven fabric is about 310 cm 2, which is A4 paper size. One of the arms is fixed and the other is rotatable and attached to the spring.

The test is performed by rotating the rotatable arm 45 ° so that after loosening, the nonwoven sample is moved from the "stretched" state to the "loose" state, whereby the rotatable arm causes the spring to actuate the rotatable arm. Return to position Arm movement is stopped by the nonwoven sample, which is susceptible to small vibration and stretching effects designed to resemble the state of the nonwoven roll when released from the converter, which causes the loss of coarse fibers at the fiber surface. do. The operation is repeated 50 times. Stretching forces the sample, which is a course within the elastic limits of the nonwoven, so that the nonwoven is not deformed or damaged during the test. For the same reason, the tensile strength of the other nonwoven fabrics varies and the spring force is suitable for the nonwoven fabric being tested, so that the nonwoven fabric returns to its original stretched position, with some vibration and stretching but the other side deformed or It is not excessively stretched to be damaged.

After 50 vibration / stretching actions, the sample is weighed, the difference between the two values is calculated, and dust is expressed in mg.

In a standard dust test, the results in mg will be only about 15 mg, typically 10 mg, preferably 5 mg, more preferably 4 mg, even more preferably 3 mg, most preferably 2 It will be only mg. For nonwovens with a particularly good affinity between synthetic and natural fibers, the results can be as low as 1 mg of dust.

A preferred alternative method of defining the dust-reducing properties of a given fiber in a standard dust test is the amount of dust in a standard nonwoven fabric made from the fibers of the present invention as compared to a similar nonwoven fabric made from similar fibers without the grafted polyolefin component. Mg). In such cases, nonwovens made from the fibers of the present invention exhibit at least about 40 wt% dust reduction, typically at least about 50 wt% dust reduction compared to control nonwovens made from control fibers. Preferably, the dust reduction is at least 60% by weight, more preferably at least about 70% by weight, even more preferably at least about 80% by weight. Especially for fibers with good cellulose-binding properties, the dust reduction may be about 90% or more. The dust properties of a given nonwoven fabric vary greatly depending on factors such as bonding and unique web formation as well as other fibers and natural cellulose and natural bicomponent fibers, for example compared to similar control fibers rather than absolute values in mg. It is desirable to compare the performance of a given fiber against the rate of dust reduction.

It can be seen that the present invention provides improved fixation and bonding of cellulose fibers as well as other superabsorbent polymers (SAPs) commonly used in hygienic adsorbents produced in the form of particles or fibers. SAPs, such as crosslinked polyacrylates, are used in the form of superabsorbent particles in adsorbent cores, such as disposable diapers, to absorb the liquid multiple times and to fix the liquid in the form of a gel. Even because the fibers of the present invention are not directly bonded to the SAP particles, the fibers of the present invention, which have improved binding to cellulose fibers, will have an improved structure such that the SAP particles maintain the desired position in the adsorbent product, with the function of SAP Will be improved.

Spinning of the fibers is preferably accomplished using conventional melt spinning (also known as "long spinning") methods, with spinning and stretching being performed in two separate steps. Alternatively, other methods for the production of staple fibers, in particular "compact squares", which are a one step process, can be used for practicing the present invention. Methods for the spinning of filaments and bicomponent fibers are known to those skilled in the art. The method can be achieved by filament treatment, filament treatment with suitable spin finish that results in desirable surface properties such as using a spin finish method to provide hydrophilic properties when the fibers are used in the adsorbent core and / or provide antistatic properties. It involves cooling and drawing, melt extrusion for filament production, filament stretching, typically a second spin finish treatment, filament texturing, filament drying and staple fiber cutting.

As mentioned above, the drylay nonwoven fabric of the present invention is generally a regenerated or natural fiber selected from at least one additional fibrous material, cellulose fiber, viscose rayon fiber and lyocell fiber, in addition to the polyolefin bicomponent fiber. It consists of. Cellulose fibers can be, for example, cotton fibers or pulp fibers, and are special pulp fibers such as sulfite pulp, kraft pulp or chemi-thermo-mechanical pulp (CTMP).

Fibrous webs comprising bicomponent fibers and additional fiber materials generally comprise 5-50% by weight of bicomponent fibers and 50-95% by weight of additional fiber materials, even more preferably 10-40% by weight It is more preferred to include powdered fibers and 60-9-% by weight of additional fiber material, such as 15-25% by weight of bicomponent fiber and 75-85% by weight of additional fiber material.

Example 1

Experiments are conducted with other polyolefin bicomponent fibers to determine the adhesion to cellulose pulp fibers.

Cellulose fiber is NB 416 from Weyerhauser. The weight ratio of bicomponent fibers to cellulose fibers is 25:75.

The bicomponent fiber to be tested has the following composition, One fiber is according to the invention:

1: core: polypropylene; Seed: 10% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 90% LLDPE.

2. Control Samyu; Core: polypropylene; Seed: 100% LLDPE.

3. AL-Special-C from Danaklon A / S; Polypropylene Core, HDPE Seed

4. Hercules 449, Hercules 449, length 5 mm, roughness 1.5 dtex from Hercules Inc .; Polypropylene core / polyethylene seed.

The bicomponent fibers 1, 2 and 3 all had roughness of 1.7 dtex, 6 mm in length, and had a weight ratio of 35:65 between the core and the sheath.

Since the main purpose of the experiment is to determine the ability of the fibers to bind cellulose, the fibers are tested at very low speeds of 8.33 m / min in an airlay device (Dan-Web, Denmark). During the experiment, the aim is to ensure that the airlay nonwoven product has a unit mass of 80 g / m 2, and the experiment begins at the lowest adhesion temperature after the oven temperature has increased by 5 or 10 ° C.

result:

Cross direction (CD) dry strength, machine direction (MD) health and MD wet strength are described below (tested at EDANA test method No. 20.2-89, speed of 100 mm / min) It is measured on samples produced at different temperatures. Furthermore, the unit mass (g / m 2) and thickness of each sample are measured, and the information (not listed below) allows the difference in unit mass and thickness of each sample tested to show at least standardized values that can be compared. It is used to set the intensity value. The results are shown below.

Sample No. Adhesion Temperature (℃) MD strength (N / 5cm) CD strength (N / 5cm) MD Wet Strength (N / 5㎝) 11111 125130135140145 25.920.923.523.123.9 25.220.522.422.322.5 25.418.320.620.118.0 2222222 125130135140145150155 17.4613.6315.1716.2512.7711.284.15 15.4313.3215.0615.7213.0810.774.26 15.1311.6212.6613.499.786.772.23 333 130140150 24.0119.3415.59 23.3718.0816.66 23.5918.5714.42 44444 130140150160170 7.989.238.834.213.24 7.787.938.934.313.14 7.988.738.832.261.27

The results of the dust test are as follows (except for fiber No. 3, the average of experiment 2 is the range of results obtained in most of the tests tested with the fiber):

Fiber number dust (mg)

1 1.7

2 7.4

3 12-30

4 14.0

Compared with the control PP / PE fibers 2, 3 and 4, the fiber 1 according to the present invention gives a significantly improved result in the dust test, and the greatly reduced dust generation leads to the bicomponent fiber of the present invention in the cellulose fine pulp fiber. It clearly shows improved adhesion to adhesion. Observation of the sample under the microscope shows that the bicomponent fibers of the present invention adhere to the cellulose fibers. Fiber 1 provides a larger nonwoven fabric compared to fibers 2 and 3 (fiber 4 is not compared in this respect). Moreover, as indicated by the strengths given in the table above, the fibers of the present invention are nonwovens with improved strength and elongation properties.

Example 2

Testing of two different fiber capacities to bind cellulose is carried out on commercial airlay lines. An airlay nonwoven fabric having a thickness of about 1 mm and a unit weight of about 80 g / m 2 is produced. The nonwoven comprises about 25% bicomponent fibers and about 75% cellulose pulp fibers. The bicomponent fibers tested were 6 mm long and roughness 1.7 dtex. The aforementioned (control) fiber No. In addition to 3, the bicomponent fiber (referred to as No. 5) is a fiber No. With the same cellulose-binding additive as in 1, higher melting point polyethylene seed component (HDPE) is tested. The fiber has the following composition:

5: polypropylene; Seed: 10% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 90% HDPE.

Each nonwoven sample is bonded at different temperatures at a spacing of 3 ° C. to ascertain the optimum adhesion temperature for each fiber.

Nonwoven fabrics containing the bicomponent fibers of the present invention result in improved binding of cellulose fibers as evidence of reduced dust generation during processing compared to control fibers (in which case no quantitative measurements are performed). Moreover, the fibers of the present invention show a nonwoven fabric with improved strength properties as evidence by the following test results:

MD tensile strength, health (N / 5cm)

Adhesion Temperature (℃) fiber control 5 137140143146 13.9615.7712.56- 15.0819.0119.4015.41

Example 3

The test is run to account for the effect seen by varying the amount of additive (maleic acid grafted LLDPE with 5% active ingredient) in the seed component.

The bicomponent fibers tested all had a length of 6 mm and a roughness of 1.7 dtex. The core / seed weight ratio to fibers 6-9 was 35:65, and fiber no. For 10 it is 50:50. The core is in the case of all polypropylene. Nonwovens are produced on commercial airlay lines using Dan-Web technology in Denmark, which have a unit mass of about 80 g / m 2, a thickness of 1 mm and a mass ratio of bicomponent fibers to cellulose fibers of 25:75. . Samples with bicomponent fibers each were tested at three different adhesion temperatures 137, 140 and 143 ° C.

The seed composition of each fiber is as follows:

6: 5% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 95% LLDPE

7: 5% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 95% HDPE

8: 10% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 90% HDPE

9: 12.5% grafted LLDPE (5% maleic acid grafted to 95% LLDPE), 87.5% HDPE

10: 13% grafted LLDPE (5% maleic acid grafted with 95% LLDPE), 95% HDPE

As with the controls, Danaklon A / S's AL-Special-C (polypropylene core, HDPE sheath; No. 3 and above) is used.

Various nonwoven extensions and wet and dry tensile strengths are tested. As in the results shown below, the nonwoven fabric containing the fibers of the present invention exhibits improved wet and dry tensile strength compared to the control nonwoven fabric. In addition, some of the fibers of the invention, in particular No. 6, 7 and 8 represent the extension of the control fiber, while fiber 10 and slightly extended fiber 9 show lower extension than the control fiber. The suboptimal results of fibers 9 and 10 for extension are associated with some difficulty in spinning fibers with relatively large amounts of grafted components in the seed. Other process parameters and optimization of the square process and in other tests, other fibers having relatively large amounts of grafted polyolefin components and improved results for them can be obtained.

Tensile Strength, Health (N / 5cm) Adhesion Temperature (℃) control Fiber number 6 7 8 9 10 137 8.54 21.58 17.65 16.91 18.68 12.75 140 9.84 18.58 20.98 17.00 17.95 14.40 143 8.53 18.59 19.25 30.63 18.18 16.38

Elongation (%) Adhesion Temperature (℃) control Fiber number 6 7 8 9 10 137 185.25 190.25 154.50 199.67 174.25 133.50 140 175.00 184.75 188.25 195.67 169.00 119.00 143 178.67 189.25 185.78 184.25 185.75 144.75

Tensile Strength, Wet Strength (N / 5㎝) Adhesion Temperature (℃) control Fiber number 6 7 8 9 10 137 8.24 17.57 15.21 16.03 17.11 9.39 140 9.32 13.64 17 13.78 16.31 10.19 143 8.01 15.34 15.2 24.08 17.04 16.31

Elongation, wet (%) Adhesion Temperature (℃) control Fiber number 6 7 8 9 10 137 175.25 220.75 161.50 179.67 205.25 118.75 140 159.50 194.25 177.75 186.75 189.00 132.50 143 142.50 196.00 179.67 177.00 188.50 123.75

Visual evaluation of the dust properties of the nonwovens indicates that all tested bicomponent fibers of the present invention have improved adhesion to cellulose fibers as compared to control bicomponent fibers. Fibers 7 and 8 are particularly well used in production lines, as shown in the above results, and good strength values are obtained for the nonwovens containing the fibers.

The results of the fibers of this example in the dust test are as follows (fiber 10 is not tested):

Fiber number dust (mg)

6 6.6

7 14.9

8 5.8

9 6.7

Control 29.9

It can be concluded from the above good results that additives have been added at all stages, with about 5-10% addition showing better results.

Claims (46)

delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete delete The bicomponent fiber consists of (A) a high melt polyolefin component and (B) a low melt polyolefin component, The low melt polyolefin component (B) has a melting point at least 4 ° C. lower than the melting point of the (1) high melting polyolefin component, (2) constitutes at least a part of the surface of the bicomponent fiber, and (3) a grafted polyolefin. Consisting of a component and an grafted polyolefin component, And wherein said grafted polyolefin component is grafted with unsaturated dicarboxylic acid or anhydride thereof. The method of claim 23, The grafted polyolefin component of the bicomponent fiber includes maleic acid, maleic anhydride and derivatives thereof; Fumaric acid and derivatives thereof; Unsaturated derivatives of malonic acid; And a bicomponent fiber characterized in that it is grafted with a compound selected from the group consisting of unsaturated derivatives of succinic acid. The method of claim 24, The grafted polyolefin component of the bicomponent fiber may be citraconic acid, citraconic anhydride, pyrrocinconic anhydride, 3-butene-1,1-dicarboxylic acid, benzylidene malonic acid, isopropylidene malonic acid, ita A drylay nonwoven fabric consisting of bicomponent fibers, characterized in that it is grafted with a compound selected from the group consisting of cholic acid and itaconic anhydride. The method of claim 24, The grafted polyolefin component of the bicomponent fiber is a drylay nonwoven fabric consisting of a bicomponent fiber, characterized in that the grafted with maleic acid or maleic anhydride. The method of claim 23, The bicomponent fiber is a dry-lay nonwoven fabric consisting of a bicomponent fiber, characterized in that the low-melting polyolefin component is composed of a seed, the high-melting polyolefin component is a sheath-core fiber composed of a core. The method of claim 23, A drylay nonwoven made of bicomponent fibers, further comprising at least one additional fiber material. The method of claim 28, And said additional fiber material is selected from the group consisting of cellulose fibers, viscose fibers and lyocell fibers. The method of claim 28, And said additional fibrous material comprises cellulose fine hair pulp fibers. The method of claim 23, Wherein said high melt polyolefin component comprises polypropylene and said low melt polyolefin component comprises at least one polyolefin selected from LLDPE, HDPE and LDPE. The method of claim 23, And a melting point difference between the low melt component and the high melt component of the bicomponent fiber is at least about 20 ° C. 2. The method of claim 23, The high melt polyolefin component comprises a first polypropylene and the low melt polyolefin component comprises a second polypropylene or a polypropylene copolymer having a melting point at least 5 ° C. lower than the first polypropylene. Dry ray nonwoven fabric. The web consists of a bicomponent fiber composed of (A) a high melt polyolefin component and (B) a low melt polyolefin component, The low melt polyolefin component (B) has a melting point at least 4 ° C. lower than the melting point of the (1) high melting polyolefin component, (2) constitutes at least a part of the surface of the bicomponent fiber, and (3) a grafted polyolefin. Consisting of a component and an grafted polyolefin component, The grafted polyolefin component is grafted with unsaturated dicarboxylic acid or anhydride thereof, A drylay nonwoven fabric manufacturing method comprising the steps of forming a fibrous web using a drylay nonwoven machine and combining the fibrous webs to produce a drylay nonwoven fabric. The method of claim 34, wherein And wherein said fibrous web further comprises at least one additional fibrous material. 36. The method of claim 35 wherein Wherein said additional fiber material is selected from the group consisting of cellulose fibers, viscose fibers and lyocell fibers. 36. The method of claim 35 wherein And wherein said additional fiber material comprises cellulose fine haired pulp fibers. The method of claim 34, wherein The grafted polyolefin component of the bicomponent fiber includes maleic acid, maleic anhydride and derivatives thereof; Fumaric acid and its derivatives; Unsaturated derivatives of malonic acid; And a grafted compound selected from the group consisting of unsaturated derivatives of succinic acid. The method of claim 38, The grafted polyolefin component of the bicomponent fiber may be citraconic acid, citraconic anhydride, pyrrocinconic anhydride, 3-butene-1,1-dicarboxylic acid, benzylidene malonic acid, isopropylidene malonic acid, ita A method for producing a drylay nonwoven fabric, comprising: The method of claim 38, The grafted polyolefin component of the bicomponent fiber is grafted with maleic acid or maleic anhydride. The method of claim 34, wherein The bicomponent fiber is a method for producing a drylay nonwoven fabric, characterized in that the low-melting polyolefin component is composed of a seed, and the high-melting polyolefin component is a sheath-core fiber composed of a core. The method of claim 34, wherein Wherein said high melt polyolefin component comprises polypropylene and said low melt polyolefin component comprises at least one polyolefin selected from LLDPE, HDPE and LDPE. The method of claim 34, wherein And a melting point difference between the low melt component and the high melt component of the bicomponent fiber is at least about 20 ° C. The method of claim 34, wherein Wherein the high melt polyolefin component comprises a first polypropylene and the low melt polyolefin component comprises a second polypropylene or polypropylene copolymer having a melting point at least about 5 ° C. lower than the first polypropylene. Nonwoven Fabric Manufacturing Method. (A) a high melt polyolefin component and (B) a low melt polyolefin component, The low melt polyolefin component (B) has a melting point at least 4 ° C. lower than the melting point of the (1) high melting polyolefin component, (2) constitutes at least a part of the surface of the bicomponent fiber, and (3) a grafted polyolefin. Consisting of a component and an grafted polyolefin component, And said grafted polyolefin component is grafted with unsaturated dicarboxylic acid or anhydride thereof. The bicomponent fiber consists of (A) a high melt polyolefin component and (B) a low melt polyolefin component, The low melt polyolefin component (B) has a melting point at least 4 ° C. lower than the melting point of the (1) high melting polyolefin component, and (2) constitutes at least part of the surface of the bicomponent fiber, The bicomponent fibers have a binding affinity to natural or regenerated fibers, and the nonwoven fabric is a drylay nonwoven fabric composed of a bicomponent synthetic fiber and a natural or regenerated fibrous material, characterized by a dust value of less than about 10 mg in a standard dust test. .