KR100397606B1 - Wastewater treatment process and method using the Inorganic-coagulant and Bio-filter - Google Patents

Wastewater treatment process and method using the Inorganic-coagulant and Bio-filter Download PDF

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KR100397606B1
KR100397606B1 KR10-2001-0080323A KR20010080323A KR100397606B1 KR 100397606 B1 KR100397606 B1 KR 100397606B1 KR 20010080323 A KR20010080323 A KR 20010080323A KR 100397606 B1 KR100397606 B1 KR 100397606B1
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biofilm filtration
filtration tank
water
treated
tank
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KR20020023777A (en
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변규금
황용우
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주식회사 화인프로텍
황용우
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/06Aerobic processes using submerged filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

본 발명은 무기응집제와 생물막 여과조를 이용한 수처리 방법 및 장치에 관한 것으로서, 처리대상수(100)의 인과 질소 및 잔류 유기물을 제거하기 위한 공정이다. 공정의 구성은 처리대상수(100) 유입, 황탈질 생물막 여과조(102), 호기성 생물막 여과조(103), 처리수조(104)로 구성되어 있으며, 무기응집제(101)를 호기성 생물막 여과조(103)의 유입부에 투입하는 방법과 무기응집제(101)를 황탈질 생물막 반응조(102) 유입부에 투입하는 방법으로 구분되어진다. 기존 인 제거를 위한 처리공정은 무기응집제와 고분자응집제를 주입하여 급속 및 완속교반 후 침전장치를 통하여 고액분리하는 반면, 본 발명에서는 무기응집제만을 이용하여 인을 효과적으로 제어할 수 있는 시스템이다. 생물막 여과조(102,103)에 의해 포착된 인은 역세척을 통해 전처리설비로 이송된다. 생물막 여과조를 거친 처리수는 처리수조(104)에 일시저장 후 방류(105)된다. 상기공정은 인과 질소 및 탁도 그리고 잔류 유기물을 제거하는 고도처리공정으로 중수도 용도로의 이용이 가능하다.The present invention relates to a water treatment method and apparatus using an inorganic coagulant and a biofilm filtration tank, and is a process for removing phosphorus, nitrogen, and residual organic matter in the water to be treated (100). The configuration of the process is composed of the inflow of the object water 100, the denitrification biofilm filtration tank 102, the aerobic biofilm filtration tank 103, the treatment water tank 104, the inorganic coagulant 101 of the aerobic biofilm filtration tank 103 It is divided into a method of injecting into the inlet and a method of injecting the inorganic coagulant 101 into the inlet to the denitrification biofilm reactor (102). The conventional process for removing phosphorus is to inject the inorganic coagulant and the polymer coagulant into solid-liquid separation through the precipitation device after rapid and slow stirring. Phosphorus captured by the biofilm filtration tanks 102 and 103 is transferred to the pretreatment facility through backwashing. The treated water that has undergone the biofilm filtration tank is discharged 105 after being temporarily stored in the treated water tank 104. The process is a highly advanced process to remove phosphorus, nitrogen, turbidity and residual organics can be used for heavy water applications.

Description

무기응집제와 생물막 여과조를 이용한 수처리 방법 및 장치{Wastewater treatment process and method using the Inorganic-coagulant and Bio-filter}Wastewater treatment process and method using the Inorganic-coagulant and Bio-filter}

본 발명은 무기응집제와 생물막 여과조를 이용한 수처리 방법 및 장치에 관한 것이다. 본 발명은 생물막 여과공법(Bio-filter) 시스템의 일부를 이용한 것으로 본 발명의 선행특허인 제030468호에 상세히 나타내었으며, 본 발명의 선행특허인 공개번호 10-1999-0068787호에서는 응침침전 및 생물막 여과조(Bio-filter)에 대해 나타내었다. 또한, 공개번호 10-2001-0026410호에서는 응집침전장치가 있어 고 · 액분리하여 인을 제거한 후 상향류식 황탈질 반응조에서 질소를 제거하는 기술에 대해 언급하였으며, 단일 반응조에서 질산화 및 탈질을 수행한다고 서술하였다. 하지만 처리형태로 보아 상향류식의 경우 미세화된 황입자가 유출되어 화학적산소요구량(COD) 및 부유물질(SS)를 증가시킬 수 있다. 또한, 상향류식 단일반응조에서 질산화 영역과 탈질영역이 구분되어 역세척이 어려울 것으로 판단된다. 화학적 처리를 통한 인 제거시 고분자응집제를 투입하고 완속교반조와 침전조를 사용함으로써 인제거 효율을 높일 수 있으나 약품비 및 동력비가 증가되는 단점이 있다. 일본특허공개 평6-182393호의 경우 상향류의 무산소조건에서 황입자를 유동상으로 하여 질소를 제거한다고 기술하였으며 미세한 황입자의 유출을 방지하기 위해 내부반송을 하였다. 황반응조 내의 용존산소(DO)가 높을 경우 탈질미생물의 활동이 저하되어 질소 제거효율이 저하된다고 기술하였다. 또한, 공개번호 2001-00055891호의 경우 최종침전지의 후단에 황탈질 반응조를 설치하여 질소를 제거하지만 잔류 유기물과 탁도를 제거할 수 없고 황탈질 반응조 운전상 문제가 발생되었을 때 황탈질 반응조내에서 미생물이 탈리될 경우 응급조치를 취할 수 없다.The present invention relates to a water treatment method and apparatus using an inorganic coagulant and a biofilm filtration tank. The present invention is shown in detail in the prior art No. 030468, which uses a part of the bio-filter system (Bio-filter) system, and in the prior patent publication No. 10-1999-0068787 of the present invention, Bio-filter was shown. In addition, Korean Patent Publication No. 10-2001-0026410 describes a technique for removing nitrogen from an upflow desulfurization reactor after removing phosphorus by solid and liquid separation due to a flocculation settling device, and performing nitrification and denitrification in a single reactor. Described. However, in the form of treatment, in the upflow type, finely divided sulfur particles may leak and increase the chemical oxygen demand (COD) and the suspended solids (SS). In addition, it is difficult to backwash as the nitrification zone and the denitrification zone are separated in the upflow single reactor. Phosphorus removal through chemical treatment can increase phosphorus removal efficiency by adding a polymer coagulant and using a slow stirring tank and a precipitation tank. Japanese Patent Application Laid-open No. Hei 6-182393 describes the removal of nitrogen by using sulfur particles as a fluidized bed under anoxic conditions in an upstream flow, and internal transport was performed to prevent the fine sulfur particles from leaking out. The high dissolved oxygen (DO) in the sulfur reactor is described as the denitrification microorganism activity is reduced, the nitrogen removal efficiency is described. In addition, in the case of Publication No. 2001-00055891, a denitrification reactor is installed at the rear of the final settler to remove nitrogen, but residual organic matter and turbidity cannot be removed. You cannot take first aid if you leave.

따라서, 본 발명은 종래의 기술을 개선하기 위해 호기성 생물막 여과조(103)또는 황탈질 생물막 여과조(102)의 유입부에 알루미늄염, 철염 등과 같은 무기응집제(101)만을 투입하여 생물학적 여과에 의해 포착된 인을 제거하는데 주안점을 두었다. 특히 기존의 무기응집제(101)와 고분자응집제를 주입하여 급속교반과 완속교반 및 침전장치를 사용하는 방법과 달리 무기응집제(101)만을 이용하여 인을 제거하고자 한다. 결과적으로 고분자응집제를 투입하지 않음으로써 약품비를 절감할 수 있고, 완속교반조와 침전조를 사용하지 않기 때문에 동력비 및 소요부지를 절감할 수 있다. 또한 황탈질 미생물 여과조(102)의 후단에 호기성 생물막 여과조(103)를설치함으로써 미세한 황입자의 유출에 따른 처리수질 악화를 방지하고 안정적인 처리수질을 유지하고자 한다. 생물막 여과조(Bio-filter)의 특징은 충진된 여재에 미생물이 부착되어 생물막을 형성함으로서 미생물 서식 공간이 확대되어 고농도의 미생물 농도를 유지할 수 있다. 결과적으로 부유성장식 즉, 활성슬러지법 등에 비해 처리시간이 단축되며, 안정적이고 깨끗한 처리수질을 만들 수 있는 특징이 있다. 따라서, 본 발명은 앞서 언급한 선행특허공정을 한층 개선시킨 공정이다.Therefore, in order to improve the conventional technology, the present invention is introduced only into the inorganic coagulant 101 such as aluminum salt, iron salt, etc. at the inlet of the aerobic biofilm filtration tank 103 or the denitrification biofilm filtration tank 102 to be captured by biological filtration. The emphasis was on removing phosphorus. In particular, unlike the method of using a rapid stirring, slow stirring and precipitation device by injecting the conventional inorganic coagulant (101) and polymer coagulant to remove the phosphorus using only the inorganic coagulant (101). As a result, the chemical cost can be reduced by not adding the polymer coagulant, and the power cost and the required site can be reduced because the slow stirring tank and the sedimentation tank are not used. In addition, by installing the aerobic biofilm filtration tank 103 at the rear end of the denitrifying microorganism filtration tank 102 to prevent the deterioration of the treated water quality due to the outflow of fine sulfur particles and to maintain a stable treated water quality. The characteristic of the bio-filter is that the microorganisms are attached to the filled media to form a biofilm, thereby expanding the microbial habitat space and maintaining a high concentration of microorganisms. As a result, the treatment time is shortened compared to the floating growth type, that is, activated sludge method, and has the characteristics of making stable and clean treated water quality. Therefore, this invention is the process which improved further the above-mentioned prior patent process.

도1은 본 발명에서 사용된 반응조의 수처리 계통도이다.1 is a water treatment system diagram of a reactor used in the present invention.

<부호의 설명><Description of the code>

100: 처리 대상수, 101: 무기응집제, 102: 황탈질 생물막 여과조,100: water to be treated, 101: inorganic coagulant, 102: denitrifying biofilm filtration tank,

103: 호기성 생물막 여과조, 104: 처리수조, 105: 방류, 106: 역세척배수103: aerobic biofilm filtration tank, 104: treatment tank, 105: discharge, 106: backwash drainage

상기 기술한 목적을 달성하기 위해 도 1과 연계하여 설명하면, 처리대상수(100)에 무기응집제(101)를 호기성 생물막 여과조(103)에 투입하거나 또는 무기응집제(101)를 황탈질 생물막 여과조(102) 유입부에 투입하여 인을 포착하고 하향류식 고정상 황탈질 생물막 여과조(102)에서 질소를 제거하며 호기성 생물막 여과조(103)에서 잔류 유기물과 탁도를 제거시킨 후 처리수조(104)에 일시 저장 후 방류(105)한다. 이때 황탈질 생물막 여과조(102)에는 질소제거를 위한 탄산나트륨 등의 알카리제가 공급되어질 수 있다. 또한, 미세 플럭(floc)의 누적 및 미생물의 성장에 따른 여과저항이 발생되었을 때는 황탈질 생물막 여과조(102) 및 호기성 생물막 여과조(103)를 공기(A)와 처리수로 역세척한 후 역세척배수(106)는 전처리설비(침전지, 유입수조 등)로 이송된다. 호기성 생물막 여과조(103)는 황탈질 생물막 여과조에 독성등으로 인한 외부적 충격으로 미생물이 탈리되었을때 안전판 역할을 수행하여 안정적인 수질을 유지할 수 있다. 본 발명은 생물막 여과조(102,103)를 이용하기 때문에 완속교반조 및 침전조가 없는 시스템이다.In order to achieve the above-described purpose, in connection with FIG. 1, the inorganic coagulant 101 may be introduced into the aerobic biofilm filtration tank 103 or the inorganic coagulant 101 may be desulfurized biofilm filtration tank. 102) After entering the inlet to capture the phosphorus to remove nitrogen from the downflow fixed bed desulfurization biofilm filtration tank 102, remove the residual organic matter and turbidity in the aerobic biofilm filtration tank 103, and then temporarily stored in the treatment tank (104) Discharge 105. At this time, the denitrification biofilm filtration tank 102 may be supplied with an alkaline agent such as sodium carbonate for nitrogen removal. In addition, when filtration resistance is generated due to accumulation of fine flocs and microorganism growth, backwashing is performed after backwashing the denitrifying biofilm filtration tank 102 and the aerobic biofilm filtration tank 103 with air (A) and treated water. Drainage 106 is transferred to a pretreatment facility (precipitator, inflow water tank, etc.). The aerobic biofilm filtration tank 103 may maintain a stable water quality by performing a role of a safety plate when microorganisms are detached due to an external impact due to toxicity to the denitrifying biofilm filtration tank. The present invention is a system without a slow stirring tank and a settling tank because the biofilm filtration tanks 102 and 103 are used.

본 발명은 처리대상수(100)의 인과 질소 및 탁도 그리고 잔류 유기물을 제거하므로 처리수를 다양한 분야에 이용할 수 있다. 또한, 생물막 여과조(Bio-filter)를 이용함으로서 인제거를 위해 완속교반조와 침전장치가 필요없어 시스템을 간단히 할수 있다. 본 발명으로 처리된 처리수는 공업용수, 조경용수, 화장실 용수등 중수도용으로 이용이 가능하며, 아울러 도시의 개발로 인해 건천화된 하천에 물고기와 수생식물이 서식할 수 있는 깨끗한 처리수를 공급함으로써 친환경적인 생태공간을 조성하는 데에 이바지 할 것이다.The present invention removes phosphorus, nitrogen, turbidity and residual organics of the water 100 to be treated, so that the treated water can be used in various fields. In addition, by using a bio-filter, the system can be simplified by eliminating the need for a slow stirring tank and a precipitation device for phosphorus removal. The treated water treated with the present invention can be used for heavy water such as industrial water, landscaping water, toilet water, and also by supplying clean treated water that can inhabit fish and aquatic plants to dry streams due to urban development. It will contribute to the creation of environment-friendly ecological space.

Claims (3)

처리대상수가 유입되어 질산성 질소가 제거되는 황탈질 생물막 여과조(102)와 상기 황탈질 생물막 여과조의 후단에 연결되어 잔류 유기물 및 탁도를 제거시켜 방류시키는 친수성 여재가 충진된 호기성 생물막 여과조(103)로 구성되고, 상기 황탈질 생물막 여과조 또는 상기 호기성 생물막 여과조에 무기응집제를 투입할 수 있도록 유입부가 구비된 것을 특징으로 하는 수처리 장치To the aerobic biofilm filtration tank (103) filled with a denitrified biofilm filtration tank (102) in which the treated water is introduced to remove nitrate nitrogen, and a hydrophilic filter medium which is discharged by removing residual organic matter and turbidity connected to the rear end of the denitrification biofilm filtration tank. It is configured, the water treatment device characterized in that the inlet is provided so that the inorganic coagulant to the desulfurization biofilm filtration tank or the aerobic biofilm filtration tank 질산성 질소와 인 성분을 다량 함유한 처리 대상수의 수처리 방법에 있어서, 유입 처리대상수만을 황탈질 생물막 여과조에 유입시키거나, 또는 상기 유입 처리대상수에 무기응집제를 교반과 함께 투입하여 황탈질 생물막 여과조에 유입시켜 질산성 질소를 제거하고, 이어서, 처리수만을 호기성 생물막 여과조에 유입시키거나, 또는 상기 처리수에 무기응집제를 교반과 함께 투입하여 호기성 생물막 여과조에 유입시켜 잔류 유기물 및 탁도를 제거시킨 후, 방류시키는 것을 특징으로 하는 수처리 방법In the water treatment method of the water to be treated containing a large amount of nitrate nitrogen and phosphorus, only the water to be treated is introduced into the denitrification biofilm filtration tank, or the inorganic coagulant is added to the water to be treated with stirring to denitrate. Nitrate nitrogen is removed by entering the biofilm filtration tank, and then only the treated water is introduced into the aerobic biofilm filtration tank, or the inorganic coagulant is added to the treated water with agitation and introduced into the aerobic biofilm filtration tank to remove residual organic matter and turbidity. And then discharged. 삭제delete
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KR960013338B1 (en) * 1991-07-12 1996-10-04 타쯔오 시미즈 Waste water treatment apparatus and method
JPH08318292A (en) * 1995-05-26 1996-12-03 Tsukishima Kikai Co Ltd Waste water treatment method and apparatus
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KR960013338A (en) * 1994-10-14 1996-05-22 모리시다 요이치 hearing aid
JPH08318292A (en) * 1995-05-26 1996-12-03 Tsukishima Kikai Co Ltd Waste water treatment method and apparatus
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