KR20000019492A - Method for managing high concentrated wastewater - Google Patents
Method for managing high concentrated wastewater Download PDFInfo
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- KR20000019492A KR20000019492A KR1019980037614A KR19980037614A KR20000019492A KR 20000019492 A KR20000019492 A KR 20000019492A KR 1019980037614 A KR1019980037614 A KR 1019980037614A KR 19980037614 A KR19980037614 A KR 19980037614A KR 20000019492 A KR20000019492 A KR 20000019492A
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- 239000002351 wastewater Substances 0.000 title abstract description 14
- 238000000034 method Methods 0.000 title abstract description 12
- 239000012528 membrane Substances 0.000 claims abstract description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000005273 aeration Methods 0.000 claims abstract description 28
- 238000000926 separation method Methods 0.000 claims abstract description 24
- 239000010865 sewage Substances 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000001556 precipitation Methods 0.000 claims abstract 2
- 238000001471 micro-filtration Methods 0.000 claims description 40
- 238000004065 wastewater treatment Methods 0.000 claims description 19
- 238000000967 suction filtration Methods 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000009434 installation Methods 0.000 claims description 5
- 238000005374 membrane filtration Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 210000002445 nipple Anatomy 0.000 claims description 2
- 230000002265 prevention Effects 0.000 claims 1
- 239000010802 sludge Substances 0.000 abstract description 20
- 238000001914 filtration Methods 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 11
- 244000005700 microbiome Species 0.000 abstract description 9
- 238000003860 storage Methods 0.000 abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 238000009833 condensation Methods 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000004062 sedimentation Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 238000005345 coagulation Methods 0.000 description 5
- 230000015271 coagulation Effects 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229910017464 nitrogen compound Inorganic materials 0.000 description 4
- 150000002830 nitrogen compounds Chemical class 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000011001 backwashing Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical class [N].N CVTZKFWZDBJAHE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000001467 acupuncture Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- -1 on the other hand Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/14—Activated sludge processes using surface aeration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/308—Biological phosphorus removal
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
본 발명은 고농도 유기성 하.페수 고도처리 장치에 관한 것으로 연속 이중으로 직렬 구성된 무산소조와 폭기조를 비롯하여,전기분해 응집기와 특히,정밀여과 분리막의 적용으로 하.폐수내 고부하 유기물 및 질소.인 등 영양염류 처리효율을 대폭 향상시키고, 소요부지와 유지관리비를 저감시킬 수 있는 고농도 유기성 하.폐수 고도처리 장치이다.The present invention relates to a high concentration organic organic wastewater treatment apparatus, including an anoxic tank and an aeration tank, which are serially configured in series, and an electrolytic flocculator and, in particular, a high-load organic substance and nitrogen, phosphorus, etc. in wastewater. It is a high concentration organic sewage and wastewater treatment system that can greatly improve treatment efficiency and reduce required site and maintenance cost.
일반적으로 종래의 유기성 하.폐수처리로는 생물학적 처리가 유효한 것으로 알려져 있으며,특히 활성오니법이 가장 보편적인 방법으로 광범위하게 사용되고 있다.Generally, biological treatment is known to be effective as a conventional organic sewage and wastewater treatment, and in particular, the activated sludge method is widely used as the most common method.
그러나,이러한 활성오니 공법에서는 처리수와 미생물 슬러지의 고액분리가 침전조에서의 중력침강으로 이뤄지고 있으므로 폐수량,유입부하 변동 및 독성물질의 유입 등에 의한 충격부하 현상에 의해 침전조에서의 오니팽화 및 월류가 불시에 발생되어 처리수질을 불량하게 할 뿐만 아니라, 이에 따른 숙련된 관리 기술이 절대적으로 필요함은 물론, 항상 불안정한 처리가 지속되고 있으며,특히 호소나 강.바다 등 부영양화의 주범이 되고 있는 질소.인과 같은 영양염류의 고도처리는 거의 기대하기 힘든 실정이다.However, in this active sludge process, solid-liquid separation of treated water and microbial sludge is caused by gravity sedimentation in the sedimentation tank, so sludge swelling and overflow in the sedimentation tank are inadvertently caused by impact load phenomena due to waste water volume, inflow load fluctuations, and inflow of toxic substances. Not only impairs the quality of the treated water, but also necessitates skilled management skills, but also maintains unstable treatment all the time, especially nitrogen and phosphorus, which are the main culprit of eutrophication such as lakes, rivers and the sea. Advanced treatment of nutrients is rarely expected.
본 발명은 상기한 바와 같은 종래기술의 결점 및 문제점을 해결하기 위하여 창안한 것으로 하.폐수내 유기물 처리는 물론 질소.인의 영양염류까지 동시에 고도처리하기 위하여 무산소조와 폭기조를 이중 연속으로 구성하여 공간적 처리효율을 향상시킬 수 있도록 직렬로 보완하고,또한 잔류하는 영양염류와 난분해성 오염물질은 전기분해 응집기를 통해 해결할 수 있도록 하였으며,특히,고액분리용 친수성 정밀 여과 분리막을 이용하므로서 후단 폭기조내 슬러지와 전기분해 응집 부산물의 완벽한 고액 분리가 이뤄질 수 있도록 하여 종래의 기술로는 불가능했던 고농도 유기성 하.폐수의 고효율 처리는 물론, 동시에 탁월한 경제성과 간편한 관리가 가능한 처리장치를 제공하기 위한 것이다.The present invention was devised to solve the drawbacks and problems of the prior art as described above. In order to simultaneously process the organic matter in the wastewater as well as the nutrients of nitrogen and phosphorus at the same time, the anoxic tank and the aeration tank are constituted in a double continuous process to perform spatial treatment. In order to improve efficiency, it is complemented in series, and residual nutrients and hardly degradable contaminants can be solved by electrolytic agglomerator. Especially, it uses sludge and electricity in the rear aeration tank by using hydrophilic microfiltration membrane for solid-liquid separation. It is to provide a high-performance treatment of high concentration organic sewage and wastewater, as well as excellent economic efficiency and simple management, which can be achieved by completely solid-liquid separation of decomposed flocculation by-products.
종래 하.폐수내 유기물질과 질소화합물 등을 제거하기 위해 보통 1단으로 구성되는 무산 소조와 폭기조 시설을 처리 효율의 향상과 1차 시설의 공간적 한계를 보완할 수 있도록 2단 연속직렬로 구성하고, 오염물 처리의 주요 핵심인 미생물 보유량을 종래 활성오니공법의 약 3∼5배가 높은 10,000PPM ∼ 15,000PPM정도의 고농도로 증대 시키기 위해서 후단 폭기조내에 친수성 정밀여과 분리막을 침지하여 구성된다.In order to remove organic substances and nitrogen compounds in the wastewater, the anoxic acid tank and aeration tank facilities, which are usually composed of one stage, are composed of two consecutive series to improve treatment efficiency and complement the space limitation of the primary facilities. In order to increase the concentration of microorganisms, which are the core of pollutant treatment, to a high concentration of 10,000PPM to 15,000PPM, which is about 3 to 5 times higher than the conventional activated sludge process, hydrophilic microfiltration membranes are immersed in the rear aeration tank.
통상, 활성오니 하.폐수처리 설비의 침전분리조의 역할은 고액분리이기 때문에 막분리기술을 적용하게 되므로서 침전분리조는 불필요하게 된다.In general, since the role of the sedimentation tank of the activated sludge wastewater treatment plant is solid-liquid separation, the sedimentation tank is unnecessary because the membrane separation technique is applied.
일반적으로 정밀여과 분리막은 내압용기속에 막 엘레멘트(ELEMENT)를 설치해서 가압식으로 여과처리를 하게 되지만 폭기조내 활성오니와 같이 미생물등 SS성분이 많은 것을 가압용기내에서 가압여과를 하면 퇴적물에 의한 막간,막면에서의 막힘현상이 급속히 진행되어 여과를 안정적으로 장시간 실시할 수 없다.In general, the microfiltration membrane is pressurized by installing a membrane element in the pressure vessel, but when the membrane is filtered with a large amount of SS such as microorganisms such as activated sludge in the aeration tank in the pressurized vessel, Blockage at the membrane surface proceeds rapidly and filtration cannot be performed stably for a long time.
이때문에 종래에는 활성오니나 하천수의 여과 등,탁질성분이 높은 원수의 고액분리에서 막분리는 불가능하다고 되어 있으나,본 발명에 적용한 정밀여과분리막을 후단폭기 조내에 구성하므로서 활성오니조내 현탁물질의 99.7%이상을 제거할 수 있으므로 매우 투명도가 높은 처리수를 얻을 수 있을 뿐만 아니라,후단 연계처리 시설의 처리능력을 극대화 시킬 수 있고, 활성오니조내 고농도의 미생물 보유능력으로 인해 고도처리효율을 획기적으로 상승시키는 등 다중의 효과를 얻을 수 있다.For this reason, although membrane separation is impossible in the solid-liquid separation of raw water having a high solute component, such as filtration of activated sludge or river water, it is possible to form a fine filtration membrane according to the present invention in a rear aeration tank, and thus, As it can remove more than 99.7%, it is possible not only to obtain highly transparent treatment water, but also to maximize the processing capacity of the downstream linkage treatment facility, and dramatically increase the high treatment efficiency due to the high concentration of microorganisms in the activated sludge tank. Multiple effects can be obtained, such as raising.
그리고 본 발명은 무산소조 및 폭기조를 1차,2차로 연속 구성하므로서 국한된 공간적, 시간적 제한에 의한 처리효율 저하를 방지하고, 각 조내 탈질균과 질화균 등 각종 미생물을 고농도로 유지할 수 있기 때문에 기존시설 대비 약 50%이하의 적은 부지내에서도 단위 시간당 처리 효율 향상은 물론, 오염 부하율의 변동에 관계없이 항상 안정적 처리가 보장되는 장점이 있으며, 생물학적 처리 한계로 잔류되는 난분해성 물질과 인화합물 등은 추가로 물리.화학적 처리로서 화학적 산화분해와 응집반응을 동시에 수행할 수 있는 전기분해 응집기로 후단 처리하여 최종적으로 응집 현탁물과 처리수는 침지식 친수성 정밀 여과 분리막을 재구성하여 여과 방류하기 때문에 고농도의 유기성 하.폐수내 각종 오염물질들의 연속적이고도 완벽한 고도처리를 기대할 수 있을 뿐만 아니라,경제적으로 유리하고 매우 관리가 용이한 획기적인 장치이다.In addition, the present invention consists of an anoxic tank and an aeration tank in a series of primary and secondary to prevent treatment efficiency degradation due to limited spatial and temporal limitations, and to maintain various concentrations of microorganisms such as denitrifying bacteria and nitrifying bacteria in each tank, and thus, compared to existing facilities. It has the advantage of improving the treatment efficiency per unit time even at less than 50% of sites, and ensuring stable treatment at all times regardless of the change in pollution load rate. As a chemical treatment, it is subjected to a post-treatment with an electrolytic coagulant that can simultaneously perform chemical oxidation and coagulation reactions. Expect continuous and complete advanced treatment of various pollutants in wastewater Not only can this be a breakthrough device that is economically advantageous and very easy to manage.
도 1 내지 도 5은 본 발명 장치에 관한 도면으로서,1 to 5 are views of the device of the present invention,
도 1은 본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치의 평면도.1 is a plan view of a high concentration organic wastewater wastewater treatment apparatus according to the present invention.
도 2a,2b는 본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치의 종단면도.Figure 2a, 2b is a longitudinal sectional view of a high concentration organic sewage wastewater treatment apparatus according to the present invention.
도 3는 정밀 여과 분리막 유니트의 평면도.3 is a plan view of the microfiltration membrane unit.
도 4는 정밀 여과 분리막 유니트의 정면도.4 is a front view of the microfiltration membrane unit.
도 5는 정밀 여과 분리막 유니트의 부분 측면도 및 종단면도.5 is a partial side view and a longitudinal sectional view of a microfiltration separator unit;
〈도면의 주요부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>
5 : 제1무산소조 6 : 폭기조5: first anaerobic tank 6: aeration tank
7 : 제2무산소조 8 : 분리막 폭기조7: second anoxic tank 8: membrane aeration tank
9 : 분리막 여과조 12 : 슬러지 저류조9: Separation membrane filtration tank 12: Sludge storage tank
20 : 미세 스크린 40,70 : 정밀여과 분리막 유니트20: fine screen 40, 70: microfiltration membrane unit
44 : 정밀여과 중공사 분리막 48 : 분리막 세정 산기관44: microfiltration hollow fiber membrane 48: membrane cleaning diffuser
50,80 : 흡인 여과펌프 60 : 전기분해 응집기50,80: suction filtration pump 60: electrolytic flocculator
90 : 블로워 92 : 산기장치90: blower 92: diffuser
110 : 분리막 역세탱크 130 : 수중 교반장치110: membrane backwash tank 130: underwater stirring device
140 : 순환펌프 150 : 원수 이송펌프140: circulation pump 150: feed water pump
이하,이와 같은 본 발명을 첨부한 도면 도 1 내지 도 5에 의하여 실시예를 자세히 설명하면 다음과 같다.Hereinafter, the embodiment will be described in detail with reference to the accompanying drawings of the present invention 1 to 5 as follows.
도 1은 본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치의 평면도를 보인 것이고, 도 2a,2b는 본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치의 종단면도, 도 3는 정밀 여과 분리막 유니트의 평면도, 도 4는 정밀 여과 분리막 유니트의 정면도, 도 5는 정밀 여과 분리막 유니트의 부분 측면도 및 종단면도를 각각 보인것으로 먼저,도 1과 도2를 참조하면,유입 침사조(1),원수저장조(2),반응조(3),응집조(4),제 1무산소조(5),폭기조(6),제 2무산소조(7),분리막폭기조(8),분리막 여과조(9),소독조(10),방류조(11)와 발생 슬러지를 저장하는 슬러지 저장조(12)로 구성 배치되고,본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치는 통상의 하.폐수처리 장치에서 처리효율을 극대화 시키기 위하여 제 1무산소조(5)와 제 2무산소조(7)의 이중 연속 직렬구성과 함께 침전분리조 대용으로 분리막 폭기조(8)내 활성오니 고액분리와 분리막 여과조(9)내 전기분해 응집기(60)를 거쳐 형성된 응집 현탁 물질의 고액분리용으로 친수성 정밀여과 분리막 유니트(40,70)을 적용한 것으로 주요 특징으로 하고 있다.1 is a plan view of a high concentration organic sewage wastewater treatment apparatus according to the present invention, Figure 2a, 2b is a longitudinal sectional view of a high concentration organic sewage wastewater treatment apparatus according to the present invention, Figure 3 is a microfiltration membrane unit 4 is a front view of the microfiltration membrane unit, and FIG. 5 is a partial side view and a longitudinal cross-sectional view of the microfiltration membrane unit, respectively. Referring to FIGS. 1 and 2, the inlet sedimentation tank 1 and the raw water storage tank are shown in FIG. (2), reaction tank (3), aggregation tank (4), first anoxic tank (5), aeration tank (6), second anoxic tank (7), membrane aeration tank (8), membrane filtration tank (9), disinfection tank (10) It is composed of a discharge tank 11 and a sludge storage tank 12 for storing the generated sludge, the high concentration organic wastewater wastewater treatment apparatus according to the present invention is made in order to maximize the treatment efficiency in a conventional wastewater treatment apparatus. Acupuncture with dual continuous series configuration of one anoxic tank (5) and a second anoxic tank (7) A hydrophilic microfiltration membrane unit (40, 70) is used for solid-liquid separation of the activated sludge solids in the membrane aeration tank (8) as a substitute for the separation tank and for the solid-liquid separation of the flocculated suspension material formed through the electrolytic agglomerator (60) in the membrane filtration tank (9). It is an important feature.
우선, 본 발명에 의한 고농도 유기성 하.폐수 고도처리 장치의 순차적 처리구성과 작용을 보면,본 처리장치에 유입되는 원수는 유입 침사조(1)내 조목 스크린(120)을 통과하면서 처리 시설물들을 보호하기 위하여 원수내 모래,협잡물 등이 제거된 후, 원수 저장조(2)로 저장되어 분리막 폭기조(8)의 수위 레벨에 따라 자동으로 원수 이송펌프(150)를 통해 반응조(3) 및 응집조(4)를 거쳐 유입 원수의 부유 고형물을 최대한 분리제거하기 위해 미세스크린(20)을 거치게 된다.First, the sequential treatment configuration and operation of the high concentration organic sewage and wastewater treatment apparatus according to the present invention protects the treatment facilities while passing the crude water screen 120 in the inlet sedimentation tank 1. In order to remove the sand, contaminants, etc. in the raw water, and stored in the raw water storage tank (2) to automatically react according to the water level of the membrane aeration tank (8) through the raw water transfer pump 150 and the reaction tank (3) and coagulation tank (4) Pass through the fine screen 20 to separate and remove the suspended solids of the incoming raw water as possible.
이러한 일련의 전처리 이후 원수내에는 유기성 오염물질과 질소 및 인화합물 등의 수용성 오염물질들이 남게 되는데 이 오염물질중 특히 유기성물질과 질소화합물을 제거하기 위해서는 탈질반응이 일어나는 무산소조건과 질산화 반응이 일어나는 호기성조건이 필요하기 때문에 보다 더욱 처리효율을 향상시키기 위해서 이 두 조건을 이중연속 직렬로 구성,즉 제 1무산소조(5),폭기조(6),제 2무산소조(7), 분리막 폭기조(8)의 순으로 순차적 배열로 설치된다.After such a series of pretreatments, organic contaminants and water-soluble contaminants such as nitrogen and phosphorus compounds remain in the raw water. Among these contaminants, in particular, to remove organic substances and nitrogen compounds, anoxic conditions under which denitrification reactions and nitrification reactions occur. In order to further improve the processing efficiency, these two conditions are configured in a double continuous series, that is, in order of the first anoxic tank (5), the aeration tank (6), the second anoxic tank (7), and the membrane aeration tank (8). Installed in a sequential array.
상기 각 조(5,6,7,8)에서는 유기물질의 분해가 공통적으로 일어나며, 특히 폭기조(6)와 분리막 폭기조(8)에서는 질산균에 의해 주로 암모니아성 질소화합물로 구성되어 있는 질소화합물들을 질산화 상태로 산화시키기 위해 공기를 공급하게 되며,이는 공기를 공급하는 블로워(90)와 산기수단(91,92,93)으로 구성되어 있다.In each of the tanks 5, 6, 7, and 8, decomposition of organic substances occurs in common. In particular, in the aeration tank 6 and the membrane aeration tank 8, nitrification of nitrogen compounds mainly composed of ammonia nitrogen compounds by nitrate bacteria is carried out. Air is supplied to oxidize in a state, which is composed of a blower 90 for supplying air and air dispersing means 91, 92, and 93.
또한, 분리막 폭기조(8)에 내부 순환 수중펌프(140)를 설치하여, 질산화된 혼합물을 분지관(141)을 통해 제 1, 2무산소조(5,7)로 내부 순환 반송되며,제 1, 2무산소조(5,7)에서는 이미 질산화 상태의 질소화합물을 유입 원수내 유기물질과 탈질균을 이용,질소가스(N₂)로 환원시켜 대기중에 방출 처리하는 기능을 하게 되고,탈질균과 질산화합물과의 완전한 반응을 위해서는 무산소 조건하에서 내부 완전혼합 환경이 필요하므로 이를 위해 수중 교반장치(130)가 서로 대치되는 방향으로 설치되어 있다.In addition, the internal circulation submersible pump 140 is installed in the membrane aeration tank 8 so that the nitrified mixture is internally circulated and returned to the first and second anaerobic tanks 5 and 7 through the branch pipe 141. In the anoxic tank (5,7), the nitrogen compounds in nitrification state are reduced to nitrogen gas (N₂) by using organic substances and denitrification bacteria in the inflowing raw water, and are discharged to the atmosphere. In order to achieve a complete reaction, an internal complete mixing environment is required under anoxic conditions, so that the underwater agitating device 130 is installed in a direction that is opposed to each other.
상기 각 조내에서 제각기 특유의 기능으로 오염물 정화역할을 담당하는 다종의 미생물들은 분리막 폭기조(8)내 정밀여과 분리막(44)에 의해 고액분리가 진행되기 때문에 전체적으로 10,000PPM이상의 고농도 미생물량을 보유할 수 있으며,이것이 곧 생물학적 처리단계인 2차 처리에서도 이미 고도처리 효율을 얻을 수 있는 비결이 된다.The microorganisms in charge of the contaminant purification by their respective functions in each tank are capable of retaining a high concentration of microorganisms of 10,000 PPM or more as the solid-liquid separation proceeds by the microfiltration membrane 44 in the membrane aeration tank 8. This is the key to obtaining high treatment efficiency even in the second stage of biological treatment.
상기 분리막(44)은 흡인 여과방식의 친수성 정밀여과 중공사막으로 분리막 폭기조(8)내에 침지된 상태에서 활성오니와 처리수를 고액분리하기 위해 설치되어 있으며, 처리수를 이송하기 위한 흡인 여과 펌프(50)와 연결된 구성으로 되어 있다.The separation membrane 44 is a hydrophilic microfiltration hollow fiber membrane of suction filtration method is installed to solid-liquid separation of the activated sludge and the treated water in the state of being immersed in the membrane aeration tank (8), the suction filtration pump for transporting the treated water ( It is connected to 50).
내압 용기가 필요없는 침지형 흡인 및 전량여과 방식의 친수성 정밀여과 분리막 유니트(40,70)은 도 3, 도 4, 도 5와 같이 설치 및 관리상 편리한 별도의 유니트(UNIT)로 제작되어 조내(8,9)에 설치되며,여과 처리동안에는 분리막 유니트(UNIT)(40,70)하부에 별도의 분배관(91)을 통해 공기를 공급하여 막면퇴적,막면부착,막간폐색,막틈새막힘 등의 현상없이 장기적으로 안정된 운전이 가능하게 된다.Immersion type suction and total filtration hydrophilic microfiltration membrane units (40, 70), which do not require a pressure vessel, are manufactured in a separate unit (UNIT), which is convenient for installation and management as shown in FIGS. 3, 4 and 5 (8). 9), and during the filtration process, air is supplied through a separate distribution pipe 91 under the membrane unit (UNIT) (40, 70) to prevent membrane deposits, adhesion of membranes, clogging of membranes, clogging of membranes, etc. Long term stable operation is possible.
도 3과 도 4,도 5는 정밀여과 분리막 유니트(40,70)의 실시예를 나타낸 것으로 정밀여과 분리막 유니트(40,70)의 전체 틀은 하.폐수내에서의 반영구적인 내구성과 분리막의 외형적 보호를 위하여 STS 앵글(41)로 구성하였으며,흡인여과시 각각의 정밀여과 분리막(44)마다 집수역할을 하는 분리막 집수봉(44a)을 지지할 수 있도록 2단으로 환봉(46,46a)을 가로방향으로 본틀에 용접하고,집수봉(44a)중심 만큼의 간격으로 환봉을 세로 방향으로 설치후 CABLE TIE(46c)등으로 견고하게 고정한다.3, 4, and 5 show an embodiment of the microfiltration membrane units 40 and 70, and the entire frame of the microfiltration membrane units 40 and 70 is semi-permanent in the sewage and wastewater and the appearance of the membrane. It is composed of STS angle 41 for the protection of the enemy, and the round rods 46 and 46a are provided in two stages so as to support the membrane collecting rod 44a which serves as a collecting water for each microfiltration membrane 44 during suction filtration. Weld to the main frame in the transverse direction, and install the round bar in the longitudinal direction at intervals equal to the center of the collecting rod 44a, and fix it firmly with a cable tie 46c.
각 분리막 집수봉(44a)으로 부터 흡인 여과된 처리수의 각 집수배관과 분리막 여과펌프(50)와의 연결 배관을 간결하게 하기 위해 각 측면으로 두개의 집수관(43)을 BOLT &NUT로 본틀 상부에 고정하고,하부에도 같은 형태의 집수관(43a)을 설치하므로서 분리막 정밀여과 유니트(40,70)내 다수의 분리막(44)들이 전체적으로 연결될 수 있도록 구성되었다.In order to simplify the connecting pipe between each collecting pipe of the treated water sucked and filtered from each separator collecting rod 44a and the separator filtering pump 50, two collecting pipes 43 are provided on the upper side of the main frame with BOLT & NUT. By fixing and installing the same type of collecting pipe 43a in the lower part, the plurality of separators 44 in the separator precision filtration units 40 and 70 can be connected to the whole.
상기 집수관(43)들은 분리막 집수봉(44a)과의 연결을 위한 SOCKET(45a)설치가 편리토록 사각 STS PIPE로 구성되며,본 집수관(43a)과 분리막 집수봉(44a)의 조립과 분해를 보다 쉽게 조작할 수 있도록 SOCKET(45a)과 분리막 집수봉(44a) 연결부에 각각 ONE TOUCH NIPPLE(42b)과 ONE TOUCH ELBOW(42)를 설치후 우레탄 튜브(42a)로 연결된다.The collecting pipes 43 are composed of a square STS PIPE for convenient installation of the socket 45a for connection with the separator collecting rod 44a, and the assembly and disassembly of the present collecting pipe 43a and the separator collecting rod 44a. The ONE TOUCH NIPPLE (42b) and the ONE TOUCH ELBOW (42) are respectively connected to the SOCKET (45a) and the membrane collecting rod (44a) connecting portion so as to be more easily manipulated, and then connected to the urethane tube (42a).
정밀여과 분리막 유니트(40,70) 상부에 있는 2개의 집수관(43)에는 흡인 여과 펌프(50)와 연결되는 SOCKET(45)이 각각 구성되어 있으며,또한 운전 가동중에 정밀여과 분리막 유니트(40,70)의 유지.보수를 편리하게 하기위해 정밀여과 분리막 유니트(40,70)의 상부 각 코너에 I-BOLT(49)를 설치하여 CHAIN BLOCK등을 이용,인양할 수 있도록 구성된다.The two collecting pipes 43 on the upper part of the microfiltration membrane unit 40 and 70 each have a socket 45 connected to the suction filtration pump 50, and the microfiltration membrane unit 40, 70) I-BOLT (49) is installed at each upper corner of the microfiltration membrane unit (40, 70) for convenient maintenance and repair.
한편,도 4,도 5를 보면 정밀여과 분리막(44)의 막면 퇴적 및 막간 폐색등 막힘현상을 방지하기 위하여 정밀여과 분리막 유니트(40,70)하부에 별도의 분리막 세정용 산기관(48)을 정밀여과 분리막(44) 설치 방향과 직각으로 배치하고,정밀여과 분리막 유니트(40)양측면에는 STS 판(47)을 설치하여 공기 세정시 공기방울이 분산되는 것을 방지하며,정밀여과 분리막 유니트(40,70)최하단에는 공기 공급용 SOCKET(48a)을 설치하여 블로워(90)로부터 공기 분배관(91)과 연결될 수 있도록 구성된다.Meanwhile, referring to FIGS. 4 and 5, in order to prevent clogging such as deposition of the membrane surface of the microfiltration membrane 44 and blockage between the membranes, a separate membrane cleaning diffuser 48 is disposed under the microfiltration membrane unit 40 or 70. Place the microfiltration membrane 44 at right angles to the installation direction, install the STS plate 47 on both sides of the microfiltration membrane unit 40 to prevent air bubbles from scattering during air cleaning, and the microfiltration membrane unit 40, 70 It is configured to be connected to the air distribution pipe 91 from the blower 90 by installing a socket for supplying air (48a) at the bottom.
정밀여과 분리막 유니트(40,70)는 설치공간의 부지 절감을 위해 2단 또는 3단으로 구성이 가능하며, 이런 경우에는 맨 밑에 있는 정밀여과 분리막 유니트(40,70)에만 분리막 세정용 산기관(48)을 설치하면 되며,이때에 상기의 분리막 세정용 공기방울 분산 방지판(47)구성으로 정밀여과 분리막(44)의 세정 기능을 효과적으로 수행할 수 있다.The microfiltration membrane unit (40, 70) can be configured in two or three stages to reduce the site of the installation space, in this case, only the microfiltration membrane unit (40, 70) at the bottom of the membrane filter 48) may be provided, and at this time, the cleaning function of the microfiltration membrane 44 may be effectively performed by the above-described separation membrane for preventing air bubble dispersion 47.
또한,흡인 여과 펌프(50)는 정밀여과 분리막(44)을 보호하기 위해서 0.2∼0.4㎏.f/㎠정도의 차압으로 운전되며,초기운전 차압과 통상 0.3㎏.f/㎠이상 차이가 발생시에는 분리막(44) 보호 차원에서 역세척을 시행하기 위해 역세수 탱크(110)와 연결되어 완벽한 자동 운전을 수행하게 된다.In addition, the suction filtration pump 50 is operated at a differential pressure of about 0.2 to 0.4 kg.f / cm 2 in order to protect the microfiltration membrane 44, and when a difference between the initial operation differential pressure and 0.3 kg.f / cm 2 or more usually occurs In order to perform the backwash in order to protect the separator 44, the backwash tank 110 is connected to perform a perfect automatic operation.
또한, 역세척 시행시에는 흡인과 토출 배관에 설치된 4개 자동밸브의 역조정만으로도 별도의 역세척 펌프없이 분리막 여과 펌프(50)를 이용하여,여과와 역세척 기능이 자동으로 이뤄질 수 있도록 구성된다.In addition, when backwashing is performed, the filtration and backwashing functions are automatically performed by using the membrane filtration pump 50 without a separate backwashing pump only by reverse adjustment of four automatic valves installed in the suction and discharge pipes. .
이러한 기능과 작용은 전기분해 응집기(60) 후단에 설치된 응집 현탁물 고액분리용 정밀여과 분리막 유니트(70)와 흡인 여과펌프(80)에도 동일하게 이뤄지게 된다.This function and action is the same for the fine filtration membrane unit 70 and the suction filtration pump 80 for agglomeration suspension solid-liquid separation installed in the rear end of the electrolytic agglomerator 60.
고농도 유기성 하.폐수인 경우에는 정밀여과 분리막 유니트(40)을 통과한 처리수내에도 일반적으로 생물학적으로는 분해가 잘 되지 않는 난분해성 물질과 인화합물들이 잔류할 수 있는데 이런 오염물들을 동시에 처리하기 위해 전기분해 응집기(60)가 후단에 구성되어 각각, 난분해성 물질의 전기적 강제 산화분해와 잔류인의 응집 반응이 일어날 수 있도록 알루미늄과 같이 응집 이온(ION)들을 석출할 수 있는 전극판을 사용한다.In case of high concentration organic sewage and wastewater, biodegradable hardly decomposable substances and phosphorus compounds may remain in the treated water passing through the microfiltration membrane unit 40. The electrolytic agglomerator 60 is configured at the rear end, and each uses an electrode plate capable of depositing aggregated ions such as aluminum so that an electric forced oxidative decomposition of the hardly decomposable substance and a coagulation reaction of residual phosphorus can occur. .
전단의 활성오니 고액분리용으로 정밀여과 분리막 유니트(40)를 설치한 것과 마찬가지로 전기분해 응집기(60)에서 반응.생성된 응집 현탁물에서 최종 처리수를 얻기 위해 응집 현탁물 고액분리용 정밀여과 분리막 유니트(70)를 재구성하여 소독조(10)에서 처리수내에 존재하는 박테리아등을 살균.소독 시설(100)의 소독과정을 거친 후 방류조(11)를 통해 최종 방류되는 구성으로 되어 있으며,원수의 오염농도에 따라 전단의 정밀여과 분리막(40)을 통과한 처리수 또는 최종처리수는 그 수질이 매우 탁월하므로 화장실용수나 기타 청소수 등 중수로의 재이용이 가능하고,한편,분리막 폭기조(8)내에 필요이상의 미생물, 즉 잉여오니는 내부순환펌프(140)를 이용하여 분지관(142)을 통해 오니 저류조(12)로 유입 저장된다.Microfiltration for coagulation suspension solid-liquid separation in order to obtain the final treated water from the coagulation suspension produced. Reconstitution of the membrane unit 70 to sterilize bacteria present in the treated water in the disinfection tank 10. After disinfection of the disinfection facility 100, and finally discharged through the discharge tank 11, raw water Depending on the pollution concentration of the treated water or the final treated water passed through the microfiltration membrane 40 of the shear is very excellent in the quality of the water can be reused in heavy water, such as toilet water or other cleaning water, on the other hand, membrane aeration tank (8) More than necessary microorganisms, that is, excess sludge is stored in the sludge storage tank 12 through the branch pipe 142 using the internal circulation pump 140.
이러한 일련의 과정은 고농도 유기성 하.폐수고도처리장치에 있어서 각 개별 시설별로 고유의 처리기능을 지니고 있으며,원수의 성상이나 처리 목표 수질에 따라서는 각 시설의 일부 혹은 부분적인 적용으로도 그 처리 목적의 달성이 가능하다고 하겠다.This series of processes has a unique treatment function for each individual facility in the high concentration organic wastewater treatment system, and depending on the nature of the raw water and the target water quality, the purpose of the treatment may be the partial or partial application of each facility. It is possible to achieve.
이상에서 설명한 바와 같이 본 발명은 고농도 유기성 하.폐수내 유기물처리는 물론 수계내 부영양화의 주원인인 질소,인 등 영양 염류까지 동시에 완벽하게 고도처리하기 위한 장치로서 특히,종래의 침전분리조 대용으로 친수성 침지식 흡인여과 분리막(40,70)을 채용, 고농도의 미생물량 보유가 가능해지고, 또한 이중 직렬로 무산소와 호기성 환경 조건을 구성하므로서 공간적.기능적 효율을 한층 더 향상시킬 수 있으며,2차처리후 잔류될 수 있는 난분해성 물질과 인화합물의 추가 처리를 위해 전기분해응집기(60)를 구성,종래의 활성오니 공법에서는 기대할 수 없었던 고농도 유기성 하.폐수의 고도처리가 현실적으로 가능해진 첨단기술 집약장치이다.As described above, the present invention is a device for completely high-level treatment of organic matter in high concentration organic sewage and wastewater as well as nutrients such as nitrogen and phosphorus, which are the main causes of eutrophication in aquatic systems, in particular, hydrophilicity as a substitute for conventional sedimentation tanks. Submerged suction filtration membranes (40, 70) can be used to retain high concentrations of microorganisms, and in addition, the aerobic and aerobic environmental conditions can be configured in series to further improve spatial and functional efficiency. An advanced technology intensive device that constitutes an electrolytic agglomerator (60) for further treatment of remaining hardly decomposable substances and phosphorus compounds, and enables highly advanced treatment of high concentration organic sewage and wastewater, which was not expected in the conventional activated sludge process. to be.
특히,탁월한 처리효율 향상뿐만 아니라 소요부지와 유지관리비 절감 및 관리의 편리성 등이 모두 고려되어 있기 때문에 향후 하.폐수처리의 새로운 기술로서 주도해 나갈것으로 기대되고,기존 처리기술의 고정관념에서 탈피하여 한차원 높은 견지의 이해와 적용이 뒤따라야 할 것이며, 또한 본 발명의 고농도 유기성 하.폐수처리장치는 각 개별 시설별로 고유의 처리기능이 있으므로 주어진 환경조건에 따라 조합된 각 시설의 일부 혹은 부분적 적용으로도 그 목적 수행이 가능하기 때문에 본 발명의 청구된 권리의 범위안에서 수정 및 변경할 수 있는 여러가지 실시 형태는 본 발명의 보호 범위내에 저촉될 수 있음을 인지하여야 한다.In particular, it is expected to lead as a new technology for sewage and wastewater treatment, as it considers not only excellent treatment efficiency, but also required site, maintenance cost reduction, and convenience of management, and it is expected to break away from the stereotype of existing treatment technology. Therefore, the high level organic sewage and wastewater treatment apparatus of the present invention has a unique treatment function for each individual facility, and therefore, it is necessary to partially or partially apply each facility combined according to given environmental conditions. It should be appreciated that various embodiments which may be modified and changed within the scope of the claimed rights of the present invention may be violated within the protection scope of the present invention, since the performance of the object can be performed.
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Cited By (10)
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KR100325922B1 (en) * | 1999-11-30 | 2002-02-27 | 이병헌 | Method for treating unresolvable wastewater |
KR100360375B1 (en) * | 2000-10-24 | 2002-11-13 | 재단법인 포항산업과학연구원 | Apparatus and method for sludge separation and membrane cleaning |
KR100419827B1 (en) * | 2000-12-21 | 2004-02-21 | 정호봉 | Biological, pysical and chemical treatment method of waste water from livestock |
KR100435107B1 (en) * | 2001-10-29 | 2004-06-09 | 교우산업개발(주) | Advance Treatment Equipment and Process for Nitrogen and Phosphate Removal in Sewage and Wastewater |
KR100447039B1 (en) * | 2001-11-14 | 2004-09-07 | 엘바이오텍 주식회사 | A purification system and method of waste water |
KR100715020B1 (en) * | 2006-12-26 | 2007-05-09 | 주식회사 대진환경산업 | Treatment device of wastewater using a sea-water electrolysis apparatus and submerged membrane |
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KR100325922B1 (en) * | 1999-11-30 | 2002-02-27 | 이병헌 | Method for treating unresolvable wastewater |
KR100360375B1 (en) * | 2000-10-24 | 2002-11-13 | 재단법인 포항산업과학연구원 | Apparatus and method for sludge separation and membrane cleaning |
KR100419827B1 (en) * | 2000-12-21 | 2004-02-21 | 정호봉 | Biological, pysical and chemical treatment method of waste water from livestock |
KR100435107B1 (en) * | 2001-10-29 | 2004-06-09 | 교우산업개발(주) | Advance Treatment Equipment and Process for Nitrogen and Phosphate Removal in Sewage and Wastewater |
KR100447039B1 (en) * | 2001-11-14 | 2004-09-07 | 엘바이오텍 주식회사 | A purification system and method of waste water |
KR100715020B1 (en) * | 2006-12-26 | 2007-05-09 | 주식회사 대진환경산업 | Treatment device of wastewater using a sea-water electrolysis apparatus and submerged membrane |
KR100795072B1 (en) * | 2007-07-26 | 2008-01-17 | 주식회사 유성건설 | Treatment method and apparatus for wastewater include excrementitious matter of domestic animal |
KR101146125B1 (en) * | 2011-11-28 | 2012-05-17 | 김종준 | Underground reclamation type water storage tank for removing contaminants |
KR20160028317A (en) | 2014-09-03 | 2016-03-11 | 주식회사 영창터보텍 | Air supplying tube having no pipe and air supplying system using the same |
CN117285119A (en) * | 2023-09-22 | 2023-12-26 | 威海智洁环保技术有限公司 | Integrated backwash water recycling device and treatment method |
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