KR100394769B1 - Shampoo composition containing anionic surfactants and cataionic polymers - Google Patents

Abstract

The present invention relates to a shampoo composition containing an anionic surfactant and a cationic polymer at the same time, and more particularly, by adding a nonionic surfactant to a shampoo composition containing both an anionic surfactant and a cationic polymer to form a liquid crystal in the composition, The present invention relates to a shampoo composition capable of providing a stable cleaning effect, an antistatic effect in the wet state, a hair protection effect, and a conditioning effect without forming a complex due to different ionicity between anionic surfactant and cationic polymer.

Description

Shampoo composition containing anionic surfactants and cataionic polymers

The present invention relates to a shampoo composition containing an anionic surfactant and a cationic polymer at the same time, and more particularly, by adding a nonionic surfactant to a shampoo composition containing both an anionic surfactant and a cationic polymer to form a liquid crystal in the composition, The present invention relates to a shampoo composition that can provide a cleansing effect, an antistatic and hair protection effect on wet hair, and a conditioning effect without forming a complex due to different ionicity between anionic surfactant and cationic polymer. .

Shampoo is a cosmetic product for hair that is used to decontaminate the scalp and hair and keep the hair clean and beautiful.In addition to the purpose of cleaning, the shampoo is easy to comb, soft, smooth, gloss and decreases the friction of the hair surface, antistatic, It is used for additional purposes such as hair protection.

Therefore, active researches have been made on shampoo compositions having such a purpose, and among them, studies for preventing the damage of the cuticle due to friction by increasing the antistatic and wet hair of the hair are continuously increasing.

Cationic surfactants and cationic polymers are used to prevent static electricity of conventional hairs, and cationic polymers are mainly used to prevent damage to the hair cuticle layer when the wet hair is softly rinsed or when combing wet hair. In other words, wet hair during shampooing always has a negative charge because its pH is higher than the isoelectric point of 3.67. Therefore, a cationic polymer is adsorbed onto the hair by different ionicity by using a positively charged cationic polymer. In particular, the cationic polymer has a specific charge density, and since the adsorption amount increases as the charge density increases, the cationic polymer having a high charge density is used to protect the hair.

However, shampoos containing anionic surfactant bases are mainly used because of excellent cleanability and post-shampoo refreshment among shampoos, and cationic polymers are limited in use. This is because cationic polymers with relatively low charge densities of 1.5 meq / g are resolubilized in excess of anionic surfactant bases to become transparent, whereas cationic polymers with relatively high charge densities of 5.2 meq / g or higher are anionic surfactants. This is because the interaction with is so strong that there is a problem of separating the formulation by forming a complex.

Therefore, the present inventors have studied a method that can prevent the formation of the complex by the strong ionic bond between the anionic surfactant and the cationic polymer, and as a result, when adding a nonionic surfactant having a liquid crystal forming ability, Since the nonionic surfactant penetrates, weakens strong ionic bonds and transforms into a spherical liquid crystal form, the present invention has been found to provide a shampoo composition in which anionic surfactants and cationic polymers are stably dispersed.

Accordingly, it is an object of the present invention to provide a shampoo composition which can provide an antistatic effect, a hair protection effect, and a conditioning effect in a stably wet hair without formation of a composite due to different ionicity.

1 is a photograph showing that the liquid crystal is formed in the shampoo composition of the present invention (200 times optical microscope).

Figure 2 is a photograph showing that the liquid crystal is formed in the shampoo composition of the present invention (200 times polarized light microscope).

3 is a view showing the results of testing the adsorption amount of the shampoo composition of the present invention.

In order to achieve the above object, the shampoo composition according to the present invention comprises 0.01 to 5% by weight of cationic polymer, 1.0 to 10% by weight of nonionic surfactant and 5.0 to 30% by weight of anionic surfactant based on the total weight of the composition. It is characterized by containing.

Hereinafter, the present invention will be described in more detail.

In the shampoo composition according to the present invention, a liquid crystal is formed in the composition by further adding a nonionic surfactant having a liquid crystal forming ability to the shampoo composition containing the anionic surfactant and the cationic polymer, whereby the anionic surfactant and the cationic polymer are stabilized in the composition. Therefore, it is possible to stably provide the antistatic effect in the wet hair of the cationic polymer, the hair protection effect by the suppression of cuticle layer damage and the cleaning power of the anionic surfactant.

Cationic Polymer

The cationic polymer used in the present invention is a cationic polymer having a high charge density, in particular, a high charge density of 5.2 meq / g or more, and the kind thereof is not particularly limited, but there are polyethyleneimine, polyquaternium-6 and the like.

Polyquaternium-6 is a polymer of a monomer represented by the following structural formula (I). Commercialized polyquaternium-6 includes Salcare sc 30 (Ciba), which is treated as a 40% aqueous solution and has an average molecular weight of about 150,000. This polymer, when adsorbed by wet hair, prevents hair from entangled by laplace pressure, which is very soft during rinsing and prevents hair cuticle damage.

N, N-dimethyl-N-2-propenyl-2-propene-1-amininium chloride

In the shampoo composition of the present invention, the cationic polymer is preferably used in an amount of 0.01 to 5.0% by weight based on the total weight of the composition. If it is used at less than 0.01% by weight, there is little effect of conditioning the wet hair, and if it exceeds 5% by weight, the amount of adsorption is too high. This is because a lot of hair accumulation phenomenon occurs.

[Nonionic Surfactant]

The nonionic surfactant used for the sampu composition of this invention is represented by following structural formula (II).

R (OCH ₂ CH ₂ ) _n OH (II)

(Wherein R is an alkyl group having 8 to 20 carbon atoms,

n is an integer between 2 and 5)

The nonionic surfactant is preferably used in an amount of 1.0 to 10% by weight based on the total weight of the composition. This is because when used in less than 1% by weight has little effect of preventing the formation of a complex between the cationic polymer and the anionic surfactant, when used in excess of 10% by weight destroys the stable spherical liquid crystal structure, rather it lowers the stability of the formulation to be.

[Anionic Surfactant]

The anionic surfactant used in the present invention is represented by the following structural formula (III), and representative compounds include sodium lauryl sulfate, lauryl ammonium sulfate, lauryl magnesium sulfate, lauryl triethanolamine, polyoxyethylene sodium lauryl sulfate, poly Oxyethylene lauryl ammonium sulfate and the like, which serve to clean various wastes in the composition.

RO (CH ₂ CH ₂ O) _n SO ₃ M (III)

(Wherein R is an alkyl group having 8 to 20 carbon atoms,

n is an integer of 0 to 4,

M is sodium, potassium, magnesium, triethanolamine or ammonium ion.)

The anionic surfactant in the shampoo composition of the present invention is 5 to 30% by weight based on the total weight of the composition. Preferably it is used in the amount of 10-25 weight%.

[Optional ingredients]

The optional ingredients used in the shampoo composition of the present invention are well known to those skilled in the art as conventional optional ingredients for maintaining basic physical properties and quality. Specific examples include preservatives, thickeners and viscosity modifiers, pH adjusters, fragrances, dyes, hair conditioning agents.

For example, there is a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methylisothiazolinone (trade name; Kathon CG, manufactured by Rohm & Haas, USA) and includes viscosity modifiers such as sodium chloride, ammonium chloride, and propylene glycol; PH adjusting agents such as citric acid, phosphoric acid, sodium hydroxide, potassium hydroxide; Hair conditioning agents such as dimethicone, polyoxyethylene lanolin, lanolin alcohols, hydrolyzed animal proteins, ethylene glycol distearic acid; Dyestuffs such as water soluble tars are used, and perfumes may be used.

Hereinafter, the shampoo composition of the present invention will be described in more detail with reference to examples of the present invention, but the present invention is not limited to these examples.

[Examples 1-2 and Comparative Examples 1-3]

ingredient Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Ammonium Lauryl Sulfate (25%) 60.0 60.0 60.0 60.0 60.0 2. Ethylene Glycol Distearic Acid 1.5 1.5 1.5 1.5 1.5 3. Laures-3 ^* - - 6.0 6.0 6.0 4. Polyquaternium-6 - 0.5 - 0.1 0.5 5. Dimethicone 3.0 3.0 3.0 3.0 3.0 6. Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 7. Spices 0.7 0.7 0.7 0.7 0.7 8. Citric acid 0.01 0.01 0.01 0.01 0.01 9. Water to 100 to 100 to 100 to 100 to 100 In the above formula (II), R is 12 and n is 3, which is 2- [2- [2- (dodecyloxy) ethoxy] ethoxy] ethanol. Use of LAE-3 by Honam Petrochemical Co., Ltd.

<Production method>

(1) The components 1 and 2 were added to component 9, and it heated up to 70 degreeC, and stirred at that temperature for 30 minutes.

The components 3 and 4 were added to (2) and (1), and it cooled to 45 degreeC, stirring.

Components 3 to 8 were added to (3) and stirred for 30 minutes.

On the other hand, in the case of Comparative Example 2 it could not be separated immediately after manufacture to form a shampoo formulation.

Test Example 1 Liquid Crystal Formation

In order to confirm that the liquid crystal is formed in the shampoo composition of the present invention, a photograph of the shampoo of Example 1 was taken using a polarizing microscope. The results are shown in FIG. 1 and FIG. 2.

1 and 2, since the liquid crystal is formed in the composition by the addition of a nonionic surfactant, it can be seen that the anionic surfactant and the cationic polymer is present stably in the composition.

[Test Example 2] adsorption amount test

The amount of cation adsorption of the samples was measured using a wool swatch with a hair-like structure. First, make a wool swatch by taking a length of 2cm in width and length, apply 4 weights of samples (Examples 1 and 2 and Comparative Examples 1 and 3), add 2 weights of water, and rub the foam with pinsen. Simulated. The treated swatch was washed 5 times with 50 times of water, and then the prepared dye stock solution [Red 80 (Aldrich) dye 3.4m mole + 1.25ml acetic acid + 500ml ion-exchanged water] was taken 20 times by weight of wool swatch and swatch for 1 minute. Was deposited. Finally, it was rinsed five times in 50 times the water of wool swatch and dried. The results are shown in FIG. In this case, the red swatch of red color means that the cationic material is adsorbed on the swatch.

From Fig. 3, the shampoos of Comparative Examples 1 and 3 did not contain polyquaternium-6, which is a cationic polymer, so that the swatch hardly turned red, and Comparative Example 2 was used between ammonium laurate sulfate and polyquaternium-6. The formation of the complex led to separation of the formulation, which could not be tested. However, since the swatches of the examples turned red, it can be seen from this that the cationic polymer, polyquaternium-6, was stabilized by Laures-3 to adsorb a large amount of cationic polymer. It can be seen that the amount of hair adsorption also increases with increasing content.

[Test Example 3] Usability in the wet state

20 random women were selected as subjects, and each of the four shampoo compositions prepared in Example was allowed to have five subjects use them in their usual manner for two weeks, and then on the second week day After shampooing, the condition of wet hair was evaluated. Evaluation was based on the average criteria of the following Table 2, the subject was objectively scored and then averaged, and the results are shown in Table 3.

Evaluation standard Softness when rinsing wet hair Easy to comb wet hair Hair smoothness (softness) immediately after removing the moisture with a towel score Very good 5 Great 4 usually 3 A little bad 2 Very bad One

Comparative Example 1 Comparative Example 3 Example 1 Example 2 Softness when rinsing wet hair 1.2 1.5 3.0 3.0 Easy to comb wet hair 1.1 1.6 1.6 3.4 Hair smoothness (softness) immediately after removing the moisture with a towel 1.5 2.0 2.0 3.5

From Table 3, it can be seen that the shampoos of the examples are liquid crystals formed by Laureth-3, so that the polyquaternium-6, a cationic polymer, is stabilized, so that the usability in the wet state is superior to the shampoo compositions of the comparative examples. have. In addition, as the content of polyquaternium-6 increases, the usability of the wet state also increases.

As described above, in the shampoo composition of the present invention, since the cationic polymer and the anionic surfactant form a liquid crystal and can be stably present in the composition by the addition of a nonionic surfactant, the cleaning effect and the prevention of static electricity in wet hair Effect, hair protection effect, and conditioning effect.

Claims (3)

1.0 to 10% by weight of the nonionic surfactant was added to the shampoo composition containing 0.01 to 5% by weight of the high- charge cationic polymer having a charge density of 5.2 meq / g or more and 5.0 to 30% by weight of the anionic surfactant based on the total weight of the composition. Shampoo composition for promoting hair adsorption, characterized in that to form a liquid crystal in . delete The shampoo composition according to claim 1, wherein the nonionic surfactant is represented by the following structural formula (II). [Formula 2] R (OCH ₂ CH ₂ ) _n OH (II) (Wherein R is an alkyl group having 8 to 20 carbon atoms, n is an integer between 2 and 5)