KR100394137B1 - Method of high-speed spinning polyester - Google Patents

Method of high-speed spinning polyester Download PDF

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Publication number
KR100394137B1
KR100394137B1 KR1019960067930A KR19960067930A KR100394137B1 KR 100394137 B1 KR100394137 B1 KR 100394137B1 KR 1019960067930 A KR1019960067930 A KR 1019960067930A KR 19960067930 A KR19960067930 A KR 19960067930A KR 100394137 B1 KR100394137 B1 KR 100394137B1
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polyester
line
speed
speed spinning
temperature
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KR1019960067930A
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Korean (ko)
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KR19980049245A (en
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김병동
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주식회사 코오롱
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/084Heating filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

Abstract

PURPOSE: Provided is a method of high-speed spinning a polyester yarn which prevents the deterioration of a solvent, and enhances the productivity with uniform tenacity and elongation. CONSTITUTION: With the method of high-speed spinning polyester, a high-speed spun polyester is quenched in a quenching chamber(4) directly placed under a spinneret, and before the oiling treatment, heat-treated by a line heater(11), and cooled by a line quencher(12). The length of the line heater is 1.2-3.0m, and the temperature thereof is 130-180 deg.C. The length of the line quencher is 0.5-2.0m, and the temperature thereof is 15-25 deg.C.

Description

폴리에스테르의 고속방사 방법High Speed Spinning Method of Polyester

본 발명은 고속방사법에 의한 폴리에스테르 원사의 제조에 관한 것이다.The present invention relates to the production of polyester yarns by a high-speed spinning method.

일반적으로 고속방사는 방사속도가 분당 5,000m 이상을 통칭한다, 폴리에스테르 원사를 생산하는 공정에는 1차로 미연신사를 생산후 2차적으로 연신처리를 시행하는 방법과 방사와 동시에 연신공정을 수행하는 방법이 있다. 미연신사 제조 후에 연신처리를 시행하는 방법은 생산성이 낮은 반면 제품의 차별화로 다품종 소량생산에 주로 이용되고 있다. 또한 방사와 동시에 연신공정을 수행하는 방법은 생산비용이 저하되어 가격경쟁력이 높은 장점이 있다. 따라서 현재는 많은 회사들이 이 방식을 적용하고 있다.In general, high-speed spinning is known as the spinning speed is more than 5,000m per minute.In the process of producing polyester yarn, the first method of producing unstretched yarn and the second process of stretching after spinning and the process of stretching simultaneously with spinning There is this. The method of performing the stretching treatment after the production of the unstretched yarn is low in productivity, but it is mainly used for small quantity production of various kinds due to the differentiation of products. In addition, the method of performing the stretching process at the same time as spinning has the advantage of high price competitiveness due to the low production cost. Therefore, many companies are applying this method now.

방사와 동시에 연신공정을 수행하는 방법은 생산 속도를 고속화함으로서 단위생산성을 높일 수 있다. 선진 각국에서는 현재 12,000 m/분의 속도까지 연구개발을 하고 있지만, 세계적으로 상업화되어 있는 생산속도는 5,000∼7,000 m/분 수준이다. 그러나 생산효율을 증대시키기 위해 무한정 속도를 높일 수 있는 것은 아니다, 즉 방사속도 향상에 따른 역효과가 발생되기도 한다. 조업성의 저하 및 물성의 저하는 물론 고속방사에 따른 특이물성 발현으로 기존의 정번품과 상이한 가공조건으로 후가공을 실시하여야 하기 때문에 부가적인 비용의 증대 및 품질 불균일 등을 초래한다.The method of performing the stretching process simultaneously with spinning can increase the unit productivity by speeding up the production speed. The developed countries are currently conducting R & D at speeds up to 12,000 m / min, but the commercialized production speeds around the world range from 5,000 to 7,000 m / min. However, it is not possible to increase the speed indefinitely in order to increase the production efficiency, that is, the adverse effect of improving the spinning speed may occur. As a result of deterioration of workability and deterioration of physical properties as well as the expression of specific properties due to high-speed spinning, post-processing should be performed under different processing conditions than existing regular products, resulting in additional cost increase and quality unevenness.

종래의 고속방사 방법에는 제 1도와 같이 고속방사된 폴리에스테르를 구금 직하의 퀀칭 쳄버(4)에서 퀀칭처리하고, 유제 처리한 후 사조를 집속하여 권취하는 방법과 제 2도와 같이 고속방사된 폴리에스테르를 구금 직하의 퀀칭 쳄버(4)에서 퀀칭처리 하고, 계속해서 라인 히팅 장치(11)로 열처리하고 유제 처리한 후 사조를 접속하여 권취하는 방법이 있다. 그러나 이와 같은 종래의 고속방사 방법은 사조간의 마찰로 사균제도가 떨어지고, 수반 기류에 의한 유제의 열화로 인한 유제의 내열정 저하 및 윤활성능 감소 등의 문제로 인하여 조업성이 저하되는 단점이 있다.In the conventional high speed spinning method, the high speed spun polyester as shown in FIG. 1 is quenched in a quenching chamber 4 directly under the detention, and after emulsifying, the yarns are concentrated and wound and the high speed spun polyester as shown in FIG. Is quenched in the quenching chamber 4 directly under the detention, and subsequently heat treated with the line heating device 11, and then tanned. However, such a conventional high-speed spinning method has a disadvantage in that the bactericidal system is lowered due to friction between yarns, and the operability is deteriorated due to problems such as deterioration of heat resistance of the emulsion due to deterioration of the emulsion due to air flow and decrease in lubrication performance.

본 발명은 고속방사시 물성 저하 및 조업성 불량 등의 원인인 유제의 열화를 방지하여 생산성을 향상시키고, 일반 의류용 원사와 같은 우수한 물성을 갖는 폴리에스테르 원사를 제조한다.The present invention improves productivity by preventing deterioration of an oil agent, which is a cause of deterioration of physical properties and poor operability during high-speed spinning, and manufactures a polyester yarn having excellent physical properties such as a general garment yarn.

제 1도 및 제 2도는 종래의 폴리에스테르 고속방사의 공정개략도이고1 and 2 are process schematic diagrams of conventional polyester high-speed spinning

제 3도는 본 발명인 폴리에스테르 고속방사의 고정개략도이다.3 is a fixed schematic view of the polyester high-speed spinning of the present invention.

제 1도 내지 제 3도에서, 1은 스핀블록, 2는 구금, 3은 사고, 4는 퀀칭 쳄버, 5는 오일링장치, 6은 1차고뎃트롤, 7은 2차고뎃트롤, 8은 가이드, 9는 와인더, 10은 권취보빈, 11은 라인 히팅 장치, 12는 라인 퀀칭 장치이다.In Figures 1 to 3, 1 is spin block, 2 is detention, 3 is accident, 4 is quenching chamber, 5 is oiling device, 6 is primary high control, 7 is secondary high control and 8 is guide 9 is a winder, 10 is a winding bobbin, 11 is a line heating device, and 12 is a line quenching device.

본 발명은 고속방사법에 의한 폴리에스테르 원사의 제조방법에 관한 것이다. 더욱 상세하게는 폴리에스테르의 방사시 퀀칭처리 공정과 유제처리 공정 사이에서 라인 히팅 장치(11)로 열처리하고, 열처리된 사조를 라인 퀀칭 장치(12)로 냉각시켜 안정화시킴으로 공정통과성, 사주행성 및 조업성을 향상시키고 물성이 우수한 폴리에스테르 원사를 제조하는 고속방사 방법에 관한 것이다.The present invention relates to a method for producing a polyester yarn by a high speed spinning method. More specifically, heat treatment is performed by the line heating device 11 between the quenching process and the tanning process during the spinning of the polyester, and the heat treated yarn is cooled by the line quenching device 12 to stabilize the process. It relates to a high-speed spinning method for improving the operability and producing a polyester yarn excellent in physical properties.

본 발명은 고속방사된 폴리에스테르를 구금 직하의 퀀칭 쳄버(4)로 퀀칭처리 후 오일링 처리하기 전에 라인 히팅 장치(11)로 가열하고, 라인 퀀칭 장치(12)로 냉각시킨다.In the present invention, the high-speed spun polyester is quenched with a quenching chamber 4 directly under the confinement, and then heated by the line heating apparatus 11 and cooled by the line quenching apparatus 12 before oiling.

본 발명을 도면을 통하여 더욱 상세하게 설명한다. 제 3도는 본 발명인 폴리에스테르 고속방사 공정개략도이다.The present invention will be described in more detail with reference to the drawings. 3 is a schematic diagram of a polyester high-speed spinning process of the present invention.

구금(2)을 통하여 고속방사된 폴리에스테르 사조(3)는 퀀칭 쳄버(4)에서 퀀칭처리하고 계속하여 라인 히팅 장치(11)로 가열하고 라인 퀀칭 장치(12)로 냉각시킨다, 연속적으로 냉각된 사조를 오일링 장치(5)로 유제 처리한 후 사조를 접속하여 1차고뎃트롤(6), 2차고뎃트롤(7), 가이드(8) 및 와인더(9)를 통하여 권취보빈(10)에 권취한다.The polyester yarn 3 which was spun at high speed through the detention 2 was quenched in the quenching chamber 4 and subsequently heated by the line heating device 11 and cooled by the line quenching device 12, continuously cooled. After the thread is tanned with the oiling device (5), the thread is connected to the winding bobbin (10) through the primary high troll (6), the secondary high troll (7), the guide (8) and the winder (9). Wind up on.

여기서 라인 히팅 장치(11)는 원통형의 히터로 길이가 1.2∼3.0m이고 온도가 130∼180℃인 것이 바람직하며, 라인 퀀칭 장치(12)는 원통형의 냉각장치로 길이가 0.5∼2.0m이고 온도가 15∼25℃인 것이 바람직하다, 또한 냉각영역의 위치를 열처리장치와 유제처리부 사이에 위치하게 하여 주행되는 사조에 의해 가열영역의 뜨거운 가류가 유제처리부로 이행되는 것을 방지한다.Here, the line heating device 11 is a cylindrical heater having a length of 1.2 to 3.0 m and a temperature of 130 to 180 ° C., and the line quenching device 12 is a cylindrical cooling device having a length of 0.5 to 2.0 m and having a temperature. It is preferable that the temperature is 15 to 25 DEG C. Further, the position of the cooling zone is positioned between the heat treatment apparatus and the tanning treatment unit to prevent hot vulcanization of the heating zone from being transferred to the tanning treatment unit by the running thread.

라인 히팅 장치(11)의 길이 및 온도 또는 라인 퀀칭 장치(12)의 길이 및 온도가 본 발명의 범위를 벗어나는 경우에는 사균제도 및 조업성이 떨어지게 되어 제품물성이 저하되고, 후가공시 백분 발생으로 제품의 품질을 저하시킨다.If the length and temperature of the line heating device 11 or the length and temperature of the line quenching device 12 are out of the scope of the present invention, the bactericidal agent and the operation are inferior, resulting in deterioration of product properties and the production of powder by post-processing. Reduces the quality of.

이하 실시예 및 비교실시예를 통하여 본 발명을 더욱 상세하게 설명하고자 한다. 이때 본 발명의 물성 측정 방법은 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. At this time, the physical property measuring method of the present invention is as follows.

강도 및 신도(%)Strength and elongation (%)

JIS∼L1017 방법을 이용하여 측정하였다. 이때 기기 및 조건은 아래와 같다.It measured using the JIS-L1017 method. The equipment and conditions are as follows.

·인장시험기 저속신장형(인스트롱사제)Tensile testing machine low speed extension type (manufactured by Instron Co., Ltd.)

·인장 속도 :300mm/분Tensile Speed: 300mm / min

·시료 길이 :250mmSample length: 250 mm

·분위기온도 25℃, 65% RHAmbient temperature 25 ℃, 65% RH

조업성Operability

풀 드럼율(Full Drum 율) 비교Full Drum Rate Comparison

·백분 발생 여부· Percentage occurs

후가공 처리에 의해 제직 공정에서 백분 발생 확인Confirmation of white powder in the weaving process by post-processing

[실시예 1]Example 1

고유점도가 0.64이고 융점이 261℃이며 유리전이온도가 69℃인 폴리에틸렌테프탈레이트를 본 발명의 고속방사장치를 이용하여 온도가 290℃이고 구금홀 크기가 0.2mm이며 구금홀수가 36개인 방사구금으로 융용방사한다.Polyethylenetephthalate having an intrinsic viscosity of 0.64, a melting point of 261 ° C, and a glass transition temperature of 69 ° C using a spinneret having a temperature of 290 ° C, a detention hole size of 0.2 mm and a number of 36 detention holes using spinneret Melt spun.

방사구금 직하의 퀀칭 쳄버(4)에서 25℃의 퀀칭 에어(Quenching Air)로 60℃의 온도로 냉각하고, 냉각된 사조를 길이가 1.2m 온도가 180℃이고 퀀칭 쳄버 하단에 위치한 라인 히팅 장치(11)로 열처리하고, 길이가 0.5m, 온도가 15℃이고 라인 히팅 장치(11)의 하단에 위치한 라인 퀀칭 장치(12)로 냉각시키고 유제 처리한 후 사조를 집속하여 5,000 m/분의 속도로 권취 한다.In the quenching chamber 4 directly below the spinneret, it is cooled to a temperature of 60 ° C. with a quenching air of 25 ° C., and a line heating device located at the bottom of the quench chamber with a temperature of 180 ° C. with a temperature of 1.2 m in length. 11), the length is 0.5m, the temperature is 15 ℃, cooled by the line quenching device 12 located at the bottom of the line heating device (11) and emulsified, the yarns are concentrated to a speed of 5,000 m / min Wind up.

이와 같이 제조된 폴리에스테르 원사의 물성 측정 결과는 표 2와 같다.The measurement results of the physical properties of the polyester yarns thus prepared are shown in Table 2.

실시예 2∼6Examples 2-6

라인 히팅 장치(11)의 길이와 온도 및 라인 퀀칭 장치(12)의 길이와 온도를 표 1과 같이 변경한 것을 제외하고는 실시예 1과 동일한 조건으로 폴리에스테르 원사를 제조한다.A polyester yarn was manufactured under the same conditions as in Example 1 except that the length and temperature of the line heating device 11 and the length and temperature of the line quenching device 12 were changed as shown in Table 1.

이와 같이 제조된 폴리에스테르 원사의 물성 측정 결과는 표 2와 같다.The measurement results of the physical properties of the polyester yarns thus prepared are shown in Table 2.

비교실시예 1Comparative Example 1

라인 히팅 장치(11)의 길이와 온도를 표 1과 같이 변경하고 라인 퀀칭 장치(12)를 사용하지 않은 것을 제외하고는 실시예 1과 동일한 조건으로 폴리에스테르 원사를 제조한다A polyester yarn was manufactured under the same conditions as in Example 1 except that the length and temperature of the line heating device 11 were changed as shown in Table 1 and the line quenching device 12 was not used.

이와 같이 제조된 폴리에스테르 원사의 물성 측정 결과는 표 2와 같다.The measurement results of the physical properties of the polyester yarns thus prepared are shown in Table 2.

비교실시예 2Comparative Example 2

라인 히팅 장치(11) 및 라인 퀀칭 장치(12)를 사용하지 않은 것을 제외하고는 실시예 1과 동일한 조건으로 폴리에스티르 원사를 제조한다.A polyester yarn was manufactured under the same conditions as in Example 1 except that the line heating device 11 and the line quenching device 12 were not used.

이와 같이 제조된 폴리에스테르 원사의 물성 측정 결과는 표 2와 같다.The measurement results of the physical properties of the polyester yarns thus prepared are shown in Table 2.

[표 1]:처리조건[Table 1]: Processing conditions

[표 2]:물성 측정 결과TABLE 2 Property Measurement Results

본 발명은 기존의 고속방사와 비교시 조업성의 향상으로생산성이 우수하고,강도 및 신도의 편차가 감소되고 사균제도가 향상되어 일반 의류용 원사와 같은 물성을 갖는 필라멘트 원사를 생산할 수 있다. 또한 공정의 안정화로 후가공성이 향상되어 백분 발생 현상이 없고. 권취실의 흄(Fume) 발생 및 온도 상승에 의한 공조 조건 난조 등의 문제를 해결하였다. 또한 안정된 사주행성으로 우수한 물성의 폴리에스테르 원사를 제조할 수 있다.The present invention is superior in productivity compared to the existing high-speed spinning, the productivity is excellent, the variation in strength and elongation is reduced and the bactericidal system is improved to produce a filament yarn having the same physical properties as the yarn for general clothing. In addition, the post-processability is improved by stabilization of the process, and there is no occurrence of powder. Problems such as fume generation in the winding room and air conditioning conditions due to temperature rise have been solved. In addition, it is possible to manufacture a polyester yarn of excellent physical properties with stable four-run.

Claims (5)

고속방사된 폴리에스테르를 구금 직하의 퀀칭 쳄버(4)로 퀀칭처리 후 오일링 처리하기 전에 라인 히팅장치(11)로 가열하고, 라인 퀀칭 장치(12)로 냉각시키는 것을 특징으로 하는 폴리에스테르의 고속방사 방법.The high-speed spinning of the polyester, characterized in that the high-speed spun polyester is quenched with a quenching chamber (4) directly under the detention, and then heated by the line heating device (11) and cooled by the line quenching device (12) before oiling Spinning method. 1항에 있어서, 라인 히팅 장치의 길이가 1.2∼3.0m인 것을 특징으로 하는 폴리에스테르의 고속방사 방법The method of high speed spinning of polyester according to claim 1, wherein the length of the line heating device is 1.2 to 3.0 m. 1항에 있어서, 라인 히팅 장치의 온도가 130∼180℃인 것을 특징으로 하는 폴리에스테르의 고속방사 방법.The high-speed spinning method of polyester according to claim 1, wherein the temperature of the line heating device is 130 to 180 ° C. 1항에 있어서, 라인 퀀칭 장치의 길이가 0.5∼2.0m인 것을 특징으로 하는 폴리에스테르의 고속방사 방법.The method of high speed spinning of polyester according to claim 1, wherein the length of the line quenching device is 0.5 to 2.0 m. 1항에 있어서, 라인 퀀칭 장치의 온도가 15∼25℃인 것을 특징으로 하는 폴리에스테르의 고속방사 방법.The high-speed spinning method of polyester according to claim 1, wherein the temperature of the line quenching device is 15 to 25 ° C.
KR1019960067930A 1996-12-19 1996-12-19 Method of high-speed spinning polyester KR100394137B1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07268721A (en) * 1994-03-26 1995-10-17 Teijin Seiki Co Ltd Apparatus for heat-treating polyester fiber
JPH08209441A (en) * 1995-01-26 1996-08-13 Mitsubishi Rayon Co Ltd Production of polyester thick and thin yarn by direct spinning and drawing
KR0184311B1 (en) * 1994-06-30 1999-05-01 하기주 High spinning method of polyester fiber
KR100223979B1 (en) * 1994-12-29 1999-10-15 조정래 The method of preparing a polyester hollow yarn having excellent dyeing levelness

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07268721A (en) * 1994-03-26 1995-10-17 Teijin Seiki Co Ltd Apparatus for heat-treating polyester fiber
KR0184311B1 (en) * 1994-06-30 1999-05-01 하기주 High spinning method of polyester fiber
KR100223979B1 (en) * 1994-12-29 1999-10-15 조정래 The method of preparing a polyester hollow yarn having excellent dyeing levelness
JPH08209441A (en) * 1995-01-26 1996-08-13 Mitsubishi Rayon Co Ltd Production of polyester thick and thin yarn by direct spinning and drawing

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