KR100384130B1 - A shipboard cable having high retardant flame and low fume properties and Composition for sheath thereof - Google Patents

Abstract

The present invention relates to a cable used for the purpose of supplying signals and power in a ship, comprising: a conductor (1), an insulating layer (3) insulated with crosslinked polyethylene surrounding the conductor (1), and a plurality of said insulating layers ( It is characterized by consisting of a braided layer 5 braided with aluminum alloy surrounding the aggregate of insulating layers composed of 3) and a sheath layer 7 surrounding the braided layer 5.

The present invention is reduced to 30% of the outer diameter and 40% of the weight reduction compared to the conventional ship cable 21 IEC 332-3 cat. The present invention relates to a composition of a thermoplastic sheath material having excellent flame retardancy of Class A and high flame retardancy and low smoke retardant property satisfying the low smoke retardant property of IEC 1034.

Description

A shipboard cable having high retardant flame and low fume properties and Composition for sheath

The present invention relates to a highly flame-retardant low-combustion ship cable 9 and its composition for the purpose of supplying signals and power in ships such as luxury passenger ships.

Conventional marine cable 21 is divided into various products depending on the use and place of use. Recently, various quality cables have been developed to minimize the protection and loss of life and equipment in the event of fires in offshore structures and ships. Conventional ship cable 21 has less interest in fire retardant and its development, but in recent years the use of the flame retardant expansion as the scope of use expands and the interest in the use and role of the flame retardant cable in the fire inside the vessel and auxiliary facilities increases. The demand for is expanding.

According to the existing technology, IEC 332-3 cat. Marine cables have been developed that not only meet Class A but also electrical and combustion characteristics. However, the conventional ship cable 21 has a multi-layered structure as shown in FIG. 2, which requires high processing cost as well as manufacturing hassle and difficulty. Conventional products satisfy the electrical and general mechanical properties by blending inorganic flame retardants and inorganic additives with ethylene propylene rubber (EPR) as insulators on the conductors 11.

In addition, a polyvinyl chloride (PVC) bedding layer 15 is formed between the ethylene propylene rubber insulating layer 13 and the metal braided layer to prevent the penetration of moisture and other impurities from the outside of the sheath. Assigned roles. Existing products used copper as braid. As a result of the mixing of inorganic additives, the high specific gravity insulator, the bedding layer and the heavy copper braid not only increased the weight of the cable but also enlarged the outer diameter of the cable.

In the prior art, a polyvinyl chloride (PVC) bedding layer 15 having a certain flame retardant performance and a ethylene propylene rubber insulating layer having a certain flame retardancy due to the characteristics of the cable structure and the applied material Due to the flame retardant performance of 13, the flame retardancy of the sheath body which prevents heat diffusion into the insulation coated conductor during combustion was not high. And, in the case of JIS ship cable of the existing products used a polyvinyl chloride flame retardant material having a flame retardant as the sheath body.

Among the conventional techniques, advanced techniques have been applied to non-halogen flame-retardant materials as polyvinyl chloride bedding bodies and to flame-retardant halogen flame-retardant materials instead of flame-retardant sheaths containing vinyl chloride or halogen-based compounds. However, in order to satisfy the high flame retardant cable characteristics as in the present invention, the flame-retardant sheath containing no halogen was crosslinked to improve the flame retardant characteristics and the drip characteristics during combustion. However, such a crosslinking method not only requires a double process and equipment, but also increases manufacturing costs. In the case of the high flame retardant materials according to the prior art, the flame retardant grade is satisfactory, but the low smoke characteristics of the cable in the finished state are difficult to satisfy.

In the prior art and the invention, a large amount of metal hydrate or other flame retardant aid was applied to secure flame retardancy, and a smoke density inhibitor was used in a large amount for low smoke. In general, secondary smoke retardants such as zinc borate such as zinc borate or tin have been used as smoke density inhibitors. However, zinc borate has a limited effect on suppressing the smoke concentration as well as the effect of improving flame retardancy. It also leads to a drop in the characteristic value after heating of the material.

Figure 2 shows the structure of a conventional cable used in the prior art. As shown in FIG. 2, the conventional ship cable 21 includes a conductor 11, an ethylene propylene rubber (EPR) insulating layer 13, and a polyvinyl chloride (PVC) bedding layer 15. ), A galvanized steel wire braided layer 17, a polyvinyl chloride (PVC) sheath layer 19, and the like.

The present invention has been made to solve the above problems, an object of the present invention is to reduce the outer diameter and weight compared to the existing cable in the cable used to supply signals and power in ships such as luxury passenger ships IEC 332-3 cat. It is to provide a high flame retardant low smoke marine ship cable (9) characterized by a composition of excellent thermoplastic sheath material which satisfies flame retardancy of A class and low smoke characteristics of IEC 1034, and a composition for the sheath.

An object of the present invention as described above, the aluminum alloy surrounding the conductor (1), the insulating layer (3) insulated with crosslinked polyethylene surrounding the conductor (1), the aggregate of the insulating layer composed of a plurality of the insulating layer (3). It is achieved by the high flame retardant low-combustion marine cable (9) characterized in that the braid layer 5, the sheath layer (7) surrounding the braid layer (5) and the composition for the sheath used therein.

The technical field of the present invention is the International Elecrotechnical Commission (IEC) 332-3 cat. A For ship cable construction and flame retardant sheathing materials determined to be flame retardant class.

The present invention relates to a marine cable having a structure that is different from the existing marine product structure or innovative structure, and applied a crosslinked polyethylene insulating layer (3) instead of the ethylene propylene rubber (EPR) insulating layer 13 of the existing invention, The polyvinyl chloride (PVC) bedding layer 15 was removed. In addition, copper braids were replaced with aluminum alloys to reduce the weight of the cables. The innovation of the structural design invented a cable having a 30% outer diameter and a 50% weight reduction compared to the conventional ship cable 21. In addition, the innovation of the cable structure could increase the profit margin by more than 20%.

In the present invention, a thermoplastic halogen-free material having excellent flame retardancy and low smoke resistance is applied to the sheath layer 7 of the outer layer in order to secure flame retardant properties and to develop an environmentally friendly cable. By applying the flame retardant material of the present invention, it was possible to satisfy the low smoke characteristics (IEC 1034) that could not be obtained in the existing technology. In particular, the low smoke test in the invention is an evaluation of the finished cable product, it is difficult to pass the test only by the low smoke properties of the flame retardant material, it is said that the application of a flame retardant material having excellent design ability, flame retardancy and smoke resistance to the cable structure is important.

In the present invention, flame retardancy and low smoke performance were satisfied by blending a base resin having a polar group with an inorganic flame retardant and an organic flame retardant, which is different from the conventional technology. Particularly, in the present invention, polar polyethylene, polar ethylenevinyl acetate, and ethylenevinyl acetate are used as base resins, and a hydrated metal compound is added as a main flame retardant, and a silicone-based flame retardant is improved in flame retardancy and smoke. Used for density suppression.

The polar resins applied to the present invention had an oxygen index of 3% or more higher than that of the non-polar resin, and the amount of smoke released was about half of that of the non-polar resin. In addition, the solidification of the carbonized layer during combustion was accelerated, and the phenomenon that the ash layer hardened down was remarkably suppressed.

In the technique of the present invention, a silicone-based flame retardant, especially a mixture of high molecular weight silicone and polyolefin, is applied to suppress the smoke density and to promote the solidification of char by combustion and to maximize the effect of hardening ash. . In order to secure the main flame retardant, silane-treated aluminum hydroxide, hunite and hydromagnesite were used. The mixed effect of the main flame retardant was superior to the char-forming or low smoke characteristics compared to the conventional flame retardant magnesium magnesium or aluminum hydroxide.

As a characteristic of the flame retardant material of the present invention, a flame retardant material excellent in flame retardancy and low smoke characteristics, which is differentiated from existing materials, was applied by applying a base resin containing a polar group. And, by applying the above flame retardant material as the material of the sheath layer 7 of the ship cable, the International Elecrotechnical Commission (IEC) 332-3 cat. The flame retardant grade of A and the low smoke characteristics of IEC 1034 could be satisfied.

Other objects, specific advantages and novel features of the present invention will become more apparent from the following detailed description and the preferred embodiments associated with the accompanying drawings.

1 is a cross-sectional view of a high flame retardant low smoke vessel cable 9 structure according to an embodiment of the present invention.

2 is a cross-sectional view of a conventional ship cable 21 structure.

<Description of Signs of Major Parts of Drawings>

1: conductor

3: insulation layer

5: braided layer

7: sheath layer

9: high flame retardant ship cable

11: conductor

13: ethylene propylene rubber (EPR) insulation layer

15: polyvinyl chloride (PVC) bedding layer

17: galvanized steel wire braided layer

19: polyvinyl chloride (PVC) sheath layer

21: conventional ship cable

Hereinafter, the structure of the highly flame-retardant low-combustion marine cable 9 and its composition for a sheath will be described.

1 is a cross-sectional view of a high flame retardant low smoke vessel cable 9 according to an embodiment of the present invention. As shown in FIG. 1, the conductors 1 consist of an aggregate of twisted pairs or of an aggregate of unit conductors 1. The aggregates of the conductors 1 are bundled together to form the core of the high flame retardant ship cable 9.

The present invention relates to a highly flame-retardant low-smoked marine cable (9) having a differentiation or innovative structure from that of the conventional marine cable (21) product structure as shown in FIG. 2 and insulated polyethylene crosslinked on the conductor (1). It was applied as the material of layer 3. Then, the conventional polyvinyl chloride (PVC) bedding layer 15 was removed. Also, to reduce the weight of the cable, the conventional galvanized steel wire braided layer 17 has been replaced with a braided layer 5 composed of aluminum alloy.

The International Elecrotechnical Commission (IEC) 332-3 cat. On the braided layer (5). A non-toxic non-halogen flame retardant material satisfying the flame retardant grade of A and the low smoke characteristics of IEC 1034 was applied as the sheath layer (7). In the present invention, the sheath layer 7 of the outer layer is composed of a thermoplastic halogen-free material having excellent flame retardancy and low smoke resistance in order to secure flame retardant properties of the cable and to invent an environmentally friendly cable.

In the present invention, the composition of the sheath layer 7 is as follows.

The composition of the flame retardant material having high flame retardancy and low smoke characteristics is a mixed base resin of ethylenevinyl acetate, polar ethylenevinyl acetate with polar group and polar polyethylene with polar group. 100 to 180 parts by weight of the hydrated metal compound, 0.1 to 5 parts by weight of lubricant and processing aid, 0.1 to 5 parts by weight of antioxidant, and 1 to 10 parts by weight of organic additive which is a flame retardant aid.

The flame retardant material of the present invention was used by mixing three different resins having different physical properties, chemical structures and crystallization structures as base resins. Ethylene vinyl acetate was used up to 50 to 90 parts by weight with respect to 100 parts by weight of the base resin mixed with three species. Vinyl acetate content of ethylene vinyl acetate was applied to 14 to 33 parts by weight. When the content of ethylene vinyl acetate was 50 parts by weight or less, flame retardancy was lowered and elongation was lowered in mechanical properties. In addition, at 90 parts by weight or more, the properties after heating at 100 ° C. were significantly reduced, and the tensile strength value was low among the mechanical properties.

Polar ethylenevinyl acetate (polar ethylenevinyl acetate) was introduced to improve the flame retardancy, mechanical properties and thermal properties. Then, 0.5 to 2 parts by weight of a polar group was introduced into ethylene vinyl acetate. In 100 parts by weight of the three kinds of mixed base resin, ethylene vinyl acetate having a polar group introduced was applied to 3 to 20 parts by weight. When the applied amount was 3 parts by weight or less, it was not expected to improve flame retardancy, low smoke properties, mechanical properties and thermal properties, and elongation was lowered at 20 parts by weight or more.

Examples of the polyethylene resin into which the polar group is introduced include linear low density polyethylene, low density polyethylene, medium density polyethylene, and high density polyethylene. And about 0.3-1.5 weight part of polar groups were introduce | transduced into polyethylene resin. Polyethylene introduced with a polar group was applied to 3 to 40 parts by weight of 100 parts by weight of the base resin mixed with three species. When the applied amount was 3 parts by weight or less, it was not expected to improve the flame retardancy, low smoke, mechanical properties and thermal properties, and more than 20 parts by weight showed elongation and flame retardancy.

100-180 parts by weight of two kinds of metal hydride compounds were used based on 100 parts by weight of the resin. Flame retardancy was not secured at 100 parts by weight or less of the metal hydride compound, and workability and elongation were lowered at 180 parts by weight or more. In order to satisfy the flame retardancy and low smoke characteristics of the material of the present invention, a hydrated metal compound was used by mixing aluminum hydroxide and huntite / hydro magnesite surface-treated with silane.

In the present invention, the surface treatment of aluminum hydroxide with silane promoted the workability and solidification of the carbonized layer. 30 to 150 parts by weight of aluminum hydroxide was used. Below 50 parts by weight, the synergistic effect of flame retardation and the solidification of the carbonized layer were not obtained with the mixed fumedite and hydromagnesite mixed flame retardants. At 150 parts by weight or more, the effect of flame retardation by a large amount of aluminum hydroxide was not large.

In the present invention, 30 to 150 parts by weight of the mixed futonite and hydromagnesite was used. Below 30 parts by weight, the synergistic effect of flame retardation due to the mixing of hydration compounds was small and there was no effect on the decrease of the smoke concentration. Moreover, at 150 weight part or more, mechanical strength fell and solidification of the carbonized layer was small. In the present invention, a high flame retardant material having an oxygen index of 40% was invented by applying a resin and a hydrating compound in which a polar group was introduced.

In the technique of the present invention, an organic flame retardant, particularly a silicone-based flame retardant aid, which has an effect of suppressing smoke density and promoting solidification of char by combustion and hardening ash is applied. 1 to 10 parts by weight of an organic flame retardant as a flame retardant aid was used. When the content of the organic flame retardant was less than 1 part by weight, the effect of suppressing smoke density and promoting the solidification of char (char) could not be expected. On the other hand, the flame retardancy and smoke suppression effect also decreased.

0.1 to 5 parts by weight of the lubricant and the processing aid were used. If the lubricant content is 0.1 parts by weight or less, it is not expected to improve the workability such as lowering of the viscosity of the material, and more than 10 parts by weight of the flame retardancy and tensile strength was lowered.

Base resins and flame retardants described above are described in International Elecrotechnical Commission (IEC) 332-3 cat. During the class A flame retardant test, the shape of the carbonized layer was maintained to play an important role in determining the results of the flame retardant test. It also played an important role in determining the low smoke characteristics of IEC 1034.

Hereinafter will be described the operation and the embodiment for the high flame retardant ship cable 9 of the present invention having the configuration as described above.

In Examples 1 to 3, ethylenevinyl acetate, polar ethylenevinyl acetate having a polar group and polar polyethylene having a polar group were used as a matrix of the base resin. Used. In particular, the effects of matrix resin on flame retardancy, low smokeability and thermal properties were investigated. In order to promote solidification of the carbonized layer and suppress the smoke concentration in the matrix resin, silicon-based organic flame retardant was used as a flame retardant and auxiliary flame retardant. And glidants and antioxidants were applied.

Examples 4 to 6 show the effects of the ethylene vinyl acetate having a polar group and the polyethylene having the polar group introduced therein among the matrix resins. And, flame retardants and additives as in Examples 1 to 3 were applied.

In Comparative Examples 1 and 2, flame retardants such as aluminum hydroxide and huntite / hydromagnesite were applied to the matrix resin as in Examples 1 and 2 alone. In addition, zinc borates, which are known to promote low smoke properties and solidification of the carbonized layer during combustion, were applied as flame retardant aids. In Comparative Example 3, ethylenevinyl acetate was compared with ethyleneethyl acrylate. In Comparative Examples 4 to 5, medium-density polyethylene was applied in place of the polyethylene in which polar groups were introduced into the matrix resins, and flame retardancy, smokeability, and thermal characteristics were compared with the examples.

The flame retardant materials mentioned in the above examples were mixed in an open roll and then molded at 170 ° C. for 5 minutes to prepare test specimens for evaluation of properties. In addition, after manufacturing a conventional ship cable 21 having a structure as shown in Figure 2 (International Elecrotechnical Commission (IEC) 332-3 cat. A flame retardant test was performed.

<Example>

Composition by weight of each component Example Comparative example One 2 3 4 5 6 One 2 3 4 5 Ethylene Vinyl Acetate 80 70 70 80 70 80 80 70 - 70 80 Ethylene ethyl acrylate - - - - - - - - 70 - - Polar group-introduced ethylene vinyl acetate 10 10 10 20 - - 10 10 10 10 - Polar Group Introduced Polyethylene 10 20 20 - 30 20 10 20 20 - - Medium Density Polyethylene - - - - - - - - - 20 20 Aluminum hydroxide 100 100 60 100 120 100 - 160 100 120 100 Huntite and Hydromagnesite 60 60 100 60 60 60 160 - 60 60 60 Silicone Organic Flame Retardant 5 5 5 - 5 5 - - - - 5 Zinc borate - - - - - - 5 5 5 - - Lubricant 2 2 2 2 2 2 2 2 2 2 2 Antioxidant One One One One One One One One One One One

In Examples 1 to 6, ethylenevinyl acetate, ethylenevinyl acetate having a polar group and polyethylene having a polar group were used as a matrix resin, and aluminum hydroxide and huntite / hydromagnesite were mixed as a flame retardant, and a smoke density inhibitor was used. In the case of applying a silicone-based compound as a flame retardant aid, the smoke density test was carried out according to the American Society for Testing Materials (ASTM) standard, and the flaming method obtained less than half of the comparative example.

From these results, it was found that the effect of suppressing the smoke density of the hydrated metal compound and the smoke density inhibitor mixed with the resin having the polar group applied to the present invention was great. As a result of the flame-retardant test of the cable applying the same material as the embodiment of the present invention, the combustion length showed the combustion characteristics of less than 1.5 meters. However, when the same general polyolefin (ethylene) and ethylene ethyl acrylate (ethylene-ethyl acrylate) resin or aluminum hydroxide alone is applied as a comparative example, the flame retardant performance was not satisfied.

The compositions of the present invention exhibited superior mechanical properties compared to existing compositions. In addition, it can be seen that the thermal properties of the compositions of the present invention is also excellent. The flame retardant system applied to the present invention exhibited a higher oxygen index value than the zinc borate or organic halogen flame retardant, which was used as a conventional flame retardant, and exhibited a high oxygen index value and solidified shape in carbonized ash. Showed.

Physical property evaluation of each example Test Items Example Comparative example One 2 3 4 5 6 One 2 3 4 5 IEC 332-3cat. A ^(a) Combustion length (m) 1.3 1.5 1.2 1.0 1.2 1.3 Burned down Burned down Burned down Burned down Burned down Smoke density ^(b) Flaming 92 114 123 131 117 101 342 334 272 258 265 Room temperature characteristic ^(c) Tensile Strength (fg / ㎡) 1.34 1.42 1.36 1.44 1.21 1.27 1.32 1.37 1.14 1.11 1.03 Elongation (%) 187 169 173 168 174 182 167 173 155 121 113 Heat resistance ^(d) Tensile residual rate 99.7 100 10.3 94.3 92.8 94.5 98.7 94.1 99.6 96.4 97.7 Elongation 87.1 88.7 88.3 81.5 85.4 86.7 84.6 85.2 88.8 74.4 72.8 Smoke ^(e) Pass Pass Pass Pass Pass Pass Under Under Under Under Under Oxygen index (%) ^(f) 39 38 39 40 40 38 33 31 28 35 33

(a) Flame retardant: International Elecrotechnical Commission (IEC) 332-3 cat. The test was conducted according to the flame retardant test standard of A. Add 70,000 B. T. U./hr of heat for 40 minutes. After combustion test, the combustion length of cable should be less than 2.44m.

(b) Smoke density: evaluated according to American Society for Testing Materials (ASTM) E662 (heat flux; 2.5 W / cm 2) Specimen size; 7.5 cm × 7.5 cm × 3 mm

(c) Room temperature characteristics: Tensile strength and elongation were measured according to ASTM D638.

(d) Heat resistance characteristics: Elongation was measured after heat treatment at 100 ° C. for 168 hours according to ASTM D638.

(e) Flammability: The cable was tested in accordance with IEC 1034. Transmittance should be over 60%.

(f) Oxygen Index: Tested according to ASTM D2863.

According to the high flame-retardant low-combustion marine cable 9 according to the present invention as described above, compared to the conventional marine cable 21, the 30% reduction in outer diameter and 40% in weight reduced the product, (International Elecrotechnical Commission; IEC) 332-3 cat. A remarkable effect is to form a thermoplastic sheath layer having excellent flame retardancy and low flame retardancy of IEC 1034 and excellent flame retardancy. Therefore, the safety of human life protection and equipment loss in case of fire in offshore structures and ships has been improved compared to the prior art, and the profitability of the conventional ship cable 21 could be increased by 20% or more.

Although the present invention has been described in connection with the above-mentioned preferred embodiments, it is possible to make various modifications or variations without departing from the spirit and scope of the invention. Accordingly, the appended claims include such modifications and variations as fall within the spirit of the invention.

Claims (13)

Conductor 1; An insulating layer (3) insulated with crosslinked polyethylene surrounding the conductor (1); A braided layer 5 braided with aluminum alloy surrounding an aggregate of insulating layers composed of a plurality of said insulating layers 3; And A sheath layer 7 surrounding the braided layer 5 comprising ethylene vinyl acetate, polar ethylenevinyl acetate introduced with a polar group and polar polyethylene introduced with a polar group as a base resin; A high flame retardant ship cable characterized in that. The composition of claim 1, wherein the composition of the sheath layer (7) is 100 wt% of a matrix resin based on ethylene vinyl acetate, polar ethylenevinyl acetate having a polar group and polar polyethylene having a polar group introduced therein. A high flame retardant low-flammable ship cable comprising 100 to 180 parts by weight of a hydrated metal compound, 0.1 to 5 parts by weight of lubricant and processing aid, 0.1 to 5 parts by weight of antioxidant, and 1 to 10 parts by weight of a silicon-based organic flame retardant. According to claim 2, wherein the base resin is a high flame retardant low-combustion marine cable, characterized in that consisting of 50 to 90 parts by weight of ethylene vinyl acetate with respect to 100 parts by weight of the base resin mixed with two or three different resins. The cable of claim 3, wherein the content of vinyl acetate is 14 to 33 parts by weight based on 100 parts by weight of ethylene vinyl acetate. The cable of claim 2, wherein the ethylene vinyl acetate into which the polar group is introduced is composed of 3 to 20 parts by weight. The cable of claim 5, wherein the polar group content is 0.5 to 2 parts by weight based on 100 parts by weight of the ethylene vinyl acetate into which the polar group is introduced. The cable of claim 2, wherein the polyethylene having the polar group is introduced comprises 3 to 40 parts by weight. 8. The cable of claim 7, wherein the polar group content is 0.3 to 1.5 parts by weight based on 100 parts by weight of the polyethylene having the polar group introduced therein. The high flame retardant low-flammable marine cable according to claim 8, wherein the polyethylene having the polar group introduced therein is made of linear low density polyethylene, low density polyethylene, medium density polyethylene, or high density polyethylene. 3. The cable of claim 2, wherein the hydrated metal compound is composed of 100 to 180 parts by weight of a mixture of aluminum hydroxide and hoonite / hydromagnesite. The cable of claim 10, wherein the aluminum hydroxide is composed of 30 to 150 parts by weight of aluminum hydroxide surface-treated with vinylsilane or aminosilane. 12. The cable of claim 10 or 11, wherein the huntite / hydromagnesite in the mixture is composed of 30 to 150 parts by weight. 100 parts by weight of a matrix resin based on ethylene vinyl acetate, polar ethylenevinyl acetate having a polar group and polar polyethylene having a polar group; 100 to 180 parts by weight of a metal hydride compound; 0.1 to 5 parts by weight of lubricant and processing aid; 0.1 to 5 parts by weight of antioxidant; And 1 to 10 parts by weight of a silicon-based organic flame retardant; high flame retardant low-flammable marine cable sheath composition.