KR100351975B1 - Opto-acoustic gas analyzer - Google Patents

Abstract

The present invention relates to a photoacoustic sensor for measuring the emission gas, in particular in the precise analysis of the components of a particular gas contained in the exhaust gas, such as automobiles, the photoacoustic signal transmitted differently for each gas to a plurality of microphones It relates to a device for measuring and producing a precise analysis result.

In order to achieve the object of the present invention, an infrared light source for irradiating infrared rays, a chopper for collecting the infrared light emitted from the infrared light source and modulating it into a pulse form, and passing only light of a specific wavelength of the infrared light passing through the chopper A light emitting unit configured as a narrowband filter and a gas to be measured are injected, and a sample cell through which light from the narrowband filter passes, and a gas component connected to the narrowband filter and constituting the sample gas is not contained in the body. Standard gas is injected, and the standard cell through which light from the narrow-band filter passes, and the gas containing the same components as the gas constituting the sample gas inside the body and connected to the sample cell are already known. A first reference gas into which a first reference gas is injected and light from the narrow-band filter passes And a second reference gas which is connected to the standard cell and has the same concentration as a gas containing the same component as the gas constituting the sample gas in the body, but has a concentration different from or equal to that of the first reference gas. Is injected into the second reference gas cell through which light from the narrow band pass filter passes, and is attached to an end wall of the first reference gas cell and re-reflects the light irradiated into the body of the first reference gas cell. An optical cell unit comprising a first reflecting mirror and a second reflecting mirror attached to an end wall of the second reference gas cell and reflecting light irradiated into the body of the second reference gas cell;

A sample cell microphone attached to the sample cell and detecting the photoacoustic of the sample gas and converting the photoacoustic into a form of an alternating voltage; and a photocell attached to the first reference cell and detecting the photoacoustic of the first reference gas. A first reference cell microphone for converting to a form of a second reference cell, a second reference cell microphone attached to the second reference cell for detecting an optoacoustic sound of the second reference gas and converting the photoacoustic into a form of an alternating voltage; A reference cell microphone attached to the second reference cell for detecting the photoacoustic sound of the standard gas and converting the photoacoustic signal into an alternating voltage, and between the sample cell and the first reference cell. A first piezoelectric sensor for detecting a differential pressure of the liver and converting it into a form of an alternating voltage, and attached between the standard cell and the second reference cell; And the second detector consisting of two piezo sensor that converts the form of the second reference cell to the AC voltage it detects a pressure difference between;

It is electrically connected to the chopper and the detector, and provides a photoacoustic sensor for exhaust gas measurement including a signal processor for removing and amplifying a noise component of the AC voltage sensed by the detector and converting it back to a DC voltage.

Description

Opto-acoustic gas analyzer for exhaust gas measurement

The present invention relates to a photoacoustic sensor for exhaust gas measurement, and more particularly, to a plurality of microphones for photoacoustic signals transmitted differently for each gas in precisely analyzing a component of a specific gas included in the exhaust gas of an automobile. The present invention relates to a device for producing an analysis result after receiving an incoming call.

Exhaust gases such as automobiles generally contain various gas components such as CO, CO ₂ , SO _X , NO _X , HC, H ₂ O, and some of these gases also serve as pollutants that cause air pollution. .

However, as the recent serious environmental pollution and the provision of countermeasures have emerged as a very small concern, the regulation of the pollutant sources is gradually discussed in detail. This is a very natural phenomenon considering that emissions are the biggest source of air pollution. At this time, the essential procedure required in preparing a regulation for automobile emissions is to analyze the composition and concentration of the emissions.

In order to analyze the composition and concentration of the exhaust gas as described above, an infrared sensor (IR) using a photodiode is conventionally used.

1 is an infrared sensor according to the prior art.

The infrared sensor is composed of an infrared light source 110, a sample cell 120, a narrowband filter 130, and a photodiode 140.

The infrared light source 110 irradiates infrared rays into the sample cell 120, and a sample gas to be analyzed is injected into the sample cell 120. The narrowband filter 130 filters only light having a specific wavelength among infrared rays passing through the sample cell 120. In addition, the photodiode 140 measures illuminance of light passing through the narrowband filter 130.

The infrared sensor is made by focusing on the property that a specific gas absorbs only light having a specific wavelength. When the infrared light is irradiated from the infrared light source 110 while injecting the sample gas into the sample cell 120, the sample The gas only absorbs light of a certain wavelength. In this case, when the narrow band filter 130 to filter only the light of the wavelength band absorbed by the sample gas, the photodiode 140 is far less light than the infrared light irradiated from the infrared light source 110 in the first place Will be detected.

The observer can determine the gas content contained in the sample gas by analyzing which wavelength range the light intensity has decreased.

In addition, the concentration of the gas contained in the sample gas can be obtained according to the Bear's law.

Bear's law

_{I t = I o · EXP (} -A · C · L),

I _o = ΔI + I _t

Wherein I _o is the illuminance of the infrared light emitted from the infrared light source 110, I _t is the illuminance of the light detected by the photodiode 140, A is the absorption coefficient of the sample gas, and C is the sample gas. The concentration, L represents the length of the sample cell 120, ΔI represents the absorbance of the sample gas.

In the case of the infrared sensor, since the values corresponding to I _t , I _o , A, and L are already known, substituting these values into the Beer's law yields the other factor C, that is, the concentration of the sample gas. Will be.

However, when the concentration C of the sample gas is low, the infrared sensor has a low concentration because the absorbance amount ΔI of the sample gas is relatively insignificant compared to the illuminance I _t irradiated from the infrared light source 110. This has the disadvantage that the measurement accuracy at is significantly reduced.

Accordingly, in order to increase the measurement accuracy at low concentration, the length L of the sample cell 120 is inevitably increased, but in this case, the length of the sample cell 120 that can be extended in manufacturing the equipment is limited. Can't be.

As a result, the infrared sensor has a certain degree of measurement reliability when the sample gas concentration is 1 ppm or more.

In order to solve the problem of the infrared sensor, a non-dispersive infrared sensor (NDIR) (not shown) has recently been developed.

The non-dispersion infrared sensor has improved the detection limit of the photodiode 140 in order to increase the measurement accuracy at low concentration, according to the improved form of the non-dispersion infrared sensor of the quantum type, pyroelectric type, photoacoustic detection type It can be divided into three.

However, the quantum non-dispersion infrared sensor must have a cooling device, the pyroelectric non-dispersion infrared sensor uses only a piezo sensor has a disadvantage in that the structure is complicated and expensive.

In addition, the photoacoustic detection type non-dispersive infrared sensor uses a microphone, in which case there is also a problem in the measurement reliability of the individual cell structure and placement of the microphone.

That is, the photoacoustic detection type non-dispersive infrared sensor generally has one sample cell and one reference cell, and only one microphone is attached to the reference cell, and the microphone is generated between the sample cell and the reference cell. It measures the diaphragm differential pressure, which is measured in that it measures only the relative optoacoustic difference between the sample cell and the reference cell, not the absolute photoacoustic value generated in the sample cell and the reference cell. There is a limit to reliability.

In addition, the photoacoustic detection type non-dispersion infrared sensor is a problem because the noise existing when measuring the photoacoustic of the sample gas affects the photoacoustic of the sample gas.

The present invention has been conceived to solve the above problems of the prior art, and an object of the present invention is to provide a photoacoustic sensor for exhaust gas measurement with a simple structure and very high measurement reliability at low concentrations.

1 is a view showing an infrared sensor according to the prior art.

2 is a view showing a photoacoustic sensor for measuring exhaust gas according to the present invention.

Figure 3 is a view showing a signal processing process in the signal processing unit of the photoacoustic sensor for measuring the exhaust gas in accordance with the present invention.

* Brief description of symbols for the main parts of the drawings *

110: infrared light source 120: sample cell

130: narrow band filter 140: photodiode

210: light emitting unit 220: optical cell unit

230: detector 240: signal processor

In order to achieve the above object, the present invention passes only an infrared light source for irradiating infrared rays, a chopper for collecting the infrared light emitted from the infrared light source and modulating it into a pulse form, and only light of a specific wavelength of the infrared light passing through the chopper A light emitting unit comprising a narrow band filter; A sample cell is connected to the narrowband filter and is injected into the body, and a sample cell through which light from the narrowband filter passes, and a gas component connected to the narrowband filter and constituting the sample gas is provided in the body. A standard cell that contains no standard gas is injected and light from the narrowband filter passes, and a gas which is connected to the sample cell and contains the same components as the gas constituting the sample gas inside the body, and the concentration is already known. A first reference gas into which the first reference gas is injected and the light from the narrowband filter passes, and a concentration of the first reference cell connected to the standard cell and the same component as the gas constituting the sample gas in the body. Although the second reference gas having a concentration different from the concentration of the first reference gas is introduced into the narrow A second reference cell through which light from the inverse filter passes, a first reflection mirror attached to an end wall of the first reference cell and re-reflecting light irradiated into the body of the first reference cell, and the second An optical cell unit attached to an end wall of the reference cell and configured of a second reflecting mirror to reflect back light irradiated into the body of the second reference cell; A sample cell microphone attached to the sample cell and detecting the photoacoustic of the sample gas and converting the photoacoustic into a form of an alternating voltage; and a photocell attached to the first reference cell and detecting the photoacoustic of the first reference gas. A first reference cell microphone for converting into a form of a second reference cell, a second reference cell microphone attached to the second reference cell for detecting an optoacoustic sound of the second reference gas and converting it into an AC voltage form; A reference cell microphone attached to the second reference cell and detecting the photoacoustic sound of the standard gas and converting the photoacoustic signal into an AC voltage; and between the sample cell and the first reference cell. A first piezoelectric sensor for detecting a differential pressure between the reference cell and converting it into a form of an alternating voltage, and attached between the standard cell and the second reference cell; A detector comprising a second piezo sensor for detecting a differential pressure between two reference cells and converting the pressure into a form of an AC voltage; It is electrically connected to the chopper and the detection unit provides a photoacoustic sensor for exhaust gas measurement including a signal processing unit for removing and amplifying a noise component of the AC voltage sensed by the detection unit and converts it back to a DC voltage.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

2 is a view showing a photoacoustic sensor according to the present invention.

The photoacoustic sensor and the light emitting unit 210; An optical cell unit 220; A detector 230; It is composed of a signal processor 240.

The light emitting unit 210 and the infrared light source (210a); A chopper 210b; It consists of a narrow-band filter 210c, and serves to irradiate ultraviolet light of a specific wavelength to the optical cell unit 220.

At this time, the infrared light source 210a, the chopper 210b, and the narrowband filter 210c are preferably located in this order.

The infrared light source 210a emits infrared rays to be irradiated to the optical cell unit 220. For this purpose, the infrared light source 210a generally uses a nichrome wire or a carbon rod heated.

The chopper 210b modulates the infrared rays in the form of pulses in order to collect the infrared rays generated from the infrared light source 210a and to correspond to the frequency of the photoacoustics detected by the detector 230 and the signal processor 240. Device.

That is, since the holes through which the light can pass are arranged in the chopper 210b at regular intervals, as the chopper 210b rotates, the light is repeatedly passed or blocked at a predetermined time interval. The light received by the cell unit 220 is in the form of a pulse.

Therefore, the gas injected into the optical cell unit 220 absorbs light when it passes through the chopper 210b and irradiates the optical cell unit 220 to generate photoacoustic sounds, and conversely, the light is the chopper 210b. If the light is not blocked by the optical cell unit 220 and does not react, the photoacoustic detected by the detector 230 and the signal processor 240 also has a pulse shape. At this time, the frequency of the light passing through the chopper 210b and the photoacoustic frequency detected by the detector 230 and the signal processor 240 are the same.

The narrowband filter 210c passes only light having a specific wavelength among infrared rays generated from the infrared light source 210a.

Accordingly, the gas injected into the optical cell unit 220 absorbs the light having the wavelength of light passing through the narrow band filter 210c in the absorbable region, thereby generating photoacoustics, and conversely, the narrow band filter 210c. If the wavelength of the light passing through) is not in the absorbable region, no reaction is performed, and thus the observer can determine the type of gas injected into the optical cell unit 220, and at the same time, the photoacoustic generated by the gas By measuring the intensity of the gas concentration can be found.

The optical cell unit 220 and the sample cell 220a; A first reference cell 220b; A second reference cell 220c; A standard cell 220d; A first reflection mirror 220e; And a second reflecting mirror 220f.

The sample cell 220a and the first reference cell 220b are connected to each other to form a group, and the standard cell 220d and the second reference cell 220c are connected to each other to form a group.

The first reflecting mirror 220e is attached to the end wall of the first reference cell 220b, and the second reflecting mirror 220f is attached to the end wall of the second reference cell 220c.

The light emitted from the infrared light source 210a is divided into two branches to pass through the sample cell 220a, the first reference cell 220b, the standard cell 220d, and the second reference cell 220c, respectively. do.

Sample gas is injected into the sample cell 220a, wherein the sample gas means a gas whose concentration is measured by the photoacoustic sensor according to the present invention.

A first reference gas is injected into the first reference cell 220b, and a second reference gas is injected into the second reference cell 220c, wherein the reference gas is a gas whose concentration is known. It means a gas consisting of and the same kind of gas. Meanwhile, the first reference gas and the second reference gas should have different concentrations.

The standard gas is injected into the standard cell 220d, wherein the standard gas means a gas composed of pure air or pure nitrogen gas and preferably containing no gas component constituting the sample gas. .

The first reflecting mirror 220e and the second reflecting mirror 220f serve to reflect back the light irradiated to the optical cell unit 220 in the opposite direction, which is the light within the optical cell unit 220. The purpose of this is to provide abundant opportunities for gas molecules to absorb light energy, while at the same time saving the energy required for the infrared light source 210a to emit infrared light.

The sample gas and the reference gas absorb light to generate photoacoustics with intensity proportional to their respective concentrations. On the other hand, the standard gas generates photoacoustics consisting of only noise components generated by interference of light, H ₂ O contained in the gas, vibration, ambient noise, and the like.

The detector 230 includes a sample cell microphone 230a; A first reference cell microphone 230b; A second reference cell microphone 230c; A standard cell microphone 230d; A first piezo sensor 230e; It consists of the 2nd piezo sensor 230f.

The sample cell microphone 230a is attached to the sample cell 220a, and detects the photoacoustic sound of the sample gas and converts it into the form of an AC voltage.

The first reference cell microphone 230b is attached to the first reference cell 220b, and the second reference cell microphone 230c is attached to the second reference cell 220c. 230b and the second reference cell microphone 230c detect the photoacoustic sound of the reference gas injected into each reference cell and convert it into the form of an AC voltage.

The standard cell microphone 230d is attached to the standard cell 220d, and detects the photoacoustic sound of the standard gas and converts it into the form of an AC voltage.

The first piezo sensor 230e is attached between the sample cell 220a and the first reference cell 220b to detect a differential pressure between the sample cell 220a and the first reference cell 220b. The second piezoelectric sensor 230f is attached between the standard cell 220d and the second reference cell 220c so as to be converted into an AC voltage, and the standard cell 220d and the second reference cell ( The differential pressure between 220c) is detected and converted into the form of AC voltage.

The differential pressure detected by the first piezo sensor 230e is a difference between a pressure detected by the sample cell microphone 230a and a pressure detected by the first reference cell microphone 230b (hereinafter, referred to as an “photoacoustic difference”). If the differential pressure and the photoacoustic difference are different from each other, it is evidence that either the sample cell microphone 230a or the first reference cell microphone 230b is malfunctioning. In addition, the differential pressure detected by the second piezoelectric sensor 230f is a difference between the pressure detected by the standard cell microphone 230d and the pressure detected by the second reference cell microphone 230c (hereinafter, referred to as “photoacoustic difference”). If the differential pressure and the optoacoustic difference are different from each other, it is evidence that either the standard cell microphone 230d or the second reference cell microphone 230c is malfunctioning.

As a result, the first piezoelectric sensor 230e and the second piezoelectric sensor 230f include the sample cell microphone 230a, the first reference cell microphone 230b, the second reference cell microphone 230c, It supplements the detection result of the standard cell microphone 230d and checks whether they are malfunctioning.

The signal processor 240 is electrically connected to the chopper 210b and the detector 230, removes and amplifies noise components of the AC voltage sensed by the detector 230, and converts the noise components to DC voltage again. .

Hereinafter, a process of measuring the concentration of the sample gas with the photoacoustic sensor according to the present invention will be described in detail with reference to FIG. 3.

3 is a diagram illustrating a signal processing process in the signal processor 240 according to the present invention. In each graph of FIG. 3, the X axis represents time and the Y axis represents voltage. On the other hand, the reference numerals 1, 2, 3, 4, 5 and 6 shown in Fig. 2 and the reference numerals 1, 2, 3, 4, 5 and 6 shown in Fig. 3 correspond to each other.

Graph ① shows the ultraviolet rays of the pulse form passing through the chopper 210b, a portion that is repeated at regular intervals in the form of a square corresponds to the case where the ultraviolet rays pass through the chopper 210b. Graphs ②, ③, ④, and ⑤ form pulses with the same frequency as graph ①. This is because the gas contained in each cell of the optical cell unit 220 can absorb energy only when light passes through the chopper 210b.

Graph ② shows the photoacoustic sound in the form of pulses detected by the sample cell microphone 230a, graph ③ shows the photoacoustic sound in the form of pulses detected by the first reference cell microphone 230b. The photoacoustic sound of the pulse form detected by the second reference cell microphone 230c is shown, and the graph? Shows the photoacoustic sound of pulse form detected by the standard cell microphone 230d.

The thread-shaped signal constituting the upper end of the pulse of each graph means noise.

The graph ⑥ shows the result of removing the noise from the AC signal shown in the graphs ②, ③, and ④, amplifying it, and then modulating the signal into a DC signal.

At this time, the method of removing the noise is a correction to remove only the noise component shown in the graph ⑤ in the graphs (2), (3) and (4). In other words, if you go through the process of graph ②-graph ⑤, graph ③-graph ⑤, graph ④-graph ⑤, you can obtain a noise-free graph with a straight line of pulse. In addition, a method of modulating an AC signal into a DC signal is to connect only the rectangular portions of the graphs ②, ③, and ④ from which the noise is removed. By going through the above process, the graphs 2, 3, and 4 are converted into a linear graph having one voltage value corresponding to each gas concentration.

The method for measuring the concentration of the sample gas in the above state is as follows.

The concentration of the sample gas to be obtained is referred to as C _S , and the voltage value according to the photoacoustic measurement of the measured sample gas is referred to as V _S. The concentration of the first reference gas is referred to as C _R1 , and the voltage value according to the photoacoustic measurement of the measured first reference gas is referred to as V _R1 . The concentration of the second reference gas is referred to as C _R2 , and the measured voltage value according to the photoacoustic sound of the second reference gas is referred to as V _R2 .

Now, with the concentration of gas as the X value and the voltage as the Y value, the C _R1 and the C _R2 are shown on the X axis, and the V _R1 and the V _R2 are shown on the Y axis, where (C _R1 , V One straight line is formed by two points, _R1 ) and (C _R2 , V _R2 ). On the other hand, since V _S is a known value, substituting it into the Y value of the straight line can calculate C _S, which is an X value to be obtained.

Although the embodiments of the present invention have been described above, this is only an example, and the spirit of the present invention is not limited thereto. Therefore, various changes and modifications may be made. However, it will be understood through the appended claims that such changes and modifications fall within the scope of the present invention.

By practicing the present invention, since the observer directly measures the absolute photoacoustic values of the sample gas and the reference gas, the accuracy of the measurement result is higher than in the conventional method of measuring only the differential pressure, that is, the relative photoacoustic value between the sample gas and the reference gas. Get the effect.

In addition, the photoacoustic sensor according to the present invention mathematically calculates the concentration of the sample gas from a plurality of reference gases whose concentration is already known, and detects whether the microphone is malfunctioning as a piezo sensor, so the measurement result is very accurate.

In addition, since the photoacoustic sensor according to the present invention removes noise affecting the photoacoustics of the sample gas and the reference gas, accurate measurement is possible even if the concentration of the gas is very low.

Claims (1)

An infrared light source for irradiating infrared rays, A chopper for collecting the infrared rays irradiated from the infrared light source and modulating them in a pulse form; A light emitting unit comprising a narrow band filter for passing only light having a specific wavelength among infrared rays passing through the chopper; A sample cell connected to the narrowband filter and injected with a sample gas to be measured in the body, and through which light from the narrowband filter passes; A standard cell connected to the narrow band filter and injecting a standard gas containing no gas component constituting the sample gas into the body, and passing light from the narrow band filter; A first reference cell connected to the sample cell and having a first reference gas having a known concentration as a gas containing the same component as the gas constituting the sample gas and passing light from the narrowband filter. and, A second reference gas having a concentration different from the concentration of the first reference gas is injected into the body which is connected to the standard cell and contains the same component as the gas constituting the sample gas. A second reference cell through which light from the narrowband filter passes, A first reflection mirror attached to an end wall of the first reference cell and re-reflecting light irradiated into the body of the first reference cell; An optical cell unit attached to an end wall of the second reference cell and composed of a second reflecting mirror for reflecting light irradiated into the body of the second reference cell again; A sample cell microphone attached to the sample cell and detecting the photoacoustic of the sample gas and converting the sample into an AC voltage; A first reference cell microphone attached to the first reference cell and detecting the photoacoustic sound of the first reference gas and converting the photoacoustic signal into an AC voltage; A second reference cell microphone attached to the second reference cell and detecting the photoacoustic sound of the second reference gas and converting the photoacoustic signal into an AC voltage; A standard cell microphone attached to the standard cell 220d and detecting the photoacoustic sound of the standard gas and converting the photoacoustic into a form of an AC voltage; A first piezo sensor attached between the sample cell and the first reference cell and detecting a differential pressure between the sample cell and the first reference cell and converting the pressure into an AC voltage; A detection unit attached between the standard cell and the second reference cell and configured of a second piezo sensor for detecting a differential pressure between the standard cell and the second reference cell and converting the pressure into a form of an AC voltage; An optical acoustic sensor for exhaust gas measurement, which is electrically connected to the chopper and the detector and includes a signal processor for removing and amplifying a noise component among AC voltages detected by the detector and converting the amplified component into a DC voltage.