KR100327327B1 - Vertical diffusion furnace having improved heat loss blocking capability - Google Patents

Vertical diffusion furnace having improved heat loss blocking capability Download PDF

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Publication number
KR100327327B1
KR100327327B1 KR1019950054688A KR19950054688A KR100327327B1 KR 100327327 B1 KR100327327 B1 KR 100327327B1 KR 1019950054688 A KR1019950054688 A KR 1019950054688A KR 19950054688 A KR19950054688 A KR 19950054688A KR 100327327 B1 KR100327327 B1 KR 100327327B1
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diffusion furnace
boat
cap
heat loss
vertical diffusion
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KR1019950054688A
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KR970052115A (en
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전찬웅
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삼성전자 주식회사
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/54Apparatus specially adapted for continuous coating

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)

Abstract

PURPOSE: A vertical diffusion furnace having improved heat loss blocking capability is provided to prevent the outside air under the diffusion furnace from being introduced to the inside of the diffusion furnace by installing a boat cap in a portion under the diffusion furnace. CONSTITUTION: A predetermined process for forming a thin film is performed in a reaction furnace(38). A heater(34) supplies outside heat to make the reaction furnace maintain a predetermined level of temperature. A plurality of wafers on which the thin film is to be formed are loaded into a boat. The boat cap(54) of a vacuum state is connected to the lower portion of the boat, filled with quartz wool.

Description

열손실 방지기능이 향상된 종형확산로Vertical diffusion furnace with improved heat loss prevention

본 발명은 반도체 장치의 종형확산로에 관한 것으로, 특히 확산로내의 열손실 방지기능이 향상된 종형확산로에 관한 것이다.The present invention relates to a vertical diffusion furnace of a semiconductor device, and more particularly, to a vertical diffusion furnace having an improved heat loss prevention function in a diffusion furnace.

고집적반도체장치의 제조에서는 박막의 형성이 필수적이고 중요하다. 이러한 박막을 형성하는 방법은 기판과 기상증착된 물질과의 상호작용에 의한 것과, 기판물질에 변화를 주지않고 막을 형성하는 두가지 방법으로 대별된다. 전자는 단결정 및 다결정실리콘의 산화막 또는 질화막의 형성시 또는 실리사이드의 형성시에 이용되고, 후자는 화학기상증착, 물리기상증착 등에 의한 막의 성장법으로 에피택시, 스퍼터링 또는 분자빔에피택시 등에 이용된다. 그런데 고순도의 증착물을 얻을 수 있고, 다양한 화학성분을 증착시킬 수 있으며, 경제적이며 공정을 제어하는 것이 가능하다는 이유로, 박막의 형성에 화학기상증착법이 많이 이용되고 있다.In the manufacture of highly integrated semiconductor devices, the formation of thin films is essential and important. The method of forming such a thin film is classified into two methods, namely, the interaction between the substrate and the vapor deposited material and the method of forming the film without changing the substrate material. The former is used for the formation of oxide films or nitride films of monocrystalline and polycrystalline silicon, or for the formation of silicides, and the latter is used for epitaxy, sputtering, or molecular beam epitaxy in the growth of the film by chemical vapor deposition, physical vapor deposition, or the like. However, chemical vapor deposition has been widely used in the formation of thin films because it is possible to obtain high-purity deposits, to deposit various chemical components, to be economical, and to control the process.

최근에는 화학기상종착시에 종형확산로를 사용하고 있으며, 반도체장치가 고집적화됨에 따라 웨이퍼에 형성되는 박막의 균일도가 저하되고 있다. 산화막 형성시 확산로내의 온도, 압력, 반응가스의 각자의 농도 및 반응가스들의 비율 및 웨이퍼 간의 간격등이 변수로 작용하고 있다.In recent years, vertical diffusion furnaces have been used for chemical vapor deposition, and as semiconductor devices become more integrated, the uniformity of thin films formed on wafers is reduced. The temperature, pressure, respective concentrations of reactant gases, the proportion of reactant gases, and the spacing between wafers in the formation of the oxide film are variables.

특히, 웨이퍼 또는 확산장비의 교체등으로 인해 선행한 박막형성공정의 온도에 비해 후행하는 박박형성시의 온도가 낮게 되는 경우가 발생할 수 있다. 이러한 열손실을 방지하기 위해 확산로 하부에 보우트캡을 사용하고 있다.In particular, the replacement of the wafer or diffusion equipment may cause the temperature at the time of the subsequent thin film formation to be lower than that of the preceding thin film formation process. In order to prevent such heat loss, a bolt cap is used at the bottom of the diffusion furnace.

제 1도를 참고로 종래의 보우트캡을 채용한 종형확산로를 설명한다.Referring to FIG. 1, a vertical diffusion furnace employing a conventional bolt cap will be described.

참조번호 4는 히터를, 참조전호 8은 반응로를, 참조번호 12는 석영보우트를, 참조번호 16은 반응가스 유입구를, 참조번호 20은 가스배출구를, 참조번호 24는 보우트캡을, 참조번호 26 및 28은 보우트캡에 형성된 홀을 나타낸다.4 is a heater, 8 is a reactor, 12 is a quartz boat, 16 is a reaction gas inlet, 20 is a gas outlet, 24 is a boat cap, and 26 and 28 represent holes formed in the boat cap.

박막 형성을 위한 반응이 일어나는 반응로(8)는 히터(4)에 의해 둘러싸여 있다. 석영보우트(12)는 다수의 웨이퍼가 적재되도록 슬럿이 형성된 4개의 보우트바로 구성된다. 석영보우트(12)의 하부에는 보우트캡(24)이 연결되어 있다. 보우트캡(24)과 상기 보우트(12)와의 경계에서는 홀(26)이 형성되어 있으며, 보우트캡하부에도 하나의 홀(28)이 형성되어 있다. 상기 보우트캡(24) 내부는 확산로의 열손실을 방지하기 위해 석영울(quartz wool)로 채워져 있으며 비진공상태이다. 상기 보우트캡(24)이 위로 이동하면서 웨이퍼를 확산로내에 투입시키고, 가스유입구(16)를 통해 반응가스가 확산로내로 유입된다. 소정의 반응이 완료되면 보우트캡(24)이 확산로 하방으로 움직여 박막이 형성된 웨이퍼를 확산로로부터 빠지 나오고 반응에 관여한 가스는 가스배출구(20)를 통해 외부로 배출된다.The reactor 8 in which the reaction for forming the thin film takes place is surrounded by a heater 4. The quartz boat 12 is composed of four boat bars in which slots are formed so that a plurality of wafers are loaded. The boat cap 24 is connected to the lower portion of the quartz boat 12. A hole 26 is formed at the boundary between the boat cap 24 and the boat 12, and a hole 28 is formed under the boat cap. The bow cap 24 is filled with quartz wool to prevent heat loss of the diffusion furnace and is in a non-vacuum state. As the cap cap 24 moves upward, the wafer is introduced into the diffusion furnace, and the reaction gas flows into the diffusion furnace through the gas inlet 16. When the predetermined reaction is completed, the bolt cap 24 moves downward to diffuse the wafer from the diffusion path, and the gas involved in the reaction is discharged to the outside through the gas outlet 20.

그런데, 열손실방지를 위해 사용되는 보우트캡(24)이 비진공상태이므로, 열손실방지에 큰 효과가 없으며, 장비의 세정시 화학약품 및 이온제거수(deionarized water)가 상기 석영울로 유입된다.However, since the boat cap 24 used for preventing heat loss is in a non-vacuum state, there is no great effect on preventing heat loss, and chemicals and deionarized water are introduced into the quartz wool when the equipment is cleaned. .

이에 열손실을 방지하기 위해 보우트캡(24)의 하부에 위치하는 홀(28)을 막을 경우 장비의 교체에 의한 확산로 내의 공정온도의 강하는 막을 수 있으나, 이럴 경우 오히려 온도가 상승하여 보우트캡이 폭발할 우려가 있어, 진공상태인 보우트캡을 사용한 종형확산로를 사용할 수 없었다.In order to prevent heat loss, if the hole 28 located in the lower part of the cap cap 24 is blocked, the process temperature in the diffusion path may be prevented by replacing the equipment, but in this case, the temperature rises rather than the cap cap. There was a risk of this explosion, and a vertical diffusion furnace using a vacuum cap was not available.

따라서, 본 발명의 목적은 열손실방지기능이 향상된 보우트캡을 가지는 종형확산로를 제공함에 있다.Accordingly, it is an object of the present invention to provide a vertical diffusion furnace having a boat cap with improved heat loss prevention function.

본 발명의 목적을 달성하기 위한 종형확산로는, 상기 박막을 형성하기 위한 소정의 반응이 일어나는 반응로, 상기 반응로를 소정 수준의 온도상태에 있게 하기 위해 외부열을 공급하는 히터, 상기 박막이 형성될 다수의 웨이퍼가 적재된 보우트, 상기 보우트 하부에 연결되고, 석영울로 채워져 있으며, 진공상태인 보우트캡을 구비한다.In order to achieve the object of the present invention, a vertical diffusion furnace includes a reaction furnace in which a predetermined reaction for forming the thin film occurs, a heater for supplying external heat to bring the reactor to a temperature level at a predetermined level, A boat having a plurality of wafers to be formed is loaded, connected to the bottom of the boat, filled with quartz wool, and having a vacuum cap cap.

이하, 본 발명을 제 2도를 참조로 설명한다.Hereinafter, the present invention will be described with reference to FIG.

참조번호 34는 히터를, 참조번호 38은 반응로를, 참조번호 42는 석영보우트를, 참조번호 46은 반응가스 유입구를, 참조번호 50은 가스배출구를, 참조번호 54는 보우트캡을, 참조번호 56 및 58은 보우트캡에 형성된 홀을 나타내는 것으로 제 1도의 것과 동일하며, 다만, 보우트캡(54)의 내부는 진공인 것이 제 1도와 다른점이다.34 is a heater, 38 is a reactor, 42 is a quartz boat, 46 is a reaction gas inlet, 50 is a gas outlet, 54 is a boat cap, and 56 and 58 represent holes formed in the boat cap, which are the same as those in FIG. 1, except that the inside of the boat cap 54 is vacuum.

보우트캡의 내부를 종래의 비진공상테에서 진공상태로 바꿈으로써, 석영울의 열전도도를 낯출 수 있다. 즉, 확산로내와 외부와의 열전달이 차단되어 확산로내의 온도를 일정하게 유지시킬 수 있다.By changing the inside of the boat cap to a vacuum state in a conventional non-vacuum frame, the thermal conductivity of the quartz wool can be reduced. That is, heat transfer between the diffusion furnace and the outside may be blocked to maintain a constant temperature in the diffusion furnace.

아래의 표는 보우트캡의 내부를 비진공으로 한 경우와 진공으로 한 경우를 비교하여 본 발명의 효과를 나타낸 것이다.The table below shows the effect of the present invention by comparing the case of the inside of the boat cap with a non-vacuum and the case with a vacuum.

table

진행공정 : GOX 160 ± 1.5Å (온도 820℃)Process: GOX 160 ± 1.5Å (Temperature 820 ℃)

상기 표에서 알 수 있는 바와 같이 확산로 하부의 외부공기가 확산로 내부로 유입되지 못하게 되어 열손실방지에 효과가 있다. 특히 확산로의 하부에 있어서 막의 균일도는 종래의 비진공을 사용하는 경우에 비해 확산로의 중간이나 상부에서의 효과보다 온도의 유지 효과 및 박막의 균일도의 향상에 있어 탁월한 효과가 있다. 또한, 세정 작업의 번거로움을 해소할 수 있다.As can be seen in the above table, the external air at the bottom of the diffusion path is prevented from entering the diffusion path, thereby preventing heat loss. In particular, the uniformity of the film in the lower part of the diffusion furnace is superior to the effect of maintaining the temperature and improving the uniformity of the thin film than the effect in the middle or the upper part of the diffusion furnace compared to the case of using a conventional non-vacuum. Moreover, the troublesome of a washing | cleaning operation can be eliminated.

본 발명을 특별한 예를 들어 설명하였으나 본 발명은 이에 한정되지 않으며 본 발명의 본질적 범위내에서의 각종 변형이 가능함은 당해 분야의 통상의 지식을 가진 자에게 자명하다.Although the present invention has been described with specific examples, it is apparent to those skilled in the art that various modifications within the essential scope of the present invention are not limited thereto.

제1도는 일반적인 종형확산로를 개략적으로 나타내는 도면이다.1 is a view schematically showing a general bell spreader.

제2도는 열손실기능이 향상된 종형확산로를 나타내는 도면이다.2 is a view showing a vertical diffusion furnace having an improved heat loss function.

Claims (1)

박막을 형성하기 위한 종형확산로에 있어서,In the vertical diffusion furnace for forming a thin film, 상기 박막을 형성하기 위한 소정의 반응이 일어나는 반응로,A reaction in which a predetermined reaction for forming the thin film occurs, 상기 반응로를 소정 수준의 온도상태에 있게 하기 위해 외부열을 공급하는 히터,A heater for supplying external heat to keep the reactor at a predetermined level of temperature; 상기 박막이 형성될 다수의 웨이퍼가 적재된 보우트,A boat having a plurality of wafers on which the thin film is to be formed; 상기 보우트 하부에 연결되고, 석영울로 채워져 있으며, 진공상태인 보우트캡을 구비함을 특징으로 하는 종형확산로.A vertical diffusion furnace connected to the bottom of the boat, filled with quartz wool, and having a boat cap in a vacuum state.
KR1019950054688A 1995-12-22 1995-12-22 Vertical diffusion furnace having improved heat loss blocking capability KR100327327B1 (en)

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