KR100303235B1 - crack retardant mixture for cement mortar and cement mortar by using it for heating floor(on-dool) - Google Patents

crack retardant mixture for cement mortar and cement mortar by using it for heating floor(on-dool) Download PDF

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KR100303235B1
KR100303235B1 KR1020000006792A KR20000006792A KR100303235B1 KR 100303235 B1 KR100303235 B1 KR 100303235B1 KR 1020000006792 A KR1020000006792 A KR 1020000006792A KR 20000006792 A KR20000006792 A KR 20000006792A KR 100303235 B1 KR100303235 B1 KR 100303235B1
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gypsum
quicklime
cement mortar
cement
mortar
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KR20000024422A (en
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권승안
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권승안
주식회사한국포조텍
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/14Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C04B22/142Sulfates
    • C04B22/143Calcium-sulfate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/008Cement and like inorganic materials added as expanding or shrinkage compensating ingredients in mortar or concrete compositions, the expansion being the result of a recrystallisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/062Oxides, Hydroxides of the alkali or alkaline-earth metals
    • C04B22/064Oxides, Hydroxides of the alkali or alkaline-earth metals of the alkaline-earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/346Materials exhibiting reduced plastic shrinkage cracking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명은 주택바닥 등에 사용되는 시멘트 몰탈에 관한 것으로, 그 목적은 초기균열이 발생하지 않고 28일 압축강도의 발현율이 높으면서 계절특성에 따라 사용할 수 있는 수축저감재와 이 저감재를 이용한 마감미장용 시멘트 몰탈의 조성물을 제공함에 있다.The present invention relates to cement mortar used in the floor of the house, the purpose is that the initial shrinkage does not occur and the shrinkage reducing material that can be used according to the seasonal characteristics with high expression rate of 28 days compressive strength and for finishing plastering using this reducing material In providing a composition of cement mortar.

상기 목적을 달성하기 위한 본 발명은The present invention for achieving the above object

생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스 연소재로 조성되는 시멘트 몰탈용 수축저감재와Quicklime: 10-30 weight, Gypsum: 20-40 weight, Coal ash: 10-20 and the shrinkage reducing material for cement mortar composed of the remaining petroleum coke combustor

(a) 시멘트:70∼85중량와(a) cement: 70-85 weight and

(b) 생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스의 연소재로 조성되는 수축저감재: 15∼30중량를 배합한 원료에, 조립율(F.M) 2.8이상의 모래로 조성되는 온돌마감미장용 시멘트 몰탈에 관한 것을 그 기술적요지로 한다.(b) Quicklime: 10 to 30 wt%, gypsum: 20 to 40 wt%, coal ash: 10 to 20 and shrinkage reducing material composed of combustion materials of the remaining petroleum coke: 15 to 30 wt% of the raw material blended, granulation rate (FM) The technical gist of cement mortar for ondol finishing finishing composed of sand of 2.8 or more is considered to be the technical basis.

Description

시멘트 몰탈용 수축저감재와 이를 이용한 온돌마감미장용 시멘트 몰탈{crack retardant mixture for cement mortar and cement mortar by using it for heating floor(on-dool)}Shrink retardant for cement mortar and cement mortar for plastering with ondol finishing {crack retardant mixture for cement mortar and cement mortar by using it for heating floor (on-dool)}

본 발명은 주택바닥 등에 사용되는 시멘트 몰탈에 관한 것으로, 보다 상세하게는 시메트 몰탈의 건조수축으로 인한 균열을 방지할 수 있는 수축저감재와 이 저감재를 이용한 시멘트 몰탈에 관한 것이다.The present invention relates to a cement mortar used in a house floor, and more particularly, to a shrinkage reducing material capable of preventing cracking due to dry shrinkage of a simeth mortar and a cement mortar using the reducing material.

최근 들어 주택건설이 양적으로 증대함과 아울러 주택이 고층화, 대형화됨에 따라 시멘트 몰탈을 펌프로 압송하여 방바닥에 미장하는 기계화시공이 급속히 확산되고 있다. 기계화시공은 펌프압송의 편의를 위해 과도한 물이 첨가되고 있는 실정이어서 시공후에 평균 1m/평 정도의 심각한 균열하자가 발생하고 있다.In recent years, as the construction of houses has increased quantitatively and the houses have become higher and larger, the mechanized construction of cement mortar pumping and plastering on the floor is rapidly spreading. Mechanized construction is a situation in which excessive water is added for the convenience of pump pumping, so serious crack defects of about 1m / pyeong occur after construction.

이러한 균열은 시멘트가 응결되는 과정에서 수축에 의해 발생하는 것으로, 시멘트의 구성성분, 시멘트의 분말도, 물의 양 등에 가장 큰 영향을 받는다. 시멘트의 수축균열을 방지하기 위해 건조수축을 보상하는 정도로 팽창할 수 있는 팽창시멘트를 사용하는 방법이 알려져 있다.These cracks are caused by shrinkage during cement condensation and are most affected by the composition of cement, the powder of cement, the amount of water, and the like. In order to prevent shrinkage cracking of cement, it is known to use an expansion cement that can expand to a degree that compensates for dry shrinkage.

팽창시멘트로는 K, S, M 및 O형이 미국, 일본 등에서 개발되어 사용되고 있는데, 이들은 시멘트에 (3CaO·Al2O3·CaSO4)·CaO·CaSO4, (3CaO·Al2O3)와 CaSO4, CaO, 또는 CaSO4중의 1종을 적정량 혼합하여 시멘트의 팽창성을 확보하는 것이다. 팽창시멘트가 팽창하는 것은, (1)에트링게이트(Ettringite,3CaO·3CaSO4·32H2O)의 생성과정에서 수분을 흡수하여 팽창되거나, (2) 추가로 가해지는 CaO가 수산화칼슘의 결정을 형성하면서 팽창되는 것으로 알려져 있다.K, S, M and O types are developed and used in the United States, Japan, etc., and they are used in cement as (3CaO · Al 2 O 3 · CaSO 4 ) · CaO · CaSO 4 , (3CaO · Al 2 O 3 ) And one of CaSO 4 , CaO, or CaSO 4 are mixed in an appropriate amount to secure the expandability of the cement. The expansion cement expands by (1) swelling by absorbing moisture during the formation of etringite (3CaO.3CaSO 4 .32H 2 O), or (2) CaO added to form crystals of calcium hydroxide. It is known to become.

그런데, 지금까지 알려진 팽창시멘트는 그 제조과정이 복잡하여 일반주택의 바닥 마감용 시멘트몰탈로 적용하기에는 어려운 실정이다. 따라서, 시멘트 몰탈의 수축량에 해당하는 만큼의 팽창력을 내부에 화학적으로 도입하여 수축을 보상함으로써 균열발생의 원인을 근원적으로 차단하는 수축저감재를 시멘트에 혼합하여 사용하려는 기술이 시도되고 있다.By the way, the expansion cement known so far is difficult to apply as a cement mortar for finishing the floor of the general housing complex. Therefore, a technique has been attempted to mix and use a shrinkage reducing material that is essentially blocking the cause of cracks by compensating for shrinkage by chemically introducing expansion force corresponding to the shrinkage amount of cement mortar into cement.

그 대표적인 예가 본 발명자가 개발하여 한국 공개특허공보 1996-34119호에제안한 온돌마감미장용 수축저감몰탈이다. 이 몰탈은 정유공장에서 발생하는 폐기물인 석유코우크스 연소재와 시멘트로 조성되는데, 수분이 많은 몰탈에서도 균열방지에 탁월한 효과를 나타내고 있다. 그러나, 이 수축저감몰탈은 초기응결시간의 단축으로 인하여 충분한 미장시간을 얻기 힘들어 초기균열의 발생하는 경우가 있고 또한 28일 압축강도 발현이 늦으며, 계절특성에 따른 차등배합이 어려운 단점이 있다. 수축저감몰탈에 나타나는 단점은 다음의 원인에 기인하는 것으로 판단된다.A representative example thereof is a shrinkage reduction mortar for ondol finishing plastering proposed by the present inventor and proposed in Korean Unexamined Patent Publication No. 1996-34119. The mortar is composed of petroleum coke combustors and cement, which are wastes generated in oil refineries. However, this shrinkage reduction mortar is difficult to obtain sufficient plastering time due to the shortening of the initial setting time, the early cracking may occur, and the 28-day compressive strength expression is slow, and the differential mixing due to seasonal characteristics is difficult. Disadvantages of shrinkage reduction mortar are believed to be due to the following causes.

(1) 초기균열(1) initial crack

석유코우크스 연소재는 CaO, SiO2, Al2O3가 주성분으로서 주성분인 CaO중에는 석유코우크스 연소시 아황산가스와 결합한 석고(CaSO4)성분이 40∼50존재한다. 석유코우크스 연소재의 일례가 아래 표 1에 나타나 있다.In the petroleum coke combustor, CaO, SiO 2 and Al 2 O 3 are the main constituents, and the main component CaO includes 40 to 50 gypsum (CaSO 4) components combined with sulfur dioxide during petroleum coke combustion. An example of petroleum coke combustor is shown in Table 1 below.

화학조성(중량)Chemical composition (weight) CaOCaO SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 MgOMgO K2OK 2 O Na2O3 Na 2 O 3 시험방법Test Methods 75.975.9 12.4412.44 3.383.38 0.330.33 0.550.55 0.110.11 0.190.19 KSL 5120-90 I.C.P. 분석KSL 5120-90 I.C.P. analysis 분말도(mm)Powder level (mm) 1.18이상1.18 or higher 1.18∼0.61.18-0.6 0.6∼0.250.6 to 0.25 0.25∼0.1770.25-0.177 0.177∼0.1250.177 to 0.125 0.125∼0.1050.125 to 0.105 0.105-0.0750.105-0.075 0.075이하Less than 0.075 2.12.1 5.85.8 24.624.6 16.716.7 17.217.2 7.57.5 9.89.8 16.316.3

표 1에서 확인할 수 있듯이, 석유 코우크스 연소재는 분말도가 낮은데, 이미립자들이 표면에 떠오르는 현상(레이턴스 현상)에 의해 표면의 분말도가 낮아져서 초기균열이 발생하는 것으로 추정되었다. 물론 레이턴스 현상에 의해 마감후 표면이 매끄러워지는 장점이 있다.As can be seen in Table 1, the petroleum coke combustor is low in powder, it is estimated that the initial crack occurs due to the surface powder is lowered by the phenomenon that the particles are floating on the surface (latency phenomenon). Of course, there is an advantage that the surface is smooth after finishing due to the latent phenomenon.

또한, 석유코우크스 연소재에는 CaO가 많이 함유되어 있는데, 이 CaO의 높은 수화열에 의해 초기응결시간이 단축되어 충분한 미장시간(적어도 약 4회에 걸쳐 4시간 30분의 미장시간이 요구됨)이 확보되지 않음에 따라 초기균열의 발생되는 것으로 분석되었다.In addition, the petroleum coke combustor contains a lot of CaO, and the high heat of hydration of CaO shortens the initial setting time, thereby securing sufficient plastering time (at least about 4 hours and 30 minutes of plastering time). As such, it was analyzed that an initial crack occurred.

(2) 28일 강도발현율(2) 28-day intensity expression rate

석유 코우크스 연소재에 함유된 석고에는 다량의 반수석고와 이수석고가 함유되는데, 이들이 응고지연을 일으켜 28일 강도발현율이 약 70수준으로 나타났다.Gypsum contained in petroleum coke combustor contains a large amount of hemihydrate gypsum and dihydrate gypsum, which caused coagulation delay, resulting in about 70 days of strength development.

(3) 계절특성(3) Seasonal Characteristics

이와 같이 온돌마감 미장용 수축저감몰탈은 석유코우크스 연소재와 시멘트를 주요성분으로 하기 때문에 하절기와 동절기에 따라 몰탈의 초기응결시간의 조절이 안되는데, 특히 초기응결시간의 지연이 요구되는 하절기에는 그 특성이 떨어지는 단점이 있다.As such, shrinkage reduction mortar for plastering ondol is mainly composed of petroleum coke combustor and cement, so it is not possible to control the initial setting time of mortar during summer and winter, especially in summer when delay of initial setting time is required. There is a disadvantage of falling characteristics.

본 발명은 석유코우크스 연소재로 조성되는 수축저감몰탈의 갖는 단점를 개선하기 위한 일련의 연구과정에서 안출된 것으로, 초기균열이 발생하지 않음은 물론, 28일 압축강도의 발현율이 높고 계절특성에 따른 차등배합이 가능한 수축저감재와 이 저감재를 이용한 온돌마감미장용 시멘트 몰탈의 조성물을 제안하는데, 그 목적이 있다.The present invention was devised in a series of studies to improve the shortcomings of shrinkage reduction mortar made from petroleum coke combustors, the initial crack does not occur, as well as the high expression rate of 28 days compressive strength and seasonal characteristics The present invention proposes a composition of shrinkage reducing materials capable of differential blending and a composition of cement mortar for plastering ondol finishing using the materials.

도 1은 석고종류별 길이변화를 나타내는 그래프1 is a graph showing the change in length for each type of plaster

도 2는 수축저감재의 조성에 따른 길이변화를 나타내는 그래프2 is a graph showing the change in length according to the composition of the shrinkage reducing material

상기 목적을 달성하기 위한 본 발명의 수축저감재는 생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스 연소재로 조성된다.The shrinkage reducing material of the present invention for achieving the above object is composed of quicklime: 10-30 weight, gypsum: 20-40 weight, coal ash: 10-20 and the remaining petroleum coke combustion material.

또한, 본 발명의 온돌마감 미장용 시멘트 몰탈은,In addition, the cement mortar for plastering ondol finishing of the present invention,

(a) 시멘트:70∼85중량와(a) cement: 70-85 weight and

(b) 생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스의 연소재로 조성되는 수축저감재: 15∼30중량를 배합한 원료에, 조립율(F.M) 2.8이상의 모래로 조성된다.(b) Quicklime: 10 to 30 wt%, gypsum: 20 to 40 wt%, coal ash: 10 to 20 and shrinkage reducing material composed of combustion materials of the remaining petroleum coke: 15 to 30 wt% of the raw material blended, granulation rate (FM) It is composed of sand of 2.8 or more.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

[수축저감재][Reduction Reduction Material]

본 발명에서 사용하는 석유코우크스 연소재는 석회석과 석유 코우크스를 유동층 연소보일러 또는 석회 소성로에서 연소할 때 석유코우크스는 전량 연소되고석유 코우크스에 함유되어 있던 황화물이 석회의 석고 성분과 결합하면서 재로 형성하여 나오는 부산물이다. 석유코우크스 연소재는 대개 석회석 30∼70중량와 석유 코우크스 30∼70의 혼합물을 고온(약 800℃)에서 연소할 때 발생하는데, 석유 코우크스는 석유정제과정의 하이드로 크래킹 유니트에서 중질유(벙커 C유)로부터 경유를 뽑을 때 나오는 잔사유을 사용한다. 따라서, 석유 코우크스 연소재는 상기한 표 1에 그 일례가 제시되어 있듯이, 주로 CaO, SiO2, Al2O3가 주성분이고 CaO중에는 석유코우크스 연소시 아황산가스와 결합한 석고(CaSO4)성분이 40∼50존재한다.In the petroleum coke combustor used in the present invention, when the limestone and petroleum coke are combusted in a fluidized bed combustion boiler or a lime kiln, the petroleum coke is burned entirely, and the sulfides contained in the petroleum coke are combined with the gypsum component of the lime. It is a byproduct formed from ash. Petroleum coke combustors usually occur when a mixture of 30 to 70 weight of limestone and 30 to 70 of petroleum coke is combusted at high temperature (about 800 ° C). Petroleum coke is a heavy oil (bunker C) Use the residual oil that comes out when the diesel is extracted from Yu). Therefore, as shown in Table 1, the petroleum coke combustor mainly contains CaO, SiO 2 , Al 2 O 3 , and CaO contains gypsum (CaSO 4) component combined with sulfur dioxide during petroleum coke combustion. 40-50 exists.

본 발명에서는 석유 코우크스 연소재를 온돌마감미장용 시멘트 몰탈로 사용할 때 발생하는 초기균열, 28일강도발현, 계절특성을 개선하기 위해 석유코우크스 연소재에 (1) 생석회, (2) 석고, (3) 석탄회를 적정배합비로 배합하는데, 그 특징이 있다.In the present invention, (1) quicklime, (2) gypsum, to improve the initial crack, 28-day strength expression, seasonal characteristics that occur when using the petroleum coke combustor as cement mortar for ondol finishing (3) Coal ash is blended at the proper mixing ratio, which has its characteristics.

(1) 생석회(CaO)(1) quicklime (CaO)

생석회는 팽창성을 갖고 있어 수축저감재로 유효하게 이용할 수 있는 데, 본 발명에서는 이러한 팽창특성을 기본으로 하면서 분말도 조정역할을 위해 첨가한다. 생석회의 입도를 100메쉬(mesh)이하가 40이상 되도록 하여 사용하면 시멘트 몰탈이 시공될 때 표면의 분말도를 높여 초기균열의 발생을 방지하는 것을 확인할 수 있었다. 생석회는 대개 CaO가 80∼90이고 입도가 100메쉬(mesh)이하의 잔체분이 10이하이다. 따라서, 100메쉬이하가 40이하가 되도록 하기 위해서는 분말도가 높은 생석회를 혼합하는 것이 필요한데, 본 발명에서는 생석회 더스트를 이용한다. 생석회 더스트는 생석회 제조과정에서 발생하는 것으로, 100메쉬 잔체분이 40이상으로 CaO함량이 50∼70정도 된다. 따라서, 본 발명에서는 100메쉬이하가 40이하가 되도록 생석회와 생석회더스트를 적절히 혼합하여 사용하는데, 생석회 더스트에 는 CaO함량이 낮아서 수화열을 낮출 수 있기 때문에 초기응결균열의 방지에도 효과적이다.Quicklime has expandability and can be effectively used as a shrinkage reducing material. In the present invention, the quicklime is added to adjust the powder level based on the expansion characteristics. If the particle size of quicklime is used to less than 100 mesh (mesh) or more, it can be confirmed that when the cement mortar is used, the surface powder is increased to prevent the occurrence of initial cracking. Quicklime usually has a CaO of 80 to 90 and a particle size of less than 100 mesh (mesh) of 10 or less. Therefore, in order to make 100 mesh or less into 40 or less, it is necessary to mix quicklime with high powder density, but in this invention, quicklime dust is used. Quicklime dust is produced during quicklime production, with 100 mesh residue of 40 or more and CaO content of 50-70. Accordingly, in the present invention, the quicklime and the quicklime dust are appropriately mixed so that 100 mesh or less is 40 or less. Since the quicklime dust has a low CaO content, the heat of hydration can be lowered, which is effective in preventing the initial coagulation crack.

본 발명에서는 생석회를 수축저감재에 10∼30중량로 첨가하는데, 이는 생석회가 10중량미만의 경우 표면의 분말도가 낮아져서 초기균열의 억제효과가 적으면 30을 초과하는 경우에는 장기균열에 불리하기 때문이다.In the present invention, the quicklime is added to the shrinkage reducing agent in 10 to 30 weight, which is less than 10 wt% of the quicklime, so that the surface powder is low, so if the inhibitory effect of the initial cracking is less than 30, it is disadvantageous to long-term cracking. Because.

(2) 석고(2) gypsum

본 발명에서 석고는 석유 코우크스 연소재에 생석회가 추가로 함유되면서 팽창성에 유효한 에트링게이트의 생성량의 부족에 기인한 장기수축균열을 억제하기 위해 첨가하는데, 그 첨가량은 20∼40중량로 하는 것이 바람직하다. 그 이유는 석고가 20중량미만에서는 그 첨가효과를 기대하기 어려우며 40중량를 초과하는 경우에는 양생후 외부에서 수분이 침투되는 경우에 2차팽창을 일으킬 수 있다.In the present invention, the gypsum is added to suppress the long-term shrinkage cracking caused by the lack of the production amount of the Ettling gate effective in the expansion while the quicklime is contained in the petroleum coke combustion material, the addition amount is 20 to 40 desirable. The reason is that when the gypsum is less than 20 wt%, it is difficult to expect the additive effect, and when the gypsum exceeds 40 wt%, secondary expansion may occur when moisture is penetrated from the outside after curing.

본 발명에서 석고는 무수석고, 이수석고, 반수석고 어떠한 것도 가능한데, 동절기에는 무수석고를 하절기에는 이수석고를 사용하는 것이 바람직하다. 그 이유는 이수석고가 무수석고에 비해 초기응결시간이 길어 하절기에 유리하기 때문이다.In the present invention, gypsum can be any gypsum, hydrated gypsum, hemihydrate gypsum, it is preferable to use anhydrous gypsum in winter and hydrated gypsum in summer. The reason is that Isu gypsum has a longer initial setting time than anhydrous gypsum and is advantageous in summer.

(3) 석탄회(fly ash)(3) fly ash

본 발명에서 석탄회는 석유코우크스 연소재의 수화열을 감소시켜 초기크랙을 방지하는 역할을 한다. 또한 몰탈의 유동성을 개선하여 감수재로서의 역할도 한다. 석탄회는 10∼20배합하는 것이 바람직한데, 이는 석탄회의 배합비가 10미만의 경우에는 그 첨가효과가 미미하고 20를 초과하는 경우에는 수축저감재의 팽창성을 떨어뜨린다.Coal ash in the present invention serves to prevent the initial crack by reducing the heat of hydration of the petroleum coke combustion material. In addition, it improves the fluidity of mortar to play a role as a water reducing material. Coal ash is preferably blended 10 to 20, which is less than 10 when the mixing ratio of coal ash is insignificant, and when it exceeds 20, it reduces the expandability of the shrinkage reducing material.

[시멘트 몰탈][Cement mortar]

본 발명의 시멘트 몰탈은Cement mortar of the present invention

(a) 시멘트:70∼85중량와(a) cement: 70-85 weight and

(b) 생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스의 연소재로 조성되는 수축저감재: 15∼30중량를 배합한 원료에, 조립율(F.M) 2.8이상의 모래로 조성된다.(b) Quicklime: 10 to 30 wt%, gypsum: 20 to 40 wt%, coal ash: 10 to 20 and shrinkage reducing material composed of combustion materials of the remaining petroleum coke: 15 to 30 wt% of the raw material blended, granulation rate (FM) It is composed of sand of 2.8 or more.

여기서 수축저감재는 시멘트에 15∼30중량의 배합비로 혼합하는 것이 바람직한데, 이는 15중량미만의 경우 팽창효과가 적으며 30를 초과하는 경우 과팽창할 수 있기 때문이다.In this case, the shrinkage reducing material is preferably mixed with cement in a mixing ratio of 15 to 30 weight, because less than 15 weight is less inflating effect, and if it exceeds 30, it may overexpand.

또한, 수축저감재와 시멘트로 조성되는 원료와 모래의 배합비는 통상의 방법으로 하는데, 보통 1:2.5∼3으로 하고 있다. 중요한 것은 모래의 조립율을 2.8이상으로 하는데, 이는 시멘트 몰탈을 시공할 때 몰탈의 분말도를 높여 초기균열을 방지하기 위해서이다.In addition, although the mixing ratio of the raw material and sand which consist of a shrinkage reducing material and cement is a conventional method, it is usually 1: 2.5-3. Importantly, the granulation rate of sand is set to 2.8 or higher, in order to prevent the initial cracking by increasing the mortar powder when cement mortar is applied.

본 발명의 시멘트 몰탈에는 펌프압송 및 마감미장공사를 원할히 하도록 통상의 방법대로 공기연행제, 감수제, 증점제를 첨가할 수 있다.Cement mortar of the present invention can be added to the air entrainer, water reducing agent, thickener in the usual way to facilitate pump pressure and finishing plastering.

이하, 본 발명을 실시예를 통하여 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.

[실시예 1]Example 1

건조몰탈 1톤당 표 2의 석고를 종류별로 각각 40kg혼합(단위수량 15∼16)하고, 석고별 응결시간을 측정하여 표 3에, 길이변화율을 측정하여 도 1에 나타나내었다. 응결시간은 20℃온도에서 초결시점을 기준으로 하여 측정하였다. 또한, 몰탈 공시체의 길이변화는 20℃, 95RH의 항온항습기에 넣어 24시간 양생한 후, 탈형하여 길이변화측정기를 이용하여 초기 길이를 측정하였고, 측정후에는 다시 20℃, 60RH의 항온항습기에 넣어 소정의 측정재령 즉, 7일, 28일의 간격으로 각각 양생한 후 측정하였다.Gypsum of Table 2 per ton of dry mortar was mixed 40kg (unit quantity 15-16) for each type, and the settling time for each gypsum was measured in Table 3 and the length change rate was shown in FIG. The setting time was measured on the basis of the initial time at 20 ℃ temperature. In addition, the length of the mortar specimen was cured for 24 hours in a constant temperature and humidity chamber of 20 ℃, 95 RH, demolded and measured the initial length using a length change meter, and after the measurement again put into a constant temperature and humidity chamber of 20 ℃, 60 RH It was measured after curing at predetermined intervals of measurement, that is, 7 days and 28 days.

구분division 제조방법Manufacturing method 1One 이수석고Gypsum plaster 대기중에서 2일간건조, 자유수제거2 days drying in the air, free water removal 22 반수석고Half gypsum 건조기에서 120℃로 2시간제조2 hours at 120 ℃ 33 무수석고AAnhydrous Gypsum A 소성로에서 500℃로 1시간소성1 hour firing at 500 ° C in a kiln 44 무수석고BAnhydrous Gypsum B 소성로에서 800℃로 1시간소성1 hour firing at 800 ° C in a kiln 55 무수석고CAnhydrous Gypsum C 약 900∼1,200℃에서 소성Firing at about 900 to 1,200 ° C

배합NoFormulation No 1One 22 33 44 55 응결(시:분)Condensation (hour: minute) 9:039:03 8:408:40 6:006:00 6:406:40 9:429:42

표 3에 나타난 바와 같이, 무수석고(500℃), 무수석고(800℃), 반수석고, 이수석고, 무수석고(900℃이상)순으로 응결발현하였다. 특히, 무수석고(900℃이상)의 경우 응결지연현상이 두드러지게 나타나는데, 이는 석고소성 및 소성석고의 품질영향으로 판단되었다.As shown in Table 3, coagulation and expression were performed in the order of anhydrous gypsum (500 ℃), anhydrous gypsum (800 ℃), hemihydrate gypsum, dihydrate gypsum, anhydrous gypsum (above 900 ℃). In particular, in the case of anhydrous gypsum (above 900 ℃), the condensation delay phenomenon was remarkable, which was judged as the quality effect of gypsum firing and calcined gypsum.

석고의 종류별 길이변화(팽창, 수축)는 도 1에 나타난 바와 같이, 무수석고 3종의 경우 동등수준의 팽창율을 나타냈으나, 반수석고 및 이수석고의 경우 미소하게 팽창이 저하되었다. 이는 팽창반응을 일으키는 3종의 경우 SO3함유율이 동일수준이나 반수석고, 이수석고 순으로 함유율이 저하하기 때문인 것으로 판단되었다.As shown in FIG. 1, the length change (expansion and contraction) of each gypsum showed the same level of expansion rate for the three types of anhydrous gypsum, but slightly diminished in the case of hemihydrate gypsum and dihydrate gypsum. The reason for this is that the content of SO 3 in the three species causing expansion reaction decreases in the order of the same level but in the order of hemihydrate gypsum and dihydrate gypsum.

[실시예 2]Example 2

석유 코우크스 연소재, 생석회, 석고, 석탄회(당진화력발전소)를 표 5와 같이 배합한 수축저감재를 건조몰탈 1톤당 각각 50kg혼합하고(단위수량 15∼16), 응결시간을 측정하여 표 6에 나타내고 길이변화율을 측정하여 도 2에 나타내었다. 생석회는 표 4에 의 생석회더스트와 생석회B급을 1:1로 혼합하여 사용하였으며, 모래의 조립율은 2.8로 하였다.50 kg of shrinkage reducing materials containing petroleum coke combustors, quicklime, gypsum and coal ash (Dangjin Thermal Power Plant) as shown in Table 5 were mixed 50 kg per ton of dry mortar (15 to 16 units) and the coagulation time was measured. It is shown in Figure 2 and measured the length change rate. Quicklime was used by mixing the quicklime dust and quicklime B grade in 1: 1 in Table 4, and the granulation rate of sand was 2.8.

구분division 화학조성(중량)Chemical composition (weight) CaOCaO SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 MgOMgO Ig-LossIg-Loss 생석회더스트Quicklime Dust 60.8460.84 11.4711.47 22 22 5.395.39 18.318.3 생석회B급Quicklime Class B 80.2680.26 7.87.8 1One 1One 1.21.2 8.78.7 구분division 입도분포(잔량)Particle Size Distribution (Remaining) 300㎛300㎛ 150㎛150 μm 75㎛75 μm PanPan 생석회더스트Quicklime Dust 1414 1616 1616 5454 생석회B급Quicklime Class B 1010 1010 3232 4848

구분division 석유 코우크스 연소재Petroleum coke combustors 생석회quicklime 무수석고(500℃)Anhydrous Gypsum (500 ℃) 석탄회Coal ash 1One 100100 -- -- -- 22 7070 1010 2020 -- 33 5050 1010 2020 2020 44 5050 2020 1010 2020 55 3030 -- 5050 2020 66 3030 1010 4040 2020 77 3030 2020 3030 2020 88 3030 3030 2020 2020 99 3030 4040 1010 2020

구분division 1One 22 33 44 55 66 77 88 99 응결시간(시:분)Condensation time (hours: minutes) 5:055:05 5:205:20 5:405:40 5:455:45 6:156:15 6:006:00 6:006:00 6:156:15 6:506:50

표 6에 나타난 바와 같이, 수축저감재로 석유코우크스 연소재를 100사용하는 것 보다는 생석회, 무수석고, 석탄회를 혼합하여 사용하는 경우에 전반적으로 응결시간이 지연됨을 알 수 있었다.As shown in Table 6, it was found that the condensation time was delayed in the case of using quicklime, anhydrous gypsum and coal ash rather than using 100 petroleum coke combustors as shrinkage reducing materials.

석유코우크스 연소재를 30사용하는 경우(No 5,6,7,8,9)에 있어 응결시간은생석회 혼합비율이 높을 때 응결지연시간이 커짐을 알 수 있었다.In the case of using 30 petroleum coke combustors (No 5, 6, 7, 8, 9), it was found that the setting time was increased when the mixing ratio of quicklime was high.

[실시예 3]Example 3

시멘트에 상기 표 5의 7번의 조성을 갖는 수축저감재를 5∼25배합하고, 모래와 배합하여 몰탈로 만들고, 이 몰탈의 물성을 측정하여 표 8에 나타내었다.5 to 25 shrinkage reducing materials having the composition of Table 7 in cement 5 were mixed, mixed with sand to form mortar, and the physical properties of the mortar were measured and shown in Table 8.

몰탈의 길이변화는 공시체로 제작하여 건조조건과 재령에 따른 길이 변화를 측정하였으며, 몰탈 반죽시 혼합수량은 일반몰탈로 KSL 5220 시멘트계 건조 모르타르에 규정된 흐름도 100±5를 발현하는 양을 정하여 시험하였다.The change of length of mortar was made by specimen and the change of length according to drying condition and age was measured. The mixing amount of mortar was tested by specifying the amount of 100 ± 5 flow rate defined in KSL 5220 Cement-based dry mortar with general mortar. .

재료material 결합제(시멘트+수축저감재)Binder (Cement + Shrinkage Reducing Material) 모래(건조모래)Sand (dry sand) water 배합비Compounding cost 280280 720720 155155

결합제중수축저감재의 첨가량(중량)Amount of weight reduction in binders 흐름도()Flowchart () 공기량()Air volume () 압축강도(kgf/cm2)Compressive strength (kgf / cm 2 ) 길이변화(×10-5)Length change (× 10 -5 ) 7일7 days 28일28 days 7일7 days 28일28 days 55 9898 13.813.8 175175 248248 245245 -320-320 1010 9696 14.214.2 171171 235235 420420 -270-270 2020 9494 14.514.5 159159 220220 525525 8585 2525 9090 14.714.7 140140 208208 640640 110110 일반몰탈(시멘트+모래)General mortar (cement + sand) 100100 13.013.0 180180 255255 -410-410 -920-920

수축 저감재를 10함유하는 몰탈은 길이 변화가 거의 없는 것으로 나타나서 목적하는 균열효과가 나타날 것으로 기대하였으나, 실제 가공시에는 균열이 나타났고, 팽창효과가 있는 수축저감재를 20∼25함유하는 경우에 균열이 나타나지 않았다. 이는 건조과정에서 시멘트의 수축을 수축저감재의 팽창이 보상한 것에 기인하는 것으로 여겨진다.Mortar containing 10 shrinkage reducing materials showed little change in length and expected to have the desired cracking effect.However, in the case of actual processing, cracking appeared and 20-25 containing shrinkage reducing materials with expansion effect. No cracks appeared. This is believed to be due to the expansion of the shrinkage reducing material compensated for the shrinkage of the cement during the drying process.

상기 실시예에 따라 제조한 본 발명의 수축 저감재를 일반 시멘트 몰탈과 재래식 믹서기에 투입(시멘트 중량비 25)하여 건설중인 아파트의 온돌방바닥 및 거실(31평형) 5개소에 두께 50mm로 타설시공한 후 건조 수축에 의한 균열발생여부를 관찰하였다. 몰탈은 타설후 4, 5회의 흙손 누름을 1-2시간 간격으로 행하여 바닥미장마감작업을 완료하였으므로, 소성수축 균열의 발생은 거의 없었다. 2개월 양생후에도 각 온돌 방바닥에는 건조수축 균열이 전혀 나타나지 않아서 난방후 변화과정을 관찰하기 위해 일부세대에 모노륨, 장판지를 깐 후 난방을 1개월 동안 가동하였다. 그 결과, 모노륨, 장판지의 변색은 없었으나, 간혹 균열이 드물게 발생하였다. 균열이 생긴 곳의 몰탈을 파취한 결과, 난방 파이프 피복두께가 부족하여(피복 두게 15mm이내) 발생한 것으로 밝혀졌다. 현장 타설결과, 본 발명에 따른 수축저감재는 균열이 거의 나타나지 않아 온돌마감용 몰탈의 건조 수축 균열 억제 효과가 있는 것으로 나타났다.After the shrinkage reducing material of the present invention prepared according to the above embodiment was put into a general cement mortar and a conventional blender (cement weight ratio 25) and poured into 50 places of ondol floors and living rooms (31 pyeong) of a construction under construction with a thickness of 50 mm. The crack occurrence by dry shrinkage was observed. Since mortar finishes the floor finishing work by pressing the trowel four or five times after pouring for 1-2 hours, there was little occurrence of plastic shrinkage cracking. After curing for 2 months, there was no dry shrinkage crack on each floor of the ondol, so heating was run for 1 month after covering some households with monolium and cardboard to observe the change after heating. As a result, there was no discoloration of monolium and a sheet of paper, but a crack occurred rarely. The mortar of the cracked part was found to be a result of insufficient heating pipe coating thickness (within 15 mm of coating thickness). As a result of the in-site casting, the shrinkage reducing material according to the present invention showed little cracking and had an effect of suppressing dry shrinkage cracking of mortar for ondol finishing.

상술한 바와 같이, 본 발명에서는 초기균열이 발생하지 않음은 물론 28일 압축강도발현율이 높고 계절특성에 따라 차등배합하여 온돌마감미장에 탁월한 특성을 나타내는 시멘트몰탈을 제공할 수 있는 유용한 효과가 있다.As described above, in the present invention, the initial crack does not occur, as well as the 28-day compressive strength expression rate is high, and has a useful effect of providing a cement mortar exhibiting excellent properties for the ondol finisher by differentially mixing according to seasonal characteristics.

Claims (6)

생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스 연소재로 조성되는 시멘트 몰탈용 수축저감재.Quicklime: 10 to 30 wt%, gypsum: 20 to 40 wt%, coal ash: 10 to 20 and shrinkage reducing material for cement mortar composed of the remaining petroleum coke combustors. 제 1항에 있어서, 상기 생석회의 입도는 100메쉬(mesh)이하가 40이상임을 특징으로 하는 시멘트 몰탈용 수축저감재.The shrinkage reducing material for cement mortar according to claim 1, wherein the quicklime has a particle size of less than 100 mesh. 제 1항 또는 제 2항에 있어서, 상기 생석회는The method according to claim 1 or 2, wherein the quicklime is (a) 100메쉬(mesh) 잔체분이 10이하로 CaO가 80∼90의 생석회와(a) 100 mesh residues of 10 or less, and CaO of 80-90 (b) 100메쉬(mesh) 잔체분이 40이상으로 CaO함량이 50∼70의 생석회 더스트를 혼합하여 사용함을 특징으로 하는 시메트몰탈용 수축저감재.(b) Shrinkage reduction material for symmetal mortar, characterized in that the 100 mesh (mesh) residue content is more than 40, CaO content is used by mixing the quicklime dust of 50-70. 제 1항에 있어서, 상기 석고는 동절기에는 무수석고를 하절기에는 이수석고를 사용함을 특징으로 하는 시멘트 몰탈용 수축저감재.The shrinkage reducing material for cement mortar according to claim 1, wherein the gypsum is anhydrous gypsum in winter and dihydrated gypsum in summer. (a) 시멘트:70∼85중량와(a) cement: 70-85 weight and (b) 생석회:10∼30중량, 석고:20∼40중량, 석탄회:10∼20와 나머지 석유 코우크스의 연소재로 조성되는 수축저감재: 15∼30중량를 배합한 원료에, 조립율(F.M) 2.8이상의 모래로 조성되는 되는 온돌마감미장용 시멘트 몰탈.(b) Quicklime: 10 to 30 wt%, gypsum: 20 to 40 wt%, coal ash: 10 to 20 and shrinkage reducing material composed of combustion materials of the remaining petroleum coke: 15 to 30 wt% of the raw material blended, granulation rate (FM) Ondol finishing plaster mortar made of sand of 2.8 or more. 제 5항에 있어서, 상기 생석회의 입도는 100메쉬(mesh)이하가 40이상임을 특징으로 하는 온돌마감미장용 시멘트 몰탈.[6] The cement mortar for finishing plaster of claim 5, wherein the quicklime has a particle size of 100 mesh or less.
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KR101311720B1 (en) * 2013-03-05 2013-09-26 한국세라믹기술원 Contraction reduced cement composite and mortar composite using the cement composite
KR102297320B1 (en) 2021-03-04 2021-09-03 주식회사 수인건설 Expansive Amixture and, concrete composition comprising thereof, repairing method of concrete structure using the same
KR102351741B1 (en) 2020-10-21 2022-01-18 (주)후현엠에스 Additive for concrete comprising Ladle slag and, concrete composition comprising thereof, repairing method of concrete structure using the same

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KR100473507B1 (en) * 2001-05-22 2005-03-08 주식회사 실크로드시앤티 Expanding Admixture for Cement
KR100544062B1 (en) * 2003-07-24 2006-01-23 주식회사 실크로드시앤티 Crack inhibitor for cement mortar

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KR101311720B1 (en) * 2013-03-05 2013-09-26 한국세라믹기술원 Contraction reduced cement composite and mortar composite using the cement composite
KR102351741B1 (en) 2020-10-21 2022-01-18 (주)후현엠에스 Additive for concrete comprising Ladle slag and, concrete composition comprising thereof, repairing method of concrete structure using the same
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