KR100301147B1 - Composition of lamp fuel for green colored flame - Google Patents

Composition of lamp fuel for green colored flame Download PDF

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KR100301147B1
KR100301147B1 KR1019990017036A KR19990017036A KR100301147B1 KR 100301147 B1 KR100301147 B1 KR 100301147B1 KR 1019990017036 A KR1019990017036 A KR 1019990017036A KR 19990017036 A KR19990017036 A KR 19990017036A KR 100301147 B1 KR100301147 B1 KR 100301147B1
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composition
kerosene
green
weight
flame
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KR1019990017036A
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KR20000073621A (en
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김영구
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임진만
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/003Marking, e.g. coloration by addition of pigments
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1291Silicon and boron containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08Inhibitors
    • C10L2230/088Inhibitors for inhibiting or avoiding odor
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/18Function and purpose of a components of a fuel or the composition as a whole for rendering the fuel or flame visible or for adding or altering its color

Abstract

본 발명은 녹색화염의 장식조명을 발현하는 색화염 등유의 조성물관한 것으로, 5-30 중량%의 붕산염, 60-90중량%의 글리세린과 5-20 중량%의 에틸알코올로 구성됨을 특징으로 한다. 또한 글리세린 대신에 프로필렌 글리콜을 포함할 수 있다.The present invention relates to a composition of colored kerosene that expresses decorative lighting of green flame, and is characterized by consisting of 5-30% by weight borate, 60-90% by weight glycerin and 5-20% by weight ethyl alcohol. It may also include propylene glycol instead of glycerin.

Description

녹색화염 등유의 조성물{Composition of lamp fuel for green colored flame}Composition of lamp fuel for green colored flame

본 발명은 녹색의 화염(火焰)을 내는 등유(燈油)의 조성물에 관한 것으로, 특히 실내장식 또는 축제용으로 찬란한 녹색의 불꽃이 발현될 수 있는 등잔불의 연소용 연료로서 사용되는 녹색화염 등유의 조성물에 관한 것이다.The present invention relates to a composition of kerosene that emits a green flame, and in particular, a composition of green flame kerosene used as a fuel for burning lamps in which a brilliant green flame can be expressed for interior decoration or festival use. It is about.

종래 실내장식용 또는 축제용으로서 기존의 투명백색 또는 황색화염을 대신하여 장식효과가 뛰어난 녹색의 화염을 내는 유색의 연료로서 등유가 알려진 바 있다. 이러한 종래의 녹색화염 등유는 전형적으로 연소시 녹색의 화염을 발현하는 동염류(銅鹽類)를 알코올에 용해한 것이 알려져 있다. 그러나 녹색화염을 발현하는 물질인 동염류는 그 자체가 맹독성이고 동염류를 용해하는데 사용된 알코올은 인화성이 강하여 실내장식용 또는 축제용의 등유에 주요구성 성분으로 사용하는 것이 위험하다. 또한 동염류물질은 등잔의 심지에서 연소시 탄화경화되어 등유를 모세관 작용으로 끌어올리는 소위 심지의 심지효과가 떨어져 연소의 연속성이 떨어지는 문제점이 있다.Kerosene has been known as a colored fuel that emits green flames with excellent decorative effect in place of conventional transparent white or yellow flames for indoor decoration or festival use. It is known that such conventional green flame kerosene typically dissolves copper salts in alcohol that express a green flame upon combustion. However, copper salts, which express green flames, are very toxic in themselves and alcohols used to dissolve copper salts are highly flammable, which makes it dangerous to use them as main components in kerosene for interior decoration or festival use. In addition, copper salts have a problem in that the continuity of combustion is lowered by the wicking effect of the so-called wick which is hardened by carbonization during combustion in the wick of the lamp and draws kerosene into capillary action.

본 발명에 있어서는 종래의 이와 같은 점을 감안하여 창안한 것으로, 본 발명의 목적은 유색화염등유에 인체에 유해한 금속염류를 이용하지 아니하고 인체에 무해한 유색발현물질을 이용한 녹색화염의 등유를 제공하는데 있다.The present invention has been made in view of the above-mentioned conventional matters, and an object of the present invention is to provide kerosene of green flames using colored expression substances that are harmless to humans without using metal salts harmful to humans to colored flame kerosene. .

본 발명의 다른 목적은 실내장식용 또는 축제용으로 사용하기 위하여 화재를 유발하는 연료의 인화성이 낮은 물질이 사용되는 녹색화염의 등유를 제공하는데 있다.It is another object of the present invention to provide a kerosene of green flames in which a material having a low flammability of a fuel that causes a fire is used for interior decoration or festival use.

본 발명의 또 다른 목적은 연소물이 주위공기를 오염시키지 아니하고 냄새나 연기가 발생되지 아니하며 등잔의 심지가 경화되지 않는 녹색화염의 등유를 제공하는데 있다.It is another object of the present invention to provide a kerosene of green flames in which the combustion products do not pollute the surrounding air, no smell or smoke are generated, and the wick of the lamp is not cured.

이를 위하여, 본 발명에 있어서는 인체에 무해하여 여성화장품 또는 몸세척 소독수에 흔히 사용되는 붕산염을 녹색화염의 발현물질로 사용하고 연료구성요소로서 안정된 지속연소가 이루어지도록 하는 글리세린 또는 프로필렌 글리콜과 알코올 용액을 사용하여 이들 성분의 적정조성으로 상기 언급한 녹색화염 등유의 조성물을 제공한다.To this end, in the present invention, a glycerol or propylene glycol and alcohol solution is used, which is harmless to the human body and uses borate which is commonly used in feminine cosmetics or body wash disinfectant water as an expression material of green flame and enables stable sustained combustion as a fuel component. To provide the composition of the above-mentioned green flame kerosene in the proper composition of these components.

이러한 본 발명은 녹색화염의 장식조명을 발현하는 녹색화염 등유의 조성물로서 5-30 중량%의 붕산염, 60-90중량%의 글리세린과 5-20 중량%의 에틸알코올로 구성됨을 특징하고 글리세린 대신에 프로필렌 글리콜을 사용할 수 있다.The present invention is a composition of green flame kerosene expressing the decorative lighting of the green flame, characterized in that consisting of 5-30% by weight of borate, 60-90% by weight of glycerin and 5-20% by weight of ethyl alcohol, instead of glycerin Propylene glycol can be used.

본 발명에 있어서는 녹색화염을 발현할 수 있는 물질로서 붕산염을 이용하고 주연소물질로서는 글리세린 또는 프로필렌 글리콜, 디프로필렌 글리콜, 디에틸렌글리콜, 트리에타놀아민 또는 에틸렌 글리콜 등의 글리콜류를 사용하고 조연제로서는 에틸알코올, 디메틸포름아미드, 메틸알코올, 이소프로필알코올, 아미노알코올 또는 아세톤이 이용된다.In the present invention, borate is used as a material capable of expressing a green flame, and glycols such as glycerin or propylene glycol, dipropylene glycol, diethylene glycol, triethanolamine, or ethylene glycol are used as the main combustion material. Ethyl alcohol, dimethylformamide, methyl alcohol, isopropyl alcohol, amino alcohol or acetone are used.

본 발명을 실시예에 의거하여 설명하면 다음과 같다.The present invention will be described based on the following examples.

실시예 1Example 1

본 발명의 녹색화염 등유의 조성물의 조성은 다음과 같다.The composition of the composition of the green flame kerosene of the present invention is as follows.

성분ingredient 비율ratio

붕산염 5-30 중량%Borate 5-30% by weight

글리세린 60-90 중량%Glycerin 60-90 wt%

에틸알코올 5-20 중량%Ethyl alcohol 5-20% by weight

상기 조성의 성분을 균일하게 교반하여 본 발명의 녹색화염 등유의 조성물을 얻는다. 붕산염은 분자내에 OH기를 가지므로 에틸알코올에 용해되는 성질을 갖는다. 글리세린은 무색의 점성을 갖는 액체로 에틸알코올과 혼합되었을 때 이 에틸알코올과 함께 가연성을 가지므로 연소연료로 사용할 수 있으며, 상기 조성물을 등유로 사용하였을 때 붕산염의 연소로 녹색화염을 얻고 실질적인 연료인 글리세린과 에틸알코올의 연소는 지속적인 연소가 이루어질 수 있도록 한다. 이러한 등유조성물의 연소시 상기 언급된 같은 찬란한 녹색의 장식조명을 얻을 수 있으며 연소물이 인체에 유해하거나 공해물질을 생성하지 아니하며 등잔의 심지가 경화되지 않도록 하고 등유조성물 자체는 발화점이 비교적 높으므로 부주의로 등유조성물이 인화되지 아니한다. 한편 조연제로서 사용되는 에틸알코올 대신에 디메틸포름아미드, 메틸알코올, 이소프로필알코올, 아미노알코올 또는 아세톤이 사용될 수 있다.The component of the said composition is stirred uniformly, and the composition of green flame kerosene of this invention is obtained. Borate has the property of dissolving in ethyl alcohol because it has an OH group in the molecule. Glycerin is a colorless, viscous liquid that is combustible with ethyl alcohol when mixed with ethyl alcohol, and thus can be used as a combustion fuel.When the composition is used as kerosene, it obtains a green flame by burning borate and is a practical fuel. Combustion of glycerin and ethyl alcohol ensures continuous combustion. When the kerosene composition is burned, it is possible to obtain the same bright green decorative lighting as mentioned above, and the combustion product is not harmful to the human body or produces pollutants, so that the core of the lamp is not cured and the kerosene composition itself has a relatively high ignition point. Kerosene compositions are not flammable. On the other hand, dimethylformamide, methyl alcohol, isopropyl alcohol, amino alcohol or acetone may be used instead of ethyl alcohol used as a supporting agent.

실시예 2Example 2

본 발명의 다른 실시예로서 녹색화염 등유의 조성물의 조성은 다음과 같다.As another embodiment of the present invention, the composition of the green flame kerosene composition is as follows.

성분ingredient 비율ratio

붕산염 5-30 중량%Borate 5-30% by weight

프로필렌 글리콜 60-90 중량%Propylene Glycol 60-90 wt%

에틸알코올 5-20 중량%Ethyl alcohol 5-20% by weight

상기 조성의 성분은 실시예 1의 글리세린 대신에 프로필렌 글리콜이 사용된 것을 제외하고는 실시예 1과 동일하고 성분비 또한 동일하다. 프로필렌 글리콜은 무색의 점성을 갖는 액체로서 에틸알코올에 용해되어 각 성분과 함께 안정된 용액을 얻을 수 있다. 상기 조성물을 등유로 사용하였을 때 붕산염의 연소로 녹색화염을 얻고 실질적인 연료인 프로필렌 글리콜과 에틸알코올의 연소는 지속적인 연소가 이루어질 수 있도록 한다. 이러한 등유조성물의 연소시 역시 상기 언급된 같은 찬란한 녹색의 장식조명을 얻을 수 있으며 연소물이 인체에 유해하거나 공해물질을 생성하지 아니하며 등잔의 심지가 경화되지 않도록 하고 등유조성물 자체는 발화점이 비교적 높으므로 부주의로 등유조성물이 인화되지 아니한다. 주연소물로 사용되는 프로필렌 글리콜은 디프로필렌 글리콜, 디에틸렌 글리콜, 트리에타놀아민 또는 에틸렌 글리콜 등의 다른 글리콜류가 사용될 수 있으며, 조연제는 상기 실시예 1의 경우와 마찬가지로 에틸알코올 대신에 디메틸포름아미드, 메틸알코올, 이소프로필 알코올, 아미노알코올 또는 아세톤이 사용될 수 있다.The components of the composition are the same as in Example 1 except that propylene glycol is used instead of the glycerin of Example 1, and the component ratio is also the same. Propylene glycol is a colorless liquid that can be dissolved in ethyl alcohol to obtain a stable solution with each component. When the composition is used as kerosene, the combustion of borate yields a green flame, and the combustion of propylene glycol and ethyl alcohol, which are substantial fuels, enables continuous combustion. When the kerosene composition is burned, it is possible to obtain the same brilliant green decorative lighting as mentioned above, and the combustion product does not cause harmful to humans or pollutants, and the core of the lamp is not cured and the kerosene composition itself has a relatively high ignition point. The kerosene composition is not flammable. As the propylene glycol used as the main combustion product, other glycols such as dipropylene glycol, diethylene glycol, triethanolamine, or ethylene glycol may be used, and the stiffener is dimethylformamide instead of ethyl alcohol as in Example 1 above. , Methyl alcohol, isopropyl alcohol, amino alcohol or acetone can be used.

이와 같은 본 발명의 녹색화염 등유의 조성물은 인체에 유해한 금속염류를 이용하지 아니하고 인체에 무해한 유색발현물질을 이용한 녹색화염의 등유를 제공하는 것으로, 실내장식용 또는 축제용으로 사용하기 위하여 화재를 유발하는 연료의 인화성이 낮은 물질이 사용되며 연소물이 주위공기를 오염시키지 아니하고 냄새나 연기가 발생되지 아니하며 등잔의 심지가 경화되지 않는 잇점을 제공한다.Such a composition of the green flame kerosene of the present invention is to provide a kerosene of the green flame using a color expression material harmless to the human body without using metal salts harmful to the human body, causing fire to use for indoor decoration or festival use The low flammability of the fuel is used and the combustion products do not contaminate the surrounding air, do not produce odors or smoke, and the wick of the lamp does not harden.

Claims (3)

녹색화염의 장식조명을 발현하는 색화염 등유의 조성물에 있어서, 5-30 중량%의 붕산염, 60-90중량%의 글리세린과, 5-20 중량%의 에틸알코올로 구성됨을 특징으로 하는 녹색화염 등유의 조성물.Green flame kerosene comprising a composition of colored flame kerosene expressing decorative lighting of green flame, comprising 5-30% by weight of borate, 60-90% by weight of glycerin, and 5-20% by weight of ethyl alcohol. Composition. 제1항에 있어서, 글리세린 대신에 60-90 중량%의 프로필렌 글리콜을 포함함을 특징으로 하는 녹색화염 등유의 조성물.The composition of the green flame kerosene according to claim 1, comprising 60-90% by weight of propylene glycol instead of glycerin. 제1항 또는 제2항에 있어서, 에틸알코올 대신에 디메틸포름아미드을 포함함을 특징으로 하는 녹색화염 등유의 조성물.The composition of green flame kerosene according to claim 1 or 2, comprising dimethylformamide instead of ethyl alcohol.
KR1019990017036A 1999-05-12 1999-05-12 Composition of lamp fuel for green colored flame KR100301147B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100440724B1 (en) * 2001-12-26 2004-07-21 주식회사 세인트크로스 Composition of lamp fuel for colored flames and manufacturing method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7556658B2 (en) 2002-08-22 2009-07-07 Hwalim Technological Co., Ltd. Fuel composition and a device for colored flames

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100440724B1 (en) * 2001-12-26 2004-07-21 주식회사 세인트크로스 Composition of lamp fuel for colored flames and manufacturing method thereof

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