KR100295009B1 - Structural materials based on ocher and oyster shells and their manufacturing methods - Google Patents

Structural materials based on ocher and oyster shells and their manufacturing methods Download PDF

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KR100295009B1
KR100295009B1 KR1019980037461A KR19980037461A KR100295009B1 KR 100295009 B1 KR100295009 B1 KR 100295009B1 KR 1019980037461 A KR1019980037461 A KR 1019980037461A KR 19980037461 A KR19980037461 A KR 19980037461A KR 100295009 B1 KR100295009 B1 KR 100295009B1
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loess
oyster shell
product
oyster
ocher
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KR1019980037461A
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Korean (ko)
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KR20000019396A (en
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여기정
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여기정
주식회사 해중
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/023—Fired or melted materials
    • C04B18/025—Grog
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/20—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded
    • B28B3/22—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded by screw or worm
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/6261—Milling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Civil Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

본 발명은 황토 및 굴껍질을 주재로 한 구조재(주용도: 인공어초, 벽돌, 보도블럭, 방음벽, 경계석, 중앙분리대 등) 및 그 제조방법에 관한 것이다.The present invention relates to a structural material based on loess and oyster shells (main use: artificial fishes, bricks, sidewalk blocks, soundproof walls, boundary stones, median strips, etc.) and a method of manufacturing the same.

즉, 본 발명은 굴껍질 및 황토를 약 400℃의 온도에서 건조시키고, 굴껍질 및 황토의 분쇄입도가 각각 100MESH 이상의 통과분을 사용토록 체분리하며, 혼합기를 이용하여 RPM이 약 25∼30 정도되는 속도로 수분이 약 20∼25% 정도 되도록 혼합하고, 진공토련기 70HP이상, 진공도 74kg/㎠ 이상, 성형수분이 약 20∼25% 정도 되도록 진공토련기를 이용하여 제품을 성형한 후, 제품의 건조수분이 약 3.0% 이하가 되도록 건조대차에 적재하여 건조시키며, 약 1250℃∼1350℃의 온도에서 제품을 소성가공하여 구조재를 얻음으로서 다용도로 활용될 수 있으며, 특히 인공어초 등으로 사용할 경우 해양오염 방지 등에 탁월한 효과를 제공할 수 있는 것이다.That is, the oyster shell and the loess are dried at a temperature of about 400 ° C., and the oyster shell and the loess are separated from each other by using a passing powder having a particle size of 100 MESH or more, And the product is molded using a vacuum kneader such that the vacuum kneader is at least 70HP, the vacuum degree is at least 74kg / cm 2, and the molding water is about 20 to 25%. It can be used for various purposes by obtaining the structural material by calcining the product at a temperature of about 1250 ° C. to 1350 ° C. by being loaded on a drying drum to have a dry moisture of about 3.0% or less, and in particular, It is possible to provide an excellent effect on pollution prevention and the like.

Description

황토와 굴껍질을 주재로 한 구조재 및 그 제조방법Structural materials based on ocher and oyster shells and their manufacturing methods

본 발명은 황토(loess) 및 굴(oyster)껍질을 주재(主材)로 한 구조재(주용도: 인공어초, 벽돌, 보도블럭, 방음벽, 경계석, 중앙분리대 등) 및 그 제조방법에 관한 것이다.The present invention relates to a structural member made of loess and oyster shell as a main material (principal use: artificial fish candle, brick, sidewalk block, soundproof wall, boundary stone, median separator, etc.) and a manufacturing method thereof.

통상 일반 시멘트로 제조된 각종의 구조물이나 건축구조물 등의 평균수명은약 40∼50년 정도로 알려져 있으나, 철근 콘크리트로 구축된 구조물의 경우 그 수명은 철근의 산화작용으로 인하여 이 보다 더욱 짧은 것으로 알려져 있다.Generally, the average number of structures or structures made of ordinary cement is known to be about 40 to 50 years. However, in the case of a structure constructed of reinforced concrete, its lifespan is known to be shorter due to the oxidizing action of reinforcing bars.

특히 해수내에 설치되는 인공어초와 같은 구조물은 해수내에서 염분으로 인하여 심재 역할을 위해 구조물 내부에 심어놓은 철근의 산화작용이 더욱 급속히 진전되어 약 4∼5년 정도이면 철근의 산화로 인한 구조물의 파열 및 분리가 이루어지고, 분리된 구조물의 파편과 부식된 철근의 슬러지 등이 해수를 오염시킴은 물론 해양자원인 해초류, 어패류의 번식에까지 위해를 가하고 있는 실정이다.In particular, a structure such as an artificial fish that is installed in the seawater has an oxidation action of the reinforcing bar implanted in the inside of the structure for the core role due to salinity in the seawater more rapidly, and rupture of the structure due to the oxidation of the reinforcing bar takes about 4 to 5 years And segregation of separated structure and sludge of corroded reinforcing steel not only pollute seawater, but also harm the seaweed and the breeding of seafood.

또한 이러한 시멘트로 제작된 인공어초의 경우에는 강알카리 특성을 가지므로 일정기간(약 3개월 정도; 본 발명자가 실험한 바에 의하면 약 1∼2년 정도)이 경과되지 않으면 인공어초를 해수에 투입시 바로 해초류 등이 번식치 못하는 등의 문제점을 가지고 있었던 것이다.In addition, since the artificial fish made from such cement has strong alkaline properties, if the artificial fish is added to the seawater for a certain period (about 3 months or about 1 to 2 years according to the inventor's experiment) And seaweeds were not able to reproduce.

그리고 일반 철근콘크리트 구조물의 경우 압축강도 면에서도 1일 기준 통상약 82.Okg/㎠ 정도밖에 되지 않아 1개월 이상 양생시키지 않으면 각종 구조물로서사용키 어려웠고 특히 단시간의 매우 높은 강도를 가진 대체 구조물의 보완이 필요하였던 것이다.In case of ordinary reinforced concrete structures, it is only about 82.Okg / ㎠ in terms of compressive strength, so it is difficult to use it as various structures unless it is cured for more than one month. In particular, It was necessary.

근자에 들어서는 각종 시멘트의 모르타르(mortar) 압축강도를 향상키 위하여초속경성(超速硬性) 광물을 혼합한 시멘트가 시중에 선보이고 있으나, 이 또한 자연 친화적이지 못하여 상기와 같은 문제점을 안고 있는 것이다.In order to improve the mortar compressive strength of various cements in recent years, cement mixed with ultra fast hard minerals has been introduced in the market, but this is also not environmentally friendly and thus has the above problems.

이에 본 발명에서는 지금까지 각종 구조물의 재료로 사용되었던 시멘트 및 철근콘크리트 등의 문제점을 일소할 수 있는 자연 친화적인 신규한 각종 구조물(예; 인공어초, 벽돌, 보도블럭, 방음벽, 경제석, 중앙분리대 등)의 대체재로서의 구조재와, 상기 구조재의 제조방법을 제공함에 기술적 과제를 두고 본 발명을 완성한 것이다.Therefore, in the present invention, a variety of naturally friendly new structures (for example, artificial fishes, bricks, sidewalk blocks, soundproof walls, economic seats, median seals, etc.) that can solve the problems of cement and reinforced concrete, And the like, and a method for producing the above structural material, and has completed the present invention with a technical problem.

제1도는 본 발명의 바람직한 일실시예를 설명키 위한 제조공정도.FIG. 1 is a manufacturing process diagram for explaining a preferred embodiment of the present invention. FIG.

제2(a)도는 본 발명에 의한 소재별 EDS 화학분석도.FIG. 2 (a) is an EDS chemical analysis chart for each material according to the present invention. FIG.

제2(b)도는 본 발명에 의한 소재별 EDS 화학분석도.FIG. 2 (b) is a chemical analysis chart of EDS according to the present invention.

제2(c)도는 본 발명에 의한 소재별 EDS 화학분석도.FIG. 2 (c) is a chemical analysis chart of EDS according to the present invention.

제3(a)도는 본 발명에 의한 소재별 SEM 조직촬영도.FIG. 3 (a) is a SEM photograph of the material according to the present invention. FIG.

제3(b)도는 본 발명에 의한 소재별 SEM 조직촬영도.Fig. 3 (b) is a SEM photograph of the material according to the present invention. Fig.

제3(c)도는 본 발명에 의한 소재별 SEM 조직촬영도.Figure 3 (c) is a SEM chart of the material according to the present invention.

제1도는 본 발명에서 소망하는 목적을 달성하기 위한 구조재의 제조공정을 보인 블럭도이며, 제2(a)도 내지 제3(c)도는 본 발명에 의한 소재별 EDS 화학분석도, 본 발명에 의한 소재별 SEM 조직촬영도 등으로서, 이를 참고로 하여 본 발명을 상세히 설명하면 다음과 같다.FIG. 1 is a block diagram showing a manufacturing process of a structural member for achieving a desired object in the present invention. FIG. 2 (a) through FIG. 3 (c) The SEM histogram of the material, and the like, and the present invention will be described in detail with reference to the following.

[제조방법][Manufacturing method]

(1) 굴껍질 및 황토의 건조(1) drying oyster shells and loess

굴껍질 및 황토를 약 400℃의 온도에서 건조시킨다.Oyster shell and loess are dried at a temperature of about 400 ° C.

(2) 굴껍질 및 황토의 체분리(2) Sieve separation of oyster shell and loess

굴껍질 및 황토의 분쇄입도가 각각 100MESH 이상으로 통과분을 사용토록 체 분리한다.Oyster shells and loess are each separated by using the pulverized powder having a particle size of 100 MESH or more.

(3) 굴껍질 및 황토 비율별 혼합(3) mixing by oyster shell and loess ratio

원통형 혼합기(교반기)를 이용하여 RPM이 약 25∼30 정도되는 속도로 수분이 약 20∼25% 정도 되도록 혼합한다.Mix using a cylindrical mixer (agitator) at a rate of about 25-30 RPM with about 20-25% moisture.

(4) 진공토련기 이용 제품성형(4) Molding of products using vacuum punching machine

진공토련기 압력이 약 70HP이상, 진공도 74kg/㎠ 이상, 성형수분이 약 20∼25% 정도 되도록 진공토련기를 이용하여 제품을 성형한다.The product is molded using a vacuum pouring machine so that the vacuum sowing machine pressure is about 70HP or more, the vacuum degree is 74kg / cm 2 or more, and the molding water is about 20 to 25%.

(5) 선반용 건조대차 적재(5) Loading of dryers for shelves

제품의 건조수분이 약 3.0% 이하가 되도록 건조대차에 적재하여 건조시킨다.Load the product on the drying rack so that the moisture content of the product is about 3.0% or less.

(6) 제품소성(6) Product baking

약 1250℃∼1350℃의 온도에서 제품을 소성가공한다. 소성시의 오일은 가스및 경유 등을 사용한다.The product is calcined at a temperature of about 1250 ° C to 1350 ° C. Gas and diesel are used for the oil at the time of firing.

(7) 제품검사(7) Product Inspection

제품의 치수 및 강도, 기타의 시험을 행한다.The dimensions and strength of the product, and other tests.

(8)출하(8) Shipment

제품을 포장하여 출하한다.Pack the product and ship it.

상기와 같은 제조방법으로 본 발명의 구조재를 제조하되, 하기와 같은 점에특히 유의토록 한다.The structural material of the present invention is prepared by the above-mentioned production method, and the following points are particularly noteworthy.

즉, 굴껍질은 반드시 완전건조 및 소성(약 400∼600℃)한 후 분쇄하여 사용토록하며, 굴껍질의 분쇄입도는 1,000 MESH 표준체 통과분을 반드시 사용하여야 하는데, 굴껍질 입자가 미쇄할수록 황토와 비율별 혼합시 소결이 용이하게 되어 제품강도를 향상시킬 수 있다.That is, the oyster shell must be completely dried and calcined (about 400 to 600 ° C) and then used for grinding. The grain size of the oyster shell should be 1,000 MESH standard passing powder. Sintering is facilitated when mixing ratio by weight, and the product strength can be improved.

또한 굴껍질 및 황토 조합시 완전히 혼합이 되도록 교반기 등의 설비장치를구비하여야 하는데, 본 발명자가 분석한 바에 따르면 양자의 혼합이 균일하게 이루어지지 않으면 제품소성 후 강도에 막대한 영향을 미치는 것을 확인하였다.Also, it is necessary to provide an equipments such as a stirrer so as to be completely mixed when the oyster shell and the loess soil are combined. According to the analysis by the present inventor, it has been confirmed that if the mixing of the two is not uniform, the strength after the baking is greatly affected.

굴껍질과 황토의 적정 조합비를 데이터에 따른 물성을 체크해 본 결과 하기의 표 1과 같이 굴껍질의 사용량을 약 4∼6 중량% 정도 첨가시 가장 좋은 물성(즉제품강도, 수축율, 흡수율, 1g-loss)을 가지는 것으로 밝혀졌다. 또한 굴껍질의 사용량을 전기한 비율로 배합시에는 황토성분과 잘 결합 용융되며 제품강도 역시 증가시킨다.As shown in Table 1 below, when the amount of oyster husk used was about 4 to 6 wt%, the best physical properties (i.e., product strength, shrinkage, absorption rate, 1 g- loss. In addition, when the amount of oyster shell used is mixed with the ratio of the oyster shell, the strength of the product is also increased due to the good fusion with the ocher component.

상기 과정에서 굴껍질 사용량을 황토와 배합비를 약 4∼6 중량% 정도로 배합하지만 이 배합비는 중량비이기 때문에 실제로는 상당량의 굴껍질이 사용되어 폐기물을 재활용하는 효과 역시 지대한 것이다.In the above process, the amount of oyster shell used is about 4 to 6 wt% in combination with the loess, but since the blending ratio is a weight ratio, a substantial amount of oyster shell is actually used, and the effect of recycling waste is also great.

본 발명의 발명자는 본 발명의 구조재 시편 물성 테스트를 하기와 같은 실시예로 하여 다음과 같은 결과를 얻을 수 있었다The inventor of the present invention has succeeded in testing the properties of the structural specimen of the present invention as follows:

[실시예 1][Example 1]

하기 테스트에 있어서 테스트 방법 및 조건은 다음과 같이 행하였다.In the following test, the test method and conditions were as follows.

황토와 굴껍질은 약 400℃에서 9시간 건조하고, 황토는 건조 후 분쇄하여 100MESH 표준체로 분리하였으며, 굴껍질은 건조 후 분쇄하여 100MESH 표준체로 분리하였다.The ocher and oyster shells were dried at about 400 ° C for 9 hours. The loess was dried and then pulverized and separated into 100 MESH standards. The oyster shells were dried and pulverized and separated into 100 MESH standards.

성형몰드는 길이 12cm, 두께 1.5cm 짜리를 각 5개씩 성형하여 사용하되, 성형 수분은 8%, 성형압력은 600kg/㎠으로 하였으며, 성형시편은 400℃ 건조기 함량이 될 때 까지 건조(9hr)하였다.The forming mold was molded by 5 pieces each having a length of 12 cm and a thickness of 1.5 cm. The molding water was 8% and the molding pressure was 600 kg / cm 2. The molded piece was dried (9 hr) .

전기로에서 1250℃의 온도로 약 12시간(hr) 동안 시편을 소성 후 물리적 성질 및, 화학적 성분을 테스트 하였다.The specimens were fired in an electric furnace at a temperature of 1250 ° C for about 12 hours (hr), and physical properties and chemical composition were tested.

하기의 표 2내지 4에서;In Tables 2 to 4 below,

소성수축율 (단위: %)은 [(건조길이-소성길이)/건조길이]×100The plastic shrinkage ratio (unit:%) is [(dry length - firing length) / dry length] × 100

흡수율(단위: %)은 [(포화무게-소성무게)/포화무게]×100Absorption rate (unit:%) is [(saturated weight - plastic weight) / saturated weight] × 100

lg-loss(단위: %)는 [(건조무게-소성무게)/건조무게]×100lg-loss (unit:%) is [(dry weight - plastic weight) / dry weight] × 100

압축강도(M, 단위: kg/㎠)는 (3PL/2bd2)×50The compressive strength (M, unit: kg / cm 2) is (3PL / 2bd 2 ) x 50

과 같은 식으로 구하였다..

단, 상기 식에서However,

M은 압축강도(kg/㎠)M is the compressive strength (kg / cm 2)

P는 최대파괴하중(kg/㎠)P is the maximum breaking load (kg / ㎠)

L은 시편길이(cm)L is the specimen length (cm)

b는 시편폭(cm)b is the specimen width (cm)

d는 시편의 두께(cm)를 나타낸 것이다and d is the thickness (cm) of the specimen

(비고: 굴껍질은 참비중이 2.1∼2.6, 부피비중이 0.2∼0.4이며, 화학성분은 CaO가 90% 이상이며 소성온도 800∼900℃에서 CO2를 방출하며, 주로 건축자재, 단열재 및 요업 등에 사용됨).(Note: Oyster shells have a true specific gravity of 2.1 to 2.6, a bulk specific gravity of 0.2 to 0.4, a chemical composition of 90% or more of CaO and emit CO 2 at a calcination temperature of 800 to 900 ° C., and mainly contain building materials, Etc.).

이상에서 상세히 살펴 본 바와 같이 본 발명에서 제공하는 황토 및 굴껍질을주재로 한 구조재는 하기와 같은 다수의 효과를 가진다.As described in detail above, the structural material based on ocher and oyster shells provided in the present invention has a number of effects as described below.

즉 본 발명의 구조재는 기존에 시멘트, 철근콘크리트 등으로 제조되는 각종의 구조물, 즉 인공어초, 벽돌, 보도블럭, 방음벽, 경계석, 중앙분리대 등의 대체재로서 다양하게 활용될 수 있어 산업적 파급효과가 지대하며, 인공어초 등으로 해수에서 사용시 굴껍질과 황토는 흡수력이 강하여 해수중의 각종 부유물 및 오염물질을 흡착하여 해양오염을 급격히 감소시킬 수 있는 것이다.That is, the structural material of the present invention can be widely used as a substitute for various structures made of cement, reinforced concrete and the like, namely, artificial fish meal, brick, sidewalk, soundproof wall, When oyster shells and ocher are used in seawater with artificial fishes, etc., oyster shells and ocher have strong absorbing power, so that they can adsorb various floating matters and contaminants in the seawater and drastically reduce marine pollution.

그리고 본 발명의 구조재를 인공어초로 사용할 경우 그 재질특성이 중성으로바로 친화력이 뛰어나 투입 즉시 각종 해초류와 어패류 등이 기생할 수 있으며, 장기간이 경과되어 일부가 파손된다 하더라도 해양의 오염방지작용은 지속되어 인공어초 본래의 의도에 부합할 수 있는 것이며, 황토에서 방사되는 원적외선은 방사율이 약 75∼78% 정도로 높아 해양살균 효과 및 오염도 감소에 크게 기여할 수 있는등 그 기대되는 효과가 다대한 획기적인 발명이다.When the structural material of the present invention is used as an artificial fish seed, its material properties are neutral and its affinity is immediately favorable. Therefore, various seaweeds and fishes and shellfishes can be parasitized immediately upon input. It can meet the original intention of artificial fish and the far infrared rays radiated from the loess have a high emissivity of about 75 ~ 78%, which can greatly contribute to the effect of marine sterilization and pollution.

Claims (4)

완전건조 및 소성과 분쇄공정을 거친 굴껍질과, 건조 및 분쇄된 황토와, 상기 굴껍질과 황토의 중량 배합비가 굴껍질은 약 4∼6중량%, 황토는 약 94∼96%로 배합되어 소성가공된 것을 특징으로 하는 황토 및 굴껍질을 주재로 한 건축구조재.The oyster shell and the loess are mixed in an amount of about 4 to 6% by weight and about 94 to 96% by weight, respectively, Structural structural material based on ocher and oyster shell characterized by processed. 제1항에 있어서; 상기 굴껍질의 분쇄입도는 100MESH 표준체 통과분인 것을 특징으로 하는 황토 및 굴껍질을 주재로 한 건축구조재.The method of claim 1, further comprising: Characterized in that the grain size of the oyster shell is 100 MESH standard passing fraction. 제1항에 있어서; 상기 굴껍질의 소성온도는 약 1250∼1350℃로 소성된 것임을 특징으로 하는 황토 및 굴껍질을 주재로 한 건축구조재.The method of claim 1, further comprising: Wherein the baking temperature of the oyster shell is fired at about 1250 to 1350 ° C. 굴껍질 및 황토를 약 400℃의 온도에서 건조시키고, 굴껍질 및 황토의 분쇄입도가 각각 100MESH의 통과분을 사용토록 체분리하며, 혼합기를 이용하여 RPM이 약 25∼30 정도되는 속도로 수분이 약 20∼25% 정도되도록 혼합하고, 진공토련기 압력이 약 70HP이상, 진공도 74kg/㎠, 성형수분이 약 20∼25% 정도 되도록 진공토련기를 이용하여 제품을 성형한 후, 제품의 건조수분이 약 3.0% 이하가 되도록 건조대차에 적재하여 건조시키며, 약 1250∼1350℃의 온도에서 제품을 소성 가공하는 것을 특징으로 하는 황토 및 굴껍질을 주재로 한 건축 구조재의 제조방법.Oyster shell and loess are dried at a temperature of about 400 DEG C and sieved by using a passing powder having a particle size of 100 MESH of oyster shell and loess, respectively, and water is mixed at a rate of about 25 to 30 RPM using a mixer About 20 to 25%, molding the product using a vacuum pouring machine so that the vacuum pourer pressure is about 70HP or more, the degree of vacuum is about 74 kg / cm 2, and the molding water is about 20 to 25% And the product is subjected to plastic working at a temperature of about 1250 to 1350 ° C. The method for manufacturing a structural material according to claim 1,
KR1019980037461A 1998-09-08 1998-09-08 Structural materials based on ocher and oyster shells and their manufacturing methods KR100295009B1 (en)

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* Cited by examiner, † Cited by third party
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KR20020041266A (en) * 2000-11-27 2002-06-01 송유천 A manufacturing method for a solid product mainly containing shellfish and clay minerals and the product thereof.
KR100467204B1 (en) * 2002-07-05 2005-01-24 (주)디텍 Antibacterial Gypsum Board
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KR20010008287A (en) * 2000-11-21 2001-02-05 이만재 a Baked Earth Containing energy and a Preparation Method thereof
KR20020060867A (en) * 2001-01-12 2002-07-19 주식회사 해중 Blocks Manufactured from Powdered Fire Brick, and Method of Manufacturing the Same
KR100927255B1 (en) * 2006-02-23 2009-11-16 민병억 Artificial reef and its manufacturing method
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020041266A (en) * 2000-11-27 2002-06-01 송유천 A manufacturing method for a solid product mainly containing shellfish and clay minerals and the product thereof.
KR100467204B1 (en) * 2002-07-05 2005-01-24 (주)디텍 Antibacterial Gypsum Board
KR101930819B1 (en) * 2018-04-27 2018-12-19 주식회사 대성그린테크 Effective microorganisms vitalization system for control of micropollutants in wastewater

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