KR100285273B1 - A green fluorescent body based Zn2SiO4 and process for preparing them - Google Patents
A green fluorescent body based Zn2SiO4 and process for preparing them Download PDFInfo
- Publication number
- KR100285273B1 KR100285273B1 KR1019990007434A KR19990007434A KR100285273B1 KR 100285273 B1 KR100285273 B1 KR 100285273B1 KR 1019990007434 A KR1019990007434 A KR 1019990007434A KR 19990007434 A KR19990007434 A KR 19990007434A KR 100285273 B1 KR100285273 B1 KR 100285273B1
- Authority
- KR
- South Korea
- Prior art keywords
- sio
- green phosphor
- formula
- phosphor
- present
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 108010043121 Green Fluorescent Proteins Proteins 0.000 title 1
- 229910052844 willemite Inorganic materials 0.000 title 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 41
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 28
- 239000011701 zinc Substances 0.000 claims abstract description 21
- 229910004283 SiO 4 Inorganic materials 0.000 claims abstract description 13
- 239000011159 matrix material Substances 0.000 claims abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 229910021332 silicide Inorganic materials 0.000 claims description 5
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 239000012190 activator Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- 239000004110 Zinc silicate Substances 0.000 abstract description 2
- 230000000704 physical effect Effects 0.000 abstract description 2
- 235000019352 zinc silicate Nutrition 0.000 abstract description 2
- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011572 manganese Substances 0.000 description 19
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 12
- 230000005284 excitation Effects 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000000295 emission spectrum Methods 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 238000005424 photoluminescence Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/59—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing silicon
- C09K11/592—Chalcogenides
- C09K11/595—Chalcogenides with zinc or cadmium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/34—Vessels, containers or parts thereof, e.g. substrates
- H01J11/42—Fluorescent layers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/34—Vessels, containers or parts thereof, e.g. substrates
- H01J2211/42—Fluorescent layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
Abstract
본 발명은 Zn2SiO4계 녹색 형광체와 이의 제조방법에 관한 것으로서, 더욱 상세하게는 형광체 모체인 규화아연에 부활제로서 산화망간이 소정의 농도범위로 도핑되어 있어 진공자외선 영역에서의 발광 효율이 뛰어나고, 고진공에서도 안정한 물성을 가지게되므로 플라즈마 디스플레이 패널(plasma display panel, PDP)에 적합한 다음 화학식 1로 표시되는 PDP용 Zn2SiO4계 녹색 형광체와 이의 제조방법에 관한 것이다.The present invention relates to a Zn 2 SiO 4 -based green phosphor and a method for manufacturing the same, and more particularly, zinc silicate, which is a phosphor matrix, is doped with a manganese oxide as a activator in a predetermined concentration range, so that the luminous efficiency in the vacuum ultraviolet region is improved. The present invention relates to a Zn 2 SiO 4 green phosphor for PDP represented by the following Chemical Formula 1 suitable for a plasma display panel (PDP) and a method of manufacturing the same, because it has excellent physical properties even in high vacuum.
상기 화학식 1에서 0 ＜ a ＜ 0.05 이다.In Formula 1, 0 <a <0.05.
Description
본 발명은 Zn2SiO4계 녹색 형광체와 이의 제조방법에 관한 것으로서, 더욱 상세하게는 형광체 모체인 규화아연에 부활제로서 산화망간이 소정의 농도범위로 도핑되어 있어 진공자외선 영역에서의 발광 효율이 뛰어나고, 고진공에서도 안정한 물성을 가지게되므로 플라즈마 디스플레이 패널(plasma display panel, PDP)에 적합한 다음 화학식 1로 표시되는 PDP용 Zn2SiO4계 녹색 형광체와 이의 제조방법에 관한 것이다.The present invention relates to a Zn 2 SiO 4 -based green phosphor and a method for manufacturing the same, and more particularly, zinc silicate, which is a phosphor matrix, is doped with a manganese oxide as a activator in a predetermined concentration range, so that the luminous efficiency in the vacuum ultraviolet region is improved. The present invention relates to a Zn 2 SiO 4 green phosphor for PDP represented by the following Chemical Formula 1 suitable for a plasma display panel (PDP) and a method of manufacturing the same, because it has excellent physical properties even in high vacuum.
화학식 1Formula 1
상기 화학식 1에서 0 ＜ a ＜ 0.05 이다.In Formula 1, 0 <a <0.05.
정보표시용 디스플레이로서 음극선관(CRT)이 가장 많이 사용되고 있으며, 이러한 음극선관(CRT)의 단점을 보완 및 대체할 수 있는 차세대 평판 디스플레이의 하나로 플라즈마 디스플레이 패널(PDP)이 각광받고 있다. 플라즈마 디스플레이 패널(plasma display panel, PDP)은 진공에서 불활성 가스들의 방전에 의해 생성되는 자외선에 의해 형광체가 빛을 내는 형태의 디스플레이로서, 이는 진공자외선 여기를 기본으로 한다.Cathode ray tubes (CRTs) are most commonly used as displays for information display, and plasma display panels (PDPs) have been in the spotlight as one of the next-generation flat panel displays that can supplement and replace the disadvantages of the cathode ray tubes (CRTs). Plasma display panels (PDPs) are displays in which phosphors emit light by ultraviolet rays generated by discharge of inert gases in a vacuum, which are based on vacuum ultraviolet excitation.
지금까지 알려진 바에 의하면, PDP용 녹색 형광체로서는 주로 망간이 도핑된 Zn2SiO4가 사용되고 있으며 이와 관련된 종래 특허들은 모두 진공자외선 영역이 아닌 보통의 자외선 영역(254 ㎚)의 여기광을 이용하여 실험하였다. 그 결과로 인하여 상기 화학식 1에서의 a 값의 영역이 0.05 이상인 Zn2SiO4형광체가 최적 조건인 것으로 알려져 있다.As is known so far, Zn 2 SiO 4 doped with manganese is mainly used as a green phosphor for PDP, and all of the related patents have been experimented using excitation light in the normal ultraviolet region (254 nm) instead of the vacuum ultraviolet region. . As a result, it is known that Zn 2 SiO 4 phosphor having a region of a value in Formula 1 above 0.05 is an optimum condition.
그러나, 상기한 a 값의 영역을 가지는 종래 PDP용 녹색 형광체는 잔광시간이 길고 발광휘도가 낮은 단점이 지적되고 있으며, 이에 단점을 개선시킨 새로운 PDP용 녹색 형광체가 요구된다.However, it is pointed out that the conventional green phosphor for PDP having a region of the above a value has a long afterglow time and a low luminous luminance, and thus a new green phosphor for PDP has been required.
본 발명자들은 종래 PDP용 녹색 형광체의 단점을 개선하기 위하여 실제 PDP용 디스플레이의 구동조건과 같은 147 ㎚의 여기원을 사용하여 발광실험을 반복 수행하였고, 그 결과 규화아연 모체에 도핑되는 부활제 농도(a 값)가 0 ＜ a ＜ 0.05 영역에서 최적인 것으로 판명됨으로써 본 발명을 완성하였다.In order to improve the disadvantages of the conventional green phosphor for PDP, the present inventors repeatedly performed luminescence experiment using an excitation source of 147 nm which is the same as the driving conditions of the actual PDP display. The present invention was completed by a value) being found to be optimal at 0 <a <0.05.
따라서, 본 발명은 진공자외선에서 발광 효율이 뛰어난 Zn2SiO4계 녹색 형광체와 이의 제조방법을 제공하는 데 그 목적이 있다.Accordingly, an object of the present invention is to provide a Zn 2 SiO 4 -based green phosphor excellent in luminous efficiency in vacuum ultraviolet rays and a method of manufacturing the same.
도 1은 10-4∼10-5의 진공상태에서 147 ㎚의 파장으로 여기시켰을 때, 녹색형광체에 도핑되는 망간의 도핑량에 따른 빛 발광 스펙트럼을 나타낸 그래프이다.1 is a graph showing a light emission spectrum according to the doping amount of manganese doped into a green phosphor when excited at a wavelength of 147 nm in a vacuum state of 10 −4 to 10 −5 .
도 2는 147 ㎚와 254 ㎚의 파장으로 각각 여기시켰을 때, 녹색형광체에 도핑되는 망간의 도핑량에 따른 최고 발광치를 나타낸 그래프이다.2 is a graph showing peak emission values according to the amount of manganese doped into the green phosphor when excited at wavelengths of 147 nm and 254 nm, respectively.
본 발명은 다음 화학식 1로 표시되는 녹색 형광체를 그 특징으로 한다.The present invention is characterized by the green phosphor represented by the following formula (1).
화학식 1Formula 1
상기 화학식 1에서 0 ＜ a ＜ 0.05 이다.In Formula 1, 0 <a <0.05.
또한, 본 발명은 산화아연(ZnO) 및 실리카(SiO2)를 형광체 원료로 사용하여 제조한 규화아연(Zn2SiO4)을 모체에 사용하고, 여기에 산화망간을 혼합하여 1,100 ∼ 1,350℃에서 소성하고 다시 환원 분위기에서 열처리를 한 다음, 분쇄 및 여기시켜 상기 화학식 1로 표시되는 녹색 형광체를 제조하는 방법을 포함한다.In the present invention, zinc silicide (Zn 2 SiO 4 ) prepared by using zinc oxide (ZnO) and silica (SiO 2 ) as the phosphor raw material is used as a matrix, and manganese oxide is mixed therein at 1,100 to 1,350 ° C. It calcined and heat-treated again in a reducing atmosphere, and then pulverized and excited to produce a green phosphor represented by Chemical Formula 1.
이와 같은 본 발명을 더욱 상세히 설명하면 다음과 같다.Referring to the present invention in more detail as follows.
본 발명에 따른 녹색 형광체는 규화아연 모체에 부활제로 도핑되는 산화망간의 도핑량을 조절함으로써 진공자외선 영역에서의 발광 효율이 우수하고, 고진공에서도 안정한 물성을 가지게 되는 PDP용 녹색 형광체에 관한 것이다.The green phosphor according to the present invention relates to a green phosphor for PDP which has excellent luminous efficiency in the vacuum ultraviolet region and stable properties even in high vacuum by controlling the doping amount of manganese oxide doped with an activator to a zinc silicide matrix.
상기와 같은 본 발명의 녹색 형광체를 그 제조방법에 의거하여 더욱 상세히 설명하면 다음과 같다.Referring to the green phosphor of the present invention as described above in more detail based on the manufacturing method as follows.
먼저, 산화아연(ZnO) 및 실리카(SiO2)를 형광체 원료로 사용하여 제조한 규화아연(Zn2SiO4) 모체를 제조하고, 여기에 부활제로서 산화망간(MnO)를 첨가하고 혼합한다. 이때, 모체를 구성하는 산화아연(ZnO) 및 실리카(SiO2)의 함량은 형광체의 Zn/Si 몰비가 화학양론적으로 2 : 1이 되도록 하는 것이 바람직하다.First, a zinc silicide (Zn 2 SiO 4 ) matrix prepared by using zinc oxide (ZnO) and silica (SiO 2 ) as a phosphor raw material is prepared, and manganese oxide (MnO) is added and mixed thereto as an activator. At this time, the content of zinc oxide (ZnO) and silica (SiO 2 ) constituting the parent is preferably such that the Zn / Si molar ratio of the phosphor is in the stoichiometric 2: 1.
본 발명은 부활제로서 사용되는 산화망간의 도핑량 조절이 매우 중요한 바, 산화망간(a)은 형광체 원료물질중의 산화아연에 대하여 0 ＜ a ＜ 0.05 몰비 범위로 첨가하도록 한다. 만약, 산화망간이 전혀 첨가되지 않으면 전혀 발광을 하지 않는 문제가 있고, 산화망간의 첨가량이 0.05 몰비 이상이면 잔광시간이 길고 발광휘도가 낮아지는 등 발광효율이 매우 감소하는 문제가 있다.In the present invention, it is very important to control the doping amount of manganese oxide used as an activator, so that the manganese oxide (a) is added in a range of 0 <a <0.05 molar ratio with respect to zinc oxide in the phosphor raw material. If the manganese oxide is not added at all, there is a problem in not emitting light at all, and if the addition amount of manganese oxide is more than 0.05 molar ratio, there is a problem that the luminous efficiency is very low, such as long afterglow time and low luminous luminance.
상기와 같은 함량비 범위내에서 형광체 원료물질과 부활제를 원하는 조성에 따른 각각의 소정비가 되도록 평량하고, 또한 보다 효과적인 혼합을 위하여 아세톤 용매 하에서 볼밀링(ball milling) 또는 마노 유발과 같은 혼합기를 이용하여 균일한 조성이 되도록 충분히 혼합한다. 그리고, 혼합물을 고순도 알루미나 도가니에 넣은 후, 뚜껑을 덮은 상태로 공기중에서 1,100 ∼ 1,350℃ 온도로 2 ∼ 24 시간동안 소성한다. 이때, 소성 온도가 매우 중요한 바, 만일 소성 온도가 1,100℃ 미만이면 규화아연이 충분하게 형성되지 않으며, 1,350℃를 초과하면 휘발에 의한 무게 감소가 생긴다. 소성이 완료되면 발광효율이 높은 형광체를 얻기 위하여 환원분위기에서 900 ∼ 1,200℃ 온도로 2 ∼ 24 시간동안 환원시키는데, 여기서 환원분위기라함은 수소 또는 탄소 분위기를 일컫는다. 그런 다음, 1 ∼ 5 ㎛ 정도로 충분히 분쇄한다.Within the content ratio range as described above, the phosphor raw material and the activator are weighed to each predetermined ratio according to the desired composition, and a mixer such as ball milling or agate induction in acetone solvent is used for more effective mixing. And mix sufficiently to make a uniform composition. The mixture is placed in a high-purity alumina crucible and then calcined for 2 to 24 hours at 1,100 to 1,350 ° C in air with the lid closed. At this time, the firing temperature is very important, if the firing temperature is less than 1,100 ℃ zinc silicide is not formed sufficiently, if the firing temperature exceeds 1,350 ℃ weight loss by volatilization occurs. When the calcination is completed, in order to obtain a phosphor having high luminous efficiency, it is reduced for 2 to 24 hours at a temperature of 900 to 1,200 ° C. in a reducing atmosphere, where the reducing atmosphere refers to hydrogen or a carbon atmosphere. Then, it grind | pulverizes enough about 1-5 micrometers.
이상에서 설명한 바와 같은 제조방법으로 제조된 본 발명의 형광체는 발광 광도계(luminescence spectrometer, LS)를 이용하여 10-4∼ 10-5torr의 진공상태에서 147 ㎚의 파장으로 여기시킨다. 여기 과정을 수행한 후에 본 발명의 형광체에 대하여 빛 발광(photoluminescence, PL)을 측정한 결과, 500 ∼ 550 ㎚ 영역에서 강한 발광 스펙트럼을 나타냄을 확인하였다.The phosphor of the present invention prepared by the manufacturing method as described above is excited at a wavelength of 147 nm in a vacuum state of 10 −4 to 10 −5 torr using a luminescence spectrometer (LS). After performing the excitation process, the photoluminescence (PL) of the phosphor of the present invention was measured, and it was confirmed that a strong emission spectrum was exhibited in the region of 500 to 550 nm.
또한, 본 발명에서 제조한 상기 화학식 1로 표시되는 녹색 형광체는 망간 도핑량에 따라서 빛 발광 스펙트럼이 달리 나타나는데, 망간의 도핑량(a)이 0 ＜ a ＜ 0.05 몰비 범위내에서 최대의 발광 휘도를 보이며, 상기 범위를 벗어난 경우 발광 휘도가 크게 감소하는 결과를 초래하게 된다.In addition, the green phosphor represented by Chemical Formula 1 according to the present invention has a different light emission spectrum according to the amount of manganese doping, and the amount of manganese doping (a) exhibits a maximum emission luminance within a range of 0 <a <0.05 molar ratio. If it is out of the above range, the light emission luminance is greatly reduced.
따라서, 본 발명에 따른 상기 화학식 1로 표시되는 녹색 형광체는 플라즈마 디스플레이 패널(PDP)의 녹색 형광체로 유용함을 알 수 있다.Therefore, it can be seen that the green phosphor represented by Chemical Formula 1 according to the present invention is useful as a green phosphor of a plasma display panel (PDP).
이와 같은 본 발명을 다음의 실시예에 의거하여 더욱 상세하게 설명하겠는 바, 본 발명이 실시예에 한정되는 것은 아니다.Although this invention is demonstrated in more detail based on the following Example, this invention is not limited to an Example.
실시예 : Zn1.98SiO4: 0.02Mn으로 표시되는 녹색형광체의 제조Example: Preparation of green phosphor represented by Zn 1.98 SiO 4 : 0.02Mn
산화아연 3.6186 g(1.98 ㏖)과 이산화규소 1.3495 g(1.0 ㏖)을 칭량하고, 여기에 산화망간 0.0319 g(0.02 mol)를 칭량하여 마노 유발을 사용하여 고르게 혼합하였다. 이때, 비산 방지와 보다 효과적인 혼합을 위해 아세톤 50 ㎖를 첨가하며 융제(flux)는 따로 사용하지 않았다. 혼합한 시료를 고순도 알루미나 도가니에 넣은 후, 뚜껑을 덮은 상태로 전기로를 사용하여 대기하에서 1,300℃ 온도로 4 시간동안 소성하였다. 소성 후 시간당 50℃ 정도로 냉각시킨 다음 1 ∼ 5 ㎛ 정도로 충분히 분쇄하고, 다시 이 형광체를 수소 또는 탄소의 환원분위기에서 900℃ 온도로 2 시간동안 환원시킨 후에 다시 분쇄하여 녹색 형광체를 얻었다.3.6186 g (1.98 mol) of zinc oxide and 1.3495 g (1.0 mol) of silicon dioxide were weighed, and 0.0319 g (0.02 mol) of manganese oxide was weighed and mixed evenly using agate mortar. At this time, 50 ml of acetone was added to prevent scattering and more effective mixing, and no flux was used separately. The mixed samples were placed in a high purity alumina crucible, and then fired for 4 hours at 1,300 ° C. under an atmosphere using an electric furnace with a lid covered. After firing, the mixture was cooled to about 50 ° C. per hour, and then sufficiently pulverized to about 1 to 5 μm. The phosphor was further reduced to 900 ° C. for 2 hours in a reducing atmosphere of hydrogen or carbon, and then pulverized again to obtain a green phosphor.
실험예 1 :Experimental Example 1:
상기 실시예의 제조방법에 의해 제조하되, 망간(Mn)의 사용량을 달리하여 녹색 형광체를 제조하였다. 그리고, 10-4∼10-5의 진공상태에서 147 ㎚의 파장으로 여기시켰을 때, 녹색형광체에 함유된 망간(Mn)의 도핑량에 따른 빛 발광을 측정하였으며, 그 결과는 첨부도면 도 1에 나타내었다. 도 1에 의하면, 500 ∼ 550 ㎚ 영역에서 강한 발광 스펙트럼을 나타내고 있으며, 망간(Mn)의 도핑량이 증가함에 따라 빛의 세기가 감소하는 경향을 보인다.The green phosphor was manufactured by the preparation method of the above embodiment, but by varying the amount of manganese (Mn). When excited at a wavelength of 147 nm in a vacuum state of 10 −4 to 10 −5 , light emission according to the doping amount of manganese (Mn) contained in the green phosphor was measured, and the result is shown in FIG. Indicated. According to FIG. 1, a strong emission spectrum is shown in the region of 500 to 550 nm, and light intensity tends to decrease as the amount of doping of manganese (Mn) increases.
실험예 2 :Experimental Example 2:
상기 실시예의 제조방법에 의해 제조하되, 망간(Mn)의 도핑량을 달리하여 녹색 형광체를 제조하였다. 그리고, 10-4~ 10-5torr의 진공하에서의 147 ㎚와 대기중의 254 ㎚의 파장으로 각각 여기시켰을 때, 녹색형광체에 함유된 망간(Mn)의 첨가량에 따른 최고 발광치를 측정하였으며, 그 결과는 첨부도면 도 2에 나타내었다. 도 2에 의하면, 망간의 도핑량(a)이 0 ＜ a ＜ 0.05 몰비일 때 최대의 발광 휘도를 보이며, 상기 범위를 벗어난 경우 발광 휘도가 크게 감소하는 경향을 보인다.The green phosphor was manufactured by the preparation method of the above embodiment, but by varying the doping amount of manganese (Mn). In addition, when excited at a wavelength of 147 nm and 254 nm in the atmosphere under a vacuum of 10 -4 to 10 -5 torr, the highest emission value was measured according to the amount of manganese (Mn) contained in the green phosphor. 2 is shown in the accompanying drawings. According to FIG. 2, the maximum emission luminance is exhibited when the manganese doping amount a is 0 <a <0.05 molar ratio, and when it is out of the above range, the luminance is greatly decreased.
상술한 바와 같이, 본 발명의 Zn2SiO4계 녹색 형광체는 Zn2SiO4에 Mn을 소정의 함량비로 도핑함으로써, 진공자외선(10-4∼10-5의 진공 및 147 ㎚의 파장) 여기하에서 500 ∼ 550 ㎚ 영역의 색순도가 우수한 녹색 발광을 나타내었다. 한편 부활제로 첨가되는 망간(Mn)의 최대 발광농도에 있어, 진공자외선(10-4∼10-5의 진공 및 147 ㎚의 파장) 여기하에서는 기존의 254 ㎚ 여기하에서 측정한 최대 발광 농도보다 현격히 낮은 농도에서 최고의 발광휘도를 보였다. 따라서, 본 발명에서 제시한 부활제 농도 범위가 앞으로 PDP에 적용할 수 있는 가능성이 매우 크다.As described above, the Zn 2 SiO 4 -based green phosphor of the present invention is doped with Zn 2 SiO 4 by Mn in a predetermined content ratio, and thus under vacuum ultraviolet radiation (vacuum of 10 −4 to 10 −5 and a wavelength of 147 nm). Green light emission with excellent color purity in the 500 to 550 nm region was shown. On the other hand, in the maximum emission concentration of manganese (Mn) added as an activator, under vacuum ultraviolet radiation (vacuum of 10 -4 to 10 -5 and wavelength of 147 nm) excitation is significantly lower than the maximum emission concentration measured under the existing 254 nm excitation The highest luminance was shown at the concentration. Therefore, there is a great possibility that the range of the activator concentration proposed in the present invention can be applied to the PDP in the future.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019990007434A KR100285273B1 (en) | 1999-03-06 | 1999-03-06 | A green fluorescent body based Zn2SiO4 and process for preparing them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019990007434A KR100285273B1 (en) | 1999-03-06 | 1999-03-06 | A green fluorescent body based Zn2SiO4 and process for preparing them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20000059658A KR20000059658A (en) | 2000-10-05 |
| KR100285273B1 true KR100285273B1 (en) | 2001-03-15 |
Family
ID=19575744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019990007434A KR100285273B1 (en) | 1999-03-06 | 1999-03-06 | A green fluorescent body based Zn2SiO4 and process for preparing them |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100285273B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101089447B1 (en) | 2009-02-27 | 2011-12-07 | 고려대학교 산학협력단 | Microwave dielectric ceramics composition and method for fabricating microwave dielectric ceramics using the same |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100456982B1 (en) * | 2002-02-28 | 2004-11-10 | 한국과학기술연구원 | Preparation of Green Phosphors for Plasma Display Panel |
| KR100842855B1 (en) * | 2007-04-18 | 2008-07-02 | 요업기술원 | Microwave dielectric ceramics and the manufacturing method thereof |
-
1999
- 1999-03-06 KR KR1019990007434A patent/KR100285273B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101089447B1 (en) | 2009-02-27 | 2011-12-07 | 고려대학교 산학협력단 | Microwave dielectric ceramics composition and method for fabricating microwave dielectric ceramics using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20000059658A (en) | 2000-10-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| USRE45640E1 (en) | Phosphor for electron beam excitation and color display device using the same | |
| EP3297046B1 (en) | Light-emitting instrument and image display device | |
| KR100319488B1 (en) | Green fluorescent body based zinc silicate | |
| CN102933684A (en) | Zinc manganese silicate containing metal particles luminescent materials and preparation methods thereof | |
| KR100285273B1 (en) | A green fluorescent body based Zn2SiO4 and process for preparing them | |
| US20120068117A1 (en) | Green luminescent materials and their preparing methods | |
| KR100267510B1 (en) | A preparing process of green fluorescent body based zinc silicate | |
| KR101162063B1 (en) | Green emitting phosphor for vacuum ultraviolet excited light emitting device, preparation method thereof and light emitting device having the same | |
| JP4702565B2 (en) | Manganese-activated rare earth aluminate phosphor and fluorescent lamp using the same | |
| KR100265035B1 (en) | A green fluorescent body based zn2sio4 and its preparing method | |
| JP3264045B2 (en) | Phosphor manufacturing method | |
| KR100285274B1 (en) | A green fluorescent body based gadolinium aluminate and process for preparing them | |
| KR100456982B1 (en) | Preparation of Green Phosphors for Plasma Display Panel | |
| CN1212367C (en) | Red RE oxide luminophor and its prepn | |
| JP3095220B2 (en) | New green light-emitting phosphor | |
| KR100726140B1 (en) | The process of a fluorescent substance based on Zinc Silicate | |
| KR100254169B1 (en) | A method for manufacturing a manganese activating silicic acidic zinc phosphor by liquid reaction method | |
| KR100348207B1 (en) | Fluorescent Material of Lanthanum Gallate and Method for Producing The Same | |
| KR19990085329A (en) | Strontium titanate-based red phosphor and its manufacturing method | |
| KR20010026774A (en) | A red fluorescent body based SrTiO3 used in low voltage and process for preparing them | |
| KR100270409B1 (en) | Ared flurorescent body based lanthanum titanate and its preparing method | |
| KR20000059660A (en) | A red fluorescent body based SrTiO3and process for preparing them | |
| KR930005691B1 (en) | Red-luminous phosphor | |
| KR100424864B1 (en) | Process for preparing GdOBr green phosphor | |
| KR100336970B1 (en) | Novel green phosphors and methods of preparing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20060102 Year of fee payment: 6 |
|
| LAPS | Lapse due to unpaid annual fee |