KR100272421B1 - Artificial marble with a loess and zeolite as a miain ingredient and method thereof - Google Patents

Artificial marble with a loess and zeolite as a miain ingredient and method thereof Download PDF

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KR100272421B1
KR100272421B1 KR19980021639A KR19980021639A KR100272421B1 KR 100272421 B1 KR100272421 B1 KR 100272421B1 KR 19980021639 A KR19980021639 A KR 19980021639A KR 19980021639 A KR19980021639 A KR 19980021639A KR 100272421 B1 KR100272421 B1 KR 100272421B1
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zeolite
ocher
unsaturated polyester
polyester resin
artificial marble
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KR19980021639A
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Korean (ko)
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KR20000001388A (en
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권영수
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박진규
주식회사에넥스하이테크
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18—Polyesters; Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00439—Physico-chemical properties of the materials not provided for elsewhere in C04B2111/00
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00965—Uses not provided for elsewhere in C04B2111/00 for household applications, e.g. use of materials as cooking ware
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/542—Artificial natural stone
    • C04B2111/545—Artificial marble

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명은 황토와 제올라이트를 주재로한 인조대리석 및 그 제조방법에 관한 것으로 특히 가정용 욕조나 싱크대 상판, 또는 욕실 세면대 등을 불포화 폴리에스테르 수지 액으로 조성할 때 그 충진제를 황토와 제올라이트로 함으로서 윈적외선이 방사되고 항균, 탈취, 양이온 치환 능력을 갖는 욕조, 싱크대 상판 또는 세면대 등을 제공할 수 있게 한 것이다.The present invention relates to artificial marble mainly composed of ocher and zeolite, and a method of manufacturing the same. In particular, in the case of forming a bath tub, a sink top plate, or a bathroom sink in an unsaturated polyester resin liquid, the filler is made of ocher and zeolite, and thus, infrared ray It is to be able to provide a bath, sink top plate or sink having a spinning and antibacterial, deodorizing, cationic substitution ability.

Description

황토와 제올라이트를 주재로 한 인조대리석 및 그 제조방법Artificial marble based on ocher and zeolite and its manufacturing method

본 발명은 황토와 제올라이트를 주재로한 인조대리석 및 그 제조방법에 관한 것으로 특히 가정용 욕조나 싱크대 상판 또는 욕실 세면대등을 불포화 폴리에스테르 수지액으로 조성(MOLDING)할 때 그 충진제를 황토와 제올라이트로 하여서 된 일종의 인조대리석 및 그 제조방법에 관한 것이다.The present invention relates to artificial marble mainly based on ocher and zeolite, and a method of manufacturing the same, in particular, when forming a household bath, a sink top, a bathroom sink, etc. with an unsaturated polyester resin liquid, and using the filler as ocher and zeolite. It relates to a kind of artificial marble and a method of manufacturing the same.

일반적으로 제올라이트 (Zeolite:沸石)는 항균·탈취 그리고 양이온 치환 능력이 있는 것으로 알려져 있고 황토(Loess)는 원적외선이 방사되는 것으로 알려져 있으며 근래에 원적외선을 방사하는 것으로 세라믹 코팅 제품이나, 황토를 물로 교반하여 만든 제품이 주종을 이루고 있다.Generally, zeolite is known to have antibacterial, deodorizing and cation substitution ability. Loess is known to emit far infrared rays. In recent years, it is known to emit far infrared rays. The products made are dominated.

그러나 이와 같은 종래의 것은 표면 코팅층에서만 원적외선이 방사되어 그 효과가 미비하며 물과 황토를 교반하여 만든 제품은 물에 희석 및 분해되는 문제가 있음으로 그 사용처가 제한적일 수 밖에 없는 문제점이 있다.However, such a conventional one has a problem that far infrared rays are radiated only from the surface coating layer, and the effect thereof is insignificant, and a product made by stirring water and ocher has a problem of dilution and decomposition in water.

종래의 가정용 욕조나 싱크대 상판 또는 세면대등은 단순히 섬유강화 수지(FRP)로 만든 것이거나 또는 불포화 폴리에스테르 수지에 탄산칼슘(CaCo3)이나 수산화알루미나(AI2O3)를 혼합하여 성형되어지므로 단순한 구조물로서의 역할을 할 뿐 이들은 원적외선 방사라던가 항균 · 탈취 · 양이온 치환 능력은 발휘할 수 없는 것이다Conventional household bathtubs, sink tops or sinks are simply made of fiber-reinforced resins (FRP) or molded by mixing calcium carbonate (CaCo 3 ) or alumina hydroxide (AI 2 O 3 ) with unsaturated polyester resins. They only play a role as structures, and they cannot exhibit far-infrared radiation, antibacterial, deodorant, or cationic substitution.

여기서 본 발명은 그와 같은 욕조나 싱크대 상판 또는 세면대를 만드는 재료 즉 대리석의 조성과 제조방법을 달리함으로서 원적외선이 방사되고 항균 · 탈취 · 양이온 치환 능력을 갖는 욕조, 싱크대 상판 또는 세면대 등을 얻는데 그 목적이 있는 것이다.Herein, the present invention provides a bath, sink top plate, or wash basin with far-infrared rays and antibacterial, deodorant, and cationic substitution ability by varying the composition and manufacturing method of marble, that is, a material for making such a bath or sink top or sink. Is there.

제1도는 본 발명의 제조에 필요한 형틀 종단면도.1 is a longitudinal section of the mold required for the production of the present invention.

제2도는 본 발명의 표면층으로 제1도의 형틀에 제올라이트 혼합물이 도포된 상태를 보이는 종단면도.2 is a longitudinal sectional view showing a state in which the zeolite mixture is applied to the mold of FIG. 1 with the surface layer of the present invention.

제3도는 본 발명의 상형틀과 하형틀이 결합된 상태를 보이는 종단면도.Figure 3 is a longitudinal cross-sectional view showing a state in which the upper mold and the lower mold of the present invention is coupled.

제4도는 본 발명의 성형층으로 황토 혼합물이 주입된 상태를 보이는 종단면도.Figure 4 is a longitudinal cross-sectional view showing a state in which the ocher mixture is injected into the forming layer of the present invention.

제5도는 본 발명에 의하여 제조된 최종 제품의 종단면도.Figure 5 is a longitudinal sectional view of the final product produced according to the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 하형틀 2 : 제올라이트 표면층1: mold 2: zeolite surface layer

3 : 상형틀 4 : 황토 성형층3: upper frame 4: loess forming layer

5 : 주입구5: injection hole

본 발명에서는 상기 과제를 해결하기 위하여 일종의 인조대리석으로 욕조와 싱크대 상판 그리고 세면대 등을 만들되 그 조성은 황토 및 제올라이트를 충진제로 하고 불포화 폴리에스테르 수지를 결합제로 하며 불포화 폴리에스테르 수지와 황토 또는 제올라이트 혼합물을 일정 시간 동안 중온에서 속성 경화한 다음 저온에서 급냉각함으로서 원하는 목적물을 얻는다.In the present invention, in order to solve the above problems, a kind of artificial marble is used to make a bath, a sink top plate, a wash basin, etc., and its composition is ocher and zeolite as a filler, an unsaturated polyester resin as a binder, and an unsaturated polyester resin and an ocher or zeolite mixture. The desired object is obtained by flash hardening at low temperature for a certain time and then quenching at low temperature.

이를 좀더 상세히 설명하기 위하여 그 제조과정을 설명하면 먼저 하형틀(1) 표면에 이형제를 바르고 그 위에 불포화 폴리에스테르 수지액 60∼ 65 중량부와 제올라이트 35∼40 중량부를 혼합한 혼합물을 0.5∼1.0㎜ 두께로 스프레이 도포하여 이를 약 100℃가 유지되는 경화로에서 약 30분간 중온 경화한 다음 약 5℃로 급냉시킴으로서 제올라이트 표면층(2)을 형성한다.In order to explain this in more detail, first, the manufacturing process is described. First, a mold release agent is applied to the surface of the mold 1, and a mixture of 60 to 65 parts by weight of an unsaturated polyester resin solution and 35 to 40 parts by weight of zeolite is mixed at 0.5 to 1.0 mm. Spray coating to a thickness to form a zeolite surface layer (2) by curing at about 100 minutes in a curing furnace maintained at about 100 ℃ and then quenched to about 5 ℃.

이와 같이 형성된 표면층(2)위에 상형틀(3)을 설치하고 그 주입구(5)를 통하여 불포화 폴리에스테르 수지액 약 50 중량부와 황토 약 50 중량부를 혼합한 혼합물을 주입하여 9∼15㎜ 두께가 되게 하며 이를 약 100℃가 유지되는 경화로에서 약 120분간 중온 경화한 다음 약 5℃로 급냉시킴으로서 황토 성형층(4)을 제올라이트 표면층(2)과 적층 융착 구성하고 상 · 하형틀(3)(1)을 제거하여 제품을 완성한다.The upper mold 3 is formed on the surface layer 2 formed as described above, and a mixture of about 50 parts by weight of unsaturated polyester resin solution and about 50 parts by weight of ocher is injected through the injection port 5 to have a thickness of 9 to 15 mm. This was followed by a moderate temperature curing in a curing furnace maintained at about 100 ° C. for about 120 minutes, followed by quenching at about 5 ° C. to form the ocher forming layer 4 laminated and fused with the zeolite surface layer 2 and to the upper and lower molds 3 ( 1) Remove to complete the product.

[실시예]EXAMPLE

본 발명에서 사용된 황토와 제올라이트는 아래 표와 같다.The ocher and zeolite used in the present invention are shown in the table below.

본 발명에서 황토 분말:불포화 폴리에스테르 수지액과 제올라이트 분말:불포화 폴리에스테르 수지액의 배합비는 각각 50:50 중량부와 35:65 중량부로 하고 제올라이트 표면층(2)과 황토 성형층(4)의 두께는 0.6㎜와 11㎜로 하였으며 경화로 온도는 100℃ 그리고 급냉온도는 5℃로 하였다.In the present invention, the mixing ratio of the ocher powder: unsaturated polyester resin liquid and zeolite powder: unsaturated polyester resin liquid is 50:50 parts by weight and 35:65 parts by weight, respectively, and the thickness of the zeolite surface layer 2 and the ocher molding layer 4 is Was 0.6mm and 11mm, the curing furnace temperature was 100 ℃ and quenching temperature was 5 ℃.

경화 시간과 급냉시간은 제올라이트층의 경우 30분과 10분, 황토층의 경우 120분과 60분으로 하고 냉각후 상 하형틀 (3)·(1)을 탈리하면 얇은 제올라이트층을 표면층(2)으로 하고 두꺼운 황토층을 성형층(4)으로 한 인조대리석의 가정용 욕조나 싱크대 상판 또는 세면대 등을 얻는 것이다.The curing time and the quenching time were 30 minutes and 10 minutes for the zeolite layer and 120 minutes and 60 minutes for the ocher layer. After cooling, the upper and lower molds (3) and (1) were removed and the thin zeolite layer was used as the surface layer (2). It is to obtain a domestic bathtub, a sink top plate or a wash basin of an artificial marble having the ocher layer as the forming layer 4.

그리고 제올라이트 분말 및 불포화 폴리에스테르 수지액의 혼합물과 황토 분말 및 불포화 폴리에스테르 수지액의 혼합물에는 각기 경화제와 촉진제를 첨가하는데 각기 불포화 폴리에스테르 수지액의 중량부 100에 대하여 경화제로서 메틸에 틴케톤퍼옥사이드(MEKPO)와 촉진제로서 0.6% 나프탈산코발트(6% NaCaCo3)를 각기 0.75부씩 첨가한다.The mixture of zeolite powder and unsaturated polyester resin liquid and the mixture of ocher powder and unsaturated polyester resin liquid are each added with a curing agent and an accelerator, and methyl ethyl ketone peroxide as a curing agent with respect to 100 parts by weight of the unsaturated polyester resin liquid, respectively. 0.75 parts each of (MEKPO) and 0.6% cobalt naphthalate (6% NaCaCo 3 ) are added as promoters.

상기 실시예에서In the above embodiment

주] (1) 불포화 폴리에스테르 수지는 {고려화학 (주) 제품 한국}Note] (1) Unsaturated polyester resin is {Korea Chemical Co., Ltd. Korea}

(2) 황토는 {원진 (주) 제품-한국}(2) Ocher {Wonjin Co., Ltd. Products-Korea}

(3) 제올라이트는 {원진 (주) 제품-한국}(3) Zeolite {Wonjin Co., Ltd. Products-Korea}

(4) 비스 {4-T-부틸시클로헥실}(4) bis {4-T-butylcyclohexyl}

퍼옥시디카보네트는 {퍼카독스-l6(가약구악조사 제품 일본)}Peroxydicarbonone is {Percadox-L6 (Pharmaceutical Instruments of Japan)}

(5) 6% 나프탄산코발트는 {고려화학(주) 제품-한국}이다.(5) 6% cobalt naphate is {Korea Chemical Co., Ltd.-Korea}.

상기 실시예에 따라 제조된 제품에 대하여 바콜경도, 연필경도, 굴곡강도, 굴곡탄성율, 내비등수시험을 한바 그 결과는 다음 표와 같다.Barcol hardness, pencil hardness, flexural strength, flexural modulus, and boiling water tests of the products prepared according to the above examples are shown in the following table.

상기 표의 측정 기준은 바콜경도는 ASTM 2583으로 측정하였고, 연필경도는 연필경도계(미쓰비시사 제품)를 이용하여 측정하였으며, 굴곡강도는 ISO R 3286으로 측정하였으며 내비등수시험은 KSF 4810으로 측정하였다.In the measurement criteria of the table, the barcol hardness was measured by ASTM 2583, the pencil hardness was measured using a pencil hardness tester (manufactured by Mitsubishi Corporation), the flexural strength was measured by ISO R 3286, and the boiling water test was measured by KSF 4810.

상기 시험결과로 볼 때 본 발명의 제품은 제반물성이 양호하며 연필강도, 바콜강도, 내비등수등이 일반적으로 우수함을 보여준다.According to the test results, the product of the present invention exhibits good physical properties and generally shows excellent pencil strength, Bacold strength, boiling water, and the like.

특히 본 발명은 표면에 얇은 제올라이트층을 형성하고 그 이면에 두꺼운 황토 성형층을 형성함으로서 제올라이트 표면층에서는 강력한 양이온 치환 능력으로 인한 적절한 습도 조절 및 항상 쾌적한 상태를 유지시켜 주고 또한 91%대의 강력한 탈취능력으로 탈취 효과는 물론 항균 능력을 갖추게 되는 것이며 황토 주형층에서는 항균, 습도 조절, 축열성은 물론 92%대의 원적외선 방사로 인하여 인체의 신진대사 촉진등 황토 고유의 장점을 갖추게 되는 것이다.In particular, the present invention forms a thin zeolite layer on the surface and a thick ocher forming layer on the back side, so that the zeolite surface layer has a proper humidity control due to strong cation substitution ability and always maintains a comfortable state, and also has a strong deodorizing capacity of 91%. The deodorizing effect, of course, will have an antibacterial ability, and in the ocher template layer, it will have the unique advantages of ocher, such as antibacterial, humidity control, heat storage, as well as promoting metabolism of the human body by 92% of far-infrared radiation.

따라서 본 발명의 제품은 작업성이 간단하고 제품 자체의 물성이 우수하며 또한 그 사용자의 인체에 해로운 냄새, 습기 제거와 인체에 유익한 이온교환으로 신진대사 촉진, 모세혈관 확장, 혈액순환 촉진등 적정의 체온을 유지시겨 주는 온열작용으로 인간 생활의 필수적인 효과를 주는 것이다.Therefore, the product of the present invention is simple in workability and excellent in physical properties of the product itself, and also suitable for promoting metabolism, capillary expansion, blood circulation promotion, etc. by odors harmful to the human body, moisture removal and beneficial ion exchange. The warming that keeps body temperature gives the essential effects of human life.

Claims (2)

황토와 불포화 폴리에스테르 수지를 약 50 대 50의 중량비로 혼합한 혼합물을 9∼15㎜두께의 성형층(4)으로하고 제올라이트 35∼40중량부와 불포화 폴리에스테르 수지 60∼65중량부의 혼합물을 0.5∼1.00㎜두께의 표면층(2)으로 적층 경화하여서 된 황토와 제올라이트를 주재로한 인조대리석.A mixture of ocher and unsaturated polyester resin in a weight ratio of about 50 to 50 is used as a forming layer 4 having a thickness of 9 to 15 mm, and a mixture of 35 to 40 parts by weight of zeolite and 60 to 65 parts by weight of unsaturated polyester resin is 0.5. Artificial marble mainly composed of ocher and zeolite formed by laminating and hardening the surface layer 2 having a thickness of 1.00 mm. 제올라이트 35∼40중량부와 불포화 폴리에스테르 수지액 60∼65중량부의 혼합물을 하형틀(1) 일면에 0.5∼1.0㎜두께로 도포하여 이를 95∼105℃로 25∼35분간 중온 경화하고 이를 4∼7℃로 15∼25분간 급냉시킨 다음 그 위에 황토와 불포화 폴리에스테르 수지액을 약 50 대 50으로 혼합한 혼합물을 상형틀(3)의 주입구(5)를 통하여 9∼15㎜두께로 충진하고 이를 95∼105℃로 110∼130분간 중온 경화한 다음 4∼7℃로 25∼35분간 급냉시킴을 특징으로 하는 황토와 제올라이트를 주재로한 인조대리석의 제조방법.A mixture of 35 to 40 parts by weight of zeolite and 60 to 65 parts by weight of unsaturated polyester resin solution was applied to one surface of the mold 1 at a thickness of 0.5 to 1.0 mm, and then it was hardened at 95 to 105 ° C. for 25 to 35 minutes at a medium temperature. The mixture was quenched at 7 ° C. for 15 to 25 minutes and then filled with a mixture of ocher and unsaturated polyester resin solution at about 50 to 50 to a thickness of 9 to 15 mm through the inlet 5 of the upper mold 3. A process for producing artificial marble mainly composed of ocher and zeolite, characterized by hardening at 95 to 105 ° C. for 110 to 130 minutes, followed by quenching at 4 to 7 ° C. for 25 to 35 minutes.
KR19980021639A 1998-06-11 1998-06-11 Artificial marble with a loess and zeolite as a miain ingredient and method thereof KR100272421B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020027406A (en) * 2002-02-05 2002-04-13 오주희 A marble manufacture method by a loess
WO2006062373A1 (en) * 2004-12-09 2006-06-15 Cheil Industries Inc. Composite solid surface article containing ocher

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100361757B1 (en) * 1999-10-16 2002-11-22 고연종 Polyurethane Foam containing yellow soil and it's preparation method
KR100706642B1 (en) * 2006-01-06 2007-04-12 장동윤 A panel making method which happens the noctilucence with the negative ion with far infrared rays and panel
ES2336532B1 (en) * 2008-06-18 2011-02-18 Jesus Perez Gomez PROCESS FOR THE MANUFACTURE OF SINKS OR OTHER SIMILAR ELEMENTS AND SINK OR SIMILAR ELEMENT OBTAINED BY MEANS OF THIS PROCESS.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020027406A (en) * 2002-02-05 2002-04-13 오주희 A marble manufacture method by a loess
WO2006062373A1 (en) * 2004-12-09 2006-06-15 Cheil Industries Inc. Composite solid surface article containing ocher
US7875668B2 (en) 2004-12-09 2011-01-25 Cheil Industries Inc. Composite solid surface article containing loess

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