KR100262981B1 - Antibiotics compound and its lise for architecture interior decoration - Google Patents

Antibiotics compound and its lise for architecture interior decoration Download PDF

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KR100262981B1
KR100262981B1 KR1019980017413A KR19980017413A KR100262981B1 KR 100262981 B1 KR100262981 B1 KR 100262981B1 KR 1019980017413 A KR1019980017413 A KR 1019980017413A KR 19980017413 A KR19980017413 A KR 19980017413A KR 100262981 B1 KR100262981 B1 KR 100262981B1
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antimicrobial
antibiotic
interior material
composition
building
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KR1019980017413A
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Korean (ko)
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KR19990085190A (en
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홍성철
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홍성철
성진드림시스템주식회사
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/72—Pest control

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Civil Engineering (AREA)
  • Electromagnetism (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE: An interior material of a building containing antibiotic composition is provided, which can be applied to a place such as bathroom and kitchen, being in need of antibiotic function by mixing antibiotic composition with raw materials of the interior material of a building. CONSTITUTION: The interior material of a building is manufactured by following the processes of: preparing forming mold of chemical-resistant material such as aluminum mold; mixing 5% of synthetic zeolite composed of Ag2O3, ZnO, SiO2, Al2O3 as antibiotic materials, 10% of coating powder, 20% of transparent resin solvent, 5% of gel coating agent, and 60% of reinforcing filler; producing antibiotic composition; forming by spraying the composition on the mold; stripping, fabricating on the inside or the reverse side of the stripped product, reinforcing after combining with construction materials, and filling and manufacturing the antibiotic interior material.

Description

항균제 조성물 및 이를 이용한 건축물 내장재Antimicrobial composition and building interior using same

본 발명은 항균제를 원료에 배합하여 건축물 내장재를 성형함으로 욕실이나, 주방등 항균기능이 필요한 장소나 용도에 적합하게 설치될 수 있도록 한 항균제 조성물 및 이를 이용한 건축물 내장재에 관한 것이다.The present invention relates to an antimicrobial composition and a building interior material using the same by mixing the antimicrobial agent into a raw material so that the building interior material can be molded to be suitable for a place or a use that requires an antibacterial function such as a bathroom or a kitchen.

현재, 전 세계적으로 약 500여종으로 추산되는 바이러스의 출몰은 매우 치명적인 위험을 초래할 수 있는 것으로, 이를 방지하기 위한 항균제품의 선택적인 사용은 이미 전세계적인 추세로 확산되고 있다.At present, the appearance of about 500 species of viruses worldwide can pose a very fatal risk, and the selective use of antimicrobial products to prevent them is already spreading worldwide.

최근, 건강과 위생상의 관심은 전술한 항균제품의 사용을 촉진하였으며, 이에 따라 각종 문구류나, 침구(매트 등)에 선택적으로 적용되기 시작하였으며, 근래에는 벽지나, 타일등의 일부 건자재에도 한정적으로 바이오 세라믹등의 기능성 물질을 항균물질화 하여 채용하고 있다.Recently, health and hygiene interests have promoted the use of the aforementioned antimicrobial products, and thus have been selectively applied to various kinds of stationery and bedding (mats, etc.), and in recent years, limited to some building materials such as wallpaper and tiles. Functional materials such as bio ceramics are used as antibacterial materials.

그러나, 건축물의 실내에 있어서, 가장 세균의 번식과 전염이 용이한 곳의 하나로서 욕실과 주방이 선정될 수 있을 것이나, 항균 욕실에 적용될 수 있는 항균재의 개발과 안출은 현재 전혀 이루어지지 못하고 있음이 현 실정이다.However, in the interior of the building, the bathroom and the kitchen may be selected as one of the most easy to breed and spread germs, but the development and release of antimicrobial materials that can be applied to the antibacterial bathroom has not been made at all. It is the present situation.

특히, 일반 가정용 주택을 비롯하여 병원이나 호텔등의 공공시설물에서는 병원균의 2차 감염 및 불특정 다수인에의 전파 위험성 때문에 그 필요성은 매우 절실하다.In particular, in public facilities such as hospitals and hotels, as well as ordinary homes, the necessity is very urgent because of the risk of secondary infection of the pathogen and the spread to an unspecified number of people.

따라서, 본 발명은 성형품 원료에 배합되어진 항균제에 의하여 성형품 내에 함유된 항균제의 금속이온과 활성화 산소들이 세균이나 진균의 세포와 결합하여 세포의 에너지 대사를 불가능하게 함으로 효율적인 항균 작용이 가능할 수 있음을 그 안출된 목적으로 한다.Accordingly, the present invention is that the antimicrobial metal ions and active oxygen of the antimicrobial agent contained in the molded article by the antimicrobial agent blended in the raw material of the molded article can be combined with the cells of bacteria or fungi to make the energy metabolism of the cell can be effective antimicrobial effect It is for the purpose made.

이를 위하여 본 발명은 항균성을 지니고 있는 무기계화합물을 성형품에 배합하여 성형시킴으로 성형품 표면에 분포되어 있는 항균성 화합물의 이온 작용으로 표면에 붙어 있는 세균이나 곰팡이류에 대하여 적절히 항균작용이 가능할 수 있음에 착안되었다.To this end, the present invention has been conceived that the antimicrobial action can be properly applied to the bacteria or fungi attached to the surface by compounding the inorganic compound having antimicrobial properties to the molded product by forming and molding the antimicrobial compound distributed on the molded product surface.

도 1 의 (A)와 (B)도는 본 발명에 의해 제공될 수 있는 건축물 내장재의1 (A) and (B) of the building interior materials that can be provided by the present invention

성형 방법을 도시해 보인 각 단면 실시예도.Each cross-sectional example figure showing the shaping | molding method.

도 2 는 완성된 건축물 내장재의 전체적인 외관을 도시해 보인 사시도.Figure 2 is a perspective view showing the overall appearance of the finished building interior material.

*도면의 주요 부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

1 : 조립재 2 : 항균제층1: Assembly material 2: Antibacterial layer

3 : 젤 코팅층3: gel coating layer

상기의 목적 달성을 위한 본 발명의 항균제 조성물은 합성 제오라이트를 구성하는 Ag2O3, ZnO, SiO2, Al2O3의 항균재료 5％; 코팅 파우더 10％; 투명 수지 용매(M 702 Resin)20％; 겔 코팅제 5％; 및 보강 충진제 60％를 배합하여 형성됨을 특징으로 하며, 이를 이용한 건축물 내장재 제품에 있어서는 일정 형상을 유지하는 보강용 조립재; 상기 조립재의 외표면에 고른 두께 폭을 유지하도록 스프레이 도포되는 항균제층; 및 상기 항균제층의 외표면에 표면 보호막의 기능이 가능할 수 있도록 덧씌움처리되는 젤 코팅층이 일체화됨을 그 특징으로 한다.The antimicrobial composition of the present invention for achieving the above object is 5% of the antimicrobial material of Ag 2 O 3 , ZnO, SiO 2 , Al 2 O 3 constituting the synthetic zeolite; Coating powder 10%; 20% of a transparent resin solvent (M 702 Resin); Gel coating 5%; And characterized in that formed by blending 60% reinforcing filler, in the building interior products using the same, reinforcing assembly for maintaining a certain shape; An antimicrobial layer spray-coated to maintain an even thickness width on the outer surface of the assembly; And it is characterized in that the outer surface of the antimicrobial agent layer is integrated with the gel coating layer which is overlaid so that the function of the surface protective film is possible.

이하, 첨부도면을 참조하여 본 발명의 바람직한 실시예를 보다 구체적으로 상술한다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

예시된 도 1 의 (A)와 (B)도는 본 발명에 의해 제공될 수 있는 건축물 내장재의 성형 방법을 도시해 보인 각 단면 실시예도이며, 도 2 는 완성된 건축물 내장재의 전체적인 외관을 도시해 보인 사시도이다.1 (A) and (B) are illustrated each cross-sectional embodiment showing a method of forming the building interior material that can be provided by the present invention, Figure 2 shows the overall appearance of the finished building interior material Perspective view.

본 발명에 의해 제공되며, 건축물 내장재에 적용될 수 있는 항균제 조성물은 건축물 내장재의 원료에 배합됨으로 완성된 형태의 성형품이 제작되는 것으로 금속이온을 보유한 알루미나 규산염 무기화합물상의 합성 제오라이트를 구성하는 Ag2O3, ZnO, SiO2, Al2O3의 항균재료를 5％로 하며, 여기에 코팅 파우더 10％, 투명 수지 용매(상품명 M 702 Resin)20％를 배합하되, 겔 코팅제 5％와 충진 및 보강제로 60％가 더 포함되도록 하여 전체 비율 100％를 갖는 조성물을 마련하여, 통상 상기 조성물을 스프레이 도포시킴에 있어, 먼저 성형몰드가 준비된다.The antimicrobial composition provided by the present invention, which can be applied to building interior materials, is manufactured by mixing the raw materials of building interior materials with the finished form to produce a molded article of Ag 2 O 3 constituting a synthetic zeolite on an alumina silicate inorganic compound having metal ions. , ZnO, SiO 2 , Al 2 O 3 with 5% antibacterial material, 10% of the coating powder and 20% of a transparent resin solvent (trade name M 702 Resin) is blended with 5% of the gel coating agent and filling and reinforcing agent In forming a composition having a total ratio of 100% by further including 60%, and spray coating the composition, usually, a molding mold is prepared first.

상기 성형 몰드는 상기의 건축물 내장재 성형품을 형성시키기 위해 제공되는 것이며, 일반적으로 금형이나 알루미늄 몰드가 주로 채택되는데, 이때 제품의 수량이 많지 않고 형태가 다양할 경우에는 CFRP/GF계 몰드로 제품이 생산될 수 있음은 물론이다.The molding mold is provided to form the building interior molded article. In general, a mold or an aluminum mold is mainly adopted. In this case, when the quantity of the product is not large and the shape varies, the product is produced by a CFRP / GF mold. Of course it can be.

또한, 항균제에 포함된 은 이온은 성형시 산화나 열분해, 안료, 분산제 등과 같이 반응에 의해 금형의 변색이나 오염을 수반할 수 있어 비교적 충분한 내화학성을 갖는 재질을 선택하여 몰드가 제작됨이 바람직할 것이다.In addition, the silver ions included in the antimicrobial agent may be accompanied by discoloration or contamination of the mold by reaction such as oxidation, pyrolysis, pigment, dispersant, etc. during molding, so that the mold may be selected by selecting a material having relatively sufficient chemical resistance. will be.

이후, 상기에서와 같은 비율로 인해 각각의 재료가 적이 배합될 수 있는데, 내장재 제품의 용도에 따라 색상과, 질감은 물론 원료의 성분과 배합비가 결정된다.Thereafter, each material may be compounded due to the same ratio as described above. The color and texture, as well as the ingredients and the mixing ratio of the raw materials are determined according to the use of the interior product.

보편적으로, 분말상인 항균제는 수지와의 배합과정에서 기포가 발생하거나 분말이 서로 엉기지 아니하도록 각별한 주의가 요망되는 것이며, 특히 항균제중 은이온이 산화방지제나 성형시 발생하는 열, 착색용 염안료나 분산제 등에 의해서도 변색의 우려는 충분함으로 이에 대한 재료 선택에도 특별한 주의가 필요할 것이다.In general, the antimicrobial in powder form requires special care to prevent bubbles or powders from intertwining with the resin. Especially, the silver ions among the antimicrobial agents are anti-oxidants or coloring salt pigments generated during molding. However, discoloration is also a concern for discoloration, so special care should be taken in selecting the material.

이후, 첨부된 도면에서와 같이 배합된 원료를 몰드상에 주입하고 성형하는 공정이 마련되는데, 내장재의 기능의 따라 그 스프레이 도포는 단면 제품 도포방식과 양면 제품 도포 방식으로 구분된다.Subsequently, a process of injecting and molding the blended raw material into a mold is provided as shown in the accompanying drawings. The spray coating is divided into a single-sided product application method and a double-sided product application method according to the function of the interior material.

상기의 과정후에 탈형된 성형 제품의 내부 또는 뒷면으로 조립, 시공자재를 결합한 후 보강, 충진하는 공정을 거침에 따라 제품의 기능성과 함께 시공성에 충분하게 부합할 수 있으며, 장기적 사용에 의한 내구성을 향상시키게 된다.After the above process, the process of reinforcing and filling after assembling and combining construction materials into the inside or the back of the demolded molded product can be fully satisfied with the functionality and workability of the product, and improves durability by long-term use. Let's go.

따라서, 상기의 조성물에 의해 완성된 상태로 설치될 수 있는 항균성 내장재는 보강용 조립재(1)와 상기 조립재(1)의 외표면에 일정 두께를 유지한 채 고른 표면을 갖도록 스프레이 도포되는 항균제층(2), 그리고 상기 항균제층(2)의 외표면에 투명 수지 용매로 덧씌움처리되는 젤 코팅층(3)이 일체화된 형식을 갖는다.Therefore, the antimicrobial interior material that can be installed in a completed state by the composition is an antimicrobial agent spray-coated to have an even surface while maintaining a certain thickness on the reinforcing assembly material 1 and the outer surface of the assembly material 1. The layer 2 and the outer surface of the antimicrobial agent layer 2 have a form in which the gel coating layer 3 which is covered with a transparent resin solvent is integrated.

한편, 상기 항균제층(2)을 구성하는 항균제는 유기계 항균제 보다는 특히 무기계 항균제가 채용되는데, 무기계 항균제는 은(은이온)에 의한 항균효과를 주로 이용하고 있으며, 합성 제오라이트에 항균성을 지닌 은, 동, 아연등의 금속 이온을 첨가한 화합물이다.On the other hand, the antimicrobial agent constituting the antimicrobial agent layer (2), in particular inorganic antimicrobial agent is employed rather than organic antimicrobial agent, inorganic antimicrobial agent is mainly utilizing the antimicrobial effect by silver (silver ions), silver, copper having antimicrobial properties to synthetic zeolites It is a compound which added metal ions, such as zinc.

상기와 같은 본 발명에 따르면, 그 항균작용은 항균성 제오라이트를 구성하고 있는 항균성 금속(Ag, Cu, Zn 등)의 일부가 금속이온으로 해리, 확산에 의해 세균이나 미생물에 도달하여 세포내 단백질과 결합함으로 세균이나 미생물의 에너지 대사를 불가능하게 하여 항균작용을 일으킨다는 예견적 기대감을 만족시키게 된다.According to the present invention as described above, the antimicrobial action is that a part of the antimicrobial metal (Ag, Cu, Zn, etc.) constituting the antimicrobial zeolite reaches the bacteria or microorganisms by dissociation and diffusion into metal ions and binds to intracellular proteins As a result, it is possible to satisfy the predictive expectation that antibacterial activity is caused by disabling energy metabolism of bacteria or microorganisms.

또한, 항균성 제오라이트의 모체중의 산소는 결합해 있는 항균 금속의 촉매 작용에 의해서 부분적으로 활성산소(O, O2 -, O2 +)로 되어 오존(O3), 과산화수소(H2O2)와 같이 강력한 항균작용을 한다는 것이 하기의 시험표에 의하여 증명된다.Further, partly active oxygen by the catalytic action of the antimicrobial metal to oxygen is bonded in the matrix of the antimicrobial zeolite - is a (O, O 2, O 2 +) ozone (O 3), hydrogen peroxide (H 2 O 2) It is demonstrated by the following test table that the strong antibacterial action as shown in the following.

시험분석표Test Analysis Table

사용수지Resin 항균제Antimicrobial 첨가량Amount 대장균에 대한 항균효과Antibacterial Effect on Escherichia Coli 개시시At the start 6시간후6 hours later 24시간후24 hours later TPX 210TPX 210 BM 102TBM 102T 0.5%0.5% 4.9×105 4.9 × 10 5 2.8×104 2.8 × 10 4 3030 TPX 210TPX 210 BM 102TBM 102T 1.0%1.0% 〃〃 〈10〈10 〈10〈10 TPX 210TPX 210 BM 102KBM 102K 0.5%0.5% 〃〃 1.2×104 1.2 × 10 4 2020 TPX 210TPX 210 BM 102KBM 102K 1.0%1.0% 〃〃 〈10〈10 〈10〈10 TPX 210TPX 210 -- -- 〃〃 1.0×106 1.0 × 10 6 1.7×105 1.7 × 10 5 빛(샤레)Light (Share) -- -- 〃〃 7.3×105 7.3 × 10 5 2.4×106 2.4 × 10 6

사용수지Resin 항균제Antimicrobial 첨가량Amount 황색 포도상 구균에 대한 항균Antibacterial against Staphylococcus aureus 개시시At the start 6시간후6 hours later 24시간후24 hours later TPX 210TPX 210 BM 102TBM 102T 0.5%0.5% 1.4×105 1.4 × 10 5 3.8×104 3.8 × 10 4 4.2×102 4.2 × 10 2 TPX 210TPX 210 BM 102TBM 102T 1.0%1.0% 〃〃 3.9×103 3.9 × 10 3 〈10〈10 TPX 210TPX 210 BM 102KBM 102K 0.5%0.5% 〃〃 4.0×104 4.0 × 10 4 5050 TPX 210TPX 210 BM 102KBM 102K 1.0%1.0% 〃〃 4.0×103 4.0 × 10 3 〈10〈10 TPX 210TPX 210 -- -- 〃〃 9.3×104 9.3 × 10 4 1.9×105 1.9 × 10 5 빛(샤레)Light (Share) -- -- 〃〃 9.8×104 9.8 × 10 4 8.7×104 8.7 × 10 4

또한, 전술한 바와 같은 무기계 항균제의 은(Ag)은 안전도가 매우 우수한 원소로써 우리 생활용품으로 광범위하게 사용되고 있으며, 항균효과의 지속적인 유지가 가능하다는 장점이 있다.In addition, silver (Ag) of the inorganic antimicrobial agent as described above is widely used as our daily necessities as a very excellent element of safety, there is an advantage that can maintain the antibacterial effect.

따라서, 본 발명에 의한 항균성 성형품은 사용하고자 하는 용도와 기능에 따른 항균제 원료의 선택은 물론, 배합비와 성형방법, 그리고 성형의 조건을 달리하여 예컨대, 병원, 호텔등의 공공 시설물에 있어서, 욕실과 주방등 특히 위생이 요구되는 곳에 적절히 응용될 수 있는 유용성을 갖는다.Accordingly, the antimicrobial molded article according to the present invention may be used in a public facility such as a hospital or a hotel by varying the mixing ratio, the molding method, and the molding conditions, as well as the selection of the antimicrobial raw material according to the intended use and function. In kitchens, especially where hygiene is required, it can be suitably applied.

한편 본 발명은 그에 관한 최선의 실시예를 예거하였으나, 굳이 이에 한정되는 것은 아니며, 첨부된 청구 범위에 국한되어 본 발명의 범위를 벗어나지 않고 실시될 수 있다면 지금까지 설명된 실시예의 변경을 고려해 볼 수도 있음은 물론일 것이다.Meanwhile, the present invention exemplifies the best embodiment thereof, but is not necessarily limited thereto, and may be considered without departing from the scope of the present invention without departing from the scope of the present invention. Of course it will.

Claims (2)

합성 제오라이트를 구성하는 Ag2O3, ZnO, SiO2, Al2O3의 항균재료 5％; 코팅 파우더 10％; 투명 수지 용매(M 702 Resin)20％; 겔 코팅제 5％; 및 보강 충진제 60％를 배합하여 형성됨을 특징으로 하는 항균제 조성물.5% of the antibacterial material of Ag 2 O 3 , ZnO, SiO 2 , Al 2 O 3 constituting the synthetic zeolite; Coating powder 10%; 20% of a transparent resin solvent (M 702 Resin); Gel coating 5%; And 60% of a reinforcing filler. 일정 형상을 유지하는 보강용 조립재; 상기 조립재의 외표면에 고른 두께 폭을 유지하도록 스프레이 도포되는 항균제층; 및 상기 항균제층의 외표면에 표면 보호막의 기능이 가능할 수 있도록 덧씌움처리되는 젤 코팅층이 일체화됨을 그 특징으로 하는 항균제 조성물을 이용한 건축물 내장재.Reinforcing assembly to maintain a certain shape; An antimicrobial layer spray-coated to maintain an even thickness width on the outer surface of the assembly; And building interior material using an antimicrobial composition, characterized in that the gel coating layer which is overlaid so that the function of the surface protective film is integrated on the outer surface of the antimicrobial agent layer.
KR1019980017413A 1998-05-14 1998-05-14 Antibiotics compound and its lise for architecture interior decoration KR100262981B1 (en)

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Publication number Priority date Publication date Assignee Title
KR20010026322A (en) * 1999-09-04 2001-04-06 이재명 Device and method for molding interior boards for construction
KR101303530B1 (en) 2012-05-09 2013-09-03 주식회사 아담스컴퍼니 Inorganic anti-bacterial, anti-fungal and deordorizing composition and process for preparing the same

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KR101634616B1 (en) * 2014-10-22 2016-06-30 주식회사 피앤아이 Insulation sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010026322A (en) * 1999-09-04 2001-04-06 이재명 Device and method for molding interior boards for construction
KR101303530B1 (en) 2012-05-09 2013-09-03 주식회사 아담스컴퍼니 Inorganic anti-bacterial, anti-fungal and deordorizing composition and process for preparing the same

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