KR100234619B1 - Starch gel with mugwort juice - Google Patents

Starch gel with mugwort juice Download PDF

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KR100234619B1
KR100234619B1 KR1019970061772A KR19970061772A KR100234619B1 KR 100234619 B1 KR100234619 B1 KR 100234619B1 KR 1019970061772 A KR1019970061772 A KR 1019970061772A KR 19970061772 A KR19970061772 A KR 19970061772A KR 100234619 B1 KR100234619 B1 KR 100234619B1
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mugwort
starch
jelly
fiber
powder
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KR1019970061772A
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Korean (ko)
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KR19990041214A (en
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정구민
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정구민
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/09Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/105Plant extracts, their artificial duplicates or their derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/13General methods of cooking foods, e.g. by roasting or frying using water or steam
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/50Polysaccharides, gums
    • A23V2250/51Polysaccharide
    • A23V2250/5118Starch

Abstract

본 발명은 쑥에서 단단한 불용성 섬유질 성분을 제거하고 쑥의 수용성 섬유질을 함유하는 쑥즙섬유를 전분에 첨가하여 제조하는 쑥즙이 첨가된 묵에 관한 것이다.The present invention relates to a mugwort added jelly prepared by removing a hard insoluble fiber component from mugwort and adding mugwort fibers containing water-soluble fiber of mugwort to starch.

본 발명은 수분, 조단백, 조지방, 조회분, 식이섬유 등 일반 성분을 분석하는 공정; 물결합능력, 용해도, 팽윤력 같은 이화학적 성질을 측정하는 공정; 아밀로그램을 측정하는 공정; 묵을 제조하고 경도를 측정하는 공정; 묵의 호화도를 측정하는 공정; 묵의 냉동-해동시 안정도를 측정하는 공정으로 구성된다.The present invention is a process for analyzing the general components such as moisture, crude protein, crude fat, crude ash, dietary fiber; Measuring physicochemical properties such as water binding capacity, solubility, and swelling power; Measuring amylogram; Preparing jelly and measuring hardness; Measuring the degree of gelatinization of the jelly; It consists of measuring the stability of the freeze-thaw of jelly.

본 발명에 의해서 쑥즙섬유를 첨가하여 묵을 제조하면 묵의 호화도가 증대되고 강도가 향상되는 효과가 있으며, 쑥자체를 첨가할 때보다는 거친 불용성 섬유질이 제거되기 때문에 표면이 매끈하여 관능적 특성이 향상된 묵식품을 만들 수 있고, 이밖에도 쑥즙분말의 첨가함으로써 점도가 낮아져서 감자전분의 호화작업시 에너지 소비가 절감될 수 있는 효과가 있어 식품산업상 매우 유용한 발명인 것이다.According to the present invention, when the jelly is prepared by adding mugwort fibers, the gelatinization of the jelly is increased and the strength is improved, and the surface is smooth and the sensory properties are improved because the rough insoluble fiber is removed than when the mugwort is added. Food can be made, in addition to the addition of the mugwort juice powder viscosity is low because the energy consumption can be reduced during the gelatinization work of potato starch is a very useful invention in the food industry.

Description

쑥즙이 첨가된 묵 {Starch Gel with Mugwort Juice}Mugwort jelly {Starch Gel with Mugwort Juice}

본 발명은 쑥즙이 첨가된 묵에 관한 것이다. 더욱 상세하게는 본 발명은 쑥에서 단단한 불용성 섬유질 성분을 제거하고 쑥의 수용성 섬유질을 함유하는 쑥즙섬유를 전분에 첨가하여 제조하는 쑥즙이 첨가된 묵에 관한 것이다.The present invention relates to a mugwort added with mugwort juice. More specifically, the present invention relates to a mugwort added jelly prepared by removing a hard insoluble fiber component from mugwort and adding mugwort fibers containing water-soluble fiber of mugwort to starch.

식품내 존재하는 여러 성분들이 전분의 호화와 노화에 영향을 주는데 섬유질도 그중의 하나이다. Christianson등(1981) 은 밀전분에 guar gum, cellulose, xanthan gum을 첨가하였을 때 호화개시온도가 낮아진다고 하였다. Sajjan과 Rao(1987)는 hydro colloids가 전분의 아밀로그래프상의 최고점도를 증가시키고 노화를 억제한다고 하였으며 이는 hydrocolloids가 가열에 의해 전분입자로부터 유출된 아밀로오스와 상호 작용하기 때문이라고 하였다. Kohyama와 Nishinari(1992)는 고구마 전분에 여러 섬유질을 첨가해 본 결과 비수용성 cellulose derivatives는 전분의 노화를 촉진하며 수용성 methyl cellulose는 노화를 억제한다고 보고하였다. Eidam(1995)등은 caboxymethy lcellulose, locust bean gum, guar gum, k-carrageenan, xanthan gum이 전분의 초기겔화(1-2시간)를 촉진하나 ℓ-carrageenan은 겔화를 지연시킨다고 하였다. 그러나 이들 hydrocolloids 모두 겔화 종료후(약 12시간)의 겔의 강도는 감소시켰다. 김과 윤(1984)이 식이섬유를 백설기에 첨가하여 강도를 측정한 결과 sodium alginate는 강도를 증가시켰으며 gum arabic은 강도를 감소시켰다. 최와 이(1992)는 wheat bran, cellulose, pectin 모두 백설기의 강도를 감소시킨다고 하였다. 따라서, 섬유질은 그 종류에 따라 전분의 호화와 노화에 다른 영향을 끼친다고 볼 수 있다.Many of the ingredients in food affect starch gelatinization and aging, and fiber is one of them. Christianson et al. (1981) found that the gelatinization temperature decreased when guar gum, cellulose and xanthan gum were added to wheat starch. Sajjan and Rao (1987) report that hydro colloids increase starch amylograph viscosity and inhibit aging because hydrocolloids interact with amylose released from starch particles by heating. Kohyama and Nishinari (1992) reported that the addition of various fibers to sweet potato starch indicates that water-insoluble cellulose derivatives promote starch aging and water-soluble methyl cellulose inhibits aging. Eidam (1995) reported that caboxymethy lcellulose, locust bean gum, guar gum, k-carrageenan, and xanthan gum promote early gelation of starch (1-2 hours), while l-carrageenan delays gelation. However, all of these hydrocolloids had reduced gel strength after the end of gelation (about 12 hours). Kim and Yun (1984) added dietary fiber to snow white to measure the strength. Sodium alginate increased the strength and gum arabic decreased the strength. Choi and Lee (1992) found that wheat bran, cellulose and pectin all reduced the strength of snow white. Therefore, fiber can be said to have a different effect on the gelatinization and aging of starch depending on the type.

쑥은 우리나라에 널리 분포하는 다년생 식물로 예로부터 식용 및 약용으로 널리 쓰이고 있다. 더구나 근래에는 건강에 관심을 많이 갖게된 국민들이 자연식품과 식이섬유에 대한 인식이 높아져 이의 이용도가 확산되어가고 있다. 쑥의 식품등에서의 효능과 생리적 기능성을 조사한 연구를 보면 쑥을 백설기에 첨가할 때 쑥을 많이 첨가할수록 쑥설기의 조직이 부드러워진다고 하였으며, 쑥의 메탄올 추출물은 항궤양의 효과가 있고 쑥의 물추출물과 에탄올 추출물은 장내 Bifidobacteria의 증식을 촉진한다고 하였다. 또한 쑥의 열수 및 70% 아세톤 추출물은 항변이원성이 있는 것으로 알려지고 있다.Wormwood is a perennial plant widely distributed in Korea and has been widely used for food and medicine since ancient times. Moreover, in recent years, people who have been interested in health have increased their awareness of natural foods and dietary fiber, and their use is spreading. Studies on the efficacy and physiological functionalities of mugwort in foods showed that the more mugwort is added when the mugwort is added to snow white, the softer the structure of mugwort is. The methanol extract of mugwort has anti-ulcer effect and water extract of mugwort And ethanol extracts promote the growth of intestinal Bifidobacteria. In addition, mugwort's hot water and 70% acetone extract are known to be antimutagenic.

종래에, 쌀가루와 쑥 혼합물을 가열하여 쑥이 쌀가루의 페이스트와 묵에 미치는 영향에 관해 연구한 결과 쌀가루에 쑥 첨가시 고형분의 증가로 페이스트의 점도가 증가하였으며 묵 경도도 역시 커짐을 알 수 있었다. 이는 쑥 성분의 약 반정도인 비수용성 섬유가 묵 내에 있어서 단단한 뼈대 역할을 하기 때문이라고 해석하였다.Conventionally, as a result of studying the effect of mugwort on the paste and jelly of rice flour by heating the mixture of rice flour and mugwort, it was found that the viscosity of the paste was increased due to the increase of solid content when the mugwort was added to rice flour and the jelly hardness was also increased. It was interpreted that the water-insoluble fiber, which is about half of the wormwood component, acts as a solid skeleton in the jelly.

이에 본 발명자들은 쑥에서 단단한 섬유질 성분을 제거한 후 전분에 첨가한다면 상대적으로 증가한 수용성 섬유의 영향으로 호화도가 크고 적절한 강도를 갖는 우수한 묵이 제조될 것이라고 생각하고 쑥의 성분을 조사하고 녹말의 겔화에 미치는 영향을 조사하여 본 발명을 안출하게 되었다.Therefore, the present inventors thought that if the hard fiber component was removed from the mugwort and added to starch, an excellent jelly with a high degree of luxury and adequate strength would be produced under the influence of relatively increased water-soluble fibers. Investigations have been made into the present invention.

따라서, 본 발명은 상기와 같은 사실에 의거하여 안출한 것으로 쑥에서 단단한 불용성 섬유질 성분을 제거한 후 전분에 첨가하였을 때 묵의 호화도와 묵 강도등에 미치는 영향을 조사하고 쑥즙이 첨가된 묵을 제조하는 것을 그 목적으로 한다.Therefore, the present invention was made on the basis of the above facts, and after removing the hard insoluble fibrous component from the mugwort, the effect on the gelatinization and jelly strength of the jelly when added to the starch and the production of mugwort added jelly The purpose.

이하, 본 발명의 구성과 작용을 설명한다.Hereinafter, the configuration and operation of the present invention.

본 발명은 수분, 조단백, 조지방, 조회분, 식이섬유등 일반 성분을 분석하는 공정; 물결합능력, 용해도, 팽윤력 같은 이화학적 성질을 측정하는 공정; 아밀로그램을 측정하는 공정; 묵을 제조하고 묵의 경도를 측정하는 공정; 묵의 호화도를 측정하는 공정; 묵의 냉동-해동시 안정도를 측정하는 공정으로 구성된다.The present invention is a process for analyzing the general components such as moisture, crude protein, crude fat, crude ash, dietary fiber; Measuring physicochemical properties such as water binding capacity, solubility, and swelling power; Measuring amylogram; Preparing the jelly and measuring the hardness of the jelly; Measuring the degree of gelatinization of the jelly; It consists of measuring the stability of the freeze-thaw of jelly.

이하, 본 발명의 구체적인 구성과 작용을 실시예를 들어 상세히 설명한다.Hereinafter, the specific configuration and operation of the present invention will be described in detail by way of examples.

실시예 1. 일반성분 분석Example 1 General Component Analysis

본 발명에서 옥수수 전분과 감자전분은 Sigma(미국)사 제품(각각 S-4126, S-4251)을, 녹두전분은 전남 나주공산농협의 녹두를 알카리 침지법으로 제조한 것을 사용하였다. 쑥은 경북 안동시 와룡에서 채취한 것으로 쑥즙분말은 쑥을 끓는 물에서 5분간 데친 다음 녹즙기(그린파워 GP-1511)로 짠 후 냉동건조하여 사용하였다. 쑥즙분말의 수율은 약 2.2%(wet basis)이었다. 쑥즙섬유는 쑥즙분말을 식이섬유 측정방법을 응용하여 제조하였으며 그 방법은 다음과 같다. 쑥즙분말을 α-amylase, protease, amyloglucosidase로 연속적으로 처리한 후 95% 알코올로 침전시켰다. 침전물을 G4 glass filter로 여과하였고 잔유물을 아세톤으로 씻고 건조시켰으며 사용한 효소를 불활성하기 위하여 위의 건조물을 물에 푼 후 121℃에서 15분간 가열한 다음 냉동건조하였다. 쑥즙섬유의 수율은 쑥즙분말로부터 약 35%(wet basis)이었다. 사용한 효소는 Sigma사 제품(TDF-100A)이었다.In the present invention, corn starch and potato starch were manufactured by Sigma (USA), Inc. (S-4126 and S-4251, respectively), and mungbean starch was prepared by using an alkali dipping method of green beans of Naju Communist Nonghyup. Mugwort was collected from Waryong, Andong-si, Gyeongbuk. Mugwort powder was simmered in boiling water for 5 minutes, squeezed with green juice (Green Power GP-1511) and freeze-dried. The yield of mugwort powder was about 2.2% (wet basis). Wormwood fiber was prepared by applying the dietary fiber measurement method of wormwood powder as follows. Mugwort powder was successively treated with α-amylase, protease and amyloglucosidase and precipitated with 95% alcohol. The precipitate was filtered through a G4 glass filter, the residue was washed with acetone and dried, and the above dried product was poured into water to inactivate the used enzyme, heated at 121 ° C. for 15 minutes, and then freeze-dried. The yield of mugwort fiber was about 35% (wet basis) from mugwort powder. The enzyme used was Sigma Corporation (TDF-100A).

수분, 조단백, 조지방, 조회분, 식이섬유 함량은 AOAC방법으로 측정하였다.Moisture, crude protein, crude fat, crude ash, and dietary fiber content were measured by AOAC method.

실험결과, 시료로 사용한 쑥즙분말, 쑥즙섬유, 전분의 일반성분은 하기 표 1과 같다.Experimental results, the general components of mugwort powder, mugwort fiber, starch used as a sample are shown in Table 1 below.

쑥즙분말과 전분의 화학적 조성Chemical Composition of Mugwort Powder and Starch 시료sample 조단백Crude protein 조지방Crude fat 조회분View minutes 가용성 식이섬유Soluble Fiber 불용성식이섬유Insoluble Dietary Fiber 전분질1) Starch 1) 2) Wormwood 2) 32.232.2 3.53.5 5.85.8 6.76.7 42.742.7 9.19.1 쑥즙분말Wormwood powder 31.831.8 4.64.6 13.613.6 12.812.8 29.929.9 7.37.3 쑥즙섬유Mugwort fiber 22.022.0 3.83.8 19.319.3 26.226.2 32.132.1 -- 옥수수 전분Corn starch 0.440.44 0.460.46 0.050.05 -- -- -- 녹두 전분Mung bean starch 0.100.10 0.310.31 0.210.21 -- -- -- 감자 전분Potato starch 0.140.14 0.260.26 0.040.04 -- -- -- 주:1)100%-content of(crude protein+crude lipid+crude ash+dietary fibers)2)정구민: Korean J. Food Sci. Technol. 25, 626(1993) -: 미측정Note: 1) 100% -content of (crude protein + crude lipid + crude ash + dietary fibers) 2) Jung-min: Korean J. Food Sci. Technol. 25, 626 (1993)-: Not measured

쑥즙분말의 일반성분을 쑥과 비교해 보면 회분의 경우 쑥의 5.8%에 비해 상당히 많이 존재하였다. 이것은 쑥에 있는 무기질이 쑥즙 채취시 많이 추출되어 나옴을 나타낸다. 식이섬유의 함량을 보면 쑥이 수용성 식이섬유를 6.7%, 불용성 식이섬유를 42.7% 함유하고 있는데 비해 쑥즙분말은 수용성 식이섬유를 12.8%, 불용성 식이섬유를 29.9% 함유하고 있는 것으로 나타나 전체 식이섬유 함량은 줄었지만 수용성 성분의 함량은 약 2배로 증가하였다.Compared with the common components of mugwort powder, the contents of the mugwort juice were significantly higher than those of wormwood. This indicates that the mineral in the mugwort is extracted a lot during mugwort juice extraction. The contents of dietary fiber showed that wormwood contains 6.7% water soluble fiber and 42.7% insoluble fiber, whereas mugwort powder contains 12.8% water soluble fiber and 29.9% insoluble fiber. Was reduced, but the content of water-soluble components increased by about two times.

쑥즙분말에 전분 가수분해효소와 단백질 분해효소를 처리하여 만든 쑥즙섬유에는 단백질이 22.0% 함유되어 있었다. 이것은 쑥즙분말을 단백질 분해효소를 처리하여도 쑥즙에 있는 단백질이 완전히 분해되지 않았고 또 사용한 효소가 쑥즙섬유 제조시 알코올에 침전되어 쑥즙섬유에 포함되었기 때문이라 여겨진다. 쑥즙섬유의 조지방의 함량은 쑥즙분말에 비해 약간 줄어들었으며 조회분의 함량은 19.3%로 쑥즙분말에 비해 높았다. 이는 쑥즙섬유 제조시 사용한 완충용액, 산, 염기의 무기질이 단백질과 마찬가지로 알코올에 침전되면서 쑥즙섬유로 전이되었음을 나타낸다. 수용성 식이섬유의 함량은 쑥즙분말보다 높아 26.2%이었으며 불용성 식이섬유의 함량은 쑥즙분말과 비슷한 32.1%를 나타냈다. 쑥즙섬유의 제조는 쑥즙분말에 함유된 단백질과 전분을 제거하여 상대적으로 수용성 식이섬유의 함량을 높이고 이의 묵에 대한 효과를 조사하고자 한 것이었으나 그 함량의 증가는 기대치에 미치지 못하였다. 쑥즙섬유의 성분을 다 더할 때 100%가 넘는 것은 실험오차 때문이며 전분질 물질은 쑥즙섬유 제조시 효소에 의해 다 분해된 것으로 보인다.Mugwort fibers made by processing starch hydrolase and protease in mugwort powder contained 22.0% of protein. This is because the protein in mugwort was not completely decomposed even though proteolytic enzyme was treated with mugwort powder, and the enzyme used was precipitated in alcohol during the preparation of mugwort fiber and included in mugwort fiber. Crude fat content of mugwort fiber was slightly decreased compared with mugwort powder and crude ash content was 19.3% higher than mugwort powder. This indicates that the buffer, acid, and base minerals used in the production of mugwort fibers were transferred to mugwort fibers as they precipitated in alcohol as in proteins. The content of water-soluble dietary fiber was 26.2% higher than that of mugwort powder, and the content of insoluble fiber was 32.1% similar to that of mugwort powder. The production of mugwort fiber was to remove protein and starch contained in mugwort powder to increase the content of water-soluble dietary fiber and to investigate its effect on jelly. However, the increase of the content was not as expected. Adding more than 100% of the mugwort fiber is due to experimental errors and the starch material seems to be decomposed by enzymes in the production of mugwort fiber.

실시예 2. 이화학적 성질 조사Example 2 Investigation of Physicochemical Properties

전분에 쑥즙분말과 쑥즙섬유를 각각 5, 10% 첨가하여 물결합능력, 용해도, 팽윤력을 측정하였다. 다만 감자전분의 경우 용해도와 팽윤력은 85℃에서 30분간 가열한 후 페이스트를 원심분리하였을 때 상등액과 침전물이 분명하게 분리되지 않아 측정할 수 없었다.5, 10% of mugwort powder and mugwort fiber were added to starch to measure water binding ability, solubility, and swelling power. However, in the case of potato starch, the solubility and swelling power could not be measured because the supernatant and precipitate were not clearly separated when the paste was centrifuged after heating at 85 ° C. for 30 minutes.

실험결과, 전분과 쑥즙, 그리고 쑥즙을 전분에 5, 10% 첨가하여 측정한 혼합물의 물결합능력, 85℃에서의 용해도, 팽윤력은 하기 표 2와 같다.Experimental results, starch and mugwort juice, and the water binding capacity of the mixture measured by adding 5, 10% to the mugwort juice, solubility at 85 ℃, swelling power is shown in Table 2 below.

쑥즙1)과 혼합한 전분의 물결합능력, 용해도, 팽윤력Water binding capacity, solubility, swelling power of starch mixed with mugwort juice 1) 시료sample WHC(%)WHC (%) 용해도(%)Solubility (%) 85℃에서 팽윤력Swelling Force at 85 ℃ 그룹ⅠGroup I 옥수수 전분(CS)Corn Starch (CS) 232±2.0a 232 ± 2.0 a 4.48±0.629a 4.48 ± 0.629 a 9.6±0.04a 9.6 ± 0.04 a CS+5% 쑥즙분말CS + 5% Wormwood Powder 238±1.6ab 238 ± 1.6 ab 8.04±0.170c 8.04 ± 0.170 c 10.5±0.05ab 10.5 ± 0.05 ab CS+10% 쑥즙분말CS + 10% Wormwood Powder 251±8.7bc 251 ± 8.7 bc 10.55±0.330d 10.55 ± 0.330 d 11.0±0.03b 11.0 ± 0.03 b CS+5% 쑥즙섬유CS + 5% Wormwood Fiber 251±8.7bc 251 ± 8.7 bc 6.39±0.962b 6.39 ± 0.962 b 10.7±0.93ab 10.7 ± 0.93 ab CS+10% 쑥즙섬유CS + 10% Wormwood Fiber 264±3.2c 264 ± 3.2 c 8.21±0.728c 8.21 ± 0.728 c 10.1±0.28ab 10.1 ± 0.28 ab 그룹ⅡGroup II 녹두 전분(MS)Mung bean starch (MS) 229±1.2a 229 ± 1.2 a 13.75±1.230a 13.75 ± 1.230 a 15.3±0.05e 15.3 ± 0.05 e MS+5% 쑥즙분말MS + 5% mugwort powder 248±0.4b 248 ± 0.4 b 15.26±0.926a 15.26 ± 0.926 a 13.8±0.06b 13.8 ± 0.06 b MS+10% 쑥즙분말MS + 10% Wormwood Powder 263±4.8c 263 ± 4.8 c 16.21±0.332a 16.21 ± 0.332 a 12.9±0.18a 12.9 ± 0.18 a MS+10% 쑥즙섬유MS + 10% Wormwood Fiber 260±5.1c 260 ± 5.1 c 15.40±1.549a 15.40 ± 1.549 a 14.7±0.17d 14.7 ± 0.17 d MS+10% 쑥즙섬유MS + 10% Wormwood Fiber 285±0.8d 285 ± 0.8 d 16.82±2.114a 16.82 ± 2.114 a 14.3±0.09c 14.3 ± 0.09 c 그룹ⅢGroup III 감자 전분(PS)Potato Starch (PS) 239±15.9a 239 ± 15.9 a -- -- PS+5% 쑥즙분말PS + 5% Wormwood Powder 258±3.6ab 258 ± 3.6 ab -- -- PS+10% 쑥즙분말PS + 10% Wormwood Powder 278±1.5b 278 ± 1.5 b -- -- PS+5% 쑥즙섬유PS + 5% Wormwood Fiber 285±16.3bc 285 ± 16.3 bc -- -- PS+10% 쑥즙섬유PS + 10% Wormwood Fiber 311±4.5c 311 ± 4.5 c -- -- 그룹ⅣGroup IV 쑥즙분말Mugwort powder 347347 42.1242.12 10.710.7 그룹ⅤGroup V 쑥즙섬유Mugwort fiber 494494 35.4335.43 14.414.4 주:1)Average of two measurements±S.E.a-eMean in the same column not followed by the same letter are significantly different at p〈0.05 by LSD method.Note: 1) Average of two measurements ± SE ae Mean in the same column not followed by the same letter are significantly different at p 〈0.05 by LSD method.

실험결과, 전분에 쑥즙분말이나 쑥즙섬유를 첨가하였을 때 물결합능력이 증가하였는데 이는 쑥즙분말과 쑥즙섬유의 물결합능력(각각 347%와 494%)이 전분(229~239%)보다 크기 때문이었다. 용해도의 경우 옥수수 전분에서는 쑥즙을 첨가할수록 증가하였으나 팽윤력에는 별 차이가 없었다. 녹두전분에서는 용해도가 쑥즙 첨가로 약간 증가하였으나 유의성은 없었고 팽윤력은 오히려 감소하는 경향을 보였다. 이는 쑥즙분말과 쑥즙섬유 자체의 용해도와 팽윤력이 상기 표 2에서 보는 바와 같이 전분보다 높거나 낮기 때문이며 쑥즙이 전분자체의 용해도와 팽윤력에 영향을 끼치지는 못하는 것으로 보였다.Experimental results showed that the water binding capacity of mugwort powder and mugwort fiber was increased when wormwood powder or mugwort fiber was added to starch because the water binding capacity of wormwood powder and mugwort fiber (347% and 494%, respectively) was larger than starch (229 ~ 239%). . The solubility of corn starch increased with the addition of mugwort juice, but there was no difference in swelling power. The solubility of mungbean starch was slightly increased by the addition of mugwort juice, but there was no significant difference. This is because the solubility and swelling power of the mugwort powder and mugwort fiber itself is higher or lower than starch as shown in Table 2, and the mugwort juice did not seem to affect the solubility and swelling power of the starch itself.

실시예 3. 아밀로그램Example 3. Amylogram

전분에 쑥즙분말을 첨가(6% 전분+0.3% 쑥즙분말)하여 Visco/amylo/Graph를 이용하여 측정하였다. 현탁액은 30℃에서 95℃까지 분당 1.5℃로 온도를 상승시켰으며 95℃에서 15분간 유지한 후 50℃까지 분당 같은 속도로 온도를 하강시켰다.Mugwort powder was added to the starch (6% starch + 0.3% mugwort powder) and measured using Visco / amylo / Graph. The suspension was heated to 1.5 ° C. per minute from 30 ° C. to 95 ° C. and held at 95 ° C. for 15 minutes and then lowered to 50 ° C. at the same rate per minute.

전분에 쑥즙분말을 5% 첨가하여 측정한 아밀로그램의 주요 지표는 하기 표 3과 같다.Main indicators of amylogram measured by adding 5% of mugwort powder to starch are shown in Table 3 below.

쑥즙분말(0.3%)를 첨가한 전분(6%)의 Viscoamylograph dataViscoamylograph data of starch (6%) added with mugwort powder (0.3%) SampleSample Pasting temperature, ℃Pasting temperature, ℃ Viscocity(BU) atViscocity (BU) at PeakPeak 95℃95 ℃ 95℃-15min95 ℃ -15min 50℃50 ℃ 그룹ⅠGroup I 옥수수 전분(CS)Corn Starch (CS) 83.483.4 260260 245245 180180 370370 CS+쑥즙분말CS + mugwort powder 76.576.5 260260 215215 175175 320320 그룹ⅡGroup II 녹두 전분(MS)Mung bean starch (MS) 72.672.6 370370 320320 370370 790790 MS+쑥즙분말MS + mugwort powder 70.870.8 325325 300300 320320 585585 그룹ⅢGroup III 감자 전분(PS)Potato Starch (PS) 62.162.1 22802280 10701070 610610 800800 PS+쑥즙분말PS + Mugwort Powder 64.264.2 845845 805805 540540 770770

옥수수 전분의 아밀로그램에서 쑥즙분말의 첨가로 점도가 약간 감소하였으나 그 차이는 작았고, 녹두전분의 경우도 호화중 점도가 약간 낮아졌으며 특히 50℃에서의 점도가 쑥즙분말의 첨가로 790BU에서 585BU로 낮아졌다. 두 전분에서 쑥즙분말의 첨가로 호화개시온도가 낮아진 것은 쑥즙분말의 팽윤이 전분보다 먼저 일어나 점성을 나타냈기 때문이라 생각된다. 그러나 상기 표 2에서 보는 바와 같이 85℃에서의 쑥즙분말의 팽윤력은 전분과 비슷하기 때문에 호화시 점도에는 큰 영향을 끼치지 못하였다.In the amylogram of corn starch, the viscosity decreased slightly by the addition of mugwort powder, but the difference was small. The viscosity of mungbean starch was slightly lowered during gelatinization, especially the viscosity at 50 ℃ was increased from 790BU to 585BU. Lowered. The addition of mugwort powder in the two starches lowered the onset of gelatinization because the swelling of the mugwort powder occurred earlier than the starch, indicating viscosity. However, as shown in Table 2, because the swelling power of the mugwort powder at 85 ℃ is similar to the starch did not significantly affect the viscosity during gelatinization.

감자전분은 상기 두 전분과는 다른 양상을 보였다. 쑥즙분말의 첨가로 호화개시온도가 2.1℃ 높아졌으며 이는 쑥즙분말의 팽윤이 감자전분보다 늦게 일어나기 때문일 것이다. 호화중의 점도는 많이 낮아져 최고점도가 2,280BU에서 845BU로 크게 떨어졌으며 95℃에서의 점도도 1,070BU에서 805BU로 낮아졌다. 이것은 쑥즙분말의 첨가로 감자전분의 호화작업시 에너지 소비가 절감될 수 있음을 나타낸다. 최고점도가 떨어진 것은 쑥즙분말에 의해 감자전분의 팽윤과 붕괴가 억제된 결과로 보였다.Potato starch was different from the two starches. The addition of mugwort powder increased the initiation temperature of the delicacy by 2.1 ° C, probably because the swelling of the mugwort powder occurred later than the potato starch. Viscosity during gelatinization was much lower, so the peak viscosity dropped significantly from 2,280BU to 845BU and the viscosity at 95 ° C was also lowered from 1,070BU to 805BU. This indicates that the addition of mugwort powder can reduce energy consumption during the gelatinization of potato starch. The highest viscosity was seen as the result of suppressing swelling and collapse of potato starch by mugwort powder.

실시예 4. 묵의 제조 및 묵의 경도 측정Example 4. Preparation of Jelly and Hardness Measurement of Jelly

묵은 다음과 같이 제조하였다. 즉, 전분(10%)에 쑥즙분말 또는 쑥즙섬유(0.5%)를 각각 0.02% NaN3를 포함하는 물에 푼 후 쑥즙성분이 골고루 섞이게 하기 위해 실온에서 1시간 저어주었다. 다음 이를 끓는 수욕조에서 3-5분간 저어주어 진한 페이스트를 만들고 알루미늄 호일로 덮고 가열하여 전분을 호화시켰으며 총 가열시간은 30분이었다. 이 페이스트를 알루미늄 접시(직경 53.5mm, 높이 22.5mm)에 중앙의 높이가 접시보다 5mm 높게 담고 저장중 수분증발을 막기 위해 플라스틱 포장지로 두겹 덮었다. 위와 같이 만든 묵을 25℃와 4℃에서 저장하면서 1, 7일 후에 접시위의 여분의 묵을 cheese cutter나 칼로 잘라낸 다음 만능강도시험기(Tension universal testing machine, Model RTM-500, Orientec Co, Japan)로 경도를 측정하였으며, 측정조건은 Max. force: 10kgf, Head speed: 100mm/min, Chart speed: 200mm/min이었다. 사용된 probe는 묵의 5mm 깊이를 통과할 때 받는 힘을 경도로 하였다. 각 처리구마다 3 혹은 4 반복하여 평균값을 구하였다.Old was prepared as follows. That is, starch (10%) and mugwort powder or mugwort fiber (0.5%) in water containing 0.02% NaN 3 , respectively, and stirred for 1 hour at room temperature to mix the mugwort ingredients evenly. The mixture was then stirred in a boiling water bath for 3-5 minutes to make a thick paste, covered with aluminum foil and heated to gelatinize the starch. The total heating time was 30 minutes. The paste was placed in an aluminum dish (diameter 53.5 mm, height 22.5 mm) and centered 5 mm higher than the dish and covered with plastic wrapper to prevent evaporation during storage. After storing the jelly made as above at 25 ℃ and 4 ℃, cut the excess jelly on the plate with a cheese cutter or knife after 1 or 7 days, and then use a hardness universal testing machine (Model RTM-500, Orientec Co, Japan). The measurement conditions were Max. force: 10 kg f , Head speed: 100 mm / min, Chart speed: 200 mm / min. The probe used was the hardness of the force as it passed through the 5 mm depth of the jelly. The average value was calculated | required by repeating 3 or 4 for each treatment.

전분에 쑥즙분말 혹은 쑥즙섬유를 첨가하여 만든 묵을 25℃와 4℃에서 7일간 저장하면서 이들의 경도변화를 측정한 결과는 하기 표 4와 같다.The results of measuring the hardness change of the jelly made by adding mugwort powder or mugwort fiber to starch for 7 days at 25 ° C. and 4 ° C. are shown in Table 4 below.

0.5% 쑥즙을 혼합하여 만든 전분 묵(10%)의 경도 변화 측정Measurement of hardness change of starch jelly (10%) made by mixing 0.5% mugwort juice SampleSample Hardness(kgf) after storage ofHardness (kg f ) after storage of 25℃-1 day25 ℃ -1 day 25℃-7 days25 ℃ -7 days 4℃-1 day4 ℃ -1 day 4℃-7 days4 ℃ -7 days 그룹ⅠGroup I 옥수수 전분(CS)Corn Starch (CS) 0.22±0.015a 0.22 ± 0.015 a 0.22±0.017a 0.22 ± 0.017 a 0.24±0.021a 0.24 ± 0.021 a 0.50±0.061a 0.50 ± 0.061 a CS+쑥즙분말CS + mugwort powder 0.19±0.015a 0.19 ± 0.015 a 0.20±0.017 a 0.20 ± 0.017 a 0.28±0.015a 0.28 ± 0.015 a 0.57±0.067a 0.57 ± 0.067 a CS+쑥즙섬유CS + mugwort fiber 0.22±0.006a 0.22 ± 0.006 a 0.23±0.020a 0.23 ± 0.020 a 0.32±0.015b 0.32 ± 0.015 b 0.58±0.049a 0.58 ± 0.049 a 그룹ⅡGroup II 녹두 전분(MS)Mung bean starch (MS) 0.30±0.017a 0.30 ± 0.017 a 0.39±0.039b 0.39 ± 0.039 b 1.16±0.072c 1.16 ± 0.072 c 1.27±0.058a 1.27 ± 0.058 a MS+쑥즙분말MS + mugwort powder 0.27±0.026a 0.27 ± 0.026 a 0.35±0.043ab 0.35 ± 0.043 ab 0.94±0.125b 0.94 ± 0.125 b 1.22±0.072a 1.22 ± 0.072 a MS+쑥즙섬유MS + mugwort fiber 0.30±0.038a 0.30 ± 0.038 a 0.32±0.010a 0.32 ± 0.010 a 0.81±0.101a 0.81 ± 0.101 a 1.41±0.200a 1.41 ± 0.200 a 그룹ⅢGroup III 감자 전분(PS)Potato Starch (PS) 0.08±0.005a 0.08 ± 0.005 a 0.08±0.006a 0.08 ± 0.006 a 0.20±0.010a 0.20 ± 0.010 a 0.66±0.066b 0.66 ± 0.066 b PS+쑥즙분말PS + Mugwort Powder 0.08±0.021a 0.08 ± 0.021 a 0.08±0.010a 0.08 ± 0.010 a 0.19±0.023a 0.19 ± 0.023 a 0.51±0.032a 0.51 ± 0.032 a PS+쑥즙섬유PS + mugwort fiber 0.07±0.006a 0.07 ± 0.006 a 0.08±0.006a 0.08 ± 0.006 a 0.26±0.000b 0.26 ± 0.000 b 0.53±0.010a 0.53 ± 0.010 a 주:1)Average of three or four measurements±S.E.a,b,cMean in the same column not followed by the same letter are significantly different at p〈0.05 by LSD method.Note: 1) Average of three or four measurements ± SE a, b, c Mean in the same column not followed by the same letter are significantly different at p <0.05 by LSD method.

실험결과, 옥수수 전분의 경우 25℃ 저장에서는 저장기간에 따른 경도의 차이는 별로 없었으나 4℃저장에서는 변화가 커서 7일 저장의 경도가 1일 저장 보다 약 2배였다. 쑥즙첨가에 따른 경도변화는 4℃-1일 저장에서만 미약하게 나타났다. 녹두전분에서는 25℃에서 7일 저장한 것이 1일 저장한 것보다 약간 경도가 높았으며 4℃ 저장에서는 1일과 7일을 비교할 때 7일이 더 컸으나 그 증가폭은 옥수수보다 적었다. 녹두전분에서는 저장온도에 따라 경도가 많이 차이나 4℃ 저장의 경도는 25℃ 저장보다 3~4배정도 컸다. 쑥즙첨가에 따라 경도가 약간 낮아지는 현상이 25℃-7일, 4℃-1일 저장에서 나타났다. 감자전분은 세 전분중에서 가장 겔화가 느렸으며 25℃에서는 옥수수 전분과 같이 저장기간중 별 변화가 없었으나 4℃ 저장에서는 7일 저장할 때가 1일 저장했을때 보다 2~3배 정도 높은 경도를 나타냈다. 온도에 따라서는 4℃ 저장이 25℃ 저장보다 녹두 전분에서와 같이 훨씬 더 경도가 컸다. 쑥즙첨가에 따른 경도변화는 4℃-1일과 4℃-7일 저장에서 나타났으나 그 폭은 작았다. 전반적으로 어느 전분에서나 쑥즙의 첨가로 경도가 크게 변하지는 않았음을 알 수 있었다.As a result, the corn starch showed little difference in hardness according to storage period at 25 ℃ storage, but the hardness of 7 days storage was about twice as high as storage at 4 ℃ storage. The hardness change according to the addition of mugwort juice was weak only at 4 ℃ -1 days storage. In mungbean starch, storage for 7 days at 25 ° C was slightly harder than storage for 1 day, and storage at 4 ° C was 7 days larger than that for 1 day and 7 days, but the increase was less than that of corn. In mungbean starch, the hardness varies greatly depending on the storage temperature, but the hardness of 4 ℃ is about 3 ~ 4 times higher than that of 25 ℃. A slight decrease in hardness with mugwort juice was observed at 25 ° C-7 days and 4 ° C-1 days storage. Potato starch was the slowest gelling among the three starches. At 25 ℃, it showed no change during storage period like corn starch, but 7 days storage at 4 ℃ storage was 2 ~ 3 times higher than storage at 1 day. Depending on the temperature, the 4 ° C. storage was much harder as in mung bean starch than the 25 ° C. storage. Changes in hardness with mugwort juice were observed at 4 ℃ -1 days and 4 ℃ -7 days, but the width was small. Overall, the hardness did not change significantly with the addition of mugwort juice in any starch.

전분의 겔화는 초기에는 가열에 의해 물속으로 유출된 아밀로오스에 의해 좌우되고 그 후에는 전분립에 남아있는 아밀로펙틴에 의해 좌우된다고 한다. 특히 아밀로펙틴의 겔화는 저온일수록 촉진된다고 한다. 이런 점에서 볼 때 녹두전분의 경우 아밀로오스의 함량이 높아 호환중에 많이 추출된 아밀로오스가 겔의 경도를 좌우한 것으로 보인다. 그러나 옥수수 전분의 경우 추출된 아밀로오스의 양이 적어 겔의 경도에 그리 큰 영향을 미치지 못하였으며, 4℃ 저장중 경도가 크게 증가한 것은 전분립에 남아있는 상대적으로 많은 아밀로펙틴에 의한 것으로 해석할 수 있다. 감자전분의 겔화가 다른 전분보다 느린 것은 감자전분의 아밀로오스가 아밀로펙틴과 덜 분리되기 때문이거나 아밀로오스가 다른 전분에 비해 훨씬 크기 때문에 micelle 구조를 형성하기 어렵기 때문일 것이라고 하였다. 저온저장중 경도변화가 큰 이유는 옥수수 전분의 경우와 같다고 여겨진다.The gelation of starch is said to be initially dependent on amylose spilled into the water by heating and then on amylopectin remaining in the starch granules. In particular, gelation of amylopectin is promoted at lower temperatures. In view of this, the high content of amylose in mungbean starch is likely to affect the hardness of the gel extracted from a lot of amylose. However, in the case of corn starch, the amount of amylose extracted was small and did not significantly affect the hardness of the gel. The increase in hardness during storage at 4 ° C. could be interpreted as the relatively large amount of amylopectin remaining in the starch granules. The gelation of potato starch is slower than other starches, either because amylose in potato starch is less isolated from amylopectin or because it is more difficult to form micelle structures because amylose is much larger than other starches. The reason for the large change in hardness during cold storage is considered to be the same as that of corn starch.

실시예 5. 묵의 호화도 측정Example 5 Measurement of Gelatinization of Jelly

묵의 저장중 호화도 측정을 위한 시료는 경도측정 후 일부 묵을 건물로 약 1.5g 되게 취하고 이를 200mL의 무수에탄올에 넣고 blender로 고속에서 1분간 마쇄하여 탈수한 다음 G4 glass filter로 여과하고 잔유물을 에탄올로 씻고 아세톤으로 건조시켜 준비하였으며 호화도는 α-amylase-iodine방법으로 측정하였다.Samples for measuring the degree of gelatinization during the storage of jelly were taken after the hardness measurement, took about 1.5 g of some jelly into the building, put it in 200 mL of anhydrous ethanol, triturated for 1 minute at high speed with a blender, filtered through a G4 glass filter, and the residue was filtered off with ethanol. The mixture was washed with acetone and dried and prepared. The degree of gelatinization was measured by α-amylase-iodine method.

쑥즙첨가가 묵의 저장중 전분의 노화에 어떤 영향을 주는 가를 알기 위해 묵의 저장중 호화도 변화를 α-amylase 가수분해 정도로 측정하였으며 그 결과는 하기 표 5와 같다.In order to know how the mugwort addition affects the aging of starch during storage of jelly, the degree of gelatinization change during storage was measured as α-amylase hydrolysis degree. The results are shown in Table 5 below.

α-amylase-iodine 법으로 측정된 저장중 쑥즙을 첨가한 묵(10%)의 호화도1)의 변화정도Change in Gelatinization Degree 1) of Mugwort (10%) Added Mugwort During Storage Measured by α-amylase-iodine Method SampleSample DG(%) after storage ofDG (%) after storage of 0 day0 day 25℃-1 day25 ℃ -1 day 25℃-7 days25 ℃ -7 days 4℃-1 day4 ℃ -1 day 4℃-7 days4 ℃ -7 days 그룹ⅠGroup I 옥수수전분(CS)Corn Starch (CS) 89.7±0.00a 89.7 ± 0.00 a 73.0±0.14a 73.0 ± 0.14 a 72.0±0.07a 72.0 ± 0.07 a 73.0±0.50a 73.0 ± 0.50 a 74.8±1.13b 74.8 ± 1.13 b CS+쑥즙분말CS + mugwort powder 91.9±0.42b 91.9 ± 0.42 b 73.3±0.92a 73.3 ± 0.92 a 71.4±0.71a 71.4 ± 0.71 a 75.0±0.78b 75.0 ± 0.78 b 73.8±0.92b 73.8 ± 0.92 b CS+쑥즙섬유CS + mugwort fiber 91.8±0.35b 91.8 ± 0.35 b 72.4±0.28a 72.4 ± 0.28 a 72.6±0.57a 72.6 ± 0.57 a 71.6±0.00a 71.6 ± 0.00 a 70.1±0.07a 70.1 ± 0.07 a 그룹ⅡGroup II 녹두전분(MS)Mung bean starch (MS) 97.5±0.78b 97.5 ± 0.78 b 74.6±0.64b 74.6 ± 0.64 b 73.2±0.71a 73.2 ± 0.71 a 68.5±0.92b 68.5 ± 0.92 b 64.3±0.21c 64.3 ± 0.21 c MS+쑥즙분말MS + mugwort powder 95.5±0.00a 95.5 ± 0.00 a 71.3±0.57a 71.3 ± 0.57 a 70.4±1.91a 70.4 ± 1.91 a 62.8±0.50a 62.8 ± 0.50 a 60.7±0.21a 60.7 ± 0.21 a MS+쑥즙섬유MS + mugwort fiber 97.4±0.21b 97.4 ± 0.21 b 73.5±0.07b 73.5 ± 0.07 b 70.9±0.21a 70.9 ± 0.21 a 63.9±0.07a 63.9 ± 0.07 a 61.9±0.42b 61.9 ± 0.42 b 그룹ⅢGroup III 감자전분(PS)Potato Starch (PS) 99.3±0.00a 99.3 ± 0.00 a 85.9±0.00b 85.9 ± 0.00 b 83.4±0.28c 83.4 ± 0.28 c 78.3±0.28c 78.3 ± 0.28 c 73.4±0.00b 73.4 ± 0.00 b PS+쑥즙분말PS + Mugwort Powder 99.6±0.00 a 99.6 ± 0.00 a 82.8±0.57a 82.8 ± 0.57 a 79.6±0.15a 79.6 ± 0.15 a 74.9±0.14b 74.9 ± 0.14 b 68.8±0.71a 68.8 ± 0.71 a PS+쑥즙섬유PS + mugwort fiber 99.4±0.28a 99.4 ± 0.28 a 83.4±0.21a 83.4 ± 0.21 a 80.8±0.21b 80.8 ± 0.21 b 74.3±0.07a 74.3 ± 0.07 a 69.8±0.28a 69.8 ± 0.28 a 주:1)Average of two measurements±S.E.a-cMean in the same column not followed by the same letter are significantly different at p〈0.05 by LSD method.Note: 1) Average of two measurements ± SE ac Mean in the same column not followed by the same letter are significantly different at p 〈0.05 by LSD method.

실험결과, 전분은 가열에 의해 옥수수의 경우 90%내외 호화되었고 감자전분은 99% 이상이 호화되었으며 녹두전분은 95~97% 사이였다. 이는 아밀로그램의 결과에서 본 것과 같이 감자의 호화개시온도가 가장 낮고 그 다음 녹두, 옥수수 전분인 것과 일맥상통하는 결과이다. 특히 아밀로그래프에서 감자전분의 최고점도가 쑥즙분말의 첨가로 상당히 낮아져 호화도도 크게 떨어질 것으로 예상되었으나 그렇지는 않았다.As a result of the experiment, starch was gelatinized by heating about 90% of corn, potato starch was more than 99% gelatinized, and mung bean starch was 95 ~ 97%. This is in line with the lowest starting temperature of the potato, followed by green beans and corn starch, as seen in the amylogram results. In particular, the highest viscosity of potato starch in amylograph was considerably lowered by the addition of mugwort powder.

저장에 의해 호화도는 낮아졌으며 옥수수 전분에서는 저장온도나 저장시간에 따라 별차이가 없는데 반해, 녹두전분은 시간이 경과할수록 혹은 온도가 낮을수록 노화가 많이 됨을 알 수 있었다. 감자전분은 앞의 묵의 경도에서 본 것과 같이 전반적으로 노화가 느렸다. 특히 25℃에서 노화가 느려 25℃ 1일 경우 85.9%의 호화도를 보였으며 7일 경우는 83.4%의 호화도를 보였다. 그러나 감자전분도 녹두전분과 같이 시간이 경과할수록 그리고 온도가 낮을수록 노화가 많이 됨을 알 수 있었다. 쑥즙첨가가 옥수수 전분의 노화에는 별 영향을 끼치지 못하는 것으로 나타났으나, 녹두전분의 노화에는 약간 영향을 미치는 것으로 나타났다(0일, 25℃-1일, 4℃-1일, 4℃-7일). 감자전분에서는 쑥즙첨가로 노화가 위의 두 전분보다는 뚜렷하게 많이 일어나는 것으로 나타났으나(25℃-1일, 25℃-7일, 4℃-1일, 4℃-7일) 그폭은 그리 크지 않았다. 쑥즙첨가로 호화도가 부분적으로 낮아지는 현상은 쑥즙에는 섬유질 이외에도 다른 성분들이 많아 완벽하지는 않지만, 전분에 검물질을 첨가할 때 β-amylase에 의한 분해가 감소하며 이는 검물질이 용출된 아밀로오스와 결합하여 효소반응을 방해하기 때문이라는 Christianson등의 결과와 일치하였다.Gelatinization was lowered by storage and corn starch showed no difference according to storage temperature or storage time, whereas mungbean starch was more aging as time passed or at lower temperature. Potato starch was generally slow aging, as seen in the hardness of the jelly. In particular, aging was slow at 25 ℃, so that the degree of gelatinization was 85.9% at 25 ℃ 1 and 83.4% at 7, However, potato starch, like mungbean starch, was found to age more with time and with lower temperature. Mugwort addition did not appear to have any effect on the aging of corn starch, but it showed a slight effect on the aging of mung bean starch (day 0, day 25 ℃ -1, day 4 ℃ -1, day 4 ℃ -7). Work). In potato starch, mugwort was added more aging than the above two starches (25 ℃ -1 days, 25 ℃ -7 days, 4 ℃ -1 days, 4 ℃ -7 days), but the width was not so large. . Part of the deterioration of the degree of gelatinization due to the addition of mugwort juice is not perfect, because there are many other ingredients besides fiber in mugwort juice, but the degradation by β-amylase is reduced when the sample material is added to starch, which is combined with the eluted amylose. This is in agreement with Christianson et al.'S finding that it interferes with the enzyme reaction.

실시예 6. 묵의 냉동-해동시 안정도Example 6 Stability at Freezing and Thawing of Jelly

상기와 같이 제조된 묵을 밀폐가 가능한 플라스틱 용기(Nalgene, 미국)에 25g씩 담은 후 냉동고(-18℃)에 20시간 냉동, 25℃ 배양기에서 4시간 해동을 반복하면서 저장하였다. 일정한 반복 후 묵을 Buchner funnel 위의 여지에 올려놓고 묵에서 물이 더 이상 유출되지 않을 때까지 봉으로 눌러가면서 진공여과하여 분리되는 물의 양을 측정하였으며 각 처리구마다 3번 반복하여 평균값을 구하였다.The jelly prepared as described above was stored in a sealed plastic container (Nalgene, USA) for 25g, and stored in a freezer (-18 ° C) for 20 hours, and thawed in a 25 ° C incubator for 4 hours. After a certain repetition, the jelly was placed on the Buchner funnel, and the amount of water separated by vacuum filtration was measured by pressing with a rod until no more water flowed out of the jelly, and the average value was repeated three times for each treatment.

Hydrocolloid중에서 l-carrageenan과 locust bean gum, carboxymethyl-cell ulose는 냉동-해동 안정성을 향상시킨다. 본 발명에서도 수분유지능력이 높은 쑥즙을 전분에 첨가하면 냉동-해동 안정성이 높아질 것으로 예상했으나 별 효과가 나타나지 않았다. 그 결과는 하기 표 6과 같다.Among the hydrocolloids, l-carrageenan, locust bean gum, and carboxymethyl-cell ulose improve freeze-thaw stability. In the present invention, when the mugwort juice having high moisture retention ability was added to the starch, the freeze-thaw stability was expected to be increased, but there was no effect. The results are shown in Table 6 below.

쑥즙(0.5%)을 첨가한 전분(10%)묵의 냉동-해동시 안정도Freeze-thaw Stability of Starch (10%) Jelly Added with Mugwort Juice (0.5%) SampleSample Amount1)of water(g) separeted after cycles ofAmount 1) of water (g) separeted after cycles of 22 44 그룹ⅠGroup I 옥수수 전분(CS)Corn Starch (CS) 14.90±0.582a 14.90 ± 0.582 a 16.75±0.291a 16.75 ± 0.291 a CS+쑥즙분말CS + mugwort powder 14.86±0.712a 14.86 ± 0.712 a 16.36±0.323a 16.36 ± 0.323 a CS+쑥즙섬유CS + mugwort fiber 15.81±0.142a 15.81 ± 0.142 a 16.36±0.214a 16.36 ± 0.214 a 그룹ⅡGroup II 녹두 전분(MS)Mung bean starch (MS) 14.19±0.610a 14.19 ± 0.610 a 15.30±0.429a 15.30 ± 0.429 a MS+쑥즙분말MS + mugwort powder 15.27±0.704a 15.27 ± 0.704 a 15.70±0.442a 15.70 ± 0.442 a MS+쑥즙섬유MS + mugwort fiber 15.17±0.544a 15.17 ± 0.544 a 15.49±0.406a 15.49 ± 0.406 a 그룹ⅢGroup III 감자 전분(PS)Potato Starch (PS) 13.87±0.725a 13.87 ± 0.725 a 15.55±0.338ab 15.55 ± 0.338 ab PS+쑥즙분말PS + Mugwort Powder 15.53±1.275a 15.53 ± 1.275 a 16.42±0.060b 16.42 ± 0.060 b PS+쑥즙섬유PS + mugwort fiber 14.65±0.284a 14.65 ± 0.284 a 15.22±0.770a 15.22 ± 0.770 a 주:1)Average of three measurenents±S.E.a,bMean in the same column not followed by the same letter are significantly different at p〈0.05 by LSD method.Note: 1) Average of three measurenents ± SE a, b Mean in the same column not followed by the same letter are significantly different at p 〈0.05 by LSD method.

실험결과, 이것은 쑥즙의 첨가량이 작기 때문이거나 섬유질 이외의 다른 성분때문인 것으로 추정되었다.Experimental results suggest that this could be due to the small amount of wormwood added or other ingredients other than fiber.

이상 설명한 실시예와 실험예에서 입증되는 바와 같이 본 발명은 쑥에서 단단한 불용성 섬유질 성분을 제거하고 쑥의 수용성 섬유질을 함유하는 쑥즙섬유를 전분에 첨가하여 묵을 제조하면 묵의 호화도가 증대되고 강도가 향상되는 효과가 있으며, 쑥자체를 첨가할 때보다는 거친 불용성 섬유질이 제거되기 때문에 묵 표면이 매끈하게 되어 관능적 특성이 향상된 묵식품을 만들 수 있는 효과가 있다. 이밖에도 쑥즙분말을 첨가함으로써 점도가 낮아져 묵의 호화시 에너지 소비가 절감될 수 있는 효과가 있어 식품산업 및 에너지산업상 매우 유용한 발명인 것이다.As demonstrated in the above-described examples and experimental examples, the present invention removes hard insoluble fibrous components from mugwort and adds mugwort fibers containing water-soluble fiber of mugwort to starch to prepare the jelly. There is an effect that is improved, since the rough insoluble fiber is removed rather than when adding the mugwort itself, the surface of the jelly is smooth, there is an effect that can be made to improve the sensory properties. In addition, by adding the mugwort powder, the viscosity is lowered, so that the energy consumption can be reduced during gelatinization, which is a very useful invention for the food industry and the energy industry.

Claims (1)

전분과, 끓는 물에서 데친 쑥을 녹즙기로 짠 후 냉동건조한 쑥즙분말을 전분 가수분해효소와 단백질 분해효소를 처리한 후 95% 알코올로 침전시킨 침전물을 여과하고 그 잔유물을 아세톤으로 씻고 건조시킨 다음 건조물을 물에 푼 후 가열한 다음 냉동건조하여 제조되는 쑥즙섬유를 혼합하고 가열 호화시켜 제조되는 것을 특징으로 하는 쑥즙이 첨가된 묵.After squeezing the starch and mugwort boiled in boiling water with green juice, the freeze-dried mugwort juice was treated with starch hydrolase and protease, and the precipitate precipitated with 95% alcohol was filtered, and the residue was washed with acetone and dried. Mugwort added with water, characterized in that it is prepared by mixing and heating and gelatinizing the mugwort fibers produced by heating and then freeze-dried.
KR1019970061772A 1997-11-21 1997-11-21 Starch gel with mugwort juice KR100234619B1 (en)

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KR101638729B1 (en) * 2015-02-10 2016-07-11 전주대학교 산학협력단 Preparing Method for Jelly of Ledebouriella seseloides And Jelly of Ledebouriella seseloides Prepared Thereby

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KR20020094790A (en) * 2001-06-13 2002-12-18 (주)양지 Functional jelly and method of preparation thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101638729B1 (en) * 2015-02-10 2016-07-11 전주대학교 산학협력단 Preparing Method for Jelly of Ledebouriella seseloides And Jelly of Ledebouriella seseloides Prepared Thereby

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