KR100233311B1 - Cleansing composition - Google Patents
Cleansing composition Download PDFInfo
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- KR100233311B1 KR100233311B1 KR1019920016811A KR920016811A KR100233311B1 KR 100233311 B1 KR100233311 B1 KR 100233311B1 KR 1019920016811 A KR1019920016811 A KR 1019920016811A KR 920016811 A KR920016811 A KR 920016811A KR 100233311 B1 KR100233311 B1 KR 100233311B1
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- ammonium hydroxide
- liquid composition
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Abstract
본 발명은 알칼리 성분으로서 수산화 제4급암모늄염 예를 들면, 수산화테트라메틸암모늄, 수산화트리메틸(2-히드록시에틸)암모늄 등을 0.1~20중량% 사용함으로써 알칼리도가 높으면서도 계면활성제 등의 다른 성분을 균일하게 용해시키는 세정액 조성물에 관한 것으로서, 본 발명의 세정액은 종래에 비하여 우수한 용해성 및 세정성의 세정능력을 갖고 취급도 용이하다.The present invention uses 0.1 to 20% by weight of a quaternary ammonium hydroxide, for example, tetramethylammonium hydroxide, trimethyl (2-hydroxyethyl) ammonium hydroxide, or the like as an alkali component, so that other components such as surfactant may be used while the alkalinity is high. The cleaning liquid composition which dissolves uniformly, The cleaning liquid of this invention has the outstanding solubility and washability washing ability compared with the past, and is easy to handle.
Description
본 발명은 용해성, 세정성, 취급의 용이함등에 있어서 우수한 성능을 갖는 개량된 세정액 조성물에 관한 것이다.The present invention relates to an improved cleaning liquid composition having excellent performance in solubility, cleaning property, ease of handling and the like.
가정용 세정액, 자동 식기세척용 세정액, 자동차·열차용 세정액 등의 많은 세정액중에는 알칼리 성분이 함유되어 있다.Alkali component is contained in many washing | cleaning liquids, such as a household washing | cleaning liquid, the automatic dishwashing washing | cleaning liquid, and the cleaning liquid for automobiles and trains.
이러한 세정액중의 알칼리 성분의 작용으로는 유성물질의 유화작용이 있다.The action of the alkaline component in such a cleaning liquid is the emulsification of oily substances.
그래서, 천연 오물에 있는 유지중에는 유리 지방산이 30%함유되어 있고, 이 때문에 알칼리의 존재하에 검화되어 자연유화되어 피세척물로부터 제거된다. 따라서, 이 알칼리의 농도를 높이면 그 세정액의 유성물질에 대한 분해능력이 향상된다.Thus, the fats and oils contained in the natural dirt contain 30% of the free fatty acids, and thus are saponified in the presence of alkali, naturalized and removed from the cleansing object. Therefore, increasing the concentration of the alkali improves the decomposition ability of the cleaning liquid with respect to the oily substance.
그러나, 세정액은 그 알칼리 성분만으로 충분한 세정 능력을 갖는 것은 아니고 그외 다른 성분, 예를 들면 분산제, 킬레이트제, 소포제 등이 공존하여야 비로소 유효한 세정액이 될 수 있다.However, the cleaning liquid does not have sufficient cleaning ability only with its alkaline component, but can be an effective cleaning liquid only when other components such as a dispersant, a chelating agent, an antifoaming agent, etc. coexist.
그런데, 유지 분해능력을 높이기 위해 강알칼리인 NaOH나 KOH를 다량으로 사용하면, 그 강알칼리성 때문에 세정액중에 공존하는 분산제 등의 다른 성분이 충분히 균일하게 용해되지 못하고, 특히 분산제나 킬레이트제 등의 계면활성제의 용해도가 현저히 낮아져서, 실질적으로는 충분한 알칼리도를 갖는 세정액을 만드는 것은 곤란하다.However, when a large amount of NaOH or KOH, which is a strong alkali, is used in order to increase the oil-decomposable ability, other components such as a dispersant and the like that coexist in the washing solution cannot be sufficiently uniformly dissolved due to the strong alkalinity, and in particular, surfactants such as dispersants and chelating agents may Solubility is significantly lowered, making it difficult to prepare a cleaning liquid having substantially sufficient alkalinity.
그래서, 본 발명자들은 이러한 종래의 문제점을 해결하여 알칼리도가 높으면서도 충분히 계면활성제등의 다른 성분을 균일하게 용해시킨 세정액을 얻고자 예의 연구를 거듭한 결과, 놀랍게도 NaOH나 KOH등의 알칼리 성분의 일부 또는 전부를 대신하여 수산화 제4급암모늄을 사용하면, 알칼리도가 높으면서 계면활성제등의 다른 성분이 균일하게 용해된 세정액을 얻을 수 있음을 발견하고, 본 발명에 도달하였다.Therefore, the present inventors have intensively studied to solve such a conventional problem and obtain a cleaning solution in which other components such as surfactants are sufficiently dissolved evenly with high alkalinity. As a result, surprisingly, some of the alkaline components such as NaOH and KOH or When quaternary ammonium hydroxide was used instead of the whole, it discovered that the washing | cleaning liquid which the alkalinity was high and the other component, such as surfactant, was melt | dissolved uniformly was obtained, and reached this invention.
따라서, 본 발명의 목적은 종래의 세정액에 비하여 우수한 용해성, 세정성 등의 세정 능력을 갖고, 더욱이 취급의 용이성에 있어서도 우수한 세정액 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a cleaning liquid composition which has superior solubility, cleaning ability, and the like as compared with the conventional cleaning liquid, and also excellent in ease of handling.
즉, 본 발명은 알칼리 성분으로서 하기 일반식(1)로 표시되는 수산화 제4급 암모늄을 0.1중량%이상 함유하는 세정액 조성물에 관한 것이다.That is, this invention relates to the washing | cleaning liquid composition containing 0.1 weight% or more of quaternary ammonium hydroxide represented by following General formula (1) as an alkaline component.
[단, 식 중 R1, R2, R3및 R4는 탄소수 1~10의 알킬기, 알케닐기, -(CH2CH2O)m-H기(단, m은 1~10의 정수이다) 및 -(CH2CH2CH2O)n-H기(단, n은 1~10의 정수이다)로부터 선택된 1종의 치환기이며 서로 동일하거나 상이하다.][Wherein, R 1 , R 2 , R 3 and R 4 are an alkyl group having 1 to 10 carbon atoms, an alkenyl group, and a-(CH 2 CH 2 O) m -H group (where m is an integer of 1 to 10) ) And-(CH 2 CH 2 CH 2 O) n -H group (where n is an integer of 1 to 10) and is one substituent and the same or different from each other.]
이러한 수산화 제4급암모늄으로는, 구체적으로는, 수산화테트라메틸암모늄, 수산화테트라에틸암모늄, 수산화테트라프로필암모늄, 수산화테트라부틸암모늄, 수산화트리메틸에틸암모늄, 수산화디메틸디에틸암모늄, 수산화메틸트리에틸암모늄, 수산화트리메틸프로필암모늄, 수산화트리메틸부틸암모늄, 수산화트리메틸펜틸암모늄, 수산화트리메틸헥실암모늄, 수산화트리메틸(2-히드록시에틸)암모늄, 수산화트리메틸(3-히드록시프로필)암모늄, 수산화디메틸디(2-히드록시에틸)암모늄, 수산화디메틸디(3-히드록시프로필)암모늄, 수산화메틸트리(2-히드록시에틸)암모늄, 수산화메틸트리(3-히드록시프로필)암모늄, 수산화트리에틸(2-히드록시에틸)암모늄, 수산화트리에틸(3-히드록시프로필)암모늄, 수산화디에틸디(2-히드록시에틸)암모늄, 수산화디에틸디(3-히드록시프로필)암모늄, 수산화에틸트리(2-히드록시에틸)암모늄, 수산화에틸트리(3-히드록시로필)암모늄, 수산화테트라(2-히드록시에틸)암모늄, 수산화테트라(3-히드록시프로필)암모늄, 수산화트리메틸(히드로시에톡시에틸)암모늄, 수산화트리메틸(히드록시프로폭시프로필)암모늄 등이 있다. 이들 수산화 제4급암모늄은 단독으로 사용할 수도 있고, 또 2종류 이상의 것을 혼합하여 사용할 수 있다.Specific examples of such quaternary ammonium hydroxide include tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, trimethylethylammonium hydroxide, dimethyldiethylammonium hydroxide, methyltriethylammonium hydroxide, Trimethylpropyl ammonium hydroxide, trimethylbutylammonium hydroxide, trimethylpentylammonium hydroxide, trimethylhexyl ammonium hydroxide, trimethyl (2-hydroxyethyl) ammonium hydroxide, trimethyl (3-hydroxypropyl) ammonium hydroxide, dimethyldi (2-hydroxy hydroxide Ethyl) ammonium, dimethyldi (3-hydroxypropyl) ammonium, methyltri (2-hydroxyethyl) ammonium hydroxide, methyltri (3-hydroxypropyl) ammonium hydroxide, triethyl hydroxide (2-hydroxyethyl) Ammonium, triethyl (3-hydroxypropyl) ammonium, diethyldi (2-hydroxyethyl) ammonium hydroxide, diethyldi (3) -Hydroxypropyl) ammonium, ethyl tri (2-hydroxyethyl) ammonium, ethyl tri (3-hydroxyrophyl) ammonium hydroxide, tetra (2-hydroxyethyl) ammonium hydroxide, tetrahydroxy (3-hydroxy) Propyl) ammonium, trimethyl (hydroethoxyethyl) ammonium, trimethyl (hydroxypropoxypropyl) ammonium hydroxide, and the like. These quaternary ammonium hydroxides may be used alone or in combination of two or more kinds thereof.
이들 중, 바람직한 것은 수산화테트라메틸암모늄, 수산화테트라에틸암모늄 및 수산화트리메틸(2-히드록시에틸)암모늄이고, 특히 바람직한 것은 그것 자체가 천연에 존재하는 화합물로서 미생물등에 의해 용이하게 분해되어 공해의 염려가 없는점 등, 폐액 처리등의 관점에서 볼 때 수산화트리메틸(2-히드록시에틸)암모늄(통칭 코린)이다.Of these, preferred are tetramethylammonium hydroxide, tetraethylammonium hydroxide and trimethyl (2-hydroxyethyl) ammonium hydroxide, and particularly preferred is a compound which is naturally present in nature and is easily decomposed by microorganisms and the like, so that there is a risk of pollution. It is trimethyl (2-hydroxyethyl) ammonium (common name corinth) from a viewpoint of waste liquid disposal etc., etc.
이들 수산화 제4급암모늄의 첨가량에 관해서는 특별한 제한은 없지만 적은 양으로는 효과가 없고 또한 지나치게 많아도 비경제적이고, 저절로 결석으로서 석출되기 쉬우므로, 바람직하게는 0.1~20중량%, 보다 바람직하게는 0.2~10중량%이다.The addition amount of these quaternary ammonium hydroxides is not particularly limited, but it is ineffective in a small amount and is too economical even if it is too large, and easily precipitates as stones, so it is preferably 0.1 to 20% by weight, more preferably 0.2 10 wt%.
본 발명의 세정액 조성물에는 상기 알칼리성분으로서의 수산화 제4급암모늄 이외에도 다음의 첨가제를 첨가할 수 있다.The following additives can be added to the cleaning liquid composition of the present invention in addition to the quaternary ammonium hydroxide as the alkali component.
상기 알칼리 성분으로서의 수산화 제4급암모늄 이외에, 알칼리성분으로서 수산화나트륨, 수산화칼륨, 탄산나트륨, 탄산칼륨 등의 무기 알칼리나, 에탄올아민 등의 유기 알칼리를 첨가할 수 있다. 특히, 강알칼리인 수산화나트륨이나 수산화칼륨의 사용은 그 세정력을 높이기 때문에 바람직한데, 바람직하기로는 1~5중량%의 범위로 사용된다.In addition to the quaternary ammonium hydroxide as the alkali component, inorganic alkalis such as sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate and organic alkalis such as ethanolamine can be added as the alkali component. In particular, the use of strong alkali sodium hydroxide or potassium hydroxide is preferable because of its high cleaning power, and is preferably used in the range of 1 to 5% by weight.
또한, 세정액 조성물에는 유류(油類), 고체오물의 유화, 분산작용을 촉진하거나 혹은 기포작을 위해서 계면활성제를 첨가할 수 있다. 이런 계면활성제로는 예를 들면 올레산나트륨, 라우린산나트륨, 스테아르산나트륨 등의 비누 성분이나 라우릴황산나트륨, 세틸황산나트륨 등의 음이온계 계면활성제를 들 수 있다. 또한 폴리에틸렌글리콜 등의 비이온계 계면활성제도 유효하다.In addition, a surfactant may be added to the cleaning liquid composition to promote the emulsification and dispersion of oil, solid soils, or bubbles. Examples of such surfactants include soap components such as sodium oleate, sodium laurate and sodium stearate, and anionic surfactants such as sodium lauryl sulfate and sodium cetyl sulfate. Nonionic surfactants such as polyethylene glycol are also effective.
또, 세정액 조성물 중에는 금속이온 봉쇄작용, 고체의 분산작용, cmc 저하작용 혹은 오물의 검화, 중화작용 등을 목적으로 킬레이트제를 첨가할 수도 있다.In addition, a chelating agent may be added to the cleaning liquid composition for the purpose of blocking metal ions, dispersing solids, reducing cmc or saponifying dirt, neutralizing, and the like.
이런 킬레이트제로는 트리폴리인산나트륨, 피로인산나트륨, 구연산나트륨, 메타규산나트륨, EDTA, 폴리아크릴산나트륨 등을 들 수 있다.Such chelating agents include sodium tripolyphosphate, sodium pyrophosphate, sodium citrate, sodium metasilicate, EDTA, sodium polyacrylate, and the like.
한편, 상기한 각종 첨가제를 쉽게 용해시키기 위해 혹은 균일하게 현탁시키기 위해서 소량의 유기용제를 첨가하는 것도 유효하다. 이 목적으로 사용하는 유기용제로서는, 물과 균일하게 용해 혹은 현탁되는 수성 유기용제가 바람직하고, 예를들면 에탄올, 이소프로판올 등의 알콜류, 부틸셀로솔브, 부틸카르비톨 등의 글리콜 에테르류를 들 수 있다.On the other hand, it is also effective to add a small amount of an organic solvent in order to easily dissolve the above-mentioned various additives or to suspend uniformly. As the organic solvent used for this purpose, an aqueous organic solvent uniformly dissolved or suspended with water is preferable. Examples thereof include alcohols such as ethanol and isopropanol, and glycol ethers such as butyl cellosolve and butyl carbitol. have.
본 발명에 있어서 알칼리 성분으로 사용되는 수산화 제4급암모늄은 강알칼리로서 각종의 오물 성분에 대해 우수한 세정력으로 발휘하며, 이것은 유기알칼리이기 때문에 유기물인 오물 성분에 대해 우수한 용해성을 발휘하고 또 유기성의 각종 첨가제의 용해도도 향상시켜 이것들이 서로 상호작용하여 세정력을 향상시키는 것이다.The quaternary ammonium hydroxide used as the alkaline component in the present invention is a strong alkali and exhibits excellent cleaning power against various dirt components. Since it is an organic alkali, it exhibits excellent solubility with respect to organic dirt components and various organic additives. It also improves the solubility of these so that they can interact with each other to improve the cleaning power.
이하 실시예 및 비교예에 의해 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples.
[실시예 1~19 및 비교예 1~2][Examples 1-19 and Comparative Examples 1-2]
메타규산나트륨(MSN), 수산화칼륨(KHY), 피로인산칼륨(KPP), 탄산칼륨(KCA), EDTA, 폴리아크릴산나트륨(NPA), 글루콘산 50%(GA5), 글루콘산나트륨(GAN), 올레산(OLA), 구연산나트륨(NCI), 라우릴황산나트륨(NLA), 알킬에테르황산에스테르나트륨(AESE), 에탄올(EAL), 이소프로필알콜(IPA), 트리에탄올아민(TRA), TMAH 15%액(TMAH), 코린 15%액(코린) 및 [(CN3)2N(CH2CH2OH)2]+OH-(DMEH)를 표 1에 표시한 분량(중량%)으로 물에 용해 또는 분산시켜 세정액 조성물을 조제하고, 얻어진 각 실시예 및 비교예의 세정액 조성물에 관해 아래의 방법에 따라 각 세정성능을 평가하였다. 결과를 표 1에 나타내었다.Sodium metasilicate (MSN), potassium hydroxide (KHY), potassium pyrophosphate (KPP), potassium carbonate (KCA), EDTA, sodium polyacrylate (NPA), gluconic acid 50% (GA5), sodium gluconate (GAN), Oleic acid (OLA), sodium citrate (NCI), sodium lauryl sulfate (NLA), sodium alkyl ether sulfate (AESE), ethanol (EAL), isopropyl alcohol (IPA), triethanolamine (TRA), TMAH 15% liquid ( TMAH), choline 15% solution (choline) and [(CN 3) 2 N ( CH 2 CH 2 OH) 2] + OH - ( dissolved or dispersed in water to DMEH) in one portion (% by weight) shown in Table 1 The cleaning solution composition was prepared, and the cleaning performance was evaluated according to the following method with respect to the cleaning solution compositions of the obtained Examples and Comparative Examples. The results are shown in Table 1.
[세정성능의 평가][Evaluation of Cleaning Performance]
옥수수 전분 3.5중량%, 소백분 8.3중량%, 상신(上新)분말 8.3중량%, 밀크 8.3중량%, 난황 8.3중량% 및 수돗물 55.0중량%의 혼합액중에 피너츠 버터 4.1중량%, 라아드 2.1중량% 및 버터 2.1중량%의 혼합물을 첨가하고, 믹서로 혼합하여 균일하게 유화시켜 오물액을 조제한다.Peanut butter 4.1% by weight, Laard 2.1% by weight in a mixture of 3.5% by weight of corn starch, 8.3% by weight of white milk powder, 8.3% by weight of fresh fruit powder, 8.3% by weight of milk, 8.3% by weight of egg yolk and 55.0% by weight of tap water. And 2.1% by weight of a butter is added, and mixed with a mixer to emulsify uniformly to prepare a dirt solution.
이어서, 이 오물액 1g을 직경 10㎝의 크기를 갖는 도기제품의 백색팬(pan)에 놓고 전체를 80℃의 건조기 중에서 1시간 동안 건조시켜 시험용의 오물이 묻은 팬으로 사용하였다.Subsequently, 1 g of this filth liquid was placed in a white pan of a pottery product having a diameter of 10 cm, and the whole was dried for 1 hour in a dryer at 80 ° C. to be used as a test filth pan.
상기 실시예 및 비교예에서 제조한 각 세정액 조성물을 물로 100배로 희석하여 세정용 희석액을 제조하고, 이 세정용 희석액 500㎖를 덮개 있는 폴리용기에 넣고, 이것을 30℃의 항온조에 약 10분간 방치하여 30℃로 조정한 후, 준비한 시험용의 오물이 묻은 팬을 넣고, 약 80회/분의 속도로 5분간 진탕하고, 그후 수돗물로 동일하게 5분간 진탕하여 세정용 희석액을 씻어낸 다음 건조시키는 세정 시험을 행하였다.Each washing liquid composition prepared in Examples and Comparative Examples was diluted 100 times with water to prepare a washing diluent, and 500 ml of this washing diluent was placed in a covered poly container, which was left in a 30 ° C thermostat for about 10 minutes. After adjusting to 30 ° C., put the prepared test stain-filled pan, shake for 5 minutes at a rate of about 80 times / minute, and then shake the same for 5 minutes with tap water to wash the diluted solution for washing, and then dry it. Was performed.
이렇게 세정한 후, 팬의 위쪽에 약 2배로 희석된 요오드 팅크를 불어넣고, 잔류한 전분질을 착색시켜 잔류한 오물성분의 양을 관찰하고, 잔류된 오물의 정도를 눈으로 관찰하여 오물이 완전히 제거된 것 : 5로부터 전혀 제거되지 않은 것 : 1까지의 간격으로 판정하여 5단계로 평가하였다.After this cleaning, blow about twice the diluted iodine tincture on the upper part of the pan, color the remaining starch to observe the amount of remaining dirt, and observe the amount of dirt remaining. What was removed: What was not removed at all: was evaluated at intervals of up to 1 and evaluated in 5 steps.
[표 1]TABLE 1
본 발명의 세정액 조성물에 의하면, 알칼리성분으로서 유기 강알칼리인 수산화 제4급암모늄을 첨가함으로써 종래에 없던 우수한 세정효과를 발휘할 수 있다.According to the washing | cleaning liquid composition of this invention, when the quaternary ammonium hydroxide which is organic strong alkali is added as an alkali component, the outstanding washing | cleaning effect which has not existed conventionally can be exhibited.
Claims (3)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3262506A JPH0570797A (en) | 1991-09-17 | 1991-09-17 | Detergent composition |
| JP1991-262506 | 1991-09-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR930006146A KR930006146A (en) | 1993-04-20 |
| KR100233311B1 true KR100233311B1 (en) | 1999-12-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920016811A KR100233311B1 (en) | 1991-09-17 | 1992-09-16 | Cleansing composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH0570797A (en) |
| KR (1) | KR100233311B1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3437860B2 (en) * | 1993-10-15 | 2003-08-18 | ライオン株式会社 | How to wash clothing |
| JPH07305093A (en) * | 1994-05-11 | 1995-11-21 | Dai Ichi Kogyo Seiyaku Co Ltd | Cleaning agent composition |
| DE102005008939A1 (en) * | 2005-02-26 | 2006-09-21 | Sms Demag Ag | Method and device for reeling a metal strip |
| WO2010019722A2 (en) * | 2008-08-13 | 2010-02-18 | Intermolecular, Inc. | Combinatorial approach to the development of cleaning formulations for glue removal in semiconductor applications |
| JP7232958B1 (en) * | 2022-08-25 | 2023-03-03 | Ｈｉｔｏｗａライフパートナー株式会社 | Undiluted cleaning solution for air conditioners, cleaning solution and cleaning method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6021500A (en) * | 1983-07-15 | 1985-02-02 | 三井東圧化学株式会社 | Device for melting and treating granular body |
-
1991
- 1991-09-17 JP JP3262506A patent/JPH0570797A/en active Pending
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1992
- 1992-09-16 KR KR1019920016811A patent/KR100233311B1/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6021500A (en) * | 1983-07-15 | 1985-02-02 | 三井東圧化学株式会社 | Device for melting and treating granular body |
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| Publication number | Publication date |
|---|---|
| JPH0570797A (en) | 1993-03-23 |
| KR930006146A (en) | 1993-04-20 |
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