KR0179236B1 - Humidifier Detergent Composition Using Natural Extracts - Google Patents
Humidifier Detergent Composition Using Natural Extracts Download PDFInfo
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- KR0179236B1 KR0179236B1 KR1019960039682A KR19960039682A KR0179236B1 KR 0179236 B1 KR0179236 B1 KR 0179236B1 KR 1019960039682 A KR1019960039682 A KR 1019960039682A KR 19960039682 A KR19960039682 A KR 19960039682A KR 0179236 B1 KR0179236 B1 KR 0179236B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F6/00—Air-humidification, e.g. cooling by humidification
Abstract
본 발명은 가습기내의 세균, 곰팡이, 효모 등의 성장을 억제하기 위해 천연항균물질인 자몽추출물을 함유시킨 가습기세정제 조성물에 관한 것이다.The present invention relates to a humidifier cleaner composition containing grapefruit extract which is a natural antibacterial substance in order to inhibit the growth of bacteria, fungi, yeast and the like in the humidifier.
Description
[발명의 명칭][Name of invention]
천연 추출물을 이용한 가습기 세정제 조성물Humidifier Detergent Composition Using Natural Extracts
[발명의 상세한 설명]Detailed description of the invention
[발명의 목적][Purpose of invention]
본 발명은 천연추출물을 이용한 가습기 세정제 조성물에 관한 것으로, 더욱 구체적으로는 가습기 내의 세균(bacteria), 곰팡이(fungi), 효모(yeast) 등의 성장을 억제하기 위해 천연 항균 물질인 자몽 추출물을 함유시킨 가습기 세정제 조성물에 관한 것이다.The present invention relates to a humidifier cleaning composition using a natural extract, and more particularly, to contain a grapefruit extract, which is a natural antibacterial substance, to inhibit the growth of bacteria, fungi, yeast, etc. in the humidifier. A humidifier cleaner composition.
[발명이 속하는 기술분야 및 그 분야의 종래 기술]TECHNICAL FIELD OF THE INVENTION
가습기는 내부 공간에 항상 물이 고여 있어 물 속에 존재하는 세균등이 번식하기 쉬우며 이로 인하여 가습기 분무시 실내 공기가 오염될 소지가 있다. 또한 세균이나 곰팡이는 가습기 내부 벽면에 붙어 물때의 생성을 촉진시키기도 한다. 종래의 가습기 세정제는 미생물 억제를 위하여 농원예용 또는 의약품용 살균제를 이용하여 만든 제품이 대부분이다(참조 : 대한민국 특허 공고 번호 96-5160호). 이 경우에는 장시간 실내에서 사용, 흡입시 인체에 해를 끼칠 잠재적인 위험성을 가지고 있다.Humidifiers always have water in their interior spaces, making it easy to breed bacteria in the water, which can contaminate indoor air when the humidifier is sprayed. Bacteria or fungi can also stick to the internal walls of the humidifier to promote the generation of scale. Conventional humidifier cleaners are mostly products made using agricultural or horticultural or pharmaceutical fungicides to suppress microorganisms (see Korean Patent Publication No. 96-5160). In this case, there is a potential risk of harming the human body if used and inhaled indoors for a long time.
[발명이 이루고자 하는 기술적 과제][Technical problem to be achieved]
본 발명은 상기와 같은 종래의 가습기 세정제의 단점들을 해결하기 위한 것으로, 천연식품 첨가물로 쓰이는 자몽 추출물을 사용하여 가습기내의 세균, 곰팡이, 효모 등에 대한 항균효과도 우수하고 보다 인체에 안전한 가습기 세정제 조성물을 제공하는 것이다.The present invention is to solve the disadvantages of the conventional humidifier cleaner as described above, using a grapefruit extract used as a natural food additive, excellent antibacterial effect against bacteria, fungi, yeast, etc. in the humidifier and safer human body humidifier composition To provide.
[발명의 구성 및 작용][Configuration and Function of Invention]
즉, 본 발명은 자몽 추출물을 0.01 내지 10중량% 함유하는 가습기 세정제 조성물에 관한 것이다.That is, the present invention relates to a humidifier cleaner composition containing 0.01 to 10% by weight of grapefruit extract.
본 발명에 쓰인 자몽 추출물은 자몽(그레이프 후르츠) 종자 추출물로 천연 아스코르빈산, 니린진 및 토코페롤을 함유하고 있고, 세균, 곰팡이, 바이러스 등의 부패성 및 병원성 세균에 대해 뛰어난 살균 및 항균 효과를 가지고 있어 천연 식품 보존제로 사용되고 있다(참조 : 미합중국특허 1946호, 미국 식품 의약국 인가 번호 R-0013982).The grapefruit extract used in the present invention is a grapefruit (grapefruit) seed extract containing natural ascorbic acid, niringin and tocopherol, and has excellent bactericidal and antibacterial effects against decaying and pathogenic bacteria such as bacteria, fungi and viruses. It is used as a natural food preservative (see US Patent 1946, US Food and Drug Administration authorization number R-0013982).
이 중 아스코르빈산은 금속 이온의 환원제로서 하이드록시 라디칼을 생성시켜 세포막에 분포되어 있는 효소 활성을 저해시키고 세포 호흡 작용을 억제하여 미생물의 살균작용을 하는 것으로 알려져 있다. 아스코르빈산의 화학구조식은 다음 식 (1)과 같다.Among these, ascorbic acid is known to act as a reducing agent for metal ions, to generate hydroxy radicals, to inhibit enzymatic activity distributed in cell membranes, and to inhibit cellular respiration, thereby killing microorganisms. The chemical structural formula of ascorbic acid is shown in the following formula (1).
니린진은 후라보노이드의 일종으로 항 미생물 효과를 나타내는 주 성분이며 그의 화학구조식은 다음 식(2)와 같다. 니린진은 세균의 세포 호흡 작용을 억제하여 세균의 증식을 억제하며 아스코르빈산의 작용을 상승시키는 효과도 있다.Niringin is a flavonoid, a major component that has antimicrobial effects, and its chemical structure is represented by the following equation (2). Niringin inhibits the cellular respiration of bacteria, inhibits the growth of bacteria and increases the action of ascorbic acid.
자몽 추출물은 이 외에도 다량의 토코페롤을 함유하여 방취력이 있어 악취 및 부패취 제거에도 우수한 효과가 있다(참조 : 한국수산학회지, Vol. 23, No. 4, 1990).In addition, grapefruit extract contains a large amount of tocopherol and has an excellent deodorizing ability to remove odors and decaying odors (see Korean Fisheries Society, Vol. 23, No. 4, 1990).
본 발명에 따른 가습기 세정제 조성물은 자몽 추출물 이외에 금속 이온 봉집제, 용해도가 우수한 알코올계 용매 및 물, 천연 추출향을 함유한다.The humidifier cleaner composition according to the present invention contains a metal ion encapsulant, an alcohol-based solvent and water having excellent solubility, and natural extracting flavor in addition to the grapefruit extract.
가습기내 세균 및 곰팡이 생성을 방지하기 위해 사용하는 자몽 추출물은 0.01 내지 10중량% 사용하는 것이 바람직하다. 자몽 추출물을 0.01중량% 이하 사용하면 충분한 항균 효과를 기대할 수 없으며, 10중량% 이상 사용할 때에는 용액이 탁도를 띄어 제품의 상태에 영향을 주므로 바람직하지 않다. 용매로는 탄소수 2-10개 및 수산화기를 3개 이하 갖는 알코올류, 또는 물, 또는 알코올류와 물과의 혼합물이 적당하다.Grapefruit extract used to prevent the formation of bacteria and mold in the humidifier is preferably used 0.01 to 10% by weight. If the grapefruit extract is used in less than 0.01% by weight can not be expected sufficient antibacterial effect, when used in more than 10% by weight is not preferable because the solution has turbidity affecting the state of the product. As the solvent, alcohols having 2 to 10 carbon atoms and 3 or less hydroxyl groups, or water, or a mixture of alcohols and water are suitable.
상기 항균 성분의 효과를 보조하고 가습기내 물때 방지를 위해서 금속 이온봉집제를 사용한다. 금속이온봉집제로는 에틸렌 디아민 테트라 아세트산의 나트륨염 또는 구연산 또는 구연산의 나트륨 염을 단독으로 또는 혼합하여 사용할 수 있다. 금속이온봉집제의 사용량은 0.01 내지 10중량%가 바람직하다. 0.01중량% 이하 사용하면 물 때 방지 효과가 미약하며, 10중량% 이상 사용할 때에는 가습기 사용할 때 침전이 형성되어 좋지 않다.To aid the effect of the antimicrobial component and to prevent the scale in the humidifier is used a metal ion sealant. As a metal ion sealant, the sodium salt of ethylene diamine tetra acetic acid or the sodium salt of citric acid or citric acid can be used individually or in mixture. As for the usage-amount of a metal ion sealing agent, 0.01 to 10 weight% is preferable. When the amount is less than 0.01% by weight, the effect of preventing water is weak, and when it is used by more than 10% by weight, precipitation is not good when the humidifier is used.
또한 본 발명의 가습기세정제 조성물은 방향 효과와 살균 효과를 부여할 목적으로 솔향, 쑥향 등 천연 추출물을 2.0중량% 이하 사용한다.In addition, the humidifier cleaner composition of the present invention uses a natural extract of 2.0% by weight or less, such as scent, wormwood fragrance for the purpose of providing aroma effect and bactericidal effect.
이하, 본 발명을 실시예에 의거하여 상세히 설명하지만 본 발명의 기술적 범위가 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples, but the technical scope of the present invention is not limited thereto.
[실시예 및 비교예][Examples and Comparative Examples]
다음 표 1 및 표 2에 나타낸 성분을 주 성분으로하여 실시예 1-6의 가습기 세정제 조성물 및 비교예 1-4의 가습기 세정제 조성물을 제조하였다.The humidifier cleaner composition of Example 1-6 and the humidifier cleaner composition of Comparative Example 1-4 were prepared using the component shown in following Table 1 and Table 2 as a main component.
[실험예 1. 미생물 항균력 검사]Experimental Example 1. Microbial Antimicrobial Activity Test
자몽 추출물의 항균력을 확인하기 위해 대표적인 세균과 효모 및 곰팡이, 즉 에스케리키아 콜리(Escherichia coli, 대장균), 스타필로코쿠스 아우레우스(Staphlyococcus aureus, 포도상구균), 슈도모나스 아우레지노사(Pseudomonas aureginosa, 녹농균), 칸디다 알비칸스(Candida albicans), 아스페르지루스 나이저(Aspergillus niger, 흑국균)에 대해 미생물 증식 정도를 측정하였다.To check the antimicrobial activity of grapefruit extract, representative bacteria, yeasts and fungi, namely Escherichia coli, Staphlyococcus aureus, Pseudomonas aureginosa, Pseudomonas aeruginosa), Candida albicans (Candida albicans), Aspergillus niger (Aspergillus niger, the degree of microbial growth was measured.
1) 실험 시료1) Experimental sample
o 자몽추출물o grapefruit extract
o 시험균주o Test strain
2) 실험 방법2) Experiment Method
실험시료를 뉴트리언트 브로쓰(Nutrient Broth)에 차례로 희석하고 일정량의 전배양한 시험균(10 CFU/㎖)을 접종한 후 37℃에서 24시간 진탕 배양하여 미생물 증식 정도를 관찰하였다. 효모는 포테이토 덱스트로스 브로쓰(Potato Dextrose Broth)에 접종하고 (10 CFU/㎖) 30℃에서 72시간 배양하였고, 곰팡이는 포테이토 덱스트로스 아가(Potato Dextrose Agar)에 도말하여 (10 CFU/㎖) 25℃에서 5일간 배양하였다.The test sample was diluted sequentially in Nutrient Broth and a certain amount of pre-cultured test bacteria (10 CFU / mL) was inoculated and shaken at 37 ° C. for 24 hours to observe the degree of microbial growth. Yeast is inoculated into Potato Dextrose Broth (10 CFU / ml) was incubated at 30 ° C. for 72 hours, and the mold was plated on Potato Dextrose Agar (10 CFU / ml) was incubated at 25 ° C. for 5 days.
그 실험 결과는 표 3에 나타내었다.The experimental results are shown in Table 3.
육안 판별기준 +++ : 미생물이 많이 번식함.Visual discrimination criteria +++: Microorganisms multiply.
+ : 미생물이 약간 번식함.+: Microorganisms reproduce slightly.
- : 미생물이 번식하지 않음.-: Microorganisms do not breed.
상기 표 3으로부터 자몽 추출물은 일반 세균의 경우 50ppm 이하, 효모의 경우 100ppm 이하, 곰팡이의 경우 250 ppm 이하에서 우수한 항균 효과가 있음을 알 수 있다.It can be seen from the Table 3 that grapefruit extract has an excellent antimicrobial effect at 50 ppm or less in the case of general bacteria, 100 ppm or less in the yeast, and 250 ppm or less in the fungus.
[실험예 2. 항균력 비교 실험]Experimental Example 2. Antimicrobial Activity Comparison Experiment
실시예 1, 2, 3 및 5의 세정제조성물 및 비교예 1-2의 세정제조성물을 사용하여 물 속에서 생성될 수 있는 세균에 대한 항균력을 다음과 같이 실험하였다.Using the cleaning composition of Examples 1, 2, 3 and 5 and the cleaning composition of Comparative Examples 1-2, the antimicrobial activity against bacteria that can be produced in water was tested as follows.
1) 실험시료1) Experimental sample
보통의 수돗물 에 시판 설탕을 0.1% 넣은 것을 공시료로 하고 공시료에 가습기 세정제를 넣은 것을 시료로 사용한다.A sample containing 0.1% of commercial sugar in ordinary tap water is used as a sample, and a sample containing a humidifier cleaner is used as a sample.
2) 실험방법2) Experiment Method
투명한 250mL PET 용기에 설탕 0.1%의 수도물 150㎖를 넣고 가습기 세정제를 10㎖ 넣는다. 잘 흔들어 섞고 바람이 잘 통하는 양지에 방치한다. 1주일 간격으로 관찰하여 미생물 생성 여부를 육안 판별한다. 그 실험 결과를 표 4에 나타내었다.150 ml of 0.1% sugar and 10 ml of humidifier cleaner were added to a transparent 250 ml PET container. Shake well and leave in a sunny place. Observe at weekly intervals to visually determine whether microorganisms are produced. The experimental results are shown in Table 4.
육안 판별기준 +++ : 미생물이 많이 번식함.Visual discrimination criteria +++: Microorganisms multiply.
+ : 미생물이 약간 번식함.+: Microorganisms reproduce slightly.
- : 미생물이 번식하지 않음.-: Microorganisms do not breed.
상기와 같은 방법으로 수도물에서 생길 수 있는 세균에 대한 항균 효과를 알아본 결과 자몽 추출물을 0.1% 이상 포함하는 가습기 세정제의 경우 1개월이 경과하여도 미생물이 번식하지 않는 것으로 나타나 통상적인 가습기 세정제와 동등한 항균력이 있음을 알 수 있었다.As a result of examining the antimicrobial effect on the bacteria that may occur in tap water in the same way as described above, in the case of a humidifier cleaner containing more than 0.1% of grapefruit extract, microorganisms do not multiply even after one month, which is equivalent to that of a conventional humidifier cleaner. It was found that there is antibacterial activity.
[실험예 3. 피부 안전성 측정]Experimental Example 3. Skin Safety Measurement
1) 실험시료1) Experimental sample
o 가습기 소독제 수용액 (탈이온수 사용)o Humidifier disinfectant solution (using deionized water)
o 폐쇄 첩포제(Large Finn Chamber)o Large Finn Chamber
o 대상 : 성인 남녀 20명o Target: 20 adults
2) 실험방법2) Experiment Method
가습기 세정제(실시예 4,6 및 비교예 2)를 탈이온수로 10배 희석하여 각 용액 45㎕를 폐쇄 첩포제에 가하고 이를 성인 남녀의 전완에 24시간 동안 첩포한다. 첩포제를 제거하고 수도물로 첩포 부위를 씻고 1시간 후에 자극 상태를 판정한다 자극의 판정은 국제적으로 공인된 ICDRG(접촉 자극 피부염 연구회) scale에 의한다.Humidifier cleaners (Examples 4, 6 and Comparative Example 2) were diluted 10-fold with deionized water and 45 μl of each solution was added to the closed patch and it was patched on the forearm of adult men and women for 24 hours. Remove the patch, wash the patch area with tap water, and determine the irritation after 1 hour. The determination of the irritation is based on the internationally recognized ICDRG scale.
ICDRG 스케일ICDRG scale
0 : 반응 없음0: no reaction
+ : 약한 자극 반응(시료 첩포 부위 대부분에 약한 홍반이 나타남)+: Mild irritant reaction (weak erythema appears in most sample patch areas)
++ : 자극 반응(첩포 부위에 확실한 홍반이 나타나고 그 밖으로도 퍼진 홍반이 나타나기도 함).++: Irritation response (definite erythema appears on the patch and spreads erythema outside).
+++ : 아주 강한 자극 반응(부종을 동반한, 강하게 퍼진 동반)+++: Very strong irritant reaction (with edema, strongly spreading)
그 실험 결과는 표 5에 나타내었다.The experimental results are shown in Table 5.
실험 결과 자몽 추출물은 통상적인 미생물 억제제보다 훨씬 피부 자극이 적은 것으로 나타나 실내에서 사용하는 가습기 소독제의 성분으로 적합함을 알 수 있다.Experimental results show that grapefruit extract is much less skin irritant than conventional microbial inhibitors, it is suitable as a component of the humidifier disinfectant used indoors.
[실험예 4. 이온봉집력 비교 실험]Experimental Example 4. Ion Rod Force Comparison Experiment
가습기 사용시 초음파 진동자나 내부 벽면에 생성되는 물때는 제거하기가 어렵고 가습기 사용 기간을 단축시켜 사용자가 불편함을 느끼게 한다. 이런 물때는 수도물 속에 존재하는 Ca , Mg 등 금속 양이온이 만드는 염을 말하며 보통 물에 잘 녹지 않는다.When the humidifier is used, it is difficult to remove the scale generated on the ultrasonic vibrator or the inner wall and shorten the period of use of the humidifier to make the user feel uncomfortable. These scales are Ca , Mg It refers to salts made by metal cations, and is usually insoluble in water.
물때 방지를 위해 이온 봉집제를 넣어준 경우 이온 봉집제는 Ca , Mg 와 미리 착물을 형성하여 물에 녹아 있으므로 물때를 형성하지 않는다. 실제 수도물에 투입했을 때 이온 봉집 효과가 있는지 알아보기 위해 가습기 세정제를 넣은 수도물에 Ca , Mg 와 불용성 염을 형성할 수 있는 시약을 가한 후 침전 형성 여부를 관찰하였다.If an ion sealant is added to prevent scale, the ion sealant is Ca , Mg Form a complex in advance and dissolve in water, so do not form scale. Ca to the tap water with humidifier , Mg After addition of a reagent capable of forming an insoluble salt with and observed the formation of precipitates.
1) 실험시료1) Experimental sample
NaCO0.1 N 용액NaCO0.1 N solution
2) 실험방법2) Experiment Method
250㎖ 삼각 플라스크에 보통의 수도물 100㎖를 넣고 가습기 세정제(실시예 3-4, 비교예 3-4)를 10㎖ 가한 후 젓개로 계속 저어준다. 뷰렛에 0.1N NaCO용액 25㎖를 채운 후 의의 삼각 플라스크에 방울 방울 떨어뜨리며 육안으로 흰색 침전이 형성되는지 관찰한다. 그 실험 결과는 표 6에 나타내었다.100 ml of normal tap water was added to a 250 ml Erlenmeyer flask, and 10 ml of a humidifier cleaner (Examples 3-4 and Comparative Example 3-4) was added, followed by stirring with a stirrer. Fill the burette with 25 ml of 0.1 N NaCO solution, and drop it into the Erlenmeyer flask to observe whether white precipitates are formed with the naked eye. The experimental results are shown in Table 6.
- : 침전이 형성되지 않음-: No precipitation
+ : 침전이 형성됨+: Precipitation is formed
실험 결과 이온 봉집제가 포함된 가습기 세정제를 첨가한 경우에는 수도물 속의 Ca , Mg 등 금속 양이온이 봉집되어 불용성 염, 즉 물때를 형성하지 않는 것을 알 수 있었다. 이온 봉집제가 포함되어 있지 않은 경우에는 금속 양이온이 이온상태로 존재하므로 음이온과 결합하여 침전을 형성하였다.Experimental results show that Ca in tap water when a humidifier cleaner containing an ion sealant is added , Mg It was found that the back metal cations were encapsulated and did not form insoluble salts, ie, scales. When the ion sealant is not included, the metal cation is in an ionic state, thereby forming a precipitate by binding to the anion.
상기의 실험 결과로 자몽 추출물을 함유하고 있는 본 발명의 가습기 세정제 조성물이 종래의 세정제 조성물과 비교하여 동등한 항균 효과가 있으며 자극이 거의 없어 인체에 안전하며 물때 방지에도 효과가 있음을 알 수 있다.As a result of the above experiment, it can be seen that the humidifier cleaner composition of the present invention containing grapefruit extract has an equivalent antimicrobial effect compared to the conventional detergent composition, has little irritation, is safe for the human body, and is effective in preventing scale.
Claims (4)
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| KR1019960039682A KR0179236B1 (en) | 1996-09-13 | 1996-09-13 | Humidifier Detergent Composition Using Natural Extracts |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101068151B1 (en) * | 2008-08-22 | 2011-09-27 | 주식회사 마크로케어 | Composition comprising of plant extract having antimicrobial and antiseptic activity and the use thereof |
| KR101706536B1 (en) | 2016-06-15 | 2017-02-15 | 주식회사 성보네츄럴시스템 | Composition for a Humidifier Comprising Hydrorized Complex Amino Acid and Humidifying Method Thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030037094A (en) * | 2001-11-02 | 2003-05-12 | 주식회사 클린연구소 | Antibiotic compositions comprising plant extract |
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- 1996-09-13 KR KR1019960039682A patent/KR0179236B1/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101068151B1 (en) * | 2008-08-22 | 2011-09-27 | 주식회사 마크로케어 | Composition comprising of plant extract having antimicrobial and antiseptic activity and the use thereof |
| KR101706536B1 (en) | 2016-06-15 | 2017-02-15 | 주식회사 성보네츄럴시스템 | Composition for a Humidifier Comprising Hydrorized Complex Amino Acid and Humidifying Method Thereof |
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