KR0146618B1 - Liquid composition to preserve toothbrush - Google Patents

Liquid composition to preserve toothbrush

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Publication number
KR0146618B1
KR0146618B1 KR1019940015804A KR19940015804A KR0146618B1 KR 0146618 B1 KR0146618 B1 KR 0146618B1 KR 1019940015804 A KR1019940015804 A KR 1019940015804A KR 19940015804 A KR19940015804 A KR 19940015804A KR 0146618 B1 KR0146618 B1 KR 0146618B1
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KR
South Korea
Prior art keywords
toothbrush
liquid composition
present
composition
toothpaste
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Application number
KR1019940015804A
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Korean (ko)
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KR960003579A (en
Inventor
안재현
장석윤
Original Assignee
성재갑
주식회사엘지화학
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Application filed by 성재갑, 주식회사엘지화학 filed Critical 성재갑
Priority to KR1019940015804A priority Critical patent/KR0146618B1/en
Publication of KR960003579A publication Critical patent/KR960003579A/en
Application granted granted Critical
Publication of KR0146618B1 publication Critical patent/KR0146618B1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46B—BRUSHES
    • A46B17/00—Accessories for brushes
    • A46B17/06—Devices for cleaning brushes after use
    • A46B17/065—Sterilising brushes; products integral with the brush for sterilising, e.g. tablets, rinse, disinfectant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases

Abstract

본 발명은 효소제와 살균제를 함유함을 특징으로 하는 치솔보관전용 액체조성물에 관한 것이다.The present invention relates to a liquid composition for toothbrush storage, comprising an enzyme and a bactericide.

본 발명의 액체조성물은 치솔을 보관할 때 살균 및 세정작용이 있어 항상 깨끗하고 부드러운 치솔모를 유지해 줄 수 있다.Liquid composition of the present invention has a sterilization and cleaning action when storing the toothbrush can always maintain a clean and soft bristles.

Description

치솔보관 전용 액체조성물Liquid composition for toothbrush storage

본 발명에 따른 치솔보관전용 액체조성물을 사용하기 위한 도구의 일예를 도시한다.An example of a tool for using a liquid composition for toothbrush storage according to the present invention is shown.

*도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1:투명한 플라스틱 또는 유리컵 2:플라스틱으로 만든 치솔 받침대1: transparent plastic or glass 2: plastic toothbrush holder

3:본 발명의 조성물3: composition of the present invention

4:치솔이 통과하지 못하는 구멍(치솔모에서 탈착된 불용분만 통과)4: Hole through which toothbrush cannot pass (only insoluble matter removed from toothbrush)

5:치솔 6:치솔모에서 탈착된 불용성분(연마제 등)5: Toothbrush 6: Insoluble ingredients desorbed from toothbrush hair (polishing agent, etc.)

본 발명은 사용한 치솔을 보관할 수 있는 액체조성물로서, 상세하게는 치솔을 보관할 때 살균 및 세정작용이 있어 항상 깨끗하고 부드러운 치솔모를 유지해 줄 수 있는 치솔보관 전용 액체조성물에 관한 것이다.The present invention relates to a liquid composition for storing the used toothbrush, and more particularly, to a toothbrush storage liquid composition capable of maintaining a clean and soft bristles due to sterilization and cleaning action when storing the toothbrush.

일반적으로 치솔은 한번 사용한 후 컵 또는 치솔고리 같은 곳에 보관하는 것이 보편화되어 있으며 다음날 사용하는 치솔모가 뻣뻣하여 사용시 불쾌감을 느낄 뿐만 아니라 치약의 분산속도가 늦고 약한 잇몸에 상처를 줄 수도 있다. 또한 치솔을 사용한 수 장시간 보관시에는 미생물이 번식하여 구강내 질병을 유발할 수 있는 요인이 된다.In general, it is common to store the toothbrush in a cup or toothbrush ring after using it once, and the bristles used on the following day are stiff, which makes you feel uncomfortable when using the toothbrush. In addition, when stored for a long time using the toothbrush, microorganisms are a factor that can cause diseases in the oral cavity.

이와 같은 문제점을 개선하기 위하여 이미 자외선 살균작용에 의한 치솔 보관 전용 용구가 상품화되어 국.내외적으로 판매되고 있다. 그러나 이러한 제품은 치솔을 장기간 보관시 자외선에 의한 살균작용으로 미생물의 번식을 막을 수는 있으나 근본적인 치솔의 세정작용은 불가능하다. 즉 치솔에 묻혀있는 치약성분이 치솔모 하단 부위에 침착되며 또한 치약성분중 부착 성질이 강한 결합제 성분들은 치솔모에 엷게 코팅되어 치솔질 후 물로 세척시 좀처럼 떨어지지 않는 성질이 있다. 또한 자외선을 이용한 살균 기구의 경우에는 전기의 사용이 필수적인 바 수분이 많은 욕실의 경우 감전의 위험을 생각하지 않을 수 없을 것이다.In order to improve such a problem, the toothbrush storage tool by ultraviolet sterilization has already been commercialized and sold domestically and internationally. However, these products can prevent the growth of microorganisms by sterilization by ultraviolet rays when the toothbrush is stored for a long time, but it is impossible to clean the toothbrush. In other words, toothpaste buried in the toothbrush is deposited on the lower part of the toothbrush hair. Also, the strong adhesive properties of the toothpaste are lightly coated on the toothbrush hair, so that the toothbrush hair does not fall off when washed with water. In addition, in the case of ultraviolet sterilization apparatus, the use of electricity is essential, in the case of a bathroom with high humidity will be forced to consider the risk of electric shock.

통상적인 치약의 필수성분으로는 연마제, 습윤제, 기포제 및 결합제가 있으며 사용목적에 따라 여러 가지 약효성분들이 첨가된다. 또한 치약의 보관 및 사용감을 양호하게 하기 위하여 약간의 방부제와 향료 및 감미제 등이 사용될 수 있다.Essential ingredients of conventional toothpaste include abrasives, wetting agents, foaming agents and binders, and various active ingredients are added according to the purpose of use. In addition, some preservatives, flavors, sweeteners, and the like may be used to improve storage and use of the toothpaste.

연마제로는 인산일 수소칼슘, 실라카, 탄산칼륨, 함수알루미나, 불용성메타 인산나트륨 등이 사용되며, 습윤제로는 글리세린, 소르비톨액, 폴리에틸렌글리콜 및 프로필렌글리콜 등이 사용된다. 기포제로는 음이온 계면활성제인 알킬황산나트륨이 대표적이며, 처방 구성에 따라 비이온 또는 양이온 계면활성제도 사용될 수 있다. 상기 성분 이외에 통상의 연고상 치약에서는 반드시 결합제 성분을 사용하여야 치약의 안전성을 유지할 수 있으며, 만약 결합제를 사용하지 않는다면 불용성 고체성분인 연마제와 액체성분인 습윤제가 쉽게 분리되어 상품가치가 없게될 것이다. 이러한 결합제로는 합성 또는 천연 고분자류가 사용되는데 비교적 가격도 저렴하고 물성이 우수한 카르복시 메틸셀루로오즈나트륨이 보편적으로 사용되고 있다. 이외에도 알긴산 또는 알긴산나트륨, 잔탄검, 아카시아검, 카라기난류 등이 사용된다.Examples of the abrasive include monohydrogen calcium phosphate, silica, potassium carbonate, hydrous alumina, insoluble meta sodium phosphate, and humectants such as glycerin, sorbitol liquid, polyethylene glycol, and propylene glycol. Typical foaming agents include sodium alkyl sulfate, an anionic surfactant, and nonionic or cationic surfactants may be used depending on the formulation. In addition to the above components, in the conventional ointment toothpaste must use a binder component to maintain the safety of the toothpaste, and if the binder is not used, the insoluble solid component and the liquid component wetting agent will be easily separated and there will be no product value. As such a binder, synthetic or natural polymers are used, and carboxymethyl cellulose sodium sodium having a relatively low price and excellent physical properties is commonly used. In addition, alginic acid or sodium alginate, xanthan gum, acacia gum, carrageenan and the like are used.

상술한 연고상 치약의 필수성분들 중에서 치솔질 후 치솔에 부착되기 가장 쉬운 성분이 결합제이며, 연마제 성분들과 치솔모 또는 치솔모의 바닥부분에 부착 또는 침착되어 건조되며 치솔모가 뻣뻣해지고 다음 사용시 불쾌감을 줄 뿐만 아니라 장기간 보관시 미생물의 번식원이 될 수 있다.Among the essential constituents of the ointment toothpaste described above, the most easy to attach to the toothbrush after brushing is the binder, and the abrasive ingredients and the toothbrush or the bottom part of the toothbrush hair are dried or dried and the stiff bristles become uncomfortable during the next use. In addition, long-term storage can be a source of microorganisms.

따라서 본 발명자들은 상술한 종래 기술의 문제점들을 해결하기 위하여 연구한 결과, 고분자인 결합제 성분을 분해시키고 살균성분을 첨가하여 미생물에 대한 오염을 방지함으로써 항상 깨끗하고 부드러운 치솔모를 유지해주는 치솔보관 전용 액체조성물을 개발하게 되었다.Therefore, the present inventors have studied to solve the above-mentioned problems of the prior art, and as a result, detoxifying the binder component as a polymer and adding a bactericidal component to prevent microbial contamination, thus always maintaining a clean and soft brush head liquid composition Was developed.

즉, 본 발명은 효소제와 살균제를 함유함을 특징으로 하는 치솔보관 전용 액체조성물에 관한 것이다.That is, the present invention relates to a toothbrush storage liquid composition comprising an enzyme and a bactericide.

본 발명에 따른 치솔보관 전용 액체조성물은 효소제 및 살균제를 필수적으로 사용하며, 용제, pH조정제 및 향료성분 등을 추가로 함유할 수 있다. 효소제는 치솔모에 부착된 결합제를 분해 용해시키는 목적으로 가수분해 효소류를 사용할 수 있으며, 바람직하게는 셀루라아제가 사용된다. 셀루라아제는 상온에서 장기간 효과를 발휘할 수 있는 농도인 그람당 10내지 100유니트를 사용하는 것이 좋다.The liquid composition for toothbrush storage according to the present invention essentially uses enzymes and fungicides, and may further contain a solvent, a pH adjuster and a flavoring ingredient. Enzymes can be used hydrolytic enzymes for the purpose of dissolving and dissolving the binder attached to the toothbrush hair, cellulase is preferably used. Cellulase is recommended to use 10 to 100 units per gram, a concentration that can exert a long-term effect at room temperature.

살균제는 그 종류가 무한하지만 구강내에서 사용되는 치솔에 사용하는 것이기 때문에 안전성이 확보되었거나 치약의 살균성분 또는 방부성분으로 사용되는 성분이 바람직하다. 이와같은 성분으로는 클로로헥시딘류, 4급 암모늄류, 파라벤류, 트리클로산 및 항생제류 등이 있다. 살균제의 사용량은 각 살균성분의 특성에 따라 다르지만, 최소 사용량은 각 성분에 따른 최소 살균농도(MBC)이상을 사용해야 하며, 지나치게 높은 농도를 사용하면 구강점막에 자극을 줄 수 있다는 점을 고려할 때 조성물중 0.01내지 1중량% 사용하는 것이 바람직하다.Fungicides are infinite in number, but since they are used in toothbrushes used in the oral cavity, components that have secured safety or are used as sterilizing or preservative ingredients of toothpaste are preferable. Such components include chlorohexidines, quaternary ammoniums, parabens, triclosan and antibiotics. Although the amount of disinfectant used depends on the characteristics of each bactericidal component, the minimum amount should be above the minimum bactericidal concentration (MBC) for each component, and considering that excessively high concentrations may irritate the oral mucosa. It is preferable to use 0.01 to 1 weight% of the inside.

효소제 또는 살균제 등을 용해하기 위해서는 용제가 필요하며, 적당한 용제로는 정제수 또는 에틸알콜을 사용한다.A solvent is required to dissolve an enzyme or a bactericide, and purified water or ethyl alcohol is used as a suitable solvent.

또한 본 발명 조성물의 최적효과를 나타내기 위해서는 pH조정제가 사용되는데, 적당한 pH조정제로는 인산나트륨염류, 염산, 수산화 나트륨 등을 사용한다. 또한 본 발명의 조성물에는 상기 성분들 이외에도 사용감을 좋게 하기 위하여 항료 성분 또는 착색제 등을 사용할 수 있다.In addition, a pH adjuster is used to exhibit the optimum effect of the composition of the present invention. Suitable pH adjusters include sodium phosphate salt, hydrochloric acid, sodium hydroxide and the like. In addition, the composition of the present invention can be used in addition to the above components in order to improve the feeling of use, such as a component or a coloring agent.

본 발명에 따른 치솔보관 전용 액체조성물은 정제수 또는 에틸알콜의 용제에 치솔모의 치약성분을 제거시키는 가수분해 효소류와 미생물 오염을 방지하기 위한 살균제를 함유시켜 통상의 방법에 따라 제조한다.Toothbrush storage liquid composition according to the present invention is prepared according to a conventional method by containing a hydrolytic enzyme to remove toothpaste components of toothbrush hair and a fungicide to prevent microbial contamination in a solvent of purified water or ethyl alcohol.

본 발명에 따른 액체 조성물의 사용방법은 첨부한 도면에 도시되어 있다. 먼저 깨끗한 프라스틱 또는 유리컵(1) 등에 치솔모 부위가 바닥으로 향하도록 꽂아놓고 본 발명 조성물(3)을 치솔모가 잠기도록 취한다. 사용시는 치솔모를 수돗물에 살짝 헹군 다음 치약을 묻혀 사용한다. 본 발명의 치솔전용 액체 조성물을 효과적으로 사용하기 위해서는 치솔모에서 탈착된 불용성분(연마제 등)들과 치솔모가 접촉하는 것을 피하는 것이 좋다.The use of the liquid composition according to the invention is illustrated in the accompanying drawings. First, the brush head is placed in a clean plastic or glass cup 1, etc. so that the brush head part faces to the bottom, and the composition 3 of the present invention is taken so that the brush head is locked. To use, rinse the brush head slightly in tap water and apply it with toothpaste. In order to effectively use the liquid composition for toothbrushes of the present invention, it is preferable to avoid contacting the brush head with insoluble components (such as an abrasive) desorbed from the brush head.

이하, 본 발명을 실시예에 의거하여 설명하지만, 이들 실시예로 본 발명의 기술적 범위가 제한되는 것은 아니다.Hereinafter, although this invention is demonstrated based on an Example, the technical scope of this invention is not restrict | limited to these Examples.

[실시예 ]EXAMPLE

실시예의 조성물은 각각 마우스워쉬(구강청정제)의 제조방법과 거의 동일하게 제조한다. 즉 물에 용해성인 물질은 정제수에 용해시키고, 에탄올에 용해성인 물질은 에탄올에 용해시킨 다음 두 용액을 혼합하고 적당한 여과장치를 사용하여 여과시킨다.The compositions of the examples are prepared in almost the same manner as the preparation of the mouthwash (oral cleaning agent), respectively. That is, the material soluble in water is dissolved in purified water, the material soluble in ethanol is dissolved in ethanol, and then the two solutions are mixed and filtered using a suitable filtration device.

[실시예1]Example 1

[실시예2] Example 2

[실시예3]Example 3

[실시예4]Example 4

이하 실시예 조성물에 대한 사용시 사용감과 장기간 보관시 미생물오염을 평가하였다.In the following Examples composition was evaluated for the feeling of use and microbial contamination during long-term storage.

[사용감 평가][Evaluation]

사용감 평가인원 10명에게 동일한 치약과 치솔을 제공하고 한 평가군당 2명씩 매일 교대로 사용토록 하여 5일간 5개의 평가군에 대하여 사용감을 평가한 후 평균치를 나타내었다.The same toothpaste and toothbrush were provided to 10 people for evaluation, and two people per evaluation group were used alternately every day.

*평가기준*Evaluation standard

5:매우양호(사용시 치솔모가 매우 부드럽다)5: very good (brush hair is very soft when used)

4:양호4: good

3:보통3: Normal

2:불량2: defective

1:매우불량(사용시 치솔모가 매우 딱딱하다)1: very poor (when used, the bristles are very hard)

[장기간 보관시 미생물 오염도 평가][Evaluation of Microbial Contamination in Long-term Storage]

사용감 평가를 완료한 치솔을 각각의 실시예 조성물과 조성물을 사용않고 공기중에 방치 및 자외선 살균기에 각각 10일간 보관한 후 치솔모에 부착된 생균수를 측정한 바 실시예 조성물과 자외선 살균기에 보관한 치솔에서는 생균수가 없는 것으로 나타났으나, 공기중에 방치한 경우는 5×10⁴개 수준으로 나타났다.Toothbrushes that completed the evaluation of the feeling of use were stored for 10 days in the air and UV sterilizers, respectively, without using each of the example compositions and compositions, and the number of viable cells attached to the brush heads was measured. No viable cell count was found in, but it was found to be 5 × 10 mm in case of being left in the air.

Claims (4)

클로로헥시딘류, 4급 암모늄류, 파라벤류, 항생제류 및 트리클로산 중에서 선택된 살균제와 셀루라아제를 함유하는 치솔보관 전용 액체조성물.Toothbrush storage liquid composition containing a fungicide and cellulase selected from chlorohexidines, quaternary ammoniums, parabens, antibiotics and triclosan. 제1항에 있어서, 셀루라아제의 사용량이 그람당 10내지 100유니트인 치솔보관전용 조성물.The composition for toothbrush storage according to claim 1, wherein the amount of the cellulase used is 10 to 100 units per gram. 제1또는 2항에 있어서, 살균제의 사용량이 0.001내지 1중량%인 치솔보관전용 조성물.The composition for toothbrush storage according to claim 1 or 2, wherein the amount of the fungicide to be used is 0.001 to 1% by weight. 제1항에 있어서, 용제, pH조정제, 향료, 착색제를 추가로 함유하는 치솔보관전용 액체조성물.The liquid composition for toothbrush storage according to claim 1, further comprising a solvent, a pH adjuster, a perfume, and a coloring agent.
KR1019940015804A 1994-07-01 1994-07-01 Liquid composition to preserve toothbrush KR0146618B1 (en)

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