KR0137505B1 - Mixed paste composition for strengthening antibiosis of laundry - Google Patents
Mixed paste composition for strengthening antibiosis of laundryInfo
- Publication number
- KR0137505B1 KR0137505B1 KR1019950027293A KR19950027293A KR0137505B1 KR 0137505 B1 KR0137505 B1 KR 0137505B1 KR 1019950027293 A KR1019950027293 A KR 1019950027293A KR 19950027293 A KR19950027293 A KR 19950027293A KR 0137505 B1 KR0137505 B1 KR 0137505B1
- Authority
- KR
- South Korea
- Prior art keywords
- laundry
- composition
- washing
- fiber
- antimicrobial
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 238000005728 strengthening Methods 0.000 title abstract description 3
- 230000003115 biocidal effect Effects 0.000 title 1
- 239000002131 composite material Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001661 Chitosan Polymers 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 4
- 230000000996 additive effect Effects 0.000 claims abstract description 4
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 238000005406 washing Methods 0.000 abstract description 25
- 230000000845 anti-microbial effect Effects 0.000 abstract description 11
- 239000004599 antimicrobial Substances 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 4
- 230000035515 penetration Effects 0.000 abstract description 4
- 230000001580 bacterial effect Effects 0.000 abstract description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 abstract 1
- GIDATFZFENCLIM-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Cl-].[NH4+].[NH4+] Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Cl-].[NH4+].[NH4+] GIDATFZFENCLIM-UHFFFAOYSA-N 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- -1 dimethyl methyl Chemical group 0.000 abstract 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 abstract 1
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N octadecanoic acid methyl ester Natural products CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 18
- 238000012545 processing Methods 0.000 description 17
- 241000894006 Bacteria Species 0.000 description 11
- 230000000844 anti-bacterial effect Effects 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 229920000742 Cotton Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 244000025254 Cannabis sativa Species 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229920001542 oligosaccharide Polymers 0.000 description 3
- 150000002482 oligosaccharides Chemical class 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000295644 Staphylococcaceae Species 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 108700023158 Phenylalanine ammonia-lyases Proteins 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000015227 regulation of liquid surface tension Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
본 발명은 세탁기에서 세탁방법중 퍼지로스에서 최종헹굼행정시 세탁물에 투입하여 세탁물에 항균막을 형성시켜 세균서식 및 침투를 억제하도록 한 세탁물의 항균강화 복합물 조성물에 관한 것으로, 본 발명은 세탁물의 복합풀 조성에 있어서, 계면활성제인 양이온계 디메칠 디스테알인 암모늄 클로라이드 25% 초산비닐계 폴리머(POLYVINYL ACETATE)30% 키토산 1-2%, UV첨가제인 2-4 디하드로 벤조 페논 1%, 물 42% 혼합하여 조성하여서 된 것을 특징으로 한다.The present invention relates to an antimicrobial strengthening composite composition of a laundry to be put into the laundry during the final rinsing administration in the washing method in the washing machine to form an antimicrobial film in the laundry to suppress bacterial formatting and penetration, the present invention is a composite pool of laundry Composition: Cationic dimethyl methyl stearate ammonium chloride 25% POLYVINYL ACETATE 30% chitosan 1-2%, UV additive 2-4 dihydro benzophenone 1%, water 42 It is characterized in that the composition by mixing.
Description
본 발명은 세탁물의 항균강화 복합풀 조성물에 관한 것으로, 특히 세탁중에 풀가공처리를 할 때 세탁방법중 드라이코스뿐만 아니라, 퍼지로스에서도 세탁물에 항균막을 형성되도록 하여 세균서식 및 침투를 억제하도록 한 세탁물의 항균강화 복합물 조성물에 관한 것이다.The present invention relates to an antimicrobial reinforced composite composition of laundry, and in particular, when the full processing process during washing, as well as the dry course of the washing method as well as fuzzy loose to form an antimicrobial film on the laundry to prevent bacterial formatting and penetration It relates to an antimicrobial strengthening composite composition.
최근 들어 생활수준이 향상되면서 세탁의 개념도 세탁력은 물론 위생 및 청결세탁으로 전환되어 가고 있으며, 일상 의류의 경우에서도 땀의 흡수와 통풍이 잘 되는 천연섬유인 면 또는 내구성, 흡습성, 착용감이 좋고, 오염을 잘 흡수하여 위생적이며 세탁하기에 편리한 합성섬유인 폴리에스텔을 주로 사용하게 된다.Recently, as the standard of living has improved, the concept of washing has been shifted not only to washing power, but also to hygiene and clean laundry. In the case of everyday clothing, cotton is a natural fiber that absorbs sweat and is well ventilated, and has good durability, hygroscopicity, and good fit. It mainly uses polyester, which is a synthetic fiber that absorbs well and is hygienic and convenient to wash.
그러나 상기 면의 경우, 그김이 잘 생기고, 형체 안정성이 부족하며, 높은 기온과 높은 습도하에서는 곰팡이, 세균등의 미생물의 침해를 받아 변색되고 강도가 떨어지는 문제점을 가지게 된다.However, in the case of the cotton, the fineness, lack of shape stability, under high temperature and high humidity has a problem of discoloration and strength decrease under the invasion of microorganisms such as mold, bacteria.
따라서 상기 종류의 의류인 경우, 세탁완료후 풀 가공을 하게 되는데, 이때 풀가공은 주로 녹말가루 및 카복실메틸 셀부로스를 주원료로 조성되어 있어, 풀가공후 고온에서 다림질을 할 경우, 전분가루가 하얗게 석출되는 문제점이 있는가 하면, 상기 풀가공은 직접의류에 손으로 뿌리거나 혹은 분사기로 분사하여 풀가공하게 되므로, 골고루 섬유에 침투되지 못하는 문제점을 가지게 되어, 세탁시 발생된 역오염, 항균, 방오 등의 제반 문제점을 해소하지 못하고, 풀가공 완료후 세탁물의 정전기 방지, 항균, 자외선 차단 효과를 얻을 수 없으며, 설령 풀가공을 하였다 하더라도 실질적으로 가공 당시에만 효과를 가지게 되고, 소정 기간이 경과하게 되면 풀가공 효과가 급격히 저하되는 문제점을 가지고 있었다.Therefore, in the case of the above-mentioned type of clothes, the processing is completed after washing, but the processing is mainly composed of starch powder and carboxymethyl cellulose as raw materials, when ironing at high temperature after processing, starch powder becomes white If there is a problem that is precipitated, the pool processing is sprayed by hand or sprayed directly into the clothing, so that the pool is processed, there is a problem that does not evenly penetrate the fiber, back contamination generated during washing, antibacterial, antifouling, etc. It is not possible to solve all the problems of the product, and it is impossible to obtain the antistatic, antibacterial, and ultraviolet ray blocking effect of the laundry after the completion of the processing, and even if the processing is carried out, it is effective only at the time of processing. There was a problem that the processing effect is sharply lowered.
따라서 상기의 문제점을 해소하기 위하여 종래에는 소정의 복합풀을 조성하여 일련의 세탁행정중 마지막 헹굼운전에서 풀가공을 실시함으로써 세탁시 발생된 역오염, 항균, 방오효과를 향상시켜왔으나, 그러나 상기 복합풀의 조성물은 세탁시 드라이코스에서는 항균막이 형성되어 세탁시 발생된 세균에 대한 항균성이 양호하게 나타났으나, 일반적인 세탁코스인 퍼지코스에서는 풀처리효과만 있을 뿐 세균에 대한 항균성은 전혀 없어 풀가공 의류중 면과 혼방은 쉽게 마모될 뿐만 아니라, 변색의 우려도 있고 착용기간이 단축되는 문제점을 가지게 되었다.Therefore, in order to solve the above problems, conventionally, a predetermined composite pool has been formed to perform reverse processing in the last rinsing operation of a series of washing operations, thereby improving reverse pollution, antibacterial and antifouling effects generated during washing, but the composite In the composition of the grass, antibacterial membrane was formed in the dry course during washing, so the antimicrobial activity was good. However, in the general washing course, the fuzzy course has only a pool treatment effect, and there is no antibacterial activity against bacteria. Cotton and blends of clothing not only wear easily, but also have a problem of discoloration and shorten the wear period.
따라서 본 발명의 목적은 일련의 세탁방법에서 풀가공을 실시할 때 드라이코스 뿐만 아니라, 퍼지코스에서도 항균막이 형성되는 복합풀조성을 하여 의류의 굽힘강도 향상은 물론, 세균 침투를 방지하여 옷감의 손상을 방지 할 수 있는 효과를 얻고자 하는데 있다.Therefore, an object of the present invention is to improve the bending strength of the garment as well as to prevent damage to the fabric by preventing the infiltration of bacteria by the composite pool composition in which the antibacterial film is formed not only in the dry course, but also in the purge course when performing the full processing in a series of washing methods It is to get the effect that can be prevented.
상기의 목적을 실현하기 위하여 본 발명은 계면활성제로 양이온계 디메칠 디스테알린 암모늄 클라이드 25%, 풀가공처리제인 초산비닐폴리머 30%, 항균제인 키토산 1-2%, 자외선차단제인 U.V첨가제 1%, 물 42%로 혼합 조성한 것을 특징으로 한다.In order to realize the above object, the present invention provides 25% of cationic dimethyl distealine ammonium clyde as a surfactant, 30% of vinyl acetate polymer as a full processing agent, 1-2% of chitosan as an antimicrobial agent, and 1% of a UV additive as a sunscreen agent. And mixed with 42% water.
따라서 본 발명의 조성에 의하면, 계면 활성제는 디메칠디스테알린 암모늄 클라이드는 효소의 활성에 영향을 주지 않으며, 강역한 계면활성을 나타내고, 또한 엷은 용액에서도 강한 침투작용을 나타낸다.Therefore, according to the composition of the present invention, the surfactant, dimethyl distealine ammonium clyde does not affect the activity of the enzyme, exhibits a strong surfactant activity, and also exhibits a strong penetrating action even in a thin solution.
그리고 수용액중에서 이온으로 해리되는 일이 없고 유성오염의 제거효과가 크며 표면장력의 저하능력이 크며, 친수기와 친유기와의 균형을 자유로이 조절할 수 있기 때문에 매우 유용하다.It is very useful because it does not dissociate into ions in aqueous solution, has great effect of removing oil pollution, has great ability of lowering surface tension, and can freely control the balance between hydrophilic and lipophilic groups.
따라서 상기 계면활성제인 디메칠 디스테알린 암모늄 클로라이드는 25%로 하는 것이 바람직하며, 상기 디메칠 디스테알린 암모늄 클로라이드가 25% 미만이면 계면 활성효과를 얻기 어려운 문제가 있고, 그 이상이면 지나친 계면활성 효과로 인하여 세정력이 저하되는 비경제적인 문제가 있다.Therefore, the dimethyl distealine ammonium chloride, which is the surfactant, is preferably 25%. If the dimethyl distealine ammonium chloride is less than 25%, there is a problem in that it is difficult to obtain an interfacial effect. There is an uneconomical problem that the cleaning power is lowered due to the effect.
또한 본 발명의 조성에서 초산비닐폴리머는 분자량이 20만인 고분자로서 풀가공처리 즉 섬유의 표면코팅제의 기능을 하며, 상기 초산비닐폴리머가 섬유와 섬유사이를 연결시키게 되어 섬유의 표면을 코팅하게 되므로 섬유의 강도 즉 굽힘강도가 보강되게 되어 섬유의 구김이 발생을 억제시키게 되는 기능을 한다.In addition, in the composition of the present invention, the vinyl acetate polymer is a polymer having a molecular weight of 200,000, and serves as a surface processing agent of a full processing, ie, a fiber, and the vinyl acetate polymer connects the fiber and the fiber to coat the surface of the fiber. The strength, that is, the bending strength of the reinforcement is a function that suppresses the occurrence of wrinkles of the fiber.
따라서 초산 비닐폴리머의 조성 함량은 30%로 하는 것이 바람직하며, 상기 소정의 함량을 초과하게 될 경우, 섬유의 강도효과는 증가되어 구김이 잘 생기지 않으나 그 대신 한번 구김이 발생되면 잘 펴지지 않게 된다.Therefore, the composition content of the vinyl acetate polymer is preferably set to 30%, and when the content exceeds the predetermined content, the strength effect of the fiber is increased and wrinkles are not easily produced, but instead, once wrinkles are generated, they are not easily stretched.
반면에 소정의 함량을 미달되면 섬유강도가 약화되는 경우 발생되어 가능한 한 소정의 함량을 벗어나지 않는 범위에서 조성이 이루어지도록 하는 것이 바람직하다.On the other hand, if the content is less than the predetermined content is generated when the fiber strength is weakened, it is desirable to make the composition in the range as far as possible without departing from the predetermined content.
그리고 본 발명 조성에서 키토산의 경우, 항균제로서 즉 세탁시 섬유표면에 항균막을 형성시켜 세탁에 의한 잔류균의 침투를 억제는 물론 섬유에서 서식하게 되는 박테리아, 곰팡이, 특히 포도상구균의 침투를 방지시키게 된다. 이때 키토산의 조성은 1-2%로 조성되는데, 그 이유는 포도상구균을 살균하기 위한 목적으로 하기 때문에 상기 조성의 범위를 벗어날 경우, 포도상구균의 살균력이 약화되거나 혹은 다른 잔류균의 번식을 돕게 된다.In the composition of the present invention, in the case of chitosan, as an antimicrobial agent, that is, forming an antimicrobial film on the surface of the fiber during washing, it inhibits the penetration of residual bacteria by washing and prevents the penetration of bacteria, fungi, especially staphylococci, which inhabit in the fiber. . At this time, the composition of chitosan is composed of 1-2%, because the purpose is to sterilize staphylococcus, if it is out of the range of the composition, the bactericidal power of staphylococcus is weakened or it helps to propagate other residual bacteria. .
따라서 키토산은 세균이 숙주(양말, 내의, 오염된 물) 와 접촉을 하게 되면 엔도(endo)형 키토산과 엔도형 베타글루켄아제(β-glucanase)가 함께 작용하여 병원균 세포벽으로부터 키토산 올리고당을 생성한다.Thus, when the bacteria come into contact with the host (socks, inside, contaminated water), endo-type chitosan and endo-beta-glucanase work together to produce chitosan oligosaccharides from the cell wall of the pathogen. .
이때 키토산 올리고당은 상기 숙주속에 DNA를 부활하여 피토알렉신(phytlalexine) 등 항균물질이나 린닌(lignin)형성에 관여하는 페닐 알라닌 암모니아릴라제(phenylalaine ammonialyase) 생산을 촉진한다.At this time, chitosan oligosaccharides reactivate DNA in the host to promote the production of phenylalanine ammonialyase, which is involved in the formation of antibacterial substances such as phytlalexine or lignin.
한편 키토산 올리고당은 병원균 세포속에서 DNA로 부터 RNA로의 전사를 차단, 세균의 생육을 저지하여 항균효과를 나타내게 된다.On the other hand, chitosan oligosaccharides block the transcription from DNA to RNA in pathogen cells, inhibiting the growth of bacteria and exhibiting antimicrobial effects.
그러므로 본 발명에서은 상기의 풀가공조성물로 의류에 풀가공을 하게 되면, 일반적인 퍼지코스에서도 세탁물의 표면에 항균막이 형성되어 섬유의 강도가 증강은 물론 특히 반복세탁으로 인하여 후들그레지는 형태가 회복되어 본래의 힘있는 의류를 착용할 수 있고, 섬유의 표면이 매끄러워 쉽게 오염물이 부착되지 않아 오염물이나 세균이 섬유내에 침투가 어려울 뿐만 아니라, 설령 오염물이나 세균이 부착된다 하더라도 섬유의 표면에만 부착되게 되므로 세탁시 쉽게 제거할 수 있는 효과를 주게 된다,Therefore, in the present invention, when the full processing of the garment with the above-mentioned full composition, the antimicrobial film is formed on the surface of the laundry even in the general purge course, and the strength of the fiber is not only enhanced, but especially after the repeated washing, the shape of the hump grain is recovered. Powerful clothing can be worn, and the surface of the fiber is smooth, so that contaminants are not easily adhered, making it difficult for contaminants or bacteria to penetrate into the fiber, and even if contaminants or bacteria are attached, they are only attached to the surface of the fiber. Will give you an easy to remove effect.
이하 첨부된 실시예에 의거 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying examples.
[실시예]EXAMPLE
본 발명은 표 1에 도시한 바와 같이 계면활성제인 양이온계 디메칠 디스테알린 암모늄 클로라이드가 25%, 초산비닐계 폴리머(POLYVINYL ACETATE)30%, 키토산 1-2%, UV첨가제인 2-4 디하드로 벤조 페논 1%, 그리고 물 42% 혼합하여 조성을 하게 된다.In the present invention, as shown in Table 1, 25% of cationic dimethyl distealine ammonium chloride as a surfactant, 30% of vinyl acetate polymer (POLYVINYL ACETATE), 1-2% of chitosan, 2-4 di of UV additive Hard 1% benzophenone and 42% water are mixed.
(실시예)(Example)
상기와 같이 조성된 복합풀을 일련의 세탁행정인 퍼지코스 및 드라이코스로 세탁을 실시하지 전에 정전기 방지제 투입구에 물 20L 기준하여 15g, 드라이코스시 물 20L 기준하여 30g을 투입시켜 놓게 상태에서, 이후 세탁을 진행하다가 일련의 세탁행정이 완료되고, 일련의 헹굼행정에서 최종헹굼시 상기 정전기 방지제 투입구에 투입되어 있는 상기 복합풀이 자동 투입되면서 헹굼행정을 하게 되므로, 상기 복합 풀은 수류에 의하여 세탁물에 섬유와 섬유에 골고루 스며들게 되어 세탁물의 표면을 코팅하게 된다.Before washing the composite pool prepared as described above with a series of washing administration purge course and dry course, 15g of water based on 20L of water and 30g of water of 20L of dry course are put into the antistatic agent. During the washing process, a series of washing strokes are completed, and when the final rinsing in the series of rinsing strokes is performed, the composite pool, which is injected into the antistatic agent inlet, is automatically added to the rinsing stroke, and thus the composite pool is made of fiber to the laundry by water flow. It will soak evenly into the fibers and coat the surface of the laundry.
상기와 같이 실시예에 의하여 표면처리가 완료된 세탁물과 종래 풀에 의하여 표면처리가 된 세탁물과의 굽힘강도 및 마찰대전성, 항균도를 측정해 본 결과 표 1에 나타내었다.As shown in Table 1, the bending strength, the triboelectric chargeability, and the antimicrobial activity of the laundry with the surface treatment according to the embodiment and the laundry with the surface treatment by the conventional grass were measured.
시험조건Exam conditions
1.시험세탁기 : 대우 세탁기 DWF-9290RDS1.Test washing machine: Daewoo washing machine DWF-9290RDS
2.수온 : 18℃2.Water temperature: 18 ℃
3. 시험방법3. Test method
퍼지코스 : 면 100% 원단Fuzzy Course: 100% Cotton Fabric
Y셔츠 (면 60% 폴리에스테르 40% 혼방)Y-shirt (60% cotton 40% blend)
드라이 : 순모원단, 순모양복Dry: Wool Fabric, Pure Wool Clothes
[표 1]TABLE 1
상기 실험결과에 의하여 풀가공효과 즉 굽힘강도를 살펴보면, 퍼지코스에서는 종래의 풀에 비하여 섬유의 굽힘강도는 크게 향상됨을 보이지 않았지만, 드라이코스에서 본 발명제는 종래의 풀에 비하여 2배 정도 강도가 향상된 것으로 보아 양복등과 같은 고급소재의 형태안정성 유지 측면에서 매우 효과적이라 하겠다.According to the results of the experiment, the processing effect, that is, the bending strength, the fuzzy course did not show a significant improvement in the bending strength of the fiber compared to the conventional pool, but in the dry course, the present invention has about twice the strength of the conventional pool. The improvement is very effective in maintaining the shape stability of high quality materials such as suits.
또한 의류를 착용시 부수적으로 발생되는 불쾌감을 주는 정전기의 발생력 마찰대전성(정전기방지효과)을 살펴보면, 퍼지코스와 드라이코스에서 각각 종래의 풀에 비하여 본 발명제가 1/3-1/4 수준으로 낮게 나타나 본 발명제로 물 먹임을 하게 되면, 마찰에 의해서도 정전기를 느낄 수 없어 착용감이 좋아진다.In addition, when looking at the generation force of the static electricity caused by the incidental discomfort when wearing clothing (antistatic effect), in the fuzzy course and dry course, the present invention is 1 / 3-1 / 4 level compared to the conventional pool, respectively When it appears low and water is fed with the present invention, it is not possible to feel static electricity even by friction, which improves the fit.
그리고 항균력에 대하여 살펴보면, 특히 양말, 내의, 양복 등에 주로 서식하고, 세탁시 오수로 인해 세탁조에 잔류하기 쉬운 포도상구균에 풀 가공을 위한 의류를 넣고 소정시간 방치한 후 세균의 양을 측정한 결과, 종래풀의 경우 항균효과가 없는 반면에 드라이코스 뿐만 아니라 퍼지코스에서 본 발명제가 99.9%의 항균효과가 있는 것으로 나타나 일상생활에서 세탁할 때 주로 하게 되는 퍼지코스에서도 면과 폴리에스텔과 같은 의류에 안전성 회복은 물론, 세균에 대한 항균성이 부여할 수 있게 되는 것이다.In addition, the antibacterial activity, in particular, mainly in socks, underwear, clothes, etc., and put the clothing for processing in the staphylococci, which are likely to remain in the washing tank due to sewage during washing, and left for a predetermined time to measure the amount of bacteria, While conventional grass has no antibacterial effect, the present invention has a 99.9% antimicrobial effect not only in dry course but also in fuzzy course, so it is safe for clothing such as cotton and polyester even in fuzzy course which is mainly used when washing in daily life. Recovery, of course, can be given to antibacterial activity.
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950027293A KR0137505B1 (en) | 1995-08-29 | 1995-08-29 | Mixed paste composition for strengthening antibiosis of laundry |
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| KR1019950027293A KR0137505B1 (en) | 1995-08-29 | 1995-08-29 | Mixed paste composition for strengthening antibiosis of laundry |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100839089B1 (en) * | 2005-03-15 | 2008-06-20 | 가부시키 가이샤 교토산교 | Washing method |
| CN103147307A (en) * | 2012-12-06 | 2013-06-12 | 青岛海芬海洋生物科技有限公司 | Embroidery artware antibiosis and mildew-proof care solution |
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1995
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100839089B1 (en) * | 2005-03-15 | 2008-06-20 | 가부시키 가이샤 교토산교 | Washing method |
| CN103147307A (en) * | 2012-12-06 | 2013-06-12 | 青岛海芬海洋生物科技有限公司 | Embroidery artware antibiosis and mildew-proof care solution |
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